Search Results (157)

Injection-molding purges are heterogeneous, bulky residues whose uncertain composition and irregular geometry hinder direct reinsertion, making cold shredding costly and maintenance-intensive. This work develops a low-infrastructure solar-assisted pre-processing route using a PMMA Fresnel lens to induce controlled sub-onset softening and enable clean shear cutting without destructive thermal histories. The sub-onset softening is here defined into a viscoelastically active range (at or above T_g for the amorphous phase) while remaining below the melting onset (T_m, onset) and below the onset of thermal degradation (T_d, onset). The station was engineered via QFD and risk-oriented design tools, while a weighted Pugh matrix selected shear cutting over saw-based alternatives. A screening factorial DOE showed that lens height, angle, and their interaction significantly govern focal-spot diameter and receiver temperature, yielding linear relations for conservative set-point selection. Receiver benchmarking further indicated that copper reaches substantially higher temperatures than graphite under identical exposure conditions, supporting copper as the simplest, rapid-heating receiver. Under DOE-calibrated operation, tear-free shear cutting was achieved across representative purge families (PP–ABS, PC–ABS–PP, PA66, PA66-filler, and POM) without forced convection. From a recycling and waste-management perspective, the approach converts bulky purge scrap into mill-compatible feedstock with reduced mechanical resistance, lowering tool wear and fines generation, accelerating downsizing, and limiting stockpiling that elevates combustible-inventory fire risk. Overall, the proposed DOE-calibrated, operator-friendly framework improves recycling feasibility by enabling safer handling, more stable preprocessing throughput, and reduced reliance on disposal or long-term storage for heterogeneous industrial purges. Full article

Material handling is an important process in open-pit mining, where trucks transport material extracted by shovels to different destinations within the mine. The decision regarding the next destination of a truck strongly influences operational efficiency. In current mining operations, this decision is typically handled by centralized dispatching systems based on predefined criteria. However, such approaches often struggle to adapt to dynamic operating conditions and rely on a central control unit, which may reduce flexibility and robustness. This paper proposes a decentralized multi-agent system for truck dispatching with reinforcement learning (MAS-TDRL). In the proposed approach, autonomous agents representing trucks, shovels, and unloading points cooperate through a negotiation mechanism based on an enhanced Contract Net Protocol to generate operational schedules. Reinforcement learning is integrated into the decision-making process of truck agents, allowing them to learn from previous negotiations and improve their participation over time. The proposed system is evaluated through simulation using scenarios based on real data from an open-pit copper mine in Chile. The results show that incorporating reinforcement learning increases the material transported per hour by approximately 18–29% compared to a multi-agent system without learning, while maintaining computation times below 10 min even in the largest scenario, which remains compatible with operational decision-making in open-pit mining contexts. Full article

Thin, stratiform ore bodies pose persistent challenges for conventional underground mining due to limited thickness, high ore-grade dilution, and restricted operating space. This study introduces a morphology-based scoring framework for assessing the suitability of ore deposits for the Narrow Reef Mining Equipment method—an ultra-low-profile mechanized technique designed for stoping width up to 1.7 m and inclination up to 22°. A dataset comprising 178 ore deposits/mines was evaluated using integrated geological, morphological, and economic criteria. The results demonstrate that NRE suitability is primarily controlled by ore morphology, which is governed by the genetic model. The highest compatibility is associated with stratiform mineralization formed in layered mafic–ultramafic intrusions (e.g., Bushveld Complex, Great Dyke) and sediment-hosted stratiform copper and gold deposits developed along laterally extensive depositional or redox-controlled interfaces (e.g., Kupferschiefer, Witwatersrand). Although genetic origin defines deposit-scale suitability, secondary geological disturbances—post-genetic tectonism and hydrothermal overprinting—restrict NRE applicability to individual ore bodies within otherwise favourable deposits. By formalizing ore body dip and thickness into standardized efficiency and suitability classes, the proposed scoring system provides a reproducible early-stage geological screening methodology for evaluating NRE applicability during initial mine project development. Economic evaluation based on data from the Unki Mine provides operational validation of the proposed scoring framework and demonstrates that NRE increases monthly output at reduced stoping widths while maintaining ore grades and improving operational safety compared to conventional methods. Full article

The hydrogenation of CO₂ to methanol is a crucial route for achieving carbon recycling. Among the extensively studied catalysts, copper-based catalysts suffer from insufficient activity and stability, while noble metal catalysts are limited by prohibitively high cost. In contrast, metal–organic framework (MOF) materials demonstrate unique advantages due to their designable architectures and high dispersion. Conventional thermal catalysis relies on high temperature and pressure; photocatalysis suffers from low efficiency; and electrocatalysis shows poor selectivity. These limitations motivate the exploration of new catalytic approaches. Plasma catalysis, particularly dielectric barrier discharge (DBD) technology, can efficiently activate CO₂ via high-energy electrons and reactive species at ambient temperature and pressure, and generate a synergistic effect with catalysts, significantly enhancing methanol production efficiency and selectivity. Studies have shown that plasma–catalyst synergistic systems, such as those employing Cu/γ-Al₂O₃ or Pt/In₂O₃, exhibit superior performance to individual processes under mild conditions. Future research should focus on elucidating the plasma–catalyst interface mechanism, optimizing reactor design, and developing compatible, high-efficiency catalysts to establish a novel pathway for CO₂ conversion with low energy consumption and high efficiency. Full article

High-temperature superconducting (HTS) technologies continue to advance as promising solutions for large-capacity rotating electrical machinery. However, the cryogenic architecture required to maintain superconducting states remains a critical design challenge, particularly for performance evaluation systems (PESs). Conventional helium–neon (He–Ne) circulation-based cooling enables stable low-temperature operation and has been experimentally validated in previous PES implementations, but it introduces substantial limitations due to installation complexity, flow-induced instability, and limited adaptability to different coil configurations. To address these constraints, this study proposes a conduction-cooled PES architecture optimized for HTS field coil testing and examines its thermal and structural characteristics through comprehensive design and finite element method (FEM)-based analysis. A multi-stage conduction cooling pathway using a cryocooler, thermal straps, and copper heat plates was designed to achieve uniform temperature distribution and reduce thermal gradients across the HTS winding. Three-dimensional FEM simulations were performed to evaluate the steady-state temperature distribution and heat-transfer characteristics of the proposed conduction-cooled PES under representative thermal load conditions, and the predicted cooling performance was comparatively assessed against the He–Ne cooled PES. The conduction-cooled PES was analyzed by comparing its predicted performance with previously obtained experimental results from the He–Ne cooled PES. The proposed conduction cooling architecture achieved a significant reduction in total heat load, decreasing from 177 W in the He–Ne system to approximately 78 W in the conduction-cooled configuration while also improving thermal efficiency and simplifying system integration. In addition, conduction cooling enhances compatibility with a wider range of HTS coil geometries by eliminating the constraints associated with fluid-based circulation. While the proposed conduction-cooled PES has not yet been physically fabricated, the numerical framework was established based on experimentally confirmed operating conditions of the previously implemented He–Ne-cooled PES, and future work will include fabrication and experimental validation of the conduction-cooled configuration. These findings demonstrate that conduction cooling represents a practical and scalable alternative for next-generation PES platforms and provide essential design guidelines for the development of high-field HTS coils and large-capacity superconducting rotating machines. Full article

The objective of this research is to develop environmentally friendly, risk-free and effective adsorbent composite beads that remove Cu(II) ions from aqueous solutions using cost-effective biopolymers (Carboxymethylcellulose (CMC) and sodium alginate (AL)). The synthesized hydrogel beads (AL@CMC) were dried using two drying modes, namely air-drying and freeze-drying, and characterized using scanning electron microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), and Brunauer–Emmett–Teller (BET) analysis. The study investigated factors such as pH, adsorbent dosage, reaction time, Cu(II) ions concentration, and temperature to elucidate the adsorption mechanisms involved in removing copper ions. The results indicated that the hydrogel exhibited a maximum adsorption capacity of 99.05 mg·g⁻¹, which is highly competitive compared to previous studies; the AL@CMC beads prepared in this work show a significantly higher adsorption capacity, improved stability due to the interpenetrated biopolymer network, and a clear enhancement from freeze-drying, which greatly increases porosity and active surface area. In addition, the pseudo-second-order nonlinear kinetic model best described the experimental data, implying the chemical nature of the adsorption process. Furthermore, the thermodynamic studies revealed that the adsorption process was endothermic, spontaneous, and homogenous. A Monte Carlo simulation model was utilized to ensure compatibility with the adsorption mechanism, in order to delve deeper into the intricacies of the adsorption process and gain a more comprehensive understanding of its underlying mechanisms and behavior. In conclusion, the prepared hydrogel beads proved to be an effective adsorbent for efficiently removing copper ions, making them a promising solution for addressing Cu(II) ion pollution. Full article

The global transition from internal combustion engines (ICEs) to hybrid (HEVs) and electric vehicles (EVs) is fundamentally reshaping lubricant design requirements, driven by evolving thermal demands, electrical constraints, and material compatibility challenges. Conventional ICE lubricants are primarily formulated to withstand high operating temperatures, mechanical stresses, and combustion-derived contaminants through established additive chemistries such as zinc dialkyldithiophosphate (ZDDP), with thermal stability and wear protection as dominant considerations. In contrast, HEV lubricants must accommodate frequent start–stop operation, pronounced thermal cycling, and fuel dilution while maintaining performance across coupled mechanical and electrical subsystems. EV lubricants represent a paradigm shift, where requirements extend beyond tribological protection to include electrical insulation and conductivity control, thermal management of electric motors and battery systems, and compatibility with copper windings, polymers, elastomers, and advanced coatings, alongside mitigation of noise, vibration, and harshness (NVH). This review critically examines lubricant behavior, formulation strategies, and performance requirements across ICE, HEV, and EV powertrains, with specific emphasis on heat transfer, electrical performance, and lubricant–material interactions, covering mineral, synthetic, and bio-based fluids. Additionally, regulatory drivers, sustainability considerations, and emerging innovations such as nano-additives, multifunctional and smart lubricants, and AI-assisted formulation are discussed. By integrating recent research into industrial practice, this work highlights the increasingly interdisciplinary role of tribology in enabling efficient, durable, and sustainable mobility for next-generation automotive systems. Full article

This work presents a highly compact and scalable 1.2-kV SiC MOSFET half-bridge building-block module enabled by a die-integrated 3D PCB packaging technology. Compared with conventional DBC-based or TO-247-based SiC half-bridge modules, the proposed design reduces the physical volume and weight by more than 90% while maintaining full compatibility with standard PCB manufacturing processes. The vertically laminated DC+/DC− conductors and symmetric PCB–die–PCB stack establish a tightly confined commutation loop, resulting in a measured power-loop inductance of 2.2 nH and a 3.8 nH gate-loop inductance—representing up to 94% and 89% reduction relative to discrete device implementations. Because the parasitic parameters are intrinsically well-balanced across replicated units and the mutual inductance between adjacent modules remains extremely small, the structure naturally supports current sharing during parallel operation. Thermal and insulation evaluations further confirm the suitability of copper filling via high-Tg laminated PCB substrates for high-power SiC applications, achieving withstand voltages exceeding twice the rated bus voltage. The proposed module is experimentally validated through finite-element parasitic extraction and 950 V double-pulse testing, demonstrating controlled dv/dt behavior and robust switching performance. This work establishes a manufacturable and parallel-friendly packaging approach for high-density SiC power conversion systems. Full article

High-flexibility copper foils are critical for reliable flexible interconnects and displays. In this work, commercial-purity copper belts were processed by triple-layer stacked cold rolling to ultrathin foils, producing distinct surface- and layer-dependent deformation structures in the bright, matte, and central-interface layers; subsequent annealing at 600 °C then promoted orientation-selective recrystallization. Under the present conditions, the center-interface layer of the triple-rolled foil achieved the highest flexural-fatigue life (≈8.0 × 10⁴ cycles) within a window of cube ≈ 30–45% and grain size ≈ 40–60 μm. In this regime, grain-size control stabilizes intergranular slip compatibility, reduces elastic–plastic mismatch, and mitigates strain localization during cyclic bending. Even without aggressive cube enrichment, high flexural fatigue resistance can likewise be achieved through deliberate control of grain size. These findings establish a clear processing–microstructure–property linkage and indicate that layer-dependent control of texture and grain size can enhance flexural-fatigue performance in triple-layer stacked-rolled copper foils for flexible electronics. Full article

This study focuses on a proposed aluminum alloy radiant panel with 60° V-shaped grooves and integrated copper tubes. A numerical model of this novel grooved phase change material (PCM)-integrated radiant panel was established via Fluent 2022 R1 software. Through numerical simulations, the complete melting and solidification processes of two PCMs (n-hexadecane and LTXC-PCM-A-18) were analyzed, and differences in their phase change heat transfer performance were compared—revealing the role of the groove structure in enhancing PCM heat transfer and the material-structure compatibility. Results indicate that the groove structure effectively enhances convective heat transfer in the PCM liquid phase. During the melting stage, LTXC-PCM-A-18 exhibited a preheating rate of 0.00125 K/s, which is 67% higher than that of n-hexadecane (0.00075 K/s); its liquid fraction growth rate (0.0002 s⁻¹) was 2.67 times that of n-hexadecane, and the melting completion time was accelerated by 20% (2000 s). During solidification, LTXC-PCM-A-18’s initial cooling rate (0.0006 K/s) was 50% higher than that of n-hexadecane (0.0004 K/s), with a liquid fraction decay rate twice that of n-hexadecane. Additionally, its solidification temperature plateau was 1 K higher, providing superior thermal output stability. These findings reflect two distinct technical strategies: “steady-state temperature control” and “dynamic regulation.” n-Hexadecane exhibits smoother melting and solidification processes, making it suitable for continuous heating applications. In contrast, LTXC-PCM-A-18 demonstrates superior thermal responsiveness and phase change efficiency, aligning with intermittent heating requirements. This study provides quantitative guidance for PCM selection in grooved radiant panels. Full article

High-valent metal species (iron, manganese, cobalt, copper, and ruthenium) based advanced oxidation processes (AOPs) have emerged as sustainable technologies for water remediation. These processes offer high selectivity, electron transfer efficiency, and compatibility with circular chemistry principles compared to conventional systems. This comprehensive review discusses recent advances in the synthesis, stabilization, and catalytic applications of high-valent metals in aqueous environments. This study highlights their dual functionality, not only as conventional oxidants but also as mechanistic mediators within redox cycles that underpin next-generation AOPs. In this review, the formation mechanisms of these species in various oxidant systems are critically evaluated, highlighting the significance of ligand design, supramolecular confinement, and single-atom engineering in enhancing their stability. The integration of high-valent metal-based AOPs into photocatalysis, sonocatalysis, and electrochemical regeneration is explored through a newly proposed classification framework, highlighting their potential in the development of energy efficient hybrid systems. In addition, this work addresses the critical yet underexplored area of environmental fate, elucidating the post-oxidation transformation pathways of high-valent species, with particular attention to their implications for metal recovery and nutrient valorization. This review highlights the potential of high-valent metal-based AOPs as a promising approach for zero wastewater treatment within circular economies. Future frontiers, including bioinspired catalyst design, machine learning-guided optimization, and closed loop reactor engineering, will bridge the gap between laboratory research and real-world applications. Full article

Two folding screens by futurist artist Giacomo Balla (1871–1958) in the collection of the Kröller-Müller Museum (the Netherlands) were investigated: Paravento con linea di velocità (1916–1917) and Paravento (1916/1917–1958). The screens are painted on both sides, the first on four canvases, stretched onto two wooden strainers and framed with painted wooden strips, and the second on wooden panels set into four painted stiles. In the past, damages on Paravento con linea di velocità were restored by conservators, while Paravento was probably first reworked by the artist himself and later restored by conservators. Yellowed varnish and discolored retouches on both screens led to a wish for treatment. The aim of this research was to gain insight into the painting techniques, layer buildup, pigments, binders, and varnishes of the two artworks. This information supported the decision making for treatment, and it broadens the knowledge on the materials used by Balla. Up to now, only a few published studies deal with the technical examination of paintings by this artist. Both folding screens were subjected to technical photography (UV, IR photography, and X-ray) and were examined with portable point X-ray fluorescence (pXRF) and Raman spectroscopy. Moreover, samples were taken. Cross-sections were studied with optical microscopy, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX), attenuated total reflection Fourier-transform infrared (ATR-FTIR) imaging, and micro-Raman spectroscopy. Loose samples were examined with SEM-EDX, FTIR and micro-Raman spectroscopy, and pyrolysis gas chromatography mass spectrometry (Py-GC/MS). For Paravento con linea di velocità, all pigments and fillers of the painted canvases are compatible with the dating of the screen (1916–1917), but they differ from those on the frame. Here, rutile, in combination with various pigments, among which are blue copper phthalocyanine (PB15) and other synthetic organic pigments, was found. This indicates that the frame has been painted later, likely after the Second World War. The composition of the binders differs as well. Drying oil and pine resin have been used on the canvases, explaining the smooth and glossy appearance and solvent-sensitivity of the paint. On the frame, oil with some alkyd resin was identified. The provenance of the screen before 1972 is not clear, nor when the frame was made and painted and by whom. The results for Paravento indicate that the palettes of the two sides—painted in different styles—are comparable. Mainly inorganic pigments were found, except for the dark red areas, where toluidine red (PR3) is present. pXRF showed high amounts of zinc; cross-sections revealed that zinc white is present in the lower layers. These pigments are compatible with the dating of the screen (1916–1917). In many of the upper paint layers though, except for some green, dark red, and black areas, rutile has been identified. This indicates that these layers were applied later, likely after the Second World War. Since this folding screen was used by the artist and his family until his death in 1958, it seems likely that Balla himself reworked the screen. Full article

Biodegradable magnesium (Mg) alloys hold promising application prospects in the field of guided bone regeneration (GBR) membranes, particularly for oral and maxillofacial applications. However, their corrosion resistance requires further improvement. Additionally, Mg alloys are susceptible to bacterial infection upon implantation, while copper (Cu) is known for its excellent antibacterial properties. Introducing Cu into the micro-arc oxidation (MAO) coating can enhance both the corrosion resistance and antibacterial performance of Mg alloys. However, the sealing effect of such coatings remains suboptimal. Hydroxyapatite (HA), which possesses outstanding bioactivity, is a promising bone substitute material. This study investigates the influence of HA content on the microstructure, corrosion resistance, cytotoxicity, and antibacterial properties of Cu-containing MAO coatings. The results demonstrate that as the HA concentration increases, the corrosion resistance of the composite coating is significantly enhanced. The corrosion rate decreased from 0.32 mm/y for the untreated MAO coating to 0.27 mm/y and 0.23 mm/y for the HA-treated samples with EDTA–Ca concentrations of 125 mmol/L and 175 mmol/L, respectively. Cytotoxicity assessment indicates that the incorporation of an HA layer significantly improves cell compatibility compared to the bare MAO coating. However, the enhanced corrosion resistance provided by the denser HA layer (at 175 mmol/L EDTA–Ca) unfortunately acts as a barrier, limiting the release of antibacterial Cu²⁺. Among the coatings tested, the one with 125 mmol/L EDTA–Ca exhibited the best overall performance, demonstrating good corrosion resistance, cytocompatibility, and effective antibacterial properties. Full article

Generally, atomic doping is an effective method to address the weak bonding strength of the graphene/aluminum (Gr/Al) composite interface structure caused by physical adsorption, thereby enhancing the mechanical properties of the interface structure. In this paper, the nanoscopic influence mechanisms of atomic (M, including 12 types of atoms (elements)) doping in the aluminum matrix (Al) on the ideal strength of the Gr/Al interface structures are investigated based on density functional theory. The analysis of the electronic properties of the typical interface structures reveals that doping with scandium (Sc), copper (Cu) and manganese (Mn) atoms can all improve the interface binding energy of the Gr/Al structures, but their effects on the ideal strength are different. Sc doping disrupts the symmetry of the graphene structure so as to enhance the interface binding energy, but the ideal strength of the Gr/Al structures is decreased. For Cu doping it shows good compatibility with the Al matrix and the interface binding energy is enhanced through Cu alloying with the Al matrix, while the ideal strength of the interface remains basically unchanged. As for Mn doping, it causes the charge to accumulate around the Mn atoms and a resonance peak between the d_Z² orbitals of Mn and the p_x orbitals of Al to form, thereby improving the ideal strength of the interface structure. This study provides valuable insights for the design of Gr/Al composites by elucidating the underlying mechanisms for enhancing interface mechanical properties. Full article

Safe drinking water is essential, yet millions of people remain exposed to contaminated supplies. Conventional treatments such as chlorination and UV light can kill microbes, but they also create harmful byproducts, face resistance issues, and are not always sustainable. Green-synthesized nanomaterials (GSNMs) are emerging as an eco-friendly alternative. Produced with plants, microbes, algae, and natural polymers, these materials merge nanotechnology with green chemistry. Among them, silver, zinc oxide, copper oxide, titanium dioxide, and graphene-based nanomaterials show strong antimicrobial effects by disrupting membranes, generating reactive oxygen species (ROS), and damaging genetic material. Compared with chemically made nanoparticles, GSNMs are often safer, cheaper, and more environmentally compatible. Nevertheless, concerns about toxicity, environmental fate, and large-scale use remain. This review highlights recent progress in GSNM synthesis, antimicrobial mechanisms, and safety considerations, highlighting their potential to enable sustainable water disinfection while identifying critical areas for further research. Full article