Search Results (102)

As a result of long-term groundwater overexploitation, the thickness of the vadose zone in the NCP has significantly increased, leading to changes in moisture transport patterns and groundwater recharge processes. This research gathers data on soil water potential and moisture content by conducting in situ profile monitoring of a 30.4 m thick vadose zone. A 44.5 m geological borehole was drilled for the purpose of measuring the hydraulic parameters of undisturbed soil samples, collecting ³⁶Cl isotope tracer samples, and constructing a coupling model of the unsaturated–saturated zone with a depth of 47 m. The research objectives were to examine the moisture transport law and infiltration recharge mechanisms in deep vadose zones. Comprehensive analysis shows that the average infiltration velocity is 0.661–0.743 m/a and the average recharge intensity is 103.1–115.9 mm/a. The depth and silty clay play an important role in affecting the infiltration process. The characteristics of infiltration can be divided into three segments: rapid, slow, and stagnant. The residual pore gases in the clay strata have a certain inhibitory effect on moisture transport. The time required for precipitation infiltration is 75.14 years for a 44.5 m thick vadose zone; thereafter, new water replaces old water to continue recharging the aquifer. In recent years, the government has taken multiple actions to alleviate this continuous downward trend in groundwater levels, including river ecological flow replenishment and groundwater extraction reduction. Additionally, increased precipitation since 2021 has objectively halted the previous thickening trend of the vadose zone. It is recommended to further strengthen groundwater resource management and enhance groundwater-level monitoring and warning to prevent further declines. This research holds significant implications for the evaluation and sustainable management of groundwater resources in large-scale plains in semi-humid areas. Full article

Reliable surveillance of dissolved ²²²Rn in arid-region aquifers is challenged by very low natural activity and method-dependent biases, especially humidity sensitivity in electrostatic detectors and air–water partitioning during closed-loop aeration, which can obscure true concentrations needed for defensible drinking-water baselines under preventive frameworks. This study aimed to optimize and field-validate a low-background RAD7 Big-Bottle (RAD H₂O) closed-loop protocol tailored for arid conditions and apply it in a regional survey of groundwater used for potable supply in northeastern Saudi Arabia. Groundwater from wells across the region (shallow and deep completions) was collected and analyzed using isotope-resolved alpha spectroscopy (Po-218 and Po-214 windows) with strict chamber humidity control (≤7% RH), background checks, systematic blanks, duplicates, drift control (±10%), and uncertainty propagation. Air-phase chamber counts were mandatorily converted to water-phase activity using the CAPTURE parameterized by measured loop volumes, temperature, salinity, and humidity, and agreement was evaluated using regression diagnostics and Bland–Altman analysis. The optimized method achieved sub-Bq·L⁻¹ performance, with MDL improving from ~0.1645 Bq·L⁻¹ (30 min) to ~0.0233 Bq·L⁻¹ (1500 min) and ~0.0165 Bq·L⁻¹ (3000 min), and LOQ decreasing from ~0.50 to ~0.0707 and ~0.050 Bq·L⁻¹, respectively. Raw air-phase readings systematically overestimated dissolved radon by ~26% (slope ≈ 1.26), a bias removed by the validated air → water conversion. Surveyed ²²²Rn concentrations were uniformly low (0.03–3.20 Bq·L⁻¹), far below commonly used reference values (e.g., ~11.1 and ~100 Bq·L⁻¹), with no persistent spatial hotspots and broadly overlapping shallow/deep distributions, indicating variability dominated by local lithology and fracture-controlled flow rather than depth. A tiered monitoring scheme is recommended: short screening, routine baselining at ~900–1500 min total counting, and ~3000 min for ultralow verification, providing a transferable template for sustainable baseline programs in arid aquifers. Full article

Shallow coal resources are being gradually depleted, which has led to an increase in mining depth. However, the safe extraction of deep coal seams is increasingly threatened by limestone water hazards. When vertical hydraulic channels such as karst collapse columns (KCCs) develop in limestone strata, high-pressure water may flow into the mine, potentially causing substantial casualties and property losses. In this study, the 1613A stope of the Zhangji coal mine was investigated through comprehensive detection, grouting treatment, and prevention effect evaluation. A numerical model was established to simulate the dynamic changes in groundwater levels within the limestone aquifers throughout the process. The results reveal that a KCC is developed beneath the C₃³ stratum, exhibiting an oval shape with a length of 53 m and a width of 35 m in plan view. A combination of surface and underground methods, including exploration, treatment, verification, and reinforcement, has sealed the hydraulic pathway connected to the Ordovician limestone, thereby eliminating the threat of floor water inrush. These findings are of significant value for the application and dissemination of advanced regional control technologies for water hazards in coal mines. Full article

Given the challenges posed by high groundwater levels, thick sand layers, and strong permeability in water-rich sandy strata, cut-off walls often fail to fully isolate the hydraulic connection between the inside and outside of a foundation pit. As a result, dewatering inside the pit—especially from confined aquifers—can cause significant external groundwater drawdown and subsequent ground settlement. Using a deep excavation conducted in Xiamen as a case study, this study developed a two-dimensional hydro-mechanical coupled finite element model to systematically investigate the effects of various dewatering scenarios and soil permeability coefficients on surface settlement around the pit, and to reveal settlement patterns induced by dewatering and excavation in such strata. Field monitoring data were incorporated to validate the numerical model, ensuring accuracy and reliability. Key findings include the following: (1) Dewatering contributes to over 76% of the total settlement at each stage, with confined drawdown being the dominant factor, implying that dewatering optimization should take priority over controlling excavation rate. (2) Under confined dewatering, the settlement influence zone extends beyond 80 m, far exceeding the extension caused by excavation alone; thus, monitoring and protection ranges must be adjusted dynamically. (3) The horizontal permeability of sand shows a nonlinear positive correlation with settlement, and this sensitivity grows with depth, highlighting the need for accurate permeability determination and stricter controls in deep excavations within water-rich sand layers. From an engineering perspective, these findings underscore the importance of prioritizing confined aquifer dewatering management, dynamically expanding settlement monitoring zones, and rigorously characterizing permeability profiles to mitigate excessive ground settlement and protect adjacent infrastructure. Full article

Coastal groundwater in monsoon-dominated regions faces compounding threats from seasonal hydrological extremes and seawater intrusion (SWI), yet the molecular-scale response of dissolved organic matter (DOM) remains poorly understood. We conducted a two-season investigation in Mannar District, Sri Lanka, integrating hydrochemistry, fluorescence spectroscopy, and Fourier-transform ion cyclotron resonance mass spectrometry to characterize DOM dynamics across shallow and deep groundwater. Dry-season chloride averaged 302 mg/L (shallow—5 to 12 m) and 505 mg/L (tube wells—20 to 30 m), then declined by 60–80% during monsoon recharge. Despite this freshening, DOM dynamics were decoupled from salinity: shallow wells showed dry-season DOC peaks (6.64 mg/L) driven by soil concentration, while tube wells exhibited wet-season enrichment (5.02 mg/L). Shallow aquifers maintained consistently high humification indices (around 0.70) and aromatic-rich DOM, indicating sustained buffering by soil-derived inputs. In contrast, wet-season recharge in tube wells appeared to stimulate microbial processing, as indicated by elevated protein-like fluorescence (C2: 26% to 36%) and a higher contribution of nitrogen-bearing formulas (CHONs: 31.4% to 37.1%). Tube wells also accumulated reduced, energy-rich DOM with correspondingly high molecular lability indices. Paradoxically, correlation networks suggested that these saturated aliphatic and halogenated structures persist due to kinetic protection under low oxygen, high-salinity conditions. These findings indicate that aquifer structure and redox conditions control DOM biogeochemistry in coastal groundwater systems. At the molecular level, DOM dynamics are influenced by aquifer depth and seasonal recharge, leading to a decoupling between salinity and organic matter transformation. Full article

Ground subsidence and shaft lining deformation caused by compressed dewatered bottom aquifers in deep unconsolidated strata mining areas are critical engineering challenges, making the study of the seepage–soil deformation coupling mechanism during groundwater injection remediation vital. This study built a visual cylindrical model (1025 mm × 150 mm); formulated well-graded analogous materials based on the D₂₀ principle to simulate sandy gravel layers; embedded FBG sensors at 200/400/600 mm depths, combined with a dial indicator on the model top; and conducted two water injection–dewatering cycles. Results indicate: water injection generates excess pore water pressure, placing the entire model in a tensile stress state with top rebound; post-injection vertical stress redistributes (tension above the injection point, compression below, and an interlaced transitional band), validating the necessity of full-section injection; during the second injection–dewatering cycle, tensile strain at the upper monitoring point reaches 597.77 με, while compressive strain at lower depths reaches −253.90 με, internal deformation stabilizes within 6.5–10.0 days, injection improves the in situ stress state by reducing effective stress, and the deformation of the field strata remains in a stabilization period, with the stabilization time decreasing as the depth of the strata increases. This study clarifies the temporal evolution and representative spatial variation in internal strain at monitored depths during injection, providing theoretical and design references for optimizing water injection schemes to mitigate coal mine shaft damage. Full article

Geological storage of carbon dioxide in faulted sedimentary basins requires suitability evaluation methods that can address uncertainty, indicator interaction, and limited data availability. This study develops an integrated evaluation framework that combines the Analytic Hierarchy Process, triangular fuzzy numbers, and the Choquet fuzzy integral to assess basin-scale geological carbon dioxide storage suitability. The framework enables structured weight determination, explicit representation of expert uncertainty, and non-additive aggregation of interacting indicators. The evaluation focuses on deep saline aquifers in the Jianghan Basin and is based on seventeen indicators covering geological, structural, hydrogeological, and socio-economic conditions. The assessment integrates seismic interpretation, geological mapping, logging data, and published datasets, and is conducted at the level of tectonic units to support basin-scale screening. The method is applied to the Jianghan Basin using seventeen geological, structural, hydrogeological, and socio-economic indicators. The results indicate that burial depth primarily acts as a threshold condition, whereas caprock sealing capacity, fault system development, and hydrogeological stability dominate suitability differentiation. Interaction analysis reveals pronounced substitution effects among geological indicators, indicating that strong performance in key safety-related factors can compensate for less favorable secondary constraints during early-stage screening. The Qianjiang Sag and Jiangling Sag are identified as the most suitable storage units. The proposed framework provides a transparent and robust tool for basin-scale screening in structurally complex, data-limited sedimentary basins. Full article

As shallow coal resources become increasingly depleted, coal mining is extending to greater depths, making mine thermal hazards an increasingly prominent issue. This paper proposes a novel system for synergistic geothermal energy extraction from deep coal mine aquifers and coal seam cooling, aimed at achieving integrated geothermal exploitation and mine thermal hazard control. Based on a high-temperature mine in the Yuanyanghu Mining Area of Ningxia, a dual-stage, single-branch three-dimensional numerical model was established to simulate the effects of water injection pressure, water injection temperature, and level spacing on the system’s cooling performance and geothermal energy extraction efficiency. The results indicate that increasing injection pressure enhances early-stage geothermal energy extraction capacity and coal seam cooling rate, but the heat extraction power declines over long-term operation as the produced water temperature approaches the injection temperature. Lowering injection temperature significantly improves water–rock heat exchange efficiency, accelerates coal seam cooling, and increases geothermal energy extraction. Increasing level spacing helps improve geothermal energy extraction power but weakens the direct cooling effect on the coal seam. Considering the influence patterns of each parameter, the optimal combination was determined as water injection pressure of 10 MPa, water injection temperature of 10 °C, and level spacing of 80 m, which delivers the best overall performance by enabling rapid coal seam cooling and sustained geothermal energy extraction, with a cumulative geothermal output reaching 129.45 MW after 10 years of operation. This study provides a theoretical basis and technical reference for the integrated management of thermal hazards and geothermal resource development in deep coal mines. Full article

The Banji Mine, located in the western part of the Huainan Coalfield, is characterised by a deep burial depth and multiple aquifers. It faces significant water inflow risks from roof aquifers, especially from the sandstone aquifer above the No. 9 coal seam. To explore the hydrochemical evolution of this sandstone aquifer and address key scientific challenges in water hazard prevention, an integrated approach combining mathematical statistics, Piper trilinear diagrams, Gibbs diagrams, and principal component analysis (PCA) was employed. Results show that from 2020 to 2023, the average TDS increased from 1729.51 mg·L⁻¹ to 2061.22 mg·L⁻¹, and the hydrochemical types transitioned from a mix of Cl-Na (48.6% of samples) and HCO₃·Cl-Na to a dominant Cl-Na type (91.1% in 2023), exhibiting high mineralisation and a distinct trend of water salinisation. The dissolution of evaporites and evaporative concentration were identified as the primary processes influencing the hydrochemical characteristics, with PCA indicating that the dominant factor (F1) explained 66.269% of the variance. Saturation index (SI) analysis revealed that calcite and dolomite were saturated to supersaturated (SI: 0.73–2.15 and 1.66–4.81, respectively), while gypsum and halite were undersaturated but showed a tendency to dissolve towards equilibrium. Over time, the cation exchange and sulfate reduction processes weakened, indicating that mining activities have disrupted the hydrochemical equilibrium of the roof sandstone aquifer, accelerating water salinisation. This study provides a theoretical foundation for identifying the causes and early warning signs of water hazards in the roof strata of the Banji Mine. Full article

This study investigated the influence of groundwater flux and temperature on denitrification in a steep coastal agricultural Island in western Japan. Push–pull tests (PPTs) were conducted at depths of 3 m, 15 m, and 30 m, during winter, spring, and summer to assess denitrification under varying hydrogeological and seasonal conditions. The 3 m layer is silty loam, 15 m is granitic weathered soil, and 30 m is granitic weathered rock, each with distinct hydraulic conductivities and fluxes. The objectives were to assess denitrification rates and fluxes, assess depth- and season-related variability, and determine the relative roles of hydraulic flux and temperature on denitrification. Denitrification was higher at shallow (3 m) and deep (30 m) boreholes during low-flux periods, while low at the intermediate depth (15 m) where fluxes were highest. Temperature variation had weak correlations compared to hydraulic flux, which showed a strong inverse correlation with denitrification. These findings demonstrate that residence time, controlled by groundwater flux, is the dominant factor influencing nitrate attenuation in this steep coastal aquifer. The PPTs results indicate that denitrification rates derived from PPTs decrease under higher hydraulic fluxes, as these conditions promote more oxic conditions. The study highlights the potential for natural denitrification to mitigate nitrate contamination during low-flux periods, providing insights for sustainable groundwater management in agricultural island environments. Full article

Few hydrogeological studies have focused on possible per- and poly-fluoroalkyl substance (PFAS) contamination in groundwater with particular attention to the role of hydraulic interconnections and to the interdigitations present between shallow and deep aquifer layers in heterogeneous alluvial systems. In general, deeper groundwater is considered chemically safer and less impacted by contamination, especially in multilayer aquifers characterized by low permeability apparently confining horizons. Therefore, this research analyzed PFAS in groundwater at depths ranging from 20 to 120 m below ground level, combining stratigraphic, hydrogeological, and chemical data with GIS mapping to identify industrial activities potentially contributing to PFAS contamination using the cross-checking methodology. During the second survey, the monitoring network was extended along a hydrogeological transect, including two springs located upstream and downstream of the deep wells, to assess PFAS concentration in shallow groundwater and the possible transfer along the groundwater flow path. The intra-site comparative analysis reveals, for the same sampling locations, a differentiation in the PFAS profiles detected across the two monitoring campaigns, indicating a temporal evolution in the chemical composition. Furthermore, chemical results show the presence of PFAS exclusively in deep monitoring wells, confirming a spatially heterogeneous distribution within the aquifer system. These results highlight both the temporal and spatial evolution of PFAS concentration, suggesting a complex contaminant migration pathway along preferential gravel and sand horizons in deeper aquifer layers. The conceptual hydrogeological model confirmed hydraulic interconnections among aquifer layers and identified zones of higher vulnerability to contamination. The analysis of possible PFAS migration pathways at the basin scale raised some questions about the influence of wells features and management practices on PFAS distribution in shallow and deep groundwater. The findings of this research contribute to environmental sustainability, providing initial insights for measuring and managing the presence and pathways of PFAS in deep alluvial aquifers. Full article

The deep terrestrial subsurface is the largest reservoir of Earth’s freshwater resources as well as the largest habitat for prokaryotic life. However, the deep-subsurface microbiome, especially its spatial distribution across countries/continents, is still poorly understood. In this study, we compiled and compared 30 16S rRNA gene amplicon libraries from three deep fractured aquifers in different parts of the world (depth range of tens of meters to 2.4 km below surface) to understand the spatial distribution and functions of deep-subsurface microbial community, and to test for the presence of core taxa. The results revealed spatially heterogenous microbial community composition at both the local and the global scales, even at the phylum level. Environmental filtering was identified as an important driver of the microbial community structure of deep groundwaters. Despite the spatial heterogeneity, the three aquifers share a core microbiome at the genus level. Only one family, Comamonadaceae, was present in all the 30 samples analyzed. Several other families were also prevalent, including Hydrogenophilaceae, Omnitrophaceae, BSV26 (Candidatus Kryptonia), and an unclassified Thermodesulfovibrionia. FAPROTAX functional prediction indicated that chemoheterotrophic functions predominate, and the core microbial genera, together with the dominant genera, collectively govern the functional characteristics. Taken together, our findings provide new insights into the spatial heterogeneity and functional potential of deep-subsurface ecosystems across the globe. Full article

Accurate subsurface velocity modeling is of fundamental scientific and practical significance for seismic data processing and interpretation. However, conventional depth-domain methods still face limitations in physical consistency and inversion accuracy. To overcome these challenges, this study proposes a deep learning-based seismic velocity modeling approach in the time domain. The method establishes an end-to-end mapping between seismic records and velocity models directly in the time domain, reducing the nonlinear complexity of mapping time-domain data to depth-domain models and improving prediction stability and accuracy. Synthetic aquifer velocity models were constructed from representative stratigraphic features, and multi-shot seismic records were generated through forward modeling. A U-Net network was employed, taking multi-shot seismic records as input and time-domain velocity fields as output, with training guided by a mean squared error (MSE) loss function. Experimental results show that the proposed strategy outperforms conventional depth-domain approaches in aquifer structure identification, velocity recovery, and interlayer contrast depiction. Quantitatively, significant improvements in MSE, peak signal-to-noise ratio, and structural similarity index indicate higher reconstruction reliability. Overall, the results confirm the effectiveness and potential of the proposed time-domain framework for aquifer velocity inversion and its promise for intelligent seismic velocity modeling. Full article

Arsenic (As) mobility in aquifer systems is mainly governed by its adsorption and desorption behaviour at the sediment-water interface, directly influencing its environmental availability and risks to water quality. This study explores the adsorption-desorption behaviour of inorganic As species through batch experiments on environmental sediments collected from three representative depths, selected to reflect local contrasting geochemical, mineralogical, and granulometric characteristics of the Como basin aquifer (Northern Italy). This setting was selected as a case study owing to its notable gradient in As concentration in groundwater: the shallow aquifers host concentrations typically below 10 µg/L, while the deep aquifer reaches concentrations of about 250 µg/L. Statistical analyses (ANOVA and simple linear regression) identified Mn- and Al-(hydr)oxide content, grain size, and mineralogy as strong predictors of As(V) retention, whereas As(III) showed no significant correlation with individual sediment properties within the tested conditions. Shallow, Mn- and Al-rich sediments exhibited higher adsorption capacity and corresponded to lower dissolved As in groundwater, while deeper, finer-grained sediments with lower oxide content coincided with elevated groundwater As concentrations. Desorption experiments indicated that As(III) dominated the released fraction, reflecting its greater mobility under variable pH and redox aquifer conditions. These results provide mechanistic insight into sediment-water interactions controlling As distribution in multilayer aquifers, supporting improved risk assessment and management of As in complex groundwater systems. Full article

Deep saline aquifers in the eastern part of Drava Basin were screened for potential storage sites. The input dataset included three seismic volumes, a rather extensive set of old seismic sections and 71 wells. Out of all identified potential storage objects, only two sites were found to be situated in the favorable geological settings, meaning that the inspected wells drilled through structural traps had a seal at least 20 m thick which was intersected by only a few faults with rather limited displacement. Many more closed structures in the area were tested by exploration wells, but in all other wells, various problems were encountered, including inadequate reservoir properties, inadequate seal or inadequate depth of the identified trap. Analysis was highly affected by the insufficient quality and spatial distribution of the seismic input data, as well as in places with insufficient quality of input well datasets. An initial characterization of identified storage sites was performed, and their attributes were compared, with potential storage object B recognized as the one that should be further developed. However, given the depth and increased geothermal gradient of the potential storage object B, it is possible that it will be developed as a geothermal reservoir, and this brings forward the problem of concurrent subsurface use. Full article