Search Results (218)

Background/Objectives: Tegoprazan (TPZ) is a potassium-competitive acid blocker (P-CAB) used to treat conditions such as gastroesophageal reflux disease, peptic ulcer, and Helicobacter pylori infection. It exists in three solid forms: amorphous, Polymorph A, and Polymorph B. This study investigates the molecular basis of polymorph selection, focusing on conformational bias and solvent-mediated phase transformations (SMPTs). Methods: The conformational energy landscapes of two TPZ tautomers were constructed using relaxed torsion scans with the OPLS4 force field and validated by nuclear Overhauser effect (NOE)-based nuclear magnetic resonance (NMR). Hydrogen-bonded dimers were analyzed using DFT-D. Powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), solubility, and slurry tests were conducted using methanol, acetone, and water. Kinetic profiles were modeled with the Kolmogorov–Johnson–Mehl–Avrami (KJMA) equation. Results: Polymorph A was thermodynamically stable across all analyses. Both amorphous TPZ and Polymorph B converted to A in a solvent-dependent manner. Methanol induced direct A formation, while acetone showed a B → A transition. Crystallization was guided by solution conformers and hydrogen bonding. Conclusions: TPZ polymorph selection is governed by solution-phase conformational preferences, tautomerism, and solvent-mediated hydrogen bonding. DFT-D and NMR analyses showed that protic solvents favor the direct crystallization of stable Polymorph A, while aprotic solvents promote the transient formation of metastable Polymorph B. Elevated temperatures and humidity accelerate polymorphic transitions. This crystal structure prediction (CSP)-independent strategy offers a practical framework for rational polymorph control and the mitigation of disappearing polymorph risks in tautomeric drugs. Full article

In order to break through the difficulties with a very-low-frequency (VLF) miniaturized antenna with small power capacity and low radiation efficiency, this paper proposes a high-radiation-field-strength magnetic loop antenna based on a nanocrystalline alloy magnetic core. A high-permeability nanocrystalline toroidal core (μ_r = 50,000, B_s = 1.2 T) is used to optimize the thickness-to-diameter ratio (t = 0.08) and increase the effective permeability to 11,000. The Leeds wires, characterized by their substantial carrying capacity, are manufactured through a toroidal winding process. This method results in a 68% reduction in leakage compared to traditional radial winding techniques and enhances magnetic induction strength by a factor of 1.5. Additionally, this approach effectively minimizes losses, thereby facilitating support for kilowatt-level power inputs. A cascaded LC resonant network (resonant capacitance 2.3 μF) and ferrite balun transformer (power capacity 3.37 kW) realize a 20-times amplification of the input current. A series connection of a high-voltage isolation capacitor blocks DC bias noise, guaranteeing the stable transmission of 1200 W power, which is 6 times higher than the power capacity of traditional ring antenna. At 7.8 kHz frequency, the magnetic field strength at 120 m reaches 47.32 dBμA/m, and, if 0.16 pT is used as the threshold, the communication distance can reach 1446 m, which is significantly better than the traditional solution. This design marks the first instance of achieving kilowatt-class VLF effective radiation in a compact 51 cm-diameter magnetic loop antenna, offering a highly efficient solution for applications such as mine communication and geological exploration. Full article

In this research, an analysis of the thermomagnetic properties of a nanoscale spin-2 and spin-3/2 system is conducted. This system is modeled with as a quasi-spherical Ising-type nanoparticle with a diameter of 2 nm, in which atoms with spin-2 and spin-3/2 configured in body-centered cubic (BCC) lattices interact within their relevant nanostructures. To determine the thermomagnetic behaviors of the nanoparticle, numerical simulations using Monte Carlo techniques and thermal bath class algorithms are performed. The results exhibit the effects of exchange couplings ($J_1,J_2^{\prime }$), magnetocrystalline anisotropies ($D_{3/2}^{\prime },D_2^{\prime }$), and external magnetic fields ($h^{\prime }$) on the finite-temperature phase diagrams of magnetization ($M_T$), magnetic susceptibility (${\chi }_T$), and thermal energy ($k_B{T}^{\prime }$). The influences of the exchange, anisotropic, and external field parameters are clearly reflected in the compensation, hysteretic, and pseudocritical phenomena presented by the quasi-spherical nanoparticle. When the parameter reflecting ferromagnetic second-neighbor exchanges in the nanosphere ($J_2^{\prime }$) increases, for a given value of the external magnetic field, the compensation ($T_{comp}$) and pseudocritical ($T_{pc}$) temperatures increase. Similarly, in the ranges $0<J_2^{\prime }⩽4.5$ and $-15⩽h^{\prime }⩽15$ at a specific temperature, an increase in $J_2^{\prime }$ results in the appearance of exchange anisotropies (exchange bias) and and increased hysteresis loop areas in the nanomodel. Full article

This report is on Co and Ti substituted M-type barium and strontium hexagonal ferrites that are reported to be single phase multiferroics due to a transition from Neel type ferrimagnetic order to a spiral spin structure that is accompanied by a ferroelectric polarization in an applied magnetic field. The focus here is the nature of magnetoelectric (ME) interactions in the bilayers of ferroelectric PZT and Co and Ti substituted BaM and SrM. The ME coupling in the ferrite-PZT bilayers arise due to the transfer of magnetostriction-induced mechanical deformation in a magnetic field in the ferrite resulting in an induced electric field in PZT. Polycrystalline Co and Ti doped ferrites, Ba (CoTi)_x Fe_12−2xO_19, (BCTx), and Sr (CoTi)_x Fe_12−2xO₁₉ (SCTx) (x = 0–4) were found to be free of impurity phases for all x-values except for SCTx, which had a small amount of α-Fe₂O₃ in the X-ray diffraction patterns for x ≤ 2.0. The magnetostriction for the ferrites increased with applied filed H to a maximum value of around 2 to 6 ppm for H~5 kOe. BCTx/SCTx samples showed ferromagnetic resonance (FMR) for x = 1.5–2.0, and the estimated anisotropy field was on the order of 5 kOe. The magnetization increased with the amount of Co and Ti doping, and it decreased rapidly with x for x > 1.0. Measurements of ME coupling strengths were conducted on the bilayers of BCTx/SCTx platelets bonded to PZT. The bilayer was subjected to an AC and DC magnetic field H, and the magnetoelectric voltage coefficient (MEVC) was measured as a function of H and frequency of the AC field. For BCTx-PZT, the maximum value of MEVC at low frequency was ~5 mV/cm Oe, and a 40-fold increase at electromechanical resonance (EMR). SCTx–PZT composites also showed a similar behavior with the highest MEVC value of ~14 mV/cm Oe at low frequencies and ~200 mV/cm Oe at EMR. All the bilayers showed ME coupling for zero magnetic bias due to the magnetocrystalline anisotropy field in the ferrite that provided a built-in bias field. Full article

This paper presents the design, fabrication, calibration, and comprehensive characterization of a homemade tri-axial fluxgate magnetometer. The magnetometer, utilizing a ring core configuration, was developed to measure ultra-low magnetic fields with high sensitivity and stability. Critical stages from material selection to sensor geometry optimization are discussed in detail. A series of critical characterization processes were conducted, including zero-field voltage determination, scale factor calculation, resolution measurement, noise analysis, bias assessment, cross-field effect evaluation, temperature dependency, and bandwidth determination. The sensor demonstrated a minimum detectable magnetic field resolution of 2.2 nT with a noise level of 1.1 nT/√Hz at 1 Hz. Temperature dependency tests revealed minimal impact on sensor output with a maximum shift of 120 nT in the range of 60 °C, which was effectively compensated through calibration to less than 5 nT. Additionally, the paper introduces a model function in matrix form to relate the magnetometer’s output voltage to the measured magnetic field, incorporating temperature dependency and cross-field effects. This work highlights the importance of meticulous calibration and optimization in developing fluxgate magnetometers suitable for various applications, from space exploration to biomedical diagnostics. Full article

In the present paper, we discuss the thermodynamic and dynamic phase transition properties of the kinetic Blume–Capel model with spin-1, defined on non-regular lattices, namely decorated simple cubic, decorated triangular, and decorated square (Lieb) lattice geometries. Benefiting from the recent results obtained for the thermodynamic phase transitions of the aforementioned lattice topologies [Azhari, M. and Yu, U., J. Stat. Mech. (2022) 033204], we explore the variation of the dynamic order parameter, dynamic scaling variance, and dynamic magnetic susceptibility as functions of the amplitude, bias, and period of the oscillating field sequence. According to the simulations, a second-order dynamic phase transition takes place at a critical field period for the systems with zero bias. A particular emphasis has also been devoted to metamagnetic anomalies emerging in the dynamic paramagnetic phase. In this regard, the generic two-peak symmetric behavior of the dynamic response functions has been found in the slow critical dynamics (i.e. dynamic paramagnetic) regime. Our results yield that the characteristics of the dynamic phase transitions observed in the kinetic Ising model on regular lattices can be extended to such non-regular lattices with a larger spin value. Full article

We propose a low-frequency magnetic sensing method using a magnetically modulated microcavity resonant mode. Our magnetically sensitive unit with periodically changing magnetic poles is formed by combining an AC excitation coil with a microcavity. The microcavity vibrates at the frequency of the AC amplitude-modulated signal and changes its resonant mode when the sensing unit interacts with a low-frequency magnetic field. Signal processing is performed on the resonant spectrum to obtain low-frequency magnetic signals. The results of the experiment show that the measured sensitivity to a 0.5 Hz magnetic field is 12.49 V/mT, and a bias instability noise of 16.71 nT is achieved. We have extended the measurable frequency range of the whispering gallery mode microcavity magnetometer and presented a development in microcavity magnetic sensing and optical readout. Full article

Magnetic random-access memory, recognized as a breakthrough in spintronics, demonstrates substantial potential for next-generation nonvolatile memory and logic devices due to its unique magnetization-switching mechanism. However, realizing reliable perpendicular magnetization switching via spin–orbit torque necessitates an externally applied in-plane magnetic bias, a requirement that complicates integration in high-density device architectures. This study proposes a novel device architecture where geometric asymmetry engineering in an interlayer design generates an intrinsic equivalent in-plane magnetic field. By strategically introducing a non-symmetrical spacer between the heavy metal and ferromagnetic layers, we establish deterministic magnetization reversal while eliminating external field dependency. Furthermore, the energy barrier during magnetization switching is dynamically adjusted by applying a voltage across a perpendicular-anisotropy magnetic tunnel junction, leveraging the voltage-controlled magnetic anisotropy effect. We established a physics-driven compact model to assess the design and performance of voltage-controlled spin–orbit torque magnetic tunnel junction (VCSOT-MTJ) devices. Simulations reveal that the introduction of a minimally asymmetric light metal layer effectively resolves the issue of incomplete switching in field-free spin-orbit torque systems. Full article

Accurate measurement of magnetic fields holds immense significance across various disciplines, such as IC circuit measurement, geological exploration, and aerospace. The sensitivity and noise parameters of magnetic field sensors play a vital role in detecting minute fluctuations in magnetic fields. However, the current detection capability of tunneling magnetoresistance (TMR) is insufficient to meet the requirements for weak magnetic field measurement. This study investigates the impact of structural and fabrication parameters on the performance of TMR sensors. We fabricated series-connected TMR sensors with varying long-axis lengths of the elliptical cross-section and adjusted their performance by modifying annealing magnetic fields and magnetic field bias along the easy axis. The results demonstrate that TMR sensitivity decreases with increasing long-axis length, increases initially and then decreases with an annealing magnetic field, and decreases with a higher bias magnetic field along the easy axis. The voltage noise level of TMR sensors decreases as the long-axis length increases. Notably, the detection capability of TMR sensors exhibits a non-monotonic dependence on long-axis length. Moreover, we optimized the hysteresis of TMR sensors by applying a magnetic field bias along the easy axis. When the bias along the easy axis reached 16 Oe or −40 Oe, the hysteresis level was reduced to below 0.5 Oe. After encapsulating the TMR devices into a full Wheatstone bridge structure, we achieved a detection capability of 17 nT/$\sqrt{\mathrm{Hz}}$@1Hz. This study highlights that the detection capability of TMR devices is jointly influenced by fabrication parameters. By optimizing parameter configuration, this work provides theoretical guidance for further enhancing the performance of TMR devices in magnetic field measurements. Full article

We investigated the hysteresis, pseudo-critical, and compensation behaviors of a quasi-spherical FeCo alloy nanoparticle (2 nm in diameter) using Monte Carlo simulations with thermal bath-type algorithms and a 3D mixed Ising model. The nanostructure was modeled in a body-centered cubic lattice (BCC) through the following configurations: spin $S=3/2$ for Co and $Q=2$ for Fe. These simulations reveal that, under the influence of crystal and magnetic fields, the nanoparticle exhibits compensation phenomena, exchange bias, and pseudo-critical temperatures. Knowledge of this type of phenomena is crucial for the design of new materials, since compensation temperatures and exchange bias improve the efficiency of advanced magnetic devices, such as sensors and magnetic memories. Meanwhile, pseudo-critical temperatures allow the creation of materials with controlled phase transitions, which is vital for developing technologies with specific magnetic and thermal properties. An increase in single-ion anisotropies within the nanosystem leads to higher pseudo-critical and compensation temperatures, as well as superparamagnetic behavior at low temperatures. Full article

Exchange bias (EB) materials, whose magnetization curve can shift along the field axis after field cooling, have attracted tremendous attention and play a crucial role in the development of fundamental physics as well as practical applications of magnetization storage. In this work, the N-, P-, and Q-type ferrimagnets of Néel’s notation were realized in mixed valence metal formates [CH₃NH₂CH₃]_n[Cr^III_1−xFe^III_xFe^II(HCO₂)₆]_n by altering x, respectively. The positive and negative EB was found in N- and P-type ferrimagnets. The exchange anisotropy originates from the antiferromagnetic exchange interaction between the uncompensated spin of the host ferrimagnetic lattice and the pinned compensated spin of the antiferromagnetic clusters as a guest, which is rooted in the valence disorder of the iron ions. Full article

A giant magnetoelectric coefficient has been discovered in laminated magnetoelectric composites incorporating piezoelectric and magnetostrictive layers, which reveals a high sensitivity in AC magnetic field detection under a DC bias field. However, the DC-biased magnetoelectric composites are not capable of detecting DC magnetic fields due to the interference with the DC signal to be measured. Here, we demonstrate a portable magnetoelectric gaussmeter based on torque effect that can detect both DC and AC magnetic fields. The proposed gaussmeter is equipped with a magnetoelectric sensor, a charge amplification module, a signal processing circuit, a power module, a data processing program, a display module, etc. The proposed gaussmeter indicates such performance indexes as an intensity range of 0~10 Oe, frequency range of DC~500 Hz, AC detection limit of 0.01 Oe, DC detection limit of 0.08 Oe, and frequency resolution of 1 Hz. Being powered by a power adapter (or a battery) of 5V 2A, the whole device system is pocket-size, low-cost, and highly portable, demonstrating its potential for magnetic field detection as a distributed sensor. Full article

Artificial heterostructures are typically created by layering distinct materials, thereby giving rise to unique characteristics different from their individual components. Herein, two-dimensional α-MnSe nanosheets with a non-layered structure were fabricated on Ga_0.6Fe_1.4O₃ (GFO) films. The superior crystalline properties of MnSe/GFO heterostructures were confirmed through structural and morphological analyses. The remanent polarization is around 1.5 μC/cm² and the leakage current density can reach 2 × 10⁻³ A/cm² under 4 V. In addition, the piezo-response force microscopy amplitude and phase images further supported the ferroelectric property. The significant improvement of coercive field and saturated magnetization, along with the antiparallel signals of Mn and Fe ions observed through synchrotron X-ray analyses, suggest the presence of magnetic interaction within the MnSe/GFO heterostructure. Finally, the excellent photodetector with a photo detectivity of 6.3 × 10⁸ Jones and a photoresponsivity of 2.8 × 10⁻³ A·W⁻¹ was obtained under 532 nm in the MnSe/GFO heterostructure. The characteristics of this heterostructure, which include multiferroic, magnetic exchange bias effect, and photodetection capabilities, are highly beneficial for multifunctional devices. Full article

Transverse magnetic susceptibility is an excellent tool to study singularity points as anisotropy and switching fields in different bulk and nanostructured systems, as well as phase transitions. This technique has been carried out on polycrystalline Y-type hexaferrites, with compositions Ba_2−xSr_xCo₂Fe₁₂O₂₂, (0.0 ≤ x ≤ 2.0), and Ba_2−xSr_xZn₂Fe₁₂O₂₂, (1.3 ≤ x ≤ 1.7), promising candidates to exhibit multiferroic properties due to their noncollinear spin structure. In the Co₂Y system, different behavior is observed depending on the Sr substitution rate, with a secondary maximum observed for samples with x ≥ 1.0 and different shapes in the measurement temperature range analyzed. In the Zn₂Y system, several peaks related to the phase transitions that take place are observed, with certain variations depending on the degree of Ba substitution and the applied field in a more or less extended region around the ambient temperature. This type of measurement is a valuable tool to determine the bias field and temperature range of spin transitions. Full article

A new compound [Y₂(sq)₃(H₂O)₄] (Y-sq; sq = squarate (C₄O₄^2–)) was prepared and structurally characterized. Since the RE-sq family (RE = Y, Dy, Yb, Lu) gave isostructural crystals, the objective of this study is to explore the effects of diamagnetic dilution on the SIM behavior through systematic investigation and comparison of diamagnetically diluted and undiluted forms. The 1%-Diluted Dy compounds, Dy@Y-sq and Dy@Lu-sq, showed AC magnetic susceptibility peaks without any DC bias field (H_DC), whereas undiluted Dy-sq showed no AC out-of-phase response under the same conditions. The Orbach and Raman mechanisms are assumed in the Arrhenius plots, giving U_eff/k_B = 139(5) and 135(8) K for Dy@Y-sq and Dy@Lu-sq, respectively, at H_DC = 0 Oe. In contrast, Yb@Y-sq and Yb@Lu-sq behaved different; Yb@Y-sq can be regarded as a field-induced SIM because AC out-of-phase response was recorded only when H_DC was present. On the other hand, Yb@Lu-sq showed a relaxation independent from temperature around 2 K at H_DC = 0 Oe, possibly ascribed to a quantum-tunneling-magnetization mechanism. Applying H_DC = 400 Oe afforded U_eff = 61.2(14) and 62.5(16) K for Yb@Y-sq and Yb@Lu-sq, respectively. The Y/Lu matrix dependence may be related to spin–phonon coupling. The dilution technique is a facile and versatile tool for modification of SIM characteristics. Full article