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Keywords = biogas enhancement

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35 pages, 1398 KiB  
Review
Process Intensification of Anaerobic Digestion of Biowastes for Improved Biomethane Production: A Review
by Sahil Sahil and Sonil Nanda
Sustainability 2025, 17(14), 6553; https://doi.org/10.3390/su17146553 - 17 Jul 2025
Viewed by 543
Abstract
Anaerobic digestion is a widely adopted technique for biologically converting organic biomass to biogas under oxygen-limited conditions. However, several factors, including the properties of biomass and its complex structure, make it challenging to degrade biomass effectively, thereby reducing the overall efficiency of anaerobic [...] Read more.
Anaerobic digestion is a widely adopted technique for biologically converting organic biomass to biogas under oxygen-limited conditions. However, several factors, including the properties of biomass and its complex structure, make it challenging to degrade biomass effectively, thereby reducing the overall efficiency of anaerobic digestion. This review examines the recent advancements in commonly used pretreatment techniques, including physical, chemical, and biological methods, and their impact on the biodegradability of organic waste for anaerobic digestion. Furthermore, this review explores integrated approaches that utilize two or more pretreatments to achieve synergistic effects on biomass degradation. This article highlights various additives and their physicochemical characteristics, which play a vital role in stimulating direct interspecies electron transfer to enhance biomethanation reaction rates. Direct electron interspecies transfer is a crucial aspect that accelerates electron transfer among syntrophic microbial communities during anaerobic digestion, thereby enhancing biomethane formation. Finally, this article reviews potential approaches, identifies research gaps, and outlines future directions to strengthen and develop advanced pretreatment strategies and novel additives to improve anaerobic digestion processes for generating high-value biogas. Full article
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4 pages, 429 KiB  
Proceeding Paper
Overview of the Use of Anaerobic Digestion on Swine Farms and the Potential for Bioenergy Production in Minas Gerais, Brazil
by Marcela de Souza Silva, Sibele Augusta Ferreira Leite and Brenno Santos Leite
Proceedings 2025, 121(1), 5; https://doi.org/10.3390/proceedings2025121005 - 17 Jul 2025
Viewed by 222
Abstract
This study provides a comprehensive panorama of wastewater treatment on swine farms in Pará de Minas, MG, focusing on the performance of the anaerobic digester technologies adopted. Considering the economic and environmental importance of swine production, wastewater treatment is critical for mitigating environmental [...] Read more.
This study provides a comprehensive panorama of wastewater treatment on swine farms in Pará de Minas, MG, focusing on the performance of the anaerobic digester technologies adopted. Considering the economic and environmental importance of swine production, wastewater treatment is critical for mitigating environmental impacts while providing renewable energy opportunities. Data compilation from the Minas Gerais Institute of Agriculture (IMA), technical visits, and physicochemical analyses were conducted. Our results indicate that the region has significant potential to increase biogas production by expanding the number of plants and improving the efficiency of existing systems. Investments in scalable technological solutions tailored for small-scale operations are essential to enhance both wastewater treatment and biogas generation. This study demonstrates the potential for new business opportunities within the biogas value chain in Brazilian agribusiness. Full article
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19 pages, 1165 KiB  
Article
Expansion of Mechanical Biological Residual Treatment Plant with Fermentation Stage for Press Water from Organic Fractions Involving a Screw Press
by Rzgar Bewani, Abdallah Nassour, Thomas Böning, Jan Sprafke and Michael Nelles
Recycling 2025, 10(4), 141; https://doi.org/10.3390/recycling10040141 - 16 Jul 2025
Viewed by 279
Abstract
A three-year optimization study was conducted at a mechanical biological treatment plant with the aim of enhancing organic fractions recovery from mechanically separated fine fractions (MSFF) of residual waste using a screw press. The study aimed to optimize key operating parameters for the [...] Read more.
A three-year optimization study was conducted at a mechanical biological treatment plant with the aim of enhancing organic fractions recovery from mechanically separated fine fractions (MSFF) of residual waste using a screw press. The study aimed to optimize key operating parameters for the employed screw press, such as pressure, liquid-to-MSFF, feeding quantity per hour, and press basket mesh size, to enhance volatile solids and biogas recovery in the generated press water for anaerobic digestion. Experiments were performed at the full-scale facility to evaluate the efficiency of screw press extraction with other pretreatment methods, like press extrusion, wet pulping, and hydrothermal treatment. The results indicated that hydrolysis of the organic fractions in MSFF was the most important factor for improving organic extraction from the MSFF to press water for fermentation. Optimal hydrolysis efficiency was achieved with a digestate and process water-to-MSFF of approximately 1000 L/ton, with a feeding rate between 8.8 and 14 tons per hour. Increasing pressure from 2.5 to 4.0 bar had minimal impact on press water properties or biogas production, regardless of the press basket size. The highest volatile solids (29%) and biogas (50%) recovery occurred at 4.0 bar pressure with a 1000 L/ton liquid-to-MSFF. Further improvements could be achieved with longer mixing times before pressing. These findings demonstrate the technical feasibility of the pressing system for preparing an appropriate substrate for the fermentation process, underscoring the potential for optimizing the system. However, further research is required to assess the cost–benefit balance. Full article
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16 pages, 2079 KiB  
Article
Biogas Production from Agave durangensis Mezcal Bagasse Pretreated Using Chemical Processes
by Refugio Hernández-López, Iván Moreno-Andrade, Blanca E. Barragán-Huerta, Edson B. Estrada-Arriaga and Marco A. Garzón-Zúñiga
Fermentation 2025, 11(7), 399; https://doi.org/10.3390/fermentation11070399 - 12 Jul 2025
Viewed by 479
Abstract
This study evaluated the viability of using the solid residues (bagasse) of the mezcal industry produced with Agave durangensis as a substrate for biogas production, using two chemical pretreatments, acid (HCl) and alkaline (KOH + Ca(OH)2), to enhance its biodegradability and [...] Read more.
This study evaluated the viability of using the solid residues (bagasse) of the mezcal industry produced with Agave durangensis as a substrate for biogas production, using two chemical pretreatments, acid (HCl) and alkaline (KOH + Ca(OH)2), to enhance its biodegradability and improve the anaerobic digestion (AD) process. The chemical composition of bagasse was analyzed before and after the chemical pretreatments and then AD experiments were conducted in anaerobic sequential batch reactors (A-SBR) to analyze the effect of pretreatments on biogas production performance. The results showed that acid pretreatment increased cellulose content to 0.606 g, which represented an increase of 34%, and significantly reduced hemicellulose. In contrast, alkaline pretreatment did not show significant changes in cellulose composition, although it caused a swelling of the Agave durangensis mezcal bagasse (Ad-MB) fibers. In terms of biogas production, Ad-MB pretreated with acid (Ad-MB-acid) increased cumulative production by 76% compared to the Agave durangensis mezcal bagasse that was not pretreated (Ad-MB-not pretreated) and by 135% compared to Agave durangensis mezcal bagasse pretreated with an alkaline solution (Ad-MB-alkaline). These results confirmed that Agave durangensis solid waste from the mezcal industry that receives acidic chemical pretreatment has the potential to generate biogas as a sustainable biofuel that can be used to reduce the ecological footprint of this industry. Full article
(This article belongs to the Special Issue Biofuels Production and Processing Technology, 3rd Edition)
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25 pages, 1275 KiB  
Review
Biogas Slurry as a Sustainable Organic Fertilizer for Sorghum Production in Sandy Soils: A Review of Feedstock Sources, Application Methods, and Agronomic Impacts
by Yanga Mgxaji, Charles S. Mutengwa, Patrick Mukumba and Admire R. Dzvene
Agronomy 2025, 15(7), 1683; https://doi.org/10.3390/agronomy15071683 - 11 Jul 2025
Viewed by 351
Abstract
Biogas slurry (BGS), a nutrient-rich by-product of anaerobic digestion, presents a promising opportunity for sustainable agriculture on sandy soils. This review explores the agronomic potential of using BGS for improving sorghum’s (Sorghum bicolor) productivity by enhancing soil fertility and the nutrient [...] Read more.
Biogas slurry (BGS), a nutrient-rich by-product of anaerobic digestion, presents a promising opportunity for sustainable agriculture on sandy soils. This review explores the agronomic potential of using BGS for improving sorghum’s (Sorghum bicolor) productivity by enhancing soil fertility and the nutrient availability. It focuses on the sources and properties of BGS, its application methods, and their effects on the soil nutrient dynamics and crop productivity. The findings indicate that BGS improves the soil health and crop yields, offering an eco-friendly alternative to synthetic fertilizers, especially in resource-limited settings. Despite these benefits, research gaps persist, including the need for long-term field trials, the optimization of application strategies for sandy soils, and comprehensive economic evaluations. Additionally, concerns such as nutrient imbalances, phosphorus accumulation, and slurry composition variability must be addressed. This review recommends standardizing BGS nutrient profiling and adopting site-specific management practices to maximize its agronomic benefits and environmental safety. Integrating BGS into sustainable soil fertility programs could contribute significantly to achieving agricultural resilience and circular economy goals. Full article
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17 pages, 1396 KiB  
Article
Enhancing Disaster Resilience Through Mobile Solar–Biogas Hybrid PowerKiosks
by Seneshaw Tsegaye, Mason Lundquist, Alexis Adams, Thomas H. Culhane, Peter R. Michael, Jeffrey L. Pearson and Thomas M. Missimer
Sustainability 2025, 17(14), 6320; https://doi.org/10.3390/su17146320 - 10 Jul 2025
Viewed by 358
Abstract
Natural disasters in the United States frequently wreak havoc on critical infrastructure, affecting energy, water, transportation, and communication systems. To address these disruptions, the use of mobile power solutions like PowerKiosk trailers is a partial solution during recovery periods. PowerKiosk is a trailer [...] Read more.
Natural disasters in the United States frequently wreak havoc on critical infrastructure, affecting energy, water, transportation, and communication systems. To address these disruptions, the use of mobile power solutions like PowerKiosk trailers is a partial solution during recovery periods. PowerKiosk is a trailer equipped with renewable energy sources such as solar panels and biogas generators, offering a promising strategy for emergency power restoration. With a daily power output of 12.1 kWh, PowerKiosk trailers can support small lift stations or a few homes, providing a temporary solution during emergencies. Their key strength lies in their mobility, allowing them to quickly reach disaster-affected areas and deliver power when and where it is most needed. This flexibility is particularly valuable in regions like Florida, where hurricanes are common, and power outages can cause widespread disruption. Although the PowerKiosk might not be suitable for long-term use because of its limited capacity, it can play a critical role in disaster recovery efforts. In a community-wide power outage, deploying the PowerKiosk to a lift station ensures essential services like wastewater management, benefiting everyone. By using this mobile power solution, community resilience can be enhanced in the face of natural disasters. Full article
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31 pages, 2780 KiB  
Article
Multi-Criteria Analysis in the Selection of Alternative Fuels for Pulse Engines in the Aspect of Environmental Protection
by Grzegorz M. Szymański, Bogdan Wyrwas, Klaudia Strugarek, Mikołaj Klekowicki, Malwina Nowak, Aleksander Ludwiczak and Alicja Szymańska
Energies 2025, 18(14), 3604; https://doi.org/10.3390/en18143604 - 8 Jul 2025
Viewed by 313
Abstract
The growing interest in alternative fuels stems from the need to reduce greenhouse gas emissions and promote sustainable development. Despite the dominance of fossil fuels in aviation, pulsejet engines offer a promising platform for testing new fuels due to their simple design and [...] Read more.
The growing interest in alternative fuels stems from the need to reduce greenhouse gas emissions and promote sustainable development. Despite the dominance of fossil fuels in aviation, pulsejet engines offer a promising platform for testing new fuels due to their simple design and fuel versatility. This study presents a multi-criteria analysis of alternative fuels for use in pulsejet engines, emphasizing environmental impacts. Both gaseous (biogas, ethyne, LPG, and natural gas) and liquid fuels (methanol, ethanol, biodiesel, Jet A-1, and SAF) were examined. Exhaust emissions (CO2, H2O, CO) were simulated in Ansys 2025 based on literature data and chemical calculations. Additional factors analyzed included calorific value, production cost, thermal expansion, density, life cycle emissions (LCA), CO2 emissions per fuel mass, and renewable energy content. Using the zero-unitization method, results were normalized into a single aggregate variable for each fuel. The highest values were recorded for biogas and methanol, respectively, indicating their potential as alternative fuels. The findings support further development of sustainable fuels for pulsejet engines. Future research should address combustion optimization and noise reduction, enhancing viability in aviation and other transport sectors. Integration with the current fuel infrastructure is also recommended to facilitate broader implementation. Full article
(This article belongs to the Special Issue Challenges and Research Trends of Exhaust Emissions)
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16 pages, 2838 KiB  
Article
Transcriptomic Response of Azospirillum brasilense Co-Cultured with Green Microalgae Chlorella sp. and Scenedesmus sp. During CO2 Biogas Fixation
by Carolina Garciglia-Mercado, Oskar A. Palacios, Claudia A. Contreras-Godínez, Jony Ramiro Torres-Velázquez and Francisco J. Choix
Processes 2025, 13(7), 2177; https://doi.org/10.3390/pr13072177 - 8 Jul 2025
Viewed by 695
Abstract
Microalgal–bacterial consortia are the environmentally sustainable biotechnological strategy to enhance the potential of microalgae. Understanding the regulatory mechanisms that enable bacteria to adapt to culture conditions of each bioprocess is crucial to ensure a successful synergic interaction. Thus, the present study evaluated the [...] Read more.
Microalgal–bacterial consortia are the environmentally sustainable biotechnological strategy to enhance the potential of microalgae. Understanding the regulatory mechanisms that enable bacteria to adapt to culture conditions of each bioprocess is crucial to ensure a successful synergic interaction. Thus, the present study evaluated the transcriptomic response of microalgal growth-promoting bacteria (MGPB) A. brasilense separately co-cultured with both green microalgae Scenedesmus sp. and Chlorella sorokiniana during CO2 fixation from biogas through a microarray-based approach. The transcriptome profiling revealed a total of 416 differentially expressed genes (DEGs) in A. brasilense: 228 (140 upregulated and 88 downregulated) interacting with Scenedesmus sp. and 188 (40 upregulated and 148 downregulated) associated with C. sorokiniana. These results support the modulation of signal molecules: indole-3-acetic acid (IAA), riboflavin, and biotin, during co-cultivation with both microalgae. The findings suggest that the metabolic A. brasilense adaptation was mainly favored during the mutualistic interaction with Scenedesmus sp. Finally, a valuable contribution is provided to the biotechnological potential of the microalga–Azospirillum consortium as an environmentally sustainable strategy to improve the bio-refinery capacity of these microalgae and biogas upgrading by valorizing CO2 of these gaseous effluent. Full article
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20 pages, 2601 KiB  
Article
Waste as a Source of Fuel and Developments in Hydrogen Storage: Applied Cases in Spain and Their Future Potential
by Juan Pous de la Flor, María-Pilar Martínez-Hernando, Roberto Paredes, Enrique Garcia-Franco, Juan Pous Cabello and Marcelo F. Ortega
Appl. Sci. 2025, 15(13), 7514; https://doi.org/10.3390/app15137514 - 4 Jul 2025
Viewed by 362
Abstract
The integration of renewable energy with circular economy strategies offers effective pathways to reduce greenhouse gas emissions while enhancing local energy independence. This study analyses three real-world projects implemented in Spain that exemplify this synergy. LIFE Smart Agromobility converts pig manure into biomethane [...] Read more.
The integration of renewable energy with circular economy strategies offers effective pathways to reduce greenhouse gas emissions while enhancing local energy independence. This study analyses three real-world projects implemented in Spain that exemplify this synergy. LIFE Smart Agromobility converts pig manure into biomethane to power farm vehicles, using anaerobic digestion and microalgae-based upgrading systems. Smart Met Value refines biogas from a wastewater treatment plant in Guadalajara to produce high-purity biomethane for the municipal fleet, demonstrating the viability of energy recovery from sewage sludge. The UNDERGY project addresses green hydrogen storage by repurposing a depleted natural gas reservoir, showing geochemical and geomechanical feasibility for seasonal underground hydrogen storage. Each project utilises regionally available resources to produce clean fuels—biomethane or hydrogen—while mitigating methane and CO2 emissions. Results show significant energy recovery potential: biomethane production can replace a substantial portion of fossil fuel use in rural and urban settings, while hydrogen storage provides a scalable solution for surplus renewable energy. These applied cases demonstrate not only the technical feasibility but also the socio-economic benefits of integrating waste valorisation and energy transition technologies. Together, they represent replicable models for sustainable development and energy resilience across Europe and beyond. Full article
(This article belongs to the Section Energy Science and Technology)
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26 pages, 14647 KiB  
Article
Coordinated Dispatch Between Agricultural Park and Distribution Network: A Stackelberg Game Based on Carbon Emission Flow
by Jiahao Gou, Hailong Cui and Xia Zhao
Processes 2025, 13(7), 2102; https://doi.org/10.3390/pr13072102 - 2 Jul 2025
Viewed by 277
Abstract
With the acceleration of global climate warming and agricultural modernization, the energy and carbon emission issues of agricultural parks (APs) have drawn increasing attention. An AP equipped with biogas-based combined heat and power (CHP) generation and photovoltaic systems serves as a prosumer terminal [...] Read more.
With the acceleration of global climate warming and agricultural modernization, the energy and carbon emission issues of agricultural parks (APs) have drawn increasing attention. An AP equipped with biogas-based combined heat and power (CHP) generation and photovoltaic systems serves as a prosumer terminal in a distribution network (DN). This paper introduces carbon emission flow (CEF) theory into the coordinated dispatch of APs and DNs. First, a CEF model for APs is established. Then, based on this model, a carbon–energy coordinated dispatch is carried out under bidirectional CEF interaction between the park and DN. A bidirectional carbon tax mechanism is adopted to explore the low-carbon synergy potential between them. Finally, the Stackelberg game approach is employed to address the pricing of electricity purchase/sale and carbon taxes in a DN, and the particle swarm optimization algorithm is used for rapid generating solutions. The case study shows that the proposed CEF model can effectively determine CEF distribution in the park. Moreover, the proposed bidirectional carbon tax mechanism significantly enhances the low-carbon economic benefits of both the AP and the DN. Full article
(This article belongs to the Special Issue Modeling, Optimization, and Control of Distributed Energy Systems)
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15 pages, 2591 KiB  
Article
Anaerobic Co-Digestion of Dairy Manure and Cucumber Residues: Methane Production Efficiency and Microbial Community Characteristics
by Yanqin Wang, Yan Li, Yumeng Qi, Longyun Fu, Guangjie Li, Zhaodong Liu, Luji Bo and Yongping Jing
Agronomy 2025, 15(7), 1610; https://doi.org/10.3390/agronomy15071610 - 1 Jul 2025
Viewed by 329
Abstract
Anaerobic digestion for biogas production represents a crucial approach to achieving the high-value utilization of agricultural solid waste. The adoption of multi-material co-digestion offers a viable solution to overcome the inherent constraints associated with single-substrate digestion, thereby significantly enhancing the efficiency of resource [...] Read more.
Anaerobic digestion for biogas production represents a crucial approach to achieving the high-value utilization of agricultural solid waste. The adoption of multi-material co-digestion offers a viable solution to overcome the inherent constraints associated with single-substrate digestion, thereby significantly enhancing the efficiency of resource utilization. This study explored a co-digestion system using dairy manure and cucumber vines as substrates, uncovering how total solids (TS) influence the methane yield and microbial community characteristics. All treatments exhibited swift methane fermentation, with daily production initially increasing before declining. Cumulative methane production increased with the increasing TS contents. These results may be linked to pH value and the concentration of volatile fatty acids (VFAs). Except for the 6% TS treatment, digesters across different TS levels maintained a favorable final pH of 7.4–8.4, while VFA concentrations exhibited a downward trend as TS contents increased. The treatment with the highest TS concentration (25%) demonstrated superior performance, achieving the maximum volumetric methane yield. This yield was 1.6 to 9.1 times higher than those obtained at low (6–10%) and medium (12–18%) TS concentrations. Microbial community analysis revealed that during the peak methane production phase, Firmicutes and Methanoculleus were the predominant bacterial and archaeal phyla, respectively. The microbial community structure changed with different TS levels. This study offers valuable scientific insights for enhancing biogas production efficiency in co-digestion systems. Full article
(This article belongs to the Section Agricultural Biosystem and Biological Engineering)
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14 pages, 1154 KiB  
Article
Enhancing Biomethane Yield from Microalgal Biomass via Enzymatic Hydrolysis: Optimization and Predictive Modeling Using RSM Approach
by Souhaila Hangri, Kerroum Derbal, Abderrezzaq Benalia, Grazia Policastro, Antonio Panico and Antonio Pizzi
Processes 2025, 13(7), 2086; https://doi.org/10.3390/pr13072086 - 1 Jul 2025
Viewed by 327
Abstract
This study investigates the optimization of enzymatic hydrolysis for enhancing carbohydrate release from microalgal biomass and its subsequent impact on methane production during anaerobic digestion. Using Response Surface Methodology with a Box–Behnken design comprising 15 experimental runs, the effects of enzyme loading (20–40 [...] Read more.
This study investigates the optimization of enzymatic hydrolysis for enhancing carbohydrate release from microalgal biomass and its subsequent impact on methane production during anaerobic digestion. Using Response Surface Methodology with a Box–Behnken design comprising 15 experimental runs, the effects of enzyme loading (20–40 mg/gVS), pH (4.5–5.5), and incubation time (24–72 h) were evaluated. A quadratic regression model was developed to predict carbohydrate release, revealing significant interactions between these factors. The optimal conditions for enzymatic hydrolysis were determined to be a cellulase dose of 20 mg/gVS, pH 5.0, and an incubation period of 72 h. The model demonstrated excellent predictive accuracy, with an R2 value of 0.9894 and an adjusted R2 of 0.9704. Enzymatic hydrolysis significantly improved methane and biogas yields, with cumulative production reaching 52.50 mL/gVS and 95.62 mL/gVS, respectively, compared to 6.98 mL/gVS and 20.94 mL/gVS for untreated samples. The findings highlight the importance of optimizing enzyme loading and reaction time, while pH variations within the studied range had minimal impact. This study underscores the potential of enzymatic hydrolysis to enhance the bioavailability of organic matter, thereby improving the efficiency of anaerobic digestion for biogas production. Full article
(This article belongs to the Special Issue Advanced Biofuel Production Processes and Technologies)
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31 pages, 5258 KiB  
Article
Sustainable Scaling in Forest-Based Circular Models
by Eleonora Santos
Sustainability 2025, 17(13), 5967; https://doi.org/10.3390/su17135967 - 28 Jun 2025
Cited by 2 | Viewed by 391
Abstract
The transition to a circular economy is essential for enhancing sustainability and resource efficiency, particularly in forestry-dependent regions. This study examines circular economy business models (CEBMs) in Kouvola, Finland, focusing on the utilization of forestry by-products. It compares two case studies: Keltakangas Waste [...] Read more.
The transition to a circular economy is essential for enhancing sustainability and resource efficiency, particularly in forestry-dependent regions. This study examines circular economy business models (CEBMs) in Kouvola, Finland, focusing on the utilization of forestry by-products. It compares two case studies: Keltakangas Waste Station, which processes wood waste into biogas, and Koumet, a forestry company producing biochar. Using a comparative case study approach, this research integrates financial analysis (2020–2023), interviews with managers, and policy reviews to assess economic performance, scalability, and environmental impact. Additionally, this study introduces a generalizable framework—Scalability Path Dependency (SPD)—which theorizes how early strategic decisions shape the long-term growth trajectories of circular business models. The findings reveal that Keltakangas follows a capital-intensive model with declining profit margins, while Koumet operates a resource-efficient model with stable but low profitability. Their scaling strategies diverge: Keltakangas relies on external financing for expansion, whereas Koumet emphasizes cost efficiency and market diversification. Despite ongoing challenges related to infrastructure, regulation, and financial viability, both models contribute meaningfully to circularity. This study offers actionable insights for policymakers and businesses aiming to support sustainable forestry practices. Full article
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16 pages, 1769 KiB  
Article
Anaerobic Co-Digestion of Cattle Manure and Sewage Sludge Using Different Inoculum Proportions
by Caroline Carvalho Pinto, Juliana Lobo Paes, Alexia de Sousa Gomes, Daiane Cecchin, Igor Ferreira Oliva, Romulo Cardoso Valadão and Vânia Reis de Souza Sant’Anna
Fermentation 2025, 11(7), 373; https://doi.org/10.3390/fermentation11070373 - 28 Jun 2025
Viewed by 608
Abstract
Anaerobic digestion (AD) is a sustainable strategy for converting hazardous wastes into renewable energy while supporting Sustainable Development Goals (SDGs). This study aimed to evaluate the effect of inoculum on optimizing biogas production from sewage sludge (SS) and cattle manure (CM). Bench-scale digesters [...] Read more.
Anaerobic digestion (AD) is a sustainable strategy for converting hazardous wastes into renewable energy while supporting Sustainable Development Goals (SDGs). This study aimed to evaluate the effect of inoculum on optimizing biogas production from sewage sludge (SS) and cattle manure (CM). Bench-scale digesters were fed with 0, 20, and 40% inoculum prepared at a 1:3 SS:CM ratio. Substrate and digestate were analyzed for physicochemical properties, and biogas production data were fitted using nonlinear models. Kinetic parameters ranged from 0.0770 to 0.4691 L·kg−1 for Ymax, from 1.0263 to 2.1343 L·kg−1·week−1 for μmax, and from 0.8168 to 8.0114 weeks for λ, depending on the ratio. The 1:3 SS:CM with 40% inoculum significantly improved biogas production by reducing the lag phase and increasing weekly yield, with the Gompertz model showing the best fit to the digestion kinetics. This was particularly evident due to the favorable conditions for microbial adaptation and efficient substrate degradation. The results reinforce the concept of optimization as defined in this study, wherein the application of inoculum enhances the performance of AD by improving the physicochemical conditions of the substrate and accelerating microbial activity, thereby resulting in increased methane (CH4) generation and overall biogas yield. Full article
(This article belongs to the Special Issue Biorefining for Biofuel Production)
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24 pages, 5102 KiB  
Article
Electrocatalytic Investigation of the SOFC Internal CH4 Dry Reforming with Modified Ni/GDC: Effect of Au Content on the Performance Enhancement by Fe-Au Doping
by Evangelia Ioannidou, Stylianos G. Neophytides and Dimitrios K. Niakolas
Catalysts 2025, 15(7), 618; https://doi.org/10.3390/catal15070618 - 23 Jun 2025
Viewed by 412
Abstract
Internal Dry Reforming of Methane (IDRM) in biogas fed Solid Oxide Fuel Cells (SOFCs) was investigated on Fe-Au modified Ni/GDC electrolyte-supported cells at 900 and 850 °C. The aim was to clarify the synergistic interaction between Fe and Au, focusing on the effect [...] Read more.
Internal Dry Reforming of Methane (IDRM) in biogas fed Solid Oxide Fuel Cells (SOFCs) was investigated on Fe-Au modified Ni/GDC electrolyte-supported cells at 900 and 850 °C. The aim was to clarify the synergistic interaction between Fe and Au, focusing on the effect of X wt.% of Au loading (where X = 1 or 3 wt.%) in binary Au-Ni/GDC and ternary 0.5 wt.% Fe-Au-Ni/GDC fuel electrodes. The investigation combined i-V, Impedance Spectroscopy and Gas Chromatography electrocatalytic measurements. It was found that modification with 0.5Fe-Au enhanced significantly the electrocatalytic activity of Ni/GDC for the IDRM reaction, whereas the low wt.% Au content had the most promoting effect. The positive interaction of 0.5 wt.% Fe with 1 wt.% Au increased the conductivity of Ni/GDC and enhanced the corresponding IDRM charge transfer electrochemical processes, especially those in the intermediate frequency region. Comparative long-term measurements, between cells comprising Ni/GDC and 0.5Fe-1Au-Ni/GDC, highlighted the significantly higher IDRM electrocatalytic activity of the modified electrode. The latter operated for almost twice the time (280 h instead of 160 h for Ni/GDC) with a lower degradation rate (0.44 mV/h instead of 0.51 mV/h). Ni/GDC degradation was ascribed to inhibited charge transfer processes in the intermediate frequencies region and to deteriorated ohmic resistance. Stoichiometric analysis on the (post-mortem) surface state of each fuel electrode showed that the wt.% content of reduced nickel on Ni/GDC was lower, compared to 0.5Fe-1Au-Ni/GDC, verifying the lower re-oxidation degree of the latter. This was further correlated to the hindered H2O production during IDRM operation, due to the lower selectivity of the modified electrode for the non-desired RWGS reaction. Full article
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