Search Results (24)

This paper assesses the role of green hydrogen and green ammonia in the low-carbon reconstruction of Ukraine’s energy sector. The country, severely affected by war, has more than 70% of its energy infrastructure damaged or destroyed, which calls for novel solutions for not only reconstructing but also rethinking Ukraine’s energy sector shaped by the Soviet-era planning. In this context, decentralized and renewable energy solutions appear to be one of the best options to achieve this goal. This study combines four novel and mutually reinforcing methods: a Scopus-based literature review of highly cited green hydrogen publications, natural language processing (NLP) and bibliometric network analysis of Ukraine-related hydrogen research, a SWOT assessment, and a geospatial hydrogen production cost model (GEOH2). The novelty of this research lies in this integrated Ukraine-specific framework, which links research trends, wartime reconstruction constraints, hub-level policy choices, and financing risk-sensitive cost modeling. Therefore, the quantitative part of GEOH2 estimates the levelized cost of green hydrogen, while ammonia is treated as a downstream screening-level conversion and export pathway rather than as a full plant-level ammonia model. Our results show that Ukrainian green hydrogen research is concentrated on renewable-energy strategy, wind and solar electrolysis, water and desalination constraints, gas grid blending, underground storage, ammonia derivatives, and decentralized energy systems. The GEOH2 results indicate that southern Ukraine has strong physical potential for competitive green hydrogen production under de-risked financing, while war risk financing can make even resource-rich areas economically unattractive. Odesa and Dnipro emerge as important export-oriented and industrial hubs, whereas Zakarpattia remains strategically relevant as a safer western corridor linked to European markets. Our findings demonstrate that Ukraine’s hydrogen and ammonia development needs to follow a phased pathway: domestic renewable build-out and grid repair, pilot electrolysis projects and screening-level ammonia conversion pathways, targeted de-risking and insurance mechanisms, and only then broader export corridor development. This pathway can support decarbonization, energy security, industrial modernization, and Ukraine’s long-term integration into European clean energy value chains. Full article

This study reports the development of a hierarchically porous material based on natural diatomite, thermally treated diatomite (450 °C), and an activated carbon-modified diatomite composite for saline groundwater treatment in West Kazakhstan, addressing the need for efficient desalination solutions under real environmental conditions. The material was synthesized via sequential thermal activation at 450 °C followed by incorporation of activated carbon, with bentonite used as a binder to improve mechanical stability. Comprehensive physicochemical characterization (SEM, XRD, XRF, BET, DTA, and FTIR) confirmed significant structural and compositional transformations, including silica enrichment, removal of impurities, and the development of a well-defined hierarchical porous network. The specific surface area increased from 8 to 10 m²/g for natural diatomite to 35–40 m²/g for thermally treated diatomite and further to 55–60 m²/g for the activated carbon-modified diatomite composite, accompanied by enhanced pore volume and mesoporosity. Performance evaluation using real groundwater samples demonstrated that thermally treated diatomite (450 °C) improved removal efficiency by approximately 19%, while the activated carbon-modified diatomite composite achieved 35–37% removal of chloride, sulfate, and total dissolved solids under multi-ion competitive conditions. The enhanced adsorption performance is attributed to the synergistic effect of increased surface area, improved pore accessibility, and additional active sites introduced by activated carbon. The adsorption process is governed by ion bridging mediated by multivalent cations, pore filling within the hierarchical pore structure, and surface complexation on silanol and metal–hydroxyl functional groups. Leaching tests confirmed the structural stability of the composite and indicated no significant release of environmentally relevant elements under aqueous conditions. Compared with natural diatomite, the thermally treated and activated carbon-modified materials demonstrate improved adsorption efficiency and stable performance under realistic groundwater conditions. These results highlight their applicability for decentralized water treatment systems in regions affected by saline groundwater contamination. Full article

Access to freshwater is one of the major global challenges, driven by population growth, industrial development, climate change, and increasing water stress, particularly in economically constrained regions. In this context, this study designs, builds, and experimentally and numerically evaluates an indirect solar concentration desalination system (ICST) composed of a humidification–dehumidification (HDH) subsystem thermally powered by a Linear Fresnel Concentrator (LFC) under the appropriate technology paradigm. The methodology integrates an experimental campaign conducted under real climatic conditions in Bucaramanga, Colombia, mathematical modeling based on mass and energy balances, and the implementation of a TRNSYS simulation model validated through qualitative and quantitative analyses using absolute and relative errors. Results showed close agreement between experimental and simulated data, with daily freshwater production deviations of 0.53 and 0.65 L/day in tests 04 and 05, respectively, while mean relative errors remained below 5% for the main thermal and productivity variables. Experimentally, an average freshwater production of 1.13 L/h was achieved, with a production gain ratio (GOR) of 0.32 and a recovery ratio (RR) of 0.021, while maintaining total dissolved solids below 500 mg/L. Economic assessment estimated a production cost of $0.065/L, demonstrating the technical and economic feasibility of the system for decentralized small-scale applications in regions with high solar irradiance throughout the year. Full article

Damage to urban water supply infrastructure can rapidly compromise access to safe water and force households to rely on alternative sources of uncertain quality. This study presents a case-based assessment of water quality and emergency household-level treatment options in Mykolaiv, Ukraine, following conflict-induced disruption of the centralized water supply system. Water samples collected from selected groundwater and distribution-network points were analyzed for physicochemical, organoleptic, and microbiological indicators, including total dissolved solids, hardness, sulfates, chlorides, iron, permanganate oxidizability, total microbial count, and E. coli. The results showed elevated mineralization, increased sulfate and chloride concentrations, high hardness, organic load indicators, and episodic microbiological contamination in several samples. A low-cost four-stage household treatment procedure combining chemical oxidation, thermal treatment, sorption, and short-term preservation was evaluated as a preliminary emergency approach. The procedure improved odor, taste, hardness, iron content, permanganate oxidizability, and microbiological safety; however, it did not fully reduce total dissolved solids, sulfates, or chlorides to drinking-water standards. Therefore, the treated water should be considered non-potable and suitable mainly for limited domestic and hygienic uses unless additional desalination or blending is applied. The study highlights both the potential and the limitations of simple household-level interventions under emergency water supply disruption and emphasizes the need for decentralized treatment support, monitoring, and long-term infrastructure recovery. Full article

Population growth, industrialization and climate change have placed increasing stress on natural freshwater reserves, making conventional water sources inadequate. Coupled with rising energy constraints and environmental concerns, interest in desalination technologies that can operate more sustainably and efficiently has intensified. Among the available approaches, membrane desalination has gained particular importance because of its modularity, relatively low energy demand, and compatibility with decentralized water treatment. In parallel, thermoelectric devices have emerged as promising components for hybrid desalination systems due to their ability to convert temperature gradients into electricity or provide localized heating and cooling for process enhancement. This article presents a narrative review of thermoelectric integration in desalination systems, with particular emphasis on membrane desalination and membrane-hybrid water treatment configurations powered by renewable-energy or low-grade heat sources. The review examines the role of thermoelectric devices in relation to key membrane-based and hybrid desalination processes, including reverse osmosis, membrane distillation, electrodialysis, nanofiltration, forward osmosis, and selected hybrid systems. Particular attention is given to system configurations, renewable energy coupling pathways, functional roles of thermoelectric devices, water productivity, module output, desalination efficiency, water quality, and economic performance. The reviewed literature indicates that thermoelectric integration can provide meaningful benefits in hybrid desalination, particularly through improved thermal management, enhanced utilization of low-grade heat, and supplementary energy recovery. These opportunities appear especially relevant for thermally driven membrane systems such as membrane distillation and for membrane-hybrid configurations intended for decentralized or renewable-powered applications. However, the available evidence remains highly heterogeneous, with substantial variation in system scale, operating conditions, reporting metrics, and cost assumptions, which limits direct cross-study comparison and broad generalization of performance claims. This review highlights the technical challenges, reporting inconsistencies, and research gaps that currently constrain the practical development of thermoelectric-assisted membrane desalination and outlines future directions for membrane-aligned hybrid desalination research. Full article

Intermittently operated, tankless reverse osmosis (RO) systems are widely used in decentralized and point-of-use applications, yet water stagnation during idle periods remains a critical challenge, leading to degraded water quality, accelerated fouling, and performance loss. This study presents an experimentally validated engineering solution that eliminates stagnant water in intermittently operated RO systems. A dual-membrane RO configuration with flexible series–parallel switching was developed, enabling membranes to alternate between production and flushing modes. An adaptive control strategy, integrated into the system hardware, regulates membrane switching and flushing based on real-time feed-water quality. The proposed configuration and control framework was evaluated under representative intermittent operating conditions. Experimental results show that the zero-stagnant-water strategy effectively prevents residual water accumulation during shutdown and maintains stable permeate quality, with total dissolved solids consistently below 10 mg/L. Long-term testing further demonstrates reduced membrane fouling and slower performance degradation compared with conventional fixed-operation schemes, resulting in enhanced desalination efficiency and operational stability. Owing to its modular design and simple control logic, the proposed approach is readily transferable to decentralized and point-of-use membrane water treatment systems requiring reliable, high-quality water under intermittent operation. Full article

Solar-driven interfacial evaporation is a promising strategy for alleviating freshwater scarcity and water pollution. However, developing efficient evaporators using eco-friendly, renewable biomass remains a significant challenge. Herein, we report a bio-derived solar-driven interfacial evaporator (CSIE) based on iron–tannin modified collagen, further enhanced via mechanical micro-perforations to induce the Marangoni effect (EN-CSIE). The influence of pore size and open-area ratio on the Marangoni-driven flow was systematically investigated. The optimized EN-CSIE (with 1.2 mm pore size and 6.1% open-area ratio) achieved a superior evaporation rate of 2.5 kg m⁻² h⁻¹ with an energy conversion efficiency of 93.5% under 1 sun illumination. Furthermore, the system demonstrated exceptional purification capabilities, removing over 99.9% of metal ions and organic impurities. Long-term durability tests in 3.5 wt% saline water confirmed a stable evaporation rate of 2.3 kg m⁻² h⁻¹ over 15 continuous cycles. This low-cost and sustainable collagen-based evaporator presents a robust solution for solar-powered water desalination, particularly for decentralized clean water production in sun-rich regions. Full article

Global freshwater scarcity continues to escalate due to pollution, climate change, and population growth, making innovative sustainable desalination technologies increasingly vital. Solar stills offer a simple and eco-friendly method for freshwater production by utilizing renewable energy, yet their low productivity remains a major limitation. This study experimentally evaluates and quantifies several established enhancement techniques under real climatic conditions to improve evaporation and condensation efficiency. The integration of porous materials, such as black rocks, significantly improves thermal energy storage and management by retaining absorbed heat during the daytime and releasing it gradually, resulting in an average 30% increase in daily distillate production (SD = 6 mL). Additionally, forced convection using small fans enhances humid air removal and evaporation rates, increasing the average yield by approximately 11.4% (SD = 2 mL). Optical concentration through lenses intensifies solar irradiation on the evaporation surface, achieving the highest performance with an average 50% improvement in water output (SD = 5 mL). The incorporation of Phase Change Materials (PCM) is further proposed to extend thermal stability during off-sunshine hours, with materials selected based on a melting point range of 38–45 °C. To minimize nocturnal heat loss, future designs may integrate radiative cooling materials for passive night-time condensation support, by applying a radiative cooling coating to the condenser plate to enhance passive heat rejection to the sky. Overall, the validated combined use of renewable energy-driven desalination, thermal storage media, and advanced strategies presents a practical pathway toward high-efficiency solar stills suitable for sustainable buildings and decentralized water supply systems in arid regions. Full article

Water scarcity remains a critical global challenge, driving the need for efficient small-scale desalination technologies. This study presents experimental research on the performance evaluation of an innovative ultrasonic humidifier designed for the humidification–dehumidification (HDH) desalination process. A prototype was designed, incorporating a 1.7 MHz piezoelectric transducer. The efficiency of the humidifier, the vapor production rate, and the specific energy consumption were evaluated based on two operating parameters: water temperature, ranging from 30 °C to 60 °C, and airflow rate, ranging from 20 to 120 L/min. The results show that humidification efficiency increases with airflow rate, reaching values above 95% at a temperature of 60 °C, with an airflow rate of 60 L/min, decreasing slightly at higher flow rates. The system demonstrated optimal performance at 60–80 L/min, balancing high efficiency and vapor production with moderate energy demand. These findings demonstrate that ultrasonic humidification is a viable alternative, especially in decentralized applications, due to its low thermal energy requirements, compact design, and adaptability to intermittent renewable energy sources. Full article

Coastal Bangladesh faces severe drinking water scarcity due to salinity intrusion. To address this challenge, the study assesses the socio-technical and economic factors shaping the performance of small-scale reverse osmosis (RO) desalination plants through field audits, household surveys, stakeholder interviews, and water quality analysis. Community acceptance was evaluated using the Theory of Planned Behavior (TPB). Feedwater was highly contaminated, with average TDS 3732.63 mg/L, hardness 636.36 mg/L, iron (Fe) 3.23 mg/L, and turbidity 14.63 NTU. Despite this, RO systems demonstrated strong performance, achieving removal efficiencies of 95.15% for salts, 95.95% for hardness, and 91.67% for alkalinity, with an average recovery rate of 37.25% (range: 20–60%). Treated water met WHO and Bangladesh standards, with mean concentrations of TDS (195.54 mg/L), Fe (0.21 mg/L), arsenic (0.0085 mg/L), and turbidity (1.09 NTU). However, inadequate operator training and a lack of maintenance threaten sustainability. Energy consumption increased by 0.1 kWh/m³ per 1000 mg/L rise in salinity, while financial constraints hinder membrane replacement. TPB analysis revealed positive attitudes and perceived behavioral control as key adoption drivers. Untreated brine discharge (mean TDS 12,900 mg/L) posed significant environmental risks. This study provides micro-level insights to inform policy and strengthen the sustainability of decentralized RO systems in climate-vulnerable coastal regions. Full article

This study experimentally validates a solar-thermal desalination system equipped with predictive feedwater control guided by real-time solar forecasting. Unlike conventional systems that react to temperature changes, the proposed approach proactively adjusts feedwater flow in anticipation of solar variability. To assess environmental and financial sustainability, the study integrates this control logic with a full Life Cycle Assessment (LCA) and Techno-Economic Analysis (TEA). Field testing in a high-temperature, arid region demonstrated strong performance, achieving a Global Warming Potential (GWP) of 1.80 kg CO₂-eq/m³ and a Levelized Cost of Water (LCOW) of $0.88/m³. Environmental impacts were quantified using OpenLCA and ecoinvent datasets, covering climate change, acidification, and eutrophication categories. The TEA confirmed economic feasibility, reporting a positive Net Present Value (NPV) and an Internal Rate of Return (IRR) exceeding 11.5% over a 20-year lifespan. Sensitivity analysis showed that forecast precision and TES design strongly influence both environmental and economic outcomes. The integration of intelligent control with simplified thermal storage offers a scalable, cost-effective solution for off-grid freshwater production in solar-rich regions. Full article

As climate change intensified water scarcity in Southern Europe, tourism-dependent regions such as Portugal’s Algarve faced growing pressure to adapt their water management systems. This study investigated how hotel groups in the Algarve have adopted and communicated water reuse technologies—specifically desalination and greywater recycling—under environmental, institutional, and reputational constraints. A comparative qualitative case study was conducted involving three hotel groups—Vila Vita Parc, Pestana Group, and Vila Galé—selected through purposive sampling based on organizational capacity and technology adoption stage. The analysis was supported by a supplementary mini-case from Mallorca, Spain. Publicly accessible documents, including sustainability reports, media coverage, and policy frameworks, were thematically coded using organizational environmental behavior theory and the OECD Principles on Water Governance. The results demonstrated that (1) higher organizational capacity was associated with greater maturity in water reuse implementation; (2) communication transparency increased alongside technological advancement; and (3) early-stage adopters encountered stronger financial, regulatory, and operational barriers. These findings culminated in the development of the Maturity–Communication–Governance (MCG) Framework, which elucidates how internal resources, stakeholder signaling, and institutional alignment influence sustainable infrastructure uptake. This research offered policy recommendations to scale water reuse in tourism through financial incentives, regulatory simplification, and public–private partnerships. The study contributed to the literature on sustainable tourism and decentralized climate adaptation, aligning with UN Sustainable Development Goals 6.4, 12.6, and 13. Full article

Decentralized desalination systems driven by renewable energy sources have surfaced as a feasible way to alleviate water scarcity in arid and rural areas. This bibliometric study aims to clarify the research trends, conceptual frameworks, and cooperative dynamics in the scientific literature on decentralized renewable-powered desalination techniques. Using a thorough search approach, 1354 papers were found. Duplicates, thematically unrelated works, and entries with poor information were removed using the PRISMA 2020 framework. A selected 832 relevant papers from a filtered dataset were chosen for in-depth analysis. Quantitative measures were obtained by means of Bibliometrix; network visualisation was obtained by means of VOSviewer (version 1.6.19) and covered co-authorship, keyword co-occurrence, and citation structures. Over the previous 20 years, the data show a steady rise in academic production, especially in the fields of environmental science, renewable energy engineering, and water treatment technologies. Author keyword co-occurrence mapping revealed strong theme clusters centred on solar stills, thermoelectric modules, reverse osmosis, and off-grid systems. Emphasizing current research paths and emerging subject borders, this paper clarifies the intellectual and social structure of the field. The outcomes are expected to help policy creation, cooperative projects, and strategic planning meant to hasten innovation in sustainable and decentralized water desalination. Full article

Water scarcity is a pressing global issue driving the need for efficient and sustainable water reuse and desalination technologies. In the last two decades, humidification–dehumidification (HDH) has emerged as a promising method for small-scale and decentralized systems. This paper presents a comprehensive review of recent scientific literature highlighting key advancements, challenges, and potential future directions of HDH research. Because the HDH process suffers from low heat and mass transfer, as well as thermodynamic limitations due to the mild operating conditions, this work indicates three main strategies for HDH enhancement: (1) Advanced Heat and Mass Transfer Techniques, (2) Integration with Other Technologies, and (3) Optimization of System Operative Conditions. Particularly for advanced HDH systems, the reference GOR values exceed 3, and certain studies have demonstrated the potential to achieve even higher values, approaching 10. In terms of recovery ratio, there appear to be no significant process constraints, as recycling the brine prepared in innovative schemes can surpass values of 50%. Considering electricity costs, the reference range falls between 1 and 3 kWh m^–3. Notably, multi-stage processes and system couplings can lead to increased pressure drops and, consequently, higher electricity costs. Although consistent data are lacking, a baseline SEC reference value is approximately 360 kJ kg^–1, corresponding to 100 kWh m^–3. For comparable SEC data, it is advisable to incorporate both thermal and electric inputs, using a reference power plant efficiency of 0.4 in converting thermal duty to electrical power. When considering the utilization of low-temperature solar and waste heat, the proposed exergy-based comparison of the process is vital; this perspective reveals that a low-carbon HDH desalination domain, with II-law efficiencies surpassing 0.10, can be achieved. Full article

An applicable, high-volume, and sustainable water uptake technology can alleviate freshwater shortages, improve the energy utilization rate and promote the development of energy technology. Traditional seawater desalination, fog water, and dew collection are limited by the geographical environment, and the water resource transportation cost is high, or the water uptake volume is limited, so they cannot be used on a large scale. There are potential safety problems with wastewater reuse and recycled water. Atmospheric water harvesting technology uses energy for direct condensation or uses adsorbent to absorb water, which is characterized by strong sustainability, high applicability, decentralization, and stable water uptake. This study summarizes the working principle of mainstream atmospheric water harvesting technologies, mainly including condensation, absorption, and desorption water harvesting, and some active dew and fog collection technologies. It also theoretically analyzes the energy consumption of condensation and adsorption and desorption water harvesting technologies. Aiming at the problems of difficult condensing for direct condensation and long adsorption/desorption cycle of adsorption and desorption water harvesting, it summarizes the countermeasures of multi-stage condensation and multi-cycle adsorption and desorption. The development prospect of atmospheric water harvesting technologies is also discussed Full article