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Search Results (3,294)

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Keywords = co-adoption

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19 pages, 1242 KiB  
Article
Integration of Renewable Energy Sources to Achieve Sustainability and Resilience of Mines in Remote Areas
by Josip Kronja and Ivo Galić
Mining 2025, 5(3), 51; https://doi.org/10.3390/mining5030051 (registering DOI) - 6 Aug 2025
Abstract
Mining (1) operations in remote areas (2) face significant challenges related to energy supply, high fuel costs, and limited infrastructure. This study investigates the potential for achieving energy independence (3) and resilience (4) in such environments through the integration of renewable energy sources [...] Read more.
Mining (1) operations in remote areas (2) face significant challenges related to energy supply, high fuel costs, and limited infrastructure. This study investigates the potential for achieving energy independence (3) and resilience (4) in such environments through the integration of renewable energy sources (5) and battery–electric mining equipment. Using the “Studena Vrila” underground bauxite mine as a case study, a comprehensive techno-economic and environmental analysis was conducted across three development models. These models explore incremental scenarios of solar and wind energy adoption combined with electrification of mobile machinery. The methodology includes calculating levelized cost of energy (LCOE), return on investment (ROI), and greenhouse gas (GHG) reductions under each scenario. Results demonstrate that a full transition to RES and electric machinery can reduce diesel consumption by 100%, achieve annual savings of EUR 149,814, and cut GHG emissions by over 1.7 million kg CO2-eq. While initial capital costs are high, all models yield a positive Net Present Value (NPV), confirming long-term economic viability. This research provides a replicable framework for decarbonizing mining operations in off-grid and infrastructure-limited regions. Full article
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22 pages, 970 KiB  
Article
From Perception to Practice: Artificial Intelligence as a Pathway to Enhancing Digital Literacy in Higher Education Teaching
by Zhili Zuo, Yilun Luo, Shiyu Yan and Lisheng Jiang
Systems 2025, 13(8), 664; https://doi.org/10.3390/systems13080664 - 6 Aug 2025
Abstract
In the context of increasing Artificial Intelligence integration in higher education, understanding the factors influencing university teachers’ adoption of AI tools is critical for effective implementation. This study adopts a perception–intention–behavior framework to explores the roles of perceived usefulness, perceived ease of use, [...] Read more.
In the context of increasing Artificial Intelligence integration in higher education, understanding the factors influencing university teachers’ adoption of AI tools is critical for effective implementation. This study adopts a perception–intention–behavior framework to explores the roles of perceived usefulness, perceived ease of use, perceived trust, perceived substitution crisis, and perceived risk in shaping teachers’ behavioral intention and actual usage of AI tools. It also investigates the moderating effects of peer influence and organizational support on these relationships. Using a comprehensive survey instrument, data was collected from 487 university teachers across four major regions in China. The results reveal that perceived usefulness and perceived ease of use are strong predictors of behavioral intention, with perceived ease of use also significantly influencing perceived usefulness. Perceived trust serves as a key mediator, enhancing the relationship between perceived usefulness, perceived ease of use, and behavioral intention. While perceived substitution crisis negatively influenced perceived trust, it showed no significant direct effect on behavioral intention, suggesting a complex relationship between job displacement concerns and AI adoption. In contrast, perceived risk was found to negatively impact behavioral intention, though it was mitigated by perceived ease of use. Peer influence significantly moderated the relationship between perceived trust and behavioral intention, highlighting the importance of peer influence in AI adoption, while organizational support amplified the effect of perceived ease of use on behavioral intention. These findings inform practical strategies such as co-developing user-centered AI tools, enhancing institutional trust through transparent governance, leveraging peer support, providing structured training and technical assistance, and advancing policy-level initiatives to guide digital transformation in universities. Full article
(This article belongs to the Section Artificial Intelligence and Digital Systems Engineering)
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26 pages, 3478 KiB  
Article
Rethinking Routes: The Case for Regional Ports in a Decarbonizing World
by Dong-Ping Song
Logistics 2025, 9(3), 103; https://doi.org/10.3390/logistics9030103 - 4 Aug 2025
Abstract
Background: Increasing regulatory pressure for maritime decarbonization (e.g., IMO CII, FuelEU) drives adoption of low-carbon fuels and prompts reassessment of regional ports’ competitiveness. This study aims to evaluate the economic and environmental viability of rerouting deep-sea container services to regional ports in [...] Read more.
Background: Increasing regulatory pressure for maritime decarbonization (e.g., IMO CII, FuelEU) drives adoption of low-carbon fuels and prompts reassessment of regional ports’ competitiveness. This study aims to evaluate the economic and environmental viability of rerouting deep-sea container services to regional ports in a decarbonizing world. Methods: A scenario-based analysis is used to evaluate total costs and CO2 emissions across the entire container shipping supply chain, incorporating deep-sea shipping, port operations, feeder services, and inland rail/road transport. The Port of Liverpool serves as the primary case study for rerouting Asia–Europe services from major ports. Results: Analysis indicates Liverpool’s competitiveness improves with shipping lines’ slow steaming, growth in hinterland shipment volume, reductions in the emission factors of alternative low-carbon fuels, and an increased modal shift to rail matching that of competitor ports (e.g., Southampton). A dual-port strategy, rerouting services to call at both Liverpool and Southampton, shows potential for both economic and environmental benefits. Conclusions: The study concludes that rerouting deep-sea services to regional ports can offer cost and emission advantages under specific operational and market conditions. Findings on factors and conditions influencing competitiveness and the dual-port strategy provide insights for shippers, ports, shipping lines, logistics agents, and policymakers navigating maritime decarbonization. Full article
(This article belongs to the Section Maritime and Transport Logistics)
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18 pages, 1388 KiB  
Review
Simulation in the Built Environment: A Bibliometric Analysis
by Saman Jamshidi
Metrics 2025, 2(3), 13; https://doi.org/10.3390/metrics2030013 - 4 Aug 2025
Abstract
Simulation has become a pivotal tool in the design, analysis, and optimization of the built environment, and has been widely adopted by professionals in architecture, engineering, and urban planning. These techniques enable stakeholders to test hypotheses, evaluate design alternatives, and predict performance outcomes [...] Read more.
Simulation has become a pivotal tool in the design, analysis, and optimization of the built environment, and has been widely adopted by professionals in architecture, engineering, and urban planning. These techniques enable stakeholders to test hypotheses, evaluate design alternatives, and predict performance outcomes prior to construction. Applications span energy consumption, airflow, thermal comfort, lighting, structural behavior, and human interactions within buildings and urban contexts. This study maps the scientific landscape of simulation research in the built environment through a bibliometric analysis of 12,220 publications indexed in Scopus. Using VOSviewer 1.6.20, it conducted citation and keyword co-occurrence analyses to identify key research themes, leading countries and journals, and central publications in the field. The analysis revealed seven primary thematic clusters: (1) human-focused simulation, (2) building-scale energy performance simulation, (3) urban-scale energy performance simulation, (4) sustainable design and simulation, (5) indoor environmental quality simulation, (6) building aerodynamics simulation, and (7) computing in building simulation. By synthesizing these trends and domains, this study provides an overview of the field, facilitating greater accessibility to the simulation literature and informing future interdisciplinary research and practice in the built environment. Full article
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22 pages, 2179 KiB  
Article
Conversion of Oil Palm Kernel Shell Wastes into Active Biocarbons by N2 Pyrolysis and CO2 Activation
by Aik Chong Lua
Clean Technol. 2025, 7(3), 66; https://doi.org/10.3390/cleantechnol7030066 - 4 Aug 2025
Viewed by 149
Abstract
Oil palm kernel shell is an abundant agricultural waste generated by the palm oil industry. To achieve sustainable use of this waste, oil palm kernel shells were converted into valuable resources as active biocarbons. A two-stage preparation method involving N2 pyrolysis, followed [...] Read more.
Oil palm kernel shell is an abundant agricultural waste generated by the palm oil industry. To achieve sustainable use of this waste, oil palm kernel shells were converted into valuable resources as active biocarbons. A two-stage preparation method involving N2 pyrolysis, followed by CO2 activation, was used to produce the active biocarbon. The optimum pyrolysis conditions that produced the largest BET surface area of 519.1 m2/g were a temperature of 600 °C, a hold time of 2 h, a nitrogen flow rate of 150 cm3/min, and a heating rate of 10 °C/min. The optimum activation conditions to prepare the active biocarbon with the largest micropore surface area or the best micropore/BET surface area combination were a temperature of 950 °C, a CO2 flow rate of 300 cm3/min, a heating rate of 10 °C/min, and a hold time of 3 h, yielding BET and micropore surface areas of 1232.3 and 941.0 m2/g, respectively, and consisting of 76.36% of micropores for the experimental optimisation technique adopted here. This study underscores the importance of optimising both the pyrolysis and activation conditions to produce an active biocarbon with a maximum micropore surface area for gaseous adsorption applications, especially to capture CO2 greenhouse gas, to mitigate global warming and climate change. Such a comprehensive and detailed study on the conversion of oil palm kernel shell into active biocarbon is lacking in the open literature. The research results provide a practical blueprint on the process parameters and technical know-how for the industrial production of highly microporous active biocarbons prepared from oil palm kernel shells. Full article
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15 pages, 1691 KiB  
Article
tRNA Modifications: A Tale of Two Viruses—SARS-CoV-2 and ZIKV
by Patrick Eldin and Laurence Briant
Int. J. Mol. Sci. 2025, 26(15), 7479; https://doi.org/10.3390/ijms26157479 - 2 Aug 2025
Viewed by 176
Abstract
tRNA modifications are crucial for efficient protein synthesis, impacting codon recognition, tRNA stability, and translation rates. RNA viruses hijack the host’s translational machinery, including the pool of modified tRNA, to translate their own genomes. However, the mismatch between viral and host codon usage [...] Read more.
tRNA modifications are crucial for efficient protein synthesis, impacting codon recognition, tRNA stability, and translation rates. RNA viruses hijack the host’s translational machinery, including the pool of modified tRNA, to translate their own genomes. However, the mismatch between viral and host codon usage can lead to a limited availability of specific tRNA leading to ribosome stalling, posing a significant challenge for efficient protein translation. While some viruses address this challenge through codon optimization, we show here that SARS-CoV-2 (Coronavirus) and the Zika virus (ZIKV; Flavivirus) adopt a different approach, manipulating the host tRNA epitranscriptome. Analysis of codon bias indices confirmed a substantial divergence between viral and host codon usage, revealing a strong preference in viral genes for codons decoded by tRNAs requiring U34 wobble modification. Monitoring tRNA modification dynamics in infected cells showed that both SARS-CoV2 and ZIKV enhance U34 tRNA modifications during infection. Strikingly, impairing U34 tRNAs profoundly impacted viral replication, underscoring the strict reliance of SARS-CoV-2 and ZIKV on manipulating the host tRNA epitranscriptome to support the efficient translation of their genome. Full article
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21 pages, 1353 KiB  
Article
Hydrogen Cost and Carbon Analysis in Hollow Glass Manufacturing
by Dario Atzori, Claudia Bassano, Edoardo Rossi, Simone Tiozzo, Sandra Corasaniti and Angelo Spena
Energies 2025, 18(15), 4105; https://doi.org/10.3390/en18154105 - 2 Aug 2025
Viewed by 173
Abstract
The European Union promotes decarbonization in energy-intensive industries like glass manufacturing. Collaboration between industry and researchers focuses on reducing CO2 emissions through hydrogen (H2) integration as a natural gas substitute. However, to the best of the authors’ knowledge, no updated [...] Read more.
The European Union promotes decarbonization in energy-intensive industries like glass manufacturing. Collaboration between industry and researchers focuses on reducing CO2 emissions through hydrogen (H2) integration as a natural gas substitute. However, to the best of the authors’ knowledge, no updated real-world case studies are available in the literature that consider the on-site implementation of an electrolyzer for autonomous hydrogen production capable of meeting the needs of a glass manufacturing plant within current technological constraints. This study examines a representative hollow glass plant and develops various decarbonization scenarios through detailed process simulations in Aspen Plus. The models provide consistent mass and energy balances, enabling the quantification of energy demand and key cost drivers associated with H2 integration. These results form the basis for a scenario-specific techno-economic assessment, including both on-grid and off-grid configurations. Subsequently, the analysis estimates the levelized costs of hydrogen (LCOH) for each scenario and compares them to current and projected benchmarks. The study also highlights ongoing research projects and technological advancements in the transition from natural gas to H2 in the glass sector. Finally, potential barriers to large-scale implementation are discussed, along with policy and infrastructure recommendations to foster industrial adoption. These findings suggest that hybrid configurations represent the most promising path toward industrial H2 adoption in glass manufacturing. Full article
(This article belongs to the Special Issue Techno-Economic Evaluation of Hydrogen Energy)
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14 pages, 854 KiB  
Systematic Review
The Critical Impact and Socio-Ethical Implications of AI on Content Generation Practices in Media Organizations
by Sevasti Lamprou, Paraskevi (Evi) Dekoulou and George Kalliris
Societies 2025, 15(8), 214; https://doi.org/10.3390/soc15080214 - 1 Aug 2025
Viewed by 232
Abstract
This systematic literature review explores the socio-ethical implications of Artificial Intelligence (AI) in contemporary media content generation. Drawing from 44 peer-reviewed sources, policy documents, and industry reports, the study synthesizes findings across three core domains: bias detection, storytelling transformation, and ethical governance frameworks. [...] Read more.
This systematic literature review explores the socio-ethical implications of Artificial Intelligence (AI) in contemporary media content generation. Drawing from 44 peer-reviewed sources, policy documents, and industry reports, the study synthesizes findings across three core domains: bias detection, storytelling transformation, and ethical governance frameworks. Through thematic coding and structured analysis, the review identifies recurring tensions between automation and authenticity, efficiency and editorial integrity, and innovation and institutional oversight. It introduces the Human–AI Co-Creation Continuum as a conceptual model for understanding hybrid narrative production and proposes practical recommendations for ethical AI adoption in journalism. The review concludes with a future research agenda emphasizing empirical studies, cross-cultural governance models, and audience perceptions of AI-generated content. This aligns with prior studies on algorithmic journalism. Full article
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18 pages, 1819 KiB  
Article
A Multimodal Deep Learning Framework for Consistency-Aware Review Helpfulness Prediction
by Seonu Park, Xinzhe Li, Qinglong Li and Jaekyeong Kim
Electronics 2025, 14(15), 3089; https://doi.org/10.3390/electronics14153089 - 1 Aug 2025
Viewed by 110
Abstract
Multimodal review helpfulness prediction (MRHP) aims to identify the most helpful reviews by leveraging both textual and visual information. However, prior studies have primarily focused on modeling interactions between these modalities, often overlooking the consistency between review content and ratings, which is a [...] Read more.
Multimodal review helpfulness prediction (MRHP) aims to identify the most helpful reviews by leveraging both textual and visual information. However, prior studies have primarily focused on modeling interactions between these modalities, often overlooking the consistency between review content and ratings, which is a key indicator of review credibility. To address this limitation, we propose CRCNet (Content–Rating Consistency Network), a novel MRHP model that jointly captures the semantic consistency between review content and ratings while modeling the complementary characteristics of text and image modalities. CRCNet employs RoBERTa and VGG-16 to extract semantic and visual features, respectively. A co-attention mechanism is applied to capture the consistency between content and rating, and a Gated Multimodal Unit (GMU) is adopted to integrate consistency-aware representations. Experimental results on two large-scale Amazon review datasets demonstrate that CRCNet outperforms both unimodal and multimodal baselines in terms of MAE, MSE, RMSE, and MAPE. Further analysis confirms the effectiveness of content–rating consistency modeling and the superiority of the proposed fusion strategy. These findings suggest that incorporating semantic consistency into multimodal architectures can substantially improve the accuracy and trustworthiness of review helpfulness prediction. Full article
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32 pages, 9914 KiB  
Review
Technology Advancements and the Needs of Farmers: Mapping Gaps and Opportunities in Row Crop Farming
by Rana Umair Hameed, Conor Meade and Gerard Lacey
Agriculture 2025, 15(15), 1664; https://doi.org/10.3390/agriculture15151664 - 1 Aug 2025
Viewed by 279
Abstract
Increased food production demands, labor shortages, and environmental concerns are driving the need for innovative agricultural technologies. However, effective adoption depends critically on aligning robot innovations with the needs of farmers. This paper examines the alignment between the needs of farmers and the [...] Read more.
Increased food production demands, labor shortages, and environmental concerns are driving the need for innovative agricultural technologies. However, effective adoption depends critically on aligning robot innovations with the needs of farmers. This paper examines the alignment between the needs of farmers and the robotic systems used in row crop farming. We review current commercial agricultural robots and research, and map these to the needs of farmers, as expressed in the literature, to identify the key issues holding back large-scale adoption. From initial pool of 184 research articles, 19 survey articles, and 82 commercial robotic solutions, we selected 38 peer-reviewed academic studies, 12 survey articles, and 18 commercially available robots for in-depth review and analysis for this study. We identify the key challenges faced by farmers and map them directly to the current and emerging capabilities of agricultural robots. We supplement the data gathered from the literature review of surveys and case studies with in-depth interviews with nine farmers to obtain deeper insights into the needs and day-to-day operations. Farmers reported mixed reactions to current technologies, acknowledging efficiency improvements but highlighting barriers such as capital costs, technical complexity, and inadequate support systems. There is a notable demand for technologies for improved plant health monitoring, soil condition assessment, and enhanced climate resilience. We then review state-of-the-art robotic solutions for row crop farming and map these technological capabilities to the farmers’ needs. Only technologies with field validation or operational deployment are included, to ensure practical relevance. These mappings generate insights that underscore the need for lightweight and modular robot technologies that can be adapted to diverse farming practices, as well as the need for farmers’ education and simpler interfaces to robotic operations and data analysis that are actionable for farmers. We conclude with recommendations for future research, emphasizing the importance of co-creation with the farming community to ensure the adoption and sustained use of agricultural robotic solutions. Full article
(This article belongs to the Section Artificial Intelligence and Digital Agriculture)
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26 pages, 1033 KiB  
Article
Internet of Things Platform for Assessment and Research on Cybersecurity of Smart Rural Environments
by Daniel Sernández-Iglesias, Llanos Tobarra, Rafael Pastor-Vargas, Antonio Robles-Gómez, Pedro Vidal-Balboa and João Sarraipa
Future Internet 2025, 17(8), 351; https://doi.org/10.3390/fi17080351 - 1 Aug 2025
Viewed by 163
Abstract
Rural regions face significant barriers to adopting IoT technologies, due to limited connectivity, energy constraints, and poor technical infrastructure. While urban environments benefit from advanced digital systems and cloud services, rural areas often lack the necessary conditions to deploy and evaluate secure and [...] Read more.
Rural regions face significant barriers to adopting IoT technologies, due to limited connectivity, energy constraints, and poor technical infrastructure. While urban environments benefit from advanced digital systems and cloud services, rural areas often lack the necessary conditions to deploy and evaluate secure and autonomous IoT solutions. To help overcome this gap, this paper presents the Smart Rural IoT Lab, a modular and reproducible testbed designed to replicate the deployment conditions in rural areas using open-source tools and affordable hardware. The laboratory integrates long-range and short-range communication technologies in six experimental scenarios, implementing protocols such as MQTT, HTTP, UDP, and CoAP. These scenarios simulate realistic rural use cases, including environmental monitoring, livestock tracking, infrastructure access control, and heritage site protection. Local data processing is achieved through containerized services like Node-RED, InfluxDB, MongoDB, and Grafana, ensuring complete autonomy, without dependence on cloud services. A key contribution of the laboratory is the generation of structured datasets from real network traffic captured with Tcpdump and preprocessed using Zeek. Unlike simulated datasets, the collected data reflect communication patterns generated from real devices. Although the current dataset only includes benign traffic, the platform is prepared for future incorporation of adversarial scenarios (spoofing, DoS) to support AI-based cybersecurity research. While experiments were conducted in an indoor controlled environment, the testbed architecture is portable and suitable for future outdoor deployment. The Smart Rural IoT Lab addresses a critical gap in current research infrastructure, providing a realistic and flexible foundation for developing secure, cloud-independent IoT solutions, contributing to the digital transformation of rural regions. Full article
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22 pages, 1968 KiB  
Article
Evaluating the Implementation of Information Technology Audit Systems Within Tax Administration: A Risk Governance Perspective for Enhancing Digital Fiscal Integrity
by Murat Umbet, Daulet Askarov, Kristina Rudžionienė, Česlovas Christauskas and Laura Alikulova
J. Risk Financial Manag. 2025, 18(8), 422; https://doi.org/10.3390/jrfm18080422 - 1 Aug 2025
Viewed by 292
Abstract
This study evaluates the impact of digital systems and IT audit frameworks on tax performance and integrity within tax administrations. Using international data from organizations like the World Bank, OECD (Organisation for Economic Co-operation and Development), and IMF (International Monetary Fund), the research [...] Read more.
This study evaluates the impact of digital systems and IT audit frameworks on tax performance and integrity within tax administrations. Using international data from organizations like the World Bank, OECD (Organisation for Economic Co-operation and Development), and IMF (International Monetary Fund), the research examines the relationship between tax revenue as a percentage of GDP, digital infrastructure, corruption perception, e-government development, and cybersecurity readiness. Quantitative analysis, including correlation, regression, and clustering methods, reveals a strong positive relationship between digital maturity, e-governance, and tax performance. Countries with advanced digital governance systems and robust IT audit frameworks, such as COBIT, tend to show higher tax revenues and lower corruption levels. The study finds that e-government development and anti-corruption measures explain over 40% of the variance in tax performance. Cluster analysis distinguishes between digitally advanced, high-compliance countries and those lagging in IT adoption. The findings suggest that digital transformation strengthens fiscal integrity by automating compliance and reducing human contact, which in turn mitigates bribery risks and enhances fraud detection. The study highlights the need for adopting international best practices to guide the digitalization of tax administrations, improving efficiency, transparency, and trust in public finance. Full article
(This article belongs to the Section Economics and Finance)
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32 pages, 10052 KiB  
Article
A Study on Large Electric Vehicle Fires in a Tunnel: Use of a Fire Dynamics Simulator (FDS)
by Roberto Dessì, Daniel Fruhwirt and Davide Papurello
Processes 2025, 13(8), 2435; https://doi.org/10.3390/pr13082435 - 31 Jul 2025
Viewed by 334
Abstract
Internal combustion engine vehicles damage the environment and public health by emitting toxic fumes, such as CO2 or CO and other trace compounds. The use of electric cars helps to reduce the emission of pollutants into the environment due to the use [...] Read more.
Internal combustion engine vehicles damage the environment and public health by emitting toxic fumes, such as CO2 or CO and other trace compounds. The use of electric cars helps to reduce the emission of pollutants into the environment due to the use of batteries with no direct and local emissions. However, accidents of battery electric vehicles pose new challenges, such as thermal runaway. Such accidents can be serious and, in some cases, may result in uncontrolled overheating that causes the battery pack to spontaneously ignite. In particular, the most dangerous vehicles are heavy goods vehicles (HGVs), as they release a large amount of energy that generate high temperatures, poor visibility, and respiratory damage. This study aims to determine the potential consequences of large BEV fires in road tunnels using computational fluid dynamics (CFD). Furthermore, a comparison between a BEV and an ICEV fire shows the differences related to the thermal and the toxic impact. Furthermore, the adoption of a longitudinal ventilation system in the tunnel helped to mitigate the BEV fire risk, keeping a safer environment for tunnel users and rescue services through adequate smoke control. Full article
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31 pages, 3379 KiB  
Review
The Adoption of Technological Innovations in the Maritime Industry: A Bibliometric Review
by Armand Djoumessi, Alessio Tei and Claudio Ferrari
J. Mar. Sci. Eng. 2025, 13(8), 1484; https://doi.org/10.3390/jmse13081484 - 31 Jul 2025
Viewed by 174
Abstract
The adoption of technological innovations in the maritime industry is of interest to business, policy, and academic communities. In the last group, this interest has translated into the publication of a large but scattered literature, making it difficult to compare findings and identify [...] Read more.
The adoption of technological innovations in the maritime industry is of interest to business, policy, and academic communities. In the last group, this interest has translated into the publication of a large but scattered literature, making it difficult to compare findings and identify the dynamics, structures, and patterns that might inform future research. A comprehensive review of past research on this topic might help achieve this. To date, no such review has been carried out, which is an important gap in the literature that this paper contributes to bridging. Two bibliometric review techniques—co-citation analysis of cited references and bibliographic coupling of documents—are applied to 171 journal articles published between 1999 and February 2025 to answer the following questions: 1. What is the knowledge base of this literature? 2. What are the recent research trends (research fronts) in this literature? The analysis reveals that research on “shore power” dominates both the knowledge base and research fronts. Other key research themes centre on “autonomous shipping”, “blockchain”, and “alternative fuels”. Based on these results, implications for future research are drawn. Full article
(This article belongs to the Special Issue Sustainable and Efficient Maritime Operations)
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42 pages, 3564 KiB  
Review
A Review on Sustainable Upcycling of Plastic Waste Through Depolymerization into High-Value Monomer
by Ramkumar Vanaraj, Subburayan Manickavasagam Suresh Kumar, Seong Cheol Kim and Madhappan Santhamoorthy
Processes 2025, 13(8), 2431; https://doi.org/10.3390/pr13082431 - 31 Jul 2025
Viewed by 603
Abstract
Plastic waste accumulation is one of the most pressing environmental challenges of the 21st century, owing to the widespread use of synthetic polymers and the limitations of conventional recycling methods. Among available strategies, chemical upcycling via depolymerization has emerged as a promising circular [...] Read more.
Plastic waste accumulation is one of the most pressing environmental challenges of the 21st century, owing to the widespread use of synthetic polymers and the limitations of conventional recycling methods. Among available strategies, chemical upcycling via depolymerization has emerged as a promising circular approach that converts plastic waste back into valuable monomers and chemical feedstocks. This article provides an in-depth narrative review of recent progress in the upcycling of major plastic types such as PET, PU, PS, and engineering plastics through thermal, chemical, catalytic, biological, and mechanochemical depolymerization methods. Each method is critically assessed in terms of efficiency, scalability, energy input, and environmental impact. Special attention is given to innovative catalyst systems, such as microsized MgO/SiO2 and Co/CaO composites, and emerging enzymatic systems like engineered PETases and whole-cell biocatalysts that enable low-temperature, selective depolymerization. Furthermore, the conversion pathways of depolymerized products into high-purity monomers such as BHET, TPA, vanillin, and bisphenols are discussed with supporting case studies. The review also examines life cycle assessment (LCA) data, techno-economic analyses, and policy frameworks supporting the adoption of depolymerization-based recycling systems. Collectively, this work outlines the technical viability and sustainability benefits of depolymerization as a core pillar of plastic circularity and monomer recovery, offering a path forward for high-value material recirculation and waste minimization. Full article
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