Search Results (606)

The penetration rate of variable energy sources in the current power grid is increasing, with the aim being to expand the use of these energy sources and to replace the traditional black start power supply. This study investigates the black start of a photovoltaic storage joint system based on the system’s short-circuit ratio threshold. Firstly, the principles and control modes of the photovoltaic (PV) system, energy storage system (ESS), and high-voltage direct current (DC) transmission system are studied separately to build an overall model; secondly, computational determinations of the short-circuit ratio under different scenarios are introduced to analyze the strength of the system, and the virtual inertia and virtual damping of the PV system are configured based on this; finally, the change trend of the storage system’s state of charge (SOC) is computed and observed, and the limits of what the system can support in each stage are determined. An electromagnetic transient simulation model of a black start system is constructed in PSCAD/EMTDC, and according to the proposed recovery strategy, the system frequency is maintained in the range of 49.4~50.6 Hz during the entire black start process; the fluctuation in maximum frequency after the recovery of the DC transmission system is no more than 0.1%; and the fluctuation in photovoltaic power at each stage is less than 3%. In addition, all the key indexes meet the requirements for black start technology, which verifies the validity of the strategy and provides theoretical support and a practical reference for the black start of a grid with variable energy sources. Full article

Dry Turkish oak (Quercus cerris) sawdust, untreated and treated with three activators, (H₃PO₄, NaOH and H₂O₂) was pyrolyzed under limited-oxygen conditions to obtain biochar samples. The electrochemical properties of these samples were tested and compared to the properties of several commercial carbon blacks. The electrochemical characterization was performed via cyclic voltammetry, analyzing the response toward two commonly used redox probes, [Fe(CN)₆]^3−/−4− and [Ru(NH₃)₆]^2+/3+. The influence of the scan rate on this response was investigated, and the resulting data were used to obtain the values of the heterogenous charge transfer constant, k₀. Higher k₀ values were observed for carbon blacks than for investigated biochar samples. The detection of 4-nitrophenol and heavy metal ions was used to assess the applicability of biochars for electroanalytical purposes. The response of untreated biochar was comparable with the response of Vulcan carbon black, which showed the best response of all analyzed carbon blacks. Full article

Background: Self-report physical activity (PA) scales, accelerometry, and heart rate (HR) monitoring are reliable tools for PA measurement for children with cerebral palsy (CP); however, there are limitations for those who are primary wheelchair users. The purpose of our study was to evaluate face and construct validity of the PROMIS^® Pediatric PA parent proxy short form 8a in measuring PA amount and intensity in children with CP who are non-ambulatory. Methods: Face validity: Semi-structured interviews with parents and pediatric physical therapists (PTs) were conducted about the appropriateness of each item on the PROMIS^® Pediatric PA short form. Construct validity: Children with CP who were non-ambulatory participated in a one-week observational study. PA amount and intensity were examined using PA monitors (Actigraph GT9X) and HR monitors (Fitbit Charge 4). Activity counts and time in sedentary and non-sedentary intensity zones were derived and compared to the PROMIS^® T-scaled score. Results: Twenty-two physical therapists (PTs) and fifteen parents participated in the interviews, and ten children completed 1-week PA observation. Eight and seven participants completed sufficient time of uninterrupted PA and HR monitor wear, respectively. Parents and PTs agreed that several questions were not appropriate for children with CP who were non-ambulatory. PA intensity via activity counts derived from wrist worn monitors showed a strong positive correlation with the PROMIS^® PA measure. Conclusions: Construct validity in our small sample was established between PROMIS^® scores and accelerometry activity counts when documenting PA amount and intensity; however, there were some differences on PROMIS^® face validity per parent and PT respondents. Despite some concerns regarding face validity, the PROMIS^® Pediatric PA parent proxy short form 8a shows promise as a valid measure of physical activity amount and intensity in non-ambulatory children with CP, warranting further investigation and refinement. Full article

The widespread adoption of sodium-ion batteries (SIBs) remains constrained by the inherent limitations of conventional anode materials, particularly their inadequate electronic conductivity, limited active sites, and pronounced structural degradation during cycling. To overcome these limitations, we propose a novel redox engineering approach to fabricate oxygen-vacancy-rich SnO₂ dots anchored on reduced graphene oxide (rGO), which are encapsulated within N-doped carbon nanofibers (denoted as ov-SnO₂/rGO@N-CNFs) through electrospinning and subsequent carbonization. The introduction of rich oxygen vacancies establishes additional sodium intercalation sites and enhances Na⁺ diffusion kinetics, while the conductive N-doped carbon network effectively facilitates charge transport and mitigates SnO₂ aggregation. Benefiting from the well-designed architecture, the hierarchical ov-SnO₂/rGO@N-CNFs electrode achieves remarkable reversible specific capacities of 351 mAh g⁻¹ after 100 cycles at 0.1 A g⁻¹ and 257.3 mAh g⁻¹ after 2000 cycles at 1.0 A g⁻¹ and maintains 177 mAh g⁻¹ even after 8000 cycles at 5.0 A g⁻¹, demonstrating exceptional long-term cycling stability and rate capability. This work offers a versatile design strategy for developing high-performance anode materials through synergistic interface engineering for SIBs. Full article

Piezocatalytic therapy (PCT) is a promising strategy for combating implant-associated infections due to its high tissue penetration depth and non-invasive nature. However, its catalytic efficiency remains limited by inefficient electron–hole separation. In this work, an ultrasound-responsive heterojunction (BiOI/Ti₃C₂) was fabricated through in situ growth of bismuth iodide oxide on titanium carbide nanosheets. Subsequently, we integrated BiOI/Ti₃C₂ into poly(e-caprolactone) (PCL) scaffolds using selective laser sintering. The synergistic effect between BiOI and Ti₃C₂ significantly facilitated the redistribution of piezo-induced charges under ultrasound irradiation, effectively suppressing electron–hole recombination. Furthermore, abundant oxygen vacancies in BiOI/Ti₃C₂ provide more active sites for piezocatalytic reactions. Therefore, it enables ultrahigh reactive oxygen species (ROS) yields under ultrasound irradiation, achieving eradication rates of 98.87% for Escherichia coli (E. coli) and 98.51% for Staphylococcus aureus (S. aureus) within 10 minutes while maintaining cytocompatibility for potential tissue integration. This study provides a novel strategy for the utilization of ultrasound-responsive heterojunctions in efficient PCT therapy and bone regeneration. Full article

AISI 347H stainless steel is widely used in high-temperature environments due to its excellent creep strength and oxidation resistance; however, its corrosion performance remains highly sensitive to thermal oxidation, and the effects of thermal history on its passive film stability are not yet fully understood. This study addresses this knowledge gap by systematically investigating the influence of solution treatment on the corrosion and oxidation resistance of AISI 347H stainless steel. The specimens were subjected to solution heat treatment at 1050 °C, followed by air cooling, and then evaluated through electrochemical testing, high-temperature oxidation experiments at 550 °C, and multiscale surface characterization techniques. The solution treatment refined the austenitic microstructure by dissolving coarse Nb-rich precipitates, as confirmed by SEM and EBSD, and improved passive film integrity. The stabilizing effect of Nb also played a critical role in suppressing sensitization, thereby enhancing resistance to intergranular attack. Electrochemical measurements and EIS analysis revealed a lower corrosion current density and higher charge transfer resistance in the treated samples, indicating enhanced passivation behavior. ToF-SIMS depth profiling and oxide thickness analysis confirmed a slower parabolic oxide growth rate and reduced oxidation rate constant in the solution-treated condition. At 550 °C, oxidation was suppressed by the formation of compact, Cr-rich scales with dual-distributed Nb oxides, effectively limiting diffusion pathways and stabilizing the protective layer. These findings demonstrate that solution treatment is an effective strategy to improve the long-term corrosion and oxidation performance of AISI 347H stainless steel in harsh service environments. Full article

ComPair, a prototype of the All-sky Medium Energy Gamma-ray Observatory (AMEGO), completed a short-duration high-altitude balloon campaign on 27 August 2023 from Fort Sumner, New Mexico, USA. The goal of the balloon flight was to demonstrate ComPair as both a Compton and Pair telescope in flight, reject the charged particle background, and measure the background $\gamma$-ray spectrum. This analysis compares measurements from the balloon flight with Monte Carlo simulations to benchmark the instrument. The comparison finds good agreement between the measurements and simulations and supports the conclusion that ComPair accomplished its goals for the balloon campaign. Additionally, two charged particle background rejection schemes are discussed: a soft ACD veto that records a higher charged particle event rate but with less risk of event loss, and a hard ACD veto that limits the charged particle event rate on board. There was little difference in the measured spectra from the soft and hard ACD veto schemes, indicating that the hard ACD veto could be used for future flights. The successes of ComPair’s engineering flight will inform the development of the next generation of ComPair with upgraded detector technology and larger active area. Full article

The urgent demand for sustainable energy solutions in the face of climate change and resource depletion has catalyzed a global shift toward cleaner energy production and more efficient storage technologies. Lithium-ion batteries (LIBs), as the cornerstone of modern portable electronics, electric vehicles, and grid-scale storage systems, are continually evolving to meet the growing performance requirements. In this dynamic context, two-dimensional (2D) materials have emerged as highly promising candidates for use in electrodes due to their layered structure, tunable electronic properties, and high theoretical capacity. Among 2D materials, molybdenum disulfide (MoS₂) has gained increasing attention as a promising low-dimensional candidate for LIB anode applications. This review provides a comprehensive yet concise overview of recent advances in the application of MoS₂ in LIB electrodes, with particular attention to its unique electrochemical behavior at the nanoscale. We critically examine the interplay between structural features, charge-storage mechanisms, and performance metrics—chiefly the specific capacity, rate capability, and cycling stability. Furthermore, we discuss current challenges, primarily poor intrinsic conductivity and volume fluctuations, and highlight innovative strategies aimed at overcoming these limitations, such as through nanostructuring, composite formation, and surface engineering. By shedding light on the opportunities and hurdles in this rapidly progressing field, this work offers a forward-looking perspective on the role of MoS₂ in the next generation of high-performance LIBs. Full article

This paper presents the results of the mathematical modeling and experimental studies of charging a traction lithium-ion battery of a passenger electric car using an integrated charger based on a traction voltage inverter. An original three-stage charging algorithm (3PT/PN) has been developed and implemented, which provides a sequential decrease in the charging current when the specified voltage and temperature levels of the battery module are reached. As part of this study, a comprehensive mathematical model has been created that takes into account the features of the power circuit, control algorithms, thermal effects and characteristics of the storage battery. The model has been successfully verified based on the experimental data obtained when charging the battery module in real conditions. The maximum error of voltage modeling has been 0.71%; that of current has not exceeded 1%. The experiments show the achievement of a realized capacity of 8.9 Ah and an integral efficiency of 85.5%, while the temperature regime remains within safe limits. The proposed approach provides a high charge rate, stability of the thermal state of the battery and a long service life. The results can be used to optimize the charging infrastructure of electric vehicles and to develop intelligent battery module management systems. Full article

This study presents a quantitative electrophysiological method to directly measure the passive transport of ammonium ions through bacterial outer membrane porins. Using a zero-current reversal potential assay in planar lipid bilayers under defined bi-ionic gradients, this study evaluates the permeability of ammonium salts through two general diffusion porins: Omp-Pst2 from Providencia stuartii and OmpF from Escherichia coli. Under matched ionic conditions, Omp-Pst2 exhibited significantly higher ammonium flux—approximately 6000 ions per second per monomer at a 1 µM gradient—compared to ~4000 ions per second for OmpF. Importantly, the identity of the accompanying anion (chloride vs. sulfate) modulated both the ion selectivity and flux rate, highlighting the influence of counterion interactions on porin-mediated transport. These findings underscore how structural differences between porins—such as pore geometry and charge distribution—govern ion permeability. The method applied here provides a robust framework for quantifying nutrient flux at the single-channel level and offers novel insights into how Gram-negative bacteria may adapt their membrane transport mechanisms under nitrogen-limited conditions. This work not only enhances our understanding of outer membrane permeability to small ions like ammonium, but also has implications for antimicrobial strategy development and biotechnological applications in nitrogen assimilation. Full article

To address the challenges of prolonged current isolation times and high dependency on varistors in traditional flexible short-circuit fault isolation schemes for DC systems, this paper proposes a rapid fault isolation circuit design based on an adaptive solid-state circuit breaker (SSCB). By introducing an adaptive current-limiting branch topology, the proposed solution reduces the risk of system oscillations induced by current-limiting inductors during normal operation and minimizes steady-state losses in the breaker. Upon fault occurrence, the current-limiting inductor is automatically activated to effectively suppress the transient current rise rate. An energy dissipation circuit (EDC) featuring a resistor as the primary energy absorber and an auxiliary varistor (MOV) for voltage clamping, alongside a snubber circuit, provides an independent path for inductor energy release after faults. This design significantly alleviates the impact of MOV capacity constraints on the fault isolation process compared to traditional schemes where the MOV is the primary energy sink. The proposed topology employs a symmetrical bridge structure compatible with both pole-to-pole and pole-to-ground fault scenarios. Parameter optimization ensures the IGBT voltage withstand capability and energy dissipation efficiency. Simulation and experimental results demonstrate that this scheme achieves fault isolation within 0.1 ms, reduces the maximum fault current-to-rated current ratio to 5.8, and exhibits significantly shorter isolation times compared to conventional approaches. This provides an effective solution for segment switches and tie switches in millisecond-level self-healing systems for both low-voltage (LVDC, e.g., 750 V/1500 V DC) and medium-voltage (MVDC, e.g., 10–35 kV DC) smart DC distribution grids, particularly in applications demanding ultra-fast fault isolation such as data centers, electric vehicle (EV) fast-charging parks, and shipboard power systems. Full article

Lithium-polymer (LiPo) batteries are valued for their high energy density, stable voltage output, low self-discharge, and strong reliability, making them a popular choice for high-performance and portable applications. Despite these advantages, the charging behavior of LiPo batteries—especially during rapid charging—remains an area with limited understanding. This research examines the electro-thermal characteristics of VARTA LiPo batteries when subjected to high charging currents (2C, 3C, and 4C rates). A temperature-sensitive charging model is developed to address safety and efficiency concerns during fast charging. Experimental data indicate that charging at 45 °C yields the best performance, achieving 80% state of charge (SoC) within 25 min. However, charging at temperatures above or below this level (such as 25 °C) reduces efficiency due to increased internal resistance and accelerated battery aging. The model, validated across a range of temperatures (25 °C, 35 °C, 45 °C, and 60 °C), shows that longer constant-current (CC) charging phases at higher temperatures are associated with lower internal resistance. These results highlight the importance of effective thermal management for optimizing both safety and performance in LiPo battery applications. Full article

Electrospinning has evolved into a vital nanofiber production technique with broad applications across biomedical, environmental, and industrial sectors. Alternating current (AC) and pulsed voltage (PV) electrospinning offer transformative alternatives by utilizing time-varying electric fields to overcome the drawbacks of DC electrospinning by employing an oscillating electric field that facilitates balanced charge dynamics, improved jet stability, and collectorless operation, leading to enhanced fiber alignment and significantly higher production rates, with reports exceeding 20 g/h. Conversely, PV electrospinning applies intermittent high-voltage pulses, offering precise control over jet initiation and termination. This method enables the fabrication of ultrafine, bead-free, and structurally uniform fibers, making it particularly suitable for biomedical applications such as controlled drug delivery and tissue scaffolds. Both techniques support tunable fiber morphology, reduced diameter variability, and improved structural uniformity, contributing to the advancement of high-performance nanofiber materials. This review examines the underlying electrohydrodynamic mechanisms, charge transport behavior, equipment configurations, and performance metrics associated with AC and PV electrospinning. It further highlights key innovations, current limitations in scalability and standardization, and prospective research directions. Full article

As part of the global endeavor to encourage sustainable urban growth and lower carbon emissions, Hail City is leading the way in implementing cutting-edge technologies with which to improve its urban infrastructure. Initiatives for energy resilience and the environment heavily rely on shifting to electric vehicles (EVs). This work describes the strategic planning required to implement a network of solar charging stations and analyzes the parameters that affect this, supporting cleaner transport options. In addition to meeting the growing demand from an increased number of EVs, constructing a network of solar charging stations positions the city as a leader in integrating renewable energy sources into urban areas. A solar electric vehicle charging station (EVCS) will also be designed. This study highlights a competitive attitude in establishing international standards for sustainable practices and critically examines the technical factors affecting the required charging stations. Regarding the latter, the following results were obtained. The ideal number of station slots is 200. Less efficient vehicles with higher consumption rates require a more comprehensive charging infrastructure, and increasing the charging power leads to an apparent decrease in the number of stations. The influence of battery capacity on the required NSs is limited, especially at charger power values above 30 kWh. By taking proactive measures to address these factors, Hail City hopes to improve its infrastructure effectively and sustainably, keeping it competitive in a world where cities are increasingly judged on their ability to adopt new technology and green projects. A solar station was designed to supply the EVCS with a capacity of 700.56 kWp. Full article

This study focuses on the structural and electrochemical behavior of the compound ZnLaFeO₄ as a negative electrode material for nickel–metal hydride (Ni-MH) batteries. The material was synthesized by a sol–gel hydrothermal method to assess the influence of lanthanum doping on the ZnFe₂O₄ spinel structure. X-ray diffraction revealed the formation of a dominant LaFeO₃ perovskite phase, with ZnFe₂O₄ and La₂O₃ as secondary phases. SEM analysis showed agglomerated grains with an irregular morphology. Electrochemical characterization at room temperature and a discharge rate of C/10 (full charge in 10 h) revealed a maximum discharge capacity of 106 mAhg⁻¹. Although La³⁺ doping modified the microstructure and slowed the activation process, the electrode exhibited stable cycling with moderate polarization behavior. The decrease in capacity during cycling is due mainly to higher internal resistance. These results highlight the potential and limitations of La-doped spinel ferrites as alternative negative electrodes for Ni-MH systems. Full article