Search Results (45)

Road dust resuspension is widely recognized as a major contributor to traffic-related particulate matter (PM) in urban environments. Nevertheless, reported emission factors exhibit substantial variability. These discrepancies stem not only from the intrinsic complexity of the resuspension process but also from limitations in measurement techniques, which often fail to adequately control or characterize the influencing parameters. As a result, the contribution of each parameter remains difficult to isolate, leading to inconsistencies across studies. This study presents an experimental protocol developed to quantify PM10 and PM2.5 emission factors associated with vehicle-induced road dust resuspension. Experiments were conducted on a dedicated test track seeded with alumina particles of controlled mass and size distribution to simulate road dust. A network of microsensors was strategically deployed at multiple upwind and downwind locations to continuously monitor particle concentration variations during vehicle passages. Emission factors were derived through time integration of the mass flow rate of resuspended dust measured by the sensor network. The estimated PM10 emission factor showed excellent agreement, within 2.5%, with predictions from a literature-based formulation, thereby validating the accuracy and external relevance of the proposed protocol. In contrast, comparisons with U.S. EPA formulas and other empirical equations revealed substantially larger discrepancies, particularly for PM2.5, highlighting the persistent limitations of current modeling approaches. Full article

The Changjiang estuary–Hangzhou Bay region is a critical zone of land–sea interaction, where Total Suspended Matter (TSM) dynamics significantly influence coastal ecology and engineering. While previous studies have examined individual factors affecting TSM variability, the synergistic effects of “tide–monsoon–current” interactions and the actual pathways of turbid plume transport remain poorly understood. Using GOCI satellite data, in situ buoy measurements, and voyage data from 2020, this study applied Data Interpolating Empirical Orthogonal Functions (DINEOFs) and comprehensive spatio-temporal analysis to reconstruct continuous high-resolution TSM fields and elucidate multi-factor controls on TSM dynamics. Based on this high-resolution dataset of TSM, we found that, during the dry season, elevated TSM concentrations are primarily driven by wind–tide resuspension and transport under the comprehensive forcing of the Jiangsu Alongshore Current (JAC), the Yellow Sea Warm Current (YSWC), and wind–tide-induced flows. Contrary to the conventional understanding, the Jiangsu-origin surface TSM can transport to the outer sea without supplementing the TSM in the Turbidity Maximum Zone (TMZ). The YSWC in autumn can cause either low C_TSM gradients or high gradients nearshore depending on whether it is carrying Korean coastal turbid water or not. During the wet season, stratification induced by the Changjiang freshwater discharge suppresses wind–tide resuspension, reducing TSM concentrations in the TMZ and the Qidong water. However, the Changjiang freshwater combined with the Taiwan Warm Current (TWC) dilutes surface TSM in Hangzhou Bay, where the two water masses meet on the 10 m isobath. These insights into factor interactions and TSM plume pathways provide a scientific basis for improved environmental monitoring and coastal management. Full article

Microscopic Particulate Matter (PM) below 10 µm can enter the respiratory system and affect human health in the short and long term. Railway enclosures are sites with high concentrations of fine PM and technical solutions like mechanical filtration exist to increase the air quality. However, several crucial factors must be evaluated and optimized like energy consumption, maintenance cost/interval, design and control. A fast and adaptable evaluation of decontamination solutions is required to find the optimal solution. To answer this, a 1D multizone model based on station discretization aligned with the track direction is proposed to precisely place decontamination systems along the station. In each zone, a set of ordinary differential equations is used to forecast the daily progression of PM concentrations, based on physical parameters (air and train velocities, and train traffic) used to describe the different physical phenomena (resuspension, deposition, ventilation and generation). Three-dimensional CFD (Computational Fluid Dynamics) simulations are used to characterize the efficiency and range of decontamination products and reproduce their effect in the 1D model. This approach allows for flexible optimization of local and global decontamination efficiencies with multiple parameter changes. PM₁₀ and PM_2.5 (below 10 and 2.5 µm) are studied here as they are often monitored. Full article

The erodibility of natural cohesive sediments and artificial mixtures was investigated through controlled laboratory experiments and used as a basis to discuss seabed mobility and suspended particulate matter on the Continental Shelf adjacent to a river mouth. Changes in the erodibility of cohesive seabeds can influence resuspension and erosion rates and impact suspended particulate matter dispersion patterns and even the benthic community. For the experiments, sediment samples with sand content ranging from 0% to 90% were tested using an erosion testing chamber to evaluate the relationships among sand content, settling, consolidation, critical shear stress, and erosion rate. Critical shear stress values ranged from 0.31 to 0.42 N/m², and erosion rates varied up to 30 times between the most mud-rich and sand-rich samples. Natural samples exhibited lower erodibility, evidenced by higher critical shear stress and lower erosion rates compared to Industrial Clay, highlighting the role of organic matter in enhancing sediment stability. Additionally, although the sand addition reduced the critical shear stress required for sediment motion, it resulted in lower erosion rates. Results were also compared with sediment samples collected from the Continental Shelf adjacent to the Doce River mouth, a region impacted by a large-scale mining tailings spill in 2015. Although the frequency of sediment mobilization did not differ significantly between pre- and post-disaster conditions, mud-rich sediments exhibited greater erosion potential once the threshold was surpassed. This suggests that the dam failure impacted the sediment dynamics of the Continental Shelf adjacent to the Doce River mouth. These findings can be used to improve sediment transport models and environmental management strategies in disturbed coastal systems. Full article

Microplastics (MPs) are pervasive in freshwater and may threaten aquatic ecosystem health. We surveyed surface waters of Shijiu Lake and its inflowing tributaries during the dry (January–March) and rainy (May–July) seasons of 2024. MP abundance ranged within 17.54–30.93 items/L, with higher values in the rainy than in the dry season (28.18 ± 6.03 vs. 24.53 ± 5.68 items/L; one-way ANOVA, p < 0.05). Abundance correlated positively with turbidity (r = 0.44; R² = 0.20; p < 0.05), whereas associations with total nitrogen, total phosphorus, and suspended solids were not significant (p > 0.05). Small particles (38–75 μm) dominated and were slightly more prevalent in the dry season, while the fraction of larger particles (>150 μm) was relatively higher in the rainy season. Granules predominated across sites, but their share decreased in the rainy season, accompanied by a notable increase in fibers. The Pollution Load Index (PLI) indicated slight but spatially uneven pollution (PLI = 1.00–1.43), generally higher during the rainy season and consistently elevated at the lake center; the Nongkan River exhibited the lowest levels. Ecologically, the patterns indicate rainfall-driven inputs and hydrodynamic controls (runoff, resuspension, residence time), identifying the lake center and tributary interfaces as priority zones for monitoring and mitigation. These results provide lake-scale evidence to refine seasonal monitoring and inform source-reduction strategies in similar inland waters. Full article

Understanding the spatiotemporal dynamics of water quality parameters and microbial communities in drinking water distribution systems (DWDS) and their interrelationships is critical for ensuring the safety of tap water supply. This study investigated the diurnal, monthly, and annual variation patterns of water quality and the stage-specific succession behaviors of microbial communities in a DWDS located in southeastern China. Results indicated that hydraulic shear stress during peak usage periods drove biofilm detachment and particle resuspension. This process led to significant diurnal fluctuations in total cell counts (TCC) and metal ions, with coefficients of variation ranging from 0.44 to 1.89. Monthly analyses revealed the synergistic risks of disinfection by-products (e.g., 24.5 μg/L of trichloromethane) under conditions of low chlorine residual (<0.2 mg/L) and high organic loading. Annual trends suggested seasonal coupling: winter pH reductions correlated with organic acid accumulation, while summer microbial blooms associated with chlorine decay and temperature increase. Nonlinear interactions indicated weakened metal–organic complexation but enhanced turbidity–sulfate adsorption, suggesting altered contaminant mobility in pipe scales. Microbial analysis demonstrated persistent dominance of oligotrophic Phreatobacter and prevalence of Pseudomonas in biofilms, highlighting hydrodynamic conditions, nutrient availability, and disinfection pressure as key drivers of community succession. These findings reveal DWDS complexity and inform targeted operational and microbial risk control strategies. Full article

The encapsulation of hydrophobic substances remains a significant challenge due to limitations such as low loading efficiency, leakage, and poor distribution within microcapsules. This study introduces a novel strategy utilizing colloidosomes assembled from polyelectrolyte microcapsules (PMCs). PMCs were fabricated via layer-by-layer (LbL) assembly on manganese carbonate (MnCO₃) or calcium carbonate (CaCO₃) cores, followed by core dissolution. A solvent gradient replacement method was employed to substitute the internal aqueous phase of PMCs with kerosene, enabling the formation of colloidosomes through self-assembly upon resuspension in water. Comparative analysis revealed that MnCO₃-based PMCs with smaller diameters (2.5–3 µm vs. 4.5–5.5 µm for CaCO₃) exhibited 3.5-fold greater stability, attributed to enhanced inter-capsule interactions via electrostatic and hydrophobic forces. Confocal microscopy confirmed the structural integrity of colloidosomes, featuring a liquid kerosene core encapsulated within a PMC shell. Temporal stability studies indicated structural degradation within 30 min, though 5% of colloidosomes retained integrity post-water evaporation. PMC-based colloidosomes exhibit significant application potential due to their integration of colloidosome functionality with PMC-derived structural features—semi-permeability, tunable shell thickness/composition, and stimuli-responsive behavior—enabling their adaptability to diverse technological and biomedical contexts. This innovation holds promise for applications in drug delivery, agrochemicals, and environmental technologies, where controlled release and stability are critical. The findings highlight the role of core material selection and solvent engineering in optimizing colloidosome performance, paving the way for advanced encapsulation systems. Full article

Submarine groundwater discharge (SGD) refers to the flow of groundwater that enters seawater through the seabed surface at the edge of the coastal shelf. During this discharge process, seepage and initiation can easily trigger seabed instability, which significantly influences the breeding, occurrence, and evolution of marine geological events. The narrow distribution of land near the coastline and the substantial flux of groundwater discharge are closely associated with typical seabed geological events, such as submarine landslides and collapse pits, which are prevalent in the sea area. This paper analyzes the current research status of SGD both domestically and internationally, elucidates the interaction mechanisms between groundwater discharge and the seabed, and integrates existing studies on discharge-induced slope instability, collapse pit formation, and seabed erosion and resuspension. It summarizes and evaluates the existing research on the influence of seabed groundwater discharge on the evolution of seabed geological structures, identifies key scientific problems that urgently need to be addressed, and proposes future research directions that require further emphasis. Additionally, the paper conducts research on the mechanisms by which groundwater discharge affects seabed stability, providing valuable insights for the study of coastal zones in China. It also offers a scientific basis for enhancing the understanding of the generation mechanisms of marine geological events and improving the technological capabilities for their prevention and control. Full article

The present study examined the influence of controlled heat injection on the sedimentation of fine particles in a trapezoidal container, aiming to explore the combined effects of the Boycott effect and convection induced by heating. The experimental design incorporates varying initial particle concentrations (1500 ppm and 3000 ppm) and heat injection levels (0 W, 4.5 W, and 9 W imposed power) to analyze sedimentation dynamics, focusing on concentration distribution patterns and clear water production. The findings reveal complex interactions between heat injection and particle concentration. At 1500 ppm, heat injection shows minimal impact on sedimentation due to particle resuspension. However, at 3000 ppm, particularly with a 9 W heat injection, the sedimentation performance improves significantly during the early stages of the process, achieving an average sedimentation rate approximately 40 % higher than without heat injection and an average clear water generation rate nearly four times greater. These clear water generation rates were determined considering water with particle concentrations below 20 % of the initial concentration (300 ppm for 1500 ppm and 600 ppm for 3000 ppm). A further analysis of the column and row data reveals stratification patterns influenced by heat injection, characterized by distinct horizontal and vertical layers. Additionally, the results suggest that wall temperature distributions are largely unaffected by the initial particle concentration, while clear water production and sedimentation efficiency are highly dependent on heat levels and initial particle density. These results highlight the potential of heat-enhanced sedimentation to improve separation processes in industrial systems. Specifically, they provide valuable insights for optimizing the design and efficiency of lamella settlers, commonly used in water treatment and other particulate separation applications. Future studies will explore the combined use of coagulants and flocculants and the application of these findings to real mixtures, such as mine water or wastewater, to further validate and expand their industrial applicability. Full article

Submerged plants and related disturbances can affect both the phosphorus (P) release and the microbial communities in sediments. In this study, a sediment resuspension system was constructed, and P variability characteristics influenced by Vallisneria natans (V. natans) and the response mechanism of the microbial community were studied. The results indicated that the total phosphorus (TP) content increased from 678.875 to 1019.133 mg/kg and from 1126.017 to 1280.679 mg/kg in sediments and suspended solids (SSs) during the sediment resuspension process, respectively. Organic P (OP) increased by 127.344 mg/kg and 302.448 mg/kg in sediments and SSs after the disturbance, respectively. The microbial communities in the sediments and the leaves of V. natans had higher Chao values after the disturbance, while Shannon values decreased after the disturbance compared to the control in SSs. Proteobacteria had the highest abundance with the value of 51.1% after the disturbance in the sediments and SSs, and the abundance values of Proteobacteria in rhizomes and leaves of V. natans could reach 73.2% on average. Chloroflexi, Acidobacteria, and Firmicutes were also the main phyla in the sediment resuspension system. Sodium hydroxide extractable P (NaOH-P) in sediments could reduce the bioavailability of this P fraction under disturbance conditions. The decrease in the abundance of Bacteroidetes and Nitrospirae indicated that they were more sensitive to the disturbance, and the rotational speed changed the survival conditions for the Bacteroidetes and Nitrospirae. The response mechanism of microbial community during the sediment resuspension process could reflect the influence of the microbial community on the changing characteristics of P and could provide a theoretical foundation for P control at the micro level. Full article

Offshore wind farms (OWFs), built extensively in recent years, induce changes in the surrounding water environment. The changes in the suspended sediment concentration (SSC) and chlorophyll-a concentration (Chl-aC) induced by an OWF in the Yangtze River Estuary were analyzed based on Chinese Gaofen (GF) satellite data. The results show the following: (1) The flow near the wind turbines makes the bottom water surge, driving the sediment to “re-suspend” and be lost, deepening the scour pit around the bottom of the wind turbines, which is known as “self-digging”. The interaction between the pillar of a wind turbine and tidal currents makes hydrodynamic factors more complicated. Blocking by wind turbines promoting the scour of the bottom seabed of the OWF results in speeding up the circulation rate of sediment loss and “re-suspension”, which contributes to the change in the SSC and Chl-aC. This kind of change in sediment transport in estuarine areas due to human construction affects the balance of the ecological environment. Long-term sediment loss around wind turbines also influences the safety of wind turbines. (2) The SSC and Chl-aC are mainly in the range of 200–600 mg/L and 3–7 μg/L, respectively, in the OWF area, higher than the values obtained in surrounding waters. The SSC and Chl-aC downstream of the OWF are higher than those upstream, with differences of 100–300 mg/L and 0.5–2 μg/L. High SSC and Chl-aC “tails” appear downstream of wind turbines, consistent with the direction of local tidal currents, with lengths in the range of 2–4 km. In addition, the water environment in the vicinity of a wind turbine array, with a roughly 2–5 km scope (within 4 km during flooding and around 2.5 km during ebbing approximately) downstream of the wind turbine array, is impacted by the OWF. (3) In order to solve the problem of “self-digging” induced by OWFs, it is suggested that the distance between two wind turbines should be controlled within 2–3.5 km in the main flow direction, promising that the second row of wind turbines will be placed on the suspended sediment deposition belt induced by the first row. In this way, the problems of ecosystem imbalance and tidal current structure change caused by sediment loss because of local scouring can be reduced. Furthermore, mutual compensation between wind turbines can solve the “self-digging” problem to a certain extent and ensure the safety of OWFs. Full article

Guangzhou and Shenzhen are two core cities in the Guangdong-Hong Kong-Macao Greater Bay Area (GBA). It is increasingly important to regulate water quality in urban development. The Forel–Ule Index (FUI) can be obtained by optical data and is an important indicator. Therefore, we used Sentinel-2 to calculate the FUI of 41 lakes and reservoirs in Guangzhou and Shenzhen from January to December in 2016–2021, and analyzed their spatio-temporal variations, including spatial distributions, seasonal variations, and inter-annual variations. We also performed a correlation analysis of driving factors. In Guangzhou, the FUI was low in the north and west, and high in the south and east. In Shenzhen, the FUI was high in the west and low in the east. Moreover, 68% of the lakes and reservoirs in Guangzhou exhibited seasonal variations, with a low FUI in summer and autumn, and high levels in spring and winter. Shenzhen had the lowest FUI in autumn. Furthermore, 36% of the lakes and reservoirs in Guangzhou exhibited increasing inter-annual variations, whereas Shenzhen exhibited stable and decreasing inter-annual variations. Among the 41 lakes and reservoirs analyzed herein, the FUI of 10 water areas were positively correlated with precipitation, while the FUI of 31 water areas were negatively correlated with precipitation. Increased precipitation leads to an increase in external pollutants and sediment, as well as the resuspension of substances in the water, resulting in more turbid water. Therefore, an increase in precipitation is positively correlated with the FUI, whereas a decrease in precipitation is negatively correlated with the FUI. These findings can be used to design suitable management policies to maintain and control the local water quality. Full article

Emission control regulations have been essential in reducing vehicular exhaust emissions. However, the contribution of exhaust and non-exhaust emissions to ambient particulate matter (PM) has not yet been accurately quantified due to the lack of standardized sampling and measurement methods to set regulations. The identified sources and the source profiles generated have not been comparable as none of the emission data collection techniques and the receptor models applied in the literature have produced a standard or reference method to simultaneously identify and quantify the non-exhaust emission sources. This study utilized and thoroughly characterized PM samples including 32 major and trace elements from a mixed fleet in a mountain highway tunnel atmosphere in Bolu, Türkiye. This work proposed a two-stage, simple, and robust method based on road dust enrichment factor (EF) and elemental carbon (EC) tracer methods (EFECT) for the identification and prediction of the exhaust (exh), and non-exhaust (n-exh) emissions in PM. The indicated method revealed that road dust resuspension emissions are the most significant contributor to the concentrations of crustal elements. This method was used successfully to determine the real-world elemental contributions of road dust resuspension (rdrs), emissions (em), exhaust (exh), and non-exhaust (n-exh) emission sources to the elemental concentrations in PM samples. This study provided significant insights into generating actual source profiles, source-specific emission factors, and the source apportionment results for vehicular emission sources worldwide. Considering this, PM data of any particle size fraction (PM₁₀, PM_10-2.5, and PM_2.5, for example) can be used as input for the EFECT, provided that the data include the analytical results of elemental carbon in both the atmospheric PM and road dust samples having similar PM sizes. Full article

Biodegradable nanocarriers represent promising tools for controlled drug delivery. However, one major drawback related to their use is the long-term stability, which is largely influenced by the presence of water in the formulations, so to solve this problem, freeze-drying with cryoprotectants has been proposed. In the present study, the influence of the freeze-drying procedure on the storage stability of poly(lactide-co-glycolide) (PLGA) nanoparticles and liposomes was evaluated. In particular, conventional cryoprotectants were added to PLGA nanoparticle and liposome formulations in various conditions. Additionally, hyaluronic acid (HA), known for its ability to target the CD44 receptor, was assessed as a cryoprotective excipient: it was added to the nanocarriers as either a free molecule or conjugated to a phospholipid to increase the interaction with the polymer or lipid matrix while exposing HA on the nanocarrier surface. The formulations were resuspended and characterized for size, polydispersity index, zeta potential and morphology. It was demonstrated that only the highest percentages of cryoprotectants allowed the resuspension of stable nanocarriers. Moreover, unlike free HA, HA-phospholipid conjugates were able to maintain the particle mean size after the reconstitution of lyophilized nanoparticles and liposomes. This study paves the way for the use of HA-phospholipids to achieve, at the same time, nanocarrier cryoprotection and active targeting. Full article

Shallow water has low depth, and hydrodynamic conditions may change with the effect of wind and waves, resulting in sediment suspension and pollutant release. To investigate the influence of sediment incipient motion on ammonia nitrogen (NH₃-N) release in shallow lakes under hydrodynamic disturbance, we monitored ammonia nitrogen concentration in the overlying water of sediments in Chaohu Lake under static, weak, and strong disturbance conditions and analyzed the ammonia nitrogen release rate based on the these concentrations. In static condition, the sediment particles on the surface moved individually (individual movement), and the ammonia nitrogen release rate was 9.59 mg/m²/day. When the disturbance was weak and a small proportion of sediment particles started to move (small movement), the ammonia nitrogen release rate increased to 34.21 mg/m²/day. When the disturbance was further strengthened, and most of the sediment particles moved (general movement), the ammonia nitrogen release rate was 77.04 mg/m²/day. Distribution showed that the release rate varied the most in the western area followed by the eastern area, and the central area had the lowest release rate. The daily release of ammonia nitrogen in Chaohu Lake ranged from 8742.3 kg to 61,008.59 kg. In this experiment, we combined sediment movement and pollutant release, which provides a new reference for the study of pollutant release in shallow lakes and for ammonia nitrogen management in other shallow lakes. Full article