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Keywords = electromagnetically stirred

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26 pages, 8248 KB  
Article
Crack Suppression in Metal Active Gas Overlay Remanufacturing of Tunnel Boring Machine Cutter Rings Under Longitudinal Alternating Magnetic Field Stirring of the Weld Pool
by Feiqi Fan, Xing Zeng, Shuhao Dai, Kui Zhang and Fei He
Coatings 2026, 16(7), 758; https://doi.org/10.3390/coatings16070758 - 26 Jun 2026
Viewed by 262
Abstract
Crack defects are prone to occur during MAG overlay remanufacturing of TBM cutter rings, thereby affecting the repair quality and service reliability of the remanufactured layer. In this study, longitudinal alternating magnetic field (LAMF) stirring was introduced into the MAG overlay remanufacturing process [...] Read more.
Crack defects are prone to occur during MAG overlay remanufacturing of TBM cutter rings, thereby affecting the repair quality and service reliability of the remanufactured layer. In this study, longitudinal alternating magnetic field (LAMF) stirring was introduced into the MAG overlay remanufacturing process of H13 steel cutter rings to regulate molten-pool behavior and suppress crack defects. A molten-pool-scale sequentially coupled thermo-fluid-electromagnetic model was developed to compare the relative changes in the temperature and velocity fields with and without LAMF under identical MAG process parameters, heat-source input, material properties, and boundary conditions. In the model, the effect of LAMF was introduced through a Lorentz-force source term acting on the electrically conductive molten metal. The simulation results show that LAMF promoted heat redistribution within the molten pool, smoothed the thermal transition near the rear region of the molten pool, and reduced local heat accumulation. Meanwhile, LAMF modified the molten-pool flow pattern by weakening excessive flow along the welding direction and enhancing transverse circulation and vortex-induced mixing. Comparative overlay remanufacturing experiments were then conducted using a self-built magnetic-field stirring platform. Penetrant testing, X-ray inspection, metallographic observation, and industrial CT reconstruction were combined to characterize surface cracks, internal defects, and post-solidification microstructure. Compared with the non-LAMF condition, the maximum internal crack length decreased from 29.41 mm to 20.30 mm, corresponding to a reduction of 30.98%, and the crack-defect volume fraction decreased from 0.93% to 0.28%, corresponding to a decrease of 0.65 percentage points. The combined simulation and characterization results indicate that Lorentz-force-driven electromagnetic stirring improves the thermal-fluid conditions near the solidification front, thereby effectively reducing the formation tendency of solidification-related crack defects during MAG overlay remanufacturing. Full article
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21 pages, 4734 KB  
Article
Multiphysics Simulation of Shell Solidification Evolution in CSP Thin Slab Casting of Silicon Steel with Box-Type Electromagnetic Stirring
by Hong Xiao, Jian Liu, Lang Wang, Sheng-Zhao Wang, Yan-Zhong Li and Pu Wang
Materials 2026, 19(12), 2521; https://doi.org/10.3390/ma19122521 - 11 Jun 2026
Viewed by 252
Abstract
In CSP thin slab casting, high casting speeds promote excessive columnar grain growth, leading to low equiaxed grain ratios in non-oriented silicon steel and resulting in wrinkling defects. This study employs a box-type electromagnetic stirrer (B-EMS) to address this issue. A multiphysics model [...] Read more.
In CSP thin slab casting, high casting speeds promote excessive columnar grain growth, leading to low equiaxed grain ratios in non-oriented silicon steel and resulting in wrinkling defects. This study employs a box-type electromagnetic stirrer (B-EMS) to address this issue. A multiphysics model was established, in which grain transformation and its associated effects were neglected. The effects of B-EMS on the flow of molten steel, temperature distribution and evolution of solidified shell were analyzed, and industrial trials were conducted to verify the influence of B-EMS on grains. Results show that B-EMS generates asymmetric magnetic fields and electromagnetic forces, driving width-directional flow that enhances scouring of the solidification front. Compared with the experiment and simulation, the error in the magnetic field excited by B-EMS is within 5%. Under 800 A current, narrow-face center shell thickness increased from 22.88 mm (no stirring) to 23.62 mm (starting side) and 23.21 mm (pushing side). The central mushy zone area and liquid fraction decreased significantly, indicating accelerated solidification and more uniform shell growth. Industrial trials confirmed that the equiaxed grain ratio increased to approximately 30%, with significantly improved internal strand quality. This study demonstrates B-EMS’s metallurgical effects in regulating solidification structure, optimizing shell morphology, and improving continuous casting slab quality. The numerical simulation can be correlated with the industrial production process to better guide manufacturing practices. Full article
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15 pages, 3054 KB  
Article
Control of Macrosegregation in Titanium Alloy VAR Ingots via Alternating Magnetic Fields: Governing Roles of Field Strength and Frequency
by Meirong Jiang, Yulun Wu, Qing Wang, Jie Fu, Jinjin Shang, Tao He, Longchao Huang, Kaixuan Wang, Zhongqiu Liu and Xianghong Liu
Metals 2026, 16(4), 448; https://doi.org/10.3390/met16040448 - 20 Apr 2026
Viewed by 803
Abstract
Vacuum arc remelting (VAR) is essential for producing premium titanium alloys, where an externally applied alternating magnetic field enables circumferential stirring to control ingot homogeneity. However, current magnetic field parameter design relies on empirical trial-and-error approaches, lacking systematic theoretical guidance. To address this [...] Read more.
Vacuum arc remelting (VAR) is essential for producing premium titanium alloys, where an externally applied alternating magnetic field enables circumferential stirring to control ingot homogeneity. However, current magnetic field parameter design relies on empirical trial-and-error approaches, lacking systematic theoretical guidance. To address this issue, this study establishes a comprehensive multi-physics framework through a two-dimensional axisymmetric swirl model integrating electromagnetic, fluid dynamics, thermal, and solute transport phenomena. Our findings demonstrate that both the magnetic field strength and period exhibit optimal operating ranges, which directly influence ingot homogeneity. As magnetic field strength increases progressively, ingot uniformity shows a distinctive non-monotonic response—initially improving before subsequently deteriorating. Correspondingly, with increasing stirring period, macrosegregation undergoes a distinct three-stage evolution: initial mitigation, subsequent aggravation, and final alleviation. These phenomena originate from the small-scale circulatory flow generated by the external magnetic field on the surface of the VAR molten pool. The interactions among the flow, the solute diffusion layer, and the mushy zone collectively alter elemental diffusion behavior, ultimately determining the homogeneity of the ingot. This study provides a theoretical foundation for precise control of ingot homogeneity in titanium alloy VAR processes and demonstrates significant potential for engineering applications. Full article
(This article belongs to the Topic Numerical Modelling on Metallic Materials, 2nd Edition)
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14 pages, 3557 KB  
Article
Influence of Secondary Electromagnetic Stirring and Soft Reduction on Slab Macrosegregation Evolution of E355 Steel
by Xin Xie, Peng Shi, Baohui Yuan, Chenhui Wu and Daiwei Liu
Materials 2026, 19(6), 1164; https://doi.org/10.3390/ma19061164 - 17 Mar 2026
Viewed by 464
Abstract
Macrosegregation in continuous casting slabs remains a critical defect that adversely affects the homogeneity and mechanical properties of the final rolled products. Industrial experiments were conducted on E355 steel continuous casting slabs to investigate the effects of electromagnetic stirring (EMS) and soft reduction [...] Read more.
Macrosegregation in continuous casting slabs remains a critical defect that adversely affects the homogeneity and mechanical properties of the final rolled products. Industrial experiments were conducted on E355 steel continuous casting slabs to investigate the effects of electromagnetic stirring (EMS) and soft reduction (SR) on the evolution of slab macrosegregation. Furthermore, the inheritance of segregation from the slab to the rolled plate was analyzed. The results indicate that the equiaxed crystal ratio increases and the centerline segregation decreases with increasing stirring intensity. The application of both secondary EMS and SR minimized the centerline segregation in the slab. When the current intensity was increased from 0 A to 320 A in continuous stirring mode, the equiaxed crystal fraction increased from 22.52% to 32.52%, and the centerline segregation index decreased from 1.23 to 1.17. Compared with the continuous stirring mode, the alternating stirring mode promoted a more pronounced increase in the equiaxed crystal ratio and a further reduction in the centerline segregation. The centerline segregation in the slab correlates with the banded structure observed in the rolled plate. A higher degree of slab centerline segregation corresponds to a more severe banded structure and greater fluctuations in the mechanical properties of the plate. Through parameter optimization, the recommended settings are an alternating stirring mode with a current of 320 A at 5 Hz and an SR amount of 3 mm. Under these optimized conditions, the equiaxed crystal ratio of the slab increased to 35.22%, the centerline segregation index dropped to 1.15, and the banded structure in the rolled plate was reduced to grade 2.0. Consequently, the standard deviations of the tensile strength and elongation were 8.03 MPa and 1.1%, respectively. Full article
(This article belongs to the Section Metals and Alloys)
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22 pages, 10664 KB  
Article
Performance Enhancement of Low-Altitude Intelligent Network Communications Using Spherical-Cap Reflective Intelligent Surfaces
by Hengyi Sun, Xingcan Feng, Weili Guo, Xiaochen Zhang, Yuze Zeng, Guoshen Tan, Yong Tan, Changjiang Sun, Xiaoping Lu and Liang Yu
Electronics 2025, 14(24), 4848; https://doi.org/10.3390/electronics14244848 - 9 Dec 2025
Viewed by 863
Abstract
Unmanned Aerial Vehicles (UAVs) are integral components of future 6G networks, offering rapid deployment, enhanced line-of-sight communication, and flexible coverage extension. However, UAV communications in low-altitude environments face significant challenges, including rapid link variations due to attitude instability, severe signal blockage by urban [...] Read more.
Unmanned Aerial Vehicles (UAVs) are integral components of future 6G networks, offering rapid deployment, enhanced line-of-sight communication, and flexible coverage extension. However, UAV communications in low-altitude environments face significant challenges, including rapid link variations due to attitude instability, severe signal blockage by urban obstacles, and critical sensitivity to transmitter–receiver alignment. While traditional planar reconfigurable intelligent surfaces (RIS) show promise for mitigating these issues, they exhibit inherent limitations such as angular sensitivity and beam squint in wideband scenarios, compromising reliability in dynamic UAV scenarios. To address these shortcomings, this paper proposes and evaluates a spherical-cap reflective intelligent surface (ScRIS) specifically designed for dynamic low-altitude communications. The intrinsic curvature of the ScRIS enables omnidirectional reflection capabilities, significantly reducing sensitivity to UAV attitude variations. A rigorous analytical model founded on Generalized Sheet Transition Conditions (GSTCs) is developed to characterize the electromagnetic scattering of the curved metasurface. Three distinct 1-bit RIS unit cell coding arrangements, namely alternate, chessboard, and random, are investigated via numerical simulations utilizing CST Microwave Studio and experimental validation within a mechanically stirred reverberation chamber. Our results demonstrate that all tested ScRIS coding patterns markedly enhance electromagnetic field uniformity within the chamber and reduce the lowest usable frequency (LUF) by approximately 20% compared to a conventional metallic spherical reflector. Notably, the random coding pattern maximizes phase entropy, achieves the most uniform scattering characteristics and substantially reduces spatial field autocorrelation. Furthermore, the combined curvature and coding functionality of the ScRIS facilitates simultaneous directional focusing and diffuse scattering, thereby improving multipath diversity and spatial coverage uniformity. This effectively mitigates communication blind spots commonly encountered in UAV applications, providing a resilient link environment despite UAV orientation changes. To validate these findings in a practical context, we conduct link-level simulations based on a reproducible system model at 3.5 GHz, utilizing electromagnetic scale invariance to bridge the fundamental scattering properties observed in the RC to the application band. The results confirm that the ScRIS architecture can enhance link throughput by nearly five-fold at a 10 km range compared to a baseline scenario without RIS. We also propose a practical deployment strategy for urban blind-spot compensation, discuss hybrid planar-curved architectures, and conduct an in-depth analysis of a DRL-based adaptive control framework with explicit convergence and complexity analysis. Our findings validate the significant potential of ScRIS as a passive, energy-efficient solution for enhancing communication stability and coverage in multi-band 6G networks. Full article
(This article belongs to the Special Issue 5G Technology for Internet of Things Applications)
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13 pages, 5693 KB  
Article
Effect of a Single-Sided Magnetic Field on Microstructure and Properties of Resistance Spot Weld Nuggets in H1000/DP590 Dissimilar Steels
by Qiaobo Feng, Jiale Li, Detian Xie and Yongbing Li
Metals 2025, 15(11), 1259; https://doi.org/10.3390/met15111259 - 18 Nov 2025
Cited by 1 | Viewed by 787
Abstract
H1000 stainless steel is defined as a nickel-saving austenitic stainless steel, characterized by high strength and high elongation. DP590 steel is widely used in the manufacturing of vehicle bodies. DP590 dual-phase steel is classified as a high-strength low-alloy steel, known for its high [...] Read more.
H1000 stainless steel is defined as a nickel-saving austenitic stainless steel, characterized by high strength and high elongation. DP590 steel is widely used in the manufacturing of vehicle bodies. DP590 dual-phase steel is classified as a high-strength low-alloy steel, known for its high strength and good formability. To address issues such as nugget deviation, inhomogeneous mixing of the internal nugget microstructure, and interfacial fracture during tensile-shear testing in resistance spot-welded joints of these dissimilar materials, a unilateral magnetic-assisted resistance spot-welding process was proposed. The influence of the external magnetic field on various properties of the joint was systematically investigated. The results indicate that the application of an external magnetic field significantly enhances the strength of H1000/DP590 dissimilar spot-welded joints, with joint strength increasing by approximately 14% and energy absorption capacity improving by about 30%. These improvements are attributed to the electromagnetic stirring effect induced by the magnetic field, through which the effective nugget diameter was enlarged, the microstructure was homogenized, and the macroscopic morphology of the nugget was modified. As a result, the bonding area between the nugget and the base metal is expanded, and the fracture mode of the joint is shifted from interfacial failure to partial button failure, thereby enhancing the mechanical properties of the joint. Full article
(This article belongs to the Special Issue Welding and Joining Technology of Dissimilar Metal Materials)
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21 pages, 1669 KB  
Article
Comparison of the CO2 Balance in Electroslag Reduction of Cadmium with Pyrometallurgical and Hydrometallurgical Recovery Methods
by Ervīns Blumbergs, Michail Maiorov, Artūrs Brēķis, Ernests Platacis, Sergei Ivanov, Jekaterina Nikitina, Artur Bogachov and Vladimir Pankratov
Metals 2025, 15(11), 1197; https://doi.org/10.3390/met15111197 - 27 Oct 2025
Cited by 1 | Viewed by 869
Abstract
This study presents a carbon footprint assessment of a novel electroslag method for cadmium (Cd) recovery from spent nickel–cadmium (Ni-Cd) batteries in comparison with the carbon footprints of pyrometallurgical and hydrometallurgical cadmium recovery methods. A comparison of CO2 emissions in three types [...] Read more.
This study presents a carbon footprint assessment of a novel electroslag method for cadmium (Cd) recovery from spent nickel–cadmium (Ni-Cd) batteries in comparison with the carbon footprints of pyrometallurgical and hydrometallurgical cadmium recovery methods. A comparison of CO2 emissions in three types of technological processes during the recovery of 1 kg of cadmium is carried out. Energy inputs and CO2 emissions are calculated for the electroslag process and compared to conventional methods, such as pyrometallurgical and hydrometallurgical reduction methods. The electroslag process eliminates cadmium vaporization by using molten KCl–NaCl flux and carbon under electromagnetic stirring. Cadmium reduction occurs under a layer of flux, which prevents the contact of the reduced cadmium with the atmosphere. The electroslag process temperature is limited to 700 °C, which is lower than the boiling point of cadmium (767 °C). The electroslag remelting process uses molten KCl–NaCl flux and carbon as a reductant under electrovortex flow stirring. The pyrometallurgical method for extracting cadmium from nickel–cadmium batteries is based on the reduction of cadmium with carbon at high temperatures. In the pyrometallurgical process, coal (anthracite) is used as the carbonaceous material, which can extract 99.92% of cadmium at 900 °C. Cadmium is separated using a vacuum at temperatures ranging from 800 °C to 950 °C for several hours. Hydrometallurgy is a metal extraction process involving chemical reactions that occur in organic or aqueous solutions at low temperatures. The hydrometallurgical process involves a series of acid or alkaline leaches, followed by separation and purification methods such as absorption, cementation, ion exchange, and solvent extraction to separate and concentrate metals from leach solutions. Full article
(This article belongs to the Section Extractive Metallurgy)
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15 pages, 16004 KB  
Article
Fabrication of Graphite Flake/Al Composites via the Hybrid Powder-Melt Process: Synergistic Enhancement of Strength and Conductivity Through Low Content Addition
by Jiapeng Luo, Chunyang Lu, Feihua Liu, Xinwei Yang, Ziren Wang, Qian Qian, Ming Yan and Haihui Lin
Materials 2025, 18(20), 4683; https://doi.org/10.3390/ma18204683 - 13 Oct 2025
Cited by 1 | Viewed by 1019
Abstract
This study addresses the challenge of simultaneously improving the electrical conductivity and strength of aluminum alloys. We innovatively combine powder metallurgy with melt stirring casting to fabricate graphite flake-added aluminum matrix composites through secondary remelting, electromagnetic stirring, and extruding. The influence of graphite [...] Read more.
This study addresses the challenge of simultaneously improving the electrical conductivity and strength of aluminum alloys. We innovatively combine powder metallurgy with melt stirring casting to fabricate graphite flake-added aluminum matrix composites through secondary remelting, electromagnetic stirring, and extruding. The influence of graphite flake content gradient (0–3.0 wt.%) on the mechanical properties and electrical conductivity was systematically investigated. Our results demonstrate that the composite with 0.2 wt.% graphite flakes (sample GM02) exhibits optimal comprehensive performance: tensile strength reaches 100.9 MPa (a 124% increase over pure Al), and electrical conductivity reaches 67.1% IACS (a 9.6% increase). Microstructural analysis reveals that low-content graphite flakes effectively suppressed electron scattering by forming semi-coherent interfaces. However, when graphite flake content exceeds 0.5 wt.%, a significant decrease in conductivity and plasticity (elongation below 10%) occurs due to increased Al4C3 phase formation, enhanced grain boundary scattering caused by grain refinement, and porosity defects induced by graphite flake agglomeration. This study provides a novel approach for the industrial production of high-performance, lightweight conductive components. Full article
(This article belongs to the Special Issue Advanced Materials Processing Technologies for Lightweight Design)
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35 pages, 9383 KB  
Review
Advances in Integrated Extraction of Valuable Components from Ti-Bearing Slag
by Chenhui Li, Peipei Du, Jiansong Zhang, Suxing Zhao, Minglei Gao, Qianhua Wang, Tielei Tian, Lanjie Li and Yue Long
Metals 2025, 15(10), 1080; https://doi.org/10.3390/met15101080 - 27 Sep 2025
Cited by 3 | Viewed by 2103
Abstract
Ti-bearing blast furnace slag (TBS), a byproduct of vanadium–titanium magnetite smelting, serves as an important secondary resource for titanium recovery. However, the complex mineralogical composition and finely dispersed nature of titanium in TBS present significant challenges for efficient extraction. This review systematically examines [...] Read more.
Ti-bearing blast furnace slag (TBS), a byproduct of vanadium–titanium magnetite smelting, serves as an important secondary resource for titanium recovery. However, the complex mineralogical composition and finely dispersed nature of titanium in TBS present significant challenges for efficient extraction. This review systematically examines four major titanium extraction routes: hydrometallurgical leaching, pyrometallurgical smelting, molten salt electrolysis, and selective precipitation, focusing on their limitations and recent improvements. For instance, conventional acid leaching suffers from acid mist release, a colloidal formation that hinders titanium recovery, and waste acid pollution. The adoption of concentrated sulfuric acid roasting activation effectively suppresses acid mist emission and prevents colloidal generation. Pyrometallurgical approaches are hampered by high energy consumption and substantial carbon emissions, which can be alleviated through the use of gaseous reductants to enhance reaction efficiency and reduce environmental impact. Molten electrolysis faces issues such as polarization and undesirable dendritic deposition; these are mitigated by employing liquid metal cathodes integrated with vacuum distillation to achieve high-purity titanium products. Selective precipitation struggles with strict crystallization conditions and low separation efficiency, though advanced techniques like supergravity separation show improved extraction performance. We propose an integrated technical strategy termed “Online conditioning driven by waste heat-mineral phase reconstruction-directional crystallization-optimized liberation.” This approach utilizes the inherent waste heat of slag combined with electromagnetic stirring to enhance homogeneity and promote efficient titanium recovery, offering a sustainable and scalable solution for industrial TBS treatment. Full article
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22 pages, 6310 KB  
Article
A Green Electroslag Technology for Cadmium Recovery from Spent Ni-Cd Batteries Under Protective Flux with Electromagnetic Stirring by Electrovortex Flows
by Ervīns Blumbergs, Michail Maiorov, Artur Bogachov, Ernests Platacis, Sergei Ivanov, Pavels Gavrilovs and Vladimir Pankratov
Metals 2025, 15(9), 959; https://doi.org/10.3390/met15090959 - 29 Aug 2025
Cited by 3 | Viewed by 1417
Abstract
The recycling of nickel–cadmium batteries poses a significant environmental challenge due to cadmium’s high biotoxicity. This study proposes a green method for recovering cadmium from cadmium oxide (CdO) using carbon (coal) in the presence of a molten binary flux (KCl:NaCl = 0.507:0.493, melting [...] Read more.
The recycling of nickel–cadmium batteries poses a significant environmental challenge due to cadmium’s high biotoxicity. This study proposes a green method for recovering cadmium from cadmium oxide (CdO) using carbon (coal) in the presence of a molten binary flux (KCl:NaCl = 0.507:0.493, melting point 667 °C). The flux’s relatively low density and conductivity enable cadmium reduction beneath and through the flux layer. Brown coal (5–25 mm) served as the reductant. The reduction of cadmium from cadmium oxide with carbon (brown coal) took place in the temperature range from 667 °C to 700 °C. To enhance the process, electrovortex flows (EVF) were employed—generated by the interaction between non-uniform AC electric currents and their self-induced magnetic fields resembling conditions in a fluidised bed reactor. The graphite crucible acted as both one of the electrodes, with a graphite rod as the second electrode. As Cd and CdO are denser than both the flux and coal, the reduction proceeded below the flux layer. The flux facilitated CdO transport to the reductant, speeding up the reaction. X-ray diffraction (XRD) and scanning electron microscopy (SEM) confirmed the formation of metallic cadmium beneath and within the flux layer. This method demonstrates the feasibility of flux-assisted cadmium recovery without prior mixing and offers a foundation for further optimisation of sustainable battery recycling. Full article
(This article belongs to the Special Issue Green Technologies in Metal Recovery)
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13 pages, 2073 KB  
Article
Dynamic Nucleation in Zr-2.5Nb During Reduced-Gravity Electromagnetic Levitation Experiments
by Gwendolyn P. Bracker, Stephan Schneider, Sarah Nell, Mitja Beckers, Markus Mohr and Robert W. Hyers
Crystals 2025, 15(8), 703; https://doi.org/10.3390/cryst15080703 - 31 Jul 2025
Viewed by 1110
Abstract
Levitation techniques reduce the available heterogeneous nucleation sites and provide stable access to deeply undercooled melts. However, some samples have repeatably demonstrated that, in the presence of strong stirring, solidification may be induced at moderate, sub-critical undercoolings. Dynamic nucleation is a mechanism by [...] Read more.
Levitation techniques reduce the available heterogeneous nucleation sites and provide stable access to deeply undercooled melts. However, some samples have repeatably demonstrated that, in the presence of strong stirring, solidification may be induced at moderate, sub-critical undercoolings. Dynamic nucleation is a mechanism by which solidification may be induced through flow effects within a sub-critically undercooled melt. In this mechanism, collapsing cavities within the melt produce very high-pressure shocks, which shift the local melting temperature. In these regions of locally shifted melt temperatures, thermodynamic conditions enable nuclei to grow and trigger solidification of the full sample. By deepening the local undercooling, dynamic nucleation enables solidification to occur in conditions where classical nucleation does not. Dynamic nucleation has been observed in several zirconium and zirconium-based samples in the Electromagnetic Levitator onboard the International Space Station (ISS-EML). The experiments presented here address conditions in which a zirconium sample alloyed with 2.5 atomic percent niobium spontaneously solidifies during electromagnetic levitation experiments with strong melt stirring. In these experimental conditions, classical nucleation predicts the sample to remain liquid. This solidification behavior is consistent with the solidification behavior observed in prior experiments on pure zirconium. Full article
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14 pages, 2508 KB  
Article
Enhancement of Efficiency in an Ex Situ Coprecipitation Method for Superparamagnetic Bacterial Cellulose Hybrid Materials
by Thaís Cavalcante de Souza, Italo José Batista Durval, Hugo Moraes Meira, Andréa Fernanda de Santana Costa, Eduardo Padrón Hernández, Attilio Converti, Glória Maria Vinhas and Leonie Asfora Sarubbo
Membranes 2025, 15(7), 198; https://doi.org/10.3390/membranes15070198 - 1 Jul 2025
Cited by 2 | Viewed by 1373
Abstract
Superparamagnetic magnetite nanoparticles (Fe3O4) have garnered considerable interest due to their unique magnetic properties and potential for integration into multifunctional biomaterials. In particular, their incorporation into bacterial cellulose (BC) matrices offers a promising route for developing sustainable and high-performance [...] Read more.
Superparamagnetic magnetite nanoparticles (Fe3O4) have garnered considerable interest due to their unique magnetic properties and potential for integration into multifunctional biomaterials. In particular, their incorporation into bacterial cellulose (BC) matrices offers a promising route for developing sustainable and high-performance magnetic composites. Numerous studies have explored BC-magnetite systems; however, innovations combining ex situ coprecipitation synthesis within BC matrices, tailored reagent molar ratios, stirring protocols, and purification processes remain limited. This study aimed to optimize the ex situ coprecipitation method for synthesizing superparamagnetic magnetite nanoparticles embedded in BC membranes, focusing on enhancing particle stability and crystallinity. BC membranes containing varying concentrations of magnetite (40%, 50%, 60%, and 70%) were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and vibrating sample magnetometry (VSM). The resulting magnetic BC membranes demonstrated homogenous dispersion of nanoparticles, improved crystallite size (6.96 nm), and enhanced magnetic saturation (Ms) (50.4 emu/g), compared to previously reported methods. The adoption and synergistic optimization of synthesis parameters—unique to this study—conferred greater control over the physicochemical and magnetic properties of the composites. These findings position the optimized BC-magnetite nanocomposites as highly promising candidates for advanced applications, including electromagnetic interference (EMI) shielding, electronic devices, gas sensors, MRI contrast agents, and targeted drug delivery systems. Full article
(This article belongs to the Section Membrane Fabrication and Characterization)
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17 pages, 5463 KB  
Article
The Effect of Forced Melt Flow by a Rotating Magnetic Field and Solid/Liquid Front Velocity on the Size and Morphology of Primary Si in a Hypereutectic Al-18 wt.% Si Alloy
by Dimah Zakaraia, András Roósz, Arnold Rónaföldi and Zsolt Veres
Materials 2025, 18(11), 2581; https://doi.org/10.3390/ma18112581 - 31 May 2025
Cited by 2 | Viewed by 1048
Abstract
Hypereutectic Al-Si alloys containing primary Si exhibit unique material properties that make them suitable for various industrial applications. Understanding the characteristics of primary Si is crucial for predicting the effect of solidification conditions on the microstructure of these alloys. This paper presents a [...] Read more.
Hypereutectic Al-Si alloys containing primary Si exhibit unique material properties that make them suitable for various industrial applications. Understanding the characteristics of primary Si is crucial for predicting the effect of solidification conditions on the microstructure of these alloys. This paper presents a comprehensive characterisation study of primary Si in hypereutectic alloys. This study provides a detailed analysis of the size, distribution, and morphology of primary Si, providing valuable insights into the alloy structure, mechanical properties, and even the performance of the production process. The effect of forced melt flow by a rotating magnetic field (RMF) and solid/liquid front velocity on the size and morphology of primary Si in a hypereutectic Al-18 wt.% Si alloy was investigated. The purpose of using the RMF technique during the solidification process of Al-Si alloys is to enhance the alloy’s microstructure by inducing electromagnetic stirring. The hypereutectic samples were solidified at five different front velocities (0.02, 0.04, 0.08, 0.2, and 0.4 mm/s), under an average temperature gradient (G) of 8 K/mm, in a crystalliser equipped with an RMF inductor. Each sample was divided into two parts: the first solidified without stirring, while the second underwent electromagnetic stirring using RMF at an induction (B) of 7.2 mT. The results revealed that increasing the front velocity during solidification refined the primary Si in stirred and non-stirred parts. In non-stirred parts, it decreased dendritic forms and increased star-like Si, while polyhedral shapes remained nearly constant. Stirred parts showed stable Si morphology across velocities. Higher velocities also promoted equiaxed over elongated Si forms in both parts. Full article
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15 pages, 4626 KB  
Article
Numerical Simulation of Fluid Flow and Solidification in Round Bloom Continuous Casting with Alternate Final Electromagnetic Stirring
by Bingzhi Ren, Lilong Zhu, Hongdan Wang and Dengfu Chen
Metals 2025, 15(6), 605; https://doi.org/10.3390/met15060605 - 28 May 2025
Cited by 4 | Viewed by 2201
Abstract
Final electromagnetic stirring (F-EMS) effectively improves macrosegregation and central porosity in round bloom continuous casting, while the flow and solidification of molten steel under F-EMS have a direct impact on metallurgical properties. Fluid flow and solidification behavior in a 600 mm round bloom [...] Read more.
Final electromagnetic stirring (F-EMS) effectively improves macrosegregation and central porosity in round bloom continuous casting, while the flow and solidification of molten steel under F-EMS have a direct impact on metallurgical properties. Fluid flow and solidification behavior in a 600 mm round bloom continuous casting process with F-EMS were simulated. The influence of the liquid fraction model on strand temperature distribution was investigated. The flow of molten steel was analyzed under both continuous and alternate stirring modes. The results indicated that in continuous stirring mode, the stirring velocity fluctuates between peaks and troughs over a specific period. The closer the F-EMS is to the meniscus, the larger the mushy zone area and the higher the stirring velocity. Due to the 10+ s rise time for current intensity, a 25 s forward and reverse stirring duration is recommended for Φ600 mm round bloom continuous casting with F-EMS. Full article
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21 pages, 8308 KB  
Article
Endogenous–Exogenous Analyses of the Solidification Structure in 475 mm Extra-Thick Slabs: Columnar-to-Equiaxed Positioning and Effect of Strand Electromagnetic Stirring
by Kezai Yu, Lijun Xu, Yanling Zhang, Haibo Zhang and Zhonghua Zhan
Materials 2025, 18(10), 2179; https://doi.org/10.3390/ma18102179 - 8 May 2025
Cited by 2 | Viewed by 1031
Abstract
The spatial distribution of equiaxed crystal zones during extra-thick slab solidification exerts a critical influence on the mechanical performance of the final product. This investigation establishes a dual-pathway control framework for solidification structure modulation, differentiating between intrinsic regulation through columnar-to-equiaxed transition (CET) positioning [...] Read more.
The spatial distribution of equiaxed crystal zones during extra-thick slab solidification exerts a critical influence on the mechanical performance of the final product. This investigation establishes a dual-pathway control framework for solidification structure modulation, differentiating between intrinsic regulation through columnar-to-equiaxed transition (CET) positioning and extrinsic intervention via strand electromagnetic stirring (S-EMS) parameter adjustment. The aim is to improve the internal quality of extra-thick slabs, enabling further investigations into the material properties. To achieve this, a solidification heat transfer model along with a cellular automata–finite element model were developed to characterize the thermal conditions at CET initiation, with experimental validation conducted on a 475 mm extra-thick slab. The systematic analysis identified a significant correlation between continuous casting parameters, alloy concentrations, and CET positioning, while S-EMS experiments further elucidated the distribution patterns of the solidification structure and the formation mechanism of the white band in the mushy zone. This methodology bridges computational metallurgy with process engineering, offering systematic guidance for solidification structure control in extra-thick slabs. Full article
(This article belongs to the Section Advanced Materials Characterization)
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