Search Results (38)

Traditional coal quality assessment methods rely exclusively on the laboratory testing of physical samples, which impedes detailed stratigraphic evaluation and limits the integration of intelligent precision mining technologies. To resolve this challenge, this study investigates geophysical logging as an innovative method for coal quality prediction. By integrating scanning electron microscopy (SEM), X-ray analysis, and optical microscopy with interdisciplinary methodologies spanning mathematics, mineralogy, and applied geophysics, this research analyzes the coal quality and mineral composition of the Shanxi Formation coal seams in northern Jiangsu, China. A predictive model linking geophysical logging responses to coal quality parameters was established to delineate relationships between subsurface geophysical data and material properties. The results demonstrate that the Shanxi Formation coals are gas coal (a medium-metamorphic bituminous subclass) characterized by low sulfur content, low ash yield, low fixed carbon, high volatile matter, and high calorific value. Mineralogical analysis identifies calcite, pyrite, and clay minerals as the dominant constituents. Pyrite occurs in diverse microscopic forms, including euhedral and semi-euhedral fine grains, fissure-filling aggregates, irregular blocky structures, framboidal clusters, and disseminated particles. Systematic relationships were observed between logging parameters and coal quality: moisture, ash content, and volatile matter exhibit an initial decrease, followed by an increase with rising apparent resistivity (LLD) and bulk density (DEN). Conversely, fixed carbon and calorific value display an inverse trend, peaking at intermediate LLD/DEN values before declining. Total sulfur increases with density up to a threshold before decreasing, while showing a concave upward relationship with resistivity. Negative correlations exist between moisture, fixed carbon, calorific value lateral resistivity (LLS), natural gamma (GR), short-spaced gamma-gamma (SSGG), and acoustic transit time (AC). In contrast, ash yield, volatile matter, and total sulfur correlate positively with these logging parameters. These trends are governed by coalification processes, lithotype composition, reservoir physical properties, and the types and mass fractions of minerals. Validation through independent two-sample t-tests confirms the feasibility of the neural network model for predicting coal quality parameters from geophysical logging data. The predictive model provides technical and theoretical support for advancing intelligent coal mining practices and optimizing efficiency in coal chemical industries, enabling real-time subsurface characterization to facilitate precision resource extraction. Full article

Lanthanum strontium manganate (La_1−xSr_xMnO₃) is considered a highly promising material for the development of intelligent thermal control coatings due to its exceptional properties. Recent studies on this material have primarily utilized solid-state synthesis as the main preparation method. Research efforts have predominantly focused on investigating the effects of material composition, heat treatment processes, and other factors on the properties of the synthesized material. There has been a limited amount of research investigating the influence of chemical precipitation process parameters on the properties of the synthesized La_1−xSr_xMnO₃ material. In this study, the intelligent thermal control coating material La_0.8Sr_0.2MnO₃ was synthesized using the chemical precipitation method. The effects of varying precipitant concentrations on the properties of the synthesized material were investigated. When the precipitant concentration is 12 wt.% or 15 wt.%, the synthesized powder agglomerates predominantly form three-dimensional blocky structures after sintering. At lower concentrations such as 6 wt.% and 9 wt.%, the powder agglomerates predominantly form two-dimensional sheet-like structures after sintering. At precipitant concentrations of 6 wt.% and 9 wt.%, the strontium content in the synthesized powder becomes significantly lower than the designed theoretical value. When the precipitant concentration is relatively high, localized manganese aggregation occurs in the synthesized lanthanum strontium manganate material. The temperature dependence of the emittance test result indicates that the emissivity variation of La_0.8Sr_0.2MnO₃ material synthesized using 12 wt.% ammonia solution as precipitant reaches 0.428 from 173 K to 373 K, demonstrating excellent emissivity modulation performance. Full article

Poly(lactic acid) (PLA) is a widely used biobased polyester which can be derived from renewable resources. Due to its excellent properties, it has already been adopted in various industrial sectors. While PLA is compostable, its degradation to the environment is very slow, necessitating the development of efficient recycling methods. This study focuses on the chemical recycling via microwave-assisted alkaline hydrolysis of PLA and its copolymers with poly(ethylene azelate) (PEAz), aiming to recover both carboxylic acid monomers: lactic acid and azelaic acid. Moreover, our method tunes the degradation of PLA via the synthesis of the novel aliphatic PLA-based copolyesters, targeting engineering-like applications, specifically in the field of printed electronics. Various process parameters were analyzed, including the temperature and the duration of the experiments as well as different phase transfer catalysts. Complete degradation was achieved at low temperatures (110–125 °C) and short times (12–15 min) for the PLA-based copolyesters, offering significant environmental benefits, as considerably less energy is consumed compared to chemical conventional methods. So, by changing the composition of the copolyesters through the incorporation of PEAz blocky segments, the ester bonds became more susceptible to hydrolysis under alkaline conditions assisted with microwave irradiation. Additionally, enzymatic hydrolysis was also studied in parallel for comparative purposes, revealing low degradation rates, thus establishing the microwave-assisted alkaline hydrolysis as a solid and reliable method for tuning the degradation of PLA-based materials. Full article

This study conducted a systematic investigation on how Ca content affected Mg-6Al-1Sn alloys as anodes for Mg-air batteries in terms of their microstructure, electrochemical corrosion behavior, and discharge performance. According to the investigation results, incorporating Ca induces the formation of blocky β-Mg₁₇Al₁₂ phases containing Ca and refines the grain structure. Compared to Mg alloys without Ca, the alloys with Ca exhibit significantly improved self-corrosion resistance because the preferential enrichment of Ca at the grain boundaries within β-Mg₁₇Al₁₂ phases reduces the potential difference between β-Mg₁₇Al₁₂ phases and Mg matrix. Consequently, galvanic corrosion is mitigated, together with the effective suppression of the self-corrosion reaction of Mg anodes. Additionally, Mg alloy shows a higher anode utilization efficiency with Ca content. The combined results indicate that Mg-6Al-1Sn-0.5Ca alloy exhibits superior self-corrosion resistance and discharge properties vs. other tested compositions. Furthermore, the Mg-air battery using Mg-6Al-1Sn-0.5Ca alloy as the anode demonstrates a heavier average discharge potential and a utilization efficiency of 71.12%, which is 7.56% higher than Mg-6Al-1Sn alloy. Full article

This study aimed to investigate the disintegration resistance of schist on the eastern slope of the Tongman open-pit mine. It examined the effects of cycle number and mineral composition on the disintegration resistance indexes of four types of schist through thin section identification and laboratory disintegration resistance tests. Furthermore, we analyzed the morphological characteristics of the disintegration residues using laboratory tests. Based on pore micro-damage theory, the mechanisms responsible for the differences in disintegration resistance among the four types of schist were further explored. The results show a negative correlation between the disintegration resistance index and the number of cycles. For the same number of cycles, the disintegration resistance indices for the four schist types were ranked as follows: greenish-gray chlorite-bearing muscovite schist > gray weakly chloritized biotite–muscovite schist > greenish-gray muscovite schist > gray muscovite schist. The disintegration residues of schist samples were categorized into four morphological patterns: thin sheet-like, moderately thick sheet-like, blocky, and granular. These patterns were then thoroughly elucidated. The differences in the disintegration resistance characteristics of schist were closely related to their material composition. The microstructural pore damage within the rock is the essential factor causing schist disintegration. Variations in rock porosity led to differing damage factors, which explain the distinct disintegration resistance characteristics observed across the four types of schist. The proposed preventive measures, developed through a systematic analysis of schist disintegration mechanisms, provide an effective framework for slope stability management. This research offers valuable insights into the weathering characteristics of rock masses in slope engineering, which is significant for understanding the progressive failure modes of disintegrating metamorphic formations. Full article

Composite roll produced through casting methods typically remain in the as-cast state after forming. During the preparation process, extended exposure to high temperatures often results in microstructural coarsening at the interface and surface layers, restricting their mechanical performance. To overcome this limitation, we developed a novel vacuum billet forging process for the fabrication of composite rolls. By integrating numerical simulations with experimental validation, we successfully prepared a 42CrMo/Cr5 composite roll. The comprehensive characterization of the interface, including microstructure, elemental distribution, grain texture, grain type, and mechanical properties, was conducted using OM, SEM, EPMA, EBSD, Vickers hardness testing, and a universal testing machine. The relationship between the interface microstructure and mechanical performance was systematically analyzed. The results indicate that complete metallurgical bonding at the interface was achieved with an upsetting reduction ratio of 40% and a single-pass elongation reduction ratio of less than 10%. The interfacial microstructure consisted of four zones: the roll core exhibited lamellar pearlite and blocky ferrite; the diffusion layer near 42CrMo featured pearlite; the diffusion layer near Cr5 contained pearlite and Cr carbides; the Cr5 layer contained fine lamellar pearlite with a greater amount of dispersed Cr carbides. Significant diffusion of Cr and Ni elements was observed, with Cr diffusion extending to 70–90 μm. The interface grains experienced substantial deformation and recrystallization, enhancing the bonding strength. Tensile tests indicated that fracture occurred on the 42CrMo side, with yield and tensile strengths of 371 MPa and 729 MPa, respectively. The microhardness of the composite interface gradually increased from 190 HV to 305 HV without abrupt changes. A significant hardness difference was observed on both sides of the interface, while the variation within the diffusion layer was relatively smooth, indicating good bonding performance at the composite interface. Full article

In view of the deep burial depth, high formation pressure, and presence of top and bottom water in offshore extra-heavy-oil reservoirs, this paper conducts a study on the production performance and flow field variation law of steam huff-and-puff to steam flooding conversion in thick heavy-oil reservoirs based on physical simulation, and analyzes the development effect of the conversion from steam huff-and-puff to steam flooding. On this basis, by comprehensively considering the advantages of gravity-assisted steam flooding and a three-dimensional HHSD well pattern obtained from physical simulation experiments, this paper proposes a well pattern development mode of steam huff-and-puff to composite displacement and drainage, and analyzes the development effect of this well pattern mode using the reservoir numerical simulation method. The research results show that, compared with the planar well pattern of steam huff-and-puff to steam flooding conversion, the adoption of the three-dimensional well pattern can significantly improve the degree of reservoir production and the expansion dynamics of the steam chamber, and mitigate adverse effects such as the increase in water cut caused by top and bottom water on thermal recovery. The composite development of steam huff-and-puff to composite displacement and drainage can be divided into three stages: thermal communication, gravity drainage-assisted steam flooding, and thermal breakthrough erosion and oil washing. The steam chamber presents a development mode of “single-point development–rapid longitudinal expansion–rapid transverse expansion upon reaching the top–polymerization into a sheet”, and simultaneously possesses the oil displacement mechanisms of both steam displacement and gravity drainage. The proposed composite mode of steam huff-and-puff to composite displacement and drainage has guided the implementation of adjustment wells in the Bohai L Oilfield, and the recovery factor has been increased by about 20% compared with the steam huff-and-puff development of the basic well pattern. This study has reference and guiding significance for the efficient thermal recovery development of this oilfield. Full article

This study investigated the fabrication and characterization of large ceramic-reinforced TWIP (twinning-induced plasticity) steel matrix composites using the lost-foam casting technique. Various ceramic shapes and sizes, including blocky, flaky, rod-like, and granular forms, were evaluated for their suitability as reinforcement materials. The study found that rod-like and granular ceramics exhibited superior structural integrity and formed strong interfacial bonds with the TWIP steel matrix compared to blocky and flaky ceramics, which suffered from cracking and fragmentation. Detailed microstructural analysis using scanning electron microscopy (SEM) and industrial computed tomography (CT) revealed the mechanisms influencing the composite formation. The results demonstrated that rod-like and granular ceramics are better for reinforcing TWIP steel composites, providing excellent mechanical stability and enhanced performance. This work contributes to the development of advanced composite structures with potential applications in industries requiring high-strength and durable materials. Full article

A large amount of primary energy is lost due to friction, and the study of new additive materials to improve friction performance is in line with the concept of low carbon. Carbon nanotubes (CNTs) have advantages in drag reduction and wear resistance with their hollow structure and self-lubricating properties. This review investigated the mechanism of improving friction properties of blocky composites (including polymer, metal, and ceramic-based composites) with CNTs’ incorporation. The characteristic tubular structure and the carbon film make low wear rate and friction coefficient on the surface. In addition, the effect of CNTs’ aggregation and interfacial bond strength on the wear resistance was analyzed. Within an appropriate concentration range of CNTs, the blocky composites exhibit better wear resistance properties. Based on the differences in drag reduction and wear resistance in different materials and preparation methods, further research directions of CNTs have been suggested. Full article

Pressure solution processes taking place during diagenesis deeply modify the hydraulic properties of carbonates, affecting their mechanical layering and hence the dimension, distribution, and connectivity of high-angle fractures. The formation of stylolites is controlled by the texture of the host rock and therefore by the depositional environment and the diagenetic processes that involve it. This study reports the results of a multidisciplinary study carried out on a Jurassic–Cretaceous carbonate platform in southern Italy. The goal is to unravel the control exerted by single carbonate textures and specific diagenetic processes on the formation of bed-parallel stylolites. Microfacies analyses of thin sections are aimed at obtaining information regarding the composition and texture of the carbonates. Petrographic observations coupled with CL analyses are key to deciphering their diagenetic history. Results are consistent with carbonates originally deposited in a shallow-water realm in which carbonate mud is occasionally abundant. In this environment, early cementation inhibits their chemical compaction. In grain-supported facies, pressure solution is only localized at the grain contacts. During shallow burial diagenesis, precipitation of blocky calcite predates the formation of bed-parallel stylolites in the grain-supported facies. Contrarily, mud-supported facies favor chemical compaction, which results in stylolites showing a good lateral extension and thick sediment infill. A classification of different types of stylolite morphology is attempted in relation to facies texture. In detail, rougher morphology (sharp-peak) characterizes the stylolites nucleated in grain-supported facies, while smoother morphology (rectangular to wave-like) is observed in stylolites on mud-supported facies. Application of this knowledge can be helpful in constraining the diagenetic history of carbonate rocks cored from depth, and therefore predict the fracture stratigraphy properties of carbonates buried at depth. Full article

Multicomponent clay and cenosphere linings protecting ceramic parts exposed to contact with liquid metal during continuous steel casting (CSC) are intended to diminish thermo-mechanical stresses at the beginning of this process. They are effective in their role, but due to their brittle nature, parts of them come off during transport or mounting. The admixture of polypropylene fibers into linings helps to alleviate problems with handling such parts, though the interaction of such a modified material with liquid steel should be re-assessed. The present experiment involved the preparation of a crucible with a Thermacoat™ (Vesuvius, Skawina, Poland) lining with the addition of Belmix™ (Belgian Fibers Group NV, Mouscron, Belgium) fibers and filling it with a drop of liquid steel. Next, the crucible was sectioned and the changes in its microstructure and phase composition were investigated with optical, scanning and transmission electron microscopy (OM/SEM/TEM) methods. This showed that the modified lining retained its non-wetting property against the steel of the non-modified material. The part with the lining, being in direct contact with the liquid steel, developed a highly porous layer filled with AlSiOx amorphous flakes with some larger blocky Al₂O₃ and SiO₂ particles. Right below this, a heat-affected zone (HAZ) consisting of fine γ-Al₂O₃ platelets immersed in amorphous silica was formed. Some of the voids with a size corresponding to polymer fiber diameter carried significant carbon deposits on their walls. The performed investigation indicated that the polymer fiber-modified linings were capable of withstanding at least short-term contact with liquid steel without instantaneous defragmentation, i.e., they retained the good high-temperature properties of the non-modified material. Full article

The Panjshir Fe-Polymetallic ore deposit is a valuable geological resource in Afghanistan, rich in iron and multiple essential metallic minerals, with substantial potential for industrial development. The exploration phase faces challenges related to the complex geological settings, high variability of mineral compositions, and the need for advanced geophysical techniques to accurately locate and assess valuable metallic resources. Considering the strong magnetic characteristics exhibited by Fe-Polymetallic elements, geomagnetic data were employed to analyze and map the likely prospectivity of Fe-Polymetallic deposits within the study area. Multi-scale edge detection techniques were employed to accurately map the boundaries of magnetic bodies by utilizing the upward continued analytical signal amplitude. The presence of a fault system on the geological map confirmed the structural information derived from our edge detection techniques. Advanced magnetic data inversion techniques were employed to create a three-dimensional representation of the distribution of magnetic bodies linked to Fe-Polymetallic deposits. In our efforts to reduce the impact of remnant magnetization in the study area, we adopted a comprehensive strategy by employing both magnetic susceptibility and magnetization vector inversion techniques. The use of a sparse and blocky norm regularization [0,1,1,1] is well-suited for magnetic susceptibility inversion, while a blocky norm [0000,0000,0000] is the appropriate choice for magnetization vector inversion in our study. Ultimately, the zones characterized by a high magnetic susceptibility and a high magnetization amplitude are considered promising areas for potential Fe-polymetallic occurrences. Full article

The article reveals for the first time the features of nanoparticle morphology, phase compositions, and their changes when heating FePt and CoPt nanoalloys. Nanoparticles were obtained by co-reduction of precursor solution mixtures with hydrazine hydrate. The features were found by a complex of methods of X-ray diffraction (in situ XRD and X-ray scattering), TEM HR, and cyclic voltammetry. In addition, adsorbometry results were obtained, and the stability of different nanocluster structures was calculated by the molecular dynamics method. There were only FCC solid solutions in the X-ray patterns of the FePt and CoPt nanoalloys. According to XRD, in the case of nanoparticle synthesis with Fe and Co content less than 10 at. %, the composition of solid solutions was close to or practically equal to the composition of the as-synthesized nanoparticles quantified by inductively coupled plasma optical emission spectrometry. For systems synthesis with Fe and Co content greater than the above, the solubility limits (SLs) of Fe and Co in Pt were set 11.4 ± 0.7 at. % and 17.5 ± 0.6 at. %, respectively. Therefore, there were non-registered XRD extra-phases (XRNDPh-1) in the systems when C_Fe,Co ≥ SL. This statement was supported by the results of TEM HR and X-ray scattering: the smallest nanocrystals (1–2 nm) and amorphous particles were found, which qualitatively agreed with the sorbometry and SAXS results. Molecular dynamics calculations of stability for FePt and CoPt alloys claimed the structures of the most stable phase corresponded to phase diagrams (A1 and L12). Specific peculiarities of the morphology and compositions of the solid solutions of nanoalloys were established: structural blockiness (domain) and composition heterogeneity, namely, platinum enrichment of internal (deep) layers and homogenization of the nanoalloy compositions at relatively low temperatures (130–200 °C). The suggested model of the formation of nanoalloys during the synthesis, qualitatively, was compliant with the results of electrochemical deposition of FePt films on the surface of various electrodes. When nanocrystals of solid solutions (C(Fe, Co) < SL) were heated above specific temperatures, there were phase transformations with the formation of two-phase regions, with solid solutions enriched with platinum or iron (non-registered XRD phase XRNDPh-2). The newly formed phase was most likely intermetallic compounds, FePt₃, CoPt₃. As a result of the study, the model was developed, taking into account the nanoscale of the particles: XRDPh (A1, Fe_aPt_1−a) → XRDPh (A1, Fe_m×a−xPt_m−m×a+x) + XRNDPh-2 (Fe_n×a+yPt_n−n×a−y) (here, m + n = 1, m ≤ 1, n ≤ 1). Full article

In this study, the Fe-16Mn-9Al-0.8C-3Ni (wt.%) lightweight steel was fabricated by novel twin-roll strip casting technology. The microstructure, tensile properties and strain-hardening behavior of the present steel have been investigated and compared to those of conventionally processed steels with similar chemical compositions. After annealing, a unique gradient microstructure of intermetallic compound (B2)-austenite was obtained along the thickness direction, consisting of granular B2 (average: 430 nm) and fine austenite (average: 1.82 μm) at the surface layer, blocky B2 (average: 1.03 μm) and medium austenite (average: 3.98 μm) at the quarter layer and polygonal B2 (average: 1.94 μm) and coarse austenite (average: 6.13 μm) at the center layer. The cooperative action of B2 pinning dislocation, plane slip and back stress led to stronger strain hardening, among which the strong back stress effect originated from the multistage discontinuous austenite deformation and the mechanical incompatibility between austenite and B2 is believed to be the most important reason, thereby achieving an excellent balance of strength (ultimate tensile strength: 1147 MPa) and ductility (total elongation: 43.2%). This work not only developed a new processing way to fabricate Ni-containing Fe-Mn-Al-C lightweight steel with outstanding mechanical properties, but also provided a potential solution for manufacturing some other metallic materials accompanied by brittle B2 intermetallic. Full article

Pectin, a plant-derived polysaccharide, possesses immense technological and biological application value. Several variables influence pectin’s physicochemical aspects, resulting in different fermentations, interactions with receptors, and other functional properties. Some of those variables are molecular weight, degree of methylation and blockiness, and monosaccharide composition. Cancer cell cytotoxicity, important fermentation-related byproducts, immunomodulation, and technological application were found in cell culture, animal models, and preclinical and clinical assessments. One of the greater extents of recent pectin technological usage involves nanoencapsulation methods for many different compounds, ranging from chemotherapy and immunotherapy to natural extracts from fruits and other sources. Structural modification (modified pectin) is also utilized to enhance the use of dietary fiber. Although pectin is already recognized as a component of significant importance, there is still a need for a comprehensive review that delves into its intricate relationships with biological effects, which depend on the source and structure of pectin. This review covers all levels of clinical research, including cell culture, animal studies, and clinical trials, to understand how the plant source and pectin structures influence the biological effects in humans and some technological applications of pectin regarding human health. Full article