Search Results (640)

As semiconductor packaging technology evolves from two-dimensional to three-dimensional integration, the through-glass via (TGV) technique, as a core interconnect method in advanced packaging, is emerging as a strong candidate to replace through-silicon vias (TSVs) and plated through-holes (PTHs) in organic substrates. Glass substrates offer excellent electrical insulation, low dielectric loss, tunable thermal expansion coefficients, and the potential for large-scale panel-level manufacturing. However, issues related to TGV hole quality, metallization uniformity, and thermomechanical reliability remain key bottlenecks limiting their large-scale industrialization. This investigation provides a comparative review of non-laser and laser machining for TGVs to address the above problems. First, the technical background and core advantages of TGVs are outlined. Second, this study details non-laser processing methods, including sandblasting erosion, mechanical drilling, the photosensitive glass method, electrochemical discharge machining (ECDM), deep reactive ion etching (DRIE), and others. Third, laser processing methods, covering laser ablation drilling, laser-induced deep etching (LIDE), femtosecond laser-assisted wet etching and others, are given focus. Moreover, this study analyzes typical applications of TGVs in 3D/2.5D packaging, MEMS devices, optoelectronic integration, and others. In addition, the machining processes of non-laser and laser-based TGVs, such as mechanical machining, ECDM, and LIDE, are compared, and key process challenges, technical trade-offs, and reliability failure mechanisms are discussed. Finally, this review looks ahead to future trends, aiming to provide a systematic technical reference for researchers in the TGV field. Full article

We report a low-temperature plasma–liquid synthesis of crystalline β-Ga₂O₃ nanoparticles directly from aqueous solution. Pulsed discharge plasma bubbles generate reactive species that drive in situ dehydration and crystallization, bypassing the high-temperature calcination required by conventional methods. By varying the carrier gas, we tune morphology from uniform nanorice structures (He, Ar, and N₂) to amorphous microspheres (O₂ and air), revealing how plasma composition governs interfacial hydroxyl radical chemistry and growth kinetics. This approach demonstrates that localized plasma heating and reactive-species flux can achieve phase-selective oxide crystallization under ambient conditions, establishing plasma bubble reactors as a broadly applicable, low-temperature route for direct aqueous synthesis of crystalline wide-bandgap oxides that bridge solution chemistry and plasma nanomaterials design. Full article

This study evaluates the ecological impacts of seawater desalination discharge on coastal marine ecosystems through a sequential analytical framework linking systematic literature synthesis, field-monitoring evidence, spatial analysis, and predictive ecological modeling. The novelty of the study lies in combining multi-regional evidence from Mediterranean coastal zones, Persian Gulf waters, and Pacific coastal environments with threshold-based ecological risk assessment, thereby linking discharge-related environmental stressors with biological responses and ecosystem-function alterations. The systematic review first retained 750 studies published between 2004 and 2024 for qualitative synthesis. On this basis, 59 high-quality references with sufficient numerical information were selected for the main quantitative meta-analysis, while field-monitoring data were used to support the interpretation of distance-based discharge gradients. Spatial interpolation and hierarchical modeling were then applied to evaluate exposure–response patterns and ecological threshold behavior. The results showed that desalination facilities generated measurable ecological impacts mainly within 50–200 m of discharge points, with a critical transition distance of approximately 127 m where hypersaline conditions, typically 1.5–2.0 times ambient seawater levels, were associated with marked changes in marine community structure. Benthic assemblages showed taxon-specific responses, with mollusks and echinoderms exhibiting greater sensitivity than polychaetes and small crustaceans. Marine vegetation declined strongly under combined salinity, thermal, and chemical stress, while phosphonate-based antiscalants accumulated in filter-feeding organisms and produced bioaccumulation factors up to 42.1 times ambient levels. Ecosystem-function indicators, including microbial community composition and sediment organic matter processing, remained altered up to 300 m from discharge points, indicating that functional impacts may extend beyond the primary hypersaline plume. The predictive modeling framework further demonstrated that ecological risk decreased nonlinearly with distance and varied according to discharge intensity, local hydrodynamics, and biological sensitivity. These findings indicate that conventional uniform buffer-based assessment may underestimate the ecological footprint of desalination discharge. Sustainable desalination management should therefore adopt site-specific monitoring, species-sensitive protection thresholds, improved brine-management technologies, and adaptive mitigation strategies based on real-time environmental feedback. Full article

Rising demand for high-performance battery thermal management systems (BTMSs) has rendered single-mode cooling insufficient for advanced lithium-ion batteries (LIBs) in new energy vehicles (NEVs), particularly under high discharge rates. This study proposes a synergistic hybrid BTMS integrating composite phase-change material (CPCM)–aluminum foam with liquid cooling to enhance thermal regulation of cylindrical battery modules under 5 C discharge conditions. Multiple liquid-cooled plate (LCP) configurations, including serpentine, straight, and leaf-shaped designs, together with different flow channel topologies (FCTs), were systematically investigated and optimized. The effects of coolant flow speed (CFS) and ambient temperature were also analyzed. Results indicate that the optimized leaf-shaped LCP with FCT #2 delivers superior performance, limiting the maximum temperature to 309.98 K, reducing temperature difference by 7.6%, and decreasing pressure drop by 88.79% compared to the serpentine configuration. Increasing CFS improves heat dissipation and delays PCM melting, although it raises pressure losses. Furthermore, the proposed system maintains a cell-to-cell temperature difference below 0.51 K, indicating excellent thermal uniformity. Compared to a CPCM-only system, the hybrid BTMS reduces peak temperature by 8.81 K under elevated ambient conditions (309.15 K), demonstrating strong potential for reliable and efficient thermal management in demanding operating environments. Full article

TiO₂/activated carbon (TiO₂/AC) was coated on mesh using the dip-coating method employing polyvinyl pyrrolidone (PVP) as a copolymer via a simple mixing method. The obtained catalyst was used to treat real wastewater from a building discharge with a horizontal photoreactor with a continuous flow system. The synthesis of 20%wt TiO₂/AC-coated mesh was performed with a fixed TiO₂:AC ratio of 1:0.05 wt/wt, as confirmed by employing various characterization techniques, which resulted in a composite TiO₂/AC characterized by XRD, FE-SEM, and EDS, confirming the uniform distribution of TiO₂/AC nanoparticles coated on mesh substrates. The influence of vital parameters on the best conditions of the photoreactor design, including flow rate (8.0 L/min), light intensity position (5.0 cm), and the number of mesh layers (20 mesh layers), was systematically examined during photocatalytic oxidation. The treatment efficiency of domestic building wastewater was evaluated using a TiO₂/AC coated on mesh under visible light irradiation for 120 min. The recirculating batch photoreactor was operated at a continuous flow rate of 8.0 L/min, corresponding to a total treated wastewater volume of 960 L. In real wastewater treatment, the optimized TiO₂/AC-coated mesh exhibited the highest activity, achieving approximately 68% BOD removal and 65% COD removal. This study indicates that TiO₂/AC-coated mesh can be a good candidate for building wastewater treatment systems using photocatalytic activity under visible light irradiation. However, the TiO₂/AC coating exhibited limited reusability, with BOD degradation decreasing to 53% after three cycles. Future work must develop a more stable binder to improve its durability and reusability. Full article

Layered Li-rich manganese-based Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ (LNCMO) is regarded as a promising high-capacity cathode material. However, its commercial application is severely hindered by rapid capacity fading, serious voltage decay and poor cycling stability. Herein, a facile non-sintering electrostatic adsorption strategy employing PDDA is proposed to fabricate a uniform and dense graphene oxide (GO) coating on LNCMO particles. Structural and morphological characterizations confirm the successful decoration of GO on the surface of LNCMO. The optimized 0.5@LNCMO sample delivers a discharge capacity of 330 mAh g⁻¹ at 0.1C, and maintains a capacity retention of 86.5% after 200 cycles at 1C and 83.3% after 400 cycles at 5C, showing much better electrochemical performance than pristine LNCMO. This study proves that the proposed strategy is an effective modification method for constructing high-performance Li-rich cathode materials. Full article

To address heat accumulation, localized hot spots, and non-uniform temperature distribution in large-capacity lithium iron phosphate energy storage battery modules under high ambient temperature and high-rate charge/discharge conditions, this study proposes a fin-enhanced phase change material (PCM)-air hybrid thermal management structure for a 100 Ah prismatic lithium iron phosphate battery and a 2P18S energy storage battery module. First, the battery thermal model is validated using single-cell experimental data reported in the literature. Subsequently, a three-dimensional transient fluid–solid coupled heat transfer model is established by considering transient battery heat generation, PCM solid–liquid phase change, air-side flow and heat transfer, and temperature-dependent thermophysical properties. User-defined functions are employed to implement the transient heat source and temperature-dependent material properties. Under identical boundary conditions, the thermal management performances of three configurations, namely Fin-Air, PCM-Air, and Fin-PCM-Air, are compared. The effects of ambient temperature (20 °C, 25 °C, and 30 °C) and inlet air velocity (1 m/s, 2 m/s, and 3 m/s) on the maximum module temperature, temperature uniformity, PCM liquid fraction evolution, and flow field distribution are quantitatively analyzed. The results show that, compared with the Fin–Air system without PCM and the PCM-Air system without fins, the Fin-PCM-Air configuration reduces the maximum module temperature by 1.57% and 0.25%, respectively, at an ambient temperature of 30 °C and an inlet air velocity of 3 m/s. After four charge–discharge cycles, the peak maximum temperature of the module is approximately 38.56 °C, and the peak maximum temperature difference remains below 3.6 K, indicating good temperature uniformity and latent heat buffering capability. In addition, the air velocity trade-off analysis indicates that increasing the inlet air velocity can improve cooling performance but also increases the air-channel pressure drop and fan power consumption. Therefore, the Fin-PCM-Air structure is more suitable for high-thermal-load conditions, and its practical application should comprehensively consider cooling benefits, additional mass, manufacturing cost, and long-term reliability. This study provides a reference for the design and engineering application of hybrid thermal management structures for large-capacity energy storage battery modules. Full article

Powdered organic fertilizer is crucial for sustainable agriculture, but its poor flowability and hygroscopic compaction and caking nature cause frequent blockages during mechanized strip application. While a single Johnson–Kendall–Roberts (JKR) discrete element method (DEM) model simulates powder flow well, it fails to reflect the mechanical breakage of hard caked lumps. Thus, this study established a comprehensive DEM model simultaneously simulating both powder and caked lumps. Based on coarse-graining theory, 0.147 mm particles were scaled to 2 mm spheres. Contact parameters (e.g., JKR surface energy) were calibrated using response surface methodology, yielding a repose angle simulation error of only 0.18%. The actual three-dimensional (3D) geometry of caked lumps was reconstructed via 3D scanning, and breakage mechanical parameters were accurately calibrated by combining uniaxial compression tests with a Bonding model (errors for ultimate load and displacement < 2%). Applying this model to an anti-blocking fertilizer discharge device, simulations and performance tests demonstrated an acceptable macroscopic representation of both powder flow and lump breakage. The optimized device achieved a strip application uniformity coefficient of variation of 3.87–6.40%. By simulating the complex coexistence of powder flow and lump breakage, this study provides a feasible parameter calibration method and numerical reference for optimizing anti-blocking discharge devices. Full article

In the renewable energy-driven “green electricity–green hydrogen–green ammonia” pathway, the development of low-temperature and low-energy-consumption ammonia synthesis technologies is of great significance. In this work, a plasma-catalytic ammonia synthesis system was established using a coaxial dielectric barrier discharge (DBD) reactor. The effects of different catalysts, including Ag, Cu, γ-Al₂O₃, BaTiO₃ and Co/BaTiO₃, Ni/BaTiO₃ on ammonia synthesis performance were systematically investigated. The reaction process was analyzed using voltage–current waveforms, Lissajous figures, and optical emission spectroscopy (OES). The results show that different catalytic systems have a significant influence on ammonia synthesis performance, with the promotional effect ranked as follows: Ni/BaTiO₃ > Co/BaTiO₃ > BaTiO₃ > Ag > γ-Al₂O₃ > Cu. Among them, Ni/BaTiO₃ exhibited the best performance. Under the conditions of N₂:H₂ = 1:1 and a gas flow rate of 2.5 L/min, the NH₃ synthesis rate reached 259.48 μmol/min, and the maximum energy efficiency reached 1.40 g-NH₃/kWh. Catalyst characterization results indicate that the BaTiO₃ support maintained a stable crystal structure, while the loaded metal species were highly dispersed and uniformly distributed on the support surface, which is beneficial for the adsorption and conversion of reactive species on the catalyst surface. Discharge characteristic analysis shows that the introduction of BaTiO₃ enhanced the local electric field and improved the uniformity of micro-discharges, while the further incorporation of metal active components strengthened the micro-discharge behavior. OES results reveal that the intensities of characteristic emission lines, such as NH, N₂⁺, and Hα, were significantly enhanced in the Ni/BaTiO₃ system, facilitating the formation and conversion of NH_x intermediates. The superior performance of Ni/BaTiO₃ is attributed to the coupling between BaTiO₃-induced dielectric enhancement and Ni-promoted surface hydrogenation and NH₃ desorption. This work provides mechanistic insight into catalyst-dependent DBD plasma-catalytic ammonia synthesis and offers an experimental basis for the further optimization of plasma-based ammonia production. Full article

Conventional maize fertilization suffers from uneven distribution, fertilizer waste, and environmental pollution. To address these issues and achieve precision fertilization for maize, a straight grooved-wheel fertilizer apparatus (SGWFA) was designed and optimized using the discrete element method (DEM). The blocking characteristic of the SGWFA was also evaluated. The optimal configuration (eight grooves, inner diameter of 26 mm) yielded a minimum discharge uniformity coefficient of variation of 2.50% and mild blocking, with a maximum total force of 161.884 N. Furthermore, a nonsingular terminal sliding mode control (NTSMC) algorithm was proposed for the speed loop of the brushless DC (BLDC) motor drive, while the current loop used conventional proportional-integral (PI) control. The overall system achieved dual closed-loop speed and current regulation with finite-time convergence of the speed tracking error. Simulations showed that, compared with conventional PI and fuzzy PI controllers, NTSMC had the smallest overshoot of 3.4%, the shortest settling time of 0.165 s, and the fastest disturbance rejection. Bench tests confirmed that the coefficient of variation under NTSMC was 2.85%, markedly better than fuzzy PI’s 3.15% and conventional PI’s 4.03%. It is also basically consistent with the simulation results. Field tests at 6, 9, and 12 km/h demonstrated over 95% per-row fertilization accuracy, with a maximum relative error of only 4.61%. This integrated system can effectively achieve precise fertilizer application under variable field conditions. Full article

Liquid-cooled battery thermal management systems are essential for maintaining thermal safety, temperature uniformity, and hydraulic efficiency in electric vehicle battery modules. However, improving heat dissipation often increases pressure drop and pumping demand, making the thermal–hydraulic trade-off a key challenge in cooling plate design. This study develops a CFD–GPR–NSGA-II-based multi-objective optimization framework for a mini-channel liquid cooling plate applied to a cylindrical 18650 lithium-ion battery module under a 4C discharge condition. The mini-channel thickness, wall thickness, and coolant inlet velocity are selected as design variables, while the maximum battery temperature, temperature difference, and pressure drop are used as objective functions. Sixty design samples are generated using Latin hypercube sampling and evaluated through CFD simulations. Gaussian process regression models are then constructed to approximate the nonlinear relationships between the design variables and the thermal–hydraulic responses, and the trained surrogate models are coupled with NSGA-II to identify Pareto-optimal solutions. The selected compromise design is finally verified using a full CFD simulation. Compared with the initial configuration, the CFD-verified optimized design reduces the maximum temperature, temperature difference, and pressure drop by 0.569 K, 0.557 K, and 338.612 Pa, respectively. Although the reduction in peak temperature is moderate, the optimized design improves temperature uniformity by 10.06% and reduces pressure drop by 43.25%, demonstrating a balanced improvement in thermal and hydraulic performance. A heat-load robustness check further confirms that the optimized design maintains a predictable thermal response under different heat generation levels. These results indicate that the proposed CFD–GPR–NSGA-II framework provides an effective and computationally efficient approach for designing mini-channel liquid cooling plates for electric vehicle battery thermal management. Full article

A series of Mg-Al LDH-based photocatalysts were synthesized via a one-pot steam-assisted method, including pure Mg-Al LDH (MA), Zn-In ion-exchange-modified Mg-Al LDH (MAZ), BiOCl-loaded pristine Mg-Al LDH (MAB), and Zn-In-modified Mg-Al LDH co-loaded with TiO₂ and BiOCl (MA/Zn-In/TiO₂/BiOCl, MAZB). The one-pot synthesis facilitated the in situ intercalation and uniform loading of BiOCl/TiO₂/Zn-In, while Zn²⁺/In³⁺ modified the MA layers via ion exchange, leading to an expansion of the interlayer spacing. The innovation of this work is reflected in two aspects: first, all raw materials are added via a one-pot strategy to achieve in situ preparation of modified hydrotalcite; second, this synthetic route features simple post-treatment without complicated washing, pressure filtration, and other tedious operations. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and N₂ adsorption–desorption isotherms. The bismuth chloride oxide/TiO₂/LDHs exhibited a layered structure, with the active components uniformly distributed between the layers and on the MA surface. Under simulated sunlight irradiation, MAZB achieved 97.5% degradation of 20 mg/L MB within 120 min, with an apparent rate constant of 0.0297 min⁻¹, which is 7.2 times, 2.4 times, and 2.9 times that of MA, MAZ, and MAB, respectively. The degradation rate of MAZB still remained at 89.5% after five cycles, demonstrating excellent stability and reusability. Compared with traditional hydrothermal methods, this steam-assisted system features mild reaction conditions (180 °C, atmospheric pressure), sodium-free raw materials, no washing requirement, and zero waste discharge, showing prominent green advantages. Full article

The development of cost-effective and resource-rich materials is crucial for the practical application of microwave absorbers. This study demonstrates the successful fabrication of core-shell Fe and TiC nanoparticles encapsulated within carbon shells using the arc discharge method. The samples are designated as Fe3Ti1 and Fe1Ti3, where the numbers indicate the Fe-to-Ti mass ratio in the precursor (e.g., Fe1Ti3 = 1:3 by mass). In the arc discharge synthesis mechanism, the mass ratio of Fe to Ti in the raw material was adjusted from 3:1 to 1:3 to optimize the Fe/TiC/C interfaces under a CH₄ forming gas atmosphere. TEM analysis reveals spherical and polyhedral nanoparticles with diameters of 30–50 nm and a uniform carbon shell thickness of 3–4 nm. Raman spectroscopy shows that the Fe1Ti3 sample has a higher defect density (I_D/I_G = 1.13) compared to Fe3Ti1 (0.87), indicating a more disordered carbon structure. Magnetic measurements yield saturation magnetization values of 87 emu/g for Fe3Ti1 and 50 emu/g for Fe1Ti3, with coercivities of 190.72 Oe and 203.65 Oe, respectively. When composited with paraffin at 50 wt% loading, the Fe1Ti3 sample exhibits superior microwave absorption performance, achieving a minimum reflection loss (RL) of −25.22 dB at 8.23 GHz and an effective absorption bandwidth (RL ≤ −10 dB) of 4 GHz (6.5–10.5 GHz) at a thickness of 2.5 mm. This enhanced performance is attributed to the synergistic effect of multiple loss mechanisms, including conduction loss within the three-dimensional core-shell architecture, interfacial polarization at the heterojunctions between the core and the carbon shell, and magnetic loss induced by ferromagnetic behavior associated with defects in both the shell and carbon atomic layers. The magnetic loss in the (Fe/TiC)@C nanocomposites primarily arises from the natural resonance (at ~6.5 GHz) and exchange resonance (at ~12 GHz) of the Fe cores. The dielectric loss is primarily attributed to dipole, interfacial, and space charge polarization from TiC and the carbon shell, as well as multiple scattering effects between nanoparticles. Furthermore, far-field radar cross-section simulations substantiate that the Fe/TiC@C nanocomposite demonstrates excellent radar wave attenuation capability. Further, first principles simulations reveal that introducing Fe at the C/TiC interface induces strong charge redistribution and orbital hybridization, transforming a localized dielectric interface into a highly conductive and electronically coupled C/Fe/TiC system. This interfacial modulation enhances both dielectric loss (via charge transport and polarization) and magnetic loss (via Fe-induced magnetic interactions), thereby enabling optimized dielectric-magnetic synergy for broadband microwave absorption in (Fe/TiC)@C nanocomposites. Full article

The objective of this study was to further improve the wear and corrosion resistance of biomedical Ti6Al4V alloy micro-arc oxidation coating, so as to improve its comprehensive service performance. In this study, the effects of pulsed laser power (20–100 W) on the structure, composition, tribological properties and corrosion resistance of the composite coating were systematically studied by using pulsed laser remelting pretreatment technology. The results show that when the power is 100 W, the microwave stripe and fine grain structure formed by pulsed laser remelting can improve the discharge uniformity during the micro-arc oxidation process. The porosity of the composite coating decreases from 21.32% to 10.94%, and the thickness increases from 8.14 μm to 19.49 μm, which is beneficial to improve the compactness and uniformity of the micro-arc oxidation coating. In addition, the pulse laser remelting pretreatment increased the surface hardness of the composite coating to 745.5 HV, and the friction coefficient decreased from 0.76 to 0.51, thereby improving the wear resistance of the composite coating. The electrochemical test results show that the corrosion current density of the composite coating is reduced from 7.28 × 10⁻⁸ A·cm⁻² to 1.91 × 10⁻⁸ A·cm⁻² due to the optimization of the composite coating structure, and the corrosion resistance is significantly enhanced. This study provides an effective pretreatment strategy for the construction of high-performance MAO composite coatings. Full article

To address the industry pain points of domestic traditional fish meal processing equipment, such as low protein retention, low drying efficiency, and poor operational reliability, this study focuses on high-moisture, heat-sensitive cod meal as the test material to investigate the structural improvement and synergistic optimization of process parameters for vacuum low-temperature fish meal dryers. The conventional uniform-pitch heating coil was optimized into a three-section differentiated structure, with a wear-resistant protective structure additionally incorporated to fundamentally resolve issues including insufficient heat transfer at the feed end, coking at the discharge end, and coil wear-induced leakage. Verification via COMSOL Multiphysics simulation revealed that the axial temperature gradient of the optimized equipment decreased from 8.6 °C/m to 6.2 °C/m, while the thermal fatigue life of the coil was extended from 2–3 years to over 10 years. A three-factor, three-level response surface methodology (RSM) was employed to design the experiments, with the heating temperature, vacuum degree, and drying time as independent variables and the fish meal protein content as the response variable. A total of 17 experimental runs were constructed, including 12 factorial points and 5 central points; each run was replicated three times in parallel, and data were reported as mean values. Analysis of variance (ANOVA) demonstrated that the regression model was highly statistically significant (p < 0.0001), with a coefficient of variation (CV) of 0.2464% and a coefficient of determination (R²) of 0.9944, indicating excellent fitting accuracy. The determined optimal process parameters were as follows: a drying temperature of 65 °C, vacuum degree of 0.08 MPa, and drying time of 75 min. Compared with the traditional process, the optimized process shortened the drying cycle by 37.5%, reduced unit energy consumption by 29.2%, and increased the fish meal protein content by 6.6%. This research provides a reliable technical solution for the localized processing of high-end fish meal. Full article