Search Results (328)

Bi₆Fe₂Ti₃O₁₈ (BFTO) ceramics were synthesized via a solid-state reaction route using stoichiometric amounts of Bi₂O₃, TiO₂, and Fe₂O₃ powders. A thermal analysis of the powder mixture was conducted to optimize the heat treatment parameters. Energy-dispersive X-ray spectroscopy (EDS) confirmed the conservation of the chemical composition following calcination. Final densification was achieved through hot pressing. The crystal structure of the sintered samples, examined via X-ray diffraction at room temperature, revealed a tetragonal symmetry for BFTO ceramics sintered at 850 °C. Electron backscatter diffraction (EBSD) provided detailed insight into the crystallographic orientation and microstructure. Broadband dielectric spectroscopy (BBDS) was employed to investigate the dielectric response of BFTO ceramics over a frequency range of 10 mHz to 10 MHz and a temperature range of −30 °C to +200 °C. The temperature dependence of the relative permittivity (ε_r) and dielectric loss tangent (tan δ) were measured within a frequency range of 100 kHz to 900 kHz and a temperature range of 25 °C to 570 °C. The impedance data obtained from the BBDS measurements were validated using the Kramers–Kronig test and modeled using the Kohlrausch–Williams–Watts (KWW) function. The stretching parameter (β) ranged from ~0.72 to 0.82 in the impedance formalism within the temperature range from 200 °C to 20 °C. Full article

Relaxation behavior of water confined in reverse micelles under temperature-induced micelle clustering is undertaken using broadband dielectric spectroscopy in frequency range 1 Hz–20 GHz. All microemulsion systems with sufficiently noticeable micelle water pool (water/surfactant molar ratio W > 10) depict three relaxation processes, in low, high and microwave frequencies, anchoring with relaxation of shell (bound) water, orientation of surfactant anions at water-surfactant interface and relaxation of bulk water confined in reverse micelles. The analysis of dielectric relaxation processes in AOT-based w/o microemulsions under temperature induced clustering of reverse micelles were made according to structural information obtained in NMR and conductometry experiments. The “wait and switch” relaxation mechanism was applied for the explanation of results for water in the bound and bulk states under spatial limitation in reverse micelles. It was shown that surfactant layer predominantly influences the bound water. The properties of water close to AOT interface are determined by strong interactions between water and ionic AOT molecules, which perturb water H-bonding network. The decrease in micelle size causes a weakening of hydrogen bonds, deformation of its steric network and reduction in co-operative relaxation effects. Full article

Topological insulators (TIs) hold considerable promise for the advancement of optoelectronic technologies, including spectroscopy, imaging, and communication, owing to their remarkable optical and electrical characteristics. This study proposes a novel combination of Bi${}_2$Se${}_3$ TIs and ReSe${}_2$ for self-powered broadband photodetectors with high sensitivity and fast response time. The Bi${}_2$Se${}_3$/ReSe${}_2$ heterojunction photodetector achieves broadband response spectra ranging for 375 nm to 1 $\mathsf{\mu }$m. It demonstrates a significant responsivity of 64 mA/W at a wavelength of 600 nm (1 mW/cm${}^2$), exhibits a rapid response speed of 345 $\mathsf{\mu }$s rise/336 $\mathsf{\mu }$s fall time, and has a 3 dB bandwidth of 1.4 kHz under zero-bias conditions. The high performance can be attributed to the suitable energy band structure of Bi${}_2$Se${}_3$/ReSe${}_2$ and high carrier mobility in surface states of Bi${}_2$Se${}_3$. Excitingly, self-powered TIs photodetectors allow for high-quality signal transmission. The TIs employed in photodetectors can stimulate the production of new optoelectronic features, but they could also be used for highly integrated photonic circuits in the future. Full article

There is considerable interest in broadband nanomaterials, particularly transparent semiconductor oxides, within both fundamental research and technological applications. Historically, it has been considered that the variation in dopant concentration during the synthesis of semiconductor materials is a crucial factor in activating and/or modulating the optical and structural properties, particularly the bandgap and the parameters of the unit cell, of semiconductor oxides. Recently, tin oxide has emerged as a key material due to its excellent structural properties, optical transparency, and various promising applications in optoelectronics. This study utilized the ultrasonic spray pyrolysis technique to synthesize aluminum-doped tin oxide (ATO) thin films on quartz and polished single-crystal silicon substrates. The impact of varying aluminum doping levels (0, 2, 5, and 10 at. %) on morphology and structural and optical properties was examined. The ATO thin films were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and transmittance spectroscopy. SEM images demonstrated a slight reduction in the size of ATO nanoparticles as the aluminum doping concentration increased. XRD analysis revealed a tetragonal crystalline structure with the space group P42/mnm, and a shift in the XRD peaks to higher angles was noted with increasing aluminum content, indicating a decrease in the crystalline lattice parameters of ATO. The transmittance of the ATO films varied between 75% and 85%. By employing the transmittance spectra and the established Tauc formula the optical bandgap values of ATO films were calculated, showing an increase in the bandgap with higher doping levels. These findings were thoroughly analyzed and discussed; additionally, an effort was made to clarify the contradictory analyses present in the literature and to identify a doping range that avoids the onset of a secondary phase. Full article

Three liquid crystalline mixtures were investigated, consisting of compounds abbreviated as MHPOBC and 3F5FPhF6 with molar ratios 0.9:0.1 (MIX5FF6-1), 0.75:0.25 (MIX5FF6-2), and 0.5:0.5 (MIX5FF6-3). The presence of the smectic A*, smectic C*, and smectic C_A* phases was observed in all mixtures. The hexatic smectic X_A* phase, present in pure MHPOBC, disappeared quickly with an increasing admixture of 3F5FPhF6. Vitrification of smectic C_A* was observed for the equimolar mixture, with the glass transition temperature and fragility index comparable to the pure glassforming 3F5FPhF6 component. Partial crystallization to conformationally or orientationally disordered crystal phases was observed on cooling in two mixtures with a smaller fraction of 3F5FPhF6. Broadband dielectric spectroscopy was applied to study the relaxation times in smectic and crystal phases. Vogel–Fulcher–Tammann, Mauro–Yue–Ellison–Gupta–Allan, and critical-like models were applied for analysis of the α-relaxation time in supercooled smectic X_A* and smectic C_A* phases. Full article

The theory of orientational polarization and dielectric relaxation was developed by P. Debye more than 100 years ago. It approximates a molecule by a sphere having one or more dipole moments. While in the beginning the experimentally accessible spectral range was limited to roughly 6 decades in frequency, at the end of the last century, novel spectroscopic techniques were developed and dielectric spectroscopy became broadband, nowadays covering 18 decades with no gaps.This paved the avenue for a multitude of novel fields of research in soft matter and solid-state physics including fundamental questions like the scaling of relaxation processes or the dynamics of glasses. Yet the analysis of dielectric spectra is still based on the classical approach by Debye which does not consider the multitude of intra- and inter-molecular interactions within a molecular system. To experimentally overcome these principal limitations, it is suggested to take advantage of the molecular specificity of the infrared spectral range. This offers the unique possibility to realize a novel “Orientational Polarization Spectroscopy”, in which the orientational response of a molecular system can be analyzed on an atomistic scale. For that, the theory will be outlined and the first experimental results will be presented. Full article

Lithium (Li)-rich continental brines found in the Lithium Triangle region in South America are a natural resource of paramount importance. In the present research, the analytical performance of laser-induced breakdown spectroscopy (LIBS) technology was assessed for the quantitative analysis of Li in natural brines aimed at enhancing the efficient exploration of salt flats (called salars). Brine samples were collected from different salars located in the Puna plateau (Northwest Argentina) and analyzed by LIBS in the form of solid pressed pellets. Broadband emission spectra (180–900 nm) were recorded and spectrally analyzed by specially designed computational algorithms. The laser-induced plasmas were characterized by calculating the electron density and the temperature. The Li elemental concentrations in the brines were determined through univariate calibration with the Li I emission line at 670.77 nm by using a suitable set of standards with Li concentrations up to 1300 $\mathsf{\mu }$g/g. The calculated limit of detection was LoD = 0.2 ± 0.1 $\mathsf{\mu }$g/g. The Li content in the brines determined with LIBS showed a good agreement (normalized standard deviation: σ_N = 25%) with the concentrations measured with atomic absorption spectroscopy. The results demonstrated the feasibility of the LIBS technique for the quantitative analysis of Li in natural brines, thus contributing to advancing the exploration of Li-rich resources. Full article

Cross-linked polyethylene (XLPE) cables will gradually experience aging under various stresses during long-term operation, which may lead to faults and seriously affect the safe and stable operation of the power system. This article prepares aged cable samples by accelerating the thermal aging of XLPE cables, and combines frequency-domain dielectric spectroscopy (FDS) and the polarization–depolarization current method (PDC) for detection and analysis. By measuring the dielectric loss of aged cables using frequency-domain dielectric spectroscopy, it was found that the dielectric loss value in the low-frequency region significantly increases with aging time, indicating that aging leads to an increase in polarity groups and polarization loss. The high-frequency dielectric loss also significantly increases with the strengthening of dipole polarization. At the same time, using the polarization–depolarization current method to measure the polarization current and depolarization current of cables, it was found that the stable value of polarization current increases with aging time, further verifying the changes in the conductivity and polarization characteristics of insulation materials. Combining the broadband dielectric response characteristics of FDS (0.001 Hz–1 kHz) with the time-domain charge transfer analysis of PDC, the molecular structure degradation (dipole polarization enhancement) and interface defect accumulation (space charge effect) of cable aging are revealed from both frequency- and time-domain perspectives. The experimental results show that the integral value of the low-frequency region of the frequency-domain dielectric spectrum and the stable value of the polarization depolarization current are positively correlated with the aging time, and can make use of effective indicators to evaluate the aging state of XLPE cables. Full article

The dielectric relaxation dynamics in polymer composites critically determine their functional performance in advanced electrical systems. This study systematically investigates hybrid epoxy composites comprising neat epoxy resin (EP) and paper-reinforced systems (EIP), modified with 10–50 wt% polypropylene glycol diglycidyl ether (PEGDGE) plasticizer. Through synergistic application of differential scanning calorimetry (DSC) and broadband dielectric spectroscopy (10⁻¹–10⁶ Hz), the quantitative relationships between plasticizer content, glass transition temperature (Tg), and dielectric relaxation processes were established. DSC analysis reveals a linear Tg dependence with increasing PEGDGE content, attributed to enhanced molecular mobility. Dielectric characterization demonstrates three distinct relaxation regimes: α-relaxation below Tg, interfacial polarization at epoxy/PEGDGE boundaries, and paper/epoxy interfacial effects in EIP systems. A quantitative dielectric relaxation model was developed based on complex modulus formalism, coupled with Vogel–Fulcher–Tammann (VFT) analysis of DC conductivity. Activation energy mapping through Arrhenius decomposition reveals three characteristic values: (1) 82.01–87.80 kJ/mol for α-relaxation, (2) 55.96–64.64 kJ/mol for epoxy/PEGDGE interfaces, and (3) 30.88–44.38 kJ/mol for epoxy/paper interfaces. Crucially, the plasticizer content modulates these activation energies, demonstrating its role in tailoring interfacial dynamics. Full article

A methane (CH₄) sensor based on off-axis integrated cavity output spectroscopy (OA-ICOS) was developed, equipped with two measurement schemes: direct absorption spectroscopy (DAS) and wavelength modulation spectroscopy (WMS). The sensor used an optical resonant cavity composed of two high reflection mirrors (reflectivity > 99%). With a cavity length of 7 cm, an effective optical path length of 10.8 m and a cavity volume of 8.9 mL were achieved. A distributed feedback laser was used to precisely target the CH₄ absorption line near 1.6537 µm. Compared with the original system, the cavity mode noise of the CH₄ sensor was further reduced by adding white noise perturbations. The white noise perturbations were generated by the broadband random noise from the signal generator. The special customized narrowband RF noise source was not required. The system complexity and cost could be reduced. In DAS mode, the signal-to-noise ratio (SNR) of the OA-ICOS was 16.2 and the minimum detection limit (MDL) was 2.2 ppm at 117 s. In WMS mode, the SNR of the OA-ICOS was 113.9 and the MDL was 1.2 ppm at 106 s. Compared with the results obtained from the WMS mode and DAS mode, the SNR and MDL was improved 7.0 times and 1.8 times, respectively. The proposed sensor system not only enabled high-accuracy trace gas measurement, but also demonstrated strong potential for applications due to its compact design and low cost. Full article

Formaldehyde is the most abundant carbonyl globally and the biggest driver of cancer risk in the United States among hazardous air pollutants. Ambient formaldehyde concentration measurements are generally sparse due to high measurement costs and limited measurement infrastructure. Recent studies have used low-cost air quality sensors to affordably improve spatial coverage and provide real-time measurements. Our previous research evaluated the laboratory performance of a low-cost electrochemical formaldehyde sensor (Sensirion SFA30) over formaldehyde concentrations ranging from 0 to 76 ppb. The sensors exhibited good linearity of response, a low limit of detection, and good accuracy in detecting formaldehyde. This study evaluated the cross-sensitivity of the SFA30 and the Gravity sensors (electrochemical formaldehyde sensors) over formaldehyde concentrations ranging from 0 to 326 ppb in a laboratory evaluation system, with broadband cavity-enhanced absorption spectroscopy used to obtain the reference measurements. We evaluated the sensors in a mixture of formaldehyde with five outdoor trace gases (CO, NO, NO₂, O₃, and isobutylene) and two indoor VOCs (methanol and isopropyl alcohol). The results suggest that the Gravity sensors may be useful for outdoor formaldehyde measurements when formaldehyde levels are well above background levels and that the SFA30 sensors may be useful screening tools for indoor environments, if properly calibrated. Full article

Incorporating lead (Pb) into the germanium (Ge) lattice emerges as a promising approach for bandgap engineering, enabling luminescence at longer wavelengths and paving the way for enhanced applications in short-wave infrared (SWIR) light sources and photodetectors. In this work, we report on optical properties of GePb alloys fabricated by a complementary metal-oxide semiconductor (CMOS)-compatible process that includes Pb ion implantation followed by solid-phase epitaxial regrowth via flash-lamp annealing. Optical characterization, including photoluminescence spectroscopy and Fourier-transform infrared reflectance spectroscopy, reveals that GePb alloys exhibit a reduced bandgap compared to pure Ge, resulting in longer-wavelength emission, while also providing broadband antireflective properties below 1800 nm wavelengths due to the surface subwavelength nanostructure. These findings position nanostructured GePb as a highly promising candidate for SWIR optoelectronic applications. Full article

Multisine electrochemical impedance spectroscopy (EIS) represents a highly promising technique for the online characterization of battery functional states, offering the potential to monitor, in real-time, key degradation phenomena such as aging, internal resistance variation, and state of health (SoH) evolution. However, its widespread adoption in embedded systems is currently limited by the need to balance measurement accuracy with strict energy constraints and the requirement for short acquisition times. This work proposes a novel broadband EIS approach based on a multiband multisine excitation strategy in which the excitation signal spectrum is divided into multiple sub-bands that are sequentially explored. This enables the available energy to be concentrated on a limited portion of the spectrum at a time, thereby significantly improving the signal-to-noise ratio (SNR) without substantially increasing the total measurement time. The result is a more energy-efficient method that maintains high diagnostic precision. We further investigated the optimal design of these multiband multisine sequences, taking into account realistic constraints imposed by the sensing hardware such as limitations in excitation amplitude and noise level. The effectiveness of the proposed method was demonstrated within a comprehensive simulation framework implementing a complete impedance measurement system. Compared with conventional excitation techniques (i.e., the sine sweep and the classical single-band multisine methods), the proposed strategy is an optimal trade-off solution both in terms of energy efficiency and measurement time. Therefore, the technique is a valuable solution for real-time, embedded, and in situ battery diagnostics, with direct implications for the development of intelligent battery management systems (BMS), predictive maintenance, and enhanced safety in energy storage applications. Full article

This report discusses the impact of nanoparticles on glass-forming systems composed of a liquid crystalline (LC) mixture E7 and paraelectric BaTiO₃ particles ($d\approx 50 \mathrm{n}\mathrm{m}$, globular), tested via broadband dielectric spectroscopy. In the isotropic phase, critical changes in the dielectric constant are shown. They are related to the weakly discontinuous nature of the isotropic–nematic transition. In the nematic phase, two primary relaxation times/processes and DC electric conductivity are considered, down to the glass temperature $T_g$. The prevalence of portrayals via the ‘double exponential’ MYEGA equation and the critical & activated Drozd-Rzoska relation for dynamic properties are shown. For the primary loss curve, critical-like changes of its maximum (peak) are evidenced: ${\epsilon }_{peak}^{″}\propto 1/\left(T-T_g^{*}\right)$ for $T_g<T<\left(T_g+25 \mathrm{K}\right)$, where $T_g^{*}<T_g$ denotes the extrapolated singular temperature. Dielectric constant monitoring revealed the permanent arrangement of rod-like LC molecules by nanoparticles’ endogenic impact in the nematic phase. The heuristic model regarding this unique behavior is presented. It considers a hypothetical link between the glass transition and a hidden near-critical discontinuous phase transition, uniquely avoiding a symmetry change. The uniaxiality of LC molecules enables the detection of critical-like features when approaching the glass transition, hypothetically associated with a specific ‘amorphous’ phase transition. Full article

The eco-friendly flame retardancy of polycarbonate (PC) was achieved by blending with phosphorylated-PC in the range of 1–5% w/w. Dynamic properties were characterized using broadband dielectric relaxation spectroscopy (DRS), while structural and thermal properties were investigated using Fourier transform infrared spectroscopy, wide-angle X-ray diffraction, small-angle X-ray scattering, differential scanning calorimetry, and thermogravimetric analysis. A reduction in the single glass transition temperature with increasing phosphorylated-PC content was observed, indicating that the blends were miscible. No crystalline phases were detected in any of the samples. The thermo-oxidative stability and UL-94 ratings of flame-retardant polycarbonates (FRPCs) improved compared to neat PC, with char residue increasing as the phosphorylated-PC content rose. DRS analysis revealed the formation of a well-defined local (β) relaxation in the FRPC samples, originating from the motion of phosphorylated branches. All samples exhibited the segmental (α) relaxation of PC chains above the glass transition temperature. The size of the cooperatively rearranging domain played a significant role in the dynamic fragility of the rigid FRPCs. Additionally, DRS analysis highlighted the presence of physical crosslinks from nanoclusters of phosphorylated polar groups, approximately 14 nm in size. Full article