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18 pages, 441 KiB  
Article
Classical SO(n) Spins on Geometrically Frustrated Crystals: A Real-Space Renormalization Group Approach
by Angel J. Garcia-Adeva
Crystals 2025, 15(8), 715; https://doi.org/10.3390/cryst15080715 (registering DOI) - 5 Aug 2025
Abstract
A real-space renormalization group (RG) framework is formulated for classical SO(n) spin models defined on d-dimensional crystal lattices composed of corner-sharing hyper-tetrahedra, a class of geometrically frustrated crystal structures. This includes, as specific instances, the classical Heisenberg model on the kagome and pyrochlore [...] Read more.
A real-space renormalization group (RG) framework is formulated for classical SO(n) spin models defined on d-dimensional crystal lattices composed of corner-sharing hyper-tetrahedra, a class of geometrically frustrated crystal structures. This includes, as specific instances, the classical Heisenberg model on the kagome and pyrochlore crystals. The approach involves computing the partition function and corresponding order parameters for spin clusters embedded in the crystal, to leading order in symmetry-breaking fields generated by surrounding spins. The crystal geometry plays a central role in determining the scaling relations and the associated critical behavior. To illustrate the efficacy of the method, a reduced manifold of symmetry-allowed ordered states for isotropic nearest-neighbor interactions is analyzed. The RG flow systematically excludes the emergence of a q=0 ordered phase within the antiferromagnetic sector, independently of both the spatial dimensionality of the crystal and the number of spin components. Extensions to incorporate more elaborate crystal-symmetry-induced ordering patterns and fluctuation-driven phenomena—such as order-by-disorder—are also discussed. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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18 pages, 1481 KiB  
Article
Ambiguities, Built-In Biases, and Flaws in Big Data Insight Extraction
by Serge Galam
Information 2025, 16(8), 661; https://doi.org/10.3390/info16080661 - 2 Aug 2025
Viewed by 62
Abstract
I address the challenge of extracting reliable insights from large datasets using a simplified model that illustrates how hierarchical classification can distort outcomes. The model consists of discrete pixels labeled red, blue, or white. Red and blue indicate distinct properties, while white represents [...] Read more.
I address the challenge of extracting reliable insights from large datasets using a simplified model that illustrates how hierarchical classification can distort outcomes. The model consists of discrete pixels labeled red, blue, or white. Red and blue indicate distinct properties, while white represents unclassified or ambiguous data. A macro-color is assigned only if one color holds a strict majority among the pixels. Otherwise, the aggregate is labeled white, reflecting uncertainty. This setup mimics a percolation threshold at fifty percent. Assuming that directly accessing the various proportions from the data of colors is infeasible, I implement a hierarchical coarse-graining procedure. Elements (first pixels, then aggregates) are recursively grouped and reclassified via local majority rules, ultimately producing a single super-aggregate for which the color represents the inferred macro-property of the collection of pixels as a whole. Analytical results supported by simulations show that the process introduces additional white aggregates beyond white pixels, which could be present initially; these arise from groups lacking a clear majority, requiring arbitrary symmetry-breaking decisions to attribute a color to them. While each local resolution may appear minor and inconsequential, their repetitions introduce a growing systematic bias. Even with complete data, unavoidable asymmetries in local rules are shown to skew outcomes. This study highlights a critical limitation of recursive data reduction. Insight extraction is shaped not only by data quality but also by how local ambiguity is handled, resulting in built-in biases. Thus, the related flaws are not due to the data but to structural choices made during local aggregations. Although based on a simple model, these findings expose a high likelihood of inherent flaws in widely used hierarchical classification techniques. Full article
(This article belongs to the Section Artificial Intelligence)
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27 pages, 5776 KiB  
Review
From “Information” to Configuration and Meaning: In Living Systems, the Structure Is the Function
by Paolo Renati and Pierre Madl
Int. J. Mol. Sci. 2025, 26(15), 7319; https://doi.org/10.3390/ijms26157319 - 29 Jul 2025
Viewed by 162
Abstract
In this position paper, we argue that the conventional understanding of ‘information’ (as generally conceived in science, in a digital fashion) is overly simplistic and not consistently applicable to living systems, which are open systems that cannot be reduced to any kind of [...] Read more.
In this position paper, we argue that the conventional understanding of ‘information’ (as generally conceived in science, in a digital fashion) is overly simplistic and not consistently applicable to living systems, which are open systems that cannot be reduced to any kind of ‘portion’ (building block) ascribed to the category of quantity. Instead, it is a matter of relationships and qualities in an indivisible analogical (and ontological) relationship between any presumed ‘software’ and ‘hardware’ (information/matter, psyche/soma). Furthermore, in biological systems, contrary to Shannon’s definition, which is well-suited to telecommunications and informatics, any kind of ‘information’ is the opposite of internal entropy, as it depends directly on order: it is associated with distinction and differentiation, rather than flattening and homogenisation. Moreover, the high degree of structural compartmentalisation of living matter prevents its energetics from being thermodynamically described by using a macroscopic, bulk state function. This requires the Second Principle of Thermodynamics to be redefined in order to make it applicable to living systems. For these reasons, any static, bit-related concept of ‘information’ is inadequate, as it fails to consider the system’s evolution, it being, in essence, the organized coupling to its own environment. From the perspective of quantum field theory (QFT), where many vacuum levels, symmetry breaking, dissipation, coherence and phase transitions can be described, a consistent picture emerges that portrays any living system as a relational process that exists as a flux of context-dependent meanings. This epistemological shift is also associated with a transition away from the ‘particle view’ (first quantisation) characteristic of quantum mechanics (QM) towards the ‘field view’ possible only in QFT (second quantisation). This crucial transition must take place in life sciences, particularly regarding the methodological approaches. Foremost because biological systems cannot be conceived as ‘objects’, but rather as non-confinable processes and relationships. Full article
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24 pages, 4106 KiB  
Article
Visualizing Three-Qubit Entanglement
by Alfred Benedito and Germán Sierra
Entropy 2025, 27(8), 800; https://doi.org/10.3390/e27080800 - 27 Jul 2025
Viewed by 129
Abstract
We present a graphical framework to represent entanglement in three-qubit states. The geometry associated with each entanglement class and type is analyzed, revealing distinct structural features. We explore the connection between this geometric perspective and the tangle, deriving bounds that depend on the [...] Read more.
We present a graphical framework to represent entanglement in three-qubit states. The geometry associated with each entanglement class and type is analyzed, revealing distinct structural features. We explore the connection between this geometric perspective and the tangle, deriving bounds that depend on the entanglement class. Based on these insights, we conjecture a purely geometric expression for both the tangle and Cayley’s hyperdeterminant for non-generic states. As an application, we analyze the energy eigenstates of physical Hamiltonians, identifying the sufficient conditions for genuine tripartite entanglement to be robust under symmetry-breaking perturbations and level repulsion effects. Full article
(This article belongs to the Special Issue Editorial Board Members' Collection Series on Quantum Entanglement)
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22 pages, 4611 KiB  
Article
MMC-YOLO: A Lightweight Model for Real-Time Detection of Geometric Symmetry-Breaking Defects in Wind Turbine Blades
by Caiye Liu, Chao Zhang, Xinyu Ge, Xunmeng An and Nan Xue
Symmetry 2025, 17(8), 1183; https://doi.org/10.3390/sym17081183 - 24 Jul 2025
Viewed by 322
Abstract
Performance degradation of wind turbine blades often stems from geometric asymmetry induced by damage. Existing methods for assessing damage face challenges in balancing accuracy and efficiency due to their limited ability to capture fine-grained geometric asymmetries associated with multi-scale damage under complex background [...] Read more.
Performance degradation of wind turbine blades often stems from geometric asymmetry induced by damage. Existing methods for assessing damage face challenges in balancing accuracy and efficiency due to their limited ability to capture fine-grained geometric asymmetries associated with multi-scale damage under complex background interference. To address this, based on the high-speed detection model YOLOv10-N, this paper proposes a novel detection model named MMC-YOLO. First, the Multi-Scale Perception Gated Convolution (MSGConv) Module was designed, which constructs a full-scale receptive field through multi-branch fusion and channel rearrangement to enhance the extraction of geometric asymmetry features. Second, the Multi-Scale Enhanced Feature Pyramid Network (MSEFPN) was developed, integrating dynamic path aggregation and an SENetv2 attention mechanism to suppress background interference and amplify damage response. Finally, the Channel-Compensated Filtering (CCF) module was constructed to preserve critical channel information using a dynamic buffering mechanism. Evaluated on a dataset of 4818 wind turbine blade damage images, MMC-YOLO achieves an 82.4% mAP [0.5:0.95], representing a 4.4% improvement over the baseline YOLOv10-N model, and a 91.1% recall rate, an 8.7% increase, while maintaining a lightweight parameter count of 4.2 million. This framework significantly enhances geometric asymmetry defect detection accuracy while ensuring real-time performance, meeting engineering requirements for high efficiency and precision. Full article
(This article belongs to the Special Issue Symmetry and Its Applications in Image Processing)
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36 pages, 3106 KiB  
Article
Tamed Euler–Maruyama Method of Time-Changed McKean–Vlasov Neutral Stochastic Differential Equations with Super-Linear Growth
by Jun Zhang, Liping Xu and Zhi Li
Symmetry 2025, 17(8), 1178; https://doi.org/10.3390/sym17081178 - 23 Jul 2025
Viewed by 187
Abstract
This paper examines temporal symmetry breaking and structural duality in a class of time-changed McKean–Vlasov neutral stochastic differential equations. The system features super-linear drift coefficients satisfying a one-sided local Lipschitz condition and incorporates a fundamental duality: one drift component evolves under a random [...] Read more.
This paper examines temporal symmetry breaking and structural duality in a class of time-changed McKean–Vlasov neutral stochastic differential equations. The system features super-linear drift coefficients satisfying a one-sided local Lipschitz condition and incorporates a fundamental duality: one drift component evolves under a random time change Et, while the other progresses in regular time t. Within the symmetric framework of mean-field interacting particle systems, where particles exhibit permutation invariance, we establish strong convergence of the tamed Euler–Maruyama method over finite time intervals. By replacing the one-sided local condition with a globally symmetric Lipschitz assumption, we derive an explicit convergence rate for the numerical scheme. Two numerical examples validate the theoretical results. Full article
(This article belongs to the Section Mathematics)
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20 pages, 3164 KiB  
Review
Is Hydra Axis Definition a Fluctuation-Based Process Picking Up External Cues?
by Mikhail A. Zhukovsky, Si-Eun Sung and Albrecht Ott
J. Dev. Biol. 2025, 13(3), 24; https://doi.org/10.3390/jdb13030024 - 17 Jul 2025
Viewed by 370
Abstract
Axis definition plays a key role in the establishment of animal body plans, both in normal development and regeneration. The cnidarian Hydra can re-establish its simple body plan when regenerating from a random cell aggregate or a sufficiently small tissue fragment. At the [...] Read more.
Axis definition plays a key role in the establishment of animal body plans, both in normal development and regeneration. The cnidarian Hydra can re-establish its simple body plan when regenerating from a random cell aggregate or a sufficiently small tissue fragment. At the beginning of regeneration, a hollow cellular spheroid forms, which then undergoes symmetry breaking and de novo body axis definition. In the past, we have published related work in a physics journal, which is difficult to read for scientists from other disciplines. Here, we review our work for readers not so familiar with this type of approach at a level that requires very little knowledge in mathematics. At the same time, we present a few aspects of Hydra biology that we believe to be linked to our work. These biological aspects may be of interest to physicists or members of related disciplines to better understand our approach. The proposed theoretical model is based on fluctuations of gene expression that are triggered by mechanical signaling, leading to increasingly large groups of cells acting in sync. With a single free parameter, the model quantitatively reproduces the experimentally observed expression pattern of the gene ks1, a marker for ‘head forming potential’. We observed that Hydra positions its axis as a function of a weak temperature gradient, but in a non-intuitive way. Supposing that a large fluctuation including ks1 expression is locked to define the head position, the model reproduces this behavior as well—without further changes. We explain why we believe that the proposed fluctuation-based symmetry breaking process agrees well with recent experimental findings where actin filament organization or anisotropic mechanical stimulation act as axis-positioning events. The model suggests that the Hydra spheroid exhibits huge sensitivity to external perturbations that will eventually position the axis. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Developmental Biology 2025)
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18 pages, 1709 KiB  
Article
Fluid and Dynamic Analysis of Space–Time Symmetry in the Galloping Phenomenon
by Jéssica Luana da Silva Santos, Andreia Aoyagui Nascimento and Adailton Silva Borges
Symmetry 2025, 17(7), 1142; https://doi.org/10.3390/sym17071142 - 17 Jul 2025
Viewed by 299
Abstract
Energy generation from renewable sources has increased exponentially worldwide, particularly wind energy, which is converted into electricity through wind turbines. The growing demand for renewable energy has driven the development of horizontal-axis wind turbines with larger dimensions, as the energy captured is proportional [...] Read more.
Energy generation from renewable sources has increased exponentially worldwide, particularly wind energy, which is converted into electricity through wind turbines. The growing demand for renewable energy has driven the development of horizontal-axis wind turbines with larger dimensions, as the energy captured is proportional to the area swept by the rotor blades. In this context, the dynamic loads typically observed in wind turbine towers include vibrations caused by rotating blades at the top of the tower, wind pressure, and earthquakes (less common). In offshore wind farms, wind turbine towers are also subjected to dynamic loads from waves and ocean currents. Vortex-induced vibration can be an undesirable phenomenon, as it may lead to significant adverse effects on wind turbine structures. This study presents a two-dimensional transient model for a rigid body anchored by a torsional spring subjected to a constant velocity flow. We applied a coupling of the Fourier pseudospectral method (FPM) and immersed boundary method (IBM), referred to in this study as IMERSPEC, for a two-dimensional, incompressible, and isothermal flow with constant properties—the FPM to solve the Navier–Stokes equations, and IBM to represent the geometries. Computational simulations, solved at an aspect ratio of ϕ=4.0, were analyzed, considering Reynolds numbers ranging from Re=150 to Re = 1000 when the cylinder is stationary, and Re=250 when the cylinder is in motion. In addition to evaluating vortex shedding and Strouhal number, the study focuses on the characterization of space–time symmetry during the galloping response. The results show a spatial symmetry breaking in the flow patterns, while the oscillatory motion of the rigid body preserves temporal symmetry. The numerical accuracy suggested that the IMERSPEC methodology can effectively solve complex problems. Moreover, the proposed IMERSPEC approach demonstrates notable advantages over conventional techniques, particularly in terms of spectral accuracy, low numerical diffusion, and ease of implementation for moving boundaries. These features make the model especially efficient and suitable for capturing intricate fluid–structure interactions, offering a promising tool for analyzing wind turbine dynamics and other similar systems. Full article
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14 pages, 8428 KiB  
Article
Spin-Orbit-Coupling-Governed Optical Absorption in Bilayer MoS2 via Strain, Twist, and Electric Field Engineering
by Lianmeng Yu, Yingliang Chen, Weibin Zhang, Peizhi Yang and Xiaobo Feng
Nanomaterials 2025, 15(14), 1100; https://doi.org/10.3390/nano15141100 - 16 Jul 2025
Viewed by 287
Abstract
This paper investigates strain-, twist-, and electric-field-tuned optical absorption in bilayer MoS2, emphasizing spin-orbit coupling (SOC). A continuum model reveals competing mechanisms: geometric perturbations (strain/twist) and Stark effects govern one-/two-photon absorption, with critical thresholds (~9% strain, ~2.13° twist) switching spin-independent to [...] Read more.
This paper investigates strain-, twist-, and electric-field-tuned optical absorption in bilayer MoS2, emphasizing spin-orbit coupling (SOC). A continuum model reveals competing mechanisms: geometric perturbations (strain/twist) and Stark effects govern one-/two-photon absorption, with critical thresholds (~9% strain, ~2.13° twist) switching spin-independent to spin-polarized regimes. Strain gradients and twist enhance nonlinear responses through symmetry-breaking effects while electric fields dynamically modulate absorption via band alignment tuning. By linking parameter configurations to absorption characteristics, this work provides a framework for designing tunable spin-resolved optoelectronic devices and advancing light–matter control in 2D materials. Full article
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19 pages, 3024 KiB  
Article
Feedback-Driven Dynamical Model for Axonal Extension on Parallel Micropatterns
by Kyle Cheng, Udathari Kumarasinghe and Cristian Staii
Biomimetics 2025, 10(7), 456; https://doi.org/10.3390/biomimetics10070456 - 11 Jul 2025
Viewed by 362
Abstract
Despite significant advances in understanding neuronal development, a fully quantitative framework that integrates intracellular mechanisms with environmental cues during axonal growth remains incomplete. Here, we present a unified biophysical model that captures key mechanochemical processes governing axonal extension on micropatterned substrates. In these [...] Read more.
Despite significant advances in understanding neuronal development, a fully quantitative framework that integrates intracellular mechanisms with environmental cues during axonal growth remains incomplete. Here, we present a unified biophysical model that captures key mechanochemical processes governing axonal extension on micropatterned substrates. In these environments, axons preferentially align with the pattern direction, form bundles, and advance at constant speed. The model integrates four core components: (i) actin–adhesion traction coupling, (ii) lateral inhibition between neighboring axons, (iii) tubulin transport from soma to growth cone, and (iv) orientation dynamics guided by substrate anisotropy. Dynamical systems analysis reveals that a saddle–node bifurcation in the actin adhesion subsystem drives a transition to a high-traction motile state, while traction feedback shifts a pitchfork bifurcation in the signaling loop, promoting symmetry breaking and robust alignment. An exact linear solution in the tubulin transport subsystem functions as a built-in speed regulator, ensuring stable elongation rates. Simulations using experimentally inferred parameters accurately reproduce elongation speed, alignment variance, and bundle spacing. The model provides explicit design rules for enhancing axonal alignment through modulation of substrate stiffness and adhesion dynamics. By identifying key control parameters, this work enables rational design of biomaterials for neural repair and engineered tissue systems. Full article
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14 pages, 2812 KiB  
Perspective
The Generation of Wind Velocity via Scale Invariant Gibbs Free Energy: Turbulence Drives the General Circulation
by Adrian F. Tuck
Entropy 2025, 27(7), 740; https://doi.org/10.3390/e27070740 - 10 Jul 2025
Viewed by 286
Abstract
The mechanism for the upscale deposition of energy into the atmosphere from molecules and photons up to organized wind systems is examined. This analysis rests on the statistical multifractal analysis of airborne observations. The results show that the persistence of molecular velocity after [...] Read more.
The mechanism for the upscale deposition of energy into the atmosphere from molecules and photons up to organized wind systems is examined. This analysis rests on the statistical multifractal analysis of airborne observations. The results show that the persistence of molecular velocity after collision in breaking the continuous translational symmetry of an equilibrated gas is causative. The symmetry breaking may be caused by excited photofragments with the associated persistence of molecular velocity after collision, interaction with condensed phase surfaces (solid or liquid), or, in a scaling environment, an adjacent scale having a different velocity and temperature. The relationship of these factors for the solution to the Navier–Stokes equation in an atmospheric context is considered. The scale invariant version of Gibbs free energy, carried by the most energetic molecules, enables the acceleration of organized flow (winds) from the smallest planetary scales by virtue of the nonlinearity of the mechanism, subject to dissipation by the more numerous average molecules maintaining an operational temperature via infrared radiation to the cold sink of space. The fastest moving molecules also affect the transfer of infrared radiation because their higher kinetic energy and the associated more-energetic collisions contribute more to the far wings of the spectral lines, where the collisional displacement from the central energy level gap is greatest and the lines are less self-absorbed. The relationship of events at these scales to macroscopic variables such as the thermal wind equation and its components will be considered in the Discussion section. An attempt is made to synthesize the mechanisms by which winds are generated and sustained, on all scales, by appealing to published works since 2003. This synthesis produces a view of the general circulation that includes thermodynamics and the defining role of turbulence in driving it. Full article
(This article belongs to the Section Statistical Physics)
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13 pages, 3092 KiB  
Article
Carbon Dioxide Gas Sensor Based on Terahertz Metasurface with Asymmetric Cross-Shaped Holes Empowered by Quasi-Bound States in the Continuum
by Kai He and Tian Ma
Sensors 2025, 25(13), 4178; https://doi.org/10.3390/s25134178 - 4 Jul 2025
Viewed by 357
Abstract
In this paper, a novel type of polarization-insensitive terahertz metal metasurface with cross-shaped holes is presented, which is designed based on the theory of bound states in continuous media. The fundamental unit of the metasurface comprises a metal tungsten sheet with a cross-shaped [...] Read more.
In this paper, a novel type of polarization-insensitive terahertz metal metasurface with cross-shaped holes is presented, which is designed based on the theory of bound states in continuous media. The fundamental unit of the metasurface comprises a metal tungsten sheet with a cross-shaped hole structure. A thorough analysis of the optical properties and the quasi-BIC response is conducted using the finite element method. Utilizing the symmetry-breaking theory, the symmetry of the metal metasurface is broken, allowing the excitation of double quasi-BIC resonance modes with a high quality factor and high sensitivity to be achieved. Analysis of the multipole power distribution diagram and the spatial distribution of the electric field at the two quasi-BIC resonances verifies that the two quasi-BIC resonances of the metasurface are excited by electric dipoles and electric quadrupoles, respectively. Further simulation analysis demonstrates that the refractive index sensitivities of the two quasi-BIC modes of the metasurface reach 404.5 GHz/RIU and 578.6 GHz/RIU, respectively. Finally, the functional material PHMB is introduced into the metasurface to achieve highly sensitive sensing and detection of CO2 gas concentrations. The proposed metallic metasurface structure exhibits significant advantages, including high sensitivity, ease of preparation, and a high Q-value, which renders it highly promising for a broad range of applications in the domains of terahertz biosensing and highly sensitive gas sensing. Full article
(This article belongs to the Special Issue The Advanced Flexible Electronic Devices: 2nd Edition)
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18 pages, 3039 KiB  
Article
Security Symmetry in Embedded Systems: Using Microsoft Defender for IoT to Detect Firmware Downgrade Attacks
by Marian Hristov, Maria Nenova and Viktoria Dimitrova
Symmetry 2025, 17(7), 1061; https://doi.org/10.3390/sym17071061 - 4 Jul 2025
Viewed by 367
Abstract
Nowadays, the world witnesses cyber attacks daily, and these threats are becoming exponentially sophisticated due to advances in Artificial Intelligence (AI). This progress allows adversaries to accelerate malware development and streamline the exploitation process. The motives vary, and so do the consequences. Unlike [...] Read more.
Nowadays, the world witnesses cyber attacks daily, and these threats are becoming exponentially sophisticated due to advances in Artificial Intelligence (AI). This progress allows adversaries to accelerate malware development and streamline the exploitation process. The motives vary, and so do the consequences. Unlike Information Technology (IT) breaches, Operational Technology (OT)—such as manufacturing plants, electric grids, or water and wastewater facilities—compromises can have life-threatening or environmentally hazardous consequences. For that reason, this article explores a potential cyber attack against an OT environment—firmware downgrade—and proposes a solution for detection and response by implementing Microsoft Defender for IoT (D4IoT), one of the leading products on the market for OT monitoring. To detect the malicious firmware downgrade activity, D4IoT was implemented in a pre-commissioning (non-production) environment. The solution passively monitored the network, identified the deviation, and generated alerts for response actions. Testing showed that D4IoT effectively detected the firmware downgrade attempts based on a protocol analysis and asset behavior profiling. These findings demonstrate that D4IoT provides valuable detection capabilities against an intentional firmware downgrade designed to exploit known vulnerabilities in the older, less secure version, thereby strengthening the cybersecurity posture of OT environments. The explored attack scenario leverages the symmetry between genuine and malicious firmware flows, where the downgrade mimics the upgrade process, aiming to create challenges in detection. The proposed solution discerns adversarial actions from legitimate firmware changes by breaking this functional symmetry through behavioral profiling. Full article
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23 pages, 5294 KiB  
Article
CMB Parity Asymmetry from Unitary Quantum Gravitational Physics
by Enrique Gaztañaga and K. Sravan Kumar
Symmetry 2025, 17(7), 1056; https://doi.org/10.3390/sym17071056 - 4 Jul 2025
Viewed by 273
Abstract
Longstanding anomalies in the Cosmic Microwave Background (CMB), including the low quadrupole moment and hemispherical power asymmetry, have recently been linked to an underlying parity asymmetry. We show here how this parity asymmetry naturally arises within a quantum framework that explicitly incorporates the [...] Read more.
Longstanding anomalies in the Cosmic Microwave Background (CMB), including the low quadrupole moment and hemispherical power asymmetry, have recently been linked to an underlying parity asymmetry. We show here how this parity asymmetry naturally arises within a quantum framework that explicitly incorporates the construction of a geometric quantum vacuum based on parity (P) and time-reversal (T) transformations. This framework restores unitarity in quantum field theory in curved spacetime (QFTCS). When applied to inflationary quantum fluctuations, this unitary QFTCS formalism predicts parity asymmetry as a natural consequence of cosmic expansion, which inherently breaks time-reversal symmetry. Observational data strongly favor this unitary QFTCS approach, with a Bayes factor, the ratio of marginal likelihoods associated with the model given the data pM|D, exceeding 650 times that of predictions from the standard inflationary framework. This Bayesian approach contrasts with the standard practice in the CMB community, which evaluates pD|M, the likelihood of the data under the model, which undermines the importance of low- physics. Our results, for the first time, provide compelling evidence for the quantum gravitational origins of CMB parity asymmetry on large scales. Full article
(This article belongs to the Special Issue Quantum Gravity and Cosmology: Exploring the Astroparticle Interface)
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35 pages, 3949 KiB  
Review
The Influence of Defect Engineering on the Electronic Structure of Active Centers on the Catalyst Surface
by Zhekun Zhang, Yankun Wang, Tianqi Guo and Pengfei Hu
Catalysts 2025, 15(7), 651; https://doi.org/10.3390/catal15070651 - 3 Jul 2025
Cited by 1 | Viewed by 713
Abstract
Defect engineering has recently emerged as a cutting-edge discipline for precise modulation of electronic structures in nanomaterials, shifting the paradigm in nanoscience from passive ‘inherent defect tolerance’ to proactive ‘defect-controlled design’. The deliberate introduction of defect—including vacancies, dopants, and interfaces—breaks the rigid symmetry [...] Read more.
Defect engineering has recently emerged as a cutting-edge discipline for precise modulation of electronic structures in nanomaterials, shifting the paradigm in nanoscience from passive ‘inherent defect tolerance’ to proactive ‘defect-controlled design’. The deliberate introduction of defect—including vacancies, dopants, and interfaces—breaks the rigid symmetry of crystalline lattices, enabling new pathways for optimizing catalysis performance. This review systematically summarizes the mechanisms underlying defect-mediated electronic structure at active sites regulation, including (1) reconstruction of the electronic density of states, (2) tuning of coordination microenvironments, (3) charge transfer and localization effects, (4) spin-state and magnetic coupling modulation, and (5) dynamic defect and interface engineering. These mechanisms elucidate how defect-induced electronic restructuring governs catalytic activity and selectivity. We further assess advanced characterization techniques and computational methodologies for probing defects-induced electronic states, offering deeper mechanistic insights at atomic scales. Finally, we highlight recent breakthroughs in defect-engineered nanomaterials for catalytic applications, including hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and beyond, while discussing existing challenges in scalability, defect stability, and structure–property causality. This review aims to provide actionable principles for the rational design of defects to tailor electronic structures toward next-generation energy technologies. Full article
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