Search Results (33)

This pilot study investigated an automated pilot plant for removing microplastics (MPs) from industrial wastewater that are generated during packaging production. MP removal is based on organosilane-induced agglomeration-fixation (clump & skim technology) followed by separation. The wastewater had high MP loads (1725 ± 377 mg/L; 673 ± 183 million particles/L) and an average COD of 7570 ± 1339 mg/L. Over 25 continuous test runs, the system achieved consistent performance, removing an average of 97.4% of MPs by mass and 99.1% by particle count, while reducing the COD by 78.8%. Projected over a year, this equates to preventing 1.7 tons of MPs and 6 tons of COD from entering the sewage system. Turbidity and photometric TSS measurements proved useful for process control. The approach supports water reuse—with water savings up to 80%—and allows recovery of agglomerates for recycling and reuse. Targeting pollutant removal upstream at the source provides multiple financial and environmental benefits, including lower overall energy demands, higher removal efficiencies, and process water reuse. This provides financial and environmental incentives for industries to implement sustainable solutions for pollutants and microplastic removal. Full article

The envelopes of Red Supergiants (RSGs) have a unique chemical environment not seen in other types of stars. They foster an oxygen-rich synthesis but are tempered by sporadic and chaotic mass loss, which distorts the envelope and creates complex outflow sub-structures consisting of knots, clumps, and arcs. Near the stellar photosphere, molecules and grains form under approximate LTE conditions, as predicted by chemical models. However, the complicated outflows appear to have distinct chemistries generated by shocks and dust destruction. Various RSG envelopes have been probed for their molecular content, mostly by radio and millimeter observations; however, VY Canis Majoris (VY CMa) and NML Cygni (NML Cyg) display the highest chemical complexity, and also the most complicated envelope structure. Thus far, over 29 different molecules have been identified in the envelopes of RSGs. Some molecules are common for circumstellar gas, including CO, SiO, HCN and H₂O, which have abundances of ∼10⁻⁶–10⁻⁴, relative to H₂. More exotic oxides have additionally been discovered, such as AlO, AlOH, PO, TiO₂, and VO, with abundances of ∼10⁻⁹–10⁻⁷. RSG shells support intricate maser emission in OH, H₂O and SiO, as well. Studies of isotope ratios in molecules suggest dredge-up at least into the H-burning shell, but further exploration is needed. Full article

Background: Animal-associated antimicrobial-resistant staphylococci pose a One Health concern, as they can spread into the environment and cause serious infections. Yet, donkeys in Nigeria have been largely overlooked as potential reservoirs of these pathogens. Aim/Objectives: To isolate Staphylococcus aureus from donkeys in Obollo-Afor, southeast Nigeria, assess their antimicrobial resistance profiles, and evaluate their virulence potential. Materials and Methods: Staphylococci were isolated from the nasal swabs of 250 donkeys, using mannitol salt agar, confirmed biochemically, with Staphylococcus aureus identified via a latex agglutination test and mass spectrometry. The resistance profiles of the isolates, including in regard to methicillin, inducible clindamycin, and β-lactamase production, were determined using disc diffusion, while vancomycin resistance was assessed through the use of agar dilution. The virulence factors were evaluated phenotypically. Results: Of the 250 samples, 11 (4.4%) contained S. aureus and 239 (95.6%) grew other Staphylococcus species. The resistance rates of the 11 S. aureus isolates to gentamicin, penicillin, tigecycline, cefoxitin, linezolid, and chloramphenicol were 45.5%, 66.7%, 54.5%, 27.3%, 36.4%, and 18.1%, respectively. The phenotypic methicillin-resistant S. aureus prevalence was 1.2%. Additionally, 23.5% of the S. aureus isolates were multidrug resistant, with a mean antibiotic resistance index of 0.25. All the S. aureus isolates exhibited virulence factors like clumping factor expression, catalase, caseinase, lecithinase, and gelatinase activity, while the occurrence of haemagglutinin, biofilm, pellicle, and hemolysin occurred in 27.3%, 54.5%, 36.4%, 72.2%, respectively. Conclusion: Although a small percentage of donkeys in Nigeria may harbor S. aureus, these animals are potentially spreading antimicrobial resistance, including multidrug and methicillin resistance, to humans and the environment. Full article

Gravitational fragmentation of a protoplanetary disk is considered a possible mechanism for the formation of planets and brown dwarfs. In this process, transitory objects are formed that are known as clumps, which are compact gas–dust condensations with a size of several astronomical units. The contraction of these clumps to planetary sizes via the dissociation of molecular hydrogen or tidal downsizing can ultimately lead to planet or brown dwarf formation. Here, we present a comprehensive numerical and statistical study of the clump properties in protoplanetary disks formed from cloud cores of similar mass (0.9–1.0 $M_{\odot }$). We focus on possible differences in their characteristics depending on the metallicity of the parental disk. We show that notable differences can be expected in the clump characteristics in terms of their number, internal energetics, mass, and distance to the star. For all metallicities considered, the propensity to forming planets or brown dwarfs via disk fragmentation is challenged by large amounts of gravitationally unbound clumps. We conclude that giant planet formation via disk fragmentation is possible down to 1/100 solar metallicity but it should be a rare outcome. Brown dwarf formation via disk fragmentation is possible only down to 1/10 solar metallicity. Our results stand for similar masses of the central star on the order of the Sun. Full article

HKUST-1 (HKUST = Hong Kong University of Science and Technology) is one of the most recognized metal-organic frameworks (MOFs) based on copper and trimesate, extensively studied for a variety of applications, such as gas storage, separation, adsorption, electrocatalysis, drug delivery, sensor and photodegradation, etc. In this work, we introduce a novel nanofused HKUST-1, referred to as N-CuBTC (BTC = trimesate), which has been synthesized with the hydrothermal method at room temperature (typical synthesis temperature is from 80~120 °C). The resulting N-CuBTC features an irregular particle morphology, with numerous crystals clustering together and edges that have fused, creating a hierarchical pore structure. In contrast to the traditional micro-sized octahedral HKUST-1 (named as M-CuBTC), N-CuBTC displays a unique clumped morphology, where the HKUST-1 crystals are seamlessly integrated into a cohesive structure. This innovative formation significantly enhances mass transfer capabilities and porosity accessibility. Consequently, N-CuBTC demonstrates markedly improved catalytic performance in the cyanosilylation of aldehydes. Full article

Fibers are widely used in concrete structures to control crack propagation and widening due to sustained or impact loads. Nevertheless, the concrete’s mechanical and structural properties are strongly affected by the fibers’ spatial distribution and clumping tendency within the mass material. The main objective of this paper is to assess the efficiency of stochastic finite element modeling to predict the shear strength properties of fiber-reinforced concrete (FRC) beams without stirrups, as tested by four-point loading. Polypropylene and polyvinyl alcohol micro-filament fibers are investigated in this experimental program at relatively high rates, varying from 0.5% to 1% by volume. A stochastic sensitivity analysis is performed using both random fields and random variables to determine the effect of fiber additions on the concrete’s mechanical properties (i.e., splitting tensile strength and modulus of elasticity) including the beam cracking patterns, ductility, mid-span deflection, and ultimate load. Such data could be of interest to civil engineers and structural designers to reduce the effort and resources needed to assess the FRC strength variability and failure behaviors of structural members. Full article

Infrared dark clouds (IRDCs) are fruitful objects to study the fragmentation of interstellar filaments and initial conditions and early stages of high-mass ($M>8$ M_⊙) star formation. We used the Yebes 40 m and Institut de Radioastronomie Millimétrique (IRAM) 30 m radio telescopes to carry out the first single-pointing spectral line observations towards the IRDC G1.75-0.08, which is a filamentary Central Molecular Zone (CMZ) cloud. Our aim is to reach an improved understanding of the gas kinematics and dynamical state of the cloud and its two clumps that we call clumps A and B. We also aim to determine the fractional abundances of the molecules detected at 3 mm towards G1.75-0.08. We detected HNCO$(J_{K_a,K_c}=4_{0,4}-3_{0,3})$, HCN$(J=1-0)$, and HCO⁺$(J=1-0)$ towards both clumps. The N₂H⁺$(J=1-0)$ line was detected only in clump B, while N₂D⁺$(J=1-0)$ was not detected at all. The HCN and HNCO spectra exhibit two velocity components. The abundances of the detected species are comparable to those in other IRDCs. An upper limit to the [N₂D⁺]/[N₂H⁺] deuterium fraction of <0.05 derived towards clump B is consistent with values observed in many high-mass clumps. The line mass analysis suggests that the G1.75-0.08 filament is subcritical by a factor of $11\pm 6$, and the clumps were found to be gravitationally unbound (${\alpha }_{\mathrm{vir}}>2$). Our finding that G1.75-0.08 is strongly subcritical is atypical compared to the general population of Galactic filamentary clouds. The cloud’s location in the CMZ might affect the cloud kinematics similar to what has been found for the Brick IRDC, and the cloud’s dynamical state might also be the result of the turbulent motions or shear and tidal forces in the CMZ. Because the target clumps are dark at 70 $\mathsf{\mu }$m and massive (several ${10}^3$ M_⊙), they can be considered candidates for being high-mass starless clumps but not prestellar because they are not gravitationally bound. Full article

In order to separate the colloidal in high-turbidity water, a kind of magnetic composite (Fe₃O₄/HBPN) was prepared via the functional assembly of Fe₃O₄ and an amino-terminal hyperbranched polymer (HBPN). The physical and chemical characteristics of Fe₃O₄@HBPN were investigated by different means. The Fourier Transform infrared spectroscopy (FTIR) spectra showed that the characteristic absorption peaks positioned at 1110 cm⁻¹, 1468 cm⁻¹, 1570 cm⁻¹ and 1641 cm⁻¹ were ascribed to C–N, H–N–C, N–H and C=O bonds, respectively. The shape and size of Fe₃O₄/HBPN showed a different and uneven distribution; the particles clumped together and were coated with an oil-like film. Energy-dispersive spectroscopy (EDS) displayed that the main elements of Fe₃O₄/HBPN were C, N, O, and Fe. The superparamagnetic properties and good magnetic response were revealed by vibrating sample magnetometer (VSM) analysis. The characteristic diffraction peaks of Fe₃O₄/HBPN were observed at 2θ = 30.01 (220), 35.70 (311), 43.01 (400), 56.82 (511), and 62.32 (440), which indicated that the intrinsic phase of magnetite remained. The zeta potential measurement indicated that the surface charge of Fe₃O₄/HBPN was positive in the pH range 4–10. The mass loss of Fe₃O₄/HBPN in thermogravimetric analysis (TGA) proved thermal decomposition. The –C–NH₂ or –C–NH perssad of HBPN were linked and loaded with Fe₃O₄ particles by the N–O bonds. When the Fe₃O₄/HBPN dosage was 2.5 mg/L, pH = 4–5, the kaolin concentration of 1.0 g/L and the magnetic field of 3800 G were the preferred reaction conditions. In addition, a removal efficiency of at least 86% was reached for the actual water treatment. Fe₃O₄/HBPN was recycled after the first application and reused five times. The recycling efficiency and removal efficiency both showed no significant difference five times (p > 0.05), and the values were between 84.8% and 86.9%. Full article

Objective: To compare and determine discriminative magnetic resonance imaging (MRI) findings of idiopathic granulomatous mastitis (IGM) and breast cancer (BC) that present as non-mass enhancement. Materials and Methods: This retrospective study includes 68 IGM and 75 BC cases that presented with non-mass enhancement on breast MRI. All patients with a previous history of breast surgery, radiotherapy, or chemotherapy due to BC or a previous history of mastitis were excluded. On MRI images, presence of architectural distortion skin thickening, edema, hyperintense ducts containing protein, dilated fat-containing ducts and axillary adenopathies were noted. Cysts with enhancing walls, lesion size, lesion location, fistulas, distribution, internal enhancement pattern and kinetic features of non-mass enhancement were recorded. Apparent diffusion coefficient (ADC) values were calculated. Pearson chi-square test, Fisher’s exact test, independent t test and Mann–Whitney U test were used as needed for statistical analysis and comparison. Multivariate logistic regression model was used to determine the independent predictors. Results: IGM patients were significantly younger than BC patients (p < 0.001). Cysts with thin (p < 0.05) or thick walls (p = 0.001), multiple cystic lesions, (p < 0.001), cystic lesions draining to the skin (p < 0.001), and skin fistulas (p < 0.05) were detected more often in IGM. Central (p < 0.05) and periareolar (p < 0.001) location and focal skin thickening (p < 0.05) were significantly more common in IGM. Architectural distortion (p = 0.001) and diffuse skin thickening (p < 0.05) were associated with BC. Multiple regional distribution was more common in IGM, whereas diffuse distribution and clumped enhancement were more common in BC (p < 0.05). In kinetic analysis, persistent enhancement was more common in IGM, whereas plateau and wash-out types were more common in BC (p < 0.001). Independent predictors for BC were age, diffuse skin thickening and kinetic curve types. There was no significant difference in the diffusion characteristics. Based on these findings, MRI had a sensitivity, specificity and accuracy of 88%, 67.65%, and 78.32%, respectively, in differentiating IGM from BC. Conclusions: In conclusion, for non-mass enhancement, MRI can rule out malignancy with a considerably high sensitivity; however, specificity is still low, as many IGM patients have overlapping findings. Final diagnosis should be complemented with histopathology whenever necessary. Full article

The present investigation is focused on exploring the possibilities of identifying biomolecules from the fruiting body of the medicinal mushroom Ganoderma lucidum against the mango anthracnose pathogen Colletotrichum gloeosporioides. The fruiting body (cap and stipe portion) of G. lucidum extracted with ethyl acetate solvent at a maximum inhibitory concentration of 1 percent exhibited the maximum mycelial growth inhibition of C. gloeosporioides with 70.10 percent and 40.77 percent, respectively. Furthermore, subjecting the ethyl acetate extracts from the cap portion of G. lucidum through thin layer chromatography (TLC) revealed the presence of two bands with Rf values of 0.38 and 0.35. The compounds eluted from band 1 recorded with the maximum mycelial growth inhibition of C. gloeosporioides by 53.77 percent followed by band 2 (46.33 percent) using an agar well diffusion test. Similarly, the analysis of ethyl acetate extracts from the cap portion of G. lucidum through Gas Chromatography-Mass spectroscopy (GC-MS) revealed the presence of the organoheterocyclic compound benzothiazole, as expressed in the highest peak area at 22.03 RT with the highest probability percentage (97%). Confirmation of the antifungal nature of benzothiazole was obtained by testing the standard sample of benzothiazole which showed a cent percent of inhibition on mycelial growth of C. gloeosporioides at 50 ppm minimum fungicidal concentration. Furthermore, benzothiazole caused abnormality in the mycelial structures, viz., distortion, shrinkage, clumping of mycelium, conidial malformation, and complete arrestment of conidial germination of C. gloeosporioides as observed through Scanning Electron Microscopy. The research on biomolecular extract of G. lucidum could be a novel and interesting concept for the possibility in suppression of plant pathogenic microbes in the natural field. Full article

The in vitro propagation and ex situ conservation strategy provides new means for the conservation and mass propagation of economically and medicinally important plants. The present work aimed to observe the main characteristics of the in vitro propagation of Garcinia livingstonei from matured seed segments. Successful multiple shoots were induced on a woody plant (WP) medium supplemented with cytokinins. An average of 13.0 shoots per explant were grown from matured seed segments on a WP medium containing 15.0 µM BAP after 12 weeks of culture. The shoot elongation and multiplication were achieved using a repeated and periodic subculturing of shoot clumps in the same medium. The optimum in vitro rooting of shoots was obtained on the half-strength WP medium supplemented with IBA (5.0 µM). The regenerated plantlets were successfully transplanted to pots containing soil, sand, and farmyard manure (1:1:1) and were maintained in a greenhouse with a survival frequency was 80%. Full article

We report a case of a 74-year-old gentleman who presented with floaters and decreased vision in the right eye after cataract surgery. His past medical history was significant for metastatic renal cell carcinoma (mRCC) to bone, lung and abdomen which was presumed stable for the last two years while on the tyrosine kinase inhibitor (TKI), pazopanib. Clinical examination revealed significant vitritis with a distinctive clumping of cells on the pre-retinal surface and posterior hyaloid face. Magnetic resonance imaging of the brain revealed new lesions suspicious for metastases. A diagnostic vitrectomy was performed to determine the nature of the vitritis and clear the visual axis. Cytopathologic evaluation of the vitreous demonstrated clusters of malignant cells that were positive for AE1/AE3 and PAX-8, and negative for the CD20, CD3, RCC, SOX-10 and S-100 immunohistochemical markers. The overall findings favored a metastatic RCC to the vitreous. Choroidal and retinal metastases from mRCC have been previously reported; however, vitreous involvement by mRCC with no evidence of retinal or choroidal mass has not been described. New treatments of mRCC include TKIs which target vascular endothelial growth factor receptors (VEGFRs). Herein, we analyze the factors that could have precipitated this unusual metastasis to the vitreous. Full article

The first objective of this study was to characterize the chemical properties of three lots of whey protein hydrolysate (WPH) obtained from a commercial manufacturer. The degree of hydrolysis (DH) of WPH was between 13.82 and 15.35%, and was not significantly (p > 0.05) different between the batches. From MALDI-TOF, 10 to 13 different peptides were observed in the range of 2.5–5 kDa and 5–8 kDa, respectively. The second objective of the study was to evaluate the effectiveness of WPH as a binder in whey protein isolate (WPI) wet agglomeration. For this purpose, a 3 × 3 × 2 factorial design was conducted with pre-wet mass (60, 100, and 140 g), WPH concentration (15, 20, and 25%), and flow rate (4.0 and 5.6 mL·min⁻¹) as independent variables. WPI agglomeration was carried out in a top-spray fluid bed granulator (Midi-Glatt, Binzen, Germany). Agglomerated WPI samples were stored at 25 °C and analyzed for moisture content (MC), water activity, relative dissolution index (RDI), and emulsifying capacity. Pre-wet mass, flow rate, and the WPH concentration had a significant (p < 0.05) effect on the MC. Moreover, all interactions among the main effects had also a significant (p < 0.05) effect on MC. High MC and water activity were observed for the treatments with a higher pre-wet volume and higher flow rate, which also resulted in clumping of the powders. The treatment with the 60 g pre-wet mass, 20% WPH concentration, and 5.6 mL·min⁻¹ flow rate combination had the highest RDI among all the samples. In conclusion, WPH can be used as a potential alternative to soy lecithin in WPI wet agglomeration. Full article

Using a code that employs a self-consistent method for computing the effects of photo-ionization on circumstellar gas dynamics, we model the formation of wind-driven nebulae around massive stars. We take into account changes in stellar properties and mass-loss over the star’s evolution. Our simulations show how various properties, such as the density and ionization fraction, change throughout the evolution of the star. The multi-dimensional simulations reveal the presence of strong ionization front instabilities in the main-sequence phase, similar to those seen in galactic ionization fronts. Hydrodynamic instabilities at the interfaces lead to the formation of filaments and clumps that are continually being stripped off and mixed with the low density interior. Even though the winds start out as completely radial, the spherical symmetry is quickly destroyed, and the shocked wind region is manifestly asymmetrical. The simulations demonstrate that it is important to include the effects of the photoionizing photons from the star, and simulations that do not include this may fail to reproduce the observed density profile and ionization structure of wind-blown bubbles around massive stars. Full article

Floating wind turbine vibration controlling becomes more and more important with the increase in wind turbine size. Thus, a novel three-bifurcated mooring system is proposed for Spar-type floating wind turbines. Compared with the original mooring system using three mooring lines, three-bifurcated sub-mooring-lines are added into the novel mooring system. Specifically, each three-bifurcated sub-mooring-line is first connected to a Spar-type platform using three fairleads, then it is connected to the anchor using the main mooring line. Six fairleads are involved in the proposed mooring system, theoretically resulting in larger overturning and torsional stiffness. For further improvement, a clump mass is attached onto the main mooring lines of the proposed mooring system. The wind turbine surge, pitch, and yaw movements under regular and irregular waves are calculated to quantitatively examine the mooring system performances. A recommended configuration for the proposed mooring system is presented: the three-bifurcated sub-mooring-line and main mooring line lengths should be (0.0166, 0.0111, 0.0166) and 0.9723 times the total mooring line length in the traditional mooring system. The proposed mooring system can at most reduce the wind turbine surge movement 37.15% and 54.5% when under regular and irregular waves, respectively, and can at most reduce the yaw movement 30.1% and 40% when under regular and irregular waves, respectively. Full article