Search Results (706)

This study examines the effects of temperature, relative humidity, moisture content, and density on the dielectric constant (ε′) and dielectric loss tangent (tan δ) of oak wood lamellae within a frequency range of 0.079 MHz to 25.1 MHz. The hypothesis tested was that increased temperature and moisture content enhance both dielectric polarization and loss, while density acts as a dominant structural determinant of dielectric behaviour. Oak lamellas were conditioned above saturated salt solutions at 20 °C and measured using an Agilent 4285A LCR meter according to ASTM D150-22. Multiple linear regression was used to demonstrate the statistically significant influence of temperature, relative humidity, moisture content, and density on the tested electrical properties of the lamellas. The results showed that the dielectric properties increase with higher sample density and higher air humidity. Temperature also had an influence, but it was significantly smaller, though still statistically significant (p < 0.05). Changes in dielectric properties were most pronounced at frequencies below 1 MHz, suggesting that dipolar and interfacial polarization are greater at lower frequencies. The findings in this paper provide a basis for optimizing the high frequency/dielectric heating process for heating before bending of oak and other similar hardwoods. Full article

In the present study, ten type-V natural deep eutectic solvents (NADESs) were synthesized and comprehensively characterized, based on urea as a hydrogen-bond acceptor and three different groups of donors—glycerol, organic carboxylic acids, and carbohydrates. Their physicochemical parameters, spectral characteristics (FTIR), surface tension, and solvatochromic properties were determined using Nile Red, betaine 30, and Kamlet–Taft parameters. The densities of the systems (1.243–1.361 g/cm³) and the high values of molar refraction and polarizability indicate the formation of highly organized hydrogen-bonded networks, with the incorporated carboxyl and hydroxyl groups enhancing the structural compactness of the NADES. Surface tension varied significantly (46.9–80.3 mN/m), defining systems with low, medium, and high polarity. Solvatochromic analysis revealed high E_NR, E_T(30), and E_T^N values, positioning all NADES as highly polar media, comparable or close to water, but with distinguishable H-bond donating/accepting ability depending on the third component. The normalized Kamlet–Taft parameters show that the NADES cover a broad solvent spectrum—from highly H-bond accepting to strongly H-bond donating or dipolar systems—highlighting the potential for fine-tuning the solvent according to target applications. The obtained results highlight the applicability of these NADESs as green, tunable media for the extraction and solvation of bioactive compounds. Full article

Microtubules are cylindrical protein polymers that organize the cytoskeleton and play essential roles in intracellular transport, cell division, and possibly cognition. Their highly ordered, quasi-crystalline lattice of tubulin dimers, notably tryptophan residues, endows them with a rich topological and arithmetic structure, making them natural candidates for supporting coherent excitations at optical and terahertz frequencies. The Penrose–Hameroff Orch OR theory proposes that such coherences could couple to gravitationally induced state reduction, forming the quantum substrate of conscious events. Although controversial, recent analyses of dipolar coupling, stochastic resonance, and structured noise in biological media suggest that microtubular assemblies may indeed host transient quantum correlations that persist over biologically relevant timescales. In this work, we build upon two complementary approaches: the parametric resonance model of Nishiyama et al. and our arithmetic–geometric framework, both recently developed in Quantum Reports. We unify these perspectives by describing microtubules as rectangular lattices governed by the imaginary quadratic field $\mathbb{Q}\left(i\right)$, within which nonlinear dipolar oscillations undergo stochastic parametric amplification. Quantization of the resonant modes follows Gaussian norms $N=p^2+q^2$, linking the optical and geometric properties of microtubules to the arithmetic structure of $\mathbb{Q}\left(i\right)$. We further connect these discrete resonances to the derivative of the elliptic L-function, $L\prime (E,1)$, which acts as an arithmetic free energy and defines the scaling between modular invariants and measurable biological ratios. In the appended adelic extension, this framework is shown to merge naturally with the Bost–Connes and Connes–Marcolli systems, where the norm character on the ideles couples to the Hecke character of an elliptic curve to form a unified adelic partition function. The resulting arithmetic–elliptic resonance model provides a coherent bridge between number theory, topological quantum phases, and biological structure, suggesting that consciousness, as envisioned in the Orch OR theory, may emerge from resonant processes organized by deep arithmetic symmetries of space, time, and matter. Full article

The 1,4-dipolar cycloaddition of the ylidene derivative of 1H-pyrrole-2,3-dione to a dipole generated in situ from 1-benzylbenzimidazole and dimethyl acetylenedicarboxylate proceeds via the exocyclic multiple bond of the ylidene derivative and affords a mixture of diastereomeric spiro[benzo[4,5]imidazo[1,2-a]pyridine-3,3’-pyrroles], which slowly epimerized in a solution. Full article

A strategy for constructing trifluoromethylated spiroisoxazolones has been developed. This approach relies on the 1,3-dipolar cycloaddition of CF₃-substituted nitrile imines, generated in situ from trifluoroacetyl hydrazonoyl bromides and K₂CO₃, with the exocyclic double bond of 4-benzylidene-3-methylisoxazol-5(4H)-ones. The reaction provides a series of trifluoromethylated spiro(isoxazolone-pyrazoline) derivatives in moderate to high yields (up to 93%). The protocol exhibits broad substrate compatibility with respect to aromatic substituents on both reaction partners. To the best of our knowledge, the introduction of a trifluoromethyl group at the 3-position of the pyrazoline ring via nitrile imine cycloaddition chemistry has not been previously reported. The resulting products incorporate a valuable CF₃-substituted pyrazoline pharmacophore spiro-fused to an isoxazolone core and may be of interest for medicinal chemistry programs. Full article

This work provides the first systematic survey of the two–photon properties of 97 natural 9,10–anthraquinones from plants and fungi. A comprehensive computational dataset of two–photon absorption properties calculated using RI–CC2/aug–cc–pVDZ is presented. Single degenerate photon energies required for two–photon excitation span 491.6–1007.9 nm across the five lowest singlet states, with all S₀→S₁ transitions falling within the biological therapeutic window. Remarkably, S₃ state exhibits systematically enhanced TPA efficiency, with 60% of compounds surpassing 1 GM and achieving a mean cross–section of 29.9 GM–substantially higher than S₁ (mean: 7.5 GM). Three compounds demonstrate exceptional performance: cynodontin (73.6 GM, S₂), dermocybin (68.7 GM, S₄), and morindone (50.7 GM, S₃). Orbital analysis reveals that these excitations possess high configurational purity and diagnostics validating the single–reference treatment. The observed spatial separation between hole and particle NTOs, combined with extreme transition dipole anisotropy along the molecular long axis, indicates dipolar charge–transfer enhancement. Comprehensive structure–property analysis establishes that strategic modification may maximise TPA cross–sections. Comparison with aqueous–phase calculations for three compounds reveals non–systematic solvent–induced redistributions of TPA activity across excited states, indicating that gas–phase outcomes serve primarily as internal benchmarks and intrinsic descriptors of structure–property relationships rather than quantitative predictors of photoactivity. Full article

This study investigates the aerodynamic and aeroacoustics behavior of automotive cooling modules in both conventional internal combustion engine (ICE) vehicles and electric vehicles (EVs), with a particular focus on installation effects. Numerical simulations based on the Lattice Boltzmann Method (LBM) are conducted to analyze noise generation mechanisms and flow characteristics across four configurations. The study highlights the challenges of adapting classical cooling module components to EV setups, emphasizing the influence of heat exchanger (HE) placement and duct geometry on noise levels and flow dynamics. The results show that the presence of the HE smooths the upstream flow, improves rotor loading distribution and disrupts long, coherent vortical structures, thereby reducing tonal noise. However, the additional resistance introduced by the HE leads to increased rotor loading and enhanced leakage flow through the shroud-rotor gap. Despite these effects, the overall sound pressure level (OASPL) remains largely unchanged, maintaining a similar magnitude and dipolar directivity pattern as the configuration without the HE. In EV modules, the inclusion of ducts introduces significant flow disturbances and localized pressure fluctuations, leading to regions of high flow rate and rotor loading. These non-uniform flow conditions excite duct modes, resulting in troughs and humps in the acoustic spectrum and potentially causing resonance at the blade-passing frequency, which increases the amplitude in the lower frequency range. Analysis of the loading force components reveals that rotor loading is primarily driven by thrust forces, while duct loading is dominated by lateral forces. Across all configurations, fluctuations at the leading and trailing edges of the rotor are observed, originating from the blade tip and extending to approximately mid-span. These fluctuations are more pronounced in the EV module, identifying it as the dominant source of pressure disturbances. The numerical results are validated against experimental data obtained in the anechoic chamber at the University of Sherbrooke and show good agreement. The relative trends are accurately predicted at lower frequencies, with slight over-prediction, and closely match the experimental data at mid-frequencies. Full article

We present systematic experimental studies of the impact of subwavelength structural geometries and electromagnetic field polarization on the resonance behavior of metallic metasurfaces at D-band frequencies. The measured influence of the photoconductive receiver antenna design in terahertz time-domain spectroscopy on the frequency-domain spectral features was analyzed. Numerical simulations reveal distinct resonance characteristics in the D-band regime, where extraordinary amplitude transmission is highly dependent on the array dimensions and field polarization orientation. The metasurface enables significant enhancements in surface electric fields and resonance response, attributed to the effective excitation of strong dipolar modes. These results demonstrate the extraordinary transmission capabilities of subwavelength metallic arrays and provide valuable insights for designing compact, low-loss, and tunable terahertz functional components needed in next-generation communications. Full article

Subradiance is a phenomenon where coupled emitters radiate light at a slower rate than independent ones. While its observation was first reported in disordered cold atom clouds, ordered subwavelength arrays of emitters have emerged as promising platforms to design highly cooperative optical properties based on dipolar interactions. In this work we characterize the eigenmodes of 2D and 3D regular arrays, using a method which can be used for both infinite and very large systems. In particular, we show how finite-size effects impact the lifetimes of these large arrays. Our results may have interesting applications for quantum memories and topological effects in ordered atomic arrays. Full article

This research focused on the synthesis of triangular silver nanoplates (TSNPs) with sharp corners using a photomediated seed growth method. The TSNPs produced had an average edge length of 27.2 ± 9.2 nm and a (110) crystalline plane structure. In terms of optical properties, the TSNPs displayed three key absorbance peaks at approximately 400 nm, 500 nm, and 660 nm, which correspond to out-of-plane dipolar resonance, in-plane quadrupolar resonance, and in-plane dipolar resonance, respectively. The prepared TSNP colloidal solutions served as surface-enhanced Raman spectroscopy (SERS)-active materials for detecting paraquat residue in aqueous samples. We optimized the mixing time of the liquid SERS with the sample, maintaining a 1:1 volume ratio. The findings showed a remarkable enhancement of the Raman signal with 10 min mixing time using laser excitation at a wavelength of 785 nm. This study achieved the development of novel SERS-active substrates capable of detecting pesticides with excellent accuracy, sensitivity, and reproducibility for both qualitative and quantitative analysis in tap water, river water, drinking water, and cannabis water. Additionally, it paved the way for using the SERS technique as a promising approach in the areas of food safety and environmental monitoring, especially in the organic farming field. Full article

The selective decomposition of formic acid to hydrogen gas represents a highly promising strategy for sustainable energy production. The influence of solvent effects on the selective decomposition of formic acid into H₂ and CO₂ or H₂O and CO was investigated. A variety of solvents, including polar protic solvents (e.g., water, ethanol, methanol), polar aprotic solvents (e.g., tetrahydrofuran, dimethyl sulfoxide), and ionic liquids, were employed in conjunction with a 5 wt% Pd/C catalyst. The yield of formic acid decomposition and the turnover number (TON) were found to be dependent on the choice of solvent. To elucidate the solvent effects, classical solvent parameters and Kamlet–Taft solvatochromic parameters were studied. The study revealed correlations between the TON and the solubility of hydrogen, Kamlet–Taft parameters (acidity, basicity, and polarity/dipolarity), hydrogen bond donor (HBD) capability, and hydrogen bond acceptor (HBA) capacity. The solvent identity was found to play a dominant role in both the polarity/dipolarity and the catalytic mechanism of formic acid decomposition. Full article

Chitosan is a biopolymer with excellent properties such as biodegradability, biocompatibility, bioactivity, and non-toxicity, making it an attractive material for various applications. In this study, to enhance these properties particularly for the development of food coatings chitosan derivatives (1,2,3-triazoles) were synthesized via microwave-assisted 1,3-dipolar cycloaddition (CuAAC) using different terminal alkynes. The resulting compounds were obtained in high yields 79.7–88.0% and characterized by vibrational (IR) and electronic (UV–Visible) spectroscopy. Films were formed by combining the derivatives with PVA and characterized using differential scanning calorimetry (DSC), tensile strength testing, and water vapor permeability analysis. The resulting films exhibited improved mechanical properties, homogeneous thicknesses, low-porosity surfaces, and favorable barrier properties, highlighting their potential applicability as food coating materials. Full article

We report the first green and diastereoselective synthesis of novel thiophene bioisosteres designed to mimic the privileged pyrrolo[3,2-c]quinoline core of martinelline alkaloids. The key step features an intramolecular 1,3-dipolar cycloaddition of in situ generated non-stabilized azomethine ylides from sarcosine, which proceeds with excellent yield and diastereoselectivity. This sustainable protocol, leveraging ultrasonic irradiation, recyclable hydrotalcite catalysts, and the green solvent cyclopentyl methyl ether (CPME), efficiently constructs the complex tricyclic framework. The structure and stereochemistry of the novel bioisostere were unambiguously confirmed by X-ray crystallography. This method offers a valuable, eco-friendly approach for diversifying natural product-inspired libraries in medicinal chemistry. Full article

Dielectric characterization offers valuable insights into fruit structure, ripening, and storage stability. However, systematic studies on apples are still limited. This work elucidates the electrical and physicochemical properties of a specific variety of apples, Malus domestica, using Electrochemical Impedance Spectroscopy (EIS), a non-destructive, fast and cost-effective technique, suitable for real-time quality assessments. The apple samples were analyzed over the frequency range of 20 Hz–120 MHz at 25 °C, and impedance data were modeled using equivalent circuits and dielectric relaxation models. Physicochemical analyses confirmed a high moisture content (84%, wwb), pH 4.81, TSS 14.58 °Brix, and acidity 0.64%, which is typical of fresh Red Delicious apples. Impedance spectra revealed semicircular and Warburg elements in Nyquist plots, indicating resistive, capacitive, and diffusive processes. Equivalent circuit fitting with the proposed R-C-Warburg impedance model outperformed (R² = 0.9946 and RMSE = 6.610) the classical Cole and Double-Shell models. The complex permittivity (ε) represented a frequency-dependent ionic diffusion, space-charge polarization, and dipolar relaxation decay, while electrical modulus analysis highlighted polarization and charge carrier dynamics. The translational hopping of charge carriers was confirmed through AC conductivity following Jonscher’s power law with an exponent of ƞ = 0.627. These findings establish a comprehensive dielectric profile and advanced circuit fitting for biological tissues, highlighting a promising non-invasive approach using EIS for real-time monitoring of fruit quality, with direct applications in post-harvest storage, supply chain management, and non-destructive quality assurance in the food industry. Full article

This study reports the synthesis, structural characterization, and electromagnetic shielding performance of tantalum (Ta)-doped nickel ferrite (NiFe₂O₄) composites reinforced with chopped strands. Ta-doped NiFe₂O₄ powders were prepared via the conventional mixed-oxide route and sintered at 1200 °C for 4 h, resulting in a well-crystallized single-phase spinel structure. Comprehensive structural and chemical analyses were carried out using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS), confirming the successful incorporation of Ta into the NiFe₂O₄ lattice and the uniform microstructural distribution. The ferrite powders were subsequently embedded with chopped strands and epoxy resin through hot pressing to fabricate composites with varying filler contents. The electromagnetic interference (EMI) shielding effectiveness (SE) of the composites was systematically evaluated in the 7–18 GHz frequency range using a network analyzer (NA). The optimized composite, with a thickness of 1.2 mm, demonstrated a maximum SE of 34.74 dB at 17.4 GHz, primarily attributed to interfacial polarization, dipolar relaxation, and multiple scattering effects induced by the chopped strands. The results indicate that the shielding performance of the composites can be precisely tuned by modifying the filler concentration and microstructural characteristics, enabling selective frequency-band applications. Overall, this work highlights the potential of Ta-doped NiFe₂O₄/chopped strand composites as lightweight, cost-effective, and high-performance candidates for advanced microwave absorption and electromagnetic shielding applications in defense, and next-generation communication technologies. Full article