Search Results (232)

The present study aimed to estimate the contribution of the mining and mineral processing steps of lithium concentrate production in Brazil to the Global Warming Potential (GWP100) using an LCA perspective. No previous national study was identified that quantified national GHG emissions in mining and beneficiation operations for lithium ores. This study is considered original and aims to contribute to filling this gap. The functional unit was 1 ton of lithium carbonate equivalent (LCE) in the mineral concentrate. The contribution to GWP100 was estimated at 1220 kg of CO_2eq per ton of LCE, of which 262 kg originated from foreground processes. In the background processes, the largest contribution was 456 kg of CO_2eq from emissions in the production of ammonium nitrate, used in the manufacture of mining explosives. An analysis of substituting electricity sources in the product system showed a reduction of 22.7% and 14.7% in the estimated global warming impact when using wind or solar power, respectively. Full article

In this study, we systematically investigated the characteristic parameter evolution laws of thermal runaway with respect to 18,650 lithium-ion batteries (LIBs) under thermal abuse conditions at five state-of-charge (SOC) levels: 0%, 25%, 50%, 75%, and 100%. In our experiments, we combined infrared thermography, mass loss analysis, temperature monitoring, and gas composition detection to reveal the mechanisms by which SOC affects the trigger time, critical temperature, maximum temperature, mass loss, and gas release characteristics of thermal runaway. The results showed that as the SOC increases, the critical and maximum temperatures of thermal runaway increase notably. At a 100% SOC, the highest temperature on the positive electrode side reached 1082.1 °C, and the mass loss increased from 6.90 g at 0% SOC to 25.75 g at 100% SOC, demonstrating a salient positive correlation. Gas analysis indicated that under high-SOC conditions (75% and 100%), the proportion of flammable gases such as CO and CH₄ produced during thermal runaway significantly increases, with the CO/CO₂ ratio exceeding 1, indicating intensified incomplete combustion and a significant increase in fire risk. In addition, flammability limit analysis revealed that the lower explosive limit for gases is lower (17–21%) at a low SOC (0%) and a high SOC (100%), indicating greater explosion risks. We also found that the composition of gases released during thermal runaway varies substantially at different SOC levels, with CO, CO₂, and CH₄ accounting for over 90% of the total gas volume, while toxic gases, such as HF, although present in smaller proportions, pose noteworthy hazards. Unlike prior studies that relied on post hoc analysis, this work integrates real-time multi-parameter monitoring (temperature, gas composition, and mass loss) and quantitative explosion risk modeling (flammability limits via the L-C formula). This approach reveals the unique dynamic SOC-dependent mechanisms of thermal runaway initiation and gas hazards. This study provides theoretical support for the source tracing of thermal runaway fires and the development of preventive LIB safety technology and emphasizes the critical influence of the charge state on the thermal safety of batteries. Full article

The effective use of biowaste resources becomes crucial for the development of bioprocessing alternatives to current oil- and chemical-based value chains. Targeting the development of multi-product biorefinery approaches benefits the viability and profitability of these process schemes. Certain oleaginous microorganisms, such as oleaginous red yeast, can co-produce industrially relevant bio-based products. This work aims to explore the use of industrial and urban waste as cost-effective feedstock for producing microbial oil and carotenoids using Rhodosporidium toruloides. The soluble fraction, resulting from homogenization, crushing, and centrifugation of discarded vegetable waste, was used as substrate under a pulse-feeding strategy with a concentrated enzymatic hydrolysate from municipal forestry residue obtained after steam explosion pretreatment (190 °C, 10 min, and 40 mg H₂SO₄/g residue). Additionally, the initial nutrient content was investigated to enhance process productivity values. The promising results of these cultivation strategies yield a final cell concentration of 36.4–55.5 g/L dry cell weight (DCW), with an intracellular lipid content of up to 42–45% (w/w) and 665–736 µg/g DCW of carotenoids. These results demonstrate the potential for optimizing the use of waste resources to provide effective alternative uses to current biowaste management practices, also contributing to the market of industrially relevant products with lower environmental impacts. Full article

This study conducted systematic experimental research on methane safety issues in industrial production environments, with a particular focus on the impacts of high-temperature conditions and complex atmospheres on methane explosion characteristics. The research team designed and constructed a dedicated combustible gas explosion experimental setup, performing in-depth experimental analyses across a broad temperature range from 25 °C to 600 °C. The results demonstrate that elevated temperatures significantly reduced the methane’s lower explosion limit (LEL), with the LEL decreasing to approximately 40% of its room-temperature value at 600 °C. The investigation systematically examined the influence mechanisms of common industrial atmospheric components, including carbon dioxide (CO₂), ammonia (NH₃), oxygen (O₂), and water vapor (H₂O) on methane explosion behavior. Key findings reveal that CO₂ exhibited notable suppression effects, increasing methane’s LEL by approximately 15% per 10% increment in CO₂ concentration. NH₃ demonstrated dual mechanisms, promoting methane explosions at low concentrations (<5%) while inhibiting them at higher concentrations. Increased O₂ concentration significantly expanded the methane’s explosive range, with the LEL decreasing by about 22% when O₂ concentration increased from 21% to 30%. Water vapor manifested differentiated impacts depending on temperature regimes, primarily elevating LEL through dilution effects below 200 °C while reducing LEL via radical reaction promotion above 400 °C. Furthermore, this study reveals synergistic coupling effects between temperature and gas components—for instance, CO₂’s suppression efficacy weakened under high temperatures, whereas NH₃’s promotion effect intensified. These discoveries provide scientific foundations for formulating industrial safety standards, designing explosion-proof equipment, and conducting risk assessments in production processes. Full article

The thermal runaway of lithium-ion batteries is a critical factor influencing their safety. Investigating the thermal runaway characteristics is essential for battery safety design. In this study, the thermal runaway characteristics of 18650 lithium-ion batteries under different SOCs were systematically analyzed by experiment and simulation. It was found that at high SOC (100%), the highly lithium state accelerated lattice oxygen release, promoted the formation of LiNiO and intensified electrolytic liquid oxygenation combustion, while at low SOC (20%), the reduction environment dominated, and the metal Ni and residual graphite were significantly enriched. Gas analysis shows that CO₂ and H₂ account for more than 80%, and their proportion is regulated by SOC. Temperature and pressure monitoring showed that the increase in SOC significantly increased the thermal runaway peak temperature (100% SOC up to 508.4 °C) and pressure (0.531 MPa).The simulation results show that when the battery pack is out of control, the ejection fire and explosion pressure wave are concentrated in the middle and upper region (overpressure up to 0.8 MPa). This study reveals the mechanism by which SOC affects the path of product and gas generation by regulating the oxidation/reduction balance, which lays a theoretical and simulation foundation for the safe design of batteries and the quantitative evaluation of thermal runaway. Full article

Polymer co-extrusion experiments are described simulating the dynamics of two different magmas (e.g., silicic and mafic having different viscosities) flowing simultaneously in a vertical volcanic pipe or conduit which results in the effusion of composite lava domes on the surface. These experiments, involving geologically realistic conduit length-to-diameter aspect ratios of 130:1 or 380:1, demonstrate that co-extrusion of magmas having different viscosities can explain not only the observed normal zoning observed in planar dikes and the pipelike conduits that evolve from dikes but also the compositional layering of effused lava domes. The new results support earlier predictions, based on observations of induced core-annular flow (CAF), that dike and conduit zoning along with dome layering are found to depend on the viscosity contrast of the non-Newtonian (shear-thinning) magmas. Any magma properties creating viscosity differences, such as crystal content, bubble content, water content and temperature may also give rise to the CAF regime. Additionally, codependent flow behavior involving the silicic and mafic magmas may play a significant role in modifying the nature of volcanic eruptions. For example, lubrication of the flow by an annulus of a more mafic, lower-viscosity component allows a more viscous but more volatile-charged magma to be injected rapidly to greater vertical distances along a dike into a lower pressure regime that initiates exsolving of a gas phase, further assisting ascent to the surface. The rapid ascent of magmas exsolving volatiles in a dike or conduit is associated with explosive silicic eruptions. Full article

This study investigates the suppression effect of ultrafine CaCO₃ powder on gas explosions through a series of experiments conducted in a medium-scale explosion tube (9.6 m in length) with varying concentrations of ultrafine CaCO₃. The gas explosion suppression concentration was established at 9.5%. The results indicate that, at concentrations of 125 g/m³ and 300 g/m³, ultrafine CaCO₃ powder significantly reduced the flame propagation speed of the gas explosion. Among the concentrations that did not fully suppress the gas explosion, 20 g/m³ effectively mitigated the flame propagation speed and overpressure throughout the entire process. The concentration of 75 g/m³ demonstrated a suppression–promotion–suppression–promotion pattern regarding the flame propagation rate, with significant fluctuations observed throughout the process. While the maximum suppression rate reached 60.9%, the maximum promotion rate was 131.12%. At 10 g/m³, the flame propagation rate initially increased before decreasing, with the most effective suppression observed within the first 6.6 m, where flame propagation suppression increased rapidly from 58.13% to 74.82%, and the peak explosion overpressure was reduced by up to 62.94%. These findings contribute valuable insights for the development of effective gas explosion suppression strategies in mining environments. Full article

The poor thermal stability of polypropylene (PP) separators poses risks of electrolyte leakage and battery short-circuiting, limiting their application in lithium metal batteries (LMBs). To address these challenges, a gel polymer membrane was designed using polymer blending technology. This membrane effectively retains the electrolyte, provides a stable environment, enhances thermal stability, and significantly decreases the risk of battery explosions and side reactions between the lithium metal and the electrolyte. Compared to commercial PP separators, the developed blend-type gel polymer electrolyte (b-GPE) demonstrates a superior performance, including structural stability at temperatures up to 150 °C and a high lithium-ion transference number ($t_{{Li}^{+}}$) of 0.513. Furthermore, a cell with a LiCoO₂ cathode operated at a 1 C rate retains 97.4% of its capacity after 300 cycles. After exposure to 120 °C, the b-GPE-120 demonstrates that its performance is comparable to that of the b-GPE, such as a $t_{{Li}^{+}}$ of 0.506, a high electrolyte absorption rate, and a wide electrochemical window of 5.2 V. Full article

5-aminotetrazole (5AT)-based gas generators, particularly the 5AT/NaIO₄ system, have garnered interest for their high gas production and energy potential. This study investigates the impact of various metal oxides (MnO₂, Al₂O₃, TiO₂, CuO, Fe₂O₃, MgO, ZnO, and MoO₃) on the thermal decomposition and combustion performance of 5AT/NaIO₄. The REAL calculation program was used to infer reaction products, which indicated that the gas products are almost all harmless, with negligibly low percentages of NO and CO. Thermogravimetric analysis revealed that metal oxides, especially MoO₃, significantly advance the decomposition process above 400 °C, reducing the activation energy by 130 kJ/mol and lowering critical ignition and thermal explosion temperatures. Combustion performance tests and closed bomb tests confirmed MoO₃’s positive effect, accelerating reaction rates and enhancing decomposition efficiency. The system’s high Gibbs free energy indicates non-spontaneous reactions. These findings provide valuable insights for designing environmentally friendly gas generators, highlighting MoO₃’s potential as an effective catalyst. Full article

The article reports on the development of a fundamentally new, effective technology for recycling waste tires using the explosive-circulation technology method, which was implemented in industry at a working factory. The construction of an explosion-circulation reactor, in which tires are destroyed under the influence of an explosion, is described. The main technological stages of the reactor operation include the formation of a tire package with a height of about 2.4 m and a mass of up to 1000 kg; cooling the package by air turbo-cooling machine to a temperature of minus 70–80 °C; placing the package into the reactor; initiating the explosive charge; and removing the tire shedding products with a subsequent granulometric classification of the resulting rubber crumb. The resulting rubber crumb has good wettability, which eliminates the need for an additional technological stage of activating the crumb surface. This made it possible to successfully use the obtained rubber crumb to improve the characteristics of road construction bitumen, the hardness of which at −16 °C decreased from 217 to 161 MPa. Using atomic force microscopy (AFM), gas chromatography, mass spectrometry, GPC, and XPS, it was established that the good wettability of the crumbs is explained by the formation of molecules with polar groups (C-O, C=O, C(O)O, C-S, C-SO_x, Zn-S, O-Si(O)-O) on the crumb surface as a result of the explosion. Full article

Hydrothermal carbonization (HTC) technology converts biomass into a carbon-rich, oxygen-containing solid fuel. Most studies have focused on hydrochar produced under laboratory conditions, leaving a gap in understanding the performance of industrially produced hydrochar. This study comprehensively analyzes three types of industrially produced hydrochar for blast furnace (BF) injection. The results indicate that hydrochar has a higher volatile and lower fixed carbon content. It has a lower high heating value (HHV) than coal and contains more alkali matter. Nevertheless, hydrochar exhibits a better grindability and combustion performance than coal. Blending hydrochar with anthracite significantly enhances the combustion reactivity of the mixture. The theoretical conversion rate calculations reveal a synergistic effect between hydrochar and anthracite during co-combustion. Environmental benefit calculations show that replacing 40% of bituminous coal with hydrochar can reduce CO₂ emissions by approximately 145 kg/tHM, which is equivalent to an annual reduction of 528 kton of CO₂ and 208 kton of coal in BF operations. While industrially produced hydrochar meets BF injection requirements, its low ignition point and high explosivity necessitate the careful control of the blending ratio. Full article

Lithium batteries are widely used in fields such as engineering micro-machines, robotics, and transportation. However, safety issues caused by battery thermal runaway limit their further promotion. This study used a sealed heating pressure chamber (SHPC) to perform “heat-wait-seek (HWS)” stepwise heating on a 50 Ah lithium iron phosphate (LiFePO₄) battery to trigger thermal runaway. It was found that the state of charge (SOC) has a significant impact on the safety of the battery. There was no significant correlation between the valve opening temperature (T₁) and the temperature at which the battery’s thermal runaway rapidly self-heats (T₂) and SOC. However, as SOC increased, the maximum temperature (T₃) of the battery’s thermal runaway increased, reaching up to 357.4 °C. The mass loss rate due to thermal runaway increased with SOC. The critical point of the battery’s safety valve was essentially independent of SOC and was mainly influenced by temperature. After thermal runaway, the mixed gas was passed through a gas chromatograph (GC) to detect its composition. When the SOC was below 50%, the total gas production from thermal runaway increased slowly (0.68–0.90 mol). Above 50% SOC, the total gas production from the battery increased sharply (at 75% SOC, 1.17504 mol; at 100% SOC, 2.33047 mol). Among these gases, the amount of H₂ increased sharply with SOC (from 0.01 mol at 0% SOC to 0.93 mol at 100% SOC), while the amount of CO₂ remained almost constant. Considering the inerting effect of CO₂ in the gas produced during thermal runaway of LiFePO₄ batteries, the lower flammability limit of the mixed gas increased as SOC decreased (from 6.91% at 100% SOC to 55.43% at 0% SOC). The risk of explosion during thermal runaway of high SOC batteries significantly increased. Notably, within the SOC range of 25% to 100%, the flammable range remained stable at 34–43%, but at 0% SOC, it sharply dropped to 0.5%. Therefore, batteries that are deeply discharged have higher safety. Full article

High-entropy oxides are a new type of material that consists of five or more principal elements in an equimolar or nearly equimolar ratio. They have many excellent properties and are rapidly becoming a hotspot for the development of new high-performance materials. In this study, electrical explosion is used for the first time to synthesize high-entropy oxide nanopowders with different crystal structures. (FeCoNiCrCu)O is the rock salt structure, (FeCoNiCrTi)O is the spinel structure, and (CoNiTiCuZn)O contains the two phases. According to the TEM and EDS results, the distribution of the five metal elements in the electrical explosion products is comparatively homogeneous, and the particle size of the products is concentrated in 20–40 nm. Elements such as Ti are prone to the formation of spinel structure, and the element Cu is prone to the formation of rock salt structure. The study shows that the electrical explosion of wires is a new method for the synthesis of high-entropy oxide nanopowders. Full article

The reserves of hot dry rock (HDR) geothermal resources are huge. The main method used to develop HDR geothermal resources is called an enhanced geothermal system (EGS), and this generally uses hydraulic fracturing. After nearly 50 years of research and development, more and more countries have joined the ranks engaged in the exploration and development of HDR in the world. This paper summarizes the base technologies, key technologies, and game-changing technologies used to promote the commercialization of HDR geothermal resources. According to the present situation of the exploration, development, and utilization of HDR at home and abroad, the evaluation and site selection, efficient and low-cost drilling, and geothermal utilization of HDR geothermal resources are defined as the base technologies. Key technologies include the high-resolution exploration and characterization of HDR, efficient and complex fracture network reservoir creation, effective microseismic control, fracture network connectivity, and reservoir characterization. Game-changing technologies include downhole liquid explosion fracture creation, downhole in-situ efficient heat transfer and power generation, and the use of CO₂ and other working fluids for high-efficient power generation. Most of the base technologies already have industrial applications, but future efforts must focus on reducing costs. The majority of key technologies are still in the site demonstration and validation phase and have not yet been applied on an industrial scale. However, breakthroughs in cost reduction and application effectiveness are urgently needed for these key technologies. Game-changing technologies remain at the laboratory research stage, but any breakthroughs in this area could significantly advance the efficient development of HDR geothermal resources. In addition, we conducted a comparative analysis of the respective advantages of China and the United States in some key technologies of HDR development. On this basis, we summarized the key challenges identified throughout the discussion and highlighted the most pressing research priorities. We hope these technologies can guide new breakthroughs in HDR geothermal development in China and other countries, helping to establish a batch of HDR exploitation demonstration areas. In addition, we look forward to fostering collaboration between China and the United States through technical comparisons, jointly promoting the commercial development of HDR geothermal resources. Full article

The increasing environmental concerns regarding plastic waste, especially in agriculture, have driven the search for sustainable alternatives. Agricultural plastics, such as mulching films and greenhouse covers, are heavily reliant on petrochemical-derived materials, which persist in the environment and contribute to long-term pollution. This study explores the use of biodegradable biocomposites made from steam explosion-treated chicken feathers and various polymer matrices to address these issues. Chicken feathers, a waste by-product of the poultry industry, present an excellent biodegradability as a result of the steam explosion treatment and contain nitrogen, potentially enhancing soil fertility. The biocomposites were characterized by thermal stability, mechanical properties, and biodegradability, and ecotoxicity assessments were carried out studying the incorporation of feathers into the soil. Results showed that the incorporation of treated chicken feathers increased the water absorption capacity of the composites, promoting faster disintegration and biodegradation. In particular, biocomposites made with polyhydroxyalkanoates and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) exhibited a significant increase in degradation rates, from 3–10% in the first month for pure matrices to 40–50% when reinforced with treated feathers. Meanwhile, those made from polylactic acid showed slower degradation. Furthermore, the addition of feathers positively influenced crop growth at low concentrations, acting as a slow-release fertilizer. However, high concentrations of feathers negatively affect plant growth due to excess nitrogen. These findings highlight the potential of poultry feathers as a valuable, sustainable filler for agricultural bioplastics, contributing to waste valorization and environmentally friendly farming practices. Full article