Search Results (1,543)

Lightweight polymer composites with effective electromagnetic interference (EMI) shielding are of increasing interest for advanced electronic and aerospace applications; however, conventional glass fiber-reinforced polymers (GFRPs) exhibit inherently low electrical conductivity, limiting their shielding performance. In this study, a hierarchical hybrid conductive architecture was developed by integrating graphene-coated multiaxial glass fiber fabrics with carbon black (CB)-reinforced epoxy matrices to enhance EMI shielding behavior in the X-band (8–12 GHz). Graphene coatings were deposited onto glass fibers via a surfactant-assisted ultrasonic dispersion method, while carbon black (0–1 wt.%) was incorporated into the epoxy matrix using ultrasonication-assisted mixing. Multilayer composites were fabricated using a vacuum bagging process. X-ray diffraction analysis revealed that the composites retained a predominantly amorphous epoxy/glass fiber matrix while exhibiting broad carbon-related diffraction features associated with disordered graphitic domains. Electrical conductivity measurements indicated that all composites remained in the insulating regime (~10⁻⁹ S/m), suggesting that a fully interconnected conductive network was not established within the investigated filler range. Despite the absence of a continuous conductive network, measurable EMI shielding performance was achieved. The composite containing 0.25 wt.% CB exhibited the highest shielding effectiveness, reaching approximately 12 dB at ~11.2 GHz. Analysis of the shielding contributions showed that absorption contributions (SEA) were consistently higher than reflection contributions (SER) across the studied frequency range. Morphological observations revealed that well-dispersed CB at low loading facilitated the formation of localized conductive domains that may contribute to tunneling-assisted polarization and interfacial charge accumulation. At higher CB contents, particle agglomeration reduced dispersion quality and limited effective pathway formation, while dynamic mechanical analysis indicated enhanced stiffness at low CB loading. FTIR results confirmed the absence of new chemical bonding, indicating that CB acts as a physically dispersed conductive filler. Overall, the results show that effective EMI shielding can be achieved in electrically insulating composites through the combined effect of hierarchical structural design and localized conductive features. This approach provides a practical pathway for developing lightweight EMI shielding materials with controlled filler loading and preserved structural integrity for aerospace and electronic applications. Full article

Aiming to develop high-performance flexible electrode materials for dielectric elastomer actuation systems applied to micro-crawling robots, this study proposes multi-dimensional filler composite electrode materials with a methyl vinyl silicone rubber matrix. Three types of conductive fillers—namely, zero-dimensional super-conductive carbon black, one-dimensional single-walled carbon nanotubes, and two-dimensional flaky micron-sized silver powder—were employed to construct a hierarchical multi-dimensional conductive network within the silicone rubber matrix via a three-stage fabrication strategy. The electrical conductivity and conductive stability of the as-prepared composite electrode materials were systematically investigated, where the intrinsic mechanisms and evolutionary laws of material electrical performance variations were analyzed. Furthermore, the effects of fillers with different dimensional morphologies on the comprehensive properties of the composites at each fabrication stage were explored, and the optimal filler dosage for each component was determined. Microstructural observations of the staged conductive network formation further verified the rationality of the stage-based functional design model. The optimized composite electrode delivers an initial electrical conductivity of 1.5 × 10⁴ S/m, with only a 14.9% conductivity attenuation under 50% tensile strain, demonstrating excellent electromechanical stability. Moreover, a prototype micro-crawling robot was fabricated using the optimized composite electrode, achieving a maximum linear crawling speed of 8 mm/s. These experimental results validate the feasibility and superiority of the proposed multi-dimensional filler composite strategy. This work provides a novel technical approach for the design and development of high-performance flexible electrode materials for flexible electronic and micro-robotic actuation applications. Full article

Silts are generally unsuitable for direct use as subgrade fill material due to their low shear strength and deformation resistance. In this study, a novel technique for strengthening silt using enzyme-induced calcium carbonate precipitation (EICP) with the addition of non-fat milk powder is proposed to improve the mechanical properties of silt for use as subgrade fill material. The effect of EICP on the mechanical properties of silt, in terms of internal friction angle and shear strength, was examined through consolidated undrained (CU) triaxial shear tests. The results showed that, with the EICP technique involving non-fat milk powder, the mechanical behaviors of silts were significantly enhanced due to the improved bonding ability of the silt particles. Furthermore, an optimum content of non-fat milk powder of 6 g/L is proposed to increase the mechanical properties. Compared with EICP treatment alone, under the optimum condition of 6 g/L non-fat milk powder and 14 days of curing, the shear strength, cohesion, and internal friction angle increased by 44.1%, 51.86%, and 31.4%, respectively. Finally, microstructural analyses were conducted using Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD) to provide insight into the mechanisms underlying the improvement of silt. The findings of this study can provide guidance for the application of silt improvement through the EICP technique involving non-fat milk powder. Full article

The spatial organization of microscale fillers is critical for macroscopic performance, yet precise control over their distribution and orientation remains a major challenge in direct ink writing. Here, we present an acoustofluidic capillary nozzle that integrates acoustic manipulation into direct ink writing, enabling programmable in situ assembly of functional fillers during extrusion. By coupling a piezoelectric transducer with a commercial glass capillary, stable acoustic standing waves are established within the flow channel, driving suspended filler particles toward pressure nodes via acoustic radiation forces. Simulations and experiments systematically investigate how capillary geometry and material properties influence acoustic energy distribution and particle assembly behavior. In particular, rectangular capillaries generate stable multi-node standing waves, inducing periodic alignment of nickel-coated carbon fibers into ordered conductive bundles. This acoustically programmed microstructure reduces the percolation threshold from 8 wt% to 2 wt% and enhances electrical conductivity by up to 32.1-fold at identical filler contents. Meanwhile, the composites exhibit pronounced anisotropic conductivity and maintain excellent mechanical flexibility, with stable electromechanical performance under 16% bending strain and cyclic loading. This work demonstrates a simple and scalable acoustofluidic nozzle platform for programmable microstructure engineering in direct ink writing, offering new opportunities for fabricating high-performance multifunctional composites. Full article

Polyhydroxyalkanoates (PHAs) are bio-based, biodegradable polyesters increasingly explored as sustainable biomaterials for regenerative medicine. This review summarizes recent advances in PHA-based bone substitute materials, highlighting their properties, fabrication methods, and biological performance. PHAs combine biocompatibility, tunable mechanical behavior, and degradation into non-toxic metabolites, while copolymerization and monomer selection modulate the stiffness, crystallinity, and resorption rate. Processing techniques such as solvent casting, electrospinning, and additive manufacturing allow the production of porous architectures that mimic bone extracellular matrix. Electrospinning is particularly suitable for nanoscale fibrous matrices, whereas 3D printing enables patient-specific scaffolds with controlled geometry and interconnected porosity. Scaffold performance can be further improved through the incorporation of osteoconductive fillers, including hydroxyapatite, β-tricalcium phosphate, bioactive glasses, graphene oxide, and carbon nanotubes, as well as through drug-delivery and pro-angiogenic functionalization. In vitro and in vivo studies consistently report favorable cytocompatibility, enhanced osteogenic differentiation, vascularization, and effective repair of bone defects in animal models. However, clinical translation remains limited by production costs, variability in polymer quality, thermal processing constraints, and regulatory challenges. Future progress will rely on more efficient biosynthesis, medical-grade purification, multifunctional scaffold design, and stronger collaboration between academia, industry, and clinicians to unlock the full potential of PHAs in regenerative bone therapies. Full article

Two-dimensional nanomaterials exhibit excellent physical barrier properties, which can effectively enhance the corrosion resistance of waterborne epoxy coatings. Herein, we report a facile strategy for preparing a multi-component synergistic anti-corrosion coating, where two-dimensional graphitic carbon nitride (g-C₃N₄) and high-entropy layered double hydroxides (HE-LDHs) are integrated into a waterborne epoxy matrix via magnetic-ultrasonic synergistic dispersion. The resulting HE-LDHs/g-C₃N₄-epoxy coating exhibits exceptional corrosion resistance for Q235 steel. Electrochemical impedance spectroscopy (EIS) and polarization curves showed that when the mass ratio of g-C₃N₄ to HE-LDHs was 1:1, the resulting coating (PCN-LDH-1.0) maintained a coating resistance of 5.48 × 10⁵ Ω·m² after 28 days of immersion in 3.5% NaCl solution, which was five orders of magnitude higher than that of pure waterborne epoxy coating. Meanwhile, the corrosion current density was reduced by four orders of magnitude, from 5.83 × 10⁻¹ A·m⁻² to 1.68 × 10⁻⁵ A·m⁻². After 30 days of salt spray testing, no rust, blistering or adhesion loss was observed on the coating surface. These enhanced performances by addition of g-C₃N₄ and HE-LDHs were attributed to the combined effects of the tortuous diffusion pathways. Additionally, the PCN-LDH-1.0 coating retained excellent mechanical properties, including a pencil hardness of 3H and the highest adhesion grade. This study provides a facile method for preparing high-performance waterborne anti-corrosion coatings. Full article

Five modifications of polytetrafluoroethylene (PTFE) are considered as a modern alternative to PTFE as sliding layers of bridge bearing parts. Radiation-modified PTFE without additives and with nano-additives as well as composites based on PTFE with bronze inclusions and nanomodified carbon fiber fillers were investigated. Ultra-high-molecular-weight polyethylene (UHMWPE) and classic pure PTFE were considered as control samples. The thermomechanical properties of the materials were studied within the framework of dynamic mechanical analysis in the operating temperature range of bridge structures [−40; +80] °C. The exit zones from the linear theory of viscoelasticity were established for all the materials considered. Temperature dependencies of the storage modulus and the loss modulus were determined. Thermoviscoelastic models of material behavior were constructed using a numerical identification procedure, experimental data, and simulation models. The thermomechanics of materials during the deformation of the spherical support part of the bridge were analyzed. Temperature dependencies of the parameters of the contact stress-strain state were determined with an average coefficient of determination R² = 0.97 and an average error size RMSE = 0.092. Full article

Carbon/inorganic hybrid composites have evolved from filler-reinforced materials into design platforms for coupled electromagnetic, thermal, sensing, environmental, protective and energy-related functions. Their distinctive value lies in the possibility of combining a conductive, polarizable or porous carbon phase with an inorganic phase that contributes dielectric, magnetic, catalytic, ionic, thermally conductive or barrier behavior. This review examines carbon/inorganic hybrid multifunctional composites from the viewpoint of structure–property relationships, with emphasis on interfacial design, percolation, anisotropy, hierarchical architecture, processing and metrology. Selected graphitic composite studies are discussed as case studies for broadband dielectric spectroscopy, microwave shielding, high-frequency contact metrology, thermal diffusivity analysis and impedance-monitored graphene filters; these case studies are integrated with the broader international literature on CNT and graphene polymer composites, MXene films and foams, graphene/metal oxide photocatalysts, boron nitride/carbon thermal networks, biochar–graphene adsorbents, smart coatings, sensors, supercapacitors and water remediation systems. The central argument is that credible multifunctionality requires more than measuring several properties on the same material. It requires simultaneous or service-relevant co-optimization under constraints of thickness, density, processability, aging, humidity, corrosive media, regeneration, toxicity, economic feasibility and scalable fabrication. The review concludes with design rules and reporting recommendations intended to help move the field from impressive property demonstrations toward application-ready hybrid material systems. Full article

Various forms of Bacopa monnieri (BM), including original powder (Mp), tea form (Mo), and post-extraction residues (Mf), were used as natural bio-based additives in rigid polyurethane–polyisocyanurate (RPU/PIR) foams. The study investigated the influence of BM form and content on the physical, mechanical, thermal, and flammability properties of the foams. The results demonstrated that both the type and concentration of BM significantly affected foam performance. Foams containing Mf exhibited the lowest apparent density and reduced brittleness, whereas foams modified with Mp showed the highest compressive strength. The incorporation of BM also contributed to reduced flammability and enhanced thermal resistance of the foams. Thermal analysis indicated that BM additives modified the degradation behavior of RPU/PIR foams by promoting char formation and improving thermal stability at elevated temperatures. In particular, samples containing tea and post-extraction residues showed increased stability of the carbonized residue during the final degradation stage. The most favorable overall properties were obtained for BM contents between 3 and 7 wt%, while higher filler concentrations negatively affected the structural integrity of the foam matrix. The results confirm that the performance of RPU/PIR foams strongly depends on the balance between matrix continuity and biofiller functionality. The obtained materials show potential for application in floristry products and lightweight insulating systems where low density, dimensional stability, and enhanced thermal resistance are required. Full article

The development of multifunctional biomaterials for bone repair requires precursors that combine bioactivity, moderate antimicrobial growth-inhibitory effect, and imaging. This study demonstrates the multifunctional versatility of a single family of rare-earth-doped β-tricalcium phosphates (β-TCPs), Ca₉Eu(PO₄)₇ and Ca₉Dy(PO₄)₇, across three distinct formats: bioactive thin films (for implant coatings), brushite cements (for injectable bone fillers), and radiopaque PMMA bone composites (for load-bearing applications). This work serves as a proof-of-concept that the same doped phosphate precursors can address different clinical needs while retaining bioactivity, antimicrobial properties, and radiopacity. The phosphate precursors were synthesized via solid-state reaction. Pulsed laser deposition (PLD) was used to form amorphous, dense, and crack-free coatings, which exhibited excellent in vitro bioactivity through the rapid dissolution–reprecipitation of a carbonated apatite layer in simulated body fluid. The brushite-based bone cements were produced from doped β-TCPs. These cements demonstrated high cytocompatibility with mesenchymal stromal cells (>89% viability) and significantly enhanced osteogenic differentiation with antimicrobial activity against common pathogens (S. aureus, E. coli, P. aeruginosa). Furthermore, incorporation of these phosphates as fillers into PMMA bone cement resulted in a homogeneous particle distribution with reduced agglomeration compared to undoped β-TCPs, achieving clinically relevant radiopacity values (913 ± 22.4 HU for Dy-doped sample). Post-mortem studies by the CT method were performed on the vertebrae with PMMA–phosphate composites and brushite cements. It was shown that brushite cement in ovine lumbar vertebrae defects exhibited the highest radiopacity (1450–1550 ± 25 HU). The findings establish rare-earth-doped β-TCP as a unified multifunctional precursor that imparts bioactivity, the ability to support in vitro mineralization, antimicrobial properties, and enhanced radiopacity to thin films, phosphate cements, and polymer composite materials. Full article

Electrically conductive polymer composites (ECPCs) have attracted growing interest in applications requiring lightweight, processable, and electrically functional materials. Their increasing use has created a strong need for reliable models capable of predicting electrical conductivity from component properties, composite composition, and microstructural features. Although classical percolation theory can describe the sharp increase in conductivity near the percolation threshold, it is often insufficient for predicting conductivity over a wider range of filler concentrations or for distinguishing the underlying conduction mechanisms. This review examines the main modeling approaches used for carbon-filled polymer composites, including percolation-centered, homogenization, network-based, and data-driven models. These approaches are compared in terms of their assumptions, required inputs, strengths, and limitations, with emphasis on how they account for filler morphology, orientation, dispersion, tunneling effects, and conductive-network formation. The review also identifies key challenges and future needs, particularly the development of integrated, orientation-sensitive, and physically informed models for predicting anisotropic electrical conductivity in processed ECPCs. Full article

The present study addresses the fabrication of porous gyroid architectures by additive manufacturing from preceramic polymer feedstocks. Photocurable emulsions were engineered by combining a silicone powder with acrylate monomers and dispersing an emulsified secondary phase of calcium nitrate. The formulations showed light-curing behaviour compatible with digital light processing vat photopolymerization (DLP-VPP), enabling high-fidelity replication of triply periodic minimal surface (TPMS) gyroids (designed porosity: 85 vol.%). After pyrolysis in nitrogen at 700 °C, the lattices converted into CaO–SiO₂-derived amorphous matrices embedding an in situ turbostratic/pyrolytic carbon fraction, as suggested by the photothermal response and preliminary impedance behaviour, although the latter was measured in liquid electrolyte and therefore does not isolate electronic transport. To improve robustness during polymer-to-ceramic conversion, pharmaceutical borosilicate waste glass (BASG) was added as a passive filler (30–70 wt.%). The waste-glass phase acts as a passive filler that improves processing robustness and can mitigate shrinkage-induced damage during pyrolysis, while remaining electrically insulating (dielectric) and therefore not directly contributing to electronic conduction. The resulting structures combine high surface-to-volume ratio, controlled open porosity, and structural integrity with electrochemical responsiveness under the adopted test conditions, making them promising architected platforms for electrochemical components where interconnected porosity is advantageous. Full article

Seed pelleting improves seed handling and precision sowing, but its performance depends strongly on the physicochemical properties of filler materials. This study evaluated the effects of talc-based mineral filler combinations on pellet characteristics, germination, greenhouse emergence, seed vigor, and seedling growth of Chinese cabbage (Brassica rapa L. var. pekinensis). Talc (TC) was used alone or combined with bentonite (BE), calcium carbonate (CC), and diatomaceous earth (DE). Pellet physical properties, morphology, and surface elemental composition were analyzed using hardness measurements, porosity analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. TC + BE exhibited excessive swelling-driven water retention, prolonged disintegration time, and severe surface cracking, which were associated with reduced germination, delayed emergence, and poor seed vigor. In contrast, TC + CC + DE showed balanced physicochemical properties, including adequate hardness, moderate porosity, acceptable disintegration time, and improved water-holding capacity, producing superior greenhouse emergence while maintaining seedling growth comparable to the unpelleted control. Overall, successful seed pelleting depended on balancing structural integrity, water retention, and mass transfer properties within the pellet matrix. TC + CC + DE appears to be a promising formulation for Chinese cabbage seed pelleting. Full article

This study aims to develop sustainable conductive nanocomposites based on poly(lactic acid) (PLA)/poly(ε-caprolactone) (PCL) blends reinforced with multi-walled carbon nanotubes (MWCNT) and graphene nanoplatelets (G), focusing on their multifunctional performance. The novelty lies in the production of hybrid nanocomposites based on PLA/PCL blends with MWCNT/G using conventional industrial processing techniques, enabling the development of eco-friendly nanocomposites with tailored electrical, mechanical, and electromagnetic properties. The nanocomposites were prepared by twin-screw extrusion followed by injection molding. Rheological, scanning electron microscopy (SEM), mechanical, thermal, thermomechanical, electrical conductivity, and electromagnetic shielding properties were systematically evaluated. From a rheological perspective, the PLA/PCL/MWCNT and PLA/PCL/MWCNT/G nanocomposites exhibited a plateau at low frequencies, associated with the formation of a percolated network. This was confirmed by the significant increase in electrical conductivity and electromagnetic shielding response. The morphology observed by SEM showed a refinement of the PCL phase in the PLA matrix with the incorporation of MWCNT. The PLA/PCL/MWCNT/G (4/2 parts per hundred resin, phr) nanocomposite showed a 309% increase in impact strength compared to neat PLA, while maintaining the heat deflection temperature (HDT). The elastic modulus exceeded 2300 MPa and accelerated the crystallization process by more than 15 °C compared to PLA, which makes it important to reduce injection molding time. Additionally, it exhibited the highest electrical conductivity level, around 6.79 × 10⁻⁵ S/cm, which resulted in improved electromagnetic shielding performance in the 8.2–18 GHz range, highlighting the synergistic effect between 1D and 2D fillers. The developed PLA/PCL/MWCNT and PLA/PCL/MWCNT/G nanocomposites demonstrate potential for antistatic applications, combining sustainability with multifunctional performance and industrial scalability. Full article

This study investigated the feasibility of using hydroxyapatite (HAp) derived from pyrolyzed waste chicken bones as a sustainable cement replacement material for cement mortar. Commercial tricalcium phosphate (TCP), which belongs to the same calcium phosphate family but possesses distinct crystalline characteristics, was used as a comparative material. HAp and TCP were incorporated as partial cement replacements at 2, 5, 10, and 20% by weight, and the workability, compressive strength, flexural strength, microstructure, and CO₂ emission characteristics of the resulting mortars were evaluated. The results showed that low replacement ratios improved early-age strength owing to the micro-filler effect of fine calcium phosphate particles. In particular, the HAp mixtures exhibited superior long-term performance compared with the TCP mixtures, with the 2% HAp mixture achieving the highest compressive strength of 54.5 MPa at 56 days. Flexural strength results showed a similar trend, with HAp effectively suppressing microcrack propagation through improved matrix densification and interfacial bonding. However, replacement ratios exceeding 10% reduced mechanical performance due to cement dilution, increased porosity, and particle agglomeration. SEM observations confirmed that HAp replacement levels of 2–5% densified the mortar matrix, whereas excessive replacement caused localized agglomeration and microstructural defects. The carbon emission assessment indicated that pyrolysis reduced direct CO₂ emissions compared with incineration by immobilizing part of the carbon in solid char; however, laboratory-scale pyrolysis increased total emissions because of high electricity consumption. Nevertheless, process integration with cement clinker production could enable waste valorization and carbon reduction by utilizing existing high-temperature kiln systems. Overall, chicken bone-derived HAp–carbon composite demonstrated strong potential as an eco-friendly cement replacement material, with an optimal replacement ratio of 5% or less. Full article