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9 pages, 913 KiB  
Article
Test of Diamond sCVD Detectors at High Flux of Fast Neutrons
by Leo Weissman, Asher Shor and Sergey Vaintraub
Particles 2025, 8(3), 75; https://doi.org/10.3390/particles8030075 - 7 Aug 2025
Viewed by 176
Abstract
We have tested the performance of spectroscopic single-crystal Chemical Vapor-Deposited (sCVD) diamond detectors with radioactive sources and with a pulsed deuterium-tritium neutron generator. The tests demonstrate that the detectors could provide good timing and spectroscopic information at high neutron fluxes. The spectroscopic information [...] Read more.
We have tested the performance of spectroscopic single-crystal Chemical Vapor-Deposited (sCVD) diamond detectors with radioactive sources and with a pulsed deuterium-tritium neutron generator. The tests demonstrate that the detectors could provide good timing and spectroscopic information at high neutron fluxes. The spectroscopic information can be obtained at a 14 MeV neutron rate as high as 1010 n/cm2/s, despite some limitations associated with pulse character of the used neutron generator. Monte-Carlo simulations were performed in order to achieve better understanding of neutron interaction with the detector material. Possible applications for the use of the detectors at Soreq Applied Research Accelerator Facility (SARAF) are considered. The detectors could be used as reliable neutron rate monitors in the vicinity of a strong accelerator-based source of energetic neutrons. The detectors could also be utilized as time-of-flight tagging counters in nuclear physics experiments under condition of high neutron fluxes during short beam pulses. In particular, measurement of the 12C(n,n′)3α cross-section is discussed. Full article
(This article belongs to the Section Experimental Physics and Instrumentation)
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22 pages, 6376 KiB  
Article
Components for an Inexpensive CW-ODMR NV-Based Magnetometer
by André Bülau, Daniela Walter and Karl-Peter Fritz
Magnetism 2025, 5(3), 18; https://doi.org/10.3390/magnetism5030018 - 1 Aug 2025
Viewed by 663
Abstract
Quantum sensing based on NV-centers in diamonds has been demonstrated many times in multiple publications. The majority of publications use lasers in free space or lasers with fiber optics, expensive optical components such as dichroic mirrors, or beam splitters with dichroic filters and [...] Read more.
Quantum sensing based on NV-centers in diamonds has been demonstrated many times in multiple publications. The majority of publications use lasers in free space or lasers with fiber optics, expensive optical components such as dichroic mirrors, or beam splitters with dichroic filters and expensive detectors, such as Avalanche photodiodes or single photon detectors, overall, leading to custom and expensive setups. In order to provide an inexpensive NV-based magnetometer setup for educational use in schools, to teach the three topics, fluorescence, optically detected magnetic resonance, and Zeeman splitting, inexpensive, miniaturized, off-the-shelf components with high reliability have to be used. The cheaper such a setup, the more setups a school can afford. Hence, in this work, we investigated LEDs as light sources, considered different diamonds for our setup, tested different color filters, proposed an inexpensive microwave resonator, and used a cheap photodiode with an appropriate transimpedance amplifier as the basis for our quantum magnetometer. As a result, we identified cheap and functional components and present a setup and show that it can demonstrate the three topics mentioned at a hardware cost <EUR 100. Full article
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21 pages, 8731 KiB  
Article
Individual Segmentation of Intertwined Apple Trees in a Row via Prompt Engineering
by Herearii Metuarea, François Laurens, Walter Guerra, Lidia Lozano, Andrea Patocchi, Shauny Van Hoye, Helin Dutagaci, Jeremy Labrosse, Pejman Rasti and David Rousseau
Sensors 2025, 25(15), 4721; https://doi.org/10.3390/s25154721 - 31 Jul 2025
Viewed by 346
Abstract
Computer vision is of wide interest to perform the phenotyping of horticultural crops such as apple trees at high throughput. In orchards specially constructed for variety testing or breeding programs, computer vision tools should be able to extract phenotypical information form each tree [...] Read more.
Computer vision is of wide interest to perform the phenotyping of horticultural crops such as apple trees at high throughput. In orchards specially constructed for variety testing or breeding programs, computer vision tools should be able to extract phenotypical information form each tree separately. We focus on segmenting individual apple trees as the main task in this context. Segmenting individual apple trees in dense orchard rows is challenging because of the complexity of outdoor illumination and intertwined branches. Traditional methods rely on supervised learning, which requires a large amount of annotated data. In this study, we explore an alternative approach using prompt engineering with the Segment Anything Model and its variants in a zero-shot setting. Specifically, we first detect the trunk and then position a prompt (five points in a diamond shape) located above the detected trunk to feed to the Segment Anything Model. We evaluate our method on the apple REFPOP, a new large-scale European apple tree dataset and on another publicly available dataset. On these datasets, our trunk detector, which utilizes a trained YOLOv11 model, achieves a good detection rate of 97% based on the prompt located above the detected trunk, achieving a Dice score of 70% without training on the REFPOP dataset and 84% without training on the publicly available dataset.We demonstrate that our method equals or even outperforms purely supervised segmentation approaches or non-prompted foundation models. These results underscore the potential of foundational models guided by well-designed prompts as scalable and annotation-efficient solutions for plant segmentation in complex agricultural environments. Full article
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43 pages, 10261 KiB  
Review
X-Ray and UV Detection Using Synthetic Single Crystal Diamond
by Maurizio Angelone, Francesca Bombarda, Silvia Cesaroni, Marco Marinelli, Angelo Maria Raso, Claudio Verona and Gianluca Verona-Rinati
Instruments 2025, 9(2), 9; https://doi.org/10.3390/instruments9020009 - 11 Apr 2025
Viewed by 1954
Abstract
Diamond is a semiconductor with a large band gap (5.48 eV), high carrier mobility (the highest for holes), high electrical resistance and low capacitance. Thanks to its outstanding properties, diamond-based detectors offer several advantages, among others: high signal-to-noise ratio, fast response, intrinsic pulse-shape [...] Read more.
Diamond is a semiconductor with a large band gap (5.48 eV), high carrier mobility (the highest for holes), high electrical resistance and low capacitance. Thanks to its outstanding properties, diamond-based detectors offer several advantages, among others: high signal-to-noise ratio, fast response, intrinsic pulse-shape discrimination capabilities for distinguishing different types of radiation, as well as operation in pulse and current modes. The mentioned properties meet most of the demanding requests that a radiation detection material must fulfil. Diamond detectors are suited for detecting almost all types of ionizing radiation including X-ray and UV photons, resulting also in blindness to visible photons and are used in a wide range of applications including ones requiring the capability to withstand harsh environments. After reviewing the fundamental physical properties of synthetic single crystal diamond (SCD) grown by microwave plasma enhanced chemical vapor deposition (MWPECVD) technique and the basic principles of diamond-photon interactions and detection, the paper focuses on SCD detectors developed for X-ray and UV detection, discussing their configurations, construction techniques, advantages, and drawbacks. Applications ranging from X-ray detection around accelerators to UV detection for fusion plasmas are addressed, and future trends are highlighted too. Full article
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10 pages, 2639 KiB  
Communication
A High-Performance All-Carbon Diamond Pixel Solar-Blind Detector with In Situ Converted Graphene Electrodes
by Mingxin Jiang, Zhenglin Jia, Mengting Qiu, Xingqiao Chen, Jiayi Cai, Mingyang Yang, Yi Shen, Chaoping Liu, Kuan W. A. Chee, Nan Jiang, Kazuhito Nishimura, Qingning Li, Qilong Yuan and He Li
Materials 2025, 18(6), 1222; https://doi.org/10.3390/ma18061222 - 10 Mar 2025
Viewed by 801
Abstract
Solar-blind ultraviolet detectors, known for their low background noise and high sensitivity, have garnered significant attention in various applications such as space communications, ozone layer monitoring, guidance applications, and flame detection. Pixel photodetectors, as the cornerstone of imaging technology in this field, have [...] Read more.
Solar-blind ultraviolet detectors, known for their low background noise and high sensitivity, have garnered significant attention in various applications such as space communications, ozone layer monitoring, guidance applications, and flame detection. Pixel photodetectors, as the cornerstone of imaging technology in this field, have become a focal point of research in recent years. In this work, a solar-blind photodetector with a 6 × 6 planar pixel array was fabricated on single-crystal diamond substrate, utilizing in situ conversed graphene electrodes. The graphene electrodes achieved exceptional Ohmic contact with the diamond surface, boasting a remarkably low specific contact resistance of 6.73 × 10−5 Ω·cm2. The diamond pixel detector exhibited high performance consistency with an ultra-low dark current ranging from 10−11 to 10−12 A and a photocurrent of 10−8~10−9 A under 222 nm illumination with a bias of 10 V. This work not only demonstrates the feasibility of fabricating all-carbon solar-blind photodetectors on diamond but also highlights their potential for achieving high spatial resolution in solar-blind image detection. Full article
(This article belongs to the Section Electronic Materials)
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17 pages, 4616 KiB  
Article
All-Metal Metamaterial-Based Sensor with Novel Geometry and Enhanced Sensing Capability at Terahertz Frequency
by Sagnik Banerjee, Ishani Ghosh, Carlo Santini, Fabio Mangini, Rocco Citroni and Fabrizio Frezza
Sensors 2025, 25(2), 507; https://doi.org/10.3390/s25020507 - 16 Jan 2025
Cited by 5 | Viewed by 1626
Abstract
This research proposes an all-metal metamaterial-based absorber with a novel geometry capable of refractive index sensing in the terahertz (THz) range. The structure consists of four concentric diamond-shaped gold resonators on the top of a gold metal plate; the resonators increase in height [...] Read more.
This research proposes an all-metal metamaterial-based absorber with a novel geometry capable of refractive index sensing in the terahertz (THz) range. The structure consists of four concentric diamond-shaped gold resonators on the top of a gold metal plate; the resonators increase in height by 2 µm moving from the outer to the inner resonators, making the design distinctive. This novel configuration has played a very significant role in achieving multiple ultra-narrow resonant absorption peaks that produce very high sensitivity when employed as a refractive index sensor. Numerical simulations demonstrate that it can achieve six significant ultra-narrow absorption peaks within the frequency range of 5 to 8 THz. The sensor has a maximum absorptivity of 99.98% at 6.97 THz. The proposed absorber also produces very high-quality factors at each resonance. The average sensitivity is 7.57/Refractive Index Unit (THz/RIU), which is significantly high when compared to the current state of the art. This high sensitivity is instrumental in detecting smaller traces of samples that have very correlated refractive indices, like several harmful gases. Hence, the proposed metamaterial-based sensor can be used as a potential gas detector at terahertz frequency. Furthermore, the structure proves to be polarization-insensitive and produces a stable absorption response when the angle of incidence is increased up to 60°. At terahertz wavelength, the proposed design can be used for any value of the aforementioned angles, targeting THz spectroscopy-based biomolecular fingerprint detection and energy harvesting applications. Full article
(This article belongs to the Special Issue Recent Advances in THz Sensing and Imaging)
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12 pages, 5657 KiB  
Article
Steering Mirror System with Closed-Loop Feedback for Free-Space Optical Communication Terminals
by Chris Graham, David Bramall, Othman Younus, Amna Riaz, Richard Binns, Eamon Scullion, Robert T. Wicks and Cyril Bourgenot
Aerospace 2024, 11(5), 330; https://doi.org/10.3390/aerospace11050330 - 23 Apr 2024
Cited by 5 | Viewed by 3349
Abstract
Precision beam pointing plays a critical role in free-space optical communications terminals in uplink, downlink and inter-satellite link scenarios. Among the various methods of beam steering, the use of fast steering mirrors (FSM) is widely adopted, with many commercial solutions employing diverse technologies, [...] Read more.
Precision beam pointing plays a critical role in free-space optical communications terminals in uplink, downlink and inter-satellite link scenarios. Among the various methods of beam steering, the use of fast steering mirrors (FSM) is widely adopted, with many commercial solutions employing diverse technologies, particularly focusing on small, high-bandwidth mirrors. This paper introduces a method using lightweight, commercial off-the-shelf components to construct a custom closed-loop steering mirror platform, suitable for mirror apertures exceeding 100 mm. The approach involves integrating optical encoders into two off-the-shelf open-loop actuators. These encoders read the signal reflected on purposefully diamond-machined knurled screw knobs, providing maximum contrast between light and dark lines. The resulting steering mirror has the potential to complement or replace FSM in applications requiring a larger stroke, at the expense of motion speed. In the presented setup, the mirror tilt resolution achieved based on the encoder closed-loop signal feedback is 45 μrad, with a mean slew rate of 1.5 mrad/s. Importantly, the steering assembly is self-locking, requiring no power to maintain a steady pointing angle. Using the mirror to actively correct for a constantly moving incoming beam, a 5-fold increase in concentration of the beam spot on the center of the detector was obtained compared to a fixed position mirror, demonstrating the mirrors ability to correct for satellite platform jitter and drift. Full article
(This article belongs to the Special Issue Space Telescopes & Payloads)
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15 pages, 9244 KiB  
Article
XMEA: A New Hybrid Diamond Multielectrode Array for the In Situ Assessment of the Radiation Dose Enhancement by Nanoparticles
by Patricia Nicolucci, Guilherme Gambaro, Kyssylla Monnyelle Araujo Silva, Iara Souza Lima, Oswaldo Baffa and Alberto Pasquarelli
Sensors 2024, 24(8), 2409; https://doi.org/10.3390/s24082409 - 10 Apr 2024
Cited by 1 | Viewed by 1419
Abstract
This work presents a novel multielectrode array (MEA) to quantitatively assess the dose enhancement factor (DEF) produced in a medium by embedded nanoparticles. The MEA has 16 nanocrystalline diamond electrodes (in a cell-culture well), and a single-crystal diamond divided into four quadrants for [...] Read more.
This work presents a novel multielectrode array (MEA) to quantitatively assess the dose enhancement factor (DEF) produced in a medium by embedded nanoparticles. The MEA has 16 nanocrystalline diamond electrodes (in a cell-culture well), and a single-crystal diamond divided into four quadrants for X-ray dosimetry. DEF was assessed in water solutions with up to a 1000 µg/mL concentration of silver, platinum, and gold nanoparticles. The X-ray detectors showed a linear response to radiation dose (r2 ≥ 0.9999). Overall, platinum and gold nanoparticles produced a dose enhancement in the medium (maximum of 1.9 and 3.1, respectively), while silver nanoparticles produced a shielding effect (maximum of 37%), lowering the dose in the medium. This work shows that the novel MEA can be a useful tool in the quantitative assessment of radiation dose enhancement due to nanoparticles. Together with its suitability for cells’ exocytosis studies, it proves to be a highly versatile device for several applications. Full article
(This article belongs to the Section Biosensors)
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33 pages, 11185 KiB  
Article
Evaluation of Coarse Gold-Bearing Conglomerate Mineralisation at Beatons Creek, Pilbara, Western Australia: Sampling for Resource Development and Grade Control
by Simon C. Dominy, Janice C. Graham and Ian M. Glacken
Minerals 2024, 14(4), 337; https://doi.org/10.3390/min14040337 - 25 Mar 2024
Cited by 2 | Viewed by 2243
Abstract
Many styles of gold mineralisation are challenging to sample because of the presence of coarse gold and a high spatial heterogeneity. The coarse gold-bearing conglomerates of the Beatons Creek deposit provide some challenges related to the presence of gold particles up to 8 [...] Read more.
Many styles of gold mineralisation are challenging to sample because of the presence of coarse gold and a high spatial heterogeneity. The coarse gold-bearing conglomerates of the Beatons Creek deposit provide some challenges related to the presence of gold particles up to 8 mm and gold particle clusters (up to 500 mm3) at low in situ grades (<2 g/t Au). Novo has attempted to address these issues over the last six years of exploration, resource development and mining. The Beatons Creek open pit operation was the first Pilbara conglomerate-hosted gold deposit to go into production. Between January 2021 and September 2022, it produced 2.5 Mt at 1.2 g/t Au for 87,300 oz Au recovered. Gold is present within a matrix of multiple, narrow-stacked oxide and fresh (sulphide) conglomeritic reef horizons, which are interbedded with unmineralised conglomerate, sandstones and grits. It is strongly associated with detrital pyrite and authigenic nodules. Several sampling techniques have been applied across the project, including diamond core and RC drilling, trench channel sampling and bulk sampling. Assay methods applied include fire assay, screen fire assay, LeachWELL™ and more recently PhotonAssay™. The dominant sampling protocol applied for resource development and grade control utilised 0.5 m length RC samples; a 50% rig split (c. 8.5 kg) and laboratory crushing to 3 mm, followed by a 2.5 kg split and total assay via PhotonAssay™. For part of the 2022 RC programme, the detectORE™ technique was used to screen primary RC samples and reduce the feed to the laboratory. Novo operated a sampling and assay programme that aimed to reduce the impact of coarse gold on sample and assay preparation biases and to improve estimation. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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36 pages, 5342 KiB  
Review
Diamond for High-Power, High-Frequency, and Terahertz Plasma Wave Electronics
by Muhammad Mahmudul Hasan, Chunlei Wang, Nezih Pala and Michael Shur
Nanomaterials 2024, 14(5), 460; https://doi.org/10.3390/nano14050460 - 1 Mar 2024
Cited by 14 | Viewed by 5319
Abstract
High thermal conductivity and a high breakdown field make diamond a promising candidate for high-power and high-temperature semiconductor devices. Diamond also has a higher radiation hardness than silicon. Recent studies show that diamond has exceptionally large electron and hole momentum relaxation times, facilitating [...] Read more.
High thermal conductivity and a high breakdown field make diamond a promising candidate for high-power and high-temperature semiconductor devices. Diamond also has a higher radiation hardness than silicon. Recent studies show that diamond has exceptionally large electron and hole momentum relaxation times, facilitating compact THz and sub-THz plasmonic sources and detectors working at room temperature and elevated temperatures. The plasmonic resonance quality factor in diamond TeraFETs could be larger than unity for the 240–600 GHz atmospheric window, which could make them viable for 6G communications applications. This paper reviews the potential and challenges of diamond technology, showing that diamond might augment silicon for high-power and high-frequency compact devices with special advantages for extreme environments and high-frequency applications. Full article
(This article belongs to the Special Issue Advances in Nanotechnology for RF and Terahertz)
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16 pages, 1760 KiB  
Review
FLASH Radiotherapy and the Use of Radiation Dosimeters
by Sarkar Siddique, Harry E. Ruda and James C. L. Chow
Cancers 2023, 15(15), 3883; https://doi.org/10.3390/cancers15153883 - 30 Jul 2023
Cited by 33 | Viewed by 5120
Abstract
Radiotherapy (RT) using ultra-high dose rate (UHDR) radiation, known as FLASH RT, has shown promising results in reducing normal tissue toxicity while maintaining tumor control. However, implementing FLASH RT in clinical settings presents technical challenges, including limited depth penetration and complex treatment planning. [...] Read more.
Radiotherapy (RT) using ultra-high dose rate (UHDR) radiation, known as FLASH RT, has shown promising results in reducing normal tissue toxicity while maintaining tumor control. However, implementing FLASH RT in clinical settings presents technical challenges, including limited depth penetration and complex treatment planning. Monte Carlo (MC) simulation is a valuable tool for dose calculation in RT and has been investigated for optimizing FLASH RT. Various MC codes, such as EGSnrc, DOSXYZnrc, and Geant4, have been used to simulate dose distributions and optimize treatment plans. Accurate dosimetry is essential for FLASH RT, and radiation detectors play a crucial role in measuring dose delivery. Solid-state detectors, including diamond detectors such as microDiamond, have demonstrated linear responses and good agreement with reference detectors in UHDR and ultra-high dose per pulse (UHDPP) ranges. Ionization chambers are commonly used for dose measurement, and advancements have been made to address their response nonlinearities at UHDPP. Studies have proposed new calculation methods and empirical models for ion recombination in ionization chambers to improve their accuracy in FLASH RT. Additionally, strip-segmented ionization chamber arrays have shown potential for the experimental measurement of dose rate distribution in proton pencil beam scanning. Radiochromic films, such as GafchromicTM EBT3, have been used for absolute dose measurement and to validate MC simulation results in high-energy X-rays, triggering the FLASH effect. These films have been utilized to characterize ionization chambers and measure off-axis and depth dose distributions in FLASH RT. In conclusion, MC simulation provides accurate dose calculation and optimization for FLASH RT, while radiation detectors, including diamond detectors, ionization chambers, and radiochromic films, offer valuable tools for dosimetry in UHDR environments. Further research is needed to refine treatment planning techniques and improve detector performance to facilitate the widespread implementation of FLASH RT, potentially revolutionizing cancer treatment. Full article
(This article belongs to the Topic Recent Advances in Anticancer Strategies)
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40 pages, 13678 KiB  
Review
Deep Ultraviolet Photodetector: Materials and Devices
by Wannian Fang, Qiang Li, Jiaxing Li, Yuxuan Li, Qifan Zhang, Ransheng Chen, Mingdi Wang, Feng Yun and Tao Wang
Crystals 2023, 13(6), 915; https://doi.org/10.3390/cryst13060915 - 5 Jun 2023
Cited by 27 | Viewed by 7297
Abstract
The application of deep ultraviolet detection (DUV) in military and civil fields has increasingly attracted the attention of researchers’ attention. Compared with the disadvantages of organic materials, such as complex molecular structure and poor stability, inorganic materials are widely used in the field [...] Read more.
The application of deep ultraviolet detection (DUV) in military and civil fields has increasingly attracted the attention of researchers’ attention. Compared with the disadvantages of organic materials, such as complex molecular structure and poor stability, inorganic materials are widely used in the field of DUV detection because of their good stability, controllable growth, and other characteristics. Rapid advances in preparing high-quality ultrawide-bandgap (UWBG) semiconductors have enabled the realization of various high-performance DUV photodetectors with different geometries, which provide an avenue for circumventing numerous disadvantages in traditional detectors. Herein, the development history and types of DUV detectors are briefly introduced. Typical UWBG detection materials and their preparation methods, as well as their research and application status in the field of DUV detection, are emphatically summarized and reviewed, including III-nitride semiconductors, gallium oxide, diamond, etc. Finally, problems pertaining to DUV detection materials, such as the growth of materials, the performance of devices, and their future development, are also discussed. Full article
(This article belongs to the Special Issue Wide-Bandgap Semiconductors)
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66 pages, 52190 KiB  
Review
Ultraviolet Photodetectors: From Photocathodes to Low-Dimensional Solids
by Antoni Rogalski, Zbigniew Bielecki, Janusz Mikołajczyk and Jacek Wojtas
Sensors 2023, 23(9), 4452; https://doi.org/10.3390/s23094452 - 2 May 2023
Cited by 51 | Viewed by 11010
Abstract
The paper presents the long-term evolution and recent development of ultraviolet photodetectors. First, the general theory of ultraviolet (UV) photodetectors is briefly described. Then the different types of detectors are presented, starting with the older photoemission detectors through photomultipliers and image intensifiers. More [...] Read more.
The paper presents the long-term evolution and recent development of ultraviolet photodetectors. First, the general theory of ultraviolet (UV) photodetectors is briefly described. Then the different types of detectors are presented, starting with the older photoemission detectors through photomultipliers and image intensifiers. More attention is paid to silicon and different types of wide band gap semiconductor photodetectors such as AlGaN, SiC-based, and diamond detectors. Additionally, Ga2O3 is considered a promising material for solar-blind photodetectors due to its excellent electrical properties and a large bandgap energy. The last part of the paper deals with new UV photodetector concepts inspired by new device architectures based on low-dimensional solid materials. It is shown that the evolution of the architecture has shifted device performance toward higher sensitivity, higher frequency response, lower noise, and higher gain-bandwidth products. Full article
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12 pages, 1806 KiB  
Article
First Characterization of Novel Silicon Carbide Detectors with Ultra-High Dose Rate Electron Beams for FLASH Radiotherapy
by Francesco Romano, Giuliana Milluzzo, Fabio Di Martino, Maria Cristina D’Oca, Giuseppe Felici, Federica Galante, Alessia Gasparini, Giulia Mariani, Maurizio Marrale, Elisabetta Medina, Matteo Pacitti, Enrico Sangregorio, Verdi Vanreusel, Dirk Verellen, Anna Vignati and Massimo Camarda
Appl. Sci. 2023, 13(5), 2986; https://doi.org/10.3390/app13052986 - 25 Feb 2023
Cited by 26 | Viewed by 3913
Abstract
Ultra-high dose rate (UHDR) beams for FLASH radiotherapy present significant dosimetric challenges. Although novel approaches for decreasing or correcting ion recombination in ionization chambers are being proposed, applicability of ionimetric dosimetry to UHDR beams is still under investigation. Solid-state sensors have been recently [...] Read more.
Ultra-high dose rate (UHDR) beams for FLASH radiotherapy present significant dosimetric challenges. Although novel approaches for decreasing or correcting ion recombination in ionization chambers are being proposed, applicability of ionimetric dosimetry to UHDR beams is still under investigation. Solid-state sensors have been recently investigated as a valuable alternative for real-time measurements, especially for relative dosimetry and beam monitoring. Among them, Silicon Carbide (SiC) represents a very promising candidate, compromising between the maturity of Silicon and the robustness of diamond. Its features allow for large area sensors and high electric fields, required to avoid ion recombination in UHDR beams. In this study, we present simulations and experimental measurements with the low energy UHDR electron beams accelerated with the ElectronFLASH machine developed by the SIT Sordina company (IT). The response of a newly developed 1 × 1 cm2 SiC sensor in charge as a function of the dose-per-pulse and its radiation hardness up to a total delivered dose of 90 kGy, was investigated during a dedicated experimental campaign, which is, to our knowledge, the first characterization ever done of SiC with UHDR-pulsed beams accelerated by a dedicated ElectronFLASH LINAC. Results are encouraging and show a linear response of the SiC detector up to 2 Gy/pulse and a variation in the charge per pulse measured for a cumulative delivered dose of 90 kGy, within ±0.75%. Full article
(This article belongs to the Special Issue Detectors for Medical Physics)
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16 pages, 3963 KiB  
Article
Fourier Transform Infrared Spectroscopy to Assess the Degree of Alteration of Artificially Aged and Environmentally Weathered Microplastics
by Claudia Campanale, Ilaria Savino, Carmine Massarelli and Vito Felice Uricchio
Polymers 2023, 15(4), 911; https://doi.org/10.3390/polym15040911 - 11 Feb 2023
Cited by 114 | Viewed by 15752
Abstract
Fourier transform infrared (FTIR) is a spectroscopy technique widely used to identify organic materials. It has recently gained popularity in microplastic (MP) pollution research to determine the chemical composition of unknown plastic fragments. However, it could also be used to evaluate the degree [...] Read more.
Fourier transform infrared (FTIR) is a spectroscopy technique widely used to identify organic materials. It has recently gained popularity in microplastic (MP) pollution research to determine the chemical composition of unknown plastic fragments. However, it could also be used to evaluate the degree of ageing of MPs collected from the environment. In this context, the principal aim of our research has been to qualitatively evaluate the natural weathering of environmental MPs collected in an Italian freshwater body (the Ofanto River) using ATR-FTIR technology. Furthermore, we compared environmental particles to weathered artificial MPs under controlled light and temperature conditions and to unaltered pristine materials to assess the results. FTIR spectra were acquired using a Nicolet Summit FTIR (ThermoFisher Scientific) equipped with an Everest ATR with a diamond Crystal plate and a DTGS KBr detector (wavenumber range 4000–500 cm−1, 32 scans per spectrum, spectral resolution of 4 cm−1). The degree of ageing was assessed using three different indexes known to be related to changes in MPs: Carbonyl Index (CI), Hydroxyl Index (HI), and Carbon-Oxygen Index (COI). The overall results showed that the regions reflecting changes (hydroxyl groups, peaks from 3100 to 3700 cm−1, alkenes or carbon double bonds, 1600 and 1680 cm−1, and carbonyl groups, 1690 and 1810 cm−1) appeared significantly modified in artificial and natural weathered particles compared to the pristine materials. The indexes calculated for polymers degraded under the artificial photo and thermo ageing conditions displayed a general tendency to increase with the time in contact with irradiation time. Particular enhancements of CI of PS fragment and PE pellet, HI of PE and PS fragments and PE pellet, and COI of PS fragment were observed. Otherwise, the following incubation of the same particles at a constant temperature of 45 °C did not further affect the chemical composition of the particles. Moreover, new unique peaks were also observed in the freshwater particles, almost all in the fingerprint region (1500–500 cm−1). Differences in CI, HI, and COI were evidenced among the different morphological MP shapes. On the one hand, the CI calculated for the environmental PE pellets showed values ranging from 0.05 to 0.26 with a mean value of 0.17 ± 0.10. Most samples (57%) presented a CI with values between 0.16 and 0.30. On the other hand, fragments presented slicer modifications in the carbonyl region with CI values lower than pellets (0.05 ± 0.05). This index helps evaluate the degradation of PE MPs by UV light, increasing with enhancing residence time in the environment. Conversely, fragments showed greater values of HI (5.90 ± 2.57) and COI (1.04 ± 0.48) than pellets, as well as lines, which presented the maximum value of HI (11.51). HI is attributed to the bond vibrations of hydroxyl, carboxyl, or phenol groups. In contrast, COI is frequently attributed to the vibrations of C_O bonds found in carbohydrates, alkanes, secondary alcohols, and ketones. In conclusion, our results showed characteristics spectra acquired from environmental particles compared to pristine and artificial aged ones. The interpretation of our main results emphasizes the need to conduct ecotoxicological experimental studies using naturally weathered particles due to the unicity of their properties, which are more helpful for understanding microplastic pollution effects. Full article
(This article belongs to the Special Issue Polymer Degradation and Its Environmental Impacts)
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