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13 pages, 2935 KB  
Article
Research on Strontium-Doped Scandate Cathode Based on Computer Simulation
by Zepeng Li, Na Li, Xin Sun, Guanghui Hao, Ke Zhang and Jinjun Feng
Electronics 2026, 15(8), 1722; https://doi.org/10.3390/electronics15081722 - 18 Apr 2026
Viewed by 341
Abstract
Scandate cathodes have garnered significant attention for their exceptional low-temperature, high-current-density emission characteristics. However, their widespread deployment in vacuum electronic devices is currently hindered by stringent vacuum requirements and susceptibility to ion bombardment. To enhance the engineering applicability of scandate cathodes, this study [...] Read more.
Scandate cathodes have garnered significant attention for their exceptional low-temperature, high-current-density emission characteristics. However, their widespread deployment in vacuum electronic devices is currently hindered by stringent vacuum requirements and susceptibility to ion bombardment. To enhance the engineering applicability of scandate cathodes, this study employs first-principles density functional theory (DFT) to model the surface microstructures of strontium (Sr)–scandium (Sc) co-doped systems. Guided by simulation predictions regarding surface elemental ratios, corresponding emission active materials and cathode samples were fabricated. A systematic comparison between theoretical calculations and experimental measurements reveals a critical trade-off: while increasing Sr content enhances structural stability (indicated by lower formation energies), it concurrently increases the work function. Consequently, an optimal Sr doping level of approximately 2 wt% is identified, which significantly improves emission current density without compromising stability. Cathodes fabricated with this optimized composition were tested in a practical electron gun configuration. Results demonstrate that under low-temperature conditions (1000 °C) and wide-pulse operation (2 ms), the cathode achieves an emission current density of 21.57 A/cm2. These findings validate the efficacy of simulation-guided material design and highlight the potential of Sr-doped scandate cathodes for high-power microwave applications. Full article
(This article belongs to the Section Electronic Materials, Devices and Applications)
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19 pages, 1747 KB  
Article
Design and Implementation of a Low-Cost Dual-Structure Laser Shooting System with Physical and Web-Based Targets for School Physical Education
by Yongchul Kwon, Donghyun Kim, Dongsuk Yang, Minseo Kang and Gunsang Cho
Appl. Sci. 2026, 16(7), 3347; https://doi.org/10.3390/app16073347 - 30 Mar 2026
Viewed by 558
Abstract
Shooting activities offer educational and recreational value; however, their application in school physical education and recreational settings remains limited due to safety concerns, high costs, and restricted access to specialized facilities and equipment. To address these constraints, this study designed and implemented a [...] Read more.
Shooting activities offer educational and recreational value; however, their application in school physical education and recreational settings remains limited due to safety concerns, high costs, and restricted access to specialized facilities and equipment. To address these constraints, this study designed and implemented a low-cost laser shooting system suitable for school physical education and recreational use. The proposed system comprises a laser-gun module, a physical electronic target providing immediate on-site feedback using an illuminance sensor, a Fresnel lens, and RGB LEDs, and a web-based electronic target that enables real-time scoring, logging, and visualization via smartphone or tablet cameras and browser-based processing. By adopting a low-power, projectile-free laser structure with pulse-limited emission, the system enhances operational safety, while the use of general-purpose components and web standards reduces cost and lowers barriers to adoption. Technical verification conducted under controlled indoor conditions demonstrated stable single-shot operation, reliable hit detection, and accurate score calculation for both the physical and web-based targets. Expert validation involving specialists in physical education, educational technology, and sports technology yielded consistently high evaluations across safety, cost efficiency, functional completeness, and field applicability. These findings suggest that the proposed system represents a practical and scalable alternative for school physical education classes and recreational programs. Future research should examine user-level usability, learning outcomes, system robustness under diverse environmental conditions, and structured expert consensus processes. Full article
(This article belongs to the Special Issue Technologies in Sports and Physical Activity)
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20 pages, 4954 KB  
Article
Mechanistic Insights into the Inhibition of Yersinia enterocolitica Biofilm Formation by Lipoic Acid
by Sichen Liao, Siqi Yang, Guoli Gong, Zhenbin Liu, Jiayi Zhang, Hongbo Li, Qing Sun, Haizhen Mo, Liangbin Hu and Lu Tian
Microorganisms 2026, 14(3), 558; https://doi.org/10.3390/microorganisms14030558 - 28 Feb 2026
Cited by 1 | Viewed by 739
Abstract
Yersinia enterocolitica is a foodborne pathogen that forms biofilms on surfaces, enhancing its survivability and increasing bacterial resistance, which poses a significant challenge to public health. Therefore, developing effective strategies to inhibit biofilm formation is crucial. Lipoic acid (LA) is a compound with [...] Read more.
Yersinia enterocolitica is a foodborne pathogen that forms biofilms on surfaces, enhancing its survivability and increasing bacterial resistance, which poses a significant challenge to public health. Therefore, developing effective strategies to inhibit biofilm formation is crucial. Lipoic acid (LA) is a compound with antibiofilm properties. This study investigates the effects of LA on biofilm formation by Y. enterocolitica BNCC 108930 (a standard strain from the BeNa Culture Collection). Biofilm formation, maturation, removal, and cell viability were evaluated by crystal violet staining, extracellular polysaccharide assay, Methylthiazolyldiphenyl-tetrazolium bromide assays, motility, and quorum sensing (QS) assays. The results indicate that LA interferes with the early stages of biofilm formation by compromising cell membrane integrity and reducing cellular adhesion. Furthermore, 2.5 mg/mL of LA reduced biofilm biomass (with a 48 h treatment inhibition rate of 51.46 ± 1.29%) and extracellular polysaccharide production (with a relative inhibition rate of 30.09 ± 1.8%), while significantly reducing the metabolic activity of bacteria within the biofilm (inhibition rate over 85%) compared to the untreated group. Confocal laser scanning microscopy and field emission gun scanning electron microscopy confirm that LA induces a sparse biofilm structure, reduced aggregation, and decreased biofilm thickness to 21.33 ± 2.27 μm. Motility and QS assays demonstrate that LA affects flagellar motility and the secretion of N-acyl homoserine lactones. Transcriptome analysis revealed downregulation of genes involved in the QS system and biofilm formation (e.g., lsrA, lsrC, lsrD, lsrR, and oppA), as well as upregulation of genes related to bacterial chemotaxis and flagellar assembly (e.g., RS19655, RS15590, fliE, fliJ, fliP, fliA, and fliK). These alterations suggest that LA inhibits Y. enterocolitica biofilm formation by affecting intercellular communication and flagellar motility. This study highlights the antibiofilm properties of LA, providing a theoretical basis for potential applications in microbial and biofilm control. Full article
(This article belongs to the Collection Feature Papers in Biofilm)
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15 pages, 3850 KB  
Article
The Influence of Electron Beam Treatment on the Structure and Properties of the Surface Layer of the Composite Material AlMg3-5SiC
by Shunqi Mei, Roman Mikheev, Pavel Bykov, Igor Kalashnikov, Lubov Kobeleva, Andrey Sliva and Egor Terentyev
Lubricants 2026, 14(2), 50; https://doi.org/10.3390/lubricants14020050 - 25 Jan 2026
Viewed by 754
Abstract
The influence of electron beam treatment parameters (electron gun speed, electron beam current, scanning frequency, and sweep type) on the structure and properties of the surface layer of the composite material AlMg3-5SiC has been investigated. Composite specimens of AlMg3 alloy reinforced with [...] Read more.
The influence of electron beam treatment parameters (electron gun speed, electron beam current, scanning frequency, and sweep type) on the structure and properties of the surface layer of the composite material AlMg3-5SiC has been investigated. Composite specimens of AlMg3 alloy reinforced with 5 wt.% silicon carbide particles were manufactured via the stir casting process. Experimentally, processing modes with heat input from 120 to 240 J/mm yield a modified layer thickness from 74 to 1705 µm. Heat input should not exceed 150 J/mm to ensure a smooth and defect-free surface layer. The macro- and microstructure were examined using optical microscopy. Brinell hardness was measured. Friction and wear tests were performed under dry sliding friction conditions using the “bushing on plate” scheme. This evaluated the tribological properties of the composite material in its original cast state and after modifying treatment. Due to the matrix alloy structure refinement by 5–10 times, the surface layer’s hardness increases by 11% after treatment. The modified specimens have superior tribological properties to the initial ones. Wear rate reduces by 17.5%, the average friction coefficient reduces by 32%, and the root mean squared error of the friction coefficient, which measures friction process stability, reduces by 50% at a specific load of 2.5 MPa. Therefore, the electron beam treatment process is a useful method for producing high-quality and uniform wear-resistant aluminum matrix composite surface layers. Full article
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16 pages, 2734 KB  
Article
Experimental Study on the Impact Resistance of UHMWPE Flexible Film Against Hypervelocity Particles
by Chen Liu, Zhirui Rao, Hao Liu, Changlin Zhao, Yifan Wang and Aleksey Khaziev
Polymers 2026, 18(2), 161; https://doi.org/10.3390/polym18020161 - 7 Jan 2026
Cited by 1 | Viewed by 1012
Abstract
The increasing threat posed by micrometeoroids and orbital debris to in-orbit spacecraft necessitates the development of lightweight and deformable shielding systems capable of withstanding hypervelocity impacts. Ultra-high-molecular-weight polyethylene (UHMWPE) films, owing to their high specific strength and energy-absorption capacity, present a promising candidate [...] Read more.
The increasing threat posed by micrometeoroids and orbital debris to in-orbit spacecraft necessitates the development of lightweight and deformable shielding systems capable of withstanding hypervelocity impacts. Ultra-high-molecular-weight polyethylene (UHMWPE) films, owing to their high specific strength and energy-absorption capacity, present a promising candidate for such applications. However, the hypervelocity impact response of thin, highly oriented UHMWPE films—distinct from bulk plates or composites—remains poorly understood, particularly for micron-scale particles at velocities relevant to space debris (≥8 km/s). In this study, we systematically investigate the impact resistance of 0.1 mm UHMWPE films using a plasma-driven microparticle accelerator and a hypervelocity dust gun to simulate impacts by micron-sized Al2O3 and Fe particles at velocities up to ~8.5 km/s. Through detailed analysis of crater morphology via scanning electron microscopy, we identify three distinct damage modes: plastic-dominated craters (Type I), fracture-melting craters (Type II), and perforations (Type III). These modes are correlated with impact energy and particle size, revealing the material’s transition from large-scale plastic deformation to localized thermal softening and eventual penetration. Crucially, we provide quantitative penetration thresholds (e.g., 2.25 μm Al2O3 at 8.5 km/s) and establish a microstructure-informed damage classification that advances the fundamental understanding of UHMWPE film behavior under extreme strain rates. Our findings not only elucidate the energy-dissipation mechanisms in oriented polymer films but also offer practical guidelines for the design of next-generation, flexible spacecraft shielding systems. Full article
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15 pages, 1969 KB  
Article
Ion-Type Irradiation Effect on Optical, Structural, and Morphological Properties of ZnO Thin Films
by Alejandra López-Suárez, Dwight R. Acosta, Juan López-Patiño and Beatriz E. Fuentes
Surfaces 2025, 8(4), 74; https://doi.org/10.3390/surfaces8040074 - 24 Oct 2025
Cited by 2 | Viewed by 1421
Abstract
ZnO thin films were deposited on soda–lime glass substrates using the chemical spray pyrolysis method at a temperature of 500 °C. After the deposition, the substrates were irradiated with 10 keV H+ and Ar+ ions using a Colutron ion gun. We [...] Read more.
ZnO thin films were deposited on soda–lime glass substrates using the chemical spray pyrolysis method at a temperature of 500 °C. After the deposition, the substrates were irradiated with 10 keV H+ and Ar+ ions using a Colutron ion gun. We investigated the optical, structural, and morphological properties of the irradiated samples using Rutherford Backscattering Spectrometry, Ultraviolet and Visible Spectroscopy, X-ray diffraction, and Scanning Electron Microscopy. Our results showed a slight decrease in the optical band gap of the irradiated samples, which can be attributed to the quantum confinement effect caused by changes in the crystallite size. The diffractograms displayed diffraction peaks corresponding to the characteristic planes of the hexagonal wurtzite phase of ZnO, indicating that the films were polycrystalline with a preferential orientation along the c-axis. We also observed a reduction in the average crystallite size of the samples after ion irradiation. The morphological study showed that the average grain size increased and the shape changed from spherical in the pristine sample to flake-like after irradiation. Additionally, the samples irradiated with Ar+ ions exhibited a bimodal distribution in grain size, which is attributed to the defects and nucleation centers generated during the irradiation process. Full article
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30 pages, 10791 KB  
Review
Research Progress in Carbon Nanotube-Based Cold Cathode Electron Guns
by Jiupeng Li, Yu Tu, Dewei Ma and Yun Yang
Nanomaterials 2025, 15(18), 1403; https://doi.org/10.3390/nano15181403 - 12 Sep 2025
Cited by 9 | Viewed by 2891
Abstract
Field emission (FE) cold-cathodes have some important characteristics, including instant turn-on, room temperature operation, miniaturization, low power consumption, and nonlinearity. As emitters, Carbon nanotubes (CNTs) exhibit a high field enhancement factor, low turn-on voltage, high current density, high thermal conductivity, and temporal stability. [...] Read more.
Field emission (FE) cold-cathodes have some important characteristics, including instant turn-on, room temperature operation, miniaturization, low power consumption, and nonlinearity. As emitters, Carbon nanotubes (CNTs) exhibit a high field enhancement factor, low turn-on voltage, high current density, high thermal conductivity, and temporal stability. These properties make them highly suitable for applications in FE cold-cathodes. In addition, Carbon nanotube (CNT) cold cathodes have specialized applications in electron beams, which are modulated by high-frequency electric fields and exhibit low energy dispersion. There have been substantial studies on CNT-based cold cathode electron guns with diverse structural configurations. These studies have laid the foundation for the applications of microwave vacuum electron devices, X-ray equipments, flat-panel displays, and scanning electron microscopes. The review primarily introduces cold cathode electron guns based on CNT emitters with diverse morphologies, including disordered CNTs, aligned CNTs, CNT paste, and other CNTs with special surface morphologies. Additionally, the research results of microwave electron guns based on CNT cathodes are also mentioned. Finally, the problems that need to be resolved in the practical applications of CNT cold cathode electron guns are summarized, and some suggestions for future development are provided. Full article
(This article belongs to the Special Issue Nanoelectronics: Materials, Devices and Applications (Second Edition))
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21 pages, 6437 KB  
Article
Assessment of the Surface Characteristics of ISO 5832-1 Stainless Steel for Biomaterial Applications
by Eurico Felix Pieretti, Davide Piaggio and Isolda Costa
Materials 2025, 18(17), 4020; https://doi.org/10.3390/ma18174020 - 27 Aug 2025
Viewed by 1393
Abstract
Marking techniques are employed to guarantee the identification and traceability of biomedical materials. This study investigated the impact of laser and mechanical marking processes on the tribological performance of ISO 5832-1 austenitic stainless steel (SS), specifically examining corrosion resistance, the coefficient of friction, [...] Read more.
Marking techniques are employed to guarantee the identification and traceability of biomedical materials. This study investigated the impact of laser and mechanical marking processes on the tribological performance of ISO 5832-1 austenitic stainless steel (SS), specifically examining corrosion resistance, the coefficient of friction, and wear volume in ball-cratering wear tests. The laser marking was performed using a nanosecond Q-switched Nd:YAG laser. Cytotoxicity tests assessed the biocompatibility of the biomaterial. Non-marked surfaces were also evaluated for comparison. A phosphate-buffered saline solution (PBS) served as both the lubricant and corrosion medium. The surface finishing was analyzed using optical microscopy and scanning electron microscopy coupled with a field-emission gun (SEM-FEG), combined with an energy-dispersive X-ray spectrometer. The oxide film was examined through X-ray photoelectron spectroscopy (XPS). Wear tests lasted 10 min, with PBS drops applied every 10 s at 75 rpm; solid balls of AISI 316L stainless steel (SS) and polypropylene (PP), each 1 inch in diameter, were used as counter-bodies. Corrosion resistance was assessed using electrochemical methods. Results showed variations in roughness and microstructure due to laser marking. The tribological behaviour was influenced by the type of marking process, and the wear amount depended on the normal force and ball nature. None of the samples was considered cytotoxic, although laser-marked surfaces exhibited the lowest cellular viability among the tested surfaces and the lowest corrosion resistance. Full article
(This article belongs to the Section Biomaterials)
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9 pages, 2467 KB  
Article
Design and Simulation of an Electron Optical System for Terahertz Vacuum Devices
by Muhammad Haris Jamil, Zhiwei Lin, Hamid Sharif, Nazish Saleem Abbas and Wenlong He
Micromachines 2025, 16(8), 928; https://doi.org/10.3390/mi16080928 - 13 Aug 2025
Cited by 1 | Viewed by 1228
Abstract
An electron optic system (EOS) consisting of a sheet electron beam gun (SEB) and a pole offset periodic cusped magnet (PO-PCM) is reported for 340-GHz frequency. A sheet electron beam with a voltage of 29 kV, beam compression ratio of 16, and a [...] Read more.
An electron optic system (EOS) consisting of a sheet electron beam gun (SEB) and a pole offset periodic cusped magnet (PO-PCM) is reported for 340-GHz frequency. A sheet electron beam with a voltage of 29 kV, beam compression ratio of 16, and a beam waist of size 0.17 mm × 0.044 mm was designed and optimized using computer simulation technology (CST). The EOS was capable of transmitting the beam with a current of 6.9 mA through a beam tunnel of size 0.516 mm × 0.091 mm, having a length of 60 mm with the help of a pole offset periodic cusped magnet. The axial magnetic field generated by the PCM was 0.32 T. The EOS was efficient enough to transmit the beam stably through the beam tunnel with a transmission rate of 100%. Full article
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20 pages, 2093 KB  
Review
A Practical Guide Paper on Bulk and PLD Thin-Film Metals Commonly Used as Photocathodes in RF and SRF Guns
by Alessio Perrone, Muhammad Rizwan Aziz, Francisco Gontad, Nikolaos A. Vainos and Anna Paola Caricato
Chemistry 2025, 7(4), 123; https://doi.org/10.3390/chemistry7040123 - 30 Jul 2025
Cited by 1 | Viewed by 2240
Abstract
This paper serves as a comprehensive and practical resource to guide researchers in selecting suitable metals for use as photocathodes in radio-frequency (RF) and superconducting radio-frequency (SRF) electron guns. It offers an in-depth review of bulk and thin-film metals commonly employed in many [...] Read more.
This paper serves as a comprehensive and practical resource to guide researchers in selecting suitable metals for use as photocathodes in radio-frequency (RF) and superconducting radio-frequency (SRF) electron guns. It offers an in-depth review of bulk and thin-film metals commonly employed in many applications. The investigation includes the photoemission, optical, chemical, mechanical, and physical properties of metallic materials used in photocathodes, with a particular focus on key performance parameters such as quantum efficiency, operational lifetime, chemical inertness, thermal emittance, response time, dark current, and work function. In addition to these primary attributes, this study examines essential parameters such as surface roughness, morphology, injector compatibility, manufacturing techniques, and the impact of chemical environmental factors on overall performance. The aim is to provide researchers with detailed insights to make well-informed decisions on materials and device selection. The holistic approach of this work associates, in tabular format, all photo-emissive, optical, mechanical, physical, and chemical properties of bulk and thin-film metallic photocathodes with experimental data, aspiring to provide unique tools for maximizing the effectiveness of laser cleaning treatment. Full article
(This article belongs to the Section Electrochemistry and Photoredox Processes)
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16 pages, 3798 KB  
Article
High Average Current Electron Beam Generation Using RF Gated Thermionic Electron Gun
by Anjali Bhagwan Kavar, Shigeru Kashiwagi, Kai Masuda, Toshiya Muto, Fujio Hinode, Kenichi Nanbu, Ikuro Nagasawa, Kotaro Shibata, Ken Takahashi, Hiroki Yamada, Kodai Kudo, Hayato Abiko, Pitchayapak Kitisri and Hiroyuki Hama
Particles 2025, 8(3), 68; https://doi.org/10.3390/particles8030068 - 8 Jul 2025
Viewed by 2284
Abstract
High-current electron beams can significantly enhance the productivity of variety of applications including medical radioisotope (RI) production and wastewater purification. High-power superconducting radio frequency (SRF) linacs are capable of producing such high-current electron beams due to the key advantage to operate in continuous [...] Read more.
High-current electron beams can significantly enhance the productivity of variety of applications including medical radioisotope (RI) production and wastewater purification. High-power superconducting radio frequency (SRF) linacs are capable of producing such high-current electron beams due to the key advantage to operate in continuous wave (CW) mode. However, this requires an injector capable of generating electron bunches with high repetition rate and in CW mode, while minimizing beam losses to avoid damage to SRF cavities due to quenching. RF gating to the grid of a thermionic electron gun is a promising solution, as it ensures CW bunch generation at the repetition rate same as the fundamental or sub-harmonics of the accelerating RF frequency, with minimal beam loss. This paper presents detailed beam dynamics simulations demonstrating that an RF-gated gun operating at 1.3 GHz can generate bunches with 148 ps full width with 8.96 pC charge. Full article
(This article belongs to the Special Issue Generation and Application of High-Power Radiation Sources 2025)
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20 pages, 3123 KB  
Article
Cryogenic Distribution System and Entropy-Based Analysis of Chosen Design Options for the Example of the Polish FEL Facility
by Tomasz Banaszkiewicz, Maciej Chorowski and Paweł Duda
Energies 2025, 18(13), 3554; https://doi.org/10.3390/en18133554 - 5 Jul 2025
Viewed by 1011
Abstract
The Polish Free-Electron Laser (PolFEL), which is currently under construction in the National Centre for Nuclear Research in Świerk near Warsaw, will comprise an electron gun and from four to six cryomodules, each accommodating two nine-cell TESLA RF superconducting resonant cavities. To cool [...] Read more.
The Polish Free-Electron Laser (PolFEL), which is currently under construction in the National Centre for Nuclear Research in Świerk near Warsaw, will comprise an electron gun and from four to six cryomodules, each accommodating two nine-cell TESLA RF superconducting resonant cavities. To cool the superconducting resonant cavities, the cryomodules will be supplied with superfluid helium at a temperature of 2 K. Other requirements regarding the cooling power of PolFEL result from the need to cool the power couplers for the accelerating cryomodules (5 K) and thermal shields, which limit the heat inleaks due to radiation (40–80 K). The machine will utilize several thermodynamic states of helium, including two-phase superfluid helium, supercritical helium, and low-pressure helium vapours. Supercritical helium will be supplied from a cryoplant by a cryogenic distribution system (CDS)—transfer line and valve boxes—where it will be thermodynamically transformed into a superfluid state. This article presents the architecture of the CDS, discusses several design solutions that could have been decided on with the use of second law analysis, and presents the design methodology of the chosen CDS elements. Full article
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20 pages, 4044 KB  
Article
Pressure Drop Process as a Pretreatment for Enhancing Rehydration of Adzuki Beans (Vigna angularis)
by Suyeon Lee, Sangoh Kim and Seokwon Lim
Foods 2025, 14(13), 2286; https://doi.org/10.3390/foods14132286 - 27 Jun 2025
Viewed by 1068
Abstract
Pressure drop processes, such as dissolved inorganic carbon and gun-puffing, have shown utility in the food industry, but their reliance on heat remains a limiting factor. This study involved the development of a processor capable of performing nonthermal pressure drop treatment, which minimizes [...] Read more.
Pressure drop processes, such as dissolved inorganic carbon and gun-puffing, have shown utility in the food industry, but their reliance on heat remains a limiting factor. This study involved the development of a processor capable of performing nonthermal pressure drop treatment, which minimizes thermal changes in food. In addition, its effects on the structure and soaking efficiency of adzuki beans were analyzed. Two improved pressure drop processes were tested: PDA, which applied 1 kgf/cm2 of pressure before release, and PDB, which applied a higher pressure and gradually decreased it in steps of 1 kgf/cm2. Both the PDA and PDB pretreatments enhanced soaking more effectively than heat treatments at 60 °C and 100 °C, whereas no significant effect was observed at 25 °C, indicating a minimal heat requirement for moisture and gas release. Notably, repeated PDB application (more than 40 times) further increased the moisture absorption without thermal influence. Scanning electron microscopy revealed that the PDA, PDB, and heat treatments caused cracks in the hilum region and increased surface wrinkling and mesh structure deformation. These findings demonstrate the potential of pressure drop treatment to improve soaking efficiency through structural modification, supporting its use as an effective nonthermal pretreatment method. Full article
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14 pages, 938 KB  
Article
Gun–Bullet Model-Based Noncovalent Interactions Boosting Visible Light Photocatalytic Hydrogen Production in Poly Thieno[3,2-b]Thiophene/Graphitic Carbon Nitride Heterojunctions
by Yong Li, Jialu Tong, Zihao Chai, Yuanyuan Wu, Dongting Wang and Hongbin Li
Polymers 2025, 17(10), 1417; https://doi.org/10.3390/polym17101417 - 21 May 2025
Cited by 5 | Viewed by 899
Abstract
Linear conjugated polymer photocatalysts are still hampered by challenges involving low charge separation efficiency and poor water dispersibility, which are crucial factors during the photocatalytic water splitting process. Herein, we synthesized Poly thieno[3,2-b]thiophene (PTT) nanoparticles with excellent visible light response characteristic. Subsequently, we [...] Read more.
Linear conjugated polymer photocatalysts are still hampered by challenges involving low charge separation efficiency and poor water dispersibility, which are crucial factors during the photocatalytic water splitting process. Herein, we synthesized Poly thieno[3,2-b]thiophene (PTT) nanoparticles with excellent visible light response characteristic. Subsequently, we constructed the gun–bullet model PTT/graphitic carbon nitride (PTT/g-C3N4) heterojunctions for photocatalytic hydrogen production, where PTT with good visible light response characteristic serves as the bullets and g-C3N4 with good water dispersibility serves as the guns. The as-prepared PTT/g-C3N4 heterojunctions show greatly accelerated charge separation and excellent photocatalytic hydrogen production performance. Specifically, 10PTT/g-C3N4 demonstrates extraordinary hydrogen production performance, reaching 6.56 mmol g−1 h−1 (2 wt% Pt loading, 0.1 M AA as sacrificial agent, λ > 420 nm), calculated to be 15.3 and 22.6 times those of PTT and g-C3N4, respectively. Mechanistic studies reveal that the significantly improved performance of PTT/g-C3N4 heterojunctions is ascribed to the accelerated charge transfer, which originates from the C…S/N…S noncovalent interactions among PTT and g-C3N4. The C…S/N…S noncovalent interactions act as an efficient interface charge transmission channel (ICTC), accelerating the steady stream of excited electron transfer from the lowest unoccupied molecular orbital (LUMO) of PTT to that of g-C3N4. The gun–bullet model heterojunctions proposed here provide a practical strategy for achieving exceptional visible light photocatalytic hydrogen production by combining charge separation with water dispersibility in polymer/polymer heterojunctions via noncovalent interactions. Full article
(This article belongs to the Section Polymer Applications)
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14 pages, 4842 KB  
Article
Direct Detection of Biosignature Gasses Using Corrosion-Resistant QIT-MS Sensor for Planetary Exploration
by Dragan Nikolić and Stojan M. Madzunkov
Biophysica 2025, 5(2), 17; https://doi.org/10.3390/biophysica5020017 - 3 May 2025
Cited by 1 | Viewed by 1901
Abstract
We present a corrosion-resistant quadrupole ion trap mass spectrometer (QIT-MS) for the direct detection of biosignature gasses in chemically reactive planetary atmospheres, such as Venusian clouds. The system employs a Paul trap with hyperbolic titanium alloy electrodes and alumina spacers for chemical durability [...] Read more.
We present a corrosion-resistant quadrupole ion trap mass spectrometer (QIT-MS) for the direct detection of biosignature gasses in chemically reactive planetary atmospheres, such as Venusian clouds. The system employs a Paul trap with hyperbolic titanium alloy electrodes and alumina spacers for chemical durability and precise ion confinement. An yttria-coated iridium filament serves as the thermionic emitter within a modular electron gun capable of axial and radial ionization. Analytes are introduced through fused silica capillaries and crescent inlets into a miniature pressure cell. The testbed integrates high-voltage RF electronics, pressure-regulated sample delivery, and FPGA-based control for real-time tuning. Continuous operation in 98% sulfuric acid vapor for over three months demonstrated no degradation in emitter or sensor performance. Mass spectra revealed H2SO4 fragmentation and thermally induced decomposition up to 425 K. Spectral variations with filament current and electron energy highlight thermal and electron-induced dissociation dynamics. Operational modes include high-resolution scans and selective ion ejection (e.g., CO2+, N2+) to enhance the detection of PH3+, H2S+, and daughter ions. The compact QIT-MS platform is validated for future missions targeting corrosive atmospheres, enabling in situ astrobiological investigations through the detection of biosignature gasses such as phosphine and hydrogen sulfide. Full article
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