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19 pages, 20933 KB  
Article
Spatiotemporal Climate–Vegetation Dynamics and the Vegetation Ecological Quality-Based Zoning Under Climate Change: Evidence from the Qinling Mountains
by Yishan Xu, Zilin Chen, Lina Jin, Jiangfeng Cao, Zimo Huang, Yanshuo Dong, Binqing Zhai and Xin Wang
Land 2026, 15(5), 694; https://doi.org/10.3390/land15050694 (registering DOI) - 22 Apr 2026
Abstract
This study analyzed the spatiotemporal dynamics of the vegetation ecological quality under climate change. Focusing on the vegetation conditions, a vegetation ecological quality index was constructed, expressing as the product of vegetation fraction cover (VFC), net primary productivity (NPP), and geographic coverage area. [...] Read more.
This study analyzed the spatiotemporal dynamics of the vegetation ecological quality under climate change. Focusing on the vegetation conditions, a vegetation ecological quality index was constructed, expressing as the product of vegetation fraction cover (VFC), net primary productivity (NPP), and geographic coverage area. The results of trend and significance analysis showed that from 2000 to 2023, the VEQI in the Qinling Mountains exhibited a significant improvement, with an average slope of 4.91 gC·a−1 and 96.2% of the area showing high stable improvement. Partial correlation analysis revealed that precipitation had a stronger positive influence on VEQI than temperature, with over 98% of the area showing a positive correlation with precipitation, while temperature was positively correlated in 95.0% of the area but negatively correlated in high-altitude mountain zones. Therefore, four climate-driven patterns were identified: precipitation-driven (31.2%), temperature-driven (2.3%), co-driven (54.2%), and climate-stable (12.3%), suggesting that vegetation ecological quality in most regions is co-driven by both temperature and precipitation. Based on the results of trend and significance analysis and climate-driven patterns, the Qinling Mountains were divided into three ecological risk zones: low-risk (36.1%), middle-risk (56.9%), and high-risk (7.0%), with corresponding differentiated control measures proposed. Full article
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22 pages, 2114 KB  
Article
The Physiological Mechanism of Coupled Regulation Between Water Deficit Severity and Deficit Period on Winter Wheat Yield
by Ting Yu, Guang Yang, Huifeng Ning, Yunliang Wei and Xiaoman Qiang
Agronomy 2026, 16(9), 847; https://doi.org/10.3390/agronomy16090847 (registering DOI) - 22 Apr 2026
Abstract
Regulated deficit irrigation is a vital method for developing water-saving agriculture. The degree of and the period of water deficit are two key factors determining the effectiveness of regulated deficit irrigation. In this study, winter wheat was used as the experimental material, and [...] Read more.
Regulated deficit irrigation is a vital method for developing water-saving agriculture. The degree of and the period of water deficit are two key factors determining the effectiveness of regulated deficit irrigation. In this study, winter wheat was used as the experimental material, and water deficit was imposed by reducing the irrigation lower limit. Three water deficit treatments were established, with irrigation lower limits set at 65%, 55%, and 45% of field capacity, respectively. There were three stages of water deficit: the jointing stage, the heading-anthesis stage, and the ripening stage; full irrigation (with a minimum irrigation level of 75% field capacity) served as the control. The physiological and growth indicators were measured, including plant water status, osmotic regulation, antioxidant activity, leaf gas exchange and yield. The variation patterns of physiological indicators during the irrigation cycle under reduced irrigation lower limits at different growth stages were explored. The synergistic response relationships among physiological indicators were analyzed; the physiological mechanism by which the degree and stage of water deficit jointly influence winter wheat yield was elucidated. The results indicate that lowering the lower limit of irrigation reduces net photosynthesis prior to irrigation. When the lower irrigation threshold exceeds 55%, chlorophyll content remains largely unaffected. However, increased stomatal conductance following irrigation results in higher net photosynthesis under the low irrigation threshold treatment compared to the control. When the irrigation lower limit is below 55%, chlorophyll content decreases significantly, resulting in net photosynthesis remaining markedly lower than the control even after irrigation. During the jointing stage and heading-anthesis stage, plants exhibit weaker osmotic regulation and antioxidant capacity, and the chlorophyll content is greatly affected by water deficit, resulting in reduced net photosynthesis before and after irrigation, leading to a greater decrease in winter wheat yield. The results on the physiological and biochemical characters (excluding gas exchange parameters) are limited to one year. The research findings provide the theoretical reference for regulated deficit irrigation of winter wheat. Full article
(This article belongs to the Special Issue Crop Management in Water-Limited Cropping Systems)
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26 pages, 8980 KB  
Article
Experimental Study on the Aerodynamic Characteristics of a Swept-Blade Wind Turbine Under Turbulent Inflow Conditions
by Junwei Yang, Chenglong Sha, Xiangjun Wang and Hua Yang
Biomimetics 2026, 11(5), 293; https://doi.org/10.3390/biomimetics11050293 (registering DOI) - 22 Apr 2026
Abstract
Avian wings enable autonomous control over flight trajectory and speed, and their swept-wing geometry inspires the application of sweep modifications to horizontal-axis wind turbine blades, an approach that is critical for improving aerodynamic performance. Hence, wind tunnel experiments were performed to evaluate the [...] Read more.
Avian wings enable autonomous control over flight trajectory and speed, and their swept-wing geometry inspires the application of sweep modifications to horizontal-axis wind turbine blades, an approach that is critical for improving aerodynamic performance. Hence, wind tunnel experiments were performed to evaluate the output power and wake features of a baseline straight-bladed and a swept-blade wind turbine. The experimental results demonstrate that inflow turbulence intensity (T.I.) affects the peak power coefficient of the swept-bladed turbine, with power coefficient gains being more significant when the tip speed ratio is greater than 3.0 and under yawed conditions. At a yaw angle of 20°, when the T.I. is 0.5%, 10.5%, and 19.0%, respectively, the corresponding increased values are 13.17%, 3.44%, and 4.68%. Cross-stream velocity in the near-wake region of the swept-bladed turbine is markedly higher than that for the baseline condition. The averaged T.I. in the wake velocity region of the swept-blade conditions is greater than that of the baseline condition at most measurement positions. Moreover, power spectral density (PSD) magnitudes behind the blade tip for the swept-blade configuration are higher than those of the baseline, particularly in the medium- and high-frequency domains. This work clarifies the aerodynamic characteristics of swept-blade wind turbines to varying levels of turbulent inflow. Full article
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21 pages, 2641 KB  
Article
AICEBERG: A Novel Agentic AI Framework for Autonomous Radio Monitoring, Compliance and Governance Based on LLM, MCP, and SCPI in Smart Cities
by Florin Popescu and Denis Stanescu
Smart Cities 2026, 9(5), 73; https://doi.org/10.3390/smartcities9050073 (registering DOI) - 22 Apr 2026
Abstract
Urban radio spectrum monitoring is becoming increasingly complex due to the rapid growth of wireless devices, unauthorized emissions, and dynamic electromagnetic environments in smart cities. Traditional spectrum analysis approaches, based on manual operation or static detection techniques, are no longer sufficient to ensure [...] Read more.
Urban radio spectrum monitoring is becoming increasingly complex due to the rapid growth of wireless devices, unauthorized emissions, and dynamic electromagnetic environments in smart cities. Traditional spectrum analysis approaches, based on manual operation or static detection techniques, are no longer sufficient to ensure scalable, autonomous, and secure monitoring. The convergence of two emergent technologies—Large Language Models (LLMs) and the Model Context Protocol (MCP)—facilitates a fundamental shift in radio monitoring. We define this as the AICEBERG paradigm: a novel, stratified architecture where a high-level, intelligent agentic interface (the peak) abstracts the underlying complexity of SCPI-driven hardware integration and radio governance protocols (the foundational base). This autonomous framework provides the necessary objective rigor to audit the stochastic ‘ocean of electromagnetic waves’ characteristic of modern smart cities, ensuring a stable platform for regulatory enforcement amidst high-density signal interference. The proposed system implements a three-layer processing flow, enabling high-level natural language commands to be translated into validated and secure hardware actions on RF spectrum analyzers. A dual-server design separates operational execution from safety validation, ensuring controlled SCPI command handling, parameter verification, and instrument health monitoring. Experimental validation demonstrates the feasibility of autonomous measurement execution. The results show that the proposed architecture reduces human dependency, enhances reproducibility and lowers the expertise barrier required for RF spectrum surveillance. To the best of our knowledge, AICEBERG represents one of the first integrated frameworks to bridge LLMs with SCPI-compliant hardware through the MCP for autonomous radio governance. Full article
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15 pages, 7399 KB  
Article
Association Between Psychological Factors and Masticatory Muscle Thickness Assessed by Ultrasonography in Female Dental Students with TMD-Related Myalgia: A Cross-Sectional Study
by Marcin Wójcicki, Monika Litko-Rola, Jacek Szkutnik, Michał Ginszt, Piotr Gawda and Ingrid Różyło-Kalinowska
J. Clin. Med. 2026, 15(9), 3183; https://doi.org/10.3390/jcm15093183 - 22 Apr 2026
Abstract
Objectives: The aim of this study was to compare the relationship between psychological factors and the thickness of masticatory muscles in patients with temporomandibular disorders (TMD) and healthy controls. Methods: This cross-sectional study included 106 female participants aged 18–35 years, recruited from [...] Read more.
Objectives: The aim of this study was to compare the relationship between psychological factors and the thickness of masticatory muscles in patients with temporomandibular disorders (TMD) and healthy controls. Methods: This cross-sectional study included 106 female participants aged 18–35 years, recruited from students of the Medical University of Lublin. The study group consisted of individuals diagnosed with myalgia based on the Diagnostic Criteria for Temporomandibular Disorders (DC/TMD), while the control group included participants without TMD. Psychological factors were assessed using the PHQ-9, GAD-7, and PHQ-15 questionnaires. The thickness of the temporalis and masseter muscles was measured using an M-Turbo (Sonosite) ultrasound device under relaxed and contracted conditions. Results: Participants with TMD-related myalgia scored significantly higher on the PHQ-9 (mean ± SD: 8.82 ± 5.02 vs. 5.00 ± 3.41; p < 0.001), GAD-7 (8.53 ± 4.48 vs. 4.65 ± 3.58; p < 0.001), and PHQ-15 (9.47 ± 4.07 vs. 6.02 ± 3.89; p < 0.001) compared to controls. No statistically significant differences were observed in temporalis or masseter muscle thickness at rest or during contraction between groups (p > 0.05). Significant differences in correlations were found between depression scores and temporalis muscle thickness in the study group compared to the control group (r = 0.32 vs. −0.13, p = 0.011) as well as between anxiety scores and temporalis muscle thickness (r = 0.25 vs. −0.30, p = 0.002) No significant associations were found for the masseter muscle. Conclusions: Individuals with myalgia did not show increased muscle thickness compared to healthy individuals. Psychological distress, particularly depression and anxiety, was differentially related to temporalis muscle morphology in individuals with myalgia compared to healthy controls. Full article
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14 pages, 261 KB  
Article
Early Postural Instability with History of COVID-19 Influence Related to Diabetes: An Exploratory Cross-Sectional Study
by Kathrine Jáuregui-Renaud, José Adán Miguel-Puga, Aida García-López and María de Lourdes Tirado-Mondragón
J. Clin. Med. 2026, 15(9), 3178; https://doi.org/10.3390/jcm15093178 - 22 Apr 2026
Abstract
Background/Objective: In late adulthood, the increasing prevalence of diabetes overlaps with the highest prevalence of postural instability. A cross-sectional study was designed to explore the combined influence of age, gender, history of COVID-19 quadriceps strength, and Body Mass Index (B.M.I.) on the postural [...] Read more.
Background/Objective: In late adulthood, the increasing prevalence of diabetes overlaps with the highest prevalence of postural instability. A cross-sectional study was designed to explore the combined influence of age, gender, history of COVID-19 quadriceps strength, and Body Mass Index (B.M.I.) on the postural stability of adults with/without diabetes, under a variety of sensory conditions. Methods: A total of 263 adults aged 21 to 82 years old accepted to participate, 99 with and 164 without diabetes. They had no history of vestibular/otology/neurology/autoimmune/orthopedic disease or proliferative retinopathy/severe renal dysfunction/traumatic injury. After clinical and vestibular evaluations, postural sway was recorded on hard/soft surface, eyes open/closed, and without/with 30° neck extension. Bivariate analysis and repeated measures multivariate analysis of covariance were performed with 0.05 significance. Results: In the two groups, two thirds of the participants had excess weight and almost half had history of COVID-19. Overall conditions, gender and diabetes were the main factors contributing to sway area (multiple R = 0.28–0.31, p ≤ 0.001) and to sway length (multiple R = 0.34–0.47, p ≤ 0.00001). Compared to adults without diabetes, in those with diabetes, the age was not related to sway measurements; with contribution to sway from history of COVID-19 and quadriceps strength, and decreased contribution of the study variables to both the anterior–posterior position of the center of pressure and ankle movement (velocity as a function of the anterior–posterior position of the center of pressure) (p > 0.05). Conclusions: Diabetes may interfere with the influence of individual cofactors contributing to postural sway, including decreased influence of age and reduced ankle movement. A history of mild–moderate COVID-19 may have influence on postural control in varied sensory conditions. Full article
(This article belongs to the Section Clinical Neurology)
15 pages, 813 KB  
Article
Intra-Alveolar Gelatin Sponge Delivery of Dexamethasone vs. Methylprednisolone After Mandibular Third-Molar Surgery: A Randomized Controlled Trial
by Shabnam Sahebpanah, Atalay Elver, Mehmet Gagari Caymaz, Erdoğan Kıbcak and Melika Ghasemi Ghane
Appl. Sci. 2026, 16(8), 4060; https://doi.org/10.3390/app16084060 - 21 Apr 2026
Abstract
Impacted mandibular third-molar surgery commonly causes early postoperative pain, swelling, and trismus. This randomized, controlled, three-arm parallel trial evaluated whether intra-alveolar corticosteroid delivery via an absorbable gelatin sponge improves postoperative recovery compared with a saline control. Fifty-five patients were assessed for eligibility; 37 [...] Read more.
Impacted mandibular third-molar surgery commonly causes early postoperative pain, swelling, and trismus. This randomized, controlled, three-arm parallel trial evaluated whether intra-alveolar corticosteroid delivery via an absorbable gelatin sponge improves postoperative recovery compared with a saline control. Fifty-five patients were assessed for eligibility; 37 healthy adults (18–35 years) undergoing standardized mandibular third-molar extraction were randomized to dexamethasone 8 mg (Decort®), methylprednisolone 40 mg (Prednol®), or control (saline), all applied intra-alveolarly using a gelatin sponge carrier. Doses were selected using standard systemic glucocorticoid equivalence tables as a pragmatic potency reference, acknowledging unknown intra-alveolar pharmacokinetics/bioavailability. The prespecified primary endpoint (used for sample size planning) was postoperative Day 1 VAS pain; key secondary endpoints were Day 1 analgesic consumption and Day 3 facial swelling. Pain (VAS), analgesic use, trismus, and facial swelling (tragus–pogonion, tragus–labial commissure, and angulus–canthus distances) were assessed on postoperative Days 1, 2, 3, and 7 by a blinded evaluator. Two participants in the methylprednisolone group did not attend postoperative visits. To address potential attrition bias, an Intention-to-Treat (ITT) sensitivity analysis using conservative control-median imputation was performed alongside the available-case analyses. A global False Discovery Rate (FDR) correction was also applied to control for multiplicity. In both analyses, the steroid groups showed lower Day 1 pain scores than the control group. Methylprednisolone was associated with lower Day 3 swelling values than control for the tragus–pogonion and angulus–canthus measurements. These findings should be interpreted as preliminary, given the small sample size, linear swelling measurements, and lack of blinding verification. Full article
(This article belongs to the Special Issue Orofacial Pain: Diagnosis and Treatment)
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22 pages, 793 KB  
Systematic Review
Update on Repetitive Transcranial Magnetic Stimulation in Post-Stroke Cognitive Rehabilitation: A Systematic Review of Randomized Clinical Trials
by Davide N. Tringali, Rosario Ferlito, Rita Bella, Mariagiovanna Cantone, Rita Chiaramonte, Raffaele Ferri, Francesco Fisicaro, Michele Iacona, Maria P. Mogavero, Manuela Pennisi, Michele Vecchio and Giuseppe Lanza
Life 2026, 16(4), 700; https://doi.org/10.3390/life16040700 (registering DOI) - 21 Apr 2026
Abstract
Background: We synthesized evidence from randomized clinical trials (RCTs) published between 2019 and 2025 on repetitive transcranial magnetic stimulation (rTMS) in post-stroke cognitive impairment (PSCI) and compared different stimulation parameters, cortical targets, and combinations with rehabilitation interventions. Methods: A systematic review according to [...] Read more.
Background: We synthesized evidence from randomized clinical trials (RCTs) published between 2019 and 2025 on repetitive transcranial magnetic stimulation (rTMS) in post-stroke cognitive impairment (PSCI) and compared different stimulation parameters, cortical targets, and combinations with rehabilitation interventions. Methods: A systematic review according to PRISMA guidelines examined the RCTs applying rTMS in adults with PSCI compared with control or sham groups. The primary outcome was improvement in cognitive function and functional outcomes measured with standardized scales. Results: Fifteen studies, involving a total of 732 patients, were included. The most frequently investigated were high-frequency (≥10 Hz) stimulation protocols of the left dorsolateral prefrontal cortex, with treatment cycles ranging from 2 to 6 weeks. Overall, rTMS was generally safe and well tolerated, with rare and mild adverse events. Several studies reported improvements in cognitive performance following rTMS, although effects were variable across trials and need caution in light of heterogeneity in stimulation protocols, sample sizes, outcome measures, and methodological quality. In most cases, rTMS or intermittent theta burst stimulation combined with structured cognitive training yielded greater cognitive and functional gains than stimulation or rehabilitation alone. This suggests a positive interaction between rTMS and cognitive training, although current evidence does not yet allow definitive conclusions. Conclusions: rTMS appears to be a promising strategy for post-stroke cognitive rehabilitation, particularly for attention and executive functioning. However, heterogeneity in stimulation protocols and outcome measures, along with limited sample sizes and short follow-up, reduces the certainty and comparability of current evidence. The widespread reliance on global screening tools may further underestimate domain-specific effects. Future multicentre trials with standardized protocols and more sensitive cognitive assessments are needed to clarify efficacy and guide further clinical application of rTMS in PSCI. Full article
24 pages, 2609 KB  
Article
Physical Modeling of Seepage Control Using Upstream Blanket and Cutoff in Earth Dams: A Hele–Shaw Experimental Study
by Ahmed M. Abdelrazek, Mohamed A. Hafez, Abdulrahman Mohammed and Mohammed A. Abourohiem
Water 2026, 18(8), 989; https://doi.org/10.3390/w18080989 (registering DOI) - 21 Apr 2026
Abstract
Seepage beneath earth dams founded on pervious strata can cause excessive under-seepage, elevated downstream exit gradients, and high phreatic levels, thereby increasing susceptibility to internal erosion and piping. This study presents a Hele–Shaw laboratory investigation of seepage-control efficiency for an upstream impervious blanket [...] Read more.
Seepage beneath earth dams founded on pervious strata can cause excessive under-seepage, elevated downstream exit gradients, and high phreatic levels, thereby increasing susceptibility to internal erosion and piping. This study presents a Hele–Shaw laboratory investigation of seepage-control efficiency for an upstream impervious blanket used alone and in combination with a vertical cutoff (blanket–cutoff system). The experimental geometry reproduces a zoned earth dam cross-section at a scale of 1:200. Five foundation thickness ratios (T/B = 0.184–1.00) were tested. For the blanket-only system, four blanket length ratios (Lb/B = 0.50–1.25) were examined. For the blanket–cutoff system, cutoff depth ratios (S/T = 0.20–0.80) were investigated using (i) a representative blanket length Lb/B = 0.75 across all foundation depths and (ii) a deep-foundation case T/B = 1.00 across all blanket lengths. Seepage discharge, head loss due to seepage-control measures, maximum exit gradient at the downstream toe, and phreatic line location were measured at steady state and expressed in dimensionless form using the equivalent Hele–Shaw hydraulic conductivity. Relative to the no-measure reference case, the upstream blanket reduced dimensionless discharge by 20.8–70.2%, reduced the exit-gradient indicator by 6.4–50.2%, and reduced the downstream seepage-surface height by 58.9–92.8%. Adding a vertical cutoff provided further reductions relative to the blanket-only configuration, up to 34.4% in discharge and to 29.8% in exit-gradient indicator at Lb/B = 0.75—while increasing head loss across the upstream control system. Regression-based correlations and main-text design maps are proposed for preliminary sizing. The proposed correlations and design maps are intended for screening-level use only within the tested ranges 0.18 ≤ T/B ≤ 1.00, 0.50 ≤ Lb/B ≤ 1.25, and 0.20 ≤ S/T ≤ 0.80. Because the Hele–Shaw model is a two-dimensional viscous-flow analog of saturated seepage, the results provide a physical basis for relative comparison of seepage-control measures rather than a direct substitute for site-specific analysis of heterogeneous three-dimensional foundations. Accordingly, the agreement discussed in this paper is qualitative and trend-based, and the proposed tools are intended to complement rather than replace quantitative FEM for site-specific design. Full article
(This article belongs to the Special Issue Advances in Hydraulic and Water Resources Research, 4th Edition)
13 pages, 2946 KB  
Article
Aerobic Exercise Alleviates Oxidative Stress and Inflammation to Attenuate High-Fat Diet-Induced Non-Alcoholic Fatty Liver Disease in ApoE-/- Mice
by Liang Zhang, Wenxin Wang, Fengting Zheng, Jialu Weng, Yao Lu, Qingbo Li, Ting Li, Wei Li and Lifeng Wang
Metabolites 2026, 16(4), 285; https://doi.org/10.3390/metabo16040285 - 21 Apr 2026
Abstract
Background/Objectives: The development of non-alcoholic fatty liver disease (NAFLD) is closely linked to oxidative stress and inflammation. Aerobic exercise has been shown to improve NAFLD, although its underlying mechanisms remain incompletely understood. This study utilized ApoE-/- mice to investigate the role [...] Read more.
Background/Objectives: The development of non-alcoholic fatty liver disease (NAFLD) is closely linked to oxidative stress and inflammation. Aerobic exercise has been shown to improve NAFLD, although its underlying mechanisms remain incompletely understood. This study utilized ApoE-/- mice to investigate the role of Sestrin2 in aerobic exercise-induced amelioration of NAFLD. Methods: Random assignment of C57BL/6J and ApoE-/- mice yielded four groups: C (control), CE (aerobic exercise), AS (ApoE-/- control), and AE (ApoE-/- aerobic exercise). Aerobic exercise lasting 12 weeks was administered to the CE and AE groups. Serum biomarkers were analyzed by ELISA, liver tissue morphology was assessed via HE and ORO staining, and macrophage polarization was evaluated through immunofluorescence. Additionally, mRNA and protein expression levels were measured by qPCR and Western blot. Results: Aerobic exercise reduced liver wet weight, lipid accumulation, and steatosis in ApoE-/- mice. Aerobic exercise attenuates hepatic oxidative stress, and upregulated the expression of regulation oxidative stress related gene and proteins of Nrf2, HO-1, CAT, and SOD1 in ApoE-/- mice. Aerobic exercise promoted a shift in macrophage polarization from the pro-inflammatory M1 phenotype toward the anti-inflammatory M2 phenotype in the liver, and significantly reduced TNF-α and IL-1β levels, accompanied by upregulation of Sestrin2 expression, enhanced AMPK phosphorylation, inhibited mTORC1 in the liver. Conclusions: These findings suggest that aerobic exercise alleviates oxidative stress and inflammation in NAFLD, with Sestrin2 activation playing a central role. Full article
(This article belongs to the Section Endocrinology and Clinical Metabolic Research)
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24 pages, 6658 KB  
Article
Geochemical Characteristics and Paleoenvironmental Reconstruction of the Cretaceous Qingshankou Formation Shales in the Southeastern Uplift of the Songliao Basin: A Case Study from the Niaohexiang Section of Binxian, China
by Yangxin Su, Xiuli Fu, Hongjun Shao, Qinghai Xu, Kun Wang and Qiang Zheng
Appl. Sci. 2026, 16(8), 4052; https://doi.org/10.3390/app16084052 - 21 Apr 2026
Abstract
The Qingshankou Formation shales in the southeastern uplift of the Songliao Basin provide an ideal archive for constraining the controls of paleoenvironment on organic matter enrichment. Taking the shale succession at the Niaohexiang section of Binxian as the study object, we combined field [...] Read more.
The Qingshankou Formation shales in the southeastern uplift of the Songliao Basin provide an ideal archive for constraining the controls of paleoenvironment on organic matter enrichment. Taking the shale succession at the Niaohexiang section of Binxian as the study object, we combined field sampling with TOC measurements, whole-rock X-ray diffraction, and major, trace, and rare earth element analyses. The strata are dominated by black shale and dark gray mudstone, with mineral assemblages composed mainly of clay, felsic, and carbonate minerals; argillaceous shale exceeds 60%. Normal alkanes display a post-peak distribution with C27 as the dominant peak, low Pr/Ph ratios, and gammacerane index values of 0.18–0.26. Regular steranes are generally V-shaped, whereas some samples show high C29 sterane contents and a reversed L-shaped pattern. Major elements are dominated by SiO2 and Al2O3, trace elements such as Sr and Ba are relatively enriched, and rare earth elements show light REE enrichment with a pronounced negative Eu anomaly. These signatures indicate an upper-crustal felsic provenance and a continental island arc tectonic setting. Organic matter contents are low and derived mainly from terrestrial higher plants with minor aquatic input. Paleoenvironmental reconstruction suggests deposition in a freshwater to slightly brackish, semi-arid, anoxic-reducing shallow lacustrine setting with relatively low productivity, whereas dolostone formed under more saline, arid, and more productive conditions. Climatic fluctuations, salinity variations, and alternating redox states jointly controlled organic matter enrichment, and late-stage lacustrine salinization and anoxia associated with dolostone horizons enhanced organic matter preservation. Full article
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19 pages, 3934 KB  
Article
Evaluating the Influence of Terracing Induced Modifications of Runoff Patterns on Soil Redistribution Using In Situ 137Cs Measurements with a LaBr3 Scintillation Detector
by Leticia Gaspar and Ana Navas
Hydrology 2026, 13(4), 118; https://doi.org/10.3390/hydrology13040118 - 21 Apr 2026
Abstract
In subhumid Mediterranean agroecosystems, runoff drives soil erosion by controlling particle detachment and transport, with its generation and connectivity strongly influenced by land use. In areas affected by land abandonment and reforestation, terracing modifies hillslope morphology and flow pathways, thereby altering soil redistribution [...] Read more.
In subhumid Mediterranean agroecosystems, runoff drives soil erosion by controlling particle detachment and transport, with its generation and connectivity strongly influenced by land use. In areas affected by land abandonment and reforestation, terracing modifies hillslope morphology and flow pathways, thereby altering soil redistribution patterns. Fallout 137Cs has been widely used to assess medium term soil redistribution, and in situ gamma ray spectrometry using scintillation detectors provides an alternative for improving spatial coverage, yet the influence of factors specific to the site on measurements remains insufficiently explored. This study investigates how 137Cs counts obtained in situ with a LaBr3 detector can be used to interpret soil redistribution patterns in two paired catchments that experienced land abandonment since the mid-1960s. Following abandonment, catchment A underwent natural revegetation, whereas catchment B was terraced for reforestation, allowing the effects of water erosion and terracing on soil mobilisation to be analyzed through the spatial distribution of 137Cs. By linking 137Cs counts with catchment physiography, land use, flow pathways, and NDVI, the study aims to identify the main controls on soil redistribution in both catchments. 137Cs counts were significantly higher in catchment A (156.8 ± 108.2 counts) than in catchment B (53.2 ± 68.1), with coefficients of variation of 69% and 128%, respectively. The in situ 137Cs measurements provide reliable indicators of soil redistribution patterns controlled not only by runoff but also by anthropogenic modifications of hillslope morphology that alter flow pathways and hydrological connectivity following terracing. The paired catchment approach, combined with in situ 137Cs measurements, provides valuable insights into the key controls on soil redistribution, which is essential for effective land management. Full article
(This article belongs to the Special Issue The Influence of Landscape Disturbance on Catchment Processes)
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34 pages, 4612 KB  
Article
A Robust Numerical Framework for Hollow-Fiber Membrane Module Simulation and Solver Performance Analysis
by Diego Queiroz Faria de Menezes, Marília Caroline Cavalcante de Sá, Nayher Andres Clavijo Vallejo, Thainá Menezes de Melo, Luiz Felipe de Oliveira Campos, Thiago Koichi Anzai and José Carlos Costa da Silva Pinto
Membranes 2026, 16(4), 154; https://doi.org/10.3390/membranes16040154 - 21 Apr 2026
Abstract
Robust numerical frameworks are essential for the simulation, design, monitoring, and control of membrane-based separation units, particularly under highly nonlinear and industrially relevant operating conditions. In this context, a comprehensive phenomenological and numerical framework is proposed for the simulation of hollow-fiber membrane modules, [...] Read more.
Robust numerical frameworks are essential for the simulation, design, monitoring, and control of membrane-based separation units, particularly under highly nonlinear and industrially relevant operating conditions. In this context, a comprehensive phenomenological and numerical framework is proposed for the simulation of hollow-fiber membrane modules, incorporating coupled mass, momentum (through pressure drop), and energy transport equations. The governing equations are discretized using a rigorous orthogonal collocation formulation, and the performances of two numerical solution strategies are systematically investigated for the first time to allow the in-line and real-time implementation of the model: a steady-state approach based on the Newton–Raphson method with careful treatment of initial estimates, and a pseudotransient formulation. Particularly, an original and consistent numerical treatment is introduced for the energy balance at boundaries where the permeate flow vanishes, enabling the stable incorporation of thermal effects and Joule–Thomson phenomena. The results clearly show that the steady-state Newton–Raphson approach provides the best overall performance in terms of computational efficiency, numerical robustness, and accuracy when physically consistent initial profiles are employed. In particular, the combination of a linear initial guess and a numerical mesh constituted of four collocation points yielded the most favorable balance between convergence speed, numerical robustness, and accuracy for the base-case sensitivity analysis. For monitoring-oriented applications, the numerical choice should be weighted primarily toward computational performance once physical consistency and convergence criteria are satisfied, rather than toward maximum mesh-refinement accuracy. In this context, small differences in internal-fiber profiles can be compensated through real-time permeance estimation and are negligible when compared with measurement uncertainty in real industrial processes. Under extreme operating conditions involving low concentrations, low flow rates, and highly permeable species, the pseudotransient formulation proved to be a reliable auxiliary strategy, enabling robust convergence when suitable initial guesses were not readily available. The proposed framework is validated against experimental data from the literature and subjected to extensive convergence and sensitivity analyses, providing a reliable basis for simulation and for assessing computational feasibility in in-line and real-time monitoring-oriented applications. A full demonstration of digital-twin integration, online parameter updating, reduced-order coupling, and closed-loop control is beyond the scope of the present study and will be addressed in future work. Full article
27 pages, 7025 KB  
Article
Flower-Like Stearic Acid/Rosehip Oil Self-Assembled Layers for Copper Corrosion Protection
by Regina Fuchs-Godec
ChemEngineering 2026, 10(4), 53; https://doi.org/10.3390/chemengineering10040053 - 21 Apr 2026
Abstract
The corrosion protection of copper in acidic urban rain environments was studied using self-assembled hydrophobic layers (SAHLs) based on stearic acid (SA), with and without rosehip seed oil (RH). The limited durability of fatty acid-based self-assembled layers under acidic conditions was addressed by [...] Read more.
The corrosion protection of copper in acidic urban rain environments was studied using self-assembled hydrophobic layers (SAHLs) based on stearic acid (SA), with and without rosehip seed oil (RH). The limited durability of fatty acid-based self-assembled layers under acidic conditions was addressed by correlating surface wettability, morphology, and electrochemical behaviour. Contact angle and SEM analyses showed that SA alone forms a moderately hydrophobic but structurally irregular layer, whereas the addition of 2.0 wt.% RH produces a hierarchical micro/nanostructure with near-superhydrophobic characteristics (CA ≈ 149°). Electrochemical measurements in simulated acid rain solutions (pH 5, 3, and 1) revealed a strong pH dependence of protective performance. While SA-derived layers provided effective protection at pH 5, they deteriorated at lower pH due to protonation of carboxylate anchoring groups and electrolyte ingress. In contrast, SAHLs containing 2.0 wt.% RH maintained polarisation resistance in the MΩ cm2 range and inhibition efficiencies above 99% at pH 3, and remained effective even at pH 1. Long-term EIS results indicate a predominantly diffusion-controlled, barrier-type inhibition mechanism associated with defects sealing and interfacial reorganisation. Notably, the rosehip seed oil used is a commercially available, bio-based material with expired shelf life, highlighting the potential of waste-derived resources for sustainable corrosion protection. Full article
(This article belongs to the Special Issue Advances in Sustainable and Green Chemistry)
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13 pages, 709 KB  
Article
On-Field Assessment of Joint Load in Football Using Machine Learning (Part II)
by Anne Benjaminse, Margherita Mendicino, Eline M. Nijmeijer, Pietro Margheriti, Alli Gokeler and Stefano Di Paolo
Sensors 2026, 26(8), 2562; https://doi.org/10.3390/s26082562 - 21 Apr 2026
Abstract
Anterior cruciate ligament (ACL) injury risk is elevated in female youth football, yet knee joint loading has mainly been studied under controlled laboratory conditions. This limits understanding of how injury risk emerges during realistic match situations. This study provided a field-based kinetic characterization [...] Read more.
Anterior cruciate ligament (ACL) injury risk is elevated in female youth football, yet knee joint loading has mainly been studied under controlled laboratory conditions. This limits understanding of how injury risk emerges during realistic match situations. This study provided a field-based kinetic characterization of football-specific movements by estimating knee abduction moments (KAMs) using wearable sensors and machine learning. Fifty-two highly talented female youth players performed agility tasks during training, including structured exercises (F-EX) and game-based play (F-GAME). Full-body kinematics were collected with inertial measurement units, and a validated support vector machine model, trained on synchronized motion capture and force plate data, classified trials as high or low KAM. Across 662 change-in-direction trials, 9–12% were classified as high KAM in both conditions, indicating that potentially high-risk loading regularly occurs during routine actions. High KAM trials showed reduced knee and pelvis flexion, increased hip flexion, and greater pelvis rotation toward the cutting direction, reflecting upright, stiff movement strategies. Performance analyses revealed smaller cut angles in exercises and greater approach acceleration in game play, without differences in peak velocity. These findings demonstrate the feasibility of field-based kinetic screening and support a complex-systems perspective on ACL injury risk. Full article
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