Search Results (39)

The encapsulation of hydrophobic substances remains a significant challenge due to limitations such as low loading efficiency, leakage, and poor distribution within microcapsules. This study introduces a novel strategy utilizing colloidosomes assembled from polyelectrolyte microcapsules (PMCs). PMCs were fabricated via layer-by-layer (LbL) assembly on manganese carbonate (MnCO₃) or calcium carbonate (CaCO₃) cores, followed by core dissolution. A solvent gradient replacement method was employed to substitute the internal aqueous phase of PMCs with kerosene, enabling the formation of colloidosomes through self-assembly upon resuspension in water. Comparative analysis revealed that MnCO₃-based PMCs with smaller diameters (2.5–3 µm vs. 4.5–5.5 µm for CaCO₃) exhibited 3.5-fold greater stability, attributed to enhanced inter-capsule interactions via electrostatic and hydrophobic forces. Confocal microscopy confirmed the structural integrity of colloidosomes, featuring a liquid kerosene core encapsulated within a PMC shell. Temporal stability studies indicated structural degradation within 30 min, though 5% of colloidosomes retained integrity post-water evaporation. PMC-based colloidosomes exhibit significant application potential due to their integration of colloidosome functionality with PMC-derived structural features—semi-permeability, tunable shell thickness/composition, and stimuli-responsive behavior—enabling their adaptability to diverse technological and biomedical contexts. This innovation holds promise for applications in drug delivery, agrochemicals, and environmental technologies, where controlled release and stability are critical. The findings highlight the role of core material selection and solvent engineering in optimizing colloidosome performance, paving the way for advanced encapsulation systems. Full article

Submarine groundwater discharge (SGD) refers to the flow of groundwater that enters seawater through the seabed surface at the edge of the coastal shelf. During this discharge process, seepage and initiation can easily trigger seabed instability, which significantly influences the breeding, occurrence, and evolution of marine geological events. The narrow distribution of land near the coastline and the substantial flux of groundwater discharge are closely associated with typical seabed geological events, such as submarine landslides and collapse pits, which are prevalent in the sea area. This paper analyzes the current research status of SGD both domestically and internationally, elucidates the interaction mechanisms between groundwater discharge and the seabed, and integrates existing studies on discharge-induced slope instability, collapse pit formation, and seabed erosion and resuspension. It summarizes and evaluates the existing research on the influence of seabed groundwater discharge on the evolution of seabed geological structures, identifies key scientific problems that urgently need to be addressed, and proposes future research directions that require further emphasis. Additionally, the paper conducts research on the mechanisms by which groundwater discharge affects seabed stability, providing valuable insights for the study of coastal zones in China. It also offers a scientific basis for enhancing the understanding of the generation mechanisms of marine geological events and improving the technological capabilities for their prevention and control. Full article

The present study examined the influence of controlled heat injection on the sedimentation of fine particles in a trapezoidal container, aiming to explore the combined effects of the Boycott effect and convection induced by heating. The experimental design incorporates varying initial particle concentrations (1500 ppm and 3000 ppm) and heat injection levels (0 W, 4.5 W, and 9 W imposed power) to analyze sedimentation dynamics, focusing on concentration distribution patterns and clear water production. The findings reveal complex interactions between heat injection and particle concentration. At 1500 ppm, heat injection shows minimal impact on sedimentation due to particle resuspension. However, at 3000 ppm, particularly with a 9 W heat injection, the sedimentation performance improves significantly during the early stages of the process, achieving an average sedimentation rate approximately 40 % higher than without heat injection and an average clear water generation rate nearly four times greater. These clear water generation rates were determined considering water with particle concentrations below 20 % of the initial concentration (300 ppm for 1500 ppm and 600 ppm for 3000 ppm). A further analysis of the column and row data reveals stratification patterns influenced by heat injection, characterized by distinct horizontal and vertical layers. Additionally, the results suggest that wall temperature distributions are largely unaffected by the initial particle concentration, while clear water production and sedimentation efficiency are highly dependent on heat levels and initial particle density. These results highlight the potential of heat-enhanced sedimentation to improve separation processes in industrial systems. Specifically, they provide valuable insights for optimizing the design and efficiency of lamella settlers, commonly used in water treatment and other particulate separation applications. Future studies will explore the combined use of coagulants and flocculants and the application of these findings to real mixtures, such as mine water or wastewater, to further validate and expand their industrial applicability. Full article

Submerged plants and related disturbances can affect both the phosphorus (P) release and the microbial communities in sediments. In this study, a sediment resuspension system was constructed, and P variability characteristics influenced by Vallisneria natans (V. natans) and the response mechanism of the microbial community were studied. The results indicated that the total phosphorus (TP) content increased from 678.875 to 1019.133 mg/kg and from 1126.017 to 1280.679 mg/kg in sediments and suspended solids (SSs) during the sediment resuspension process, respectively. Organic P (OP) increased by 127.344 mg/kg and 302.448 mg/kg in sediments and SSs after the disturbance, respectively. The microbial communities in the sediments and the leaves of V. natans had higher Chao values after the disturbance, while Shannon values decreased after the disturbance compared to the control in SSs. Proteobacteria had the highest abundance with the value of 51.1% after the disturbance in the sediments and SSs, and the abundance values of Proteobacteria in rhizomes and leaves of V. natans could reach 73.2% on average. Chloroflexi, Acidobacteria, and Firmicutes were also the main phyla in the sediment resuspension system. Sodium hydroxide extractable P (NaOH-P) in sediments could reduce the bioavailability of this P fraction under disturbance conditions. The decrease in the abundance of Bacteroidetes and Nitrospirae indicated that they were more sensitive to the disturbance, and the rotational speed changed the survival conditions for the Bacteroidetes and Nitrospirae. The response mechanism of microbial community during the sediment resuspension process could reflect the influence of the microbial community on the changing characteristics of P and could provide a theoretical foundation for P control at the micro level. Full article

Offshore wind farms (OWFs), built extensively in recent years, induce changes in the surrounding water environment. The changes in the suspended sediment concentration (SSC) and chlorophyll-a concentration (Chl-aC) induced by an OWF in the Yangtze River Estuary were analyzed based on Chinese Gaofen (GF) satellite data. The results show the following: (1) The flow near the wind turbines makes the bottom water surge, driving the sediment to “re-suspend” and be lost, deepening the scour pit around the bottom of the wind turbines, which is known as “self-digging”. The interaction between the pillar of a wind turbine and tidal currents makes hydrodynamic factors more complicated. Blocking by wind turbines promoting the scour of the bottom seabed of the OWF results in speeding up the circulation rate of sediment loss and “re-suspension”, which contributes to the change in the SSC and Chl-aC. This kind of change in sediment transport in estuarine areas due to human construction affects the balance of the ecological environment. Long-term sediment loss around wind turbines also influences the safety of wind turbines. (2) The SSC and Chl-aC are mainly in the range of 200–600 mg/L and 3–7 μg/L, respectively, in the OWF area, higher than the values obtained in surrounding waters. The SSC and Chl-aC downstream of the OWF are higher than those upstream, with differences of 100–300 mg/L and 0.5–2 μg/L. High SSC and Chl-aC “tails” appear downstream of wind turbines, consistent with the direction of local tidal currents, with lengths in the range of 2–4 km. In addition, the water environment in the vicinity of a wind turbine array, with a roughly 2–5 km scope (within 4 km during flooding and around 2.5 km during ebbing approximately) downstream of the wind turbine array, is impacted by the OWF. (3) In order to solve the problem of “self-digging” induced by OWFs, it is suggested that the distance between two wind turbines should be controlled within 2–3.5 km in the main flow direction, promising that the second row of wind turbines will be placed on the suspended sediment deposition belt induced by the first row. In this way, the problems of ecosystem imbalance and tidal current structure change caused by sediment loss because of local scouring can be reduced. Furthermore, mutual compensation between wind turbines can solve the “self-digging” problem to a certain extent and ensure the safety of OWFs. Full article

Guangzhou and Shenzhen are two core cities in the Guangdong-Hong Kong-Macao Greater Bay Area (GBA). It is increasingly important to regulate water quality in urban development. The Forel–Ule Index (FUI) can be obtained by optical data and is an important indicator. Therefore, we used Sentinel-2 to calculate the FUI of 41 lakes and reservoirs in Guangzhou and Shenzhen from January to December in 2016–2021, and analyzed their spatio-temporal variations, including spatial distributions, seasonal variations, and inter-annual variations. We also performed a correlation analysis of driving factors. In Guangzhou, the FUI was low in the north and west, and high in the south and east. In Shenzhen, the FUI was high in the west and low in the east. Moreover, 68% of the lakes and reservoirs in Guangzhou exhibited seasonal variations, with a low FUI in summer and autumn, and high levels in spring and winter. Shenzhen had the lowest FUI in autumn. Furthermore, 36% of the lakes and reservoirs in Guangzhou exhibited increasing inter-annual variations, whereas Shenzhen exhibited stable and decreasing inter-annual variations. Among the 41 lakes and reservoirs analyzed herein, the FUI of 10 water areas were positively correlated with precipitation, while the FUI of 31 water areas were negatively correlated with precipitation. Increased precipitation leads to an increase in external pollutants and sediment, as well as the resuspension of substances in the water, resulting in more turbid water. Therefore, an increase in precipitation is positively correlated with the FUI, whereas a decrease in precipitation is negatively correlated with the FUI. These findings can be used to design suitable management policies to maintain and control the local water quality. Full article

Emission control regulations have been essential in reducing vehicular exhaust emissions. However, the contribution of exhaust and non-exhaust emissions to ambient particulate matter (PM) has not yet been accurately quantified due to the lack of standardized sampling and measurement methods to set regulations. The identified sources and the source profiles generated have not been comparable as none of the emission data collection techniques and the receptor models applied in the literature have produced a standard or reference method to simultaneously identify and quantify the non-exhaust emission sources. This study utilized and thoroughly characterized PM samples including 32 major and trace elements from a mixed fleet in a mountain highway tunnel atmosphere in Bolu, Türkiye. This work proposed a two-stage, simple, and robust method based on road dust enrichment factor (EF) and elemental carbon (EC) tracer methods (EFECT) for the identification and prediction of the exhaust (exh), and non-exhaust (n-exh) emissions in PM. The indicated method revealed that road dust resuspension emissions are the most significant contributor to the concentrations of crustal elements. This method was used successfully to determine the real-world elemental contributions of road dust resuspension (rdrs), emissions (em), exhaust (exh), and non-exhaust (n-exh) emission sources to the elemental concentrations in PM samples. This study provided significant insights into generating actual source profiles, source-specific emission factors, and the source apportionment results for vehicular emission sources worldwide. Considering this, PM data of any particle size fraction (PM₁₀, PM_10-2.5, and PM_2.5, for example) can be used as input for the EFECT, provided that the data include the analytical results of elemental carbon in both the atmospheric PM and road dust samples having similar PM sizes. Full article

Biodegradable nanocarriers represent promising tools for controlled drug delivery. However, one major drawback related to their use is the long-term stability, which is largely influenced by the presence of water in the formulations, so to solve this problem, freeze-drying with cryoprotectants has been proposed. In the present study, the influence of the freeze-drying procedure on the storage stability of poly(lactide-co-glycolide) (PLGA) nanoparticles and liposomes was evaluated. In particular, conventional cryoprotectants were added to PLGA nanoparticle and liposome formulations in various conditions. Additionally, hyaluronic acid (HA), known for its ability to target the CD44 receptor, was assessed as a cryoprotective excipient: it was added to the nanocarriers as either a free molecule or conjugated to a phospholipid to increase the interaction with the polymer or lipid matrix while exposing HA on the nanocarrier surface. The formulations were resuspended and characterized for size, polydispersity index, zeta potential and morphology. It was demonstrated that only the highest percentages of cryoprotectants allowed the resuspension of stable nanocarriers. Moreover, unlike free HA, HA-phospholipid conjugates were able to maintain the particle mean size after the reconstitution of lyophilized nanoparticles and liposomes. This study paves the way for the use of HA-phospholipids to achieve, at the same time, nanocarrier cryoprotection and active targeting. Full article

Shallow water has low depth, and hydrodynamic conditions may change with the effect of wind and waves, resulting in sediment suspension and pollutant release. To investigate the influence of sediment incipient motion on ammonia nitrogen (NH₃-N) release in shallow lakes under hydrodynamic disturbance, we monitored ammonia nitrogen concentration in the overlying water of sediments in Chaohu Lake under static, weak, and strong disturbance conditions and analyzed the ammonia nitrogen release rate based on the these concentrations. In static condition, the sediment particles on the surface moved individually (individual movement), and the ammonia nitrogen release rate was 9.59 mg/m²/day. When the disturbance was weak and a small proportion of sediment particles started to move (small movement), the ammonia nitrogen release rate increased to 34.21 mg/m²/day. When the disturbance was further strengthened, and most of the sediment particles moved (general movement), the ammonia nitrogen release rate was 77.04 mg/m²/day. Distribution showed that the release rate varied the most in the western area followed by the eastern area, and the central area had the lowest release rate. The daily release of ammonia nitrogen in Chaohu Lake ranged from 8742.3 kg to 61,008.59 kg. In this experiment, we combined sediment movement and pollutant release, which provides a new reference for the study of pollutant release in shallow lakes and for ammonia nitrogen management in other shallow lakes. Full article

Suspended sediment dynamics play an important role in controlling nearshore and estuarine geomorphology and the associated ecological environments. Modeling the transport of suspended sediment is a complicated and challenging research topic. The goal of this study is to improve the accuracy of modeling the suspended sediment concentrations (SSCs) with newly developed techniques. Based on a three-dimensional suspended cohesive sediment transport model, the transport of suspended sediment and SSCs are simulated by assimilating SSCs retrieved from the Geostationary Ocean Color Imager (GOCI) with the adjoint data assimilation in the Hangzhou Bay, a typical strong tidal estuary along the coast of the East China Sea. To improve the effect of the data assimilation, the penalty function method, in which the reasonable constraints of the estimated model parameters are added to the cost function as penalty terms, will be introduced for the first time into the adjoint data assimilation in the SSCs modeling. In twin experiments, the prescribed spatially varying settling velocity is estimated by assimilating the synthetic SSC observations, and the results show that the penalty function method can further improve the effect of data assimilation and parameter estimation, regardless of synthetic SSC observations being contaminated by random artificial errors. In practical experiments, the spatially varying settling velocity is firstly estimated by assimilating the actual GOCI-retrieved SSCs. The results demonstrate that the simulated results can be improved by the adjoint data assimilation, and the penalty function method can additionally reduce the mean absolute error (MAE) between the independent check observations and the corresponding simulated SSCs from 1.44 × 10⁻¹ kg/m³ to 1.30 × 10⁻¹ kg/m³. To pursue greater simulation accuracy, the spatially varying settling velocity, resuspension rate, critical shear stress and initial conditions are simultaneously estimated by assimilating the actual GOCI-retrieved SSCs to simulate the SSCs in the Hangzhou Bay. When the adjoint data assimilation and the penalty function method are simultaneously used, the MAE between the independent check observations and the corresponding simulated SSCs is just 9.90 × 10⁻² kg/m³, which is substantially less than that when only the settling velocity is estimated. The MAE is also considerably less than that when the four model parameters are estimated to be without using the penalty function method. This study indicates that the adjoint data assimilation can effectively improve the SSC simulation accuracy, and the penalty function method can limit the variation range of the estimated model parameters to further improve the effect of data assimilation and parameter estimation. Full article

Due to their long half-life, polychlorinated biphenyls (PCBs) tend to contaminate not only coastal areas, but they travel over long distances, eventually reaching remote areas such the Arctic. The physical and biogeochemical features of every coastal area govern the main distribution patterns of freshly introduced PCBs into the marine system. Some of these processes are determined by chemical properties of the individual PCB congener. Thus, atmospheric influx along with ad/absorption on non-living organic material, photolytical and biological degradation processes vary from one PCB congener to another. For a detailed fate analysis of individual congeners, we developed a new chemical model, based on the GOTM-ECOSMO-FABM model framework. Here, we exemplarily present results for PCB₁₅₃ based on 1D simulations of four regions in the North-Baltic Sea. The study area is characterized by different hydrodynamic and biogeochemical conditions. We investigate the impact of resuspension, mixing and the biological pump, sea ice and tides on the final phasal distribution of PCB₁₅₃. Different combinations of these factors lead to the development of different areas of PCB₁₅₃ accumulation, with the formation of hotspot areas, and influence the total uptake and concentration of PCB₁₅₃ in the water column. As a result, two major dynamics determine the fate of PCB₁₅₃ in the coastal ocean: (i) Primary production leads to PCB₁₅₃ being adsorbed by organic material. Partitioning to organic material and sedimentation of organic particles removes dissolved PCB₁₅₃ from the surface ocean and increases atmospheric influx. (ii) Tidal-induced resuspension and mixing control the benthic–pelagic exchange of PCB₁₅₃ and its distribution in the water column. Depending on the resuspension regime and stratification, sediments can become a permanent (Gotland Deep, the Baltic Sea) or seasonal sink for PCB₁₅₃. In regions with seasonal stratification and high near bottom turbulence (Northern North Sea), resuspension events can lead to pronounced peaks in PCB₁₅₃ concentrations and can therefore have a major impact on bioaccumulation. Under the conditions of permanent mixing and high bottom turbulence (Southern North Sea, Bothnian Bay), pollutants are hardly accumulating in sediments. Full article

In this study, the effect of media composition, N/P ratio and cultivation strategy on the formation of carotenoids in a Coelastrella sp. isolate was investigated. A two-stage process utilizing different media in the vegetative stage, with subsequent re-suspension in medium without nitrate, was employed to enhance the formation of carotenoids. The optimal growth and carotenoid content (β-carotene and lutein) in the vegetative phase were obtained by cultivation in M-8 and BG11 media. Use of a N/P ratio of 37.5 and low light intensity of 40 μmol m⁻² s⁻¹ (control conditions) led to optimal biomass production of up to 1.31 g L⁻¹. Low concentrations of astaxanthin (maximum of 0.31 wt. %) were accumulated under stress conditions (nitrogen-deficient medium containing 1.5 % of NaCl and light intensity of 500 μmol m⁻² s⁻¹), while β-carotene and lutein (combined maximum of 2.12 wt. %) were produced under non-stress conditions. Lipid analysis revealed that palmitic (C16:0) and oleic (C18:1) constituted the main algal fatty acid chains (50.2 ± 2.1% of the total fatty acids), while esterifiable lipids constituted 17.2 ± 0.5% of the biomass by weight. These results suggest that Coelastrella sp. could also be a promising feedstock for biodiesel production. Full article

In freshwater ecosystems, dynamic hydraulic events (floods or dam maintenance) lead to sediment resuspension and mixing with waters of different composition. Microbial communities living in the sediments play a major role in these leaching events, contributing to organic matter degradation and the release of trace elements. However, the dynamics of community diversity are seldom studied in the context of ecological studies. Therefore, we carried out laboratory-induced leaching experiments, using sediments from the Villerest dam reservoir (Villerest, France). To assess whole microbial community diversity, we sequenced the archaeal and bacterial 16S rRNA genes using Illumina MiSeq. Our results suggest that the degree of dissolved oxygen found in the water during these resuspension episodes influenced community dynamics, with anoxic waters leading to drastic shifts in sedimentary communities compared to oxic waters. Furthermore, the release of microbial cells from sediments to the water column were more favorable to water colonization when events were caused by oxic waters. Most of the bacteria found in the sediments were chemoorganotrophs and most of the archaea were methanogens. Methylotrophic, as well as archaeal, and bacterial chemoorganotrophs were detected in the leachate samples. These results also show that organic matter degradation occurred, likely participating in carbonate dissolution and the release of trace elements during freshwater resuspension events. Full article

The cycle of biogenic elements in lakes is intimately linked with particulate organic matter (POM), which plays a critical role in ecosystem restoration and the control of eutrophication. However, little is known regarding the functionality of ecosystem degradation on the source of POM in the water of a karst lake. To fill this knowledge gap, herein we compared the temporal and spatial distribution characteristics of POM prior to and after ecosystem degradation in the karst lake Caohai Lake, located in the southwest of China, and analyzed the source of POM using a combination of carbon and nitrogen stable isotopes (δ¹³C–δ¹⁵N). Our results showed that the dissolved oxygen (DO) concentration and pH values decreased, and the concentrations of POM in water increased by 11% and 31% in the wet and dry seasons, respectively. The decrease in the δ¹³C value of POM was accompanied by the increase in the δ¹⁵N value of POM in the water of Caohai lake. Prior to the ecosystem’s degradation, sediment resuspension (28%) and submerged macrophytes (33%) were the dominant sources of POM in lake water. In contrast, sediment resuspension (51%) was the major source of POM after the ecosystem’s degradation. Environmental factors, including DO, turbidity, water depth, and water temperature, that are related to photosynthesis and sediment resuspension are the main factors controlling the spatiotemporal distribution of POM. The resuspension of sediment reduced the transparency of the water, limiting effective photosynthesis, impeding the survival of submerged macrophytes, and, consequently, deteriorating the ecosystem. We propose that the control of sediment resuspension is important for improving the water transparency that creates an appropriate habitat for the restoration of the submerged macrophyte community. Full article

Changes in coastal environments are usually caused by anthropogenic activities such as habitat degradation and nonpoint source pollution. Such changes reduce the life quality of the living organisms in altered environments, decreasing biotic descriptors and jeopardizing biodiversity. The aim of this study was to compare eventual changes in minor and trace elements in otoliths of the catfish Genidens genidens in two periods (1980s and 2017–2018) in an altered tropical bay (Sepetiba Bay, RJ, Brazil). The concentrations of 34 elements were determined by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) in fish otoliths. Although some elements have shown higher concentrations in more contemporary periods (2017–2018) such as ⁷Li, ¹¹Br, ⁸⁵Rb, and ²⁰⁵Tl, and some did not differ between the two periods (²⁰⁸Pb, ³⁴S, ⁴⁴Ca, ⁵⁵Mn, ⁸²Se, and ¹³⁷Ba), but most of the examined elements (such as ²⁴Mg, ⁵⁹Co, ⁶⁰Ni, ⁶⁵Cu, ¹⁰⁵Pd, ¹⁰⁷Ag, ⁶⁶Zn, ⁷⁵As, ⁶⁹Ga, ⁹⁸Mo, ⁵³Cr, ²⁷Al, ¹¹⁴Cd, and ¹¹B) had higher concentrations in the 1980s compared to 2017-2018 (test w, p < 0.05). Although this result was the opposite of what was expected, this could be associated with the intensity of activities without any environmental control in the past and with the first dredging to deepen the access channel to the port created in 1982, allowing the operation of large ships, which promoted the resuspension of trace elements trapped in the sediment and the pollution carried into the bay. The stability of the incorporation of elements in otoliths, compared to other tissues, allows such records, which are consistent over time, to be used in order to better understand past and present variations in the quality of the environment. Such information can be useful in conservation programs as it provides a historical view of variations in the quality of the environment. Full article