Search Results (21)

In this study, we present a basic idea for a robust optical measurement method for the practical monitoring of slurry sprays with high mass concentrations, as typically used in combustion processes. The proposed approach is based on analyzing the transparency properties of individual dynamic droplets within the slurry spray. These so-called dynamic slurry droplets consist of a base fluid and suspended solid particles. Our method enables the determination of the mass concentration of solid particles and provides an estimate of their average size. The resolution of this technique allows for the detection of errors in the slurry-mixing process and even in the milling process of the solid particles prior to mixing. To atomize slurries with high mass concentration, an experimental setup with a gas-assisted coaxial nozzle was employed. Slurries with three different mass concentrations and three particle size distributions were tested, resulting in five combinations. The theoretical expectations and experimental results show a strong correlation, highlighting the potential of the proposed method for slurry-spray monitoring. Full article

This study investigates the impact of circumferential angle (φ) and interaction angle (θ) between hydrogen jets and diesel sprays in a co-axial hydrogen–diesel injector on combustion and emissions in a hydrogen–diesel dual-fuel engine using 3D CFD simulations. The results demonstrate that a co-axial dual-layer nozzle design significantly enhances combustion performance by leveraging hydrogen jet kinetic energy to accelerate fuel–air mixing. Specifically, a co-axial alignment (φ = 0°) between hydrogen and diesel sprays achieves optimal combustion characteristics, including the highest in-cylinder pressure (20.92 MPa), the earliest ignition timing (−0.3° CA ATDC), and the maximum indicated power of the high-pressure cycle (47.26 kW). However, this configuration also results in elevated emissions, with 29.6% higher NOx and 34.5% higher soot levels compared to a φ = 15° arrangement. To balance efficiency and emissions, an interaction angle of θ = 7.5° proves most effective, further improving combustion efficiency and increasing indicated power to 47.69 kW while reducing residual fuel mass. For applications prioritizing power output, the φ = 0° and θ = 7.5° configuration is recommended, whereas a φ = 15° alignment with a moderate θ (5–7.5°) offers a viable compromise, maintaining over 90% of peak power while substantially lowering NOx and soot emissions. Full article

In this study, SmFeN/YSZ thermal barrier coating (TBC) composites with SmFeN mass fractions of 25 wt.%, 30 wt.%, and 50 wt.% were synthesized using plasma spraying technology. Testing methods, including scanning electron microscopy (SEM), X-ray diffraction (XRD), and the coaxial method, were comprehensively employed to systematically and thoroughly investigate the influence of SmFeN content on the microstructure, electromagnetic wave absorption performance, and the underlying mechanism of the composites. The research results show that during the plasma spraying process, a significant phase transformation occurred in the SmFeN/YSZ mixed powder, where the original Sm₂Fe₁₂N_2.9 phase transformed into Fe₄N and Sm₃Fe₅O₁₂ phases. However, this phase transformation did not have an adverse effect on the electromagnetic wave absorption performance of the coating. On the contrary, further research revealed that the newly formed Fe₄N phase plays a decisive role in the electromagnetic wave absorption performance of the coating. When the SmFeN mass fraction was 30%, the proportion of Fe₄N in the coating reached its peak. At this time, the impedance matching characteristics of the coating were significantly optimized, and the dipole orientation polarization rate was significantly increased. This enhanced the dielectric relaxation loss capacity of the coating and broadened the electromagnetic wave absorption frequency band. Specifically, the coating exhibited a minimum reflection loss (RL_min) of −52.371 dB and an effective absorption bandwidth (EAB) as high as 2.1588 GHz, covering a frequency range from 11.0739 GHz to 13.2327 GHz. This result indicates that there is great application potential in preparing electromagnetic wave absorption coatings using SmFeN/YSZ mixed powder. Full article

This study developed functional white chocolate enriched with free (WC-F) and encapsulated β-carotene using whey protein isolate (WPI) and pullulan (PUL) blends through spray drying (WC-SP), freeze drying (WC-LP), and coaxial electrospinning (WC-EL). The thermal properties, rheological properties, hardness, and color of the chocolates were evaluated, and the stability of β-carotene was monitored over 4 months at 25 °C. No significant differences were found in melting profile temperatures among samples; however, WC-LP and WC-EL exhibited higher melting energies (30.88 J/g and 16.00 J/g) compared to the control (12.42 J/g). WC-F and WC-SP showed rheological behaviors similar to those of the control, while WC-LP and WC-EL displayed altered flow characteristics. Hardness was unaffected in WC-F and WC-SP (7.77 N/mm² and 9.36 N/mm²), increased slightly in WC-LP (10.28 N/mm²), and decreased significantly in WC-EL (5.89 N/mm²). Over storage, melting point, rheological parameters, and hardness increased slightly, while color parameters decreased. β-carotene degradation followed a first-order reaction model, with degradation rate constants (k) of 0.0066 day⁻¹ for WC-SP, 0.0094 day⁻¹ for WC-LP, and 0.0080 day⁻¹ for WC-EL, compared to 0.0164 day⁻¹ for WC-F. WC-SP provided the best β-carotene retention, extending the half-life period by 2 times compared to WC-F (126.04 days vs. 61.95 days). Practical implications: The findings suggest that WC-SP, with its superior β-carotene stability, is particularly suitable for the development of functional confectionery products with extended shelf life, offering potential benefits in industrial applications where product stability is crucial. Future research directions: Further studies could explore the incorporation of additional bioactive compounds in white chocolate using similar encapsulation methods, as well as consumer acceptance and sensory evaluation of these enriched products. Full article

The spray and combustion characteristics of a gas-centered swirl coaxial (GCSC) injector used in oxidizer-rich staged combustion cycle engines were analyzed. The study focused on varying the recess ratio, presence of gas swirl, and swirl direction to improve injector performance. The impact of the recess ratio was assessed by increasing it for gas jet-type injectors with varying momentum ratios. Gas-swirl effects were studied by comparing injectors with and without swirl against a baseline of a low recess ratio gas injection. In atmospheric pressure-spray experiments, injector performance was assessed using backlight photography, cross-sectional imaging with a structured laser illumination planar imaging technique (SLIPI), and droplet analysis using ParticleMaster. Increasing the recess ratio led to reduced spray angle and droplet size, and trends of gas swirl-type injectors were similar to those of high recess ratio gas jet-type injectors. Combustion tests involved fabricating combustion chamber heads equipped with identical injectors, varying only the injector type. Oxidizer-rich combustion gas, produced by a pre-burner, and kerosene served as propellants. Combustion characteristics, including characteristic velocity, combustion efficiency, and heat flux, were evaluated. Elevated recess ratios correlated with increased characteristic velocity and reduced differences in the momentum–flux ratios of injectors. However, increasing the recess ratio yielded diminishing returns on combustion efficiency enhancement beyond a certain threshold. Gas swirling did not augment characteristic velocity but notably influenced heat flux distribution. The trends observed in spray tests were related to combustion characteristics regarding heat flux and combustion efficiency. Additionally, it was possible to estimate changes in the location and shape of the flame according to the characteristics of the injector. Full article

Local chemotherapy is an alternative therapeutic strategy that involves direct delivery of drugs to the tumor site. This approach avoids adverse reactions caused by the systemic distribution of drugs and enhances the tumor-suppressing effect by concentrating the drugs at the tumor site. Drug-loaded microspheres are injectable sustained-release drug carriers that are highly suitable for local chemotherapy. However, a complex preparation process is one of the main technical difficulties limiting the development of microsphere formulations. In this study, core-shell structured microspheres loaded with paclitaxel (PTX; with a core-shell structure, calcium alginate outer layer, and a poly (lactic acid-co-glycolic acid) copolymer inner layer, denoted as PTX-CA/PLGA-MS) were prepared using coaxial electrostatic spray technology and evaluated in vitro and in vivo. PTX-CA/PLGA-MS exhibited a two-stage drug release profile and enhanced anti-tumor effect in animal tumor models. Importantly, the preparation method reported in this study is simple and reduces the amount of organic solvent(s) used substantially. Full article

Bioactive peptides derived from enzymatic hydrolysis are gaining attention for the production of supplements, pharmaceutical compounds, and functional foods. However, their inclusion in oral delivery systems is constrained by their high susceptibility to degradation during human gastrointestinal digestion. Encapsulating techniques can be used to stabilize functional ingredients, helping to maintain their activity after processing, storage, and digestion, thus improving their bioaccessibility. Monoaxial spray-drying and electrospraying are common and economical techniques used for the encapsulation of nutrients and bioactive compounds in both the pharmaceutical and food industries. Although less studied, the coaxial configuration of both techniques could potentially improve the stabilization of protein-based bioactives via the formation of shell–core structures. This article reviews the application of these techniques, both monoaxial and coaxial configurations, for the encapsulation of bioactive peptides and protein hydrolysates, focusing on the factors affecting the properties of the encapsulates, such as the formulation of the feed solution, selection of carrier and solvent, as well as the processing conditions used. Furthermore, this review covers the release, retention of bioactivity, and stability of peptide-loaded encapsulates after processing and digestion. Full article

The viscosity of adiponitrile waste liquid is as high as 1000 cp. It is challenging to spray and atomize the waste liquid normally. Based on the coaxial three-channel pneumatic atomizer, a two-stage supersonic steam atomizer is proposed in this paper, and the atomization process is simulated by Fluent software. Compared with the traditional atomization simulation method, the Volume-of-Fluid to Discrete-Phase-Model (VOF-DPM) bi-directional coupling model and Adaptive Mesh Refinement (AMR) technology can save mesh and improve the computational efficiency. The atomization processes of primary breakup and secondary breakup are entirely captured and analyzed. The results show that the Sauter Mean Diameter (SMD) is about 116–180 μm, the SMD decreases with the increase of steam inlet absolute pressure, and the atomization quality can meet the combustion requirements. This study can be used for the performance optimization of the high-viscosity liquid atomizers in the chemical and aerospace industry and shorten the time engineers spend in the simulation calculation to verify the rationality of the structure. Full article

The momentum flux ratio (MFR) significantly affects the mixing characteristics and combustion efficiency of propellants in rocket engine injectors. The spray characteristics of three gas-centered swirl-coaxial injectors used in a full-scale combustion test were investigated according to the change in the momentum flux ratio. The difference in combustion efficiency was analyzed through the comparison with combustion test results using spray visualization and quantification. The spray cross-sectional shape and droplet distribution were measured using a structured laser illumination planar imaging technique. As the swirl effect was more apparent at a low MFR, the flow rate of the liquid that was sprayed outside was high. The flow rate of the liquid sprayed around the gas injection increased with the MFR. The Sauter mean diameter (SMD) of each injector liquid spray was obtained using the laser shadow imaging method. The SMD decreased as the MFR of all injector types increased, and the injector with a high liquid flow rate and small SMD injected towards the gas center exhibited higher combustion efficiency than the injector with a dominant liquid spray and the large SMD at a large injection angle. The outcomes of the study could help contribute to the increase in the combustion efficiency of the full-scale staged combustion cycle engine combustor. Full article

To determine the dynamic characteristics of a gas-centered swirl coaxial injector under backpressure, an experimental system of dynamic injection in a backpressure chamber was constructed. Filtered water and nitrogen were used as simulant media for rocket propellants, which are typically used with this kind of injector. An inertial flow pulsator was manufactured to generate the pulsation of the flows that feed to the liquid injector. The electric conductance method was adopted to measure liquid film thickness. After the pulsation of incoming flow in the feedline was tested, and the operating conditions for the injector to start pulsating were validated, the effects of the chamber backpressure and the recess length of the injector on the dynamic characteristics of spray, such as liquid film thickness, breakup length, and amplitude of pulsation, have been investigated in detail. Experimental results demonstrated that the increase in chamber backpressure prompts the liquid sheet to rupture earlier with a shorter breakup length, which results from the increased density of the ambient gas. Chamber backpressure suppresses the pulsation of the outlet flow, especially for a longer recess length. Moreover, a decrease in the recess length results in a reduction in breakup length due to an intense gas–liquid shearing in a narrower recess section. For a lower backpressure, the amplitude of outlet flow generally increases when the recess length increases. However, this phenomenon is not obvious for the conditions of higher backpressure and lower pulsation frequency. Full article

The impact of the encapsulation technology on the oxidative stability of fish-oil-loaded capsules was investigated. The capsules (ca. 13 wt% oil load) were produced via monoaxial or coaxial electrospraying and spray-drying using low molecular weight carbohydrates as encapsulating agents (e.g., glucose syrup or maltodextrin). The use of spray-drying technology resulted in larger capsules with higher encapsulation efficiency (EE > 84%), whilst the use of electrospraying produced encapsulates in the sub-micron scale with poorer retention properties (EE < 72%). The coaxially electrosprayed capsules had the lowest EE values (EE = 53–59%), resulting in the lowest oxidative stability, although the lipid oxidation was significantly reduced by increasing the content of pullulan in the shell solution. The emulsion-based encapsulates (spray-dried and monoaxially electrosprayed capsules) presented high oxidative stability during storage, as confirmed by the low concentration of selected volatiles (e.g., (E,E)-2,4-heptadienal). Nonetheless, the monoaxially electrosprayed capsules were the most oxidized after production due to the emulsification process and the longer processing time. Full article

The current review investigates the effects of black seed (Nigella sativa) on human health, which is also used to encapsulate and oxidative stable in different food products. In recent decades, many extraction methods, such as cold pressing, supercritical fluid extraction, Soxhlet extraction, hydro distillation (HD) method, microwave-assisted extraction (MAE), ultrasound-assisted extraction, steam distillation, and accelerated solvent extraction (ASE) have been used to extract the oils from black seeds under optimal conditions. Black seed oil contains essential fatty acids, in which the major fatty acids are linoleic, oleic, and palmitic acids. The oxidative stability of black seed oil is very low, due to various environmental conditions or factors (temperature and light) affecting the stability. The oxidative stability of black seed oil has been increased by using encapsulation methods, including nanoprecipitation, ultra-sonication, spray-drying, nanoprecipitation, electrohydrodynamic, atomization, freeze-drying, a electrospray technique, and coaxial electrospraying. Black seed, oil, microcapsules, and their components have been used in various food processing, pharmaceutical, nutraceutical, and cosmetics industries as functional ingredients for multiple purposes. Black seed and oil contain thymoquinone as a major component, which has anti-oxidant, -diabetic, -inflammatory, -cancer, -viral, and -microbial properties, due to its phenolic compounds. Many clinical and experimental studies have indicated that the black seed and their by-products can be used to reduce the risk of cardiovascular diseases, chronic cancer, diabetes, oxidative stress, polycystic ovary syndrome, metabolic disorders, hypertension, asthma, and skin disorders. In this review, we are focusing on black seed oil composition and increasing the stability using different encapsulation methods. It is used in various food products to increase the human nutrition and health properties. Full article

The variable-area pintle injector has unique geometry and spray characteristics compared to traditional coaxial injectors, and is advantageous for weight lightening and deep throttling of liquid rocket engines. To obtain an accurate prediction of the spray windward distribution of a gas–liquid pintle injector with discrete radial orifices, a pintle injector element using air and water as simulants was designed for spray experiments in the atmospheric environment. The air-film injection pressure drop and water-jet injection orifice diameter were both adjusted for a wide variance range from 0.19 to 2.85 for the local momentum ratio. Backlight imaging was adopted for shooting the frozen spray pattern from one side, and a new dimensionless parameter, i.e., the spray fraction, was defined to quantitatively analyze the time-averaged windward boundary band. The dimensionless spray windward boundary band model for a circular-orifice jet and the corresponding derivative formula of the spray half angle were summarized through parameter study. The predicted results of empirical models were in good agreement with the experimental results. It was found that when the local momentum ratio was about 1, the spray distribution range basically overlapped with the coverage scope of gas film with uniform liquid mist. Full article

Microbubbles have been widely used in many research fields due to their outstanding physicochemical properties and unique structural characteristics, especially as ultrasonic contrast agents and drug delivery carriers. However, the stability of conventional microbubbles is generally poor, which limits the development of their applications. Loading nanoparticle to microbubbles has great potential in enhancing the stability of microbubbles. This paper reports for the first time the feasibility of one-step preparation of nanoparticle-loaded microbubbles by coaxial electrohydrodynamic atomization. Bovine serum albumin (BSA) was used as the model material of the bubble shell layer to study the effect of the loading of nanoparticles on the stability of microbubbles. The results show that the concentration of nanoparticles has a significant impact on the stability of microbubbles, and loading an appropriate amount of nanoparticles is helpful in improving the stability of microbubbles. The results also show that nanoparticle-loaded microbubbles with a size distribution in the range of 120–200 μm can be prepared under optimal conditions. Full article

Although a lot of research and development has been done to understand and master the major physics involved in cryogenic rocket engines (combustion, feeding systems, heat transfer, stability, efficiency, etc.), the injection system and wall heat transfer remain critical issues due to complex physics, leading to atomization in the subcritical regime and the interactions of hot gases with walls. In such regimes, the fuel is usually injected through a coaxial annulus and triggers the atomization of the central liquid oxidizer jet. This type of injector is often referred to as air-assisted, or coaxial shear, injector, and has been extensively studied experimentally. Including such injection in numerical simulations requires specific models as simulating the atomization process is still out of reach in practical industrial systems. The effect of the injection model on the flame stabilization process and thus on wall heat fluxes is of critical importance when it comes to the design of wall-cooling systems. Indeed, maximizing the heat flux extracted from the chamber can lead to serious gain for the cooling and feeding systems for expander-type feeding cycles where the thermal energy absorbed by the coolant is converted into kinetic energy to drive the turbo-pumps of the feeding system. The methodology proposed in this work to numerically predict the flame topology and associated heat fluxes is based on state-of-the-art methods for turbulent reactive flow field predictions for rocket engines, including liquid injection, combustion model, and wall treatment. For this purpose, high-fidelity Large Eddy Simulation Conjugate Heat Transfer, along with a reduced kinetic mechanism for the prediction of $H_2/O_2$ chemistry, liquid injection model LOx sprays, and the use of a specific wall modeling to correctly predict heat flux for large temperature ratio between the bulk flow and the chamber walls, is used. A smooth and a longitudinally ribbed combustor configuration from JAXA are simulated. The coupling strategy ensures a rapid convergence for a limited additional cost compared to a fluid-only simulation, and the wall heat fluxes display a healthy trend compared to the experimental measurements. An increase of heat transfer coherent with the literature is observed when walls are equipped with ribs, compared to smooth walls. The heat transfer enhancement of the ribbed configuration with respect to the smooth walls is coherent with results from the literature, with an increase of around $+80\%$ of wall heat flux extracted for the same chamber diameter. Full article