Search Results (154)

The global shift towards cleaner energy sources is driving the adoption of hydrogen as an environmentally friendly alternative to fossil fuels. Among the forms currently available, Liquid Hydrogen (LH₂) offers high energy density and efficient storage, making it suitable for large-scale transport by rail. However, the flammability of hydrogen poses serious safety concerns, especially when transported through confined spaces such as railway tunnels. In case of an accidental LH₂ release from a freight train, the rapid accumulation and potential ignition of hydrogen could cause catastrophic consequences, especially if freight and passenger trains are present simultaneously in the same tunnel tube. In this study, a three-dimensional computational fluid dynamics model was developed to simulate the dispersion and explosion of LH₂ following an accidental leak from a freight train’s cryo-container in a single-tube double-track railway tunnel, when a passenger train queues behind it on the same track. The overpressure results were analyzed using probit functions to estimate the fatality probabilities for the passenger train’s occupants. The analysis suggests that a significant number of fatalities could be expected among the passengers. However, shorter users’ evacuation times from the passenger train’s wagons and/or longer distances between the two types of trains might reduce the number of potential fatalities. The findings, by providing additional insight into the risks associated with LH₂ transport in railway tunnels, indicate the need for risk mitigation measures and/or traffic management strategies. Full article

West Africa is increasingly becoming more vulnerable to extreme heat due to climate change intensification with forecasts predicting hazardous heat days to double by 2060 affecting all societal classes and life sectors. This study examines the relationship between urbanisation, energy-efficient building design, and government guidelines within the Nigerian context. The review of the current national building codes and energy efficiency regulations revealed an alarming gap regarding the abandonment of basic sustainable design practices when addressing the needs of low-income housing. Validated simulations were used to assess the thermal performance of six distinct residential prototypes for low- and middle-income mass housing, which were previously developed by the government and are still used today as development blueprints. The effectiveness of incorporating passive design solutions into the selected prototypes was examined, providing insights into their thermal performance and practical recommendations for improving occupants’ comfort. The findings highlight the value of utilising a combination of passive design methods to achieve occupant thermal comfort, suggesting a reduction of up to 20% in the frequency of thermal discomfort during the hottest period of the year. The study advocates for more comprehensive guidelines to facilitate sustainable housing design that prioritises low-cost passive approaches to enhance indoor comfort and reduce reliance on conventional energy sources, ultimately fostering resilience in the face of climate change. Full article

Co-electrolysis of CO₂ and H₂O offers a promising route for efficient and controllable syngas production from greenhouse gases and water. However, the atomic-scale reaction mechanism remains elusive, especially on complex oxide surfaces. In this study, we employ density functional theory (DFT) to investigate the adsorption and activation of CO₂ and H₂O on the FeMoO-terminated (001) surface of Sr₂Fe_1.5Mo_0.5O₆ (SFM), a double perovskite of growing interest for solid oxide electrolysis. Our results show that CO₂ strongly interacts with surface lattice oxygen, adopting a bent configuration with substantial charge transfer. In contrast, H₂O binds more weakly at Mo sites through predominantly electrostatic interactions. Co-adsorption analyses reveal a bidirectional interplay: pre-adsorbed H₂O enhances CO₂ binding by altering its adsorption geometry, whereas pre-adsorbed CO₂ weakens H₂O adsorption due to competitive site occupation. This balance suggests that moderate co-adsorption may facilitate proton–electron coupling, while excessive coverage of either species suppresses activation of the other. Bader charge analysis, charge density differences, and projected density of states highlight the key role of Fe/Mo–O hybridized states near the Fermi level in mediating surface reactivity. These results, obtained for a perfect defect-free surface, provide a theoretical benchmark for disentangling intrinsic molecule–surface and molecule–molecule interactions, and offer guidance for designing high-performance perovskite electrocatalysts for CO₂ + H₂O co-electrolysis. Full article

Artificial intelligence (AI) is now the computational core of smart building automation, acting across the entire cyber–physical stack. This review surveys peer-reviewed work on the integration of AI with indoor environmental quality (IEQ) and energy performance, distinguishing itself by presenting a holistic synthesis of the complete technological evolution from IoT sensors to generative AI. We uniquely frame this progression within a human-centric architecture that integrates digital twins of both the building (DT-B) and its occupants (DT-H), providing a forward-looking perspective on occupant comfort and energy management. We find that deep reinforcement learning (DRL) agents, often developed within physics-calibrated digital twins, reduce annual HVAC demand by 10–35% while maintaining an operative temperature within ±0.5 °C and CO₂ below 800 ppm. These comfort and IAQ targets are consistent with ASHRAE Standard 55 (thermal environmental conditions) and ASHRAE Standard 62.1 (ventilation for acceptable indoor air quality); keeping the operative temperature within ±0.5 °C of the setpoint and indoor CO₂ near or below ~800 ppm reflects commonly adopted control tolerances and per-person outdoor air supply objectives. Regarding energy impacts, simulation studies commonly report higher double-digit reductions, whereas real building deployments typically achieve single- to low-double-digit savings; we therefore report simulation and field results separately. Supervised learners, including gradient boosting and various neural networks, achieve 87–97% accuracy for short-term load, comfort, and fault forecasting. Furthermore, unsupervised models successfully mine large-scale telemetry for anomalies and occupancy patterns, enabling adaptive ventilation that can cut sick building complaints by 40%. Despite these gains, deployment is hindered by fragmented datasets, interoperability issues between legacy BAS and modern IoT devices, and the computer energy and privacy–security costs of large models. The key research priorities include (1) open, high-fidelity IEQ benchmarks; (2) energy-aware, on-device learning architectures; (3) privacy-preserving federated frameworks; (4) hybrid, physics-informed models to win operator trust. Addressing these challenges is pivotal for scaling AI from isolated pilots to trustworthy, human-centric building ecosystems. Full article

This paper presents a novel integration of bioclimatic-passive architectural elements—Trombe walls, pergolas, and deciduous climbers—in the context of residential buildings in Eastern and Central Europe, a combination that remains largely underexplored in the current literature. The innovativeness of the proposed concept is reflected in the combined use of the following building elements: three types of passive Trombe wall (single-glazed, double-glazed, and triple-glazed), pergolas, and four types of deciduous climbers (V. coignetiae, H. lupulus, W. sinensis, and A. macrophylla). By using meteorological data for the towns Kragujevac and Kielce, the influence of location parameters for two dominant European climate zones (moderate continental and continental) is also included in this investigation. The initial single-family building models were created following the Serbian and Polish rulebooks on energy efficiency for new buildings and equipped with the same thermo-technical systems and people occupancy conditions. Based on the conducted simulations (using Google SketchUp 8 and EnergyPlus 7.1) and obtained results on the annual level, the following main conclusions can be drawn: (1) a moderate continental climate is more suitable for implementing the proposed concept; (2) a single-glazed passive Trombe wall is not energy or environmentally justified; (3) the energy, environmental, and economic benefits for both selected locations are greatest in the case of the combined use of pergolas, V. coignetiae, and triple-glazed passive Trombe wall; and (4) before the wider commercial application of the proposed concept in the future, efforts should be made to explore economic opportunities, which, among other things, involve a focus on market stability and accessibility. Full article

Laser cladding rapid solidification technique is an effective strategy for manufacturing ultra-high-strength martensitic stainless steels (UHS-MSS). Due to super-saturation solution strengthening of interstitial atoms (IAs), martensitic stainless steels containing IAs exhibit excellent ultra-high strength and toughness and have high tolerance for oxygen impurities. Hence, studying the specific speciation and structural characteristics of IAs is of great significance for guiding laser cladding of ultra-high-strength steels. Herein, we use density functional theory (DFT) computations to analyze the stable occupancies of IAs and their interactions in body-centered cubic iron (BCC Fe). The findings show that single IAs prefer to occupy octahedral sites over tetrahedral sites. Therefore, octahedral sites are selected as the optimal sites for the following double IAs study. For homo IAs, C-C and N-N configurations exhibit greater stability at long-range distances, whereas O-O demonstrate optimal stability at intermediate distances. Crucially, hetero IAs configurations are more stable compared to single IAs and homo IAs, exhibiting a synergistic effect. Especially, the C-O combination shows the highest stability and strongest bonding character. Meanwhile, the dissociation behavior of O indicates that C-O and N-O have higher dissociation temperatures than single O, further verifying the synergistic effect of hetero IAs. This provides a theoretical basis for understanding the interstitial solution strengthening of laser cladding UHS-MSS. Full article

The construction sector presently consumes about 40% of global energy and generates 36% of CO₂ emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article

The study at the Peggy Guggenheim Collection in Venice highlights critical interactions between indoor air quality, visitor dynamics, and microclimatic conditions, offering insights into preventive conservation of modern artworks. By analyzing pollutants such as ammonia, formaldehyde, and organic acids, alongside visitor density and environmental data, the research identified key patterns and risks. Through three seasonal monitoring campaigns, the concentrations of SO₂ (sulphur dioxide), NO (nitric oxide), NO₂ (nitrogen dioxide), NO_x (nitrogen oxides), HONO (nitrous acid), HNO₃ (nitric acid), O₃ (ozone), NH₃ (ammonia), CH₃COOH (acetic acid), HCOOH (formic acid), and HCHO (formaldehyde) were determined using passive samplers, as well as temperature and relative humidity data loggers. In addition, two specific short-term monitoring campaigns focused on NH₃ were performed to evaluate the influence of visitor presence on indoor concentrations of the above compounds and environmental parameters. NH₃ and HCHO concentrations spiked during high visitor occupancy, with NH₃ levels doubling in crowded periods. Short-term NH₃ campaigns confirmed a direct correlation between visitor numbers and the above indoor concentrations, likely due to human emissions (e.g., sweat, breath) and off-gassing from materials. The indoor/outdoor ratios indicated that several pollutants originated from indoor sources, with ammonia and acetic acid showing the highest indoor concentrations. By measuring the number of visitors and microclimate parameters (temperature and humidity) every 3 s, we were able to precisely estimate the causality and the temporal shift between these quantities, both at small time scale (a few minute delay between peaks) and at medium time scale (daily average conditions due to the continuous inflow and outflow of visitors). Full article

The use of LUZs in urban environments is a critical factor for ensuring efficient vehicle mobility in cities. Poor utilisation of these zones can generate negative externalities, such as double parking or illegal occupation of pedestrian crossings or garage doors. The purpose of the study is to provide city governance with a methodology based on the OEE model to evaluate the efficiency of individual zones or sets of zones and to inform decisions that improve their use without disrupting the coexistence with other city users. To validate the methodology, all deliveries made in selected areas of the city of Zaragoza over the course of one month were studied. The results of the study reveal a considerable loss of efficiency and some recommendations are proposed achieve a better use: only 51.44% of deliveries used the LUZs correctly, and the total OEE ratio was just 0.37. This low level of efficiency is due to the incorrect use by delivery drivers, who often use LUZs as parking spaces, and the illegal occupation of the zones by unauthorised private vehicles. Full article

Co-doping at Ba and Ti sites with double rare-earth elements has proven an effective strategy for enhancing the dielectric properties of BaTiO₃ ceramics. Among intermediate-sized rare-earth ions, Tb and Ho exhibit amphoteric behavior, occupying both Ba and Ti sites. Investigating the site occupation, defect chemistry, and dielectric effects of Tb and Ho in BaTiO₃ is therefore valuable. In this work, Tb/Ho-co-doped BaTiO₃ ceramics with the composition (Ba_1−xTb_x)(Ti_1−xHo_x)O₃ (x = 0.01~0.10) were fabricated at 1400 °C via solid-state reaction, and their solid solubility and crystal structures are confirmed. Microstructure, dielectric properties, photoluminescence, and valence states of samples with a single phase were systematically studied. Both the lattice parameter a and unit cell volume increase with doping level. The ceramic with x = 0.02 meets the X5S dielectric specification. Ho and Tb ions both demonstrate amphoteric site occupancy: Ho exists solely as Ho³⁺ at both Ba and Ti sites, while Tb exhibits mixed valence states as Ba-site Tb³⁺ and Ti-site Tb⁴⁺. As the doping content increases, the concentration of Tb⁴⁺ at Ti sites decreases, and the quantity of Ba-site Ho³⁺ ions initially increases to a maximum before decreasing. Defect compensation mechanisms within the samples are also discussed. Full article

Thermal comfort in public buildings is crucial for occupant well-being and energy efficiency. This study employs TRNSYS software to simulate the effects of thermal mass, window performance, and window–wall ratio (WWR) on summer thermal comfort. The results indicate that without energy-saving measures, increased thermal mass raises daily average maximum and minimum temperatures by 0.33–0.96 °C and 0.14–0.94 °C, respectively. Enhanced WWRs lead to higher daily average maximum and minimum temperatures for double-glazed windows (0.18–0.61 °C and 0.07–0.62 °C, respectively), while single-glazed windows show increased maximum temperatures (0.18–1.86 °C) but decreased minimum temperatures (−0.01 to −0.72 °C). Thermal mass has a modest effect on indoor overheating during high outdoor temperatures. Double-glazed windows and lower WWRs effectively reduce indoor overheating, decreasing the attenuation coefficient by 2.13–28.94%. Conversely, single-glazed windows and higher WWRs enhance heat dissipation, increasing daily average temperature fluctuations by 2.33–44.18%. Notably, single-glazed windows with WWRs ≥ 50% improve thermal comfort by reducing extreme superheat temperature occurrence in heavy-thermal-mass buildings by 0.81 to 14.63%. Despite lower cooling loads with heavy thermal mass, double-glazed windows, and low WWRs, the study suggests that single-glazed windows and high WWRs can enhance summer thermal comfort. Therefore, reasonable shading measures and lighter thermal mass are recommended for such buildings. Full article

The energy transition from fossil fuels to renewable sources is a key goal for the European Union, among others. Despite significant progress, Italy lags far behind the EU’s target of generating 55% of its electricity from renewables by 2030. The Apulia region in Italy needs to achieve an additional 7.4 GW of installed renewable energy capacity compared to 2021. Renewable energy installations, particularly photovoltaic systems, require land that may compete with other uses like agriculture. This can lead to land-use changes that disrupt agricultural activities. Agrivoltaics (AV) offer a possible solution by allowing energy production and food growing on the same land, which can help alleviate conflicts between energy and food needs, although concerns about landscape impact remain. This study emphasizes the need for effective spatial planning to manage these risks of land use changes and quantify possible agricultural land occupation. A GIS-based analysis was conducted in Apulia using a three-step approach to assess land use and potential AV opportunities: (a) the land protection system identified by the Apulian Landscape Plan was used to obtain a Constraint Map; (b) the agricultural land use and capability classification together with land slope and exposure was used to obtain the AV Availability Map; and (c) agricultural land conversion scenarios were developed to quantify the potential capacity of future AV installations. The results showed that a 0.25% occupation of utilized agricultural land would allow a regional installed AV capacity of 1.3 GW, while doubling this percentage would double the installed capacity to 2.6 GW. The areas potentially involved by AV installations would be 3.25 and 6.50 thousand hectares, reaching 17.5% and 35.0% of the 2030 total renewable energy target. These figures should be considered a reasonable range of AV development in the region, which can contribute both to the energy transition and the support of the agricultural sector, especially in marginal areas. Full article

The urgency of managing the COVID-19 health crisis in workplaces led to tensions, work overload, and confusion about preventive measures. This study presents a secondary analysis of qualitative data on paradoxes and double binds (PDBs) experienced by precarious essential workers in Canada who interacted with the public and their supervisors. Based on 13 interviews from a larger qualitative dataset, we examine how workers navigated public health recommendations and organisational demands during the pandemic. Findings reveal multiple organisational and managerial PDBs—both COVID-19-related and pre-existing—that contributed to psychological distress and compromised well-being. We argue that PDBs represent a significant occupational health hazard for precarious workers. Addressing these structural contradictions through proactive management strategies could help mitigate workplace tensions, reduce stress, and enhance resilience in both crisis situations and regular organisational contexts. Our study contributes to occupational health and safety (OHS) by underscoring the risks posed by PDBs and advocating for strategies to support vulnerable workers in navigating conflicting demands. Full article

The use of former foodstuff and by-products in cow diets could improve the environmental sustainability of livestock. However, knowledge about the effects of these feeds in ruminant diets on the quality of dairy products is lacking. This study investigated the effects of integrating wheat distillers’ grain with solubles (WDGS) and a former foodstuff product (FFP) into the diet of dairy cows on milk and cheese quality. The environmental impact of the two feeding systems has been evaluated by LCA. A double crossover design was set up with 84 Holstein cows, alternating a control diet and a circular one. In the circular diet, traditional feeds were partially replaced with 4 kg/d WDGS and 3 kg/d FFP. The results showed no effects on dry matter intake and milk yield, while fiber digestibility improved. A reduction in the milk fat content and a modification of the fatty acid profile of milk and cheese were observed. Conversely, cheese yield, composition, and sensory attributes were not affected. The environmental impact of the diet was significantly reduced in terms of land occupation, net fresh water, and global warming potential. These findings suggest that these feeds can be safely included in dairy cow diets. This approach could significantly contribute to reducing greenhouse gas emissions, enhancing the sustainability of the dairy system. Full article

Karst aquifers can be highly productive water sources but are vulnerable to contamination by pathogens because of integrated surface and subsurface drainage. Our study focuses on the karstic Royal Spring basin in Kentucky, encompassing urban and agricultural land uses. The city of Georgetown distributes treated water from Royal Spring to over 33,000 customers. We examined E. coli dynamics at Royal Spring from June 2021 through June 2022, assessing variability under wet versus dry weather conditions. We also used quantitative microbial risk assessment (QMRA) to estimate potential health risks from the pathogenic bacterium E. coli O157:H7. E. coli concentrations in weekly water samples varied from 12 to 1732.8 MPN/100 mL, with a geometric mean of 117.2 MPN/100 mL. The mean concentration in wet periods was approximately double that during dry conditions. Because the pathogen was not detected by quantitative PCR (qPCR), we conducted QMRA based on literature data for water treatment plant operations (occupational) and recreational activities near the spring. The median probability of annual infection was 5.11 × 10⁻³ for occupational exposure and 1.45 × 10⁻² for recreational exposure. Uncertainty and sensitivity analyses revealed that health risks were most sensitive to the pathogen/E. coli ratio and ingestion rate. Although the pathogen was not detected by qPCR, the presence of E. coli suggests potential fecal contamination. This highlights the importance of continued monitoring and investigation of different detection methods to better understand potential health risks in karst systems. Full article