Search Results (53)

As the largest cryogenic superconducting platform in China and even Asia, the Shanghai High-intensity Ultrafast X-ray Facility (SHINE) highly depends on the stable operation of 1.3 GHz superconducting accelerating modules in a 2 K superfluid helium environment. This paper elaborates on the key control technologies developed and successfully applied to ensure the smooth aging process of superconducting modules in the cryogenic experiments of the SHINE injector section. To address the issue of thermal load fluctuations caused by the dynamic changes in RF power during the aging process, a dynamic power compensation algorithm based on real-time cavity pressure feedback was proposed and implemented. Meanwhile, a multi-variable coupled PID control strategy was adopted to achieve high-precision stability of the helium tank liquid level (±1%) and cavity pressure (±10 Pa). Experimental results show that this integrated control scheme effectively suppresses the risk of quenching caused by thermal disturbances, significantly improving the aging efficiency and operational reliability of the superconducting modules. This lays a solid technical foundation for the commissioning and long-term stable operation of the superconducting systems of SHINE and similar large-scale scientific facilities. Full article

At DLR’s electric space propulsion vacuum test facility in Goettingen, spontaneous pressure rise events were observed, which led to interruptions of thruster testing. This study investigates the causes of four such events and presents a model that is able to simulate pressure rise events due to xenon ice sheet detachment from operating cryogenic pumps. The model results show good agreement with the observed pressure curves and can reproduce the pressure rise slope, event duration, down slope, and maximum pressure during these events. The masses of the detached xenon ice sheets are in the range from 2 g to 0.4 kg, which is reasonable with respect to the amount of ice on cryopump cold plates. This first modeling step is based on a phenomenological approach, but the good results show that it is worth expanding and refining the model, e.g., by introducing more ice shape options, adding ice bonding layer properties, and adding other gases and physical condensate properties. Full article

Silica-based multifunctional coatings hold great promise for applications in optical devices, lenses, and solar panels. Herein, we report a facile, low-temperature route to integrate super-hydrophobicity with high transparency and low haze. By precisely controlling particle gradation and applying fluorine passivation, a multi-scale structure with micro-scale uniformity and nano-scale asperity was constructed. This unique architecture, combined with low surface energy, effectively reduces light scattering and enhances air trapping. Consequently, the coated glass achieves a high optical transmittance of 95.24% with a low haze of 0.97%, alongside a water contact angle of 153° and a sliding angle of 3°. The coating also exhibits distinct anti-reflection (an improvement of ~5.0% relative to the bare substrate) and self-cleaning properties. Furthermore, it demonstrates impressive robustness and durability, withstanding extreme conditions including cryogenic temperatures (−50 °C), hygrothermal environments, and long-term outdoor exposure. This work demonstrates the versatile potential of our strategy for fabricating highly transparent and superhydrophobic surfaces. Full article

The cooling effect from the para-ortho hydrogen conversion (POC) combined with a vapor-cooled shield (VCS) and multi-layer insulation (MLI) can effectively extend the storage duration of liquid hydrogen in cryogenic tanks. However, there is currently no effective and straightforward empirical correlation available for predicting the catalytic POC efficiency in VCS pipelines. This study focuses on the development of correlations for the catalytic conversion of para-hydrogen to ortho-hydrogen in pipelines, particularly in the context of cryogenic hydrogen storage systems. A model that incorporates the Langmuir adsorption characteristics of catalysts and introduces the concept of conversion efficiency to quantify the catalytic process’s performance is introduced. Experimental data were obtained in the temperature range of 141.9~229.9 K from a cryogenic hydrogen catalytic conversion facility, where the effects of temperature, pressure, and flow rate on the catalytic conversion efficiency were analyzed. Based on a validation against the experimental data, the proposed model offers a reliable method for predicting the cooling effects and optimizing the catalytic conversion process in VCS pipelines, which may contribute to the improvement of liquid hydrogen storage systems, enhancing both the efficiency and duration of storage. Full article

Professor Hong Chaosheng, as the founding figure and pioneer of China’s hydrogen and helium cryogenic technology, played a pivotal role in advancing this field from its inception to global competitiveness. This paper systematically reviews the seven-decade-long cryogenic research trajectory of the Technical Institute of Physics and Chemistry, CAS (formerly the Cryogenic Technology Experimental Center), with particular emphasis on milestone scientific achievements and their significant applications. In the 1960s, the Institute’s breakthrough in long-piston-expander-precooled helium liquefaction technology provided critical support for China’s space technology and superconductivity research. Since the 21st century, building upon Professor Hong’s academic legacy, the Institute has successively overcome core technological challenges in developing high-speed helium turbine expanders, high-efficiency oil-flooded screw compressors, and superfluid helium temperature refrigeration systems. These innovations have yielded a complete series of large-scale cryogenic equipment with independent intellectual property rights. These advancements have been successfully applied in national megaprojects such as neutron sources and superconducting magnet testing facilities, with some technical parameters reaching internationally leading standards. Looking ahead, with the rapid development of quantum computing and fusion energy, China’s hydrogen–helium cryogenic technology will continue to optimize equipment performance while expanding application frontiers through enhanced international collaboration, thereby making greater contributions to cutting-edge scientific research and clean energy development. Full article

Thin-film detection technology plays a significant role in particle physics, X-ray imaging and radiation monitoring. In this paper, the detection capability of a Cs₃Cu₂I₅ thin-film scintillator toward α particles is investigated. The flexible thin-film scintillator is fabricated by a facile and cost-effective in situ strategy, exhibiting excellent scintillation properties. Upon α-particle excitation, the light yield of the Cs₃Cu₂I₅ thin-film is 2400 photons/MeV, which greatly benefits its application for single-particle events detection. Moreover, it shows linear energy response within the range of 4.7–5.5 MeV and moderate decay time of 667 ns. We further explored the cryogenic scintillation performance of Cs₃Cu₂I₅@PMMA film. As the temperature decreases from 300 K to 50 K, its light yield gradually increases to 1.3 fold of its original value, while its decay time remains almost unchanged. This scintillator film also shows excellent low-temperature stability and flexible operational stability. This work demonstrates the great potential of the Cs₃Cu₂I₅@PMMA film for the practical utilization in α-particle detection application. Full article

The Polish Free-Electron Laser (PolFEL), which is currently under construction in the National Centre for Nuclear Research in Świerk near Warsaw, will comprise an electron gun and from four to six cryomodules, each accommodating two nine-cell TESLA RF superconducting resonant cavities. To cool the superconducting resonant cavities, the cryomodules will be supplied with superfluid helium at a temperature of 2 K. Other requirements regarding the cooling power of PolFEL result from the need to cool the power couplers for the accelerating cryomodules (5 K) and thermal shields, which limit the heat inleaks due to radiation (40–80 K). The machine will utilize several thermodynamic states of helium, including two-phase superfluid helium, supercritical helium, and low-pressure helium vapours. Supercritical helium will be supplied from a cryoplant by a cryogenic distribution system (CDS)—transfer line and valve boxes—where it will be thermodynamically transformed into a superfluid state. This article presents the architecture of the CDS, discusses several design solutions that could have been decided on with the use of second law analysis, and presents the design methodology of the chosen CDS elements. Full article

Heavy industry is a significant contributor to CO₂ global emissions, accounting for approximately 25% of the total. In Europe, the continent’s largest emitting industries, including steel, cement, and power generation, face significant decarbonization challenges due to multiple interrelated factors. Heavy industry must achieve carbon neutrality by 2050, as outlined in the 13th United Nations Sustainable Goals. One strategy to achieve this goal involves Carbon Capture Utilization and Storage (CCUS) with post-combustion carbon capture (PCC) technologies playing a critical role. Key methods include absorption, which uses chemical solvents like amines; adsorption, employing solid sorbents; cyclic CO₂ capture, such as calcium looping methods; cryogenic separation, which involves chilling flue gas to liquefy CO₂; and membrane separation, leveraging polymeric materials. Each technology offers unique advantages and challenges, necessitating hybrid approaches and policy support for widespread adoption. In this sense, this review provides a comprehensive overview of the existing European pilot and demonstration units and projects, funded by the EU across several industries. It specifically focuses on PCC. This study examines 111 industrial facilities across Europe, documenting the PCC technologies deployed at plants of varying capacities, geographic locations, and operational stakeholders. The review further evaluates the techno-economic performance of these systems, assessing their potential to advance carbon neutrality in heavy industries. Full article

The Volumetric Neutron Source (VNS) is a pivotal facility proposed for advancing fusion nuclear technology, particularly for the qualification of breeding blanket systems, a key component of DEMO and future fusion reactors. This study focuses on the design and optimisation of the VNS Thermal Shield, adopting a multidisciplinary approach to address its thermal and structural behaviours. The Thermal Shield plays a crucial role in protecting superconducting magnets and other cryogenic components by limiting heat transfer from higher-temperature regions of the tokamak to the cryostat, which operates at temperatures between 4 K and 20 K. To ensure both thermal insulation and structural integrity, multiple design iterations were conducted. These iterations aimed to reduce electromagnetic (EM) forces induced during magnet charge and discharge cycles by introducing strategic cuts and reinforcements in the shield design. The optimisation process included the evaluation of various aluminium alloys and composite materials to achieve a balance between rigidity and weight while maintaining structural integrity under EM and mechanical loads. Additionally, an integrated thermal study was performed to ensure effective temperature management, maintaining the shield at an operational temperature of around 80 K. Cooling channels were incorporated to homogenise temperature distribution, improving thermal stability and reducing thermal gradients. This comprehensive approach demonstrates the viability of advanced material solutions and design strategies for thermal and structural optimisation. The findings reinforce the importance of the VNS as a dedicated platform for testing and validating critical fusion technologies under operationally relevant conditions. Full article

Recent research in the liquefied natural gas (LNG) industry has concentrated on reducing specific power consumption (SPC) during production, which helps to lower operating costs and decrease the carbon footprint. Although reducing the SPC offers benefits, it can complicate the system and increase investment costs. This review investigates the thermodynamic parameters of various natural gas (NG) liquefaction technologies. It examines the cryogenic NG processes, including integrating NG liquid recovery plants, nitrogen rejection cycles, helium recovery units, and LNG facilities. It explores various approaches to improve hybrid NG liquefaction performance, including the application of optimization algorithms, mixed refrigerant units, absorption refrigeration cycles, diffusion–absorption refrigeration systems, auto-cascade absorption refrigeration processes, thermoelectric generator plants, liquid air cold recovery units, ejector refrigeration cycles, and the integration of renewable energy sources and waste heat. The review evaluates the economic aspects of hybrid LNG systems, focusing on specific capital costs, LNG pricing, and capacity. LNG capital cost estimates from academic sources (173.2–1184 USD/TPA) are lower than those in technical reports (486.7–3839 USD/TPA). LNG prices in research studies (0.2–0.45 USD/kg, 2024) are lower than in technical reports (0.3–0.7 USD/kg), based on 2024 data. Also, this review investigates LNG accidents in detail and provides valuable insights into safety protocols, risk management strategies, and the overall resilience of LNG operations in the face of potential hazards. A detailed evaluation of LNG plants built in recent years is provided, focusing on technological advancements, operational efficiency, and safety measures. Moreover, this study investigates LNG ports in the United States, examining their infrastructures, regulatory compliance, and strategic role in the global LNG supply chain. In addition, it outlines LNG’s current status and future outlook, focusing on key industry trends. Finally, it presents a market share analysis that examines LNG distribution by export, import, re-loading, and receiving markets. Full article

Cooling down large test masses up to 200 kg, as foreseen for the Einstein Telescope, is a complex challenge combining cutting-edge technological achievements from different disciplines with the experience gained from both room-temperature and cryogenic-temperature detector development communities. We set up an apparatus designed to test cryogenic mechanical suspensions for the payload system. They should have high quality factors and enable sufficient heat extraction greater than $0.3$ W. The facility is on a university campus where cryofluid servicing is not feasible. As a result, a system that incorporates conductive cooling technology was developed. The project has two main goals: validating crystalline suspensions in a realistic Einstein Telescope cryogenic payload and testing new solutions for radiative thermal shielding. No particular measures are planned for the vibration isolation system. Full article

This paper introduces a new methodology for a routine metal analysis of plastic waste (PW) and PW blended with petroleum feedstock such as vacuum gas oil and VGO (PW/VGO). For such purposes, recycled polyethylene and polypropylene plastic were selected to mimic the potential feeds to be integrated at the Fluid Catalytic Cracking unit (FCC) to produce valuable products. Elements such as P, Ca, Al, Mg, Na, Zn, B, Fe, Ti, and Si were included in the method development. Different sample preparation methods were evaluated, such as microwave-assisted acid digestion (MWAD) and dry/wet ashing, followed by a fusion of the ash with lithium borate flux. Some PW homogenization pretreatments, such as cryogenic grinding and hot press molding, were also covered. The finding of this work suggests that MWAD with HNO₃ and H₂O₂ is adequate for both types of samples and is the quickest sample preparation; however, the sample needed to be homogenized, and recoveries for Si and Ti may be biased for PW due to the limited solubilities of these elements in the nitric acid media. Carbon removal is required before fusion sample preparation and analysis due to the amount of carbon in PW samples. The sample needed to be homogenized for wet ash fusion but not for the pre-ash (dry) method. A benefit to the damp ash pretreatment is that the ash for the sample was created in the same crucible used for fusion digestion, avoiding material loss during sample management. Fusion from wet ash or carbon removal allowed for better acid solubility for Si and Ti in PW. The results of the PW samples evaluated matched well with those of both sample preparation methodologies. For most elements, precision was <10% regardless of the sample preparation; however, Fe and P had some variation using wet ash fusion, possibly due to contamination in an open digestion system or variation due to being close to the method limit of quantification (LOQ). The methodology reported here is robust enough to be implemented as routine analysis in any laboratory facility. Full article

Controlling the hierarchical self-assembly of surfactants in aqueous solutions has drawn much attention due to their broad range of applications, from targeted drug release, preparation of smart material, to biocatalysis. However, the synthetic procedures for surfactants with stimuli-responsive hydrophobic chains are complicated, which restricts the development of surfactants. Herein, a novel single-tailed responsive surfactant, 1-methyl-3-(2-(4-((tetradecylimino) methyl) phenoxy) ethyl)-3-imidazolium bromides (C₁₄PMimBr), was facilely fabricated in situ by simply mixing an aldehyde-functionalized imidazolium cation (3-(2-(4-formylphenoxy) ethyl)-1-methyl imidazolium bromide, BAMimBr) and aliphatic amine (tetradecylamine, TDA) through dynamic imine bonding. With increasing concentration, micelles, vesicles, and hydrogels were spontaneously formed by the hierarchical self-assembly of C₁₄PMimBr in aqueous solutions without any additives. The morphologies of vesicles and hydrogels were characterized by cryogenic transmission electron microscopy and scanning electron microscopy. The mechanical properties and microstructure information of hydrogels were demonstrated by rheological measurement, X-ray diffraction, and density functional theory calculation. In addition, the vesicles could be disassembled and reassembled with the breakage and reformation of imine bonds by adding acid/bubbling CO₂ and adding alkali. This work provides a simple method for constructing stimuli-responsive surfactant systems and shows great potential application in targeted drug release, drug delivery, and intelligent materials. Full article

The application of terahertz (THz) science in industrial technology and scientific research requires efficient THz detectors. Such detectors should be able to operate under various external conditions and conform to existing geometric constraints in the required application. Pyroelectric THz detectors are among the best candidates. This is due to their versatility, outstanding performance, ease of fabrication, and robustness. In this paper, we propose a compact pyroelectric detector based on a bioriented poled polyvinylidene difluoride film coated with sputtered metal electrodes for in situ absorption measurement at cryogenic temperature. The detector design was optimized for the registration system of the electron paramagnetic resonance (EPR) endstation of the Novosibirsk Free Electron Laser facility. Measurements of the detector response to pulsed THz radiation at different temperatures and electrode materials showed that the response varies with both the temperature and the type of electrode material used. The maximum signal level corresponds to the temperature range of 10–40 K, in which the pyroelectric coefficient of the PVDF film also has a maximum value. Among the three coatings studied, namely indium tin oxide (ITO), Au, and Cu/Ni, the latter has the highest increase in sensitivity at low temperature. The possibility of using the detectors for in situ absorption measurement was exemplified using two typical molecular spin systems, which exhibited a transparency of 20–30% at 76.9 cm⁻¹ and 5 K. Such measurements, carried out directly in the cryostat with the main recording system and sample fully configured, allow precise control of the THz radiation parameters at the EPR endstation. Full article

To predict the favorable thermodynamical conditions and characterize cryogenic pellet formations for applications in nuclear fusion reactors, a high–throughput molecular dynamics study based on a unified framework to simulate the growth process of cryogenic solids (molecular deuterium, neon, argon) under gas pressure have been designed. These elements are used in fusion nuclear plants as fuel materials and to reduce the damage risks for the plasma-facing components in case of a plasma disruption. The unified framework is based on the use of workflows that permit management in HPC facilities, the submission of a massive number of molecular dynamics simulations, and handle huge amounts of data. This simplifies a variety of operations for the user, allowing for significant time savings and efficient organization of the generated data. This approach permits the use of large-scale parallel simulations on supercomputers to reproduce the solid–gas equilibrium curves of cryogenic solids like molecular deuterium, neon, and argon, and to analyze and characterize the reconstructed solid phase in terms of the separation between initial and reconstructed solid slabs, the smoothness of the free surfaces and type of the crystal structure. These properties represent good indicators for the quality of the final materials and provide effective indications regarding the optimal thermodynamical conditions of the growing process. Full article