Search Results (30)

This study investigates the provenance, weathering history, and tectono-sedimentary evolution of lower Ediacaran siliciclastic rocks of the Imiter Formation (Saghro Group, Imiter Sub-inlier, Anti-Atlas, Morocco) deposited along the northern margin of Gondwana. An integrated approach combining petrography, whole-rock major and trace element geochemistry, rare earth elements (REEs), Sm–Nd isotopes, and organic geochemistry (TOC and δ¹³C_org) was used to constrain sediment sources and depositional conditions. Geochemical proxies, including Th/Sc, La/Sc, and Zr/Sc ratios, together with REE distribution patterns, indicate that the sediments were mainly derived from felsic-to-intermediate rocks of the upper continental crust, with only minor sediment recycling. The negative εNd(t) values (−8.5 to −6.2) and Paleoproterozoic Nd model ages (1.6–2.1 Ga) further suggest the erosion of evolved crustal sources related to the West African Craton. Weathering indices (CIA, CIW, PIA) suggest weak-to-moderate chemical weathering under predominantly arid conditions. Redox-sensitive proxies (V–Ni, V/Cr, V/(V + Ni)) and low TOC content (0.1–0.3 wt.%) indicate deposition under mainly oxic-to-dysoxic conditions, with only transient reducing episodes. Tectonic discrimination diagrams, supported by regional magmatism, point to sedimentation within an extensional basin evolving from active-margin to continental rift conditions during the late Pan-African orogeny. The Imiter Formation records a system dominated by crustal recycling, syn-rift tectonics, and dynamic redox conditions in a shallow marine environment. Full article

This study integrates LA-ICP-MS zircon U–Pb ages and the first zircon trace element data from metasedimentary and metaigneous rocks of the Nyong Complex (NyC) in the NW Congo Craton, southern Cameroon, to constrain its petrogenesis, tectonic setting, and crustal evolution. Chondrite-normalized REE patterns show strong HREE enrichment, depleted LREE–MREE, and pronounced positive Ce and negative Eu anomalies, indicating a magmatic origin for the zircons. Trace element signatures suggest that the zircons derived from continental crustal magmas generated under variable oxidation conditions in a long-lived arc-related tectonic environment. Detrital zircon ages range from Archean to Paleoproterozoic, with five major age peaks at 2885 ± 8 Ma, 2775 ± 6 Ma, 2654 ± 7 Ma, 2469 ± 11 Ma, and 2316 ± 11 Ma. These ages correspond to major magmatic and metamorphic events recognized in both the Congo and São Francisco cratons. The preservation of felsic continental crust between 2.9 and 2.2 Ga in the NyC and the Borborema Province (NE Brazil) likely records a critical transition in Earth’s geodynamic regime, marked by enhanced consumption and recycling of mafic crust during Proterozoic accretion compared to the late Archean. This transition reflects the onset of modern-style plate tectonics, enabling craton stabilization and contributing to the assembly of the Nuna/Columbia supercontinent. The NyC is thus interpreted as part of the Trans-Amazonian belt, analogous to that in NE Brazil, and formed during the collision between the Congo and São Francisco cratons. Full article

The Dibaya Granitic and Migmatitic Complex (DGMC), located in the Kanyiki–Kapangu sector of the Kasaï Shield (Congo–Kasaï Craton, Democratic Republic of the Congo), represents a key exposure of Neoarchean continental crust in Central Africa. Despite its geological importance, information on its petrology, geochronology, geochemistry, and structural evolution remains dispersed across historical studies. This contribution presents a structured geological synthesis based exclusively on previously published cartographic, petrographic, structural, and isotopic data. No new analytical data are introduced; rather, existing datasets are systematically compiled, critically reassessed, and integrated into a coherent tectono-thermal framework. Published Rb–Sr and U–Pb ages indicate high-grade metamorphism and widespread migmatitization at ca. 2.72 Ga, followed by granitoid emplacement at ca. 2.65 Ga. Documented mineral assemblages (garnet–biotite–plagioclase–quartz ± K-feldspar ± amphibole) and the absence of reported high-pressure index minerals support high-temperature, moderate-pressure metamorphism consistent with intracrustal reworking. Reported regional geochemical characteristics suggest high-K calc-alkaline, weakly to moderately peraluminous granitoids derived predominantly from reworking of older TTG-type crust. Structural relationships, particularly along the Malafudi corridor, demonstrate strong coupling between deformation, anatexis, and magma emplacement. Collectively, this synthesis formalizes a Neoarchean intracrustal reworking model and provides a structured analytical basis for future high-resolution petrochronological and geochemical investigations. Although no new quantitative datasets are presented, this study provides the first systematic integration of dispersed geological and isotopic information for the Dibaya Complex, establishing a transparent analytical framework for future high-resolution investigations. Full article

Under the vision of carbon neutrality, the global energy system urgently requires storable, transportable, and tradable zero-carbon carriers. Iron, due to its high crustal abundance, low cost, environmentally friendly reaction products, and ease of closed-loop cycling, is being reconsidered as a potential “metallic energy” alternative to fossil fuels. This paper systematically reviews the conceptual evolution, scientific lineage, and paradigm shift logic of iron-based energy within the framework of dual pathways: combustion and electrochemistry. On the combustion front, a multi-level understanding has been established—ranging from microscopic reaction mechanisms to macroscopic flame propagation, and from unit combustors to diversified thermal power systems—laying a methodological foundation for an integrated “solid fuel–thermal–power” approach. In parallel, the electrochemical pathway has developed both liquid and solid routes, integrating energy storage, pollution control, and resource recovery within a single device through multi-valent redox reversibility, thereby expanding the concept of generalized energy storage under the “battery-as-factory” paradigm. Current research is shifting its focus from single performance metrics toward synergistic optimization of efficiency, lifespan, cost, safety, and environmental impact, marking a transition in technological paradigm from “material trial-and-error” to “mechanism design.” Looking forward, to advance iron energy beyond the experimental validation stage, it is imperative to establish a cross-scale, closed-loop scientific characterization system, develop recycling strategies with low entropy and low energy consumption, and deeply integrate with renewable electricity, hydrogen, and high-temperature heat sources to form spatiotemporally transferable zero-carbon energy systems. In this way, iron may integrate into global energy trade as a “metallic energy in specific scenarios like ports/islands,” offering a scalable, hydrocarbon-independent technological option for achieving carbon neutrality. Full article

The North China Craton (NCC), one of the oldest cratons worldwide, may provide information on the evolution and geodynamic processes of the early Earth, especially during the pre-Mesoarchean period. Many ancient zircons have been discovered in the Jiapigou terrane of the northeastern NCC on the basis of our recent studies, providing an excellent opportunity to trace the early crustal evolution trend of the NCC. Here, we present a detailed study of the petrography, mineralogy, zircon U–Pb dating and Lu–Hf isotopes of supracrustal rocks (biotite schist) obtained from the Jiapigou terrane. Geochronology combined with the internal structures and Th/U ratios of the zircons reveal that the zircons acquired from the supracrustal rock can be divided into the following two types: magmatic zircons and metamorphic zircons. Among the magmatic zircons, the youngest zircon age (2.49 Ga) is considered to represent the time at which the protolith of the supracrustal rock (i.e., Neoarchean) crystallized, whereas the others were likely captured or inherited from their magma sources. The zircon Hf isotopes reveal that unexposed Hadean–Paleoarchean crust (4.18–3.57 Ga) is present beneath the Jiapigou terrane, and its growth history can be traced back to the Hadean period. Moreover, the evidence derived from this and previous studies indicates that the Jiapigou terrane underwent two crustal recycling events (3.37–3.20 Ga and ~2.96 Ga) during the Paleoarchean, two crustal reworking episodes (2.53 Ga and 2.49 Ga) during the Neoarchean, and later metamorphism at 2.41 Ga. Thus, the Jiapigou terrane has undoubtedly recorded multiple episodes of early crustal growth and/or reworking that are similar to, but not limited to, those of the northern and southern margins of the NCC. Full article

The Muji carbonic springs on the northeastern margin of the Pamir Plateau provide a natural window into tectonically controlled CO₂ degassing within a continental collision zone. Through mineralogical and geochemical analyses, this study constrains the formation mechanisms and regional geological significance of carbonic spring systems. The formed deposits are dominated by calcite and aragonite, with minor dolomite, quartz, and gypsum. The compositions of major elements are consistent with the observed mineral assemblages, reflecting that the carbonate deposition was mainly governed by CO₂ degassing intensity and associated kinetic effects under cold-spring conditions. Carbon isotopes of the deposits are consistently enriched in heavy carbon with δ¹³C values of +3.5‰ to +9.1‰, indicating a persistent contribution of deep-sourced CO₂, most likely derived from metamorphic decarbonation of the crustal carbonates. Calcite exhibits moderate δ¹³C values due to rapid precipitation limiting isotope enrichment, whereas aragonite records higher δ¹³C signatures under subdued degassing and stable hydrodynamic regimes. The narrow δ¹⁸O range (−10.7‰ to −12.6‰), closely matching that of the spring waters, indicates that the tufas record the δ¹⁸O of the spring waters through DIC-water oxygen exchange. Trace element distributions (Sr–Ba–U) reveal systematic enrichment in deep-sourced fluids and progressive downstream geochemical alteration driven by spring–river mixing. The HD springs show high Sr and δ¹³C values, indicating minimal dilution of ascending CO₂-rich fluids, while MJX and MJXSP groups record variable degrees of shallow mixing. Collectively, the Muji system exemplifies a coupled process of “deep fluid input–shallow mixing–precipitation kinetics.” Its persistent heavy δ¹³C and trace-element enrichments demonstrate persistent metamorphic CO₂ release through fault conduits under ongoing compression. These findings establish the Muji springs as a key non-volcanic analogue for deep CO₂ degassing in continental collision zones and provides new insights into crustal carbon recycling and tectonic–hydrochemical coupling at plateau margins. Full article

The Altun Orogenic Belt (AOB) has undergone multiple complex subduction–collision events. However, there are numerous disagreements regarding the Early Paleozoic tectonic–magmatic evolution of the AOB, primarily due to differing interpretations of magmatic rock types and their sources. As a result, we conducted detailed geochemical analyses of granite samples obtained from several exploration wells in the Dongping area (DPA) of the South Altun Orogenic Belt (SAOB) at the western boundary of the Qaidam Basin. This approach differs from previous studies that mainly relied on outcrop samples. The granites in the study area are metaluminous and have high alkali contents (avg. 7.63%) and high TFe₂O₃/MgO ratios (avg. 4.50). Their rare-earth elements are enriched in light REEs and show weak to moderate negative Eu anomalies (δEu = 0.49–1.11). These geochemical signatures indicate an affinity to A-type granites. Through comprehensive diagram analysis, the rocks plot near the upper crustal composition in a Ta/Yb-Th/Yb diagram, indicating that they primarily originated from a mixed source of recycled and juvenile crustal material. A comprehensive analysis of the regional tectonic background shows that the Early Paleozoic granites in the SAOB formed in post-collisional extensional environments and syn-collisional volcanic arc tectonic settings. The majority formed in post-collisional extensional thinning environments, whereas a minority formed in syn-collisional volcanic arc tectonic settings, closely related to the subduction and collision of the Qaidam Block beneath the Central Altun Block. Full article

The Weimei Formation, the most complete Upper Jurassic sedimentary sequence in the Tethyan Himalaya, is crucial for understanding the tectono-sedimentary evolution of the northern Indian margin. However, its depositional environment remains debated, with conflicting shallow- and deep-water interpretations. This study integrates sedimentary facies, petrography, zircon geochronology, and geochemical analyses to constrain the provenance, depositional environment, and tectonic setting of the Weimei Formation. The results reveal that the sedimentary system primarily consists of shoreface, delta, and shelf facies, with locally developed slope-incised valleys. Detrital zircon ages are concentrated at ~468 Ma and ~964 Ma, indicating a provenance mainly derived from the Indian continent. Geochemical characteristics, such as high SiO₂, low Na₂O–CaO–TiO₂ contents, right-leaning REE patterns, and significant negative Eu anomalies, suggest the derivation of sediments from felsic upper crustal recycling within a passive continental margin. Stratigraphic comparison between southern and northern Tethyan Himalayan sub-zones reveals a paleogeographic “uplift–depression” pattern, characterized by the coexistence of shoreface–shelf deposits and slope-incised valleys. This study provides key evidence for reconstructing the Late Jurassic paleogeography of the northern Indian margin and the tectonic evolution of the Neo-Tethys Ocean. Full article

Rare-earth elements (REEs), including lanthanides, scandium, and yttrium, are important for advanced technologies such as renewable energy systems, electronics, medical diagnostics, and precision agriculture. Despite their relative crustal abundance, REE extraction is impeded by complex geochemical behavior, dispersed distribution, and environmental challenges. This review presents a comprehensive overview of REE geochemistry, mineralogy, and major deposit types including carbonatites, alkaline igneous rocks, laterites, placer deposits, coal byproducts, and marine sediments. It also highlights the global distribution and economic potential of key REE projects. The integration of machine learning has further enhanced exploration by enabling deposit classification and geochemical modeling, especially in data-limited regions. Environmental and health challenges associated with REE mining, processing, and electronic waste (e-waste) recycling are studied, along with the expanding use of REEs in agriculture and medicine. Some recycling efforts offer promise for supply diversification, but significant technological and economic barriers remain. Ensuring a secure and sustainable REE supply will require integrated approaches combining advanced analytics, machine learning, responsible extraction, and coordinated policy efforts. The present review offers a general overview that can be useful for informing future studies and resource-related discussions. Full article

Zircon serves as a robust tracer for crustal recycling processes owing to its wide stability under diverse geological conditions. Its cryptic occurrence within ophiolites offers valuable insights into regional paleotectonic evolution. In this study, we identify a few zircon xenocrysts in both peridotite and basalt units from the Neoproterozoic South Anhui Ophiolite (SAO) in the southeastern Yangtze Block, South China. Zircon xenocrysts within the peridotite yield U-Pb ages ranging from ca. 2.7 to 1.0 Ga (n = 21), with three peaks of 2.8–2.5 Ga, 2.2–1.8 Ga, and 1.2–1.0 Ga. Comparative analysis of age spectra suggests these xenocrysts likely originated from recycled subducted continental materials within the Yangtze Block. In the basaltic rocks, zircon xenocrysts exhibit ages of ca. 2.1–0.9 Ga (n = 27), with peaks of 1.1–0.9 Ga, 1.5–1.4 Ga, and 2.1–1.7 Ga. These zircons are interpreted to have been inherited from wall rocks through crustal contamination during magma ascent, as their age spectra closely resemble those of the surrounding basement strata. Collectively, these findings support that the SAO possibly formed in a back-arc basin setting, characterized by significant crust–mantle interactions. Full article

The Lower Congo Basin (LCB) is a rift-type basin with petroleum systems that developed at the western African margin in association with the opening of the South Atlantic. Two pre-salt siliciclastic units of the LCB, Lucula (uppermost Jurassic to Lower Cretaceous) and Chela (Aptian) formations, were sampled in deep wells and outcrops. Heavy mineral assemblages, XRD mineralogy and geochemistry indicate prevailing source in high rank metamorphic rocks from western regions of the Lower Congo Belt. However, sediment composition reveals some provenance heterogeneity. For the Chela Formation, occasionally abundant amphibole in the heavy mineral fraction, coupled with relatively high Fe and Ti proportions, suggest that it formed when deeper crustal units were exhumed. The Lucula Formation collected in outcrops have composition substantially different from Lucula and Chela samples collected in deep wells, indicating distinct provenance and the incorporation of recycled material. A significant diagenetic overprint compromises the interpretation of compositional features in terms of paleoclimate. The presence of a chemical component with dolomite, halite and diverse sulphates and the stratigraphic position of the Chela Formation at the transition to a thick evaporitic succession are compelling evidence of deposition under warm and dry conditions, which are probably more extreme than those associated with the original stages of rifting recorded by the Lucula Formation. Full article

The Muteh–Golpaygan metamorphic complex, situated within the Sanandaj–Sirjan zone of Iran, represents a pivotal site for investigating the late Neoproterozoic Cadomian orogeny and its implications for crustal evolution along the northern margin of Gondwana. This study integrates geochemical, isotopic, and geochronological data to elucidate the petrogenesis, magma sources, and geodynamic significance of granitic (ortho-) gneisses from this region. The granitic gneisses are predominantly peraluminous and calc-alkaline, with A/CNK [molar Al₂O₃/(CaO + Na₂O + K₂O)] values ranging from 1.05 to 1.43. They exhibit enrichment in light rare earth elements (LREEs), flat heavy REE (HREE) patterns, and pronounced negative Eu anomalies, suggesting that the magma was derived from subduction-related melts that interacted with metasedimentary materials in the upper crust. Zircon U-Pb geochronology reveals crystallization ages of ~570–560 Ma, with inherited zircons dating back to the Neoarchean and Paleoproterozoic. Isotopic signatures, including εHf(t) values (−7.2 to +6.2) and δ¹⁸O values (+7.07‰ to +9.88‰), indicate a complex interplay between juvenile mantle-derived components and reworked crustal materials. Geodynamically, the magmatic characteristics align with an active continental margin setting driven by the subduction of the Proto-Tethys Ocean. Comparisons with coeval magmatism in the Arabian–Nubian Shield and Anatolia indicate a unified tectonic framework along the northern margin of Gondwana. This study provides critical insights into the tectono-magmatic processes of the Cadomian orogeny, emphasizing the roles of subduction dynamics, crustal recycling, and juvenile contributions in shaping the early continental lithosphere. Full article

In order to better constrain the specific depositional age and provenance of the Danzhou Group and understand the geological evolution of the Jiangnan Orogenic Belt, we conducted a combined U-Pb and Hf-isotope analysis of detrital zircons from the Gongdong and Hetong formations of the Danzhou Group in the Longsheng area of the Western Jiangnan Orogenic Belt. Detrital zircons from the Gongdong Formation yield three age populations of 2658–2517 Ma, 2427–1678 Ma and 891–781 Ma, and the youngest ages suggest that the sedimentation began after ca. 783 Ma. U-Pb ages of detrital zircons from the Hetong Formation yield major populations at 2769–2502 Ma, 2492–2100 Ma, and 991–731 Ma, and the youngest ages redefine the maximum depositional age of this unit is 760 Ma, much younger than previously considered. Thus, the upper part of the Hetong Formation in the Longsheng area is newly subdivided into the Sanmenjie Formation, which is characterized by a large amount of 765–761 Ma volcanic rocks. The dominant 991–731 Ma detrital zircons for all samples were likely sourced from the Neoproterozoic igneous rocks of the southeast margin of the Yangtze Block. The subordinate 2494–1678 Ma detrital zircons were probably sourced from the Cathaysia Block. Minor amounts of 2769–2502 Ma detrital zircons may have been sourced from the Yangtze Block. Detrital zircons from the Gongdong Formation have mainly negative εHf (t) values (−1.1 to 21.8, 90%), suggesting that the detritus of the Gongdong Formation is dominated by the recycling of old crustal materials. The εHf (t) values of detrital zircons from the Hetong Formation have a large spread of −22.2 to +9.7, indicating that the source material of the Hetong Formation includes both the juvenile crustal materials and the recycled ancient crustal materials. The above age populations and Hf isotopic characteristics are consistent with the magmatic rocks in the Jiangnan Orogenic Belt and the Southeast Yangtze Block. Taking into account the lithostratigraphic features, provenances, and depositional ages, the Danzhou Group in the Western Jiangnan Orogenic Belt was deposited in a back-arc basin. Full article

This study examines the chemical and mineralogical composition of waste materials from abandoned copper and manganese mines in the Iberian Pyrite Belt, Portugal, as a first step toward their potential recycling for critical and strategic raw materials (CRM and SRM). Using portable X-ray fluorescence (pXRF) and other analytical techniques, this research highlights the presence of valuable elements, including copper, manganese, and rare earth elements, in concentrations significantly above their crustal abundance. The findings underscore the dual potential of these wastes: as sources of secondary raw materials and for mitigating environmental hazards such as acid mine drainage (AMD). Recovered materials include chalcopyrite, pyrolusite, and rhodochrosite, with critical elements like cobalt, lithium, and tungsten identified. pXRF proved to be a reliable, cost-effective tool for rapid field and laboratory analyses, demonstrating high precision and good correlation with standard laboratory methods. The study emphasizes the importance of characterizing historical mining waste to support a circular economy, reduce reliance on foreign material imports, and address environmental challenges. This approach aligns with the European Union’s Critical Raw Materials Act, promoting sustainable resource use and the recovery of strategic resources from historical mining sites. Full article

The exact geological processes involved in the formation of subduction zone-related carbonatites remain ambiguous, along with their implications for crustal/carbon recycling in carbonatite melt generation. This study provides new geochemical and stable (C, O) and radiogenic (Sr, Nd, Pb) isotope data for Huangshuian carbonatite, located within the Lesser Qinling Orogen, with the aim to decipher its complex petrogenetic history. The carbonatites display elevated CaO, low MgO and alkali contents, and significant enrichments of Pb, Mo, and HREEs compared to typical carbonatites. The δ¹³C_PDB (−4.6 to −4.9‰) and δ¹⁸O_SMOW (+6.6 to +7.8‰) values plot within the field of primary igneous carbonatites. The carbonatites are characterized by consistent radiogenic isotopic compositions [(⁸⁷Sr/⁸⁶Sr)_i = 0.70599–0.70603; εNd = −10.4 to −12.8; ²⁰⁶Pb/²⁰⁴Pb =16.24–17.74]. These combined results suggest that the carbonatites represent late-stage differentiation products of a parental, mantle-derived carbonatite melt. Their corresponding Sr-Nd-Pb isotopic compositions support the hypothesis that the Lesser Qinling carbonatites originate from a heterogeneous upper mantle source involving an EMI-like mantle component coupled with minor assimilation of the basement rocks. The parental carbonatite melt was derived by the melting of carbonate-bearing subcontinental lithospheric mantle metasomatized as the result of Early Triassic subduction of the Mianlue Ocean. Full article