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Keywords = capillary rheometer

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16 pages, 5658 KiB  
Article
Pressure Effect on the Rheological Behavior of Highly Filled Solid Propellant During Extrusion Flow
by Jun Zhang, Wei Zheng, Zhifeng Yuan, Junbo Chen, Jiangfeng Pei and Ping Xue
Polymers 2025, 17(15), 2003; https://doi.org/10.3390/polym17152003 - 22 Jul 2025
Viewed by 277
Abstract
Currently, the shear-extrusion behavior of solid propellants (SPs), which comprise a significant volume fraction of micro-/nanoscale solid particles (e.g., octogen/HMX), nitroglycerin as a plasticizer/solvent, nitrocellulose as a binder, and other functional additives, is still insufficiently understood. While the rheology of highly filled polymers [...] Read more.
Currently, the shear-extrusion behavior of solid propellants (SPs), which comprise a significant volume fraction of micro-/nanoscale solid particles (e.g., octogen/HMX), nitroglycerin as a plasticizer/solvent, nitrocellulose as a binder, and other functional additives, is still insufficiently understood. While the rheology of highly filled polymers has been extensively documented, the rheological behavior of SPs within the practical processing temperature range of 80–95 °C remains poorly understood. This study investigated, in particular, the pressure dependence of the viscosity of SPs melts during steady-state shear flow. Steady-state shear measurements were conducted using a twin-bore capillary rheometer with capillary dies of varying diameters and lengths to explore the viscosity dependence of SPs. The results reveal that interface defects between octogen particles and the polymer matrix generate a melt pressure range of 3–30 MPa in the long capillary die, underscoring the non-negligible impact of pressure on the measured viscosity (η). At constant temperature and shear rate, the measured viscosity of SPs exhibits strong pressure dependence, showing notable deviations in pressure sensitivity (β), which was found to be greatly relevant to the contents of solvent and solid particles. Such discrepancies are attributed to the compressibility of particle–particle and particle–polymer networks during capillary flow. The findings emphasize the critical role of pressure effect on the rheological properties of SPs, which is essential for optimizing manufacturing processes and ensuring consistent propellant performance. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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12 pages, 2341 KiB  
Article
Correlations Between Crystallinity, Rheological Behavior, and Short-Term Biodegradation for LDPE/Cellulose Composites with Potential as Packaging Films
by Nizar Jawad Hadi, Tomasz Rydzkowski, Zahraa Saleem Ali and Q. A. Al-Jarwany
Coatings 2025, 15(4), 397; https://doi.org/10.3390/coatings15040397 - 27 Mar 2025
Viewed by 481
Abstract
The need for renewable and biodegradable materials for packaging applications has grown significantly in recent years. Growing environmental worries over the widespread use of synthetic and non-biodegradable polymeric packaging, particularly polyethylene, are linked to this increase in demand. This study investigated the degradation [...] Read more.
The need for renewable and biodegradable materials for packaging applications has grown significantly in recent years. Growing environmental worries over the widespread use of synthetic and non-biodegradable polymeric packaging, particularly polyethylene, are linked to this increase in demand. This study investigated the degradation properties of low-density polyethylene (LDPE), a material commonly used in packaging, after incorporating various natural fillers that are sustainable, compatible, and biodegradable. The LDPE was mixed with 2.5, 5, and 10 wt.% of sawdust, cellulose powder, and Nanocrystalline cellulose (CNC). The composites were melted and mixed using a twin-screw extruder machine with a screw speed of 50 rpm at 190 °C to produce sheets using a specific die. These sheets were used to prepare samples for rheological tests that measured the viscosity curve, the flow curve, and a non-Newtonian mathematical model using a capillary rheometer at 170, 190, and 210 °C. X-ray diffraction analysis was carried out on the 5 wt.% samples, and a short-term degradation test was conducted in soil with a pH of 6.5, 50% humidity, and a temperature of 27 °C. The results revealed that the composite melts exhibited non-Newtonian behavior, with shear thinning being the dominant characteristic in the viscosity curves. The shear viscosity increased as the different cellulose additives increased. The 5% ratio had a higher viscosity for all composite melts, and the LDPE/CNC melts showed higher viscosities at different temperatures. The curve fitting results confirmed that the power-law model best described the flow behavior of all composite melts. The LDPE/sawdust and cellulose powder melts showed higher flow index (n) and lower viscosity consistency (k) values compared with LDPE/CNC melted at different temperatures. The sawdust and powder composites had greater weight loss compared with the LD vbbPE/CNC composites; digital images supported these results after 30 days. The degradation test and weight loss illustrated stronger relations with the viscosity values at low shear rates. The higher the shear viscosity, the lower the degradation and vice versa. Full article
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46 pages, 13796 KiB  
Review
Measurement Techniques for Interfacial Rheology of Surfactant, Asphaltene, and Protein-Stabilized Interfaces in Emulsions and Foams
by Ronald Marquez and Jean-Louis Salager
Colloids Interfaces 2025, 9(1), 14; https://doi.org/10.3390/colloids9010014 - 14 Feb 2025
Cited by 1 | Viewed by 2907
Abstract
This work provides a comprehensive review of experimental methods used to measure rheological properties of interfacial layers stabilized by surfactants, asphaltenes, and proteins that are relevant to systems with large interfacial areas, such as emulsions and foams. Among the shear methods presented, the [...] Read more.
This work provides a comprehensive review of experimental methods used to measure rheological properties of interfacial layers stabilized by surfactants, asphaltenes, and proteins that are relevant to systems with large interfacial areas, such as emulsions and foams. Among the shear methods presented, the deep channel viscometer, bicone rheometer, and double-wall ring rheometers are the most utilized. On the other hand, the main dilational rheology techniques discussed are surface waves, capillary pressure, oscillating Langmuir trough, oscillating pendant drop, and oscillating spinning drop. Recent developments—including machine learning and artificial intelligence (AI) models, such as artificial neural networks (ANN) and convolutional neural networks (CNN)—to calculate interfacial tension from drop shape analysis in shorter times and with higher precision are critically analyzed. Additionally, configurations involving an Atomic Force Microscopy (AFM) cantilever contacting bubble, a microtensiometer platform, rectangular and radial Langmuir troughs, and high-frequency oscillation drop setups are presented. The significance of Gibbs–Marangoni effects and interfacial rheological parameters on the (de)stabilization of emulsions is also discussed. Finally, a critical review of the recent literature on the measurement of interfacial rheology is presented. Full article
(This article belongs to the Special Issue Rheology of Complex Fluids and Interfaces)
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23 pages, 4816 KiB  
Article
Eco-Friendly Alternatives to Toluene-Based 2D Inks for Inkjet and Electrohydrodynamic Jet Printing Processes: A Rheological Study
by Pedro C. Rijo, Ilaria Tocci and Francisco J. Galindo-Rosales
Micromachines 2025, 16(2), 130; https://doi.org/10.3390/mi16020130 - 23 Jan 2025
Viewed by 1015
Abstract
Green sustainable solvents have emerged as promising alternatives to petroleum-derived options, such as toluene. This study demonstrates the use of cyrene as an effective exfoliation medium for graphene nanoplatelets (GNPs) and hexagonal boron nitride (hBN) and molybdenum disulfide (MoS2) particles. The [...] Read more.
Green sustainable solvents have emerged as promising alternatives to petroleum-derived options, such as toluene. This study demonstrates the use of cyrene as an effective exfoliation medium for graphene nanoplatelets (GNPs) and hexagonal boron nitride (hBN) and molybdenum disulfide (MoS2) particles. The incorporation of polyvinylpyrrolidone (PVP) attenuates the shear-thinning behavior of GNP and hBN suspensions, maintaining a constant shear viscosity over a wide range of shear rates regardless of PVP molecular weight. Despite the presence of polymer, elasticity is hindered by inertia effects, making it impossible to accurately measure the extensional relaxation time in the capillary breakup extensional rheometer (CaBER). Assuming the weak elasticity of the formulations has a negligible impact on the breakup mechanism, we estimated droplet sizes for drop-on-demand (DoD) inkjet printing and electrohydrodynamic (EHD) jet printing based on fluid properties, i.e., viscosity, surface tension and density, and nozzle inner diameter (Dnozzle). Results indicate that the droplet size ratio (Ddrop/Dnozzle) in DoD printing can be up to two orders of magnitude higher than the one predicted for EHD jet printing at the same flow rate. This work highlights the potential of cyrene-based 2D inks as eco-friendly alternatives for advanced printing technologies. Full article
(This article belongs to the Special Issue Two-Dimensional Materials for Emerging Applications)
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17 pages, 3883 KiB  
Article
Investigation of Rheological and Flow Properties of Buckwheat Dough with and Without Xanthan and Guar Gums for Optimized 3D Food Printing Across Temperature Variations
by Sholpan Baimaganbetova, Sagyn Omirbekov, Yanwei Wang, Mei-Yen Chan and Didier Talamona
Foods 2024, 13(24), 4054; https://doi.org/10.3390/foods13244054 - 16 Dec 2024
Cited by 1 | Viewed by 1683
Abstract
Buckwheat (Fagopyrum esculentum) is a gluten-free crop valued for its protein, fiber, and essential minerals. This study investigates the rheological properties of buckwheat (BW) dough, both with and without the addition of gums (no gum, guar (GG), xanthan (XG)), at varying [...] Read more.
Buckwheat (Fagopyrum esculentum) is a gluten-free crop valued for its protein, fiber, and essential minerals. This study investigates the rheological properties of buckwheat (BW) dough, both with and without the addition of gums (no gum, guar (GG), xanthan (XG)), at varying barrel temperatures (25, 55, and 85 °C) of the rheometer and at different water content levels (45, 50, and 55% w/w) to optimize dough formulations for 3D food printing. Using high shear stress capillary tests, the consistency coefficient (K) and flow behavior index (n) were measured. The results indicated that GG significantly increases the apparent viscosity of buckwheat dough across shear rates ranging from 200 to 2000 s−1, under all temperature and water content conditions. XG also enhanced viscosity but to a lesser extent at moderate temperatures (55 °C, 85 °C). All BW dough formulations exhibited a non-Newtonian shear-thinning behavior, crucial for 3D printing applications. In addition, computational fluid dynamics (CFD) simulations were conducted to analyze the extrusion process of BW dough formulations (50% W, 50% W + XG, and 50% W + GG), focusing on shear rate, viscosity, and pressure distribution. The simulations demonstrated that shear rates increased as the dough moved through the nozzle, while viscosity decreased, facilitating extrusion. However, gum-added formulations required higher pressures for extrusion, indicating an increased difficulty in dough flow. The study highlights the complex interactions between temperature, water content, and additive type on the rheological properties of buckwheat dough, while also incorporating CFD simulations to analyze the extrusion process. These insights provide a foundation for developing nutrient-dense, gluten-free 3D-printed foods tailored to specific dietary needs. Full article
(This article belongs to the Section Food Engineering and Technology)
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13 pages, 24238 KiB  
Article
Effects of Carbon Fiber Content on the Crystallization and Rheological Properties of Carbon Fiber-Reinforced Polyamide 6
by Jianglin Liu, Lang He, Dongdong Yang, Jianguo Liang, Runtian Zhao, Zhihui Wang, Xiaodong Li and Zhanchun Chen
Polymers 2024, 16(17), 2395; https://doi.org/10.3390/polym16172395 - 23 Aug 2024
Cited by 4 | Viewed by 1935
Abstract
Carbon fiber (CF)-reinforced polyamide 6 (PA6) composites have an excellent performance, attributed to properties such as light quality, high strength, and vibration reduction, and they are widely used in fields such as aerospace and transportation. Four kinds of carbon fiber-reinforced polyamide 6 (CF/PA6) [...] Read more.
Carbon fiber (CF)-reinforced polyamide 6 (PA6) composites have an excellent performance, attributed to properties such as light quality, high strength, and vibration reduction, and they are widely used in fields such as aerospace and transportation. Four kinds of carbon fiber-reinforced polyamide 6 (CF/PA6) composite pellets with carbon fiber contents of 20, 30, 40, and 50 wt.% were prepared using twin screw extrusion. The results were characterized using a simultaneous thermal analyzer, capillary rheometer, electronic universal material testing machine, and scanning electron microscope (SEM); their crystallization, rheological behavior, mechanical properties, surface structure, etc., were studied. DSC results indicate that an increase in carbon fiber content enhances the thermal stability of CF/PA6 and narrows the crystallization window but has a minor effect on the molecular chain diffusion time. The crystallinity reaches its maximum at a carbon fiber content of 40 wt.%, reaching 55.16%. The steady-state rheological behavior reveals that CF/PA6 behaves as a pseudoplastic fluid, exhibiting shear-thinning behavior. When the carbon fiber content is 40 wt.%, the power law exponent (n) reaches its maximum, and the consistency coefficient (K) decreases by 300 Pasn compared to the 30 wt.% content. With increasing temperature, n increases while K decreases. SEM observations reveal that samples with carbon fiber contents of 20 wt.% and 40 wt.% exhibit better fiber dispersion and orientation. However, the interfacial bonding strength is superior in the 40 wt.% sample. When the carbon fiber content reaches 50 wt.%, significant injection molding defects occur at the clamping end, leading to extensive matrix tearing during tension testing. Full article
(This article belongs to the Section Polymer Fibers)
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15 pages, 4455 KiB  
Article
Binder System Composition on the Rheological and Magnetic Properties of Nd-Fe-B Feedstocks for Metal Injection Molding
by Vahid Momeni, Sorana Luca, Joamin Gonzalez-Gutierrez, Santiago Cano, Emilie Sueur, Zahra Shahroodi, Stephan Schuschnigg, Christian Kukla and Clemens Holzer
Appl. Sci. 2024, 14(13), 5638; https://doi.org/10.3390/app14135638 - 28 Jun 2024
Cited by 2 | Viewed by 2326
Abstract
The applications of Nd-Fe-B-based magnets are experiencing significant diversification to achieve efficiency and miniaturization in different technologies. Metal injection molding (MIM) provides new opportunities to manufacture Nd-Fe-B magnets with high geometrical complexity efficiently. In this study, the impacts of the binder system composition [...] Read more.
The applications of Nd-Fe-B-based magnets are experiencing significant diversification to achieve efficiency and miniaturization in different technologies. Metal injection molding (MIM) provides new opportunities to manufacture Nd-Fe-B magnets with high geometrical complexity efficiently. In this study, the impacts of the binder system composition and powder loading on the rheological behavior, contamination, and magnetic properties of the Nd-Fe-B MIM parts were investigated. A high-pressure capillary rheometer was used to measure the apparent viscosity and pressure drops for feedstocks with different binder formulations and powder contents. Also, oxygen and carbon contamination, density, and magnetic properties were measured for different feedstock formulations and powder loadings. From the rheological, density, and magnetic properties points of view, the binder system consisting of 45 vol.% LLDPE as backbone was selected as the optimum formulation. The findings indicated that the sample with this binder system and 55 vol.% powder content had a high density (6.83 g/cm3), remanence (0.591 T), and coercivity (744.6 kA/m) compared to other binder compositions. By using 58 vol.% powder loading, the values of density (7.54 g/cm3), remanence (0.618 T), and carbon residue (982 ppm) improved, and a suitable rheological behavior was still observed. Thus, a suitable feedstock formulation was developed. Full article
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27 pages, 13432 KiB  
Article
Prediction of Plastic Shrinkage Cracking of Supplementary Cementitious Material-Modified Shotcrete Using Rheological and Mechanical Indicators
by Kyong-Ku Yun, Valerii Panov and Seungyeon Han
Materials 2023, 16(24), 7645; https://doi.org/10.3390/ma16247645 - 14 Dec 2023
Cited by 3 | Viewed by 1516
Abstract
Plastic shrinkage cracking is a complex and multifaceted process that occurs in the period between placement and the final setting. During this period, the mixture is viscoplastic in nature and therefore possesses rheological properties. The investigation of the relationship between rheological behavior and [...] Read more.
Plastic shrinkage cracking is a complex and multifaceted process that occurs in the period between placement and the final setting. During this period, the mixture is viscoplastic in nature and therefore possesses rheological properties. The investigation of the relationship between rheological behavior and its propensity to undergo cracking during the plastic phase presents an intriguing subject of study. However, many factors influence plastic cracking, and the corresponding interaction of its effects is complex in nature. This study aimed to evaluate the impact of rheological and physicomechanical properties on the occurrence of plastic cracking in high-performance shotcrete containing various supplementary cementitious materials. To achieve this, plastic cracking was evaluated employing the ASTM C 1579 standard and a smart crack viewer FCV-30, and the rheological parameters were controlled using an ICAR rheometer. In addition, a study was conducted to assess the strength development and fresh properties. Further, a relationship was established via statistical evaluation, and the best predicting models were selected. According to the study results, it can be concluded that high-yield stress and low plastic viscosity for colloidal silica mixtures are indicators of plastic cracking resistance owing to improved fresh microstructure and accelerated hydration reaction. However, earlier strength development and the presence of a water-reducing admixture allowed mixtures containing silica fume to achieve crack reduction. A higher indicator of yield stress is an indicator of the capillary pressure development of these mixtures. In addition, a series containing ultrafine fly ash (having high flow resistance and torque viscosity) exhibited a risk of early capillary pressure build-up and a decrease in strength characteristics, which could be stabilized with the addition of colloidal silica. Consequently, the mixture containing both silica fume and colloidal silica exhibited the best performance. Thus, the results indicated that rheological characteristics, compressive strength, and water-reducer content can be used to control the plastic shrinkage cracking of shotcrete. Full article
(This article belongs to the Section Construction and Building Materials)
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23 pages, 4334 KiB  
Article
Wall Slip-Free Viscosity Determination of Filled Rubber Compounds Using Steady-State Shear Measurements
by Dennis Kleinschmidt, Florian Brüning and Jonas Petzke
Polymers 2023, 15(22), 4406; https://doi.org/10.3390/polym15224406 - 14 Nov 2023
Cited by 2 | Viewed by 2220
Abstract
The high-pressure capillary rheometer (HPCR) represents a state-of-the-art instrument for the determination of rheological properties for plastics and rubber compounds. Rubber compounds have an increased tendency to exhibit flow anomalies depending on the compound ingredients and the processing parameters. Combined with non-isothermal effects [...] Read more.
The high-pressure capillary rheometer (HPCR) represents a state-of-the-art instrument for the determination of rheological properties for plastics and rubber compounds. Rubber compounds have an increased tendency to exhibit flow anomalies depending on the compound ingredients and the processing parameters. Combined with non-isothermal effects due to dissipative material heating, this causes rheological material measurements and the resulting material parameters derived from them to be affected by errors, since the fundamental analytical and numerical calculation approaches assume isothermal flow and wall adhesion. In this paper, the applicability of the empirical rheological transfer function of the Cox–Merz rule, which establishes a relationship between shear viscosity measured with a HPCR and complex viscosity measured with a closed cavity rheometer (CCR), is investigated. The Cox–Merz relation could not be verified for an unfilled EPDM raw polymer or for filled, practical rubber compounds. Using a closed cavity rheometer, a methodology based on ramp tests is then introduced to collect wall slip-free steady-state shear viscosity data under isothermal conditions. The generated data show high agreement with corrected viscosity data generated using the HPCR, while requiring less measurement effort. Full article
(This article belongs to the Special Issue Rheological Properties of Polymers and Polymer Composites)
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14 pages, 2574 KiB  
Article
Process-Relevant Flow Characteristics of Styrene-Based Thermoplastic Elastomers and Their Representation by Rheometric Data
by Markus Kaempfe, Matthieu Fischer, Ines Kuehnert and Sven Wießner
Polymers 2023, 15(17), 3537; https://doi.org/10.3390/polym15173537 - 25 Aug 2023
Cited by 2 | Viewed by 1302
Abstract
The complex multiphase morphology of thermoplastic elastomers based on styrene-block copolymers (TPSs) affects their flow behavior significantly and in a way which may not be considered by commonly used characterization and evaluation procedures. To evaluate the relevance of non-Newtonian flow phenomena for the [...] Read more.
The complex multiphase morphology of thermoplastic elastomers based on styrene-block copolymers (TPSs) affects their flow behavior significantly and in a way which may not be considered by commonly used characterization and evaluation procedures. To evaluate the relevance of non-Newtonian flow phenomena for the validity of rheometric data in processing, three commercially available TPSs with comparable hardness of about 60 Shore A but with different application fields were selected and characterized using parallel plate and high-pressure capillary rheometry. The validity of the rheometric data is assessed by modeling the flow in a high-pressure capillary rheometer by a computational fluid dynamics (CFD) simulation. The results were discussed in conjunction with close-up images of samples taken after the measurement. The materials show clearly different rheological behaviors but depend on the respective shear and geometrical conditions. In particular, for the material with the lowest viscosity, doubling the capillary diameter resulted in a disproportionate increase of the pressure loss by up to one third. Only the capillary flow of this material could not be reproduced by the CFD simulation. The results indicate that conventionally determined rheometric data of TPSs are of limited use in evaluating process flows for various material grades. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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14 pages, 3514 KiB  
Article
Experimental Validation of a Micro-Extrusion Set-Up with In-Line Rheometry for the Production and Monitoring of Filaments for 3D-Printing
by João Sousa, Paulo F. Teixeira, Loïc Hilliou and José A. Covas
Micromachines 2023, 14(8), 1496; https://doi.org/10.3390/mi14081496 - 26 Jul 2023
Cited by 3 | Viewed by 1978
Abstract
The main objective of this work is to validate an in-line micro-slit rheometer and a micro-extrusion line, both designed for the in-line monitoring and production of filaments for 3D printing using small amounts of material. The micro-filament extrusion line is first presented and [...] Read more.
The main objective of this work is to validate an in-line micro-slit rheometer and a micro-extrusion line, both designed for the in-line monitoring and production of filaments for 3D printing using small amounts of material. The micro-filament extrusion line is first presented and its operational window is assessed. The throughputs ranged between 0.045 kg/h and 0.15 kg/h with a maximum 3% error and with a melt temperature control within 1 °C under the processing conditions tested for an average residence time of about 3 min. The rheological micro slit is then presented and assessed using low-density polyethylene (LDPE) and cyclic olefin copolymer (COC). The excellent matching between the in-line micro-rheological data and the data measured with off-line rotational and capillary rheometers validate the in-line micro-slit rheometer. However, it is shown that the COC does not follow the Cox–Merz rule. The COC filaments produced with the micro-extrusion line were successfully used in the 3D printing of specimens for tensile testing. The quality of both filaments (less than 6% variation in diameter along the filament’s length) and printed specimens validated the whole micro-set-up, which was eventually used to deliver a rheological mapping of COC printability. Full article
(This article belongs to the Special Issue 3D Printing Technology and Its Applications)
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21 pages, 5857 KiB  
Article
Enhancing High-Pressure Capillary Rheometer Viscosity Data Calculation with the Propagation of Uncertainties for Subsequent Cross-Williams, Landel, and Ferry (WLF) Parameter Fitting
by Martin Hubmann, Stephan Schuschnigg, Ivica Ðuretek, Jonas Groten and Clemens Holzer
Polymers 2023, 15(14), 3147; https://doi.org/10.3390/polym15143147 - 24 Jul 2023
Cited by 1 | Viewed by 3025
Abstract
Measuring the shear viscosity of polymeric melts is an extensive effort frequently performed in high-pressure capillary rheometers, where the pressures required to push the melt through a capillary at various temperatures and volumetric flow rates are recorded. Then, the viscosity values are obtained [...] Read more.
Measuring the shear viscosity of polymeric melts is an extensive effort frequently performed in high-pressure capillary rheometers, where the pressures required to push the melt through a capillary at various temperatures and volumetric flow rates are recorded. Then, the viscosity values are obtained through Bagley and Weissenberg–Rabinowitsch corrections involving parameter fitting. However, uncertainties in those conversions due to pressure variations and measurement inaccuracies (random errors) affect the accuracy of the consequently calculated viscosities. This paper proposes quantifying them through a propagation of uncertainties calculation. This has been experimentally demonstrated for a polycarbonate melt. In addition, the derived viscosity uncertainties were used for the weighted residual sum of squares parameter estimation of the Cross-WLF viscosity model and compared with the coefficients obtained using the standard residual sum of squares minimization approach. The motivation was that, by comparison, individual poorly measured viscosity values should have a less negative impact on the overall fit quality of the former. For validation, the rheometer measurements were numerically simulated with both fits. The simulations based on the Cross-WLF fit, including the derived viscosity uncertainties, matched the measured pressures ~16% more closely for shear rates below 1500 1/s. Considering the uncertainties led to more precise coefficients. However, both fits showed substantial deviations at higher shear rates, probably due to substantial non-isothermal flow conditions that prevailed during these measurements. A capillary rheometer experiment was also simulated using arbitrarily chosen Cross-WLF parameters to exclude such systematic errors. A normally distributed error was then applied to the simulated pressures before re-fitting the parameters. Again, taking advantage of the derived viscosity uncertainties, the fit could recover the initial parameters better. Full article
(This article belongs to the Special Issue Advances in Polymers Processing and Injection Molding)
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23 pages, 7351 KiB  
Article
Compounding, Rheology and Numerical Simulation of Highly Filled Graphite Compounds for Potential Fuel Cell Applications
by Alptekin Celik, Fabian Willems, Mustafa Tüzün, Svetlana Marinova, Johannes Heyn, Markus Fiedler and Christian Bonten
Polymers 2023, 15(12), 2589; https://doi.org/10.3390/polym15122589 - 6 Jun 2023
Cited by 1 | Viewed by 2553
Abstract
Highly filled plastics may offer a suitable solution within the production process for bipolar plates. However, the compounding of conductive additives and the homogeneous mixing of the plastic melt, as well as the accurate prediction of the material behavior, pose a major challenge [...] Read more.
Highly filled plastics may offer a suitable solution within the production process for bipolar plates. However, the compounding of conductive additives and the homogeneous mixing of the plastic melt, as well as the accurate prediction of the material behavior, pose a major challenge for polymer engineers. To support the engineering design process of compounding by twin-screw extruders, this present study offers a method to evaluate the achievable mixing quality based on numerical flow simulations. For this purpose, graphite compounds with a filling content of up to 87 wt.-% were successfully produced and characterized rheologically. Based on a particle tracking method, improved element configurations were found for twin-screw compounding. Furthermore, a method to characterize the wall slip ratios of the compounded material system with different filler content is presented, since highly filled material systems often tend to wall slip during processing, which could have a very large influence on accurate prediction. Numerical simulations of the high capillary rheometer were conducted to predict the pressure loss in the capillary. The simulation results show a good agreement and were experimentally validated. In contrast to the expectation, higher filler grades showed only a lower wall slip than compounds with a low graphite content. Despite occurring wall slip effects, the developed flow simulation for the design of slit dies can provide a good prediction for both low and high filling ratios of the graphite compounds. Full article
(This article belongs to the Special Issue Rheology and Processing of Polymer Materials)
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17 pages, 4058 KiB  
Article
Investigation of Rheological Test Methods for the Suitability of Mortars for Manufacturing of Textile-Reinforced Concrete Using a Laboratory Mortar Extruder (LabMorTex)
by Matthias Kalthoff, Michael Raupach and Thomas Matschei
Constr. Mater. 2022, 2(4), 217-233; https://doi.org/10.3390/constrmater2040015 - 29 Sep 2022
Cited by 8 | Viewed by 2876
Abstract
One of the promising technologies to produce carbon textile-reinforced concrete structures is extrusion. For defect-free extrusion, high requirements are placed on the fresh concrete, since it must be transportable through the augers in the extruder and must not change the desired geometric shape [...] Read more.
One of the promising technologies to produce carbon textile-reinforced concrete structures is extrusion. For defect-free extrusion, high requirements are placed on the fresh concrete, since it must be transportable through the augers in the extruder and must not change the desired geometric shape after leaving the mouthpiece. For the rheologic description of suitable concretes or mortars for the extrusion process, there is currently a lack of test methods to characterise the fresh concrete before extrusion. At present, new mixtures are first tested in elaborate trials on laboratory extruders before they can be transferred to production scale. The development of compounds is strongly dependent on the know-how and experience of the users. Within the scope of this paper, different methods were investigated and systematic suitability tests for a successful extrusion have been carried out. The results show that the fresh mortar can only be roughly described by the measured data during the mixing process, such as the temperature or the torque. The use of a capillary rheometer only allows a basic characterisation of the fresh mortar. A clear differentiation of the fresh mortar can be made with the help of sphere penetration tests. These allow the mortar to be classified as unsuitable for the extrusion process or as extrudable before the extrusion process, and the suitability of new mixtures can be assessed in advance. The newly developed method offers the possibility of greatly accelerating the implementation of new formulations for the extrusion process, regardless of the experience of the subsequent users, and reducing the need for complex experiments using laboratory extruders. Full article
(This article belongs to the Special Issue Advances in Concrete Binders and Reinforced Concrete)
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17 pages, 7905 KiB  
Article
Rheological and Aesthetical Properties of Polyolefin Composites for Flame Retardant Cables with High Loading of Mineral Fillers
by Sara Haveriku, Michela Meucci, Marco Badalassi, Camillo Cardelli and Andrea Pucci
Micro 2022, 2(3), 524-540; https://doi.org/10.3390/micro2030034 - 2 Sep 2022
Cited by 3 | Viewed by 2860
Abstract
It was found that the use of natural magnesium hydroxide (n–MDH) as mineral filler in EVA based composites provided mechanical and rheological properties that did not completely comply with the halogen-free flame-retardant (HFFR) cables parameters. Moreover, the use of n–MDH mostly gave a [...] Read more.
It was found that the use of natural magnesium hydroxide (n–MDH) as mineral filler in EVA based composites provided mechanical and rheological properties that did not completely comply with the halogen-free flame-retardant (HFFR) cables parameters. Moreover, the use of n–MDH mostly gave a rough grey surface in the compound extruded by rheometry capillary. In contrast, with the use of synthetic material (s–MDH), a combination of better outcomes was observed. Mechanical and rheological properties were more aligned with the application, and the aesthetics were also improved, i.e., the surface was smooth and whiter. Therefore, with the aim of obtaining good aesthetical quality on the extrudate, we studied formulations by varying the type of polymer matrix and using a mixture of the natural magnesium hydroxide combined with other kind of fillers (in a 3:1 ratio using as main filler n–MDH). On this account, we found a synergistic effect in the mechanical, rheological, and aesthetic properties for the filler blend system containing n–MDH in combination with s–MDH or Böhmite AlO(OH), or using a secondary polymer belonging to the polybutene family combined with EVA. Full article
(This article belongs to the Special Issue State-of-the-Art Microscale and Nanoscale Researches in Italy)
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