Search Results (17)

Large-scale dense-phase carbon dioxide (CO₂) injection is an energy-intensive process in the carbon capture, utilization, and storage (CCUS) value chain. To address insufficient utilization of inlet pressure potential energy and sealing/friction losses of conventional reciprocating pumps under high-base-pressure dense-phase CO₂ transport conditions, this study develops a dense-phase CO₂-oriented structural optimization scheme for a hydraulically driven opposed-piston reciprocating pump based on force-coupling. A dynamic model was established to clarify the in situ recovery mechanism by which inlet pressure potential energy is converted into auxiliary thrust, enabling the drive load to shift from absolute pressure to net pressure difference. Simulation results show that under the rated 8 MPa inlet and 25 MPa discharge condition, the optimized opposed-piston configuration reduces peak driving oil pressure by 31.39% compared with the non-opposed reference configuration. Field reliability operation data show an average normalized specific energy consumption of 0.422 kWh/(MPa·m³) during the selected 24 h continuous operating period. The optimized configuration improves inlet-pressure utilization and reduces hydraulic power demand under high-base-pressure dense-phase CO₂ injection conditions, providing theoretical support and engineering reference for low-energy CCUS injection systems. Full article

Polyvinyl alcohol (PVA) is used in various fields; however, its highly flammable property greatly limits its application. In order to improve the flame-retardant properties of PVA, one method is by adding flame retardants directly, while another method is through grafting, cross-linking and hydrogen bonding. A flame retardant, 9, 10-dihydro-9, 10-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-vinyltrimethoxysilane (VTES), was synthesized through the addition reaction of a P–H bond on the DOPO and unsaturated carbon–carbon double bonds on the VTES. Then, the DOPO-VTES and zirconium phosphate (α-ZrP) were blended with PVA to cast a film, in which DOPO-VTES was grafted onto the PVA by cross-linking the hydroxyl group in the molecular structure of DOPO-VTES with the hydroxyl group in PVA; α-ZrP was used as a cooperative agent of DOPO-VTES. The cone calorimetry test (CCT) showed a significant reduction in both the heat release rate (HRR) and total heat release rate (THR) for the flame-retardant PVA films compared to pure PVA. Additionally, thermogravimetric analysis (TGA) revealed a higher residual char content in the flame-retardant PVA films than in pure PVA. These findings suggested that the combination of DOPO-VTES and α-ZrP could improve the flame retardancy of PVA. The cooperative flame-retardant mode of action at play was possibly that DOPO in the DOPO-VTES acted as a mainly gas-phase flame retardant, which yielded a PO radical; VTES in the DOPO-VTES produced silicon dioxide (SiO₂), which acted as a thermal insulator; and α-ZrP catalyzed the carbonization of the PVA. By combining DOPO-VTES with α-ZrP, a continuous dense carbon layer was formed, which effectively inhibited oxygen and heat exchange, resulting in a flame-retardant effect. It is expected that flame-retardant films for PVA have a broad development prospect and potential in the fields of packaging materials, electronic appliances, and lithium-ion battery separators. Full article

Diesel-engine Heavy-Duty Vehicle (HDV) exhaust gas mixture contains pollutants including unburned hydrocarbons, carbon monoxide, nitrogen oxides, and particulate matter. A catalyst-based emission control system is commonly used to eliminate the above pollutants. However, the excess of oxygen that exists in the exhaust gasses of diesel engines hinders the efficient and selective reduction of nitrogen oxides over conventional catalytic converters. The AdBlue^® solution, which is currently used to eliminate nitrogen oxides, is based on ammonia. The latter is toxic in high concentrations. The aim of this work is to develop an Oxygen Reduction System (ORS) to remove oxygen from the exhaust gas of diesel engines, allowing the successful catalytic reduction of nitrogen oxides on a reduction catalyst without the need for ammonia. The ORS device consists of dense composite dual-phase membranes that allow the permeation of oxygen and carbon dioxide. Even though the oxygen concentration gradient across the membranes favors oxygen spontaneous diffusion from the atmosphere to the exhaust gas, the carbonate ion-based technology proposed herein utilizes the big difference in the concentration of carbon dioxide across the membrane to remove oxygen without any power consumption requirement. The results of this study are promising for the application of O₂ reduction in diesel HDVs. Full article

With the continuous exploitation of offshore natural gas, the content of CO₂ produced gradually increases. It is not economical to separate more CO₂ from natural gas after transportation, and more CO₂ will aggravate the corrosion of pipelines. The commonly used decarburization process is not suitable for offshore platforms, and there are problems of high energy consumption and large space occupation. Therefore, dense phase separation of associated gas with high carbon dioxide content is a better separation method. In this paper, the equation of state is optimized by comparing the experimental and CO₂ system phase characteristics simulation. Based on the selected equation of state (EOS), a three-level separation model of phase equilibrium characteristics is established. The separation efficiency is simulated to complete the separation of CO₂ and methane. The separation process is optimized by a genetic algorithm, and the temperature and pressure under the best separation efficiency are determined. The PR-EOS was selected as the equation with the highest calculation accuracy. Through process simulation and algorithm optimization, the best separation efficiency was 72.23%. Full article

This research explores the two-phase flow behavior involved in enhanced dense phase carbon dioxide inactivation of E. coli DH5α, which has been shown to possess a high microbial reduction efficiency of up to 3.7 ± 0.4 log. We present an experiment in which the liquid sample was pressurized with liquid carbon dioxide to 8.2 MPa and, after saturation, was forced to flow through a mini tube. An experimental setup was developed to visualize the flow patterns (plug, slug and churn flows) occurring in the mini tube by means of high-speed imaging. The values of the wall shear stress were estimated within the mini tube with the help of the gas slug velocities (8–9 m/s) and were compared with threshold shear stress values reported for the disruption of fresh E. coli cells. The results suggest that the preliminary pressurization phase may cause a substantial destabilization of the cell wall of E. coli DH5α. Full article

Complex wells with high temperature and the presence of carbon dioxide and hydrogen sulfide acid gas require the use of high-temperature and high-density anti-corrosion cement slurry for cementing operations, and conventional cement slurry does not have the advantages of high density, high-temperature resistance, or corrosion resistance. In order to avoid the severe corrosion of cement slurry by carbon dioxide and hydrogen sulfide at high temperatures, solid phase particles with different particle sizes are combined with polymer materials to form a dense, high-density, high-temperature- and corrosion-resistant cement slurry. In this paper, we consider the use of manganese ore powder weighting agent, composite high-temperature stabilizer, inorganic preservative slag and organic preservative resin to improve the corrosion resistance of cement slurry, design a high-density cement slurry that is resistant to high temperature and carbon dioxide and hydrogen sulfide corrosion, and evaluate the performances of the cement slurry at 180 °C. The results show that the manganese ore powder weighting agent effectively improves the density of the cement slurry. Using composite silica fume with different particle sizes as a high-temperature stabilizer can ensure the rheology of the cement slurry and improve the ability of the cement sample to resist high-temperature damage. The use of slag and resin as preservatives can effectively reduce the corrosion degree in cement slurry. The high-temperature corrosion-resistant cement slurry systems with different densities designed using these materials exhibit good rheological properties, with water loss of less than 50 mL and a thickening time of more than four hours. The compressive strength decreased by less than 5.8% after 28 days at high temperatures. After being corroded by hydrogen sulfide and carbon dioxide (total pressure 30 MPa, 16.7% hydrogen sulfide and 6.7% carbon dioxide) under high temperature (180 °C) for 30 days, the corrosion depth of the cement sample was less than 2 mm, the reduction of compressive strength was low, and the corrosion resistance was strong. These research results can be used for cementing operations of high-temperature oil and gas wells containing hydrogen sulfide and dioxide. Full article

The relationship between the gel quality of golden pompano surimi treated with dense phase carbon dioxide (DPCD) and changes in water characteristics was evaluated. Low-field nuclear magnetic resonance (LF-NMR) and nuclear magnetic resonance imaging were used to monitor changes in the water status of surimi gel under different treatment conditions. Whiteness, water-holding capacity and gel strength were used as the quality indicators of the surimi gel. The results showed that DPCD treatment could significantly increase the whiteness of surimi and the strength of the gel, while the water-holding capacity decreased significantly. LF-NMR analysis showed that, as the DPCD treatment intensity increased, the relaxation component T₂₂ shifted to the right, T₂₃ shifted to the left, the proportion of A₂₂ decreased significantly (p < 0.05) and the proportion of A₂₃ increased significantly (p < 0.05). A correlation analysis of water characteristics and gel strength showed that the water-holding capacity of surimi induced by DPCD was strongly positively correlated with gel strength, while A₂₂ and T₂₃ were strongly negatively correlated with gel strength. This study provides helpful insights into the quality control of DPCD in surimi processing and also provides an approach for the quality evaluation and detection of surimi products. Full article

Surface cleaning of plastic materials of historical value can be challenging due to the high risk of inducing detrimental effects and visual alterations. As a result, recent studies have focused on researching new approaches that might reduce the associated hazards and, at the same time, minimize the environmental impact by employing biodegradable and green materials. In this context, the present work investigates the effects and potential suitability of dense carbon dioxide (CO₂) as an alternative and green solvent for cleaning plastic materials of historical value. The results of extensive trials with CO₂ in different phases (supercritical, liquid, and vapor) and under various conditions (pressure, temperature, exposure, and depressurization time) are reported for new, transparent, thick poly(methyl methacrylate) (PMMA) samples. The impact of CO₂ on the weight, the appearance of the samples (dimensions, color, gloss, and surface texture), and modifications to their physicochemical and mechanical properties were monitored via a multi-analytical approach that included optical microscopy, Raman and attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopies, and micro-indentation (Vickers hardness). Results showed that CO₂ induced undesirable and irreversible changes in PMMA samples (i.e., formation of fractures and stress-induced cracking, drastic decrease in the surface hardness of the samples), independent of the conditions used (i.e., temperature, pressure, CO₂ phase, and exposure time). Full article

Dense phase carbon dioxide (DPCD) is a new non-thermal method to induce surimi gel. However, the gel quality is affected by many factors, such as DPCD treatment time, temperature, and pressure, which makes it complicated to determine its operating parameters. Box-Behnken and backward linear regression were used to optimize the conditions (temperature, pressure, and treatment time) of DPCD-induced shrimp surimi gel formation, and a model between shrimp surimi gel strength and treatment conditions was developed and validated in the present study. Meanwhile, the heat-induced method was used as a control to analyze the effect of DPCD on the quality of shrimp surimi gel in the present study. The results showed that DPCD treatment affected the strength of shrimp surimi gel significantly, and the pressure of DPCD had the greatest influence on the gel strength of shrimp surimi, followed by time and temperature. When the processing pressure was 30 MPa, the temperature was 55 °C, and the treatment time was 60 min, the gel strength of the shrimp surimi was as high as 197.35 N·mm, which was not significantly different from the simulated value of 198.28 N mm (p > 0.05). The results of the gel quality properties showed that, compared with the heat-induced method, DPCD reduced the nutrient and quality loss of the shrimp surimi gel, and increased the gel strength and gel water-holding capacity. The results of low-field nuclear magnet resonance showed that DPCD increased the binding capacity of shrimp surimi to bound water and immobilized water, and reduced their losses. Gel microstructure further demonstrated that DPCD could improve shrimp surimi gelation properties, characterized by a finer and uniformly dense gel network structure. In summary, DPCD is a potential method for inducing shrimp surimi to form a suitable gel. The prediction model established in this study between DPCD treatment temperature, pressure, time, and gel strength can provide a reference for the production of shrimp surimi by DPCD. Full article

Dense-phase carbon dioxide (DPCD), a novel non-thermal processing technology, has attracted extensive attention due to its excellent performance in food sterilization and enzyme inactivation without quality deterioration. In this work, we aimed to extend the shelf life of quark cheese with DPCD and explore the effect of DPCD treatment as well as storage time on the quality of quark cheese. The sterilization parameters were optimized by means of orthogonal experiments, and the physiochemical, rheological, microstructural and volatile properties of cheese were investigated. The optimal DPCD treatment (20 MPa, 45 min, 55 °C) successfully extended the shelf life of quark cheese due to its inhibition effect on yeast and was able to slow down the proteolysis and alterations in pH and color of cheese. Cheese processed using DPCD after 14-day storage even displayed similar rheological properties to the control at day 0, from which bound water significantly migrated during storage. Moreover, DPCD contributed to the retention of the volatile profile of cheese during storage. This study demonstrated that DPCD is a promising pasteurization technology for quark cheese to improve its quality stability during storage. Full article

Bioactive peptides (BPs) derived from animal and plant proteins are important food functional ingredients with many promising health-promoting properties. In the food industry, enzymatic hydrolysis is the most common technique employed for the liberation of BPs from proteins in which conventional heat treatment is used as pre-treatment to enhance hydrolytic action. In recent years, application of non-thermal food processing technologies such as ultrasound (US), high-pressure processing (HPP), and pulsed electric field (PEF) as pre-treatment methods has gained considerable research attention owing to the enhancement in yield and bioactivity of resulting peptides. This review provides an overview of bioactivities of peptides obtained from animal and plant proteins and an insight into the impact of US, HPP, and PEF as non-thermal treatment prior to enzymolysis on the generation of food-derived BPs and resulting bioactivities. US, HPP, and PEF were reported to improve antioxidant, angiotensin-converting enzyme (ACE)-inhibitory, antimicrobial, and antidiabetic properties of the food-derived BPs. The primary modes of action are due to conformational changes of food proteins caused by US, HPP, and PEF, improving the susceptibility of proteins to protease cleavage and subsequent proteolysis. However, the use of other non-thermal techniques such as cold plasma, radiofrequency electric field, dense phase carbon dioxide, and oscillating magnetic fields has not been examined in the generation of BPs from food proteins. Full article

Carbon capture and storage is considered an effective mitigation strategy to reduce the most challenging emissions from heavy industries and gas processing. The safe transport of carbon dioxide via pipelines is an important aspect for developing large-scale Carbon Capture and Storage projects. Dispersion modeling for heavy gas such as carbon dioxide is considerably different from natural gas. The set up for modeling simulations is more challenging than conventional natural gas pipeline for several reasons, such as the differences in thermodynamics that must be considered. Moreover, when the carbon dioxide is transported in dense or liquid phase, the rapid phase changing, and possible consequent formation of solids should be considered. Finally, the equation of state required for accurate prediction of parameters is generally different than the ones applicable for natural gas. The main scope of this comprehensive review is to identify the most important parameters, critical events, suitable models, and identification of dispersion modeling issues. An extensive literature review of experiments conducted in the last ten years has been developed, experimental data, integral and simplified model, as well as CFD modeling issues has been identified and reported in the work proposed to highlight the advances and the gaps that could need further research activities. Full article

Chemical doping of ceramic oxides may provide a possible route for realizing high-efficient oxygen transport membranes. Herein, we present a study of the previously unreported dual-phase mixed-conducting oxygen-permeable membranes with the compositions of 60 wt.% Ce_0.85Pr_0.1M_0.05O_2-δ-40 wt.%Pr_0.6Sr_0.4Fe_0.8Al_0.2O_3-δ (M = Fe, Co, Ni, Cu) (CPM-PSFA) adding sintering aids, which is expected to not only improve the electronic conductivity of fluorite phase, but also reduce the sintering temperature and improve the sintering properties of the membranes. X-ray powder diffraction (XRD) results indicate that the CPM-PSFA contain only the fluorite and perovskite two phases, implying that they are successfully prepared with a modified Pechini method. Backscattered scanning electron microscopy (BSEM) results further confirm that two phases are evenly distributed, and the membranes are very dense after sintering at 1275 °C for 5 h, which is much lower than that (1450 °C, 5 h) of the composite 60 wt.%Ce_0.9Pr_0.1O_2-δ-40 wt.%Pr_0.6Sr_0.4Fe_0.8Al_0.2O_3-δ (CP-PSFA) without sintering aids. The results of oxygen permeability test demonstrate that the oxygen permeation flux through the CPCu-PSFA and CPCo-PSFA is higher than that of undoped CP-PSFA and can maintain stable oxygen permeability for a long time under pure CO₂ operation condition. Our results imply that these composite membranes with high oxygen permeability and stability provide potential candidates for the application in oxygen separation, solid oxide fuel cell (SOFC), and oxy-fuel combustion based on carbon dioxide capture. Full article

Fifth generation (5G) and Beyond-5G (B5G) will be characterized by highly dense deployments, both on network plane and user plane. Internet of Things, massive sensor deployments and base stations will drive even more energy consumption. User behavior towards mobile service usage is witnessing a paradigm shift with heavy capacity, demanding services resulting in an increase of both screen time and data transfers, which leads to additional power consumption. Mobile network operators will face additional energetic challenges, mainly related to power consumption and network sustainability, starting right in the planning phase with concepts like energy efficiency and greenness by design coming into play. The main contribution of this work is a two-tier method to address such challenges leading to positively-offset carbon dioxide emissions related to mobile networks using a novel approach. The first tier contributes to overall power reduction and optimization based on energy efficient methods applied to 5G and B5G networks. The second tier aims to offset the remaining operational power usage by completely offsetting its carbon footprint through geosequestration. This way, we show that the objective of minimizing overall networks’ carbon footprint is achievable. Conclusions are drawn and it is shown that carbon sequestration initiatives or program adherence represent a negligible cost impact on overall network cost, with the added value of greener and more environmentally friendly network operation. This can also relieve the pressure on mobile network operators in order to maximize compliance with environmentally neutral activity. Full article

Depleted gas reservoirs are appealing targets for carbon dioxide (CO ${}_2$ ) sequestration because of their storage capacity, proven seal, reservoir characterization knowledge, existing infrastructure, and potential for enhanced gas recovery. Low abandonment pressure in the reservoir provides additional voidage-replacement potential for CO ${}_2$ and allows for a low surface pump pressure during the early period of injection. However, the injection process poses several challenges. This work aims to raise awareness of key operational challenges related to CO ${}_2$ injection in low-pressure reservoirs and to provide a new approach to assessing the phase behavior of CO ${}_2$ within the wellbore. When the reservoir pressure is below the CO ${}_2$ bubble-point pressure, and CO ${}_2$ is injected in its liquid or supercritical state, CO ${}_2$ will vaporize and expand within the well-tubing or in the near-wellbore region of the reservoir. This phenomenon is associated with several flow assurance problems. For instance, when CO ${}_2$ transitions from the dense-state to the gas-state, CO ${}_2$ density drops sharply, affecting the wellhead pressure control and the pressure response at the well bottom-hole. As CO ${}_2$ expands with a lower phase viscosity, the flow velocity increases abruptly, possibly causing erosion and cavitation in the flowlines. Furthermore, CO ${}_2$ expansion is associated with the Joule–Thomson (IJ) effect, which may result in dry ice or hydrate formation and therefore may reduce CO ${}_2$ injectivity. Understanding the transient multiphase phase flow behavior of CO ${}_2$ within the wellbore is crucial for appropriate well design and operational risk assessment. The commonly used approach analyzes the flow in the wellbore without taking into consideration the transient pressure response of the reservoir, which predicts an unrealistic pressure gap at the wellhead. This pressure gap is related to the phase transition of CO ${}_2$ from its dense state to the gas state. In this work, a new coupled approach is introduced to address the phase behavior of CO ${}_2$ within the wellbore under different operational conditions. The proposed approach integrates the flow within both the wellbore and the reservoir at the transient state and therefore resolves the pressure gap issue. Finally, the energy costs associated with a mitigation process that involves CO ${}_2$ heating at the wellhead are assessed. Full article