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Keywords = effective thermal conductivity enhancement

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14 pages, 2058 KiB  
Article
Integration of Daylight in Building Design as a Way to Improve the Energy Efficiency of Buildings
by Adrian Trząski and Joanna Rucińska
Energies 2025, 18(15), 4113; https://doi.org/10.3390/en18154113 (registering DOI) - 2 Aug 2025
Abstract
According to the United Nations Environment Programme reports, buildings are responsible for nearly 40% of energy-related emissions; therefore, energy-optimized building design is crucial to reduce the reliance on non-renewable energy sources as well as greenhouse gas emissions. The OECD reports indicate the use [...] Read more.
According to the United Nations Environment Programme reports, buildings are responsible for nearly 40% of energy-related emissions; therefore, energy-optimized building design is crucial to reduce the reliance on non-renewable energy sources as well as greenhouse gas emissions. The OECD reports indicate the use of Building Information Modelling (BIM) as one of the effective strategies for decarbonization of buildings, since a 3D digital representation of both physical and functional characteristics of a building can help to design a more efficient infrastructure. An efficient integration of solar energy in building design can be vital for the enhancement of energy performance in terms of heating, cooling, and lighting demand. This paper presents results of an analysis of how factors related to the use of daylight, such as automatic control of artificial lighting, external shading, or the visual absorptance of internal surfaces, influence the energy efficiency within an example room in two different climatic zones. The simulation was conducted using Design Builder software, with predefined occupancy schedules and internal heat gains, and standard EPW weather files for Warsaw and Genua climate zones. The study indicates that for the examined room, when no automatic sunshades or a lighting control system is utilized, most of the final energy demand is for cooling purposes (45–54%), followed by lighting (42–43%), with only 3–12% for heating purposes. The introduction of sunshades and/or the use of daylight allowed for a reduction of the total demand by up to half. Moreover, it was pointed out that often neglected factors, like the colour of the internal surfaces, can have a significant effect on the final energy consumption. In variants with light interior, the total energy consumption was lower by about 3–4% of the baseline demand, compared to their corresponding ones with dark surfaces. These results are consistent with previous studies on daylighting strategies and highlight the importance of considering both visual and thermal impacts when evaluating energy performance. Similarly, possible side effects of certain actions were highlighted, such as an increase in heat demand resulting from a reduced need for artificial lighting. The results of the analysis highlight the potential of a simulation-based design approach in optimizing daylight use, contributing to the broader goals of building decarbonization. Full article
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18 pages, 6891 KiB  
Article
Physics-Based Data Augmentation Enables Accurate Machine Learning Prediction of Melt Pool Geometry
by Siqi Liu, Ruina Li, Jiayi Zhou, Chaoyuan Dai, Jingui Yu and Qiaoxin Zhang
Appl. Sci. 2025, 15(15), 8587; https://doi.org/10.3390/app15158587 (registering DOI) - 2 Aug 2025
Abstract
Accurate melt pool geometry prediction is essential for ensuring quality and reliability in Laser Powder Bed Fusion (L-PBF). However, small experimental datasets and limited physical interpretability often restrict the effectiveness of traditional machine learning (ML) models. This study proposes a hybrid framework that [...] Read more.
Accurate melt pool geometry prediction is essential for ensuring quality and reliability in Laser Powder Bed Fusion (L-PBF). However, small experimental datasets and limited physical interpretability often restrict the effectiveness of traditional machine learning (ML) models. This study proposes a hybrid framework that integrates an explicit thermal model with ML algorithms to improve prediction under sparse data conditions. The explicit model—calibrated for variable penetration depth and absorptivity—generates synthetic melt pool data, augmenting 36 experimental samples across conduction, transition, and keyhole regimes for 316 L stainless steel. Three ML methods—Multilayer Perceptron (MLP), Random Forest, and XGBoost—are trained using fivefold cross-validation. The hybrid approach significantly improves prediction accuracy, especially in unstable transition regions (D/W ≈ 0.5–1.2), where morphological fluctuations hinder experimental sampling. The best-performing model (MLP) achieves R2 > 0.98, with notable reductions in MAE and RMSE. The results highlight the benefit of incorporating physically consistent, nonlinearly distributed synthetic data to enhance generalization and robustness. This physics-augmented learning strategy not only demonstrates scientific novelty by integrating mechanistic modeling into data-driven learning, but also provides a scalable solution for intelligent process optimization, in situ monitoring, and digital twin development in metal additive manufacturing. Full article
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32 pages, 2962 KiB  
Article
Optimizing Passive Thermal Enhancement via Embedded Fins: A Multi-Parametric Study of Natural Convection in Square Cavities
by Saleh A. Bawazeer
Energies 2025, 18(15), 4098; https://doi.org/10.3390/en18154098 (registering DOI) - 1 Aug 2025
Abstract
Internal fins are commonly utilized as a passive technique to enhance natural convection, but their efficiency depends on complex interplay between fin design, material properties, and convective strength. This study presents an extensive numerical analysis of buoyancy-driven flow in square cavities containing a [...] Read more.
Internal fins are commonly utilized as a passive technique to enhance natural convection, but their efficiency depends on complex interplay between fin design, material properties, and convective strength. This study presents an extensive numerical analysis of buoyancy-driven flow in square cavities containing a single horizontal fin on the hot wall. Over 9000 simulations were conducted, methodically varying the Rayleigh number (Ra = 10 to 105), Prandtl number (Pr = 0.1 to 10), and fin characteristics, such as length, vertical position, thickness, and the thermal conductivity ratio (up to 1000), to assess their overall impact on thermal efficiency. Thermal enhancements compared to scenarios without fins are quantified using local and average Nusselt numbers, as well as a Nusselt number ratio (NNR). The results reveal that, contrary to conventional beliefs, long fins positioned centrally can actually decrease heat transfer by up to 11.8% at high Ra and Pr due to the disruption of thermal plumes and diminished circulation. Conversely, shorter fins located near the cavity’s top and bottom wall edges can enhance the Nusselt numbers for the hot wall by up to 8.4%, thereby positively affecting the development of thermal boundary layers. A U-shaped Nusselt number distribution related to fin placement appears at Ra ≥ 103, where edge-aligned fins consistently outperform those positioned mid-height. The benefits of high-conductivity fins become increasingly nonlinear at larger Ra, with advantages limited to designs that minimally disrupt core convective patterns. These findings challenge established notions regarding passive thermal enhancement and provide a predictive thermogeometric framework for designing enclosures. The results can be directly applied to passive cooling systems in electronics, battery packs, solar thermal collectors, and energy-efficient buildings, where optimizing heat transfer is vital without employing active control methods. Full article
18 pages, 3967 KiB  
Article
A Thorough Investigation of the Mechanism of theAntagonistic Effect Between Phosphorus and Basic Oxide-Forming Minerals as Flame Retardants of PolymericComposite Coatings
by Evangelia Mitropoulou, Georgios N. Mathioudakis, Amaia Soto Beobide, Athanasios Porfyris, Vassilios Dracopoulos, Kerim Kılınç, Theodosios Chatzinikolaou, Deniz Savci, Cem Gunesoglu, Joannis Kallitsis and George A. Voyiatzis
Coatings 2025, 15(8), 886; https://doi.org/10.3390/coatings15080886 - 30 Jul 2025
Viewed by 153
Abstract
Halogenated flame retardants have been amongst the most widely used and effective solutions for enhancing fire resistance. However, their use is currently strictly regulated due to serious health and environmental concerns. In this context, phosphorus-based and mineral flame retardants have emerged as promising [...] Read more.
Halogenated flame retardants have been amongst the most widely used and effective solutions for enhancing fire resistance. However, their use is currently strictly regulated due to serious health and environmental concerns. In this context, phosphorus-based and mineral flame retardants have emerged as promising alternatives. Despite this, their combined use is neither straightforward nor guaranteed to be effective. This study scrutinizes the interactions between these two classes of flame retardants (FR) through a systematic analysis aimed at elucidating the antagonistic pathways that arise from their coexistence. Specifically, this study focuses on two inorganic fillers, mineral huntite and chemically precipitated magnesium hydroxide, both of which produce basic oxides upon thermal decomposition. These fillers were incorporated into a poly(butylene terephthalate) (PBT) matrix to be utilized as advanced-mattress FR coating fabric and were subjected to a series of flammability tests. The pyrolysis products of the prepared polymeric composite compounds were isolated and thoroughly characterized using a combination of analytical techniques. Thermogravimetric analysis (TGA) and differential thermogravimetric analysis (dTGA) were employed to monitor decomposition behavior, while the char residues collected at different pyrolysis stages were examined spectroscopically, using FTIR-ATR and Raman spectroscopy, to identify their structure and the chemical reactions that led to their formation. X-ray diffraction (XRD) experiments were also conducted to complement the spectroscopic findings in the chemical composition of the resulting char residues and to pinpoint the different species that constitute them. The morphological changes of the char’s structure were monitored by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS). Finally, the Limited Oxygen Index (LOI) and UL94 (vertical sample mode) methods were used to assess the relative flammability of the samples, revealing a significant drop in flame retardancy when both types of flame retardants are present. This reduction is attributed to the neutralization of acidic phosphorus species by the basic oxides generated during the decomposition of the basic inorganic fillers, as confirmed by the characterization techniques employed. These findings underscore the challenge of combining organophosphorus with popular flame-retardant classes such as mineral or basic metal flame retardants, offering insight into a key difficulty in formulating next-generation halogen-free flame-retardant composite coatings. Full article
(This article belongs to the Special Issue Innovative Flame-Retardant Coatings for High-Performance Materials)
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20 pages, 3039 KiB  
Article
Heat Transfer Performance and Influencing Factors of Waste Tires During Pyrolysis in a Horizontal Rotary Furnace
by Hongting Ma, Yang Bai, Shuo Ma and Zhipeng Zhou
Energies 2025, 18(15), 4028; https://doi.org/10.3390/en18154028 - 29 Jul 2025
Viewed by 167
Abstract
Pyrolysis technology currently serves as a significant method for recycling and reducing waste tires. In this paper, in order to improve the heat transfer efficiency during the pyrolysis of waste tires in a horizontal rotary furnace and the yield of pyrolysis oil, the [...] Read more.
Pyrolysis technology currently serves as a significant method for recycling and reducing waste tires. In this paper, in order to improve the heat transfer efficiency during the pyrolysis of waste tires in a horizontal rotary furnace and the yield of pyrolysis oil, the effect laws of tire particle size, rotary furnace rotation speed, enhanced heat transfer materials, and adding spiral fins on heat transfer performance and pyrolysis product distribution were studied, respectively. The innovation lies in two aspects: first, aiming at the problems of slow heat transfer and low pyrolysis efficiency in horizontal rotary furnaces, we identified technical measures through experiments to enhance heat transfer, thereby accelerating pyrolysis and reducing energy consumption; second, with the goal of increasing high-value pyrolysis oil yield, we determined optimal operating parameters to improve economic and sustainability outcomes. The results showed that powdered particles of waste tires were heated more evenly during the pyrolysis process, which increased the overall heat transfer coefficient and the proportion of liquid products. When the rotational speed of the rotary pyrolysis furnace exceeded 2 rpm, there was sufficient contact between the material and the furnace wall, which was beneficial to the improvement of heat transfer performance. Adding heat transfer enhancement materials such as carborundum and white alundum could improve the heat transfer performance between the pyrolysis furnace and the material. Notably, a rotational speed of 3 rpm and carborundum were used as a heat transfer enhancement material with powdered waste tire particles during the pyrolysis process; the overall heat transfer coefficient was the highest, which was 16.89 W/(m2·K), and the proportion of pyrolysis oil products was 46.1%. When spiral fins were installed, the comprehensive heat transfer coefficient was increased from 12.78 W/(m2·K) to 16.32 W/(m2·K). The experimental results show that by increasing the speed of the pyrolysis furnace, adding heat transfer enhancing materials with high thermal conductivity to waste tires, and appropriate particle size, the heat transfer performance and pyrolysis rate can be improved, and energy consumption can be reduced. Full article
(This article belongs to the Special Issue Heat Transfer Performance and Influencing Factors of Waste Management)
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14 pages, 966 KiB  
Article
Investigation of the Thermal Conductance of MEMS Contact Switches
by Zhiqiang Chen and Zhongbin Xie
Micromachines 2025, 16(8), 872; https://doi.org/10.3390/mi16080872 - 28 Jul 2025
Viewed by 222
Abstract
Microelectromechanical system (MEMS) devices are specialized electronic devices that integrate the benefits of both mechanical and electrical structures. However, the contact behavior between the interfaces of these structures can significantly impact the performance of MEMS devices, particularly when the surface roughness approaches the [...] Read more.
Microelectromechanical system (MEMS) devices are specialized electronic devices that integrate the benefits of both mechanical and electrical structures. However, the contact behavior between the interfaces of these structures can significantly impact the performance of MEMS devices, particularly when the surface roughness approaches the characteristic size of the devices. In such cases, the contact between the interfaces is not a perfect face-to-face interaction but occurs through point-to-point contact. As a result, the contact area changes with varying contact pressures and surface roughness, influencing the thermal and electrical performance. By integrating the CMY model with finite element simulations, we systematically explored the thermal conductance regulation mechanism of MEMS contact switches. We analyzed the effects of the contact pressure, micro-hardness, surface roughness, and other parameters on thermal conductance, providing essential theoretical support for enhancing reliability and optimizing thermal management in MEMS contact switches. We examined the thermal contact, gap, and joint conductance of an MEMS switch under different contact pressures, micro-hardness values, and surface roughness levels using the CMY model. Our findings show that both the thermal contact and gap conductance increase with higher contact pressure. For a fixed contact pressure, the thermal contact conductance decreases with rising micro-hardness and root mean square (RMS) surface roughness but increases with a higher mean asperity slope. Notably, the thermal gap conductance is considerably lower than the thermal contact conductance. Full article
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11 pages, 2348 KiB  
Article
Study on Smoke Flow and Temperature Distribution Patterns in Fires at Deeply Buried Subway Stations
by Huailin Yan, Heng Liu, Yongchang Zhao and Zirui Bian
Fire 2025, 8(8), 296; https://doi.org/10.3390/fire8080296 - 28 Jul 2025
Viewed by 248
Abstract
To enhance the fire safety protection level of deeply buried metro stations, this study conducted full-scale fire experiments based on Wulichong Station of Guiyang Metro Line 3. It systematically investigated the laws of smoke movement and temperature distribution under the coupled effects of [...] Read more.
To enhance the fire safety protection level of deeply buried metro stations, this study conducted full-scale fire experiments based on Wulichong Station of Guiyang Metro Line 3. It systematically investigated the laws of smoke movement and temperature distribution under the coupled effects of different fire source powers and smoke extraction system states. Through the set up of multiple sets of comparative test conditions, the study focused on analyzing the influence mechanism of the operation (on/off) of the smoke extraction system on smoke spread characteristics and temperature field distribution. The results indicate that under the condition where the smoke extraction system is turned off, the smoke exhibits typical stratified spread characteristics driven by thermal buoyancy, with the temperature rising significantly as the vertical height increases. When the smoke extraction system is activated, the horizontal airflow generated by mechanical smoke extraction significantly alters the flame morphology (with an inclination angle exceeding 45°), effectively extracting and discharging the hot smoke and leading to a more uniform temperature distribution within the space. Full article
(This article belongs to the Special Issue Advances in Fire Science and Fire Protection Engineering)
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13 pages, 1758 KiB  
Article
Microwave Based Non-Destructive Testing for Detecting Cold Welding Defects in Thermal Fusion Welded High-Density Polyethylene Pipes
by Zhen Wang, Chaoming Zhu, Jinping Pan, Ran Huang and Lianjiang Tan
Polymers 2025, 17(15), 2048; https://doi.org/10.3390/polym17152048 - 27 Jul 2025
Viewed by 194
Abstract
High-density polyethylene (HDPE) pipes are widely used in urban natural gas pipeline systems due to their excellent mechanical and chemical properties. However, welding joints are critical weak points in these pipelines, and defects, such as cold welding—caused by reduced temperature or/and insufficient pressure—pose [...] Read more.
High-density polyethylene (HDPE) pipes are widely used in urban natural gas pipeline systems due to their excellent mechanical and chemical properties. However, welding joints are critical weak points in these pipelines, and defects, such as cold welding—caused by reduced temperature or/and insufficient pressure—pose significant safety risks. Traditional non-destructive testing (NDT) methods face challenges in detecting cold welding defects due to the polymer’s complex structure and characteristics. This study presents a microwave-based NDT system for detecting cold welding defects in thermal fusion welds of HDPE pipes. The system uses a focusing antenna with a resonant cavity, connected to a vector network analyzer (VNA), to measure changes in microwave parameters caused by cold welding defects in thermal fusion welds. Experiments conducted on HDPE pipes welded at different temperatures demonstrated the system’s effectiveness in identifying areas with a lack of fusion. Mechanical and microstructural analyses, including tensile tests and scanning electron microscopy (SEM), confirmed that cold welding defects lead to reduced mechanical properties and lower material density. The proposed microwave NDT method offers a sensitive, efficient approach for detecting cold welds in HDPE pipelines, enhancing pipeline integrity and safety. Full article
(This article belongs to the Special Issue Additive Agents for Polymer Functionalization Modification)
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19 pages, 6832 KiB  
Article
Study on the Optimization of Textured Coating Tool Parameters Under Thermal Assisted Process Conditions
by Xin Tong, Xiyue Wang, Xinyu Li and Baiyi Wang
Coatings 2025, 15(8), 876; https://doi.org/10.3390/coatings15080876 - 25 Jul 2025
Viewed by 243
Abstract
As manufacturing demands for challenging-to-machine metallic materials continue to evolve, the performance of cutting tools has emerged as a critical limiting factor. The synergistic application of micro-texture and coating in cutting tools can improve various properties. For the processing of existing micro-texture, because [...] Read more.
As manufacturing demands for challenging-to-machine metallic materials continue to evolve, the performance of cutting tools has emerged as a critical limiting factor. The synergistic application of micro-texture and coating in cutting tools can improve various properties. For the processing of existing micro-texture, because of the fast cooling and heating processing method of laser, there are defects such as remelted layer stacking and micro-cracks on the surface after processing. This study introduces a preheating-assisted technology aimed at optimizing the milling performance of textured coated tools. A milling test platform was established to evaluate the performance of these tools on titanium alloys under thermally assisted conditions. The face-centered cubic response surface methodology, as part of the central composite design (CCD) experimental framework, was employed to investigate the interaction effects of micro-texture preparation parameters and thermal assistance temperature on milling performance. The findings indicate a significant correlation between thermal assistance temperature and tool milling performance, suggesting that an appropriately selected thermal assistance temperature can enhance both the milling efficiency of the tool and the surface quality of the titanium alloy. Utilizing the response surface methodology, a multi-objective optimization of the textured coating tool-preparation process was conducted, resulting in the following optimized parameters: laser power of 45 W, scanning speed of 1576 mm/s, the number of scans was 7, micro-texture spacing of 130 μm, micro-texture diameter of 30 μm, and a heat-assisted temperature of 675.15 K. Finally, the experimental platform of optimization results is built, which proves that the optimization results are accurate and reliable, and provides theoretical basis and technical support for the preparation process of textured coating tools. It is of great significance to realize high-precision and high-quality machining of difficult-to-machine materials such as titanium alloy. Full article
(This article belongs to the Special Issue Cutting Performance of Coated Tools)
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19 pages, 3828 KiB  
Communication
Multifunctional Graphene–Concrete Composites: Performance and Mechanisms
by Jun Shang, Mingyang Wang, Pei Wang, Mengyao Yang, Dingyang Zhang, Xuelei Cheng, Yifan Wu and Wangze Du
Appl. Sci. 2025, 15(15), 8271; https://doi.org/10.3390/app15158271 - 25 Jul 2025
Viewed by 229
Abstract
Concrete is a cornerstone material in the construction industry owing to its versatile performance; however, its inherent brittleness, low tensile strength, and poor permeability resistance limit its broader application. Graphene, with its exceptional thermal conductivity, stable lattice structure, and high specific surface area, [...] Read more.
Concrete is a cornerstone material in the construction industry owing to its versatile performance; however, its inherent brittleness, low tensile strength, and poor permeability resistance limit its broader application. Graphene, with its exceptional thermal conductivity, stable lattice structure, and high specific surface area, presents a transformative solution to these challenges. Despite its promise, comprehensive studies on the multifunctional properties and underlying mechanisms of graphene-enhanced concrete remain scarce. In this study, we developed a novel concrete composite incorporating cement, coarse sand, crushed stone, water, and graphene, systematically investigating the effects of the graphene dosage and curing duration on its performance. Our results demonstrate that graphene incorporation markedly improves the material’s density, brittleness, thermal conductivity, and permeability resistance. Notably, a comprehensive analysis of scanning electron microscopy (SEM) images and thermogravimetric (TG) data demonstrates that graphene-modified concrete exhibits a denser microstructure and the enhanced formation of hydration products compared to conventional concrete. In addition, the graphene-reinforced concrete exhibited a 44% increase in compressive strength, a 0.7% enhancement in the photothermal absorption capacity, a 0.4% decrease in maximum heat release, a 0.8% increase in heat-storage capacity, and a 200% reduction in the maximum penetration depth. These findings underscore the significant potential of graphene-reinforced concrete for advanced construction applications, offering superior mechanical strength, thermal regulation, and durability. Full article
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24 pages, 5866 KiB  
Article
Multiscale Characterization of Thermo-Hydro-Chemical Interactions Between Proppants and Fluids in Low-Temperature EGS Conditions
by Bruce Mutume, Ali Ettehadi, B. Dulani Dhanapala, Terry Palisch and Mileva Radonjic
Energies 2025, 18(15), 3974; https://doi.org/10.3390/en18153974 - 25 Jul 2025
Viewed by 229
Abstract
Enhanced Geothermal Systems (EGS) require thermochemically stable proppant materials capable of sustaining fracture conductivity under harsh subsurface conditions. This study systematically investigates the response of commercial proppants to coupled thermo-hydro-chemical (THC) effects, focusing on chemical stability and microstructural evolution. Four proppant types were [...] Read more.
Enhanced Geothermal Systems (EGS) require thermochemically stable proppant materials capable of sustaining fracture conductivity under harsh subsurface conditions. This study systematically investigates the response of commercial proppants to coupled thermo-hydro-chemical (THC) effects, focusing on chemical stability and microstructural evolution. Four proppant types were evaluated: an ultra-low-density ceramic (ULD), a resin-coated sand (RCS), and two quartz-based silica sands. Experiments were conducted under simulated EGS conditions at 130 °C with daily thermal cycling over a 25-day period, using diluted site-specific Utah FORGE geothermal fluids. Static batch reactions were followed by comprehensive multi-modal characterization, including scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), X-ray diffraction (XRD), and micro-computed tomography (micro-CT). Proppants were tested in both granular and powdered forms to evaluate surface area effects and potential long-term reactivity. Results indicate that ULD proppants experienced notable resin degradation and secondary mineral precipitation within internal pore networks, evidenced by a 30.4% reduction in intragranular porosity (from CT analysis) and diminished amorphous peaks in the XRD spectra. RCS proppants exhibited a significant loss of surface carbon content from 72.98% to 53.05%, consistent with resin breakdown observed via SEM imaging. While the quartz-based sand proppants remained morphologically intact at the macro-scale, SEM-EDS revealed localized surface alteration and mineral precipitation. The brown sand proppant, in particular, showed the most extensive surface precipitation, with a 15.2% increase in newly detected mineral phases. These findings advance understanding of proppant–fluid interactions under low-temperature EGS conditions and underscore the importance of selecting proppants based on thermo-chemical compatibility. The results also highlight the need for continued development of chemically resilient proppant formulations tailored for long-term geothermal applications. Full article
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15 pages, 5802 KiB  
Article
Study on the Influence Mechanism of Alkaline Earth Element Doping on the Thermoelectric Properties of ZnO
by Haitao Zhang, Bo Feng, Yonghong Chen, Peng Jin, Ruolin Ruan, Biyu Xu, Zhipeng Zheng, Guopeng Zhou, Yang Zhang, Kewei Wang, Yin Zhong and Yanhua Fan
Micromachines 2025, 16(8), 850; https://doi.org/10.3390/mi16080850 - 24 Jul 2025
Viewed by 246
Abstract
As a promising n-type semiconductor thermoelectric material, ZnO has great potential in the high-temperature working temperature range due to its advantages of abundant sources, low cost, high thermal stability, and good chemical stability, as well as being pollution-free. Sr-doped ZnO-based thermoelectric materials were [...] Read more.
As a promising n-type semiconductor thermoelectric material, ZnO has great potential in the high-temperature working temperature range due to its advantages of abundant sources, low cost, high thermal stability, and good chemical stability, as well as being pollution-free. Sr-doped ZnO-based thermoelectric materials were prepared using the methods of room-temperature powder synthesis and high-temperature block synthesis. The phase composition, crystal structure, and thermoelectric performances of ZnO samples with different Sr doping levels were analyzed using XRD, material simulation software and thermoelectric testing devices, and the optimal doping concentrations were obtained. The results show that Sr doping could cause the Zn-O bond to become shorter; in addition, the hybridization between Zn and O atoms would become stronger, and the Sr atom would modify the density of states near the Fermi level, which could significantly increase the carrier concentration, electrical conductivity, and corresponding power factor. Sr doping could cause lattice distortion, enhance the phonon scattering effect, and decrease the lattice thermal conductivity and thermal conductivity. Sr doping can achieve the effect of improving electrical transport performance and decreasing thermal transport performance. The ZT value increased to ~0.418 at 873 K, which is ~4.2 times the highest ZT of the undoped ZnO sample. The Vickers hardness was increased to ~351.1 HV, which is 45% higher than the pristine ZnO. Full article
(This article belongs to the Special Issue Functional Materials and Microdevices, 2nd Edition)
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24 pages, 3123 KiB  
Article
Investigation of the Effects of Water-to-Cement Ratios on Concrete with Varying Fine Expanded Perlite Aggregate Content
by Mortada Sabeh Whwah, Hajir A Al-Hussainy, Anmar Dulaimi, Luís Filipe Almeida Bernardo and Tiago Pinto Ribeiro
J. Compos. Sci. 2025, 9(8), 390; https://doi.org/10.3390/jcs9080390 - 24 Jul 2025
Viewed by 359
Abstract
This study investigates the influence of varying water-to-cement (W/C) ratios and fine aggregate compositions on the performance of concrete incorporating expanded perlite aggregate (EPA) as a lightweight alternative to natural sand. A total of eighteen concrete mixes were produced, each with different W/C [...] Read more.
This study investigates the influence of varying water-to-cement (W/C) ratios and fine aggregate compositions on the performance of concrete incorporating expanded perlite aggregate (EPA) as a lightweight alternative to natural sand. A total of eighteen concrete mixes were produced, each with different W/C ratios and fine-to-coarse aggregate (FA/CA) ratios, and evaluated for workability, compressive strength, flexural and tensile strength, water absorption, density, and thermal conductivity. Perlite was used to fully replace natural sand in half of the mixes, allowing a direct assessment of its effects across low-, medium-, and high-strength concrete formulations. The results demonstrate that EPA can improve workability and reduce both density and thermal conductivity, with variable impacts on mechanical performance depending on the W/C and FA/CA ratios. Notably, higher cement contents enhanced the internal curing effect of perlite, while lower-strength mixes experienced a reduction in compressive strength when perlite was used. These findings suggest that expanded perlite can be effectively applied in structural and non-structural concrete with optimized mix designs, supporting the development of lightweight, thermally efficient concretes. Mixture W16-100%EPS was considered the ideal mix because its compressive strength at the age of 65 days 44.2 MPa and the reduction in compressive strength compared to the reference mix 14% and the reduction in density 5.4% compared with the reference mix and the reduction in thermal conductivity 14% compared with the reference mix. Full article
(This article belongs to the Special Issue Sustainable Composite Construction Materials, Volume II)
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16 pages, 2624 KiB  
Article
An Experimental Study on Fire Propagation and Survival in Informal Settlements
by Cristóbal Ignacio Galleguillos Ketterer, José Luis Valin Rivera, Javier Díaz Millar and Maximiliano Santander López
Fire 2025, 8(8), 290; https://doi.org/10.3390/fire8080290 - 24 Jul 2025
Viewed by 375
Abstract
In recent years, the region of Valparaíso has faced devastating fires, notably the Viña del Mar fire on 2 February 2024, which affected 9252 hectares. This study analyzes fire behavior in informal settlements and assesses the effectiveness of different construction materials through scaled [...] Read more.
In recent years, the region of Valparaíso has faced devastating fires, notably the Viña del Mar fire on 2 February 2024, which affected 9252 hectares. This study analyzes fire behavior in informal settlements and assesses the effectiveness of different construction materials through scaled prototypes of dwellings made from MDF, OSB, TetraPak, and flame-retardant resin composites. Controlled fire experiments were conducted, recording fire spread times and atmospheric conditions. Results confirm significant differences in fire spread rates and structural survival times between materials, highlighting the practical benefit of fire-resistant alternatives. The Kaplan–Meier survival analysis indicates critical time thresholds for rapid flame escalation and structural collapse under semi-open conditions, supporting the need for improved safety measures. Burn pattern observations further revealed the role of wind, thermal radiation, and material properties in fire dynamics. Overall, this study provides experimental evidence aligned with real fire scenarios, offering quantified insights to enhance fire prevention and response strategies in vulnerable settlements. These findings provide an exploratory basis for understanding fire dynamics in informal settlements but do not constitute definitive design prescriptions. Full article
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23 pages, 6601 KiB  
Article
Effect of Hemp Shive Granulometry on the Thermal Conductivity of Hemp–Lime Composites
by Wojciech Piątkiewicz, Piotr Narloch, Zuzanna Wólczyńska and Joanna Mańczak
Materials 2025, 18(15), 3458; https://doi.org/10.3390/ma18153458 - 23 Jul 2025
Viewed by 490
Abstract
This study investigates the effect of hemp shive granulometry on the thermal conductivity and microstructure of hemp–lime composites. Three distinct particle size fractions—fine, medium, and coarse—were characterized using high-resolution image analysis to determine geometric parameters such as Feret diameters, circularity, and elongation. Composite [...] Read more.
This study investigates the effect of hemp shive granulometry on the thermal conductivity and microstructure of hemp–lime composites. Three distinct particle size fractions—fine, medium, and coarse—were characterized using high-resolution image analysis to determine geometric parameters such as Feret diameters, circularity, and elongation. Composite mixtures with varying binder-to-shive and water-to-shive ratios were prepared and compacted at a consistent level to isolate the influence of aggregate granulometry on thermal performance. Results demonstrate a clear inverse relationship between particle size and thermal conductivity, with coarse fractions reducing thermal conductivity by up to 7.6% compared to fine fractions. Composite density was also affected, decreasing with increasing particle size, confirming the impact of granulometry on pore structure and packing density. However, binder content exhibited the most significant effect on thermal conductivity, with a 20% increase observed for higher binder-to-shive ratios irrespective of shive size. The study further establishes that a 15 g sample size (~2400 particles) provides sufficient statistical accuracy for granulometric characterization using image analysis. These findings provide critical insights for optimizing hemp–lime composites for enhanced thermal insulation performance, supporting sustainable construction practices by informing material formulation and processing parameters. Full article
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