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20 pages, 25581 KiB  
Article
Phase Synchronisation for Tonal Noise Reduction in a Multi-Rotor UAV
by Burak Buda Turhan, Djamel Rezgui and Mahdi Azarpeyvand
Drones 2025, 9(8), 544; https://doi.org/10.3390/drones9080544 (registering DOI) - 1 Aug 2025
Abstract
This study aims to investigate the effects of phase synchronisation on tonal noise reduction in a multi-rotor UAV using an electronic phase-locking system. Experiments at the University of Bristol explored the impact of relative phase angle, propeller spacing, and blade geometry on acoustic [...] Read more.
This study aims to investigate the effects of phase synchronisation on tonal noise reduction in a multi-rotor UAV using an electronic phase-locking system. Experiments at the University of Bristol explored the impact of relative phase angle, propeller spacing, and blade geometry on acoustic performance, including psychoacoustic annoyance. Results show that increasing the phase angle consistently reduces the sound pressure level (SPL) due to destructive interference. For the two-bladed configuration, the highest noise reduction occurred at relative phase angle Δψ=90, with a 19 dB decrease at the first blade-passing frequency (BPF). Propeller spacing had minimal impact when phase synchronisation was applied. The pitch-to-diameter (P/D) ratio also influenced results: for P/D=0.55, reductions ranged from 13–18 dB; and for P/D=1.0, reductions ranged from 10–20 dB. Maximum psychoacoustic annoyance was observed when propellers were in phase (Δψ=0), while annoyance decreased with increasing phase angle, confirming the effectiveness of phase control for noise mitigation. For the five-bladed configuration, the highest reduction of 15 dB occurred at Δψ=36, with annoyance levels also decreasing with phase offset. Full article
(This article belongs to the Special Issue Urban Air Mobility Solutions: UAVs for Smarter Cities)
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34 pages, 4436 KiB  
Article
Structure of the Secretory Compartments in Goblet Cells in the Colon and Small Intestine
by Alexander A. Mironov, Irina S. Sesorova, Pavel S. Vavilov, Roberto Longoni, Paola Briata, Roberto Gherzi and Galina V. Beznoussenko
Cells 2025, 14(15), 1185; https://doi.org/10.3390/cells14151185 - 31 Jul 2025
Abstract
The Golgi of goblet cells represents a specialized machine for mucin glycosylation. This process occurs in a specialized form of the secretory pathway, which remains poorly examined. Here, using high-resolution three-dimensional electron microscopy (EM), EM tomography, serial block face scanning EM (SBF-SEM) and [...] Read more.
The Golgi of goblet cells represents a specialized machine for mucin glycosylation. This process occurs in a specialized form of the secretory pathway, which remains poorly examined. Here, using high-resolution three-dimensional electron microscopy (EM), EM tomography, serial block face scanning EM (SBF-SEM) and immune EM we analyzed the secretory pathway in goblet cells and revealed that COPII-coated buds on the endoplasmic reticulum (ER) are extremely rare. The ERES vesicles with dimensions typical for the COPII-dependent vesicles were not found. The Golgi is formed by a single cisterna organized in a spiral with characteristics of the cycloid surface. This ribbon has a shape of a cup with irregular perforations. The Golgi cup is filled with secretory granules (SGs) containing glycosylated mucins. Their diameter is close to 1 µm. The cup is connected with ER exit sites (ERESs) with temporal bead-like connections, which are observed mostly near the craters observed at the externally located cis surface of the cup. The craters represent conus-like cavities formed by aligned holes of gradually decreasing diameters through the first three Golgi cisternae. These craters are localized directly opposite the ERES. Clusters of the 52 nm vesicles are visible between Golgi cisternae and between SGs. The accumulation of mucin, started in the fourth cisternal layer, induces distensions of the cisternal lumen. The thickness of these distensions gradually increases in size through the next cisternal layers. The spherical distensions are observed at the edges of the Golgi cup, where they fuse with SGs and detach from the cisternae. After the fusion of SGs located just below the apical plasma membrane (APM) with APM, mucus is secreted. The content of this SG becomes less osmiophilic and the excessive surface area of the APM is formed. This membrane is eliminated through the detachment of bubbles filled with another SG and surrounded with a double membrane or by collapse of the empty SG and transformation of the double membrane lacking a visible lumen into multilayered organelles, which move to the cell basis and are secreted into the intercellular space where the processes of dendritic cells are localized. These data are evaluated from the point of view of existing models of intracellular transport. Full article
10 pages, 1588 KiB  
Article
The Effect of Bioactive Varnishes Containing tt-Farnesol, Quercetin, and Theobromine in Preventing Enamel Caries Lesion Formation in a Cariogenic-Free Model
by Carine Rabelo Bispo, Regina Maria Puppin-Rontani, Frank Lippert and Aline Rogéria Freire de Castilho
Appl. Sci. 2025, 15(15), 8440; https://doi.org/10.3390/app15158440 - 30 Jul 2025
Viewed by 61
Abstract
Background: Dental enamel demineralization is a critical early event in the development of dental caries. To address this, bioactive compounds have been explored for their potential to mitigate enamel demineralization and promote remineralization. Previous studies have demonstrated that varnishes containing natural compounds such [...] Read more.
Background: Dental enamel demineralization is a critical early event in the development of dental caries. To address this, bioactive compounds have been explored for their potential to mitigate enamel demineralization and promote remineralization. Previous studies have demonstrated that varnishes containing natural compounds such as trans,trans-farnesol (tt-farnesol), quercetin, and theobromine exhibit antimicrobial activity, suggesting potential in caries prevention. Thus, this laboratory study assessed the ability of these varnishes to prevent enamel caries lesion formation by using a chemical model to determine whether these natural compounds interfered with de- and remineralization processes in the absence of a cariogenic biofilm. Methods: Sixty bovine enamel specimens, each measuring 5 × 5 × 2 mm, were selected according to their initial surface hardness (SHI), measured by Knoop hardness in three indentations spaced 100 µm apart. The specimens were allocated to the following groups in a random manner (n = 15): an experimental varnish without compounds (NC/negative control); experimental varnishes containing the combination of tt-farnesol, quercetin, and theobromine at concentrations of 1.5% (E1) and 4.5% (E2); and Duraphat™ (NaF 5%/gold standard—D). After applying the varnishes, they remained in artificial saliva for 6 h. The specimens were then subjected to 8 pH cycles, including 4 h of demineralization and 20 h of remineralization. Surface hardness was measured again to calculate the percentage of surface hardness loss (%SHL), and three specimens from each group were examined using scanning electron microscopy. Comparisons were made using ANOVA (p < 0.05). Results: The D group (5% NaF) demonstrated a significantly lower %SHL (75.5% ± 7.88) than the other groups (p < 0.05). E1 (86.3% ± 5.33) was statistically similar to NC (81.8% ± 4) but lower than E2. E2 showed the highest %SHL (91.6% ± 3.64) compared to the other groups. Surface demineralization was evident in all specimens post pH cycling. Conclusion: The bioactive varnishes containing tt-farnesol, quercetin, and theobromine at concentrations of 1.5% and 4.5% did not exhibit a protective effect against mineral loss in dental enamel in the absence of a cariogenic biofilm. Full article
(This article belongs to the Special Issue Dental Biomaterials and Implants: Latest Advances and Prospects)
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13 pages, 1022 KiB  
Article
Dual-Layer Spectral CT with Electron Density in Bone Marrow Edema Diagnosis: A Valid Alternative to MRI?
by Filippo Piacentino, Federico Fontana, Cecilia Beltramini, Andrea Coppola, Daniele Mesiano, Gloria Venturini, Chiara Recaldini, Roberto Minici, Anna Maria Ierardi, Velio Ascenti, Simone Barbera, Fabio D’Angelo, Domenico Laganà, Gianpaolo Carrafiello, Giorgio Ascenti and Massimo Venturini
J. Clin. Med. 2025, 14(15), 5319; https://doi.org/10.3390/jcm14155319 - 28 Jul 2025
Viewed by 211
Abstract
Background/Objectives: Although MRI with fat-suppression sequences is the gold standard for diagnosis of bone marrow edema (BME), Dual-Layer Spectral CT (DL-SCT) with electron density (ED) provides a viable alternative, particularly in situations where an MRI is not accessible. Using MRI as the [...] Read more.
Background/Objectives: Although MRI with fat-suppression sequences is the gold standard for diagnosis of bone marrow edema (BME), Dual-Layer Spectral CT (DL-SCT) with electron density (ED) provides a viable alternative, particularly in situations where an MRI is not accessible. Using MRI as the reference standard, this study analyzed how DL-SCT with ED reconstructions may be a valid alternative in the detection of BME. Methods: This retrospective study included 28 patients with a suspected diagnosis of BME via MRI conducted between March and September 2024. Patients underwent DL-SCT using ED reconstructions obtained through IntelliSpace software v. 12.1. Images were evaluated by two experienced radiologists and one young radiologist in a blinded way, giving a grade from 0 to 3 to classify BME (0 absence; 1 mild; 2 moderate; 3 severe). To reduce the recall bias effect, the order of image evaluations was set differently for each reader. p-Values were considered significant when <0.05. Fleiss’ Kappa was used to assess inter-rater reliability: agreement was considered poor for k < 0; slight for k 0.01–0.20; fair for 0.21–0.40; moderate for 0.41–0.60; substantial for 0.61–0.80; and almost perfect for 0.81–1.00. Results: All the readers detected the presence or absence of BME using DL-SCT. Inter-rater reliability for grade 0 resulted in 1 (p-value < 0.001); for grade 1: 0.21 (p-value < 0.001); for grade 2: 0.197 (p-value < 0.001); and for grade 3: 0.515 (p-value < 0.001). Conclusions: ED reconstructions allowed the identification of BME presence or absence in all analyzed cases, thus suggesting DL-SCT as a potentially effective method for its detection. Full article
(This article belongs to the Section Nuclear Medicine & Radiology)
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20 pages, 3560 KiB  
Article
Study on Vibration Effects and Optimal Delay Time for Tunnel Cut-Blasting Beneath Existing Railways
by Ruifeng Huang, Wenqing Li, Yongxiang Zheng and Zhong Li
Appl. Sci. 2025, 15(15), 8365; https://doi.org/10.3390/app15158365 - 28 Jul 2025
Viewed by 152
Abstract
With the development of underground space in urban areas, the demand for tunneling through existing railways is increasing. The adverse effects of cut-blasting during the construction of tunnels under crossing existing railways are investigated. Combined with the principle of blasting seismic wave superposition, [...] Read more.
With the development of underground space in urban areas, the demand for tunneling through existing railways is increasing. The adverse effects of cut-blasting during the construction of tunnels under crossing existing railways are investigated. Combined with the principle of blasting seismic wave superposition, LS-DYNA numerical simulation is used to analyze the seismic wave superposition law under different superposition methods. This study also investigates the vibration reduction effect of millisecond blasting for cut-blasting under the different classes of surrounding rocks. The results show that the vibration reduction forms of millisecond blasting can be divided into separation and interference of waveform. Based on the principle of superposition of blasting seismic waves, vibration reduction through wave interference is further divided. At the same time, a new vibration reduction mode is proposed. This vibration reduction mode can significantly improve construction efficiency while improving damping efficiency. The new vibration reduction mode can increase the vibration reduction to 80% while improving construction efficiency. Additionally, there is a significant difference in the damping effect of different classes of surrounding rock on the blasting seismic wave. Poor-quality surrounding rock enhances the attenuation of seismic wave velocity and peak stress in the surrounding rock. In the Zhongliangshan Tunnel, a tunnel cut-blasting construction at a depth of 42 m, the best vibration reduction plan of Class III is 3 ms millisecond blasting, in which the surface points achieve separation vibration reduction. The best vibration reduction plan of Class V is 1 ms millisecond blasting, in which the surface points achieve a new vibration reduction mode. During the tunnel blasting construction process, electronic detonators are used for millisecond blasting of the cut-blasting. This method can reduce the vibration effects generated by blasting. The stability of the existing railway is ultimately guaranteed. This can improve construction efficiency while ensuring construction safety. This study can provide significant guidance for the blasting construction of the tunnel through the railway. Full article
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13 pages, 8086 KiB  
Article
Flexible FLIG-Based Temperature Sensor Enabled by Femtosecond Laser Direct Writing for Thermal Monitoring in Health Systems
by Huansheng Wu, Cong Wang, Linpeng Liu and Ji’an Duan
Sensors 2025, 25(15), 4643; https://doi.org/10.3390/s25154643 - 26 Jul 2025
Viewed by 262
Abstract
In this study, a facile and mask-free femtosecond laser direct writing (FLDW) approach is proposed to fabricate porous graphene (FLIG) patterns directly on polyimide (PI) substrates. By systematically adjusting the laser scanning spacing (10–25 μm), denser and more continuous microstructures are obtained, resulting [...] Read more.
In this study, a facile and mask-free femtosecond laser direct writing (FLDW) approach is proposed to fabricate porous graphene (FLIG) patterns directly on polyimide (PI) substrates. By systematically adjusting the laser scanning spacing (10–25 μm), denser and more continuous microstructures are obtained, resulting in significantly enhanced thermal sensitivity. The optimized sensor demonstrated a temperature coefficient of 0.698% °C−1 within the range of 40–120 °C, with response and recovery times of 10.3 s and 20.9 s, respectively. Furthermore, it exhibits remarkable signal stability across multiple thermal cycles, a testament to its reliability in extreme conditions. Moreover, the sensor was successfully integrated into a 3D-printed robotic platform, achieving both contact and non-contact temperature detection. These results underscore the sensor’s practical adaptability for real-time thermal sensing. This work presents a viable and scalable methodology for fabricating high-performance FLIG-based flexible temperature sensors, with extensive application prospects in wearable electronics, electronic skin, and intelligent human–machine interfaces. Full article
(This article belongs to the Special Issue State of the Art in Wearable Sensors for Health Monitoring)
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18 pages, 384 KiB  
Article
Optimized Snappy Compression with Enhanced Encoding Strategies for Efficient FPGA Implementation
by Huan Zhang, Chenpu Li, Meiting Xue, Bei Zhao and Jianrong Bao
Electronics 2025, 14(15), 2987; https://doi.org/10.3390/electronics14152987 - 26 Jul 2025
Viewed by 219
Abstract
The extensive utilization of the Snappy compression algorithm in digital devices such as smartphones, IoT, and digital cameras has played a crucial role in alleviating demands on network bandwidth and storage space. This paper presents an improved Snappy compression algorithm optimized for implementation [...] Read more.
The extensive utilization of the Snappy compression algorithm in digital devices such as smartphones, IoT, and digital cameras has played a crucial role in alleviating demands on network bandwidth and storage space. This paper presents an improved Snappy compression algorithm optimized for implementation on field programmable gate arrays (FPGAs). The proposed algorithm enhances the compression ratio by refining the encoding format of Snappy and introduces an innovative approach utilizing fingerprints within the dictionary to minimize storage space requirements. Additionally, the algorithm incorporates a pipeline structure to optimize performance. Experimental results demonstrate that the proposed algorithm achieves a throughput of 1.6 GB/s for eight hardware kernels. The average compression ratio is 2.27, representing a 6.1% improvement over the state-of-the-art Snappy FPGA implementation. Notably, the proposed algorithm architecture consumes fewer on-chip storage resources compared to other advanced algorithms, striking a balance between logic and storage resource utilization. This optimization leads to higher FPGA resource utilization efficiency. Our design addresses the growing demand for efficient lossless data compression solutions in consumer electronics, ultimately contributing to advancements in modern digital ecosystems. Full article
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9 pages, 2733 KiB  
Data Descriptor
Investigating Mid-Latitude Lower Ionospheric Responses to Energetic Electron Precipitation: A Case Study
by Aleksandra Kolarski, Vladimir A. Srećković, Zoran R. Mijić and Filip Arnaut
Data 2025, 10(8), 121; https://doi.org/10.3390/data10080121 - 26 Jul 2025
Viewed by 171
Abstract
Localized ionization enhancements (LIEs) in altitude range corresponding to the D-region ionosphere, disrupting Very-Low-Frequency (VLF) signal propagation. This case study focuses on Lightning-induced Electron Precipitation (LEP), analyzing amplitude and phase variations in VLF signals recorded in Belgrade, Serbia, from worldwide transmitters. Due to [...] Read more.
Localized ionization enhancements (LIEs) in altitude range corresponding to the D-region ionosphere, disrupting Very-Low-Frequency (VLF) signal propagation. This case study focuses on Lightning-induced Electron Precipitation (LEP), analyzing amplitude and phase variations in VLF signals recorded in Belgrade, Serbia, from worldwide transmitters. Due to the localized, transient nature of Energetic Electron Precipitation (EEP) events and the path-dependence of VLF responses, research relies on event-specific case studies to model reflection height and sharpness via numerical simulations. Findings show LIEs are typically under 1000 × 500 km, with varying internal structure. Accumulated case studies and corresponding data across diverse conditions contribute to a broader understanding of ionospheric dynamics and space weather effects. These findings enhance regional modeling, support aerosol–electricity climate research, and underscore the value of VLF-based ionospheric monitoring and collaboration in Europe. Full article
(This article belongs to the Section Spatial Data Science and Digital Earth)
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24 pages, 8575 KiB  
Article
Space Charge Structures on Spherical Hollow Electrodes
by Florin Enescu, Codrina Ionita, Dan Gheorghe Dimitriu and Roman Schrittwieser
Plasma 2025, 8(3), 30; https://doi.org/10.3390/plasma8030030 - 25 Jul 2025
Viewed by 158
Abstract
In this article, we present an overview of our investigations on the formation and behavior of space charge structures in an argon discharge plasma on gridded and smooth spherical hollow electrodes with and without orifices. Four experiments are described, in which we have [...] Read more.
In this article, we present an overview of our investigations on the formation and behavior of space charge structures in an argon discharge plasma on gridded and smooth spherical hollow electrodes with and without orifices. Four experiments are described, in which we have used the following: (1) one spherical gridded sphere with one orifice, (2) one hollow smooth stainless steel sphere with two opposing orifices, (3) two smooth polished stainless steel spherical electrodes without orifices, (4) two smooth polished stainless steel spherical electrodes with opposing orifices. The experiments were conducted at the University of Innsbruck in a stainless steel cylindrical chamber (the former Innsbruck DP machine—IDP), and at the Alexandru Ioan Cuza University of Iaşi (Romania) in a Pyrex Vacuum Chamber (PCH). As diagnostics, we have used mainly optical emission spectroscopy to determine electron temperature and density. Full article
(This article belongs to the Special Issue Feature Papers in Plasma Sciences 2025)
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18 pages, 3870 KiB  
Article
Universal Vector Calibration for Orientation-Invariant 3D Sensor Data
by Wonjoon Son and Lynn Choi
Sensors 2025, 25(15), 4609; https://doi.org/10.3390/s25154609 - 25 Jul 2025
Viewed by 200
Abstract
Modern electronic devices such as smartphones, wearable devices, and robots typically integrate three-dimensional sensors to track the device’s movement in the 3D space. However, sensor measurements in three-dimensional vectors are highly sensitive to device orientation since a slight change in the device’s tilt [...] Read more.
Modern electronic devices such as smartphones, wearable devices, and robots typically integrate three-dimensional sensors to track the device’s movement in the 3D space. However, sensor measurements in three-dimensional vectors are highly sensitive to device orientation since a slight change in the device’s tilt or heading can change the vector values. To avoid complications, applications using these sensors often use only the magnitude of the vector, as in geomagnetic-based indoor positioning, or assume fixed device holding postures such as holding a smartphone in portrait mode only. However, using only the magnitude of the vector loses the directional information, while ad hoc posture assumptions work under controlled laboratory conditions but often fail in real-world scenarios. To resolve these problems, we propose a universal vector calibration algorithm that enables consistent three-dimensional vector measurements for the same physical activity, regardless of device orientation. The algorithm works in two stages. First, it transforms vector values in local coordinates to those in global coordinates by calibrating device tilting using pitch and roll angles computed from the initial vector values. Second, it additionally transforms vector values from the global coordinate to a reference coordinate when the target coordinate is different from the global coordinate by correcting yaw rotation to align with application-specific reference coordinate systems. We evaluated our algorithm on geomagnetic field-based indoor positioning and bidirectional step detection. For indoor positioning, our vector calibration achieved an 83.6% reduction in mismatches between sampled magnetic vectors and magnetic field map vectors and reduced the LSTM-based positioning error from 31.14 m to 0.66 m. For bidirectional step detection, the proposed algorithm with vector calibration improved step detection accuracy from 67.63% to 99.25% and forward/backward classification from 65.54% to 100% across various device orientations. Full article
(This article belongs to the Section Intelligent Sensors)
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13 pages, 3688 KiB  
Article
Influence Mechanisms of Trace Rare-Earth Ce on Texture Development of Non-Oriented Silicon Steel
by Feihu Guo, Yuhao Niu, Bing Fu, Jialong Qiao and Shengtao Qiu
Materials 2025, 18(15), 3493; https://doi.org/10.3390/ma18153493 - 25 Jul 2025
Viewed by 219
Abstract
The effects of trace Ce on the microstructure and texture of non-oriented silicon steel during recrystallization and grain growth were examined using X-ray diffraction and electron backscatter diffraction. Additionally, this study focused on investigating the mechanisms by which trace Ce influences the evolution [...] Read more.
The effects of trace Ce on the microstructure and texture of non-oriented silicon steel during recrystallization and grain growth were examined using X-ray diffraction and electron backscatter diffraction. Additionally, this study focused on investigating the mechanisms by which trace Ce influences the evolution of the {114} <481> and γ-fiber textures. During the recrystallization process, as the recrystallization fraction of annealed sheets increased, the intensity of α-fiber texture decreased, while the intensities of α*-fiber and γ-fiber textures increased. The {111} <112> grains preferentially nucleated in the deformed γ-grains and their grain-boundary regions and tended to form a colony structure with a large amount of nucleation. In addition, the {100} <012> and {114} <481> grains mainly nucleated near the deformed α-grains, which were evenly distributed but found in relatively small quantities. The hindering effect of trace Ce on dislocation motion in cold-rolled sheets results in a 2–7% lower recrystallization ratio for the annealed sheets, compared to conventional annealed sheets. Trace Ce suppresses the nucleation and growth of γ-grains while creating opportunities for α*-grain nucleation. During grain growth, trace Ce reduces γ-grain-boundary migration rate in annealed sheets, providing growth space for {114} <418> grains. Consequently, the content of the corresponding {114} <481> texture increased by 6.4%, while the γ-fiber texture content decreased by 3.6%. Full article
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18 pages, 564 KiB  
Article
Electrons in Quantum Dots on Helium: From Charge Qubits to Synthetic Color Centers
by Mark I. Dykman and Johannes Pollanen
Entropy 2025, 27(8), 787; https://doi.org/10.3390/e27080787 - 25 Jul 2025
Viewed by 149
Abstract
Electrons trapped above the surface of helium provide a means to study many-body physics free from the randomness that comes from defects in other condensed-matter systems. Localizing an electron in an electrostatic quantum dot makes its energy spectrum discrete, with controlled level spacing. [...] Read more.
Electrons trapped above the surface of helium provide a means to study many-body physics free from the randomness that comes from defects in other condensed-matter systems. Localizing an electron in an electrostatic quantum dot makes its energy spectrum discrete, with controlled level spacing. The lowest two states can act as charge qubit states. In this paper, we study how the coupling to the quantum field of capillary waves on helium—known as ripplons—affects electron dynamics. As we show, the coupling can be strong. This bounds the parameter range where electron-based charge qubits can be implemented. The constraint is different from the conventional relaxation time constraint. The electron–ripplon system in a dot is similar to a color center formed by an electron defect coupled to phonons in a solid. In contrast to solids, the coupling in the electron on helium system can be varied from strong to weak. This enables a qualitatively new approach to studying color center physics. We analyze the spectroscopy of the pertinent synthetic color centers in a broad range of the coupling strength. Full article
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29 pages, 6770 KiB  
Article
Machine Learning-Driven Design and Optimization of Multi-Metal Nitride Hard Coatings via Multi-Arc Ion Plating Using Genetic Algorithm and Support Vector Regression
by Yu Gu, Jiayue Wang, Jun Zhang, Yu Zhang, Bushi Dai, Yu Li, Guangchao Liu, Li Bao and Rihuan Lu
Materials 2025, 18(15), 3478; https://doi.org/10.3390/ma18153478 - 24 Jul 2025
Viewed by 216
Abstract
The goal of this study is to develop an efficient machine learning framework for designing high-hardness multi-metal nitride coatings, overcoming the limitations of traditional trial-and-error methods. The development of multicomponent metal nitride hard coatings via multi-arc ion plating remains a significant challenge due [...] Read more.
The goal of this study is to develop an efficient machine learning framework for designing high-hardness multi-metal nitride coatings, overcoming the limitations of traditional trial-and-error methods. The development of multicomponent metal nitride hard coatings via multi-arc ion plating remains a significant challenge due to the vast compositional search space. Although theoretical studies in macroscopic, mesoscopic, and microscopic domains exist, these often focus on idealized models and lack effective coupling across scales, leading to time-consuming and labor-intensive traditional methods. With advancements in materials genomics and data mining, machine learning has become a powerful tool in material discovery. In this work, we construct a compositional search space for multicomponent nitrides based on electronic configuration, valence electron count, electronegativity, and oxidation states of metal elements in unary nitrides. The search space is further constrained by FCC crystal structure and hardness theory. By incorporating a feature library with micro-, meso-, and macro-structural characteristics and using clustering analysis with theoretical intermediate variables, the model enriches dataset information and enhances predictive accuracy by reducing experimental errors. This model is successfully applied to design multicomponent metal nitride coatings using a literature-derived database of 233 entries. Experimental validation confirms the model’s predictions, and clustering is used to minimize experimental and data errors, yielding a strong agreement between predicted optimal molar ratios of metal elements and nitrogen and measured hardness performance. Of the 100 Vickers hardness (HV) predictions made by the model using input features like molar ratios of metal elements (e.g., Ti, Al, Cr, Zr) and atomic size mismatch, 82 exceeded the dataset’s maximum hardness, with the best sample achieving a prediction accuracy of 91.6% validated against experimental measurements. This approach offers a robust strategy for designing high-performance coatings with optimized hardness. Full article
(This article belongs to the Special Issue Advances in Computation and Modeling of Materials Mechanics)
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22 pages, 2422 KiB  
Article
OSIRIS4CubeSat—The World’s Smallest Commercially Available Laser Communication Terminal
by Benjamin Rödiger, Christian Roubal, Fabian Rein, René Rüddenklau, Anil Morab Vishwanath and Christopher Schmidt
Aerospace 2025, 12(8), 655; https://doi.org/10.3390/aerospace12080655 - 23 Jul 2025
Viewed by 166
Abstract
The New Space movement led to an exponential increase in the number of the smallest satellites in orbit in the last two decades. The number of required communication channels increased with that as well and revealed the limitations of classical radio frequency channels. [...] Read more.
The New Space movement led to an exponential increase in the number of the smallest satellites in orbit in the last two decades. The number of required communication channels increased with that as well and revealed the limitations of classical radio frequency channels. Free-space optical communication overcomes these challenges and has been successfully demonstrated, with operational systems in orbit on large and small satellites. The next step is to miniaturize the technology of laser communication to make it usable on CubeSats. Thus, the German Aerospace Center (DLR) developed, together with Tesat-Spacecom GmbH & Co. KG in Backnang, Germany, a highly miniaturized and power-efficient laser terminal, which is based on a potential customer’s use case. OSIRIS4CubeSat uses a new patented design that combines electronics and optomechanics into a single system architecture to achieve a high compactness following the CubeSat standard. Interfaces and software protocols that follow established standards allowed for an easy transition to the industry for a commercial mass market. The successful demonstration of OSIRIS4CubeSat during the PIXL-1 mission proved its capabilities and the advantages of free-space optical communication in the final environment. This paper gives an overview of the system architecture and the development of the single subsystems. The system’s capabilities are verified by the already published in-orbit demonstration results. Full article
(This article belongs to the Special Issue On-Board Systems Design for Aerospace Vehicles (2nd Edition))
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8 pages, 971 KiB  
Article
Mechanism of Topotactic Reduction-Oxidation Between Mg-Doped SrMoO3 Perovskites and SrMoO4 Scheelites, Utilized as Anode Materials for Solid Oxide Fuel Cells
by Vanessa Cascos, M. T. Fernández-Díaz and José Antonio Alonso
Materials 2025, 18(15), 3424; https://doi.org/10.3390/ma18153424 - 22 Jul 2025
Viewed by 204
Abstract
Recently, we have described SrMo1-xMgxO3-δ perovskites (x = 0.1, 0.2) as excellent anode materials for solid oxide fuel cells (SOFCs), with mixed ionic and electronic conduction (MIEC) properties. After depositing on the solid electrolyte, they were annealed for [...] Read more.
Recently, we have described SrMo1-xMgxO3-δ perovskites (x = 0.1, 0.2) as excellent anode materials for solid oxide fuel cells (SOFCs), with mixed ionic and electronic conduction (MIEC) properties. After depositing on the solid electrolyte, they were annealed for sintering at high temperatures (typically 1000 °C), giving rise to oxidized scheelite-type phases, with SrMo1-xMgxO4-δ (x = 0.1, 0.2) stoichiometry. To obtain the active perovskite phases, they were reduced again in the working anode conditions, under H2 atmosphere. Therefore, there must be an excellent reversibility between the oxidized Sr(Mo, Mg)O4-δ scheelite and the reduced Sr(Mo, Mg)O3-δ perovskite phases. This work describes the topotactical oxidation, by annealing at 400 °C in air, of the SrMo0.9Mg0.1O3-δ perovskite oxide. The characterization by X-ray diffraction (XRD) and neutron powder diffraction (NPD) was carried out in order to determine the crystal structure features. The scheelite oxides are tetragonal, space group I41/a (No. 88), whereas the perovskites are cubic, s.g. Pm-3m (No. 221). The Rietveld refinement of the scheelite phase from NPD data after annealing the perovskite at 400 °C and cooling it down slowly to RT evidences the absence of intermediate phases between perovskite and scheelite oxides, as well as the presence of oxygen vacancies in both oxidized and reduced phases, essential for their performance as MIEC oxides. The topotactical relationship between both crystal structures is discussed. Full article
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