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5 Pages

Octahedral Oxo-Bridged Tri-Nickel(II) Complex with 1,3,5-Tris(2-hydroxyphenyl)-2,4-diazapenta-1,3-diene

Daniil R. Bazanov,
Egor D. Korolyov,
Konstantin A. Lyssenko and
Natalia A. Lozinskaya

Molbank2025, 2025(1), M1945;https://doi.org/10.3390/M1945

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27 December 2024

An octahedral nickel(II) complex of 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,3-diene was obtained and characterized by X-ray crystallography. The organic ligand was obtained by the reaction of 2-hydroxybenzaldehyde with aqueous ammonia solution.

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Novel Synthesis of Substituted 2-Trifluoromethyl and 2-Perfluoroalkyl N-Arylpyridinium Compounds—Mechanistic Insights

Salem El Kharrat,
Philippe Laurent,
Laurent Boiteau and
Hubert Blancou

Molecules2019, 24(12), 2328;https://doi.org/10.3390/molecules24122328

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25 June 2019

We report a new one-pot synthesis of 2-trifluoromethylated/2-perfluoroalkylated N-aryl-substituted pyridiniums, 5,6,7,8-tetrahydroquinoliniums and 6,7,8,9-tetrahydro-5H-cyclohepta[b]-pyridinium compounds starting from an activated β-dicarbonyl a...

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