Search Results (143)

Epoxy resins are widely used as protective coatings in civil infrastructure, yet sulfate-rich environments accelerate their deterioration. This study evaluates the effectiveness of multi-walled carbon nanotubes (MWCNTs) in enhancing the sulfate resistance of epoxy resins. Neat and MWCNT-reinforced epoxy specimens (0.25 wt.% and 0.5 wt.%) were fabricated, heat cured at 100 °C and exposed to a solution of sulfuric acid and sodium chloride maintaining a pH of less than 3 for 0, 30, and 60 days. Analytical techniques, including scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS), revealed distinct degradation patterns: the neat epoxy exhibited puncture damage and extensive salt deposition, while the MWCNT-reinforced specimens showed crack propagation mitigated by nanotube bridging. Heat curing introduced micro-voids that exacerbated sulfate ingress. The salt deposition surged to 200 times for the MWCNT-reinforced specimens compared to the neat ones, whereas crack width was higher in the MWCNT reinforced specimen compared to their neat counterparts, given that crack-bridging was observed. These findings highlight the potential of MWCNTs to improve epoxy durability in sulfate-prone environments, though the optimization of curing conditions and dispersion methods is critical. Full article

This study investigates the effect of the surface functionalization of tungsten disulfide (WS₂) nanoparticles with aminoacetic acid (glycine) on the structure, curing behavior, and mechanical performance of epoxy nanocomposites. Aminoacetic acid, as a non-toxic, bio-based modifier, enables a sustainable approach to producing more efficient nanofillers. Functionalization, as confirmed by FTIR, EDS, and XRD analyses, led to elevated surface polarity and greater chemical affinity between WS₂ and the epoxy matrix, thereby promoting uniform nanoparticle dispersion. The strengthened interfacial bonding resulted in a notable decrease in the curing onset temperature—from 51 °C (for pristine WS₂) to 43 °C—accompanied by an increase in polymerization enthalpy from 566 J/g to 639 J/g, which reflects more extensive crosslinking. The SEM examination of fracture surfaces revealed tortuous crack paths and localized plastic deformation zones, indicating superior fracture resistance. Mechanical testing showed marked improvements in flexural and tensile strength, modulus, and impact toughness at the optimal WS₂ loading of 0.5 phr and a 7.5 wt% aminoacetic acid concentration. The surface-modified WS₂ nanoparticles, which perform dual functions, not only reinforce interfacial adhesion and structural uniformity but also accelerate the curing process through chemical interaction with epoxy groups. These findings support the development of high-performance, environmentally sustainable epoxy nanocomposites utilizing amino acid-modified 2D nanofillers. Full article

This paper assesses experimentally and theoretically the hydrogen-assisted cracking sensitivity of an ultrahigh-strength lath martensitic steel, recently used to manufacture tendon rods for structural engineering. The experimental values of the J-integral were obtained by tensile testing up to failure precracked SENT specimens in air, as an inert environment and in a thiocyanate aqueous solution, as a hydrogen-promoter medium. In parallel, the theoretical resources necessary to apply the Dugdale cohesive model to the SENT specimen were developed from the Green function in order to predict the J-integral dependency on the applied load and the crack size, with the cohesive resistance being the only material constant concerning fracture. The comparison of theoretical and experimental results strongly supports the premise that the cohesive crack accurately models the effect of the mechanisms by which the examined steel opposes crack propagation, both when in hydrogen-free and -embrittled conditions. The identification of experimental and theoretical limit values respectively involving a post-small-scale-yielding regime and unstable extension of the cohesive zone allowed for the value of the cohesive resistance to be determined, its condition as a material constant in hydrogen-free medium confirmed, and its strong decrease with hydrogen exposure revealed. Full article

Geopolymers (GPs), as promising alternatives to ordinary Portland cement (OPC)-based concrete, have gained interest in the last 20 years due to their enhanced mechanical properties, durability, and lower environmental impact. Synthesized from industrial by-products such as slag and fly ash, geopolymers offer a sustainable solution to waste management, resource utilization, and carbon dioxide reduction. However, similarly to OPC, geopolymers exhibit brittle behavior, and this characteristic defines a limit for structural applications. To tackle this issue, researchers have focused on the characterization, development, and implementation of fiber-reinforced geopolymers (FRGs), which incorporate various fibers to enhance toughness, ductility, and crack resistance, allowing their use in a wide range of structural applications. Following a general overview of sustainability considerations, this review critically analyzes the structural performance and capability of geopolymers in structural repair applications. Geopolymers demonstrate notable potential in new construction and repair applications. However, challenges such as complex mix designs, the availability of alkaline activators, curing temperatures, fiber matrix compatibility issues, and limited standards are restricting its large-scale adoption. The analysis and consolidation of an extensive dataset would support the viability of geopolymer as a durable and sustainable alternative to what is currently used in the construction industry, especially when fiber reinforcement is effectively integrated. Full article

The integration of fiber-reinforced cementitious composites (FRCCs) with fiber-reinforced polymer (FRP) bars represents a significant advancement in concrete technology, aimed at enhancing the structural performance of reinforced concrete elements. The incorporation of fibers into cementitious composites markedly improves their mechanical properties, including tensile strength, ductility, compressive strength, and flexural strength, by effectively bridging cracks and optimizing load distribution. Furthermore, FRP bars extend these properties with their high tensile strength, lightweight characteristics, and exceptional corrosion resistance, rendering them ideal for applications in aggressive environments. In recent years, there has been a notable increase in interest from the engineering research community regarding this topic, primarily to solve the issues of aging and deteriorating infrastructure. Researchers have conducted extensive investigations into the structural performance of FRCC and FRP composite systems. This paper presents a systematic literature review that surveys experimental and analytical studies, findings, and emerging trends in this field. A comprehensive search on the Web of Science identified 40 relevant research articles through a rigorous selection process. Key factors of structural performance, such as bond behavior, flexural behavior, ductility performance assessments, shear and torsional performance, and durability evaluations, have been documented. This review aims to provide an in-depth understanding of the structural performance of these innovative composite materials, paving the way for future research and development in construction materials technology. Full article

The spray-applied pipe lining (SAPL) method, extensively employed in the trenchless rehabilitation of reinforced concrete pipes (RCPs) due to its operational versatility, remains constrained by an incomplete understanding of the failure behavior of rehabilitated pipelines, thereby impeding optimal design strategies. This study proposes an analytical approach to evaluate the structural performance of pipes with fiber-reinforced mortar lining, with a particular focus on interface failure and its consequences. Two RCPs with an inner diameter of 1000 mm, repaired with 34 mm and 45 mm centrifugally sprayed fiber-reinforced mortar liners, were subjected to three-edge-bearing (TEB) tests. The elastic limit loads of the two pipes were 57% and 39% of their pre-rehabilitation conditions, while the ultimate loads were 45% and 69%. A thicker liner exhibits a greater susceptibility to interface failure, leading to wider cracks around the elastic stage during loading. Once the interface failure occurs, load redistribution allows the liner to resist further cracking and sustain higher capacity, demonstrating enhanced bearing performance. Critical factors influencing the failure process were analyzed to inform design optimization, revealing that improving the interface takes precedence, followed by thickness design. Full article

In contrast to brittle normal-strength concrete (NSC), high-performance steel-fiber-reinforced concrete (HPSFRC) provides better tensile and shear resistance, enabling enhanced bridge girder design. To achieve a balance between cost efficiency and quality, reducing conventional reinforcement is a viable cost-saving strategy. This study focused on the flexural behavior of a type of pre-tensioned precast HPSFRC girder without longitudinal and shear reinforcement. This type of girder consists of HPSFRC and prestressed steel strands, balancing structural performance, fabrication convenience, and cost-effectiveness. A 30.0 m full-scale girder was randomly selected from the prefabrication factory and tested through a four-point bending test. The failure mode, load–deflection relationship, and strain distribution were investigated. The experimental results demonstrated that the girder exhibited ductile deflection-hardening behavior (47% progressive increase in load after the first crack), extensive cracking patterns, and large total deflection (1/86 of effective span length), meeting both the serviceability and ultimate limit state design requirements. To complement the experimental results, a nonlinear finite element model (FEM) was developed and validated against the test data. The flexural capacity predicted by the FEM had a marginal 0.8% difference from the test result, and the predicted load–deflection curve, crack distribution, and load–strain curve were in adequate agreement with the test outcomes, demonstrating reliability of the FEM in predicting the flexural behavior of the girder. Based on the FEM, parametric analysis was conducted to investigate the effects of key parameters, namely concrete tensile strength, concrete compressive strength, and prestress level, on the flexural responses of the girder. Eventually, design recommendations and future studies were suggested. Full article

This study presents a unique and comprehensive application of ANSYS Mechanical R19.2’s SMART crack growth feature, leveraging its capabilities to conduct an unprecedented parametric investigation into fatigue crack propagation behavior under a wide range of positive and negative stress ratios, and to provide detailed insights into the influence of hole positioning on crack trajectory. By uniquely employing an unstructured mesh method that significantly reduces computational overhead and automates mesh updates, this research overcomes traditional fracture simulation limitations. The investigation breaks new ground by comprehensively examining an unprecedented range of both positive (R = 0.1 to 0.5) and negative (R = −0.1 to −0.5) stress ratios, revealing previously unexplored relationships in fracture mechanics. Through rigorous and extensive numerical simulations on two distinct specimen configurations, i.e., a notched plate with a strategically positioned hole under fatigue loading and a cracked rectangular plate with dual holes under static loading, this work establishes groundbreaking correlations between stress parameters and fatigue behavior. The research reveals a novel inverse relationship between the equivalent stress intensity factor and stress ratio, alongside a previously uncharacterized inverse correlation between stress ratio and von Mises stress. Notably, a direct, accelerating relationship between stress ratio and fatigue life is demonstrated, where higher R-values non-linearly increase fatigue resistance by mitigating stress concentration, challenging conventional linear approximations. This investigation makes a substantial contribution to fracture mechanics by elucidating the fundamental role of hole positioning in controlling crack propagation paths. The research uniquely demonstrates that depending on precise hole location, cracks will either deviate toward the hole or maintain their original trajectory, a phenomenon attributed to the asymmetric stress distribution at the crack tip induced by the hole’s presence. These novel findings, validated against existing literature, represent a significant advancement in predictive modeling for fatigue life assessment, offering critical new insights for engineering design and maintenance strategies in high-stakes industries. Full article

High concrete gravity dams, particularly Roller-Compacted Concrete (RCC) types, face long-term safety challenges due to weak interlayer formation and crack propagation. This study presented a comprehensive evaluation of safety monitoring indexes for the Guxian high RCC dam (currently under construction) using both numerical and mathematical models. A finite element method (FEM) is employed with a strength reduction approach to assess dam stability considering weak layers. In parallel, a fracture mechanical model is used to investigate the safety of the Guxian dam based on failure assessment diagrams (FADs) for calculating the safety factor and the residual strength curve for calculating critical crack depth for two different crack locations, single-edge and center-through crack, to investigate the high possible risk associated with crack location on the dam safety. Additionally, the Guxian dam’s resistance to hydraulic fracture is assessed under two fracture mechanic failure modes, Mode I (open type) and Mode II (in-plane shear), by computing the ultimate overload coefficient using a proposed novel derived formula. The results show that weak layers reduce the dam’s safety index by approximately 20%, especially in lower sections with extensive interfaces. Single-edge cracks pose greater risk, decreasing the safety factor by 10% and reducing critical crack depth by 40% compared to center cracks. Mode II demonstrates higher resistance to hydraulic fracture due to greater shear strength and fracture energy, whereas Mode I represents the most critical failure scenario. The findings highlight the urgent need to incorporate weak layer behavior and hydraulic fracture mechanisms into dam safety monitoring, and to design regulations for high RCC gravity dams. Full article

Semi-flexible pavement (SFP) materials have garnered extensive application and research attention owing to their exceptional deformation resistance. The crack resistance of SFP materials constitutes a critical aspect of their road performance. This study conducts a comprehensive analysis of the crack resistance of SFP materials through material characterization and structural mechanical response evaluation. To assess the cracking behavior of SFP materials across the entire temperature spectrum, three experimental methodologies were employed: low-temperature flexural tensile testing, indirect tensile testing, and semi-circular bending tensile testing. Experimental findings reveal that SFP materials exhibit superior crack resistance compared to SMA-13 under ambient and elevated temperature conditions, while demonstrating inferior performance relative to SMA-13 in low-temperature environments. Through a comparative analysis of structural mechanical responses between SMA-13 and SFP pavements, it was determined that the implementation of a single-layer SFP material can reduce pavement tensile strain by 30–50%. This investigation provides comprehensive insights into the crack resistance characteristics of SFP materials and offers valuable guidance for material selection in pavement structural design. Full article

Cement is widely used as the primary binder in concrete; however, growing environmental concerns and the rapid expansion of the construction industry have highlighted the need for more sustainable alternatives. Geopolymers have emerged as promising eco-friendly binders due to their lower carbon footprint and potential to utilize industrial byproducts. Geopolymer mortar, like other cementitious substances, exhibits brittleness and tensile weakness. Basalt fibers serve as fracture-bridging reinforcements, enhancing flexural and tensile strength by redistributing loads and postponing crack growth. Basalt fibers enhance the energy absorption capacity of the mortar, rendering it less susceptible to abrupt collapse. Basalt fibers have thermal stability up to about 800–1000 °C, rendering them appropriate for geopolymer mortars designed for fire-resistant or high-temperature applications. They assist in preserving structural integrity during heat exposure. Fibers mitigate early-age microcracks resulting from shrinkage, drying, or heat gradients. This results in a more compact and resilient microstructure. Using basalt fibers improves surface abrasion and impact resistance, which is advantageous for industrial flooring or infrastructure applications. Basalt fibers originate from natural volcanic rock, are non-toxic, and possess a minimal ecological imprint, consistent with the sustainability objectives of geopolymer applications. This study investigates the mechanical and thermal performance of a geopolymer mortar composed of metakaolin and red mud as binders, with basalt powder and limestone powder replacing traditional sand. The primary objective was to evaluate the effect of basalt fiber incorporation at varying contents (0.4%, 0.8%, and 1.2% by weight) on the durability and strength of the mortar. Eight different mortar mixes were activated using sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) solutions. Mechanical properties, including compressive strength, flexural strength, and ultrasonic pulse velocity (UPV), were tested 7 and 28 days before and after exposure to elevated temperatures (200, 400, 600, and 800 °C). The results indicated that basalt fiber significantly enhanced the performance of the geopolymer mortar, particularly at a content of 1.2%. Specimens with 1.2% fiber showed up to 20% improvement in compressive strength and 40% in flexural strength after thermal exposure, attributed to the fiber’s role in microcrack bridging and structural densification. Subsequent research should concentrate on refining fiber type, dose, and dispersion techniques to improve mechanical performance and durability. Examinations of microstructural behavior, long-term durability under environmental settings, and performance following high-temperature exposure are crucial. Furthermore, investigations into hybrid fiber systems, extensive structural applications, and life-cycle evaluations will inform the practical and sustainable implementation in the buildings. Full article

The 316L stainless steel material boasts exceptional corrosion resistance and plasticity, among other benefits, and finds extensive application in automotive components, molds, aerospace parts, biomedical equipment, and more. This work focuses on the surface polishing of selective laser melting (SLM) 316L stainless steel using 1064 nm nanosecond laser processing and mechanical grinding. The influence of laser processing parameters on the surface roughness of SLM-316L stainless steel was investigated using an orthogonal experiment. After laser processing, the surface roughness of SLM-316L stainless steel was reduced from 7.912 μm to 1.936 μm, but many randomly distributed irregular micro-cracks appeared on the surface. EDS and XRD detections illustrated that iron oxides were generated on the surface of SLM-316L stainless steel after laser processing. Mechanical grinding was further performed to achieve a nanometer surface finish and remove the metal oxides and micro-cracks generated on the surface of SLM-316L stainless steel after laser processing. The AFM measurement results indicate that the surface roughness of SLM-316L stainless steel was reduced to approximately 3 nm after mechanical grinding. Moreover, the micro-cracks and iron oxides on the surface of laser-processed SLM-316L stainless steel were completely removed. This work provides guidance for the precision polishing of SLM-316L stainless steel. Full article

Hydraulic concrete is subject to severe durability challenges when abraded by the high-speed flow of sandy water. Conventional concrete frequently needs to be repaired because of its high brittleness and insufficient abrasion resistance, while granular rubber can easily be dislodged from the matrix during abrasion, forming a new source of abrasion and increasing the damage to the matrix. For this reason, we used fibrous rubber concrete to systematically study the mechanisms of the influence of the dosage of nitrile rubber (5%, 10%, and 15%) and fiber length (6, 12, and 18 mm) on resistance to impact and abrasion performance. Through mechanical tests, underwater steel ball abrasion tests, three-dimensional morphology measurements, and fractal dimension analysis, the law behind the damage evolution of fibrous rubber concrete was revealed. The results show that concrete with 15% NBR and 12 mm fibers yielded the best performance, and its 144-hour abrasion resistance reached 25.0 h/(kg/m²), which is 163.7% higher than that for the baseline group. Fractal dimension analysis (D = 2.204 for the optimum group vs. 2.356 for the benchmark group) showed that the fiber network effectively suppressed surface damage extension. The long-term mass loss rate was only 2.36% (5.82% for the benchmark group), and the elastic energy dissipation mechanism remained stable under dynamic loading. The results of a microanalysis showed that the high surface roughness of NBR enhances interfacial bonding, which synergizes with crack bridging and stress dispersion and, thus, forms a multiscale anti-impact abrasion barrier. This study provides a new material solution for the design of durable concrete for use in high-impact and high-abrasion environments, which combines mechanical property preservation and resource recycling value. However, we did not systematically examine the evolution of the performance of fiber rubber concrete concrete under long-term environmental coupling conditions, such as freeze–thaw cycles, ultraviolet aging, or chemical attacks, and there are limitations to our assessment of full life-cycle durability. Full article

Modern SiC-based materials are of paramount importance in that they serve as wear-resistant and thermal protectors and as next-generation single-photon sources for photonic and quantum solutions. Efforts are underway to identify more efficient methods of manufacturing SiC-based ceramic materials. The objective of this paper is to provide a description of the optimization of sintering SiC–TiC composites by the electroconsolidation method. The influence of titanium carbide content on the physical and mechanical properties of SiC–TiC composites obtained by spark plasma sintering (SPS) at a pressure of 45 MPa was studied. It was found that compared to sintered silicon carbide, the porosity of composites with 40 mol% TiC decreased from ~30% to 0%, the crack resistance increased from 2.9 to 6.1 MPa × m^0.5, and the hardness increased from 2.9 to 21.5 GPa. The influence of sintering temperature and holding time on SiC–TiC composites’ physical and mechanical properties during sintering at a pressure of 45 MP was also investigated. An increase in temperature from 1900 °C to 2000 °C resulted in an approximately 30% rise in the composite hardness. An extension of the time allotted for the sintering process from 30 to 45 min resulted in a decrease in both the fracture toughness and hardness of the material. The utilization of two- and three-dimensional vector spaces of material features was proposed as a novel methodology for the description of manufacturing process optimization. Full article

Carbon nanotubes (CNTs) exhibit high strength and high modulus, excellent electrical and thermal conductivity, good chemical stability, and unique electronic and optical properties. These characteristics make them a one-dimensional nanomaterial with extensive potential applications in fields such as composite materials, electronic devices, energy, aerospace, and medical technology. Cement-based materials are the most widely used and extensively applied construction materials. However, these materials have disadvantages such as low tensile strength, brittleness, porosity, shrinkage, and cracking. In order to compensate for these shortcomings, in recent years, relevant scholars have proposed to integrate CNTs into cement-based materials. Incorporating CNTs into cement-based materials not only enhances the microstructure of these materials but also improves their mechanical, electrical, and durability properties. The characteristics and fabrication process of CNTs are reviewed in this paper. The different effects of CNTs on the physical properties and hydration properties of cement-based materials due to the design parameters, dispersion methods, and temperature were analyzed. The results show that the compressive and flexural strength of CNT cement-based materials with 0.02% content increased by 9.33% and 10.18% from 3 d to 28 d. In terms of reducing the shrinkage and carbonization resistance of the cement base, there is an optimal amount of carbon nanotubes. The addition of dispersed carbon nanotubes reduces the resistivity, and the nucleation of carbon nanotubes promotes the hydration reaction. In general, under the optimal dosage, carbon nanotubes with uniform dispersion and short length–diameter ratio have a significant effect on the cement-based lifting effect. In the future, CNT cement-based materials will develop high strength, multifunctionality, and low cost, realizing intelligent self-sensing and self-repair and promoting green and low-carbon manufacturing. Breakthroughs in decentralized technology and large-scale applications are key, and they are expected to help sustainable civil engineering with intelligent infrastructure. Full article