Search Results (1,695)

Traditional fermented vegetables are important resources for screening excellent antibacterial lactic acid bacteria (LAB). In this study, a strain of Lactiplantibacillus plantarum JC2211 with broad-spectrum antibacterial activity against Salmonella Typhimurium (S.T), Staphylococcus aureus (S.a), Listeria monocytogenes (L.m), and Pseudomonas aeruginosa (P.a) was isolated from Yangzhou pickles. The minimum inhibitory concentration (MIC) of its cell-free supernatant (CFS) against all four pathogens was 25 μL/mL. The strain exhibited favorable biosafety and strong environmental adaptability, tolerating 8% NaCl, pH 3.0–10.0, and 0.3% bile salt. The CFS exerted synergistic antibacterial effects via multiple pathways, including increasing cell membrane permeability, reducing membrane potential, decreasing intracellular ATP levels, and inducing ROS accumulation. Metabolite identification indicated that organic acids (dominated by D-lactic acid at 9.37%, citric acid at 8.00%, and phenyllactic acid at 4.42%) were the main components. Using chitosan (CS) as the base material, composite preservation films were fabricated by incorporating 10–50% CFS. The composite film containing 40% CFS (CS/CFS40) exhibited the optimal comprehensive performance, with ABTS and DPPH radical scavenging rates of 90.24% and 79.17%, respectively, along with satisfactory tensile strength (18.70 MPa) and elongation at break (22.93%). In chilled pork preservation, the CS/CFS40 film significantly inhibited the proliferation of spoilage microorganisms, and effectively retarded lipid oxidation. Moreover, the film suppressed the colonization of L.m and S.T on meat surfaces, with bacterial loads maintained at 2.07–2.67 lg CFU/g and 2.92–2.99 lg CFU/g, respectively, over 7 days of refrigeration. Collectively, the CS/CFS40 composite film extended the shelf life of chilled pork to approximately 6 days. This study provides a novel natural biological preservative and eco-friendly active packaging material for chilled meat preservation. Full article

This work reviews the strategic valorization of industrial by-products as sustainable sources of biopolymers and bioactive compounds, promoting a circular economy through the efficient use of renewable resources and reducing waste generation. These strategies contribute to lowering the carbon footprint of conventional packaging and plasticulture while supporting more resilient and diverse agriculture systems. Special emphasis is placed on processing roots and tubers as renewable raw materials for the production of biodegradable films for agronomic applications as eco-friendly alternatives to petroleum-based plastics and contributing to soil and ecosystem protection. Additionally, the incorporation of by-products from yerba mate (Ilex paraguariensis) demonstrate significant potential as both matrix-forming and filler materials in biodegradable composites while also providing antioxidant activity and pH-sensing capacity. This sustainable framework is further expanded through the utilization of non-traditional species like rosehip (Rosa rubiginosa), Aloe vera (Aloe barbadensis), and topinambur (Helianthus tuberosus), which provide versatile functional matrices and bioactive compounds. Finally, the development of active and intelligent food packaging is addressed. Extracting natural pH-sensitive pigments from red cabbage and topinambur flowers enables the formulation of eco-friendly inks for real-time freshness monitoring. Ultimately, integrating these waste streams drives technological disruption, scaling sustainable, tailored solutions for global industry needs. Full article

Thermosetting epoxy resins commonly used in wind turbine blades pose significant recycling challenges. This study addresses this limitation by using an eco-friendly, recyclable liquid polymethyl methacrylate (PMMA) resin to fabricate thermoplastic sandwich panels and by investigating their in-plane compressive buckling behavior. The experimental results demonstrated that the proposed PMMA thermoplastic sandwich panels exhibited improved in-plane compressive performance, with a 5.22% higher ultimate load than traditional epoxy counterparts. Furthermore, to investigate the effect of groove configuration on the buckling stability of composite sandwich panels, a finite element (FE) model for PMMA sandwich panels with initial geometric imperfections was established in this paper, and the reliability of the FE model was validated via compression and buckling tests. Finally, a Kriging surrogate model coupled with the NSGA-II algorithm was adopted to carry out multi-objective optimization, with groove parameters set as design variables. Based on the FE verification results, the optimized configuration (Point A) reduced the structural mass by 2.24%, while increasing the critical buckling load and shear modulus by 5.71% and 10.27%, respectively. Research on the buckling performance and groove configurations of PMMA sandwich panels, which can be applied to wind turbine blade webs and airfoils, can provide crucial data support for the engineering application of sustainable PMMA-based large-scale wind turbine blades. Full article

Although rice paddies are agricultural land, they also serve as artificial wetlands that deliver essential ecosystem services. Yet how farming systems affect their fish communities—and which metrics best capture those effects—remains poorly quantified in Asia. We compared fish assemblages between eco-friendly and conventional rice paddies in South Korea across the 2015 rice growing season (May–September), sampling 94 events by fyke net in Dangjin City (2704 individuals; 13 species) and analyzing the data with generalized linear mixed models and multivariate methods. Eco-friendly paddies supported 2.3-fold higher abundance and 2.6-fold higher biomass; differences were negligible in May (Cohen’s d ≈ 0) but large from June onward (d > 1.0), with a moderate-to-large pooled effect (d = 0.76–0.89). Community composition differed significantly (PERMANOVA), and eco-friendly assemblages were more consistent among fields (PERMDISP). Carassius auratus and Misgurnus anguillicaudatus were 10.8- and 2.7-fold more abundant under eco-friendly management, whereas α-diversity indices (richness, Shannon, Simpson, evenness) showed no differences, as three taxa comprised over 90% of the catch. In these species-poor, dominance-skewed systems, abundance-based and species-specific metrics detected management effects more sensitively than α-diversity indices, complementing rather than replacing them. Because these results derive from a single growing season in one region, however, they should be regarded as specific to comparable systems and require multi-year, multi-region validation before their use in biomonitoring and eco-friendly agricultural policy can be generalized. Full article

Organic pollutants in industrial wastewater present a severe threat to both the environment and human health. Photocatalytic technology, recognized for its eco-friendliness and high efficiency, has become a leading approach for degrading such pollutants. In this work, BiOCl nanosheets were first synthesized using a hydrothermal method. Subsequently, an anion exchange reaction with TAA in an oil bath generated a Bi₂S₃ intermediate layer on the BiOCl surface, followed by the in situ growth of ZIS nanostructures, successfully constructing a BiOCl@Bi₂S₃@ZIS double Z-scheme heterojunction. By adjusting the amount of BiOCl, the interface contact and dispersion of the heterojunction were optimized. Characterization results demonstrate that the BiOCl@ZIS-25 heterojunction possesses the highest specific surface area (103.5 m²·g⁻¹) and the most efficient charge separation. Under visible light irradiation, it achieved 97.88% degradation of methylene blue within 20 min, with a reaction rate constant 8 and 4 times higher than those of pure BiOCl and ZIS, respectively. Mechanistic investigations indicate that Bi₂S₃ interlayer acts as an electron-transfer bridge between BiOCl and ZIS, establishing a double Z-scheme charge transfer pathway that significantly enhanced the separation and utilization efficiency of photogenerated charge carriers. This study offers valuable insights for designing highly efficient and stable photocatalytic composite materials. Full article

In the present work, polyvinylpyrrolidone (PVP) was selected as the primary raw material and fully dissolved in N,N-dimethylformamide (DMF) solvent. Hydroxymethyl cellulose (HMC), acrylic acid (AA) monomer with outstanding chelating performance, and UR were added in sequence. On this basis, composite nanofiber membrane substrates of PVP/AA/HMC/UR were fabricated by means of electrospinning. Afterwards, silane coupling agent KH-560 was blended with polylactic acid (PLA). A uniform PLA/KH-560 functional coating was covered on the surface of the as-prepared nanofiber membrane via microfluidic coating treatment, and the target composite nanofiber adsorbent was ultimately obtained. Relevant performance characterization results indicated that moderate addition of HMC could greatly optimize the tensile strength of the membrane material, whereas excessive HMC dosage would cause a deterioration in mechanical strength. Moreover, the breaking elongation presented a slight declining trend, and the integrated mechanical stability of the membrane could fully meet the service demands for cyclic reuse. As a functional monomer, acrylic acid effectively boosted the material’s adsorption performance toward typical heavy metal ions, including Zn²⁺, Cu²⁺ and Pb²⁺. In simulated acidic wastewater generated from rare earth mining and extraction (pH = 3 and pH = 6.5), the removal efficiency of the as-prepared material for the three heavy metal ions all exceeded 95%. Even after being soaked in strong acid solution at pH 2 for 8 h, its adsorption rate was still maintained at 88.5%. In the cyclic experiment, the adsorption efficiency stayed above 75% after two recycling runs, decreased to roughly 55% in the third cycle, and dropped below 30% at the fourth reuse stage. The introduction of UR imparted remarkable acid-resistant structural stability to the composite material. The membrane structure remained complete without damage after long-term immersion in a pH 2 strong acid environment, and high-efficiency heavy metal removal capability could be guaranteed when the solution pH was not lower than 3. Targeting the practical treatment dilemma of acidic heavy metal-containing wastewater from rare earth exploitation and extraction, this research successfully developed a novel eco-friendly adsorbent featuring superior acid resistance, high adsorption performance and certain recyclability. This newly designed material makes up for the deficiencies in traditional adsorbents represented by activated carbon, including poor heavy metal removal ability in acidic media and secondary pollution risks resulting from disposable use. The research findings can offer a novel technical reference and feasible approach for the purification of acidic rare earth wastewater in practical engineering applications. Full article

Unmanned aerial vehicles (UAVs) are experiencing rapid growth across diverse sectors, creating an increasing demand for lightweight, high-performance and environmentally sustainable materials. Conventional drone materials offer excellent mechanical properties but pose environmental concerns due to their high carbon footprint, energy-intensive production and limited biodegradability. Kenaf fibre, a renewable natural fibre, presents a promising alternative owing to its low density, high specific strength, cost-effectiveness and eco-friendly characteristics. This review and research proposal explores the current and potential applications of kenaf-based materials in drone manufacturing, including kenaf fibre-reinforced biocomposites, pressed paper, composite pellets and 3D printing filaments for structural, functional and electrical housing components. Kenaf-based materials have demonstrated mechanical strengths approaching 300 MPa, dielectric constants of approximately 2.5 and electrical breakdown strengths exceeding 150 kV/mm, highlighting their potential for lightweight UAV structures and electronic insulation applications. The proposed research focuses on optimising kenaf fibre treatment, fibre–matrix compatibility, hybrid reinforcement strategies and additive manufacturing parameters to develop lightweight, durable and multifunctional kenaf-based UAV components. The framework aims to establish a systematic pathway for the development and validation of kenaf-based materials for next-generation sustainable UAVs. Full article

The sustainable reuse of industrial by-products in fermentation processes supports the transition toward a circular bioeconomy. This study evaluated the production yield of fungal chitosan (FuCho) by nine Mucorales strains, including novel species isolated from Brazilian biomes, cultivated in alternative culture media composed of corn steep liquor (CSL) and biodiesel-derived glycerol (GLY). Furthermore, the physicochemical properties, potential of irritation, and broad-spectrum antimicrobial activity of the extracted FuCho were investigated. Among the strains tested in CSL-GLY medium, FuCho yields ranged from $17.88\mathrm{mg}/\mathrm{g}$ (Absidia aguabelensis) to $126.56\mathrm{mg}/\mathrm{g}$ (Absidia caatinguensis). Optimization using a $2^2$ central composite rotatable design (CCRD) yielded maximum FuCho productions of $128.26\mathrm{mg}/\mathrm{g}$ for A. caatinguensis (center point condition) and $164.92\mathrm{mg}/\mathrm{g}$ for Cunninghamella elegans (lower CSL concentration). Physicochemical characterization revealed degrees of deacetylation of 85% (A. caatinguensis) and 75% (C. elegans), crystallinity indices of 36.74% and 37.93%, and viscometric molecular weights ($M_v$) of $1.6\times {10}^3\mathrm{g}/\mathrm{mol}$ and $2.0\times {10}^3\mathrm{g}/\mathrm{mol}$, respectively. In the HET-CAM assay, both FuCho samples were classified as non-irritating, exhibiting no inflammatory, vascular, or vasoconstrictive effects. FuCho demonstrated minimum inhibitory concentrations (MIC) against all tested pathogenic bacterial strains and Candida species, with A. caatinguensis FuCho displaying lower MIC values for the majority of microorganisms compared to C. elegans FuCho. Confocal laser scanning microscopy confirmed a significant reduction in microbial cell viability, driven by membrane disruption in Escherichia coli and Staphylococcus aureus. These findings validate the CSL-GLY mixture as a cost-effective, eco-friendly culture medium for producing high-value biopolymers with pharmaceutical potential, underscoring the biotechnological relevance of Brazilian Mucorales strains. Full article

In this study, a two-step electrodeposition strategy was proposed to fabricate an eco-friendly superhydrophobic polyaniline (PANI)/silane composite coating on mild steel for corrosion protection. The first step consists of creating a pure PANI adherent coating using a cyclic voltammetry technique and the second step consists of realizing superhydrophobic features using electrodeposition in mixed silane monomers at constant potential. The structure and composition characterization results revealed successful modification of the underlying pure PANI layer with superhydrophobic surface silane film. Wettability tests indicated a high contact angle of 155° and a low sliding angle of 4.2°. Electrochemical measurements revealed that the corrosion current density of PANI/silane-coated mild steel decreased by approximately three orders of magnitude compared to the uncoated sample and the corrosion protection efficiency was as high as 99.6%. Moreover, the prepared PANI/silane hybrid coating exhibited good chemical stability and strong adhesion after 10 days of corrosion in 3.5 wt.% NaCl solution. Full article

The corrosion-protection performance of zinc oxide-hybrid polymeric coatings is traditionally attributed to the individual contributions of their constituent phases. This study reveals that the calcination temperature of zinc oxide (ZnO) filler is a critical, previously overlooked processing parameter that dictates not only filler crystallinity but also the collective synergistic failure mechanism of the entire coating system. Herein, we demonstrate that incorporating ZnO calcined at 500 °C yields a ternary chitosan–graphene oxide–zinc oxide/epoxy (CS–GO–ZnO/EP) composite coating with a highly compact, dense morphology, minimal internal porosity, and exceptional filler dispersion, as validated by FTIR, XRD, and SEM analyses. The optimized CS–GO–ZnO/EP coating applied to carbon steel exhibits outstanding dry and wet pull-off adhesion strengths, the highest surface hydrophobicity (102.2°), and superior electrochemical barrier protection. Notably, after a 120-h immersion period in an aggressive 3.5 wt.% NaCl electrolyte, the CS–GO–ZnO/EP (500 °C) maintains excellent coating resistance (R_coat = 1.06 × 10⁵ Ω) and a minimized corrosion rate (CR = 0.074 mm/y). This thermal threshold is a key processing window that improves chemical bonding and compatibility between the different parts of the hybrid matrix without causing the severe nanoparticle sintering, phase aggregation, and micro-cracking that happen at 650 °C. This work offers a significant advancement in the design of eco-friendly, high-performance hybrid coatings, demonstrating that precise control of the inorganic phase’s thermal history provides a direct pathway toward superior durability, hydrophobicity, and electrochemical stability for carbon steel protection in aggressive marine environments. Full article

The development of sustainable, high-performance friction composites is critical for the automotive industry, given the environmental and health concerns associated with conventional brake pad materials such as asbestos and copper. This study investigates the effect of incorporating micro- and nano-sized Al₂O₃, SiC, and carbon nanotubes (CNTs) into a novel, eco-friendly, asbestos-free, and copper-free brake pad formulation. Six composite samples were fabricated via a cold-pressing and hot-molding process: five formulations containing a single, size-controlled micro-/nano-sized reinforcement (Al₂O₃, SiC, and CNTs), and one reference formulation (CBP# Reference) containing an unrefined, commercial-grade combination of Al₂O₃ and SiC in place of the size-controlled additive. All formulations were rigorously characterized for their physical, mechanical, and tribological properties. The nano-Al₂O₃ formulation exhibited the highest density (2.197 g/cm³) and compressive strength (249.7 MPa), while the micro-SiC formulation achieved superior wear resistance, recording the lowest weight loss (0.0053 g) and the highest hardness (90 HV). The nano-SiC formulation offered the most balanced overall performance, combining high hardness (86.2 HV) with the highest average friction force (33.65 N) and the most stable friction-time response among all samples. The CNT-reinforced formulation produced the highest maximum friction force (42.07 N) but showed only moderate improvement in density, hardness, and compressive strength relative to the ceramic-reinforced samples. Compared with the CBP# reference, all five developed formulations exhibited higher hardness and coefficient of friction alongside lower weight loss, confirming their potential as durable, sustainable alternatives for automotive brake friction applications. Full article

The accumulation of discarded denim waste in landfills is causing environmental pollution, creating an urgent need for sustainable solutions. This study demonstrates the recycling of denim by extracting the indigo dye and fabricating the treated fabric into a composite to develop eco-friendly and high-performance materials. The waste denim was treated with sodium borohydride under controlled conditions without damaging the fibers. To utilize the denim waste, the decolorized fabric was shredded into fibers and incorporated into two polymer matrices i.e., ethylene vinyl acetate (EVA) and vinyl acetate, (VA) to fabricate a fiber-reinforced composite. The prepared recycled denim composites were compared with composites based on raw cotton fibers. The surface morphology of the composites was studied through optical microscopy and SEM analysis to examine the structural properties. Mechanical tests including tensile, charpy impact, flexural bending and drop-weight tests were performed to evaluate performance. The results showed that the raw composite had a higher impact strength of 11.5 kJ/m², while the recycled composite had 9.89 kJ/m², showing a slight reduction but maintaining good mechanical strength and lightweight properties suitable for applications such as table tennis rackets, a sustainable sports product, thereby supporting a closed-loop denim recycling approach within a circular economy framework. Full article

Microbially induced calcium carbonate precipitation (MICP) is a promising biotechnology for environmental remediation; however, the high cost of conventional chemical-grade calcium sources limits its large-scale scalability. This study evaluated the feasibility of utilizing an aqueous extract of natural attapulgite clay as a sustainable, low-cost calcium source for MICP-mediated arsenic (As) immobilization in both aqueous and soil systems. Among the tested minerals, Baiyin attapulgite (group B) exhibited the highest calcium content (62,808.94 mg kg⁻¹) and minimal toxic metal impurities, providing a favorable chemical matrix for biomineralization. At an optimal solid-to-liquid ratio of 1:10, Lysinibacillus fusiformis LF and Enterococcus LZU-1 successfully induced calcite precipitation driven by the attapulgite extract. In batch aqueous remediation experiments (20 days), the attapulgite extract significantly enhanced As removal efficiency compared to the controls; As removal rates peaked at 66.4% for strain LZU-1 (with LZ1 extract) and 65.8% for strain LF (with group B extract), drastically outperforming the standard CaCl₂ groups (31.2–37.3%) and blank controls (21.8–24.5%). Concurrently, soil incubation experiments (30 days) demonstrated that the combined application of attapulgite and MICP bacteria reduced the highly bioavailable exchangeable As fraction from 0.115 to approximately 0.03 mg kg⁻¹, while effectively driving its transformation into more stable carbonate-bound and organic-bound fractions without causing secondary soil salinization. Morphological and mechanistic analyses revealed that, compared to the well-defined euhedral crystals in the CaCl₂ control, the precipitates mediated by the clay extract exhibited distinctly irregular, defect-rich rhombohedral structures. This structural disruption was governed by the natural matrix effect of attapulgite, which simultaneously supplied dissolved Ca²⁺ and provided an abundance of fine clay fragments, calcite micro-grains, and associated amorphous Fe/Al/Mn-bearing phases. These constituents acted as physical scaffolding and heterogeneous nucleation sites that became embedded in the growing CaCO₃ lattice, driving the formation of highly reactive, defect-rich clay-calcite-arsenic composite precipitates that efficiently encapsulated arsenate. Mantel analysis further revealed that the remediation efficiency was significantly correlated with key environmental variables including Ni, V, Ca. These findings highlight the dual-system potential of natural attapulgite as an inexpensive, eco-friendly calcium alternative for sustainable MICP-based remediation of As-contaminated water and agricultural soils. Full article

The surface modification of polyolefin separators for lithium-ion batteries using polymer particles has been extensively investigated to enhance their electrolyte wettability, thermal resistance, and mechanical properties. However, the traditional polymer synthesis and/or polymer-based separator modifications have mostly been carried out using harmful and expensive organic solvents. In this study, a powder-type polyimide (PI) was synthesized using water as a solvent, and then PI-particle-containing coating slurries were prepared in an aqueous dispersion medium. The coating slurries were applied on a polyethylene (PE) separator to obtain PI-particle-coated PE (PI-PE) separators. Thermal and mechanical properties were evaluated for the PI-PE separators. Electrolyte uptake, porosity, air permeability, and ionic conductivity of the separators were also evaluated. The electrochemical properties of coin cells assembled with the PI-PE separator were evaluated by charge–discharge property. Coating of PI particles improves the thermal stability and electrolyte wettability of the PE separator, and LiCoO₂/PI-PE separator/Li half-cells showed battery performance similar to that of bare PE half-cells. This work offers insights into the simple, eco-friendly preparation of a separator with excellent thermal stability, electrolyte wettability and effective ionic conductivity. Full article

Methods for extracting bioactive compounds are widely studied, as the global trend moves toward more efficient and eco-friendly methods. This study aimed to optimize and compare the extraction of phenolic compounds from the residual biomass of andiroba (Carapa guianensis) using the conventional method with methanol as the solvent, and a green chemistry method via ultrasound using ethanol as the solvent. The optimization of the extraction variables (time, mass/volume ratio, and ethanol concentration) was performed using a Central Composite Rotatable Design (CCRD 2³) combined with the desirability function. The established optimal conditions were an extraction time of 26.78 min, a mass/volume ratio of 86.46 mg/mL, and an ethanol concentration of 32.5%. The conventional method achieved a higher yield of total phenolic compounds (TPC) (109.05 mg GAE/mL) and total flavonoid compounds (TFC) (38.18 mg GAE/mL) compared to the ultrasound-assisted method (UAE) (82.64 and 26.27 mg GAE/mL, respectively). LC-MS analysis revealed a diversity of extracted bioactive molecules. Both methodologies yielded extracts with good in vitro antioxidant activity (DPPH and ABTS). In the antimicrobial assay, the extracts demonstrated an unprecedented bacteriostatic effect for this residue, inhibiting the growth of the Gram-positive bacterium Staphylococcus aureus at concentrations ranging from 43.83% to 52.67%, with no activity against Gram-negative bacteria. The optimization demonstrated that the industrial residue of andiroba still contains a significant concentration of bioactive compounds. These findings confirm the bioeconomic potential of this by-product for the formulation of high-value-added bio-inputs, with promising applications in the development of smart packaging or bioactive food coatings. Full article