Search Results (23)

Proton-conducting ceramics have gained significant attention in various applications. Yttrium-doped barium cerium zirconate (BaCe_xZr_1−x−yY_yO_3–δ) is the state-of-the-art proton-conducting electrolyte but poses a major challenge because of its high sintering temperature. Sintering aids have been found to substantially reduce the sintering temperature of BaCe_xZr_1−x−yY_yO_3–δ. This work evaluates, for the first time, the impact of NiO and ZnO addition in three different loadings (1, 3, 5 mol%), via wet mechanical mixing, on the sintering and electrical properties of a low cerium-containing composition, BaCe_0.2Zr_0.7Y_0.1O_3–δ (BCZY). The sintering temperature remarkably dropped from 1600 °C (for pure BCZY) to 1350 °C (for NiOBCZY and ZnOBCZY) while achieving > 95% densification. In general, ZnO gave higher densification than NiO, the highest being 99% for 5 mol% ZnOBCZY. Dilatometric studies revealed that ZnOBCZY attained complete shrinkage at temperatures lower than NiOBCZY. Up to 650 °C, ZnO showed higher conductivity compared to NiO for the same loading, mostly due to a higher extent of Zn incorporation inside the BCZY lattice as seen from the BCZY peak shift to a lower Bragg’s angle in X-ray diffractograms, and the bigger grain sizes of ZnO samples compared to NiO captured in scanning electron microscopy. At any temperature, the variation in conductivity as a function of sintering aid concentration followed the orders 1 mol% > 3 mol% > 5 mol% (for ZnO) and 1 mol% < 3 mol%~5 mol% (for NiO). This difference in conductivity trends has been attributed to the fact that Zn fully dissolves into the BCZY matrix, unlike NiO which mostly accumulates at the grain boundaries. At 600 °C, 1 mol% ZnOBCZY showed the highest conductivity of 5.02 mS/cm, which is, by far, higher than what has been reported in the literature for a Ce/Zr molar ratio <1. This makes ZnO a better sintering aid than NiO (in the range of 1 to 5 mol% addition) in terms of higher densification at a sintering temperature as low as 1350 °C, and higher conductivity. Full article

For decades, studies have been conducted on the efficiency of gas purification processes with wet scrubbers, including the Venturi scrubbers, and this is the most commonly addressed issue in the field literature. The Venturi scrubber consists of a Venturi nozzle and a cyclone. The article addresses the empirical and analytical studies on the annular–mist flow regime that exists in the throat of the Venturi nozzle with a square cross-section. The uniform distribution of droplets over the cross-section area of the Venturi’s throat strongly correlates with the efficiency of the gas cleaning process using Venturi scrubbers. Due to the above, studies on the physics of the phenomena that affect the quantity of small droplets present in the core of the flow are highly justified. The influence of body forces and diffusive mechanisms impacting the number of droplets in the core flow were investigated to tackle the problem in question. Consequently, the fractions of droplets susceptible to turbulent or inertial–turbulent diffusion mechanisms can now be predicted using the outcomes of the research carried out. The droplets were divided into three fractions that differed by their sizes as follows: airborne droplets I confirm thar italic can be removed in all cases. $(d_d\le$ 10 µm), medium-sized droplets $(d_d\le$ 20 µm), and largest droplets $(d_d$ = (50–150) µm). The estimation of diffusion coefficients $\left({\epsilon }_{d,M},{\epsilon }_{d,ref}\right)$ and stopping distances $\left(s_M,s_{ref}\right)$ of all fractions of droplets was carried out with the inclusion $\left({\epsilon }_{d,M},s_M\right)$ and exclusion $\left({\epsilon }_{d,ref},s_{ref}\right)$ of the Magnus lift force $\left(M\right)$ in equations of both the droplet’s stopping distance and its diffusion coefficient. The outcomes revealed that the inclusion of the M force translates significantly to the growth in values of ${\epsilon }_{d,M},s_M$ compared to ${\epsilon }_{d,ref},s_{ref}$. Hence, it was concluded that the M force impacts the increase in the speed of the diffusion of the droplets with $d_d\ge$ 16.45 µm, which is favorable. Hence, the inertial–turbulent diffusion of larger droplets and the turbulent diffusion of medium ones seem to be supported by the M force. The local velocity gradient, which varied within the region of the flow’s hydraulic stabilization also impacted the mass content of droplets with diameter $d_d\le$ 10 µm in the core of the flow. As the flow development progressed, the number of droplets measured at n = 5 Hz varied nonlinearly up to the point where the boundary layer thickness reached the channel radius. The quantity of small droplets in the main flow was significantly influenced by turbulence intensity $\left(Tu\right)$. The desired high number of small droplets in the core of the flow (mist flow) was estimated empirically, and it was achieved when gas flows at high speed and has a mean value of Tu. The former benefits the efficiency of gas purification. Investigations on the effects of body forces of inertia of the continuous phase on the separation of droplets with diameters of a few microns and sub-microns from the flow were performed by employing two channel elbows, namely $e_4$ and $e_1$. The curved channels were subsequently mounted at the end of the straight channel ($SC{h}_2$). The curvature angle ($\alpha$) of the $e_4$ and $e_1$ equaled 90 °C and 30 °C, respectively. The number of droplets existing in the mist flow was higher in value, as desired, when the $e_4$ was used, unlike $e_1$. Two-dimensional flow fields of the mist have been obtained using the Particle Imaging Velocimetry (PIV) technique and analyzed further. Topas LAP 332 Aerosol Spectrometer was used for the determination of droplet ($d_d\le$ 40 µm) size distribution (DSD) and particle concentrations, while the Droplet Size Analyzer D Kamika Instruments (DSA) was exploited to ascertain DSD of droplets with diameter $d_d>40$ µm. Full article

In order to study the texture evolution and the formation of an inhomogeneous microstructure in hot-rolled plate of grain-orientated silicon steel, Fe₃C (hexagonal) and ferrite phases in the subsurface layer were studied using electron backscatter diffraction. The results indicate that fiber texture (ferrite) mainly composed of {441}<104> and (110)[001] Goss oriented grains was formed at a depth of 25% of the thickness of hot-rolled plate. Matrix grains in the subsurface layer were arbitrary separated into irregular large grains (≥40 μm) and fine grains (<40 μm), and the grain boundary characteristics and texture evolution of matrix grains were studied. The results indicated that the formation of the colonies of fine grains was the result of dynamic recrystallization, and high-frequency low-misorientation-angle boundaries (0~20°) were formed between large grains (≥40 μm) and fine grains (<40 μm), which can be considered as the irregularity of large grains caused by solid-state wetting. Due to the texture evolution of large grains (≥40 μm), a large number of high-energy boundaries (20~45°) were formed between irregular large grains (≥40 μm), resulting in rapid consumption between adjacent large grains and the elongation of large grains along the rolling direction. Therefore, it can be assumed that the migration of low-misorientation-angle boundaries (0~20°) under solid-state wetting and high-energy boundaries (20~45°) are important mechanisms for non-uniform grain growth in hot-rolled plate of grain-orientated silicon steel. Full article

To enhance the safety and stability of lane change maneuvers for autonomous vehicles in adverse weather conditions, this paper proposes a quadratic programming−based trajectory planning algorithm for lane changing in rainy weather. Initially, in order to mitigate the risk of potential collisions on wet and slippery road surfaces, we incorporate the concept of road adhesion coefficients and delayed reaction time to refine the establishment of the minimum safety distance. This augmentation establishes constraints on lane change safety distances and delineates the boundaries of viable lane change domains within inclement weather contexts. Subsequently, adopting a hierarchical trajectory planning framework, we incorporate visibility cost functions and safety distance constraints during dynamic programming sampling to ensure the safety of vehicle operation. Furthermore, the vehicle lane change sideslip phenomenon is considered, and the optimal lane change trajectory is obtained based on the quadratic programming algorithm by introducing the maneuverability objective function. In conclusion, to verify the effectiveness of the algorithm, lateral linear quadratic regulator (LQR) and longitudinal double proportional−integral−derivative (DPID) controllers are designed for trajectory tracking. The results demonstrate the algorithm’s capability to produce continuous, stable, and collision−free trajectories. Moreover, the lateral acceleration varies within the range of ±1.5 m/s², the center of mass lateral deflection angle varies within the range of ±0.15°, and the yaw rate remains within the ±0.1°/s range. Full article

Magnesium-based alloys are highly sought after in the industry due to their lightweight and reliable strength. However, the hexagonal crystal structure of magnesium results in the mechanical properties’ anisotropy. This anisotropy is effectively addressed by alloying magnesium with elements like zirconium, zinc, and rare earth metals (REM). The addition of these elements promotes rapid seed formation, yielding small grains with a uniform orientation distribution, thereby reducing anisotropy. Despite these benefits, the formation of intermetallic phases (IP) containing Zn, Zr, and REM within the microstructure can be a concern. Some of these IP phases can be exceedingly hard and brittle, thus weakening the material by providing easy pathways for crack propagation along grain boundaries (GBs). This issue becomes particularly significant if intermetallic phases form continuous layers along the entire GB between two neighboring GB triple junctions, a phenomenon known as complete GB wetting. To mitigate the risks associated with complete GB wetting and prevent the weakening of the alloy’s structure, understanding the potential occurrence of a GB wetting phase transition and how to control continuous GB layers of IP phases becomes crucial. In the investigation of a commercial magnesium alloy, ZEK100, the GB wetting phase transition (i.e., between complete and partial GB wetting) was successfully studied and confirmed. Notably, complete GB wetting was observed at temperatures near the liquidus point of the alloy. However, at lower temperatures, a coexistence of a nano-scaled precipitate film and bulk particles with nonzero contact angles within the same GB was observed. This insight into the wetting transition characteristics holds potential to expand the range of applications for the present alloy in the industry. By understanding and controlling GB wetting phenomena, the alloy’s mechanical properties and structural integrity can be enhanced, paving the way for its wider utilization in various industrial applications. Full article

Grain boundaries (GBs) can be wetted by a second phase. This phase can be not only liquid (or melted), but it can also be solid. GB wetting can be incomplete (partial) or complete. In the case of incomplete (partial) wetting, the liquid forms in the GB droplets, and the second solid phase forms a chain of (usually lenticular) precipitates. Droplets or precipitates have a non-zero contact angle with the GB. In the case of complete GB wetting, the second phase (liquid or solid) forms in the GB continuous layers between matrix grains. These GB layers completely separate the matrix crystallites from each other. GB wetting by a second solid phase has some important differences from GB wetting by the melt phase. In the latter case, the contact angle always decreases with increasing temperature. If the wetting phase is solid, the contact angle can also increase with increasing temperature. Moreover, the transition from partial to complete wetting can be followed by the opposite transition from complete to partial GB wetting. The GB triple junctions are completely wetted in the broader temperature interval than GBs. Since Phase 2 is also solid, it contains GBs as well. This means that not only can Phase 2 wet the GBs in Phase 1, but the opposite can also occur when Phase 1 can wet the GBs in Phase 2. GB wetting by the second solid phase was observed in the Al-, Mg-, Co-, Ni-, Fe-, Cu-, Zr-, and Ti-based alloys as well as in multicomponent alloys, including high-entropy ones. It can seriously influence various properties of materials. Full article

To understand the effects of liquid viscosity and surface wettability on the outcomes for a drop impacting perpendicularly on a dry, clean surface at a normal temperature and pressure, experiments were conducted for a wide variety of droplets and substrate surfaces. These experiments included a range of receding contact angles (from ~18° to ~150°) and liquid viscosities (from 1 cp to 45 cp); the broadest such combination is yet published. The surface wettabilities were quantitatively characterized using a new set of definitions: superphillic (θ_rec < 30°), phillic (30° < θ_rec < 90°), phobic (90° < θ_rec < 150°), and superphobic (θ_rec > 150°). Six different outcome regimes were found (including a new beaded deposition outcome) as a function of Ohnesorge number, Weber number, and the cosine of the receding contact angle. The beaded deposition is a hybrid of the well-known splash and deposition outcomes. The critical Weber number that separates the outcome boundaries was found to be significantly influenced by both the Ohnesorge numbers and the receding contact angle. In particular, there is a consistent reduction in the critical Weber number from superphilic to philic to neutral wettability conditions. Interestingly, this same decreasing trend line continues from neutral to phobic to superphobic conditions, but instead, it separates the regimes of deposition and bouncing. At higher Weber numbers, an additional boundary regime was found between splashing and bounce, which also decreased as the surface wettability decreased. This same type of trend was seen for several Ohnesorge numbers, indicating that wetting characterization should be based on the contact angles for the combination of the droplet liquid and the surface. In addition, a new regime map for droplet rebound on superphobic surfaces was obtained from the present and previous results indicating (for the first time) that the total rebound generally occurs for Weber numbers between 2.2 and 32 with Ohnesorge numbers less than 0.17. Additional studies are recommended to explore an even broader range of test conditions (especially intermediate wettability conditions), the separate influence of advancing and/or hysteresis contact angles, and to include the effects of the inclination angle, gas pressure, and heat transfer. Full article

The results of systematic studies on the surface energy γ and its polar γ^P and dispersion γ^D components of statistical copolymers of styrene and butadiene, acrylonitrile and butadiene, and butyl acrylate and vinyl acetate, with regard to their thermal prehistory, are generalized. Along with copolymers, the surfaces of their composing homopolymers were examined. We obtained the energy characteristics of the adhesive surfaces of copolymers that contacted with air, high-energy aluminium Al (γ = 160 mJ/m²), and the low-energy substrate surface of polytetrafluoroethylene F4 (PTFE) (γ = 18 mJ/m²). The surfaces of copolymers in contact with air, aluminium, and PTFE were investigated for the first time. It was found that the surface energy of these copolymers tended to occupy an intermediate value between the surface energy of the homopolymers. The additive nature of the change in the surface energy of the copolymers with their composition, as previously established in the works of Wu, extends to the dispersive component of the free surface energy γ^D and the critical surface energy γ_cr, according to Zisman. It was shown that a significant influence on the adhesive activity of copolymers was exerted by the substrate surface upon which the adhesive was formed. Thus, for the butadiene–nitrile copolymer (BNC) samples formed in contact with a high-energy substrate, their surface energy growth was associated with a significant increase in the polar component of the surface energy γ^P from 2 mJ/m² for the samples formed in contact with air, to an increase from 10 to 11 mJ/m² for the samples formed in contact with Al. The reason why the interface influenced the change in the energy characteristics of the adhesives was the selective interaction of each macromolecule fragment with the active centres of the substrate surface. As a result, the composition of the boundary layer changed and it became enriched with one of the components. The structure of such layers is nonequilibrium. The thermal annealing of copolymers in the mode of a stepwise temperature increase led to a convergence in the values of γ, asymptotically tending to the value characteristic of the surface of the copolymers formed in air. The activation energies for the processes of the conformational rearrangements of the macromolecules in the surface layers of the copolymers were calculated. It was found that the conformational rearrangements of the macromolecules in the surface layers occurred as a result of the internal rotation of the functional groups that determined the polar component of the surface energy. Full article

This paper comparatively investigated the spreading process of an oil droplet on the surface of highly hydrophobic solid (Teflon) in air and water media using a high-speed imaging technology, and analyzed their differences in spreading behavior from the perspective of empirical relations and energy conservation. Furthermore, the classical HD and MKT wetting models were applied to describe the oil droplet spreading dynamics to reveal the spreading mechanism of oil droplets on the Teflon in different media environments. Results showed that the entire spreading process of oil droplets on Teflon in air could be separated into three stages: the early linear fast spreading stage following $\theta \left(t\right)={\theta }_0+kt$ , the intermediate exponential slow spreading stage obeying $\theta \left(t\right)=b{t}^{-3\alpha }$, and the late spreading stage described by $\theta \left(t\right)={\theta }_{\mathrm{eq}}+a\times \exp \left(-t/T\right)$. However, the dynamics behavior of dynamic contact angle during the oil droplet spreading on Teflon in water could be well described by these expressions, $\theta \left(t\right)={\theta }_0+kt$ and $\theta \left(t\right)={\theta }_{\mathrm{eq}}+a\times \exp \left(-t/T\right)$. Clearly, a significant difference in the oil droplet spreading behavior in air and water media was found, and the absence of the intermediate exponential spreading stage in the oil–water–Teflon system could be attributed to the difference in the dissipated energy of the system because the dissipation energy in the oil–water–solid system included not only the viscous dissipation energy of the boundary layer of oil droplet, but also that of the surrounding water which was not included in the dissipation energy of the oil–air–solid system. Moreover, the quantitative analysis of wetting models suggested that the MKT model could reasonably describe the late spreading dynamics of oil droplets (low TPCL velocities), while the HD model may be more suitable for describing the oil droplet spreading dynamics at the early and intermediate spreading stages (high TPCL velocities). Full article

Blazed gratings are the critical dispersion elements in spectral analysis instruments, whose performance depends on structural parameters and topography of the grating groove. In this paper, high diffraction efficiency silicon-blazed grating working at 800–2500 nm has been designed and fabricated. By diffraction theory analysis and simulation optimization based on the accurate boundary integral equation method, the blaze angle and grating constant are determined to be 8.8° and 4 μm, respectively. The diffraction efficiency is greater than 33.23% in the spectral range of 800–2500 nm and reach the maximum value of 85.62% at the blaze wavelength of 1180 nm. The effect of platform and fillet on diffraction efficiency is analyzed, and the formation rule and elimination method of the platform are studied. The blazed gratings are fabricated by anisotropic wet etching process using tilted (111) silicon substrate. The platform is minished by controlling etching time and oxidation sharpening process. The fillet radius of the fabricated grating is 50 nm, the blaze angle is 7.4°, and the surface roughness is 0.477 nm. Finally, the blazed grating is integrated in scanning micromirror to form scanning grating micromirror by MEMS fabrication technology, which can realize both optical splitting and scanning. The testing results show that the scanning grating micromirror has high diffraction efficiency in the spectral range of 810–2500 nm for the potential near-infrared spectrometer application. Full article

The stress corrosion cracking behavior of an Incoloy825/X65 bimetallic composite pipe welded joint in wet hydrogen sulfide (H₂S) environment was investigated by means of the creviced bent beam (CBB) test in this study. The microstructure, element distribution and crack propagation behavior of the welded joint were analyzed by optical microscope (OM), scanning electron microscope (SEM), electron dispersive spectroscopy (EDS) and electron backscatter diffraction (EBSD). The results showed that two types of cracks were observed in the Incoloy825/X65 bimetallic composite pipe welded joint in wet H₂S environment, they initiated from the notch and the intersection of the three zones (cladding Incoloy825, base X65 and weld), respectively, and propagated along the fusion boundary(FB) and the Type-II-like grain boundary. The mechanisms of the two types of cracks are due to the combination of anodic dissolution, stress and hydrogen. Near the FB, there are high angle grain boundaries, Type-I, Type-II and the Type-II-like grain boundaries, which have high SCC sensitivity. The element distribution in the intersection of the three zones and the crack tip is complex, with element diffusion, Cr loss and large residual strain. All these provide the conditions for cracks initiation and propagation. Full article

BN is the currently required segregant for perpendicular FePt media. We found that BN can be diffused from the MgTiOBN intermediate layer during a high temperature process. The FePtCAg film sputtered on MgTiOBN layers illustrates higher perpendicular magnetocrystalline anisotropy (K_u) (1.43 × 10⁷ erg/cm³) and coercivity (normal to film surface) (17 kOe) at 350 K compared to BN/FePtCAg/MgTiON film. From the microstructure, the FePtCAg film shows the granular structure on the MgTiOBN intermediate layer, but parts of the irregular FePt grains are agglomerated and partially separated in the matrix, with grains size being, on average, 26.7 nm. Cross-sectional imaging showed that the FePt grains have a truncated pyramid shape with a lower wetting angle, which is influenced by the surface energy of MgTiOBN. BN segregation at FePt grains or boundaries is still not clear. Using the electron energy loss spectrum (EELS), we found that part of the BN atoms were clearly observed in the FePt lattice and iron-boride oxide was indexed in the x-ray photoelectron spectroscopy (XPS) spectra. To determine the effects of BN segregant (from capping layer or intermediate layer) on the magnetic switching behavior of FePtCAg film, the intrinsic-(ΔH_int = 6.17 kOe, 6.54 kOe) and extrinsic- (ΔH_ext = 0.80 kOe, 0.39 kOe) switching field distribution (SFD) were measured by plotting saturated major- and unsaturated minor- hysteresis loops to evaluate the crystal orientation and microstructure (grains volume and distribution) for BN/FePtCAg/MgTiON and FePtCAg/MgTiOBN films, respectively. The main contribution of intrinsic SFD is the c-axis misalignment for the BN/FePt/MgTiON sample; however, the dispersed magnetic anisotropy has a higher input to intrinsic SFD for FePtCAg/MgTiOBN/CrRu film. Full article

Stator coils of automobiles in operation generate heat and are cooled by coolant poured from above. The flow characteristic of the coolant depends on the coil structure, flow condition, solid–fluid interaction, and fluid property, which has not been clarified due to its complexities. Since straight coils are aligned and layered with an angle at the coolant-touchdown region, the coil structure is simplified to a horizontal square rod array referring to an actual coil size. To obtain the flow and wetting characteristics, two-phase fluid flow simulations are conducted by using the phase-field lattice Boltzmann method. First, the flow onto the single-layered rod array is discussed. The wetting area is affected both by the rod gap and the wettability, which is normalized by the gap and the averaged boundary layer thickness. Then, the flow onto the multi-layered rod arrays is investigated with different rod gaps. The top layer wetting becomes longitudinal due to the reduction of the flow advection by the second layer. The wetting area jumps up at the second layer and increases proportionally to the below layers. These become remarkable at the narrow rod gap case, and finally, the dimensionless wetting area is discussed at each layer. Full article

In this review, we analyze the structure of multicomponent alloys without principal components (they are also called high entropy alloys—HEAs), containing not only metals but also hydrogen, nitrogen, carbon, boron, or silicon. In particular, we discuss the phenomenon of grain boundary (GB) wetting by the melt or solid phase. The GB wetting can be complete or incomplete (partial). In the former case, the grains of the matrix are completely separated by the continuous layer of the second phase (solid or liquid). In the latter case of partial GB wetting, the second solid phase forms, between the matrix grains, a chain of (usually lenticular) precipitates or droplets with a non-zero value of the contact angle. To deal with the morphology of GBs, the new GB tie-lines are used, which can be constructed in the two- or multiphase areas of the multidimensional HEAs phase diagrams. The GBs in HEAs in the case of complete or partial wetting can also contain hydrides, nitrides, carbides, borides, or silicides. Thus, GB wetting by the hydrides, nitrides, carbides, borides, or silicides can be used in the so-called grain boundary chemical engineering in order to improve the properties of respective HEAs. Full article

In this review, the phenomenon of grain boundary (GB) wetting by the second solid phase is analyzed for the high entropy alloys (HEAs). Similar to the GB wetting by the liquid phase, the GB wetting by the second solid phase can be incomplete (partial) or complete. In the former case, the second solid phase forms in the GB of a matrix, the chain of (usually lenticular) precipitates with a certain non-zero contact angle. In the latter case, it forms in the GB continuous layers between matrix grains which completely separate the matrix crystallites. The GB wetting by the second solid phase can be observed in HEAs produced by all solidification-based technologies. The particle chains or continuous layers of a second solid phase form in GBs also without the mediation of a liquid phase, for example by solid-phase sintering or coatings deposition. To describe the GB wetting by the second solid phase, the new GB tie-lines should be considered in the two- or multiphase areas in the multicomponent phase diagrams for HEAs. The GB wetting by the second solid phase can be used to improve the properties of HEAs by applying the so-called grain boundary engineering methods. Full article