Search Results (37)

Main-chain conjugated and non-conjugated polyelectrolytes are an important class of materials that have many technological applications ranging from fire-retardant materials to carbon-nanotube composites, nonlinear optical materials, electrochromic materials for smart windows, and optical sensors for biomolecules. Here, we describe a series of poly(pyridinium salt)s-fluorene containing 9,9-bis(4-aminophenyl)fluorene moieties with various organic counterions that were synthesized using ring-transmutation polymerization and metathesis reactions, which are non-conjugated polyelectrolytes. Their chemical structures were characterized by Fourier transform infrared (FTIR), proton (¹H) and fluorine 19 (¹⁹F) nuclear magnetic resonance (NMR) spectrometers, and elemental analysis. They exhibited polyelectrolytic behavior in dimethyl sulfoxide. Their lyotropic liquid-crystalline phases were examined by polarizing optical microscopy (POM) and small angle X-ray scattering (SAXS) studies. Their emission spectra exhibited a positive solvatochromism on changing the polarity of solvents. They emitted greenish-yellow lights in polar organic solvents. They formed aggregates in polar aprotic and protic solvents with the addition of water (v/v, 0–90%), whose λ_em peaks were blue shifted. Full article

We propose a new type of flexible transistor based on carbon-nanotube (CNT) composite thread (CNTCT), i.e., a thread transistor, with ionic gel. In our previous study, we demonstrated that transistor operation was possible by combining metallic and semiconducting CNTCTs as gate and channel with an insulating material. However, its performance was not sufficient. Therefore, we here aim to improve it. For this, we tried to apply ionic gel as a dielectric layer to it. With this, the transistor was expected to be an electric-double-layer transistor. The transistor performance was improved, and the on/off ratio of the transistor increased by more than 4. This is a large value compared to our previous work. In addition, we not only evaluated the performance of the transistors, but also investigated whether they could be used as logic circuits. It was confirmed that the logic circuit composed of the thread transistor also operated correctly and stably for a long period of time. It was also confirmed that the output changed in response to weak external forces. These results indicate that it is a flexible transistor that can be used in a wide range of applications such as logic circuits and sensors. Full article

Simulation of the behavior of carbon nanotubes (CNTs) can become a very challenging task considering their complicated shape and large aspect ratio. This study aims to elucidate the role of CNT shape, length, and connectivity during heat transfer in CNT dispersions through a three-dimensional (3D) simulator. Three characteristic shapes for the CNTs are considered, namely, straight, moderately curved, and strongly curved. The results reveal that the commonly used assumption of viewing CNTs as straight cylinders leads to significant overestimation of the overall medium conductivity. The CNT length has an important effect on the nanofluid conductivity for all types of CNT shapes considered here. In addition, use of CNTs with higher conductivity than a certain value appears to have no further beneficial effect, thus relaxing the need for extremely pure or single-wall CNTs. On the contrary, the conductivity remains a strong function of the CNT concentration and may be even increased upon organization of CNTs into loose clusters. The overall approach and concept can be extended to CNT composites in a straightforward manner. Full article

We propose a new type of CNT hydrogel that has unique conductive and reversible characteristics. We found in previous studies that CNT dispersions became gelatinous without any gelators when a specific CNT was combined with a specific dispersant. This hydrogel has conductive properties derived mainly from the CNTs it contains; and even after gelation, it can be returned to a liquid state by ultrasonic irradiation. Furthermore, the liquid is gelable again. In this study, we prepared several types of CNTs and several types of dispersants, experimentally verified the possibility of gelation by combining them, and geometrically investigated the gelation mechanism to determine how this unique hydrogel is formed. As a result, we found that the experimental results and the theory examined in this study were consistent with the combination of materials that actually become hydrogels. We expect that this study will allow us to anticipate whether or not an unknown combination of CNTs and dispersants will also become gelatinous. Full article

In this work, a ferrocene-containing gallic acid-derivative modified carbon-nanotube paste electrode (Gal-Fc-CNT), obtained through simple mechanical mixing, was studied for the fast simultaneous voltammetric determination of doxorubicin (DOX), capecitabine (CPB), and cyclophosphamide (CPP) as cytostatic indices based on their cumulative signals and the selective determination of DOX. The individual and simultaneous electrochemical behavior of DOX, CPB, and CPP, studied through cyclic voltammetry (CV) on the Gal-Fc-CNT paste electrode at various pHs and potential ranges, allowed for the development of a simple simultaneous determination method as a cytostatic index at a pH of 12 using square-wave voltammetry, which allowed for a better performance than reported electrodes for each individual cytostatic. A faster and selective detection of DOX, with a limit of detection of 75 ng·L⁻¹, was achieved using square-wave voltammetry at a pH of 3. The good results obtained for the real tap water assessment indicated the applicability of the Gal-Fc-CNT paste electrode for practical applications (water samples). Full article

We propose a unique form of dye-sensitized solar cells (DSSCs), paper DSSCs based on carbon-nanotube (CNT) composite papers, and the use of a gel electrolyte for the paper DSSC. In our previous study, we succeeded in developing the paper DSSC. However, its performance and lifetime were not sufficient. We considered that the problem was the use of liquid-type electrolyte. To improve the performance of the paper DSSC, a gel electrolyte was introduced to increase safety and durability. Here, a polymer gel electrolyte was synthesized using a copolymer of polyethylene glycol (PEG) and polyvinylidene fluoride (PVDF) as a matrix, mixed with iodine and potassium iodide. The resulting paper DSSC had a fill factor (FF, a performance indicator) of 0.248 and a conversion efficiency of 2.43 × 10⁻⁵% with an extended working time (lifetime) of more than 110 min. Further modifications were made to the metallic CNT composite paper and the gel electrolyte, resulting in an increased conversion efficiency of 2.02 × 10⁻³%. This study suggests the potential of gel electrolytes in enhancing the performance of paper DSSCs, providing new insights for their future applications. Full article

Serotonin (5-HT) is a neurotransmitter involved in many biophysiological processes in the brain and in the gastrointestinal tract. Electrochemical methods are commonly used to quantify 5-HT, but their reliability may suffer due to the time-dependent nature of adsorption-limited 5-HT detection, as well as electrode fouling over repeated measurements. Mathematical characterization and modeling of adsorption-based electrochemical signal generation would improve reliability of 5-HT measurement. Here, a model was developed to track 5-HT electrode adsorption and resulting current output by combining Langmuir adsorption kinetic equations and adsorption-limited electrochemical equations. 5-HT adsorption binding parameters were experimentally determined at a carbon-nanotube coated Au electrode: K_D = 7 × 10⁻⁷ M, k_on = 130 M⁻¹ s⁻¹, k_off = 9.1 × 10⁻⁵ s⁻¹. A computational model of 5-HT adsorption was then constructed, which could effectively predict 5-HT fouling over 50 measurements (R² = 0.9947), as well as predict electrode responses over varying concentrations and measurement times. The model aided in optimizing the measurement of 5-HT secreted from a model enterochromaffin cell line—RIN14B—minimizing measurement time. The presented model simplified and improved the characterization of 5-HT detection at the selected electrode. This could be applied to many other adsorption-limited electrochemical analytes and electrode types, contributing to the improvement of application-specific modeling and optimization processes. Full article

Owing to the increasing construction of new buildings, the increase in the emission of formaldehyde and volatile organic compounds, which are emitted as indoor air pollutants, is causing adverse effects on the human body, including life-threatening diseases such as cancer. A gas sensor was fabricated and used to measure and monitor this phenomenon. An alumina substrate with Au, Pt, and Zn layers formed on the electrode was used for the gas sensor fabrication, which was then classified into two types, A and B, representing the graphene spin coating before and after the heat treatment, respectively. Ultrasonication was performed in a 0.01 M aqueous solution, and the variation in the sensing accuracy of the target gas with the operating temperature and conditions was investigated. As a result, compared to the ZnO sensor showing excellent sensing characteristics at 350 °C, it exhibited excellent sensing characteristics even at a low temperature of 150 °C, 200 °C, and 250 °C. Full article

In this paper, poly-ether-ether-ketone (PEEK) carbon-nanotube (CNT) self-monitoring composites at different levels of filler loading (i.e., 3, 5 and 10% by weight) have been extruded as 3D-printable filaments, showing gauge factor values of 14.5, 3.36 and 1.99, respectively. CNT composite filaments of 3 and 5 wt% were 3D-printed into tensile samples, while the PEEK 10CNT filament was found to be barely printable. The 3D-printed PEEK 3CNT and PEEK 5CNT composites presented piezo-resistive behavior, with an increase in electrical resistance under mechanical stress, and showed an average gauge factor of 4.46 and 2.03, respectively. Mechanical tests highlighted that 3D-printed samples have a laminate-like behavior, presenting ultimate tensile strength that is always higher than 60 MPa, hence they offer the possibility to detect damages in an orthogonal direction to the applied load wit high sensitivity. Full article

Aluminum alloys are becoming increasingly significant in the manufacturing industry due to their light weight and durable properties. Widely applied in aerospace and construction, precision machining is required to ensure the best possible surface quality. The surface quality of a machined component is directly affected by the tool wear incurred during machining. This research investigated the effect of process parameters and machining conditions on tool wear. The critical process parameters selected were cutting speed, feed rate, and depth of cut. Multi-walled carbon nanotube particles were dispersed in a base fluid of mineral oil to create a new lubricant applied during machining. Pure mineral oil was also used as a lubricant to reduce friction. Machining experiments were carried out with the two lubricants, and the tool wear incurred was measured and compared using a Dinolite microscope. All experiments were carried out with high-speed steel (HSS) cutting tools. Taguchi’s L9 orthogonal array was employed as a methodology to design the experiments. A finite-element 3D simulation was also carried out using DEFORM-3D to provide a scientific explanation of the turning process. Results showed a significant reduction in tool wear when machining with multi-walled carbon nanotubes (MWCNTs), with an average reduction of 14.8% compared to mineral oil. The depth of cut was also the most influential process parameter in terms of tool wear. Full article

Oil leaks (or spills) into the aquatic environment are considered a natural disaster and a severe environmental problem for the entire planet. Samples of polyurethane (PU) composites were prepared with high specific surface area carbon nanotubes (CNT) to investigate crude oil sorption. Scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FT-IR), density measurements, and mechanical compression tests were used to characterize the polyurethane-carbon PU–CNT prepared samples. The spongy composites exhibited good mechanical behavior and a contact angle of up to 119°. The oleophilic character resulted in increased hydrophobicity, a homogeneous oil distribution inside the sponge, and a sorption capacity in a water/oil mixture of 41.82 g/g. Stress-strain curves of the prepared samples showed the good mechanical properties of the sponge, which maintained its stability after more than six sorption desorption cycles. The CNT–PU composites may prove very effective in solving oil pollution problems. Full article

Carbon-nanotube (CNT) is a promising material owing to its compelling mechanical, thermal and electrical properties and has been applied in a broad variety of fields such as composite, fiber, film and microelectronic. Although the introductions of CNT have brought huge improvement for many applications, these properties of macrostructures prepared by CNTs still cannot meet those of individual CNT. Disordered alignment of CNTs in the matrix results in degradation of performance and hinders further application. Nowadays, quantities of methods are being researched to realize alignments of CNTs. In this paper, we introduce the application of CNTs and review some typical pathways for vertical and horizontal alignment, including chemical vapor disposition, vertical self-assembly, external force, film assisted, electric field, magnetic field and printing. Besides that, advantages and disadvantages of specific methods are also discussed. We believe that these efforts will contribute to further understanding the nature of aligned CNT and generating more effective ideas to the relevant workers. Full article

This work considers the ability of carbon-nanotube (CNT)-coated plasma to inactivate bioaerosols. Escherichia coli (E. coli) and λ virus phage were chosen as the challenge bioaerosols. A test chamber was used to simulate an indoor environment and to control the air exchange rate (ACH). The results demonstrated that CNT-coated plasma had a significant antimicrobial effect on both bacterial and viral bioaerosols. The experimental results revealed that CNT-coated plasma under an operating voltage of 6.0 kV and an ACH of 0.5 h⁻¹ had significantly higher bioaerosol inactivating ability (k_CNT, 0.24 and 0.23 min⁻¹ for E. coli and λ virus phage, respectively) compared to the results without using CNT-coated plasma (k_n, 0.09 and 0.08 min⁻¹ for E. coli and λ virus phage, respectively). Under the higher ACH condition, the system demonstrated higher bioaerosol removal efficiency due to the mechanical effect of clean air exchange. Increasing flow rate and operating voltage could raise the inactivating ability of the CNT-coated plasma system. A CNT-coated plasma air-cleaning device was tested in a real indoor medical environment and yielded bacterial bioaerosol removal efficiency in the range from 70% to 80% within 6 h of operation (7.5 Lpm and 6.0 kV), which suggests that CNT-coated plasma treatment has the potential for further application in improving indoor air quality. Full article

Interfacial conductivity and “L_c”, i.e., the least carbon-nanotube (CNT) length required for the operative transfer of CNT conductivity to the insulated medium, were used to establish the most effective CNT concentration and portion of CNTs needed for a network structure in polymer CNT nanocomposites (PCNT). The mentioned parameters and tunneling effect define the effective conductivity of PCNT. The impact of the parameters on the beginning of percolation, the net concentration, and the effective conductivity of PCNT was investigated and the outputs were explained. Moreover, the calculations of the beginning of percolation and the conductivity demonstrate that the experimental results and the developed equations are in acceptable agreement. A small “L_c” and high interfacial conductivity affect the beginning of percolation, the fraction of networked CNTs, and the effective conductivity. Additionally, a low tunneling resistivity, a wide contact diameter, and small tunnels produce a highly effective conductivity. The developed model can be used to optimize breast cancer cell sensors. Full article