Search Results (49)

Granitic faults within the crystalline upper-to-middle continental crust play a critical role in accommodating tectonic deformation and controlling earthquake nucleation. To better understand their frictional behavior, we review experimental studies conducted under both dry and hydrothermal conditions using velocity-stepping (VS), constant-velocity (CV), and slide-hold-slide (SHS) tests. These approaches allow the quantification of frictional strength, velocity dependence, and healing behavior across a range of conditions. Our synthesis highlights that the friction coefficient of granite gouges decreases with increasing temperature and pore fluid pressure, decreasing slip velocity, and increasing slip displacement. The velocity-weakening regime shifts to higher temperatures with increasing slip velocity or decreasing pore fluid pressure. Temperature, normal stress, pore fluid pressure, and slip velocity interact to modulate frictional stability. In particular, microstructural observations reveal that grain size reduction, pressure solution creep, and fluid-assisted chemical processes are key mechanisms governing transitions between velocity-weakening and velocity-strengthening regimes. These insights support the growing application of microphysical-based models, which integrate micromechanical processes and offer improved extrapolation from the laboratory to natural fault systems compared to classical rate-and-state friction laws. The collective evidence underscores the importance of considering fault rheology in a temperature- and fluid-sensitive context, with implications for interpreting seismic cycle behavior in continental regions. Full article

High oil content in breaded fried small yellow croaker (BFYC) was reduced using composite batter gels consisting of tapioca starch, wheat flour, and different concentrations of cassia gum (CG; 0%, 0.2%, 0.4%, 0.6%, 0.8%, 1%). The effects of CG on the oil absorption capacity of BFYC and potential mechanisms were investigated. Dynamic rheological analysis revealed that CG addition could enhance the viscoelasticity of the batter by increasing its storage modulus and loss modulus. Furthermore, FTIR and X-ray diffraction results demonstrated that CG interacts with starch through noncovalent interactions, increasing the relative crystallinity from 9.29% to 16.49%, which promoted the formation of a gel layer. This structural improvement effectively inhibited oil absorption. Differential scanning calorimetry analysis showed that within the 0–0.8% CG range, the batter’s denaturation temperature increased from 78.23 °C to 82.08 °C with higher CG concentrations, indicating prolonged gelatinization and enhanced thermal stability that further reduced oil penetration. Low-field nuclear magnetic resonance analysis revealed that CG increased the proportion of tightly bound and weakly bound water in the batter, thereby improving water retention capacity and reducing moisture loss during frying. Microscopic structural observations and Sudan Red-staining tests confirmed that at 0.8% CG concentration, the crust exhibited the lowest porosity with approximately 40% reduction in surface fat content compared to the control group. In conclusion, CG addition significantly improves batter properties and reduces oil content in fried products, providing theoretical support for the development of low-fat fried foods. Full article

The field of newly developed two-dimensional (2D) materials with low symmetry and structural in-plane anisotropic properties has grown rapidly in recent years. The phosphorene analog of group IV monochalcogenides is a prominent subset of this group that has attracted a lot of attention because of its unique in-plane anisotropic electronic and optical properties, crystalline symmetries, abundance in the earth’s crust, and environmental friendliness. This article presents a review of the latest research advancements concerning 2D group IV monochalcogenides. It begins with an exploration of the crystal structures of these materials, alongside their optical and electronic properties. The review continues by discussing the various techniques employed for the synthesis of layered group IV monochalcogenides, including both bottom-up methods such as vapor-phase deposition and top-down techniques like mechanical and/or liquid-phase exfoliation. In the final part, the article emphasizes the application of 2D group IV monochalcogenides, particularly in the fields of photocatalysis, photodetectors, nonlinear optics, sensors, batteries, and photovoltaic cells. Full article

Transport and vehicle traffic are closely connected with particulate matter (PM) pollution, inducing various fractions into the atmosphere, some of them forming significant deposits on the surface of the car. They are washed away during carwash-inducing slurries collecting the PM deposits, which are characteristic of a large area. Crystalline PM matter was investigated by XRD coupled with polarized optical microscopy (POM). Organic matters were investigated by Fourier-Transform Infrared spectrometry (FTIR) and gas chromatography, GC-MS. Their microstructure and elemental composition were investigated by SEM-EDX. The crystalline features contain mainly quartz, calcite, and clay (muscovite and kaolinite) particles having traces of goethite and lepidocrocite. Slurry particle size distribution was established by sieving on the following meshes: 63 µm, 125 µm, 250 µm, 500 µm, 1000 µm, 2000 µm, and 4000 µm. Coarse fractions of 250–4000 μm are dominated by quartz and calcite particles. The quartz and calcite amount decreases with particle size, while the muscovite and kaolinite amount increases in the finest fractions of 0–125 μm. Organic matter was evidenced, firstly, by FTIR spectroscopy, revealing mostly CH₂; C=O, and NH₄ bonds that are more intense for the fine particulate fractions. The organic deposits form mainly amorphous crusts associated with micro- and nano-plastic particles related to the phthalates and traces of the washing detergents. Atomic Force Microscopy revealed their size range between 60 and 90 nm and evidenced nanoparticles within samples. The nanofractions adhere to the bigger particles in humid environments, assuring their immobilization to reduce their hazardous potential. Carwash slurry blending with fertile soil ensures proper grass seed germination and growth at mixtures of up to 60% slurry, allowing its sustainable reconversion as soil for landfill and dump rehabilitation, preventing the PM emission hazard. Blended compositions containing more than 60% slurry have noxious effects on the grass seeds, inhibiting their germination. Full article

The western side of the Vertiskos Unit crystalline basement in northern Greece is fringed by a Permo–Triassic low-grade metamorphic volcano-sedimentary complex that belongs to the Circum-Rhodope Belt (CRB), which is an important part of the Vardar/ Axios oceanic suture zone. The silicic volcanic rocks from the CRB are mainly rhyolitic to rhyodacitic lavas with aphyric and porphyritic textures as well as pyroclastic deposits. In this study, geochemical data obtained with X-ray fluorescence (XRF) for the CRB silicic volcanic rocks are reported and discussed to constrain their petrogenesis and tectonic setting. The rocks are peraluminous and show enrichment in K, Rb, Th, Zr, Y, and Pb while being depleted in Ba, Sr, Nb, P, and Ti, and they have Zr + Nb + Y + Ce > 350 ppm, which are characteristic features of anorogenic A-type granites. They have a Y/Nb ratio > 1.2 and belong to A2-subtype granitoids, implying crust-derived magma in a post-collisional tectonic setting. The high Rb/Sr ratio (3.45–39.14), the low molar CaO/(MgO + FeO_t) ratio, and the CaO/Na₂O ratio (<0.5), which they display, indicate that metapelites are the magma sources. Their low Al₂O₃/TiO₂ ratio (<100), consistent with their high zircon saturation temperatures (average T_Zr = 886 °C), and their low Pb/Ba ratio (average 0.06) reveal that they were generated by biotite dehydration melting. The increased Rb/Sr ratio relative to that of presumable parental metapelites of the Vertiskos Unit, coupled with their low Sr/Y ratio (0.12–1.08), reflects plagioclase and little or no garnet in the source residue, indicating magma derivation at low pressures of 0.4–0.8 GPa that correspond to a depth of ~15–30 km. The nearby tholeiitic basalts and dolerites, interstratified with the Triassic pelagic sediments, indicate bimodal volcanism in the region. They also support a model involving an upwelling asthenosphere that underplated the Vertiskos Unit basement, supplying the heat required for crustal melting at low pressures. The Permo–Triassic magmatism marks the transition from an orogenic to an anorogenic environment during the initial stage of continental breakup of the Variscan basement in a post-collision extensional tectonic framework, leading to the formation of the nascent Mesozoic Neo-Tethyan Maliac–Vardar Ocean. This apparently reveals that the Variscan continental collision between the Gondwana-derived Vertiskos and Pelagonian terranes must have been completed by at least the earliest Late Permian. Full article

The northeastern region of India is one of the six most seismically active convergent plate tectonic areas in the world. The north–south convergence along the Indo-Tibetan Himalayan Ranges and the east–west subduction within the Indo-Burma Ranges create a complex stress regime, resulting in significant seismic activity and a history of great/large earthquakes. The region’s intricate strain patterns, active faults, and potential seismic gaps underscore the need for detailed subsurface studies to effectively assess seismic hazards and impending seismicity. Geophysical research is essential for understanding the region’s geodynamic evolution, seismotectonics, and mineral resources. This manuscript reviews the geological and tectonic settings of the region and summarizes recent geophysical studies, including seismic, gravity, magnetic, and magnetotelluric surveys conducted in the Assam Valley and adjacent areas (within latitudes 24.5–28.5° N and longitudes 89–97.5° E). The review highlights key findings on hydrocarbon-bearing sediments, the configuration of the crystalline basement, the heterogeneous structures of the crust and upper mantle, and seismic discontinuities. By synthesizing these results, the review aims to enhance the understanding of seismic hazards in Northeast India, guide mitigation strategies, and identify key knowledge gaps to direct future research efforts. Full article

Borsec is one of the most important mineral water spa resorts in Romania and is also an important mineral water bottling facility. There are several public springs with significant mineral content. The present paper focuses on mineral powder extraction by the drying of water samples collected from springs no. 3, 5, 6, 10, and 11. These springs have a continuous flow being available for everyone who wants to fill a bottle; meanwhile, the rest of the water is discarded into the river. Thus, the dissolved ions such as Ca²⁺, Mg²⁺, Na⁺, and Cl⁻ are wasted. This study aims to investigate the possibility of mineral content extraction as crystalline powder by drying. The dissolved ions’ reaction with carbonic acid generates carbonates which crystallize progressively with the water evaporation. Mineralogical investigation including X-ray diffraction (XRD) and polarized light optical microscopy (POM) reveal that calcite (rhombohedral and pseudo-hexagonal crystals of about 5–25 µm) is the dominant mineral followed by pseudo-dolomite (columnar crystals of about 5–20 µm), aragonite (rhombic and granular crystals of 2.5–15 µm), and natron (prismatic crystals of about 5–20 µm), in addition to small amounts of halite. Scanning electron microscopy (SEM) investigation combined with energy dispersive (EDS) elemental analysis indicates that traces of K are uniformly distributed in the calcite mass and some S traces for springs 3 and 11 are distributed predominantly into the pseudo-dolomite crystals. The crystalline germs precipitate from the supersaturated solution via homogeneous germination and progressively grow. The latest stage is characterized by the formation of a dendritic crust of calcite mixed with halite that embeds the individually grown crystals. The amount of the formed crystals strongly depends on the water’s total dissolved solids (TDS) and salinity: the springs with high TDS and salinity form a large number of crystals and spectacular dendritic crusts such as spring 10 followed by springs 6 and 5. Lower mineralization was observed in springs 3 and 5, which was related with the S traces. Also, it is evident that mineralization is seasonally dependent: the mineral amount was lower in November 2023 than for the samples collected in March 2024. The obtained mineral powder might be used for spa baths or for the electrolytic balance regulation in dietary supplements due to the high calcium and magnesium content. Full article

Ferromanganese (Fe-Mn) deposits are widely used in paleoenvironmental reconstructions owing to their mineralogical and geochemical properties. We analyzed Fe-Mn deposits using micro-X-ray fluorescence and Raman spectroscopy to study the paleo-ocean environment. Samples were collected from the OSM-XX seamount in the western Pacific. The Fe-Mn crust was divided into three parts: phosphatized, massive non-phosphatized, and porous non-phosphatized. Vernadite was identified in all layers. Furthermore, in the nodule, high values of Mn, Ni, and Cu were observed near the nucleus, with vernadite and todorokite, and these values decreased outward. A high Mn/Fe ratio near the nucleus indicates early diagenetic processes. Formation of Fe-Mn nodules began around 19–16 Ma, and this period corresponded to a minor phosphatization event and persistent reducing conditions. From 11–10 Ma, the Mn/Fe and Co/Mn ratios decreased due to the formation of a western Pacific warm pool during this period. Subsequently, with the opening of the Indonesian seaway and global cooling, the Mn/Fe and Co/Mn ratios in the Fe-Mn deposits increased again. The comparative analysis of variations in Mn/Fe ratio and vernadite crystallinity in the Fe-Mn deposits confirmed that it is possible to reconstruct paleo-productivity and redox condition changes in the western Pacific Magellan Seamount. Full article

Silicon dioxide (SiO₂), commonly known as silica, is a naturally occurring mineral extracted from the Earth’s crust. It is widely used in commercial products such as food, medicine, and dental ceramics. There are few studies on the health effects of pyrogenic and colloidal silica after ingestion. No research has compared the impact of microscale morphologies on mitochondrial activity in colon cells after acute exposure. The results show that crystalline and amorphous silica had a concentration-independent effect on cells, with an initial increase in mitochondrial activity followed by a decrease. Vitreous silica did not affect cells. Diatomaceous earth and pyrogenic silica had a concentration-dependent response, causing a reduction in mitochondrial activity as concentration increased. Diatomaceous earth triggered the highest cellular response, with mitochondrial activity ranging from 78.84% ± 12.34 at the highest concentration (1000 ppm) to 62.54% ± 17.43 at the lowest concentration (0.01 ppm) and an average H₂O₂ concentration of 1.48 ± 0.15 RLUs. This research advances our understanding of silica’s impact on human gastrointestinal cells, highlighting the need for ongoing exploration. These findings can improve risk mitigation strategies in silica-exposed environments. Full article

Migmatites and partial melts are exposed in both the lower and upper package of the Higher Himalayan Crystallines (HHC) thrust sheet within the Sikkim Himalayas. Zircon monazite and quartz oxygen isotopic ratios from Yumthang Valley, North Sikkim, and Rathong Chuu, West Sikkim, have been used to identify their sources and equilibrium conditions. Monazites show homogeneous growth, whereas zircons show growth rings. U-Th-Pb data on monazite only indicate the latest metamorphic event. However, zircons show metamorphic rim growth between 36 and 24 Ma over their detrital core with trailing growth from 22 Ma to 15 Ma. Pervasive fluids have been interpreted in coeval development during metamorphism, as shown by monazite and zircon c. 30 Ma. The Th/U ratio of zircon is higher and variable with weak residual zoning in the samples from higher elevations. Quartz–metamorphic zircon oxygen fractionation suggests Teq > 600 °C, while quartz–monazite fractionation shows the same or lower temperatures. Multiple sources of melts in the HHC (even along a single valley) have been observed by δ¹⁸O of 7‰ to 10‰ in zircon and 5‰ to 9‰ in monazite. Zircon and monazite generated in the same rock have similar δ18O values. Monazite grown ~20 Ma in the lower elevation sample had a low δ¹⁸O, suggesting interaction with an external fluid. Full article

The Nanling region is located at the intersection of the Yangtze Block and Cathaysia Block and is characterized by complex geological and tectonic processes, as well as distinct W-Sn-REE mineralization. Despite extensive research on the mineralization of W-Sn and REE deposits in the Nanling region, the factors impacting the distribution pattern of eastern tungsten and western tin deposits, as well as the mechanism of REE enrichment in the parent rocks, remain uncertain. Deep structural and tectonic variability plays a crucial role in the formation of mineral deposits in the upper crust. Information on deep structural and tectonic variability is contained in the Moho depth, Curie depth, effective elastic thickness, lithospheric density, and thermal structure derived from the processing and inversion of satellite gravity and magnetic data. In this paper, we comprehensively analyse satellite gravity and magnetic data from the Nanling region, integrating the processing and inversion results with the tectonic evolution of this region and relevant geological information. It is hypothesized that the Chenzhou–Linwu fault serves as a channel for mineral and thermal transfer in the Sn ore aggregation zone, facilitating the material transport from the deep mantle to the surface and ultimately leading to the formation of Sn-enriched granite. The collection area of tungsten ore is more weakly associated with the Chenzhou–Linwu fault, and through deep heat transfer, tungsten components are primarily concentrated in the Earth’s crust to produce W-enriched granite. The primary source of REE enrichment in the parent rocks associated with REE mineralization is predominantly derived from the felsic crust, and the rapid intrusion of deep magma resulting from the subduction and retraction of the Palaeo-Pacific Plate is a contributing factor to the contrasting enrichment of light and heavy rare-earth elements. Mineral crystalline differentiation is relatively high, leading to the formation of ore-forming parent rocks with high heavy rare-earth element contents. Full article

Rhenium is an extremely rare critical metal element in Earth’s continental crust. Owing to its extremely high melting point and heat-stable crystalline structure, rhenium is an essential component of alloy materials used in high-performance aircraft engines. Demand for rhenium resources is therefore growing. Currently, most rhenium is produced as a byproduct of molybdenum mining in porphyry copper–molybdenum deposits. Research has therefore focused on the enrichment characteristics of rhenium in this type of deposit, with little attention paid to rhenium in other types of deposits. This study reports the occurrence state and enrichment mechanism of rhenium in the Qianjiadian sandstone-type uranium deposit in the Songliao Basin, Northeast China. Sequential extraction revealed that the average proportions of different forms of rhenium are as follows: water-soluble (57.86%) > organic-sulfide-bound (13.11%) > residual (12.26%) > Fe/Mn oxide-bound (10.67%) > carbonate-bound (6.10%). Combining mineralogical analysis techniques such as SEM-EDS, EMPA, and XRD, it has been established that rhenium does not occur as a substitute in sulfides (e.g., molybdenite) or uranium minerals in various types of deposits. Instead, it is mainly adsorbed onto clay minerals and Fe-Ti oxides, and in a small number of other minerals (pyrite, organic matter, and pitchblende). Rhenium is similar to redox-sensitive elements such as uranium and vanadium, and it is transported in a water-soluble form by oxidizing groundwater to the redox transition zone for enrichment. However, unlike uranium, which generally forms as uranium minerals, rhenium is mainly adsorbed and enriched onto clay minerals (kaolinite and interlayered illite–smectite). Most of the rhenium in sandstone-type uranium deposits occurs in an ion-adsorption state, and is easily leached and extracted during in-situ leaching mining of uranium ores. This type of deposit demonstrates excellent production potential and will become a crucial recoverable resource for future rhenium supply. Full article

Since the early Paleozoic, numerous metallogenic events produced in the Sardinian massif a singular concentration of mineral deposits of various kinds. Among them, the Variscan metallogenic peak represents a late Paleozoic phase of diffuse ore formation linked to the tectonomagmatic evolution of the Variscan chain. Two main classes of ores may primarily be attributed to this peak: (1) mesothermal orogenic-type As-Au ± W ± Sb ores, only found in E Sardinia, and (2) intrusion-related Sn-W-Mo-F and base metals-bearing ores found in the whole Sardinian Batholith, but mainly occurring in central–south Sardinia. Both deposit classes formed diachronously during the Variscan post-compressional extension. The orogenic-type ores are related to regional-scale flows of mineralizing fluids, and the intrusion-related ores occur around fertile intrusions of different granite suites. Metallogenic reconstructions suggest almost entirely crustal processes of mineralization without a significant contribution from the mantle. We summarized these processes with a holistic approach and conceptualized the Sardinian Variscan Mineral System (SVMS), a crustal-scale physical system of ore mineralization in the Sardinian basement. The SVMS required suitable metal sources in the crust and diffuse crustal reworking triggered by heat that allowed (a) the redistribution of the original metal budget of the crust in magmas by partial melting and (b) the production of metal-bearing fluids by metamorphic dehydration. Heat transfer in the Sardinian Variscan crust involved shear heating in lithospheric shear zones and the role of mantle uplift as a thermal engine in an extensional tectonic setting. Lithospheric shear zones acted as effective pathways in focusing fluid flow through a large-scale plumbing system into regional-scale structural traps for ores. Pre-Variscan metal sources of metallogenic relevance may have been (1) the magmatic arc and magmatic arc-derived materials of Ordovician age, extensively documented in E Sardinia crust, and (2) an inferred Precambrian crystalline basement lying under the Phanerozoic crustal section, whose presence has been assumed from geophysical data and from petrological and geochemical characteristics of granite suites. At shallower crustal levels, important contributions of metals may have come from pre-Variscan ore sources, such as the Pb-Zn MVT Cambrian ores of SW Sardinia or the REE-bearing Upper Ordovician paleoplacers of E Sardinia. Full article

Featuring subtle lithological alterations in the host rocks and containing colossal gemstone crystals, the scheelite deposit at Xuebaoding in the Pingwu region of Sichuan Province exhibits characteristics typical of a vein-like hydrothermal-type deposit. The scheelite from the Xuebaoding region is renowned for its high saturation of color, perfect crystal shape, and pure color. In this study, its crystal structure and mineralogical, geochemical, and in situ Sr-Nd isotope characteristics are all systematically characterized. Our objective is to determine the source of ore-forming materials, the timing of the mineralization, and the chemical composition of scheelite, including major elements, trace elements, and rare earths elements (REE). The scheelite samples were analyzed with a variety of methods such as polarizing microscopy, X-ray powder diffraction (XRD), X-ray fluorescence spectrometry (XRF), electron probing, and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). In addition, conventional gemological tests were performed using instruments including gemstone microscopes, GI-UVB ultraviolet fluorescent lamps, grating spectroscopy, etc. The results demonstrate that scheelite exhibits a high refractive index, excellent crystallinity, and a granular structure. Clear color bands and ring structures are observed within the minerals, accompanied by interference colors of light blue, blue, and yellow. Additionally, the mineral components are relatively concentrated, with muscovite and illite serving as accessory minerals. Furthermore, the chemical composition of scheelite reveals a WO₃/CaO mass ratio that approaches or exceeds the ideal value. Moreover, it exhibits a wide range of variations in total rare earth element (∑REE) content, which is characterized by an enrichment of light rare earths (LREE), significant negative Eu anomalies, and insignificant Ce anomalies. In addition, the metallogenic formation of scheelite can be estimated to have occurred during the Toarcian stage in the Lower Jurassic Epoch period, approximately 183 Ma. The study further revealed that A-type granite serves as the genesis type of scheelite, with most of the ore-forming materials originating from the upper crust and a few derived from younger crustal sources. Full article

The aseismic Nazca Ridge produces localized flat-slab subduction beneath the South American margin at latitudes 10° to 15° S. The geological evolution and the spatio-temporal pattern of deformation of the upper plate have been strongly influenced by the presence of the flat slab. In this study, we investigated the lithospheric thermal structure of this region by elaborating a 2D geothermal model along a section across the top of the Nazca Ridge, the Peru–Chile trench, the Andean Cordillera, and the Amazonian Basin, for a total length of 1000 km. For the sake of modelling, the crust of the overriding plate was subdivided into two parts, i.e., a sedimentary cover (including the entire lithostratigraphic sequence) and a crystalline basement. Applying an analytical methodology, we calculated geotherms and isotherms by setting (i) thickness, (ii) density, (iii) heat production, and (iv) thermal conductivity for each geological unit and considering (v) heat flux at the Moho, (vi) frictional heating produced by faults, and (vii) plate convergence rate. The resulting model could make a significant advance in our understanding of how flat slab geometry associated with the Nazca Ridge subduction affects the thermal structure and hence the tectonic evolution of the region. Full article