Search Results (372)

High demand for sustainable solutions in the construction industry determines the significant relevance of developing new eco-friendly composites with a reduced carbon impact on the environment. The main aim of this study is to investigate the possibility and efficiency of using technical sulfur (TS) as a modifying additive for geopolymer composites and to select the optimal content of polypropylene fiber (PF). To assess the potential of TS, experimental samples of geopolymer solutions based on metakaolin and fly ash were prepared. The TS content varied from 0% to 9% by weight of binder in 3% increments. In the first stage, the density, compressive and flexural strength, capillary water absorption and microstructure of hardened geopolymer composites were tested. The TS additive in an amount of 3% was the most effective and provided an increase in compressive strength by 12.6%, flexural strength by 12.8% and a decrease in capillary water absorption by 18.2%. At the second stage, the optimal PF content was selected, which was 0.75%. The maximum increases in strength properties were recorded for the composition with 3% TS and 0.75% PF: 8% for compression and 32.6% for bending. Capillary water absorption decreased by 12.9%. The geopolymer composition developed in this work, modified with TP and PF, has sufficient mechanical and physical properties and can be considered for further study in order to determine its competitiveness with cement composites in real construction practice. Full article

To address the growing demand for sustainable materials in advanced manufacturing, the objective of this study was to develop and characterize a novel 3D-printable biocomposite using ruminant-digested corn stover (DCS) as a reinforcement for polylactic acid (PLA). The methodology involved systematically optimizing DCS particle size (80–140 mesh) and loading concentration (5–20 wt.%), followed by fabricating composite filaments via melt extrusion and 3D printing test specimens. The resulting materials were comprehensively characterized for their morphological, physical, and mechanical properties. The optimal formulation, achieved with 120-mesh particles at 15 wt.% loading, exhibited a 15.6% increase in tensile strength to 64.17 MPa and a 21.1% enhancement in flexural modulus to 4.19 GPa compared to neat PLA. In addition to the mechanical improvements, the biocomposite offers an advantageous density reduction, enabling the fabrication of lightweight structures for resource-efficient applications. Comprehensive characterization revealed effective interfacial integration and uniform fiber dispersion, validating biological preprocessing as a viable method for unlocking the reinforcement potential of this abundant biomass. While the composite exhibits characteristic trade-offs, such as reduced impact strength, the overall performance profile makes it a promising candidate for structural applications in sustainable manufacturing. This research establishes a viable pathway for agricultural waste valorization, demonstrating that biological preprocessing can convert agricultural residues into value-added engineering materials for the circular bioeconomy. Full article

Modern aerospace engineering places increasing emphasis on materials that combine low weight with high mechanical performance. Fiber metal laminates (FMLs), which merge metal layers with fiber-reinforced composites, meet this demand by delivering improved fatigue resistance, impact tolerance, and environmental durability, often surpassing the performance of their constituents in demanding applications. Despite these advantages, inspecting such thin, layered structures remains a significant challenge, particularly when they are difficult or impossible to access. As with any new invention, they always come with challenges. This study examines the effectiveness of the fundamental anti-symmetric Lamb wave mode (A0) in detecting weak interfacial defects within Carall laminates, a type of hybrid fiber metal laminate (FML). Delamination detectability is analyzed in terms of strong wave dispersion observed downstream of the delaminated sublayer, within a region characterized by acoustic distortion. A three-dimensional finite element (FE) model is developed to simulate mode trapping and full-wavefield local displacement. The approach is validated by reproducing experimental results reported in prior studies, including the author’s own work. Results demonstrate that the A0 mode is sensitive to delamination; however, its lateral resolution depends on local position, ply orientation, and dispersion characteristics. Accurately resolving the depth and extent of delamination remains challenging due to the redistribution of peak amplitude in the frequency domain, likely caused by interference effects in the acoustically sensitive delaminated zone. Additionally, angular scattering analysis reveals a complex wave behavior, with most of the energy concentrated along the centerline, despite transmission losses at the metal-composite interfaces in the Carall laminate. The wave interaction with the leading and trailing edges of the delaminations is strongly influenced by the complex wave interference phenomenon and acoustic mismatched regions, leading to an increase in dispersion at the sublayers. Analytical dispersion calculations clarify how wave behavior influences the detectability and resolution of delaminations, though this resolution is constrained, being most effective for weak interfaces located closer to the surface. This study offers critical insights into how the fundamental anti-symmetric Lamb wave mode (A0) interacts with delaminations in highly attenuative, multilayered environments. It also highlights the challenges in resolving the spatial extent of damage in the long-wavelength limit. The findings support the practical application of A0 Lamb waves for structural health assessment of hybrid composites, enabling defect detection at inaccessible depths. Full article

Natural-fiber-reinforced polypropylene (PP) composites are gaining increasing interest as lightweight, sustainable alternatives for various packaging and applications. This study investigates the effect of filler addition sequence on the mechanical, morphological, thermal, and dynamic mechanical properties of PP-based composites reinforced with graphite nanoplatelets (GnP) and kenaf fiber (KF). Two filler incorporation sequences were evaluated: GnP/KF/PP (GnP initially mixed with KF before PP addition) and GnP/PP/KF (KF added after mixing GnP with PP). The GnP/KF/PP composite exhibited superior mechanical properties, with tensile strength and flexural strength increasing by up to 25% compared to the control, while GnP/PP/KF showed a 13% improvement. SEM analyses revealed that initial mixing of GnP with KF significantly improved filler dispersion and interfacial bonding, enhancing stress transfer within the composite. XRD and DSC analyses showed reduced crystallinity and lower crystallization temperatures in the addition of KF due to restricted polymer chain mobility. Thermal stability assessed by TGA indicated minimal differences between the composites regardless of filler sequence. DMA results demonstrated a significantly higher storage modulus and enhanced elastic response in the addition of KF, alongside a slight decrease in glass transition temperature (T_g). The results emphasize the importance of optimizing filler addition sequences to enhance mechanical performance, confirming the potential of these composites in sustainable packaging and structural automotive applications. Full article

The timely detection of delamination is essential for preventing catastrophic failures and extending the service life of carbon fiber-reinforced polymers (CFRP). Full wavefields in CFRP encapsulate extensive information on the interaction between guided waves and structural damage, making them a widely utilized tool for damage mapping. However, due to the multimodal and dispersive nature of guided waves, interpreting full wavefields remains a significant challenge. This study proposes an end-to-end delamination imaging approach based on UNet++ using 2D frequency domain spectra (FDS) derived from full wavefield data. The proposed method is validated through a self-constructed simulation dataset, experimental data collected using Scanning Laser Doppler Vibrometry, and a publicly available dataset created by Kudela and Ijjeh. The results on the simulated data show that UNet++, trained with multi-frequency FDS, can accurately predict the location, shape, and size of delamination while effectively handling frequency offsets and noise interference in the input FDS. Experimental results further indicate that the model, trained exclusively on simulated data, can be directly applied to real-world scenarios, delivering artifact-free delamination imaging. Full article

Titanium alloy/carbon fiber-reinforced polymer (TA1/CFRP) laminates, representing the latest fourth generation of fiber metal laminates (FMLs), is a kind of high-performance composite material. However, the fragility of the fiber/resin and metal/resin interface layers in these composites directly impacts their mechanical properties. To enhance these properties, this paper investigates the preparation process of multi-walled carbon nanotube (MWCNT)-reinforced ultra-thin TA1/CFRP laminates and explores the impact of MWCNT content on the interlayer properties of these ultra-thin TA1/CFRP laminates. Initially, the challenge of dispersing carbon nanotubes using ultrasonic dispersion devices and dispersants was addressed. Vacuum-curing pressure studies revealed minimal overflow at 0.8 bar vacuum. Subsequently, the impact of MWCNT content on interlayer properties was investigated. The results indicated a significant increase in interlayer shear strength and interlayer fracture toughness with MWCNT additions at 0.5 wt% and 0.75 wt%, whereas the interlayer properties decreased at 1.0 wt% MWCNT. Fracture morphology analysis revealed that MWCNT content exceeding 0.75 wt% led to agglomeration, resulting in resin cavity formation and stress concentration. Full article

Plain concrete specimens and FRP(Fiber Reinforced Polymer)-reinforced concrete specimens were fabricated to investigate concrete’s mechanical and surface degradation behaviors reinforced with carbon, basalt, glass, and aramid fiber-reinforced polymer under coupled sulfuric acid and freeze–thaw cycles. The compressive strength of fully wrapped FRP cylindrical specimens and the flexural load capacity of prismatic specimens with FRP reinforced to the pre-cracked surface, along with the dynamic elastic modulus and mass loss, were evaluated before and after acid–freeze cycles. The degradation mechanism of the specimens was elucidated through analysis of surface morphological changes captured in photographs, scanning electron microscopy (SEM) observations, and energy-dispersive spectroscopy (EDS) data. The experimental results revealed that after 50 cycles of coupled acid–freeze erosion, the plain cylindrical concrete specimens showed a mass gain of 0.01 kg. In contrast, after 100 cycles, a significant mass loss of 0.082 kg was recorded. The FRP-reinforced specimens initially demonstrated mass loss trends comparable to those of the plain concrete specimens. However, in the later stages, the FRP confinement effectively mitigated the surface spalling of the concrete, leading to a reversal in mass loss and subsequent mass gain. Notably, the GFRP(Glassfiber Reinforced Polymer)-reinforced specimens exhibited the most significant mass gain of 1.653%. During the initial 50 cycles of acid–freeze erosion, the prismatic and cylindrical specimens demonstrated comparable degradation patterns. However, in the subsequent stages, FRP reduced the exposed surface area-to-volume ratio of the specimens in contact with the acid solution, resulting in a marked improvement in their structural integrity. After 100 cycles of acid–freeze erosion, the compressive strength loss rate and flexural load capacity loss rate followed the ascending order: CFRP-reinforced < BFRP(Basalt Fiber Reinforced Polymer)-reinforced < AFRP(Aramid Fiber Reinforced Polymer)-reinforced < GFRP-reinforced < plain specimens. Conversely, the ductility ranking from highest to lowest was AFRP/GFRP > control group > BFRP/CFRP. A probabilistic analysis model was established to complement the experimental findings, encompassing the quantification of hazard levels and reliability indices. Full article

This study analyzes a lacquered ear cup excavated from the Luobowan tomb complex in Guigang, Guangxi, attributed to the Nanyue Kingdom of the early Han dynasty. A range of analytical techniques, including optical microscopy (OM), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), pyrolysis–gas chromatography–mass spectrometry (Py-GC-MS), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD), were employed to investigate the structural layers, material composition, and preservation state of the artifact. The lacquerware consists of four traditional layers: a wooden core, fabric reinforcement, lacquer ground, and lacquer film, reflecting Central Plains lacquerware techniques. The wooden core was identified as Phoebe sp., and the fabric layer is likely hemp, though fiber degradation limited exact identification. The lacquer ground layer contains natural lacquer mixed with SiO₂ from brick or tile powder. The lacquer film is a blend of Chinese and Vietnamese lacquer, with no synthetic additives or plant oils detected. The red lacquer layer contains cinnabar (HgS) as a pigment, while the black lacquer uses carbon black. Differences in moisture content between the red and black lacquer films are attributed to variations in surface porosity and pigment characteristics. This research provides valuable insights into Nanyue lacquer technology and preservation challenges. Full article

Soil stabilization with hydraulic binders like cement is widely used in road construction but significantly contributes to CO₂ emissions. This study investigates a more sustainable alternative involving the use of dispersed polypropylene fiber reinforcement to improve the mechanical properties of stabilized soils while reducing cement consumption. Nine clay sand mixtures with varying cement (2–6%) and fiber (0–0.5%) contents were tested using unconfined compressive strength (UCS) and ultrasonic pulse velocity (UPV) methods. Fiber addition improved UCS by 5.59% in a mix with 2% cement and 0.25% fibers and by 25.45% in one with 4% cement and 0.25% fibers. This shows that fibers can improve strength at different cement levels. A novel reinforcement index ($R_i$) was introduced to predict UCS empirically. The model showed that using 0.5% fibers ($R_i=1.0\%$) enabled a 25.12% reduction in cement without compromising strength. However, this improvement came at the cost of stiffness: deformation modulus $E_{50}$ decreased by up to 67.51% at 0.5% fiber content. Statistical validation using MAE, RMSE, and MAPE confirmed the model’s accuracy. Although the results were based on a single soil type, they showed that polypropylene fibers can support decarbonization efforts by reducing cement demand and represent a technically feasible approach to more sustainable geotechnical engineering applications. Full article

The effect of the interaction between silica (nS) and hydroxyapatite (nHap) nanomaterials on the characteristics of unidirectional glass-fiber-reinforced epoxy (GF/Ep) composite systems is investigated in this work. The goal of the study is to use these nanofillers to improve the microstructure and mechanical characteristics. Pultrusion was used to produce hybrid nanocomposites while keeping the GF loading at a consistent 75% by weight. The hybrid nanocomposites were made with a total filler loading of 6 wt.%, including nHap, and a nS loading ranging from 2 to 4 wt.%. The mechanical performance of the composite was greatly improved by the use of these nanofillers. Compared to neat GF/Ep, hybrid nanocomposites with 6 wt.% combined fillers exhibited increased hardness (14%), tensile strength (25%), interlaminar shear strength (21.3%), and flexural strength (33%). These improvements are attributed to efficient filler dispersion, enhanced fiber-matrix adhesion, and crack propagation resistance. Incorporating 4 wt.% nS alone improved hardness (6%), tensile strength (9%), tensile modulus (21%), interlaminar shear strength (11.4%), flexural strength (12%), and flexural modulus (14%). FTIR analysis indicated Si-O-Si network formation and increased hydrogen bonding, supporting enhanced interfacial interactions. Ultraviolet reflectance measurements showed increased UV reflectivity with nS, especially in hybrid systems, due to synergistic effects. Impact strength also improved, with a notable 11.6% increase observed in the hybrid nanocomposite. Scanning and transmission electron microscopy confirmed that the nanofillers act as secondary reinforcements within the matrix. These hybrid nanocomposites present a promising material choice for various industries, including marine structural applications and automotive components. Full article

Geopolymer concrete is a promising construction material that acts as an alternative to cement concrete. Unlike traditional cement concrete, geopolymers are environmentally friendly materials, the production of which does not involve significant carbon dioxide emissions. However, the structure formation and properties of geopolymers significantly depend on raw materials and are insufficiently studied. The aim of the study is to select the optimal combination of ground granulated blast furnace slag (GGBS) and fly ash (FA) as a binder and the optimal content of polypropylene fiber to create a sustainable, environmentally friendly and effective geopolymer concrete. To study various compositions of geopolymer binders selected by combining GGBS and FA, experimental geopolymer concrete mixtures and samples from them were manufactured. The density and slump of fresh concrete and the density and compressive strength of hardened composites were studied as mechanical characteristics. The microstructure of the geopolymer matrix was analyzed using optical and scanning electron microscopes. The most rational combination of GGBS 80% and FA 20% was determined, which allows obtaining a composite with the highest compressive strength of up to 31.5 MPa. A dispersion reinforcement study revealed that 0.8% polypropylene fiber (PF) is optimal. This allowed us to increase the compressive strength by 7.3% and the flexural strength by 48.7%. The geopolymer fiber concrete obtained in this study is a sustainable and environmentally friendly alternative composite material and has sufficient performance properties for its use as an alternative to cement concrete. Full article

This study explores the impact of thermal cycling and rubber particle content on the static and dynamic compressive properties of rubber–polyethylene fiber-reinforced engineered cementitious composites (RPECC). Through static and dynamic compression tests, supplemented by scanning electron microscopy and energy-dispersive X-ray spectroscopy, the mechanical behavior and microstructural evolution of RPECC under thermal cycling were analyzed. Results indicate that increasing rubber content from 10% to 30% enhances toughness and strain capacity but reduces the static compressive strength of ECC by up to 17.9% at 30%. Thermal cycling reduced strength: static and dynamic compressive strengths decreased by 18.0% and 41.2%, respectively, after 270 cycles. Dynamic tests demonstrated that RPECC is sensitive to strain rate. For example, C-20 specimens exhibited increases in dynamic strength of 6.9% and 9.9% as strain rate rose from 60.2 s⁻¹ to 77.4 s⁻¹ and 110.8 s⁻¹, respectively, and the dynamic increase factor correlated linearly with strain rate. By contrast, excessive rubber content (30%) diminishes dynamic strengthening, indicating that 20% rubber is optimal for enhancing strain rate sensitivity. Thermal cycling facilitates the formation of hydration products, such as calcium hydroxide, and creates interfacial defects, further deteriorating mechanical performance. These findings provide a reliable foundation for optimizing RPECC mix design and ductility in environments subject to temperature fluctuations and dynamic loading. Full article

With growing emphasis on sustainable construction, fiber-reinforced polymer (FRP) bars are increasingly being used as alternatives to steel rebars due to their high strength-to-weight ratio, corrosion resistance, and environmental benefits. This study has investigated the bond behavior between FRP bars and concrete of different strength grades under dynamic loading conditions. To analyze the microscopic properties of FRP bar surfaces, the study employs a variety of techniques, including scanning electron microscopy (SEM), atomic force microscopy (AFM), and non-contact surface profilometry. In addition, X-ray photoelectron spectroscopy (XPS), water contact angle (WCA) measurements, and energy dispersive spectrometry (EDS) are used to further investigate surface characteristics. The results reveal a direct correlation between the resin surface roughness of FRP bars and their wettability characteristics, which in turn influence the cement hydration process. Pull-out tests under different loading rates and concrete strength grades have been conducted to evaluate the bond–slip behavior and failure modes. The results indicate that bond strength increases with increasing concrete strength. Dynamic pull-out tests further reveal that higher loading rates generate heterogeneous stress fields, which limit the deformation of FRP bars and consequently diminish the contribution of mechanical interlock to interfacial bonding. Full article

This study investigates the effect of fiber weight fraction on the tribomechanical behavior of basalt fiber-reinforced polymer (BFRP) composites under dry sliding conditions. Composite specimens with 50%, 65%, and 70% basalt fiber contents were manufactured and tested through tensile, flexural, and pin-on-disc tribological evaluations. Key tribological parameters, including the coefficient of friction (COF), specific wear rate (K), and contact temperature, were measured under various applied loads and sliding speeds. Statistical analysis was performed using a generalized linear model (GLM) to identify significant factors and their interactions. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) analyses indicated that abrasive wear, matrix cracking, and fiber–matrix interfacial failure were the dominant wear mechanisms. The experimental results revealed that the fiber weight fraction had the most significant influence on COF (42.78%), while the sliding speed had the predominant effect on the specific wear rate (77.69%) and contact temperature (32.79%). These findings highlight the potential of BFRP composites for applications requiring enhanced wear resistance and mechanical stability under varying loading conditions. Full article

Cement is widely used as the primary binder in concrete; however, growing environmental concerns and the rapid expansion of the construction industry have highlighted the need for more sustainable alternatives. Geopolymers have emerged as promising eco-friendly binders due to their lower carbon footprint and potential to utilize industrial byproducts. Geopolymer mortar, like other cementitious substances, exhibits brittleness and tensile weakness. Basalt fibers serve as fracture-bridging reinforcements, enhancing flexural and tensile strength by redistributing loads and postponing crack growth. Basalt fibers enhance the energy absorption capacity of the mortar, rendering it less susceptible to abrupt collapse. Basalt fibers have thermal stability up to about 800–1000 °C, rendering them appropriate for geopolymer mortars designed for fire-resistant or high-temperature applications. They assist in preserving structural integrity during heat exposure. Fibers mitigate early-age microcracks resulting from shrinkage, drying, or heat gradients. This results in a more compact and resilient microstructure. Using basalt fibers improves surface abrasion and impact resistance, which is advantageous for industrial flooring or infrastructure applications. Basalt fibers originate from natural volcanic rock, are non-toxic, and possess a minimal ecological imprint, consistent with the sustainability objectives of geopolymer applications. This study investigates the mechanical and thermal performance of a geopolymer mortar composed of metakaolin and red mud as binders, with basalt powder and limestone powder replacing traditional sand. The primary objective was to evaluate the effect of basalt fiber incorporation at varying contents (0.4%, 0.8%, and 1.2% by weight) on the durability and strength of the mortar. Eight different mortar mixes were activated using sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) solutions. Mechanical properties, including compressive strength, flexural strength, and ultrasonic pulse velocity (UPV), were tested 7 and 28 days before and after exposure to elevated temperatures (200, 400, 600, and 800 °C). The results indicated that basalt fiber significantly enhanced the performance of the geopolymer mortar, particularly at a content of 1.2%. Specimens with 1.2% fiber showed up to 20% improvement in compressive strength and 40% in flexural strength after thermal exposure, attributed to the fiber’s role in microcrack bridging and structural densification. Subsequent research should concentrate on refining fiber type, dose, and dispersion techniques to improve mechanical performance and durability. Examinations of microstructural behavior, long-term durability under environmental settings, and performance following high-temperature exposure are crucial. Furthermore, investigations into hybrid fiber systems, extensive structural applications, and life-cycle evaluations will inform the practical and sustainable implementation in the buildings. Full article