Search Results (578)

Graphite has been recognized as a critical material by the United States (US), the European Union (EU), and Australia. Owing to its unique structure and properties, it is utilized in many industries and has played a key role in the clean energy sector, particularly in the lithium-ion battery (LIB) industries. With the projected increase in global graphite demand, driven by the shift to clean energy and the use of EVs, as well as the geographically concentrated production and reserves of natural graphite, interest in graphite recycling has increased, with a specific focus on using spent LIBs and other waste carbon material. Although most established and developing LIB recycling technologies are focused on cathode materials, some have started recycling graphite, with promising results. Based on the different secondary sources and recycling paths reported, hydrometallurgy-based treatment is usually employed, especially for the purification of graphite; greener alternatives are being explored, replacing HF both in lab-scale research and in industry. This offers a viable solution to resource dependency and mitigates the environmental impact associated with graphite production. These developments signal a trend toward sustainable and circular pathways for graphite recycling. Full article

Monitoring water quality is crucial for achieving clean water and sanitation goals, particularly in remote areas. The project “Morbidity vs. Water Quality for Human Consumption in Tonosí: A Pilot Study” aimed to enhance water quality assessments in Panama using advanced analytical techniques to assess volatile organic compounds, heavy metals, and microbiological pathogens. To support this, the Technical Unit for Water Quality (UTECH) was established, featuring a novel mobile laboratory with cutting-edge technology for accurate testing, minimal chemical reagent use, reduced waste generation, and equipped with a solar-powered battery system. The aim of this paper is to explore the design, deployment, and impact of the UTECH. Furthermore, this study presents results from three sampling points in Tonosí, where several parameters exceeded regulatory limits, demonstrating the capabilities of the UTECH and highlighting the need for ongoing monitoring and intervention. The study also assesses the environmental, social, and economic impacts of the UTECH in alignment with the Sustainable Development Goals and national initiatives. Finally, a SWOT analysis illustrates the UTECH’s potential to improve water quality assessments in Panama while identifying areas for sustainable growth. The study showcases the successful integration of advanced mobile laboratory technologies into water quality monitoring, contributing to sustainable development in Panama and offering a replicable model for similar initiatives in other regions. Full article

The exponential growth of lithium-ion battery consumption has amplified the urgency of identifying sustainable and economically viable recycling solutions. This study proposes an integrated decision-making framework based on the T-Spherical Fuzzy Einstein Interaction Aggregator DEMATEL-CoCoSo approach to comprehensively evaluate and rank battery recycling technologies under uncertainty. Ten key evaluation criteria—encompassing environmental, economic, and technological dimensions—were identified through expert consultation and literature synthesis. The T-Spherical Fuzzy DEMATEL method was first applied to analyze the causal interdependencies among criteria and determine their relative weights, revealing that environmental drivers such as energy consumption, greenhouse gas emissions, and waste generation exert the most systemic influence. Subsequently, six recycling alternatives were assessed and ranked using the CoCoSo method enhanced by Einstein-based aggregation, which captured the complex interactions present in the experts’ evaluations and assessments. Results indicate that Direct Recycling is the most favorable option, followed by the Hydrometallurgical and Bioleaching methods, while Pyrometallurgical Recycling ranked lowest due to its high energy demands and environmental burden. The proposed hybrid model effectively handles linguistic uncertainty, expert variability, and interdependent evaluation structures, offering a robust decision-support tool for sustainable technology selection in the circular battery economy. The framework is adaptable to other domains requiring structured expert-based evaluations under fuzzy environments. Full article

Waste from zinc−carbon batteries poses a serious environmental protection problem. One of the main problems is also the reliable and rapid determination of some compounds that may be present in food and beverages consumed worldwide. This study addresses these problems and presents a possible solution for the electrochemical detection of xanthine using carbon from spent batteries. Cyclic voltammetry and differential pulse voltammetry are electrochemical methods used for the detection of xanthine. The techniques used demonstrate the mechanism of xanthine oxidation in the tested environment. A linear correlation was found between the oxidation current peaks and the xanthine concentration in the range of 5·10⁻⁷ to 1·10⁻⁴ M, as well as the values for the limit of detection and the limit of quantification, 7.86·10⁻⁸ M and 2.62·10⁻⁷ M, respectively. The interference test shows that the electrode obtained from waste Zn-C batteries has good selectivity, which means that the electrode can be used for xanthine determination in the presence of various ions. The data obtained show that carbon sensors from used zinc−carbon batteries can be used to detect xanthine in real samples. Full article

In the context of urban decarbonization, multi-energy microgrids (MEMGs) are gaining increasing relevance due to their ability to enhance synergies across multiple energy vectors. This study presents a block-based MILP framework developed to optimize the operations of a real MEMG, with a particular focus on accurately modeling the structure of electricity and natural gas bills. The objective is to assess the added economic value of integrating a battery energy storage system (BESS) under the assumption it is employed to provide implicit flexibility—namely, bill management, energy arbitrage, and peak shaving. Results show that under assumed market conditions, tariff schemes, and BESS costs, none of the analyzed BESS configurations achieve a positive net present value. However, a 2 MW/4 MWh BESS yields a 3.8% reduction in annual operating costs compared to the base case without storage, driven by increased self-consumption (+2.8%), reduced thermal energy waste (–6.4%), and a substantial decrease in power-based electricity charges (–77.9%). The performed sensitivity analyses indicate that even with a significantly higher day-ahead market price spread, the BESS is not sufficiently incentivized to perform pure energy arbitrage and that the effectiveness of a time-of-use power-based tariff depends not only on the level of price differentiation but also on the BESS size. Overall, this study provides insights into the role of BESS in MEMGs and highlights the need for electricity bill designs that better reward the provision of implicit flexibility by storage systems. Full article

The sustainable management of Municipal Solid Waste (MSW) relies heavily on community participation in separating it at the source and delivering it to collection systems. These practices are crucial for reducing pollution, protecting ecosystems, and maximizing resource recovery. However, in the Global South context, with conditions of socioeconomic vulnerability, community participation in the sustainable management of MSW remains limited, highlighting the need to generate context-specific interventions. MSW includes items such as household appliances, batteries, and electronic devices, which require specialized handling due to their size, hazardous components, or material complexity. This study implemented a Community-Based Social Marketing approach during the research and design phases of an intervention focused on promoting source separation and management of hard-to-manage MSW in five municipalities within the administrative region of Norte de Santander (Colombia), which borders Venezuela. Using a mixed-methods approach, we collected data from 1775 individuals (63.83% women; M _age = 33.48 years; SD = 17.25), employing social mapping, focus groups, semi-structured interviews, participant observation, and a survey questionnaire. The results show that the source separation and delivery of hard-to-manage MSW to collection systems are limited by a set of psychosocial, structural, and institutional barriers that interact with each other, affecting communities’ willingness and capacity for action. Furthermore, a prediction model of willingness to engage in separation and delivery behaviors showed a good fit (R2 = 0.83). The strongest predictors were awareness of the negative consequences of non-participation and perceived environmental benefits, with subjective norms contributing to a lesser extent. Based on these results, we designed a context-specific intervention focused on reducing these barriers and promoting community engagement in the sustainable management of hard-to-manage MSW. Full article

An efficient integrated energy system (IES) can enhance the potential of building energy conservation and carbon mitigation. However, imbalances between user-side demand and supply side output present formidable challenges to the operational dispatch of building energy systems. To mitigate heat rejection and improve dispatch optimization, an integrated building energy system incorporating waste heat recovery via an absorption heat pump based on the flow temperature model is adopted. A comprehensive analysis was conducted to investigate the correlation among heat pump operational strategies, thermal comfort, and the dynamic thermal storage capacity of piping network systems. The optimization calculations and comparative analyses were conducted across five cases on typical season days via the CPLEX solver with MATLAB R2018a. The simulation results indicate that the operational modes of absorption heat pump reduced the costs by 4.4–8.5%, while the absorption rate of waste heat increased from 37.02% to 51.46%. Additionally, the utilization ratio of battery and thermal storage units decreased by up to 69.82% at most after considering the pipeline thermal inertia and thermal comfort, thus increasing the system’s energy-saving ability and reducing the pressure of energy storage equipment, ultimately increasing the scheduling flexibility of the integrated building energy system. Full article

The transition to electric mobility has significantly increased the demand for lithium-ion batteries, raising concerns about their end-of-life management. Therefore, this study presents the design, development and first implementation steps of a stationary energy storage system utilizing second-life electric vehicle (EV) batteries. These batteries, no longer suitable for traction applications due to a reduced state of health (SoH) below 80%, retain sufficient capacity for less demanding stationary applications. The proposed system is designed to be flexible and scalable, serving both research and commercial purposes. Key challenges include heterogeneous battery characteristics, safety considerations due to increased internal resistance and battery aging, and the need for flexible power electronics. An optimized dual active bridge (DAB) converter topology is introduced to connect several batteries in parallel and to ensure efficient bidirectional power flow over a wide voltage range. A first prototype, rated at 50 $\mathrm{k}$$\mathrm{W}$, has been built and tested in the laboratory. This study contributes to sustainable energy storage solutions by extending battery life cycles, reducing waste, and promoting economic viability for industrial partners. Full article

This paper proposes a ladder carbon trading-based low-carbon economic dispatch model for integrated energy systems (IESs), incorporating flexible load optimization and hybrid energy storage systems consisting of battery and thermal energy storage. First, a ladder-type carbon trading mechanism is introduced, in which the carbon trading cost increases progressively with emission levels, thereby providing stronger incentives for emission reduction. Second, flexible loads are categorized and modeled as shiftable, transferable, and reducible types, each with distinct operational constraints and compensation mechanisms. Third, both battery and thermal energy storage systems are considered to improve system flexibility by storing excess energy and supplying it when needed. Finally, a unified optimization framework is developed to coordinate the dispatch of renewable generation, gas turbines, waste heat recovery units, and multi-energy storage devices while integrating flexible load flexibility. The objective is to minimize the total system cost, which includes energy procurement, carbon trading expenditures, and demand response compensation. Three comparative case studies are conducted to evaluate system performance under different operational configurations: the proposed comprehensive model, a carbon trading-only approach, and a conventional baseline scenario. Results demonstrate that the proposed framework effectively balances economic and environmental objectives through coordinated demand-side management, hybrid storage utilization, and the ladder-type carbon trading market mechanism. It reshapes the system load profile via peak shaving and valley filling, improves renewable energy integration, and enhances overall system efficiency. Full article

Production involves processes such as raw material extraction, energy consumption, and waste management, which can lead to significant environmental consequences. Therefore, supplier selection based not only on technical performance but also on environmental sustainability criteria has become a fundamental component of eco-friendly manufacturing strategies. Moreover, in the selection of electric vehicle batteries, it is essential to consider customer demands alongside environmental factors. Accordingly, selected suppliers should fulfill company expectations while also reflecting the “voice” of the customer. The objective of this study is to propose an integrated approach for green supplier selection by taking into account various environmental performance requirements and criteria. The proposed approach evaluates battery suppliers with respect to both customer requirements and green criteria. To construct the relational structure, the DEMATEL method was employed to analyze the interrelationships among customer requirements (CRs). Subsequently, the Quality Function Deployment (QFD) model was used to establish a central relational matrix that captures the degree of correlation between each pair of supplier selection criteria and CRs. Finally, to evaluate and rank alternative suppliers, the Interval Type-2 Fuzzy VIKOR (IT2 F-VIKOR) method was applied. The hybrid approach proposed by us, integrating DEMATEL, QFD, and IT2 F-VIKOR, offers significant improvements over traditional methods. Unlike previous approaches that focus independently on customer preferences or supplier criteria, our model provides a unified evaluation by considering both dimensions simultaneously. Furthermore, the use of Interval Type-2 Fuzzy Logic enables the model to better manage uncertainty and ambiguity in expert judgments, yielding more reliable results compared to conventional fuzzy approaches. Additionally, the applicability of the model has been demonstrated through a real-world case study, confirming its practical relevance and robustness in the selection of green suppliers for electric vehicle battery procurement. Full article

The transition to passenger car electrification is a crucial step in China’s strategic efforts to achieve carbon peak and carbon neutrality. However, previous research has not considered the variances in vehicle models. Hence, this study aims to fill this gap by comparing the carbon emission reduction and economic feasibility of battery electric vehicles (BEVs) in the Chinese market, taking into account different powertrains, vehicle segments, classes, and driving ranges. Next, the study identifies the most cost-effective BEV within each market segment, employing life-cycle assessment and life cycle cost analysis methods. Moreover, at different levels of technological development, we construct three low-carbon measures, including electricity decarbonization (ED), energy efficiency improvement (EEI), and vehicle lightweight (LW), to quantify the emission mitigation potentials from different carbon reduction pathways. The findings indicate that BEVs achieve an average carbon reduction of about 31.85% compared to internal combustion engine vehicles (ICEVs), demonstrating a significant advantage in carbon reduction. However, BEVs are not economically competitive. The total life cycle cost of BEVs is 1.04–1.68 times higher than that of ICEVs, with infrastructure costs accounting for 18.8–57.8% of the vehicle’ s life cycle costs. In terms of cost-effectiveness, different models yield different results, with sedans generally outperforming sport utility vehicles (SUVs). Among sedans, both A-class and B-class sedans have already reached a point of cost-effectiveness, with the BEV400 emerging as the optimal choice. In low-carbon emission reduction scenarios, BEVs could achieve carbon reduction potentials of up to 45.3%, 14.9%, and 9.0% in the ED, EEI, and LW scenarios, respectively. Thus, electricity decarbonization exhibits the highest potential for mitigating carbon emissions, followed by energy efficiency improvement and vehicle lightweight. There are obvious differences in the stages of impact among different measures. The ED measure primarily impacts the waste treatment process (WTP) stage, followed by the vehicle cycle, while the EEI measure only affects the WTP stage. The LW measure has a complex impact on emission reductions, as the carbon reductions achieved in the WTP stage are partially offset by the increased carbon emissions in the vehicle cycle. Full article

Municipal Solid Waste (MSW) management programs can help to mitigate the triple planetary crises of climate change, biodiversity loss and pollution. However, their success largely depends on the public willingness to engage in the pro-environmental separation and delivery of MSW, particularly for difficult-to-manage items such as electronics, batteries and appliances, which often contain toxic materials. Most existing research tends to focus on infrastructure improvements or behavioral interventions, with little integration of psychosocial and contextual analyses to develop evidence-based strategies for increasing community participation in the sustainable management of MSW. To address this gap, we conducted a study combining quantitative data from surveys with qualitative and geospatial data obtained through social mapping sessions and information obtained from local waste collectors in five municipalities in Norte de Santander, Colombia—a region marked by high socioeconomic vulnerability. Our study presents a novel integration of psychosocial and geospatial data to inform MSW interventions in low-resource settings. We identified that the awareness of the consequences of poor MSW management, the awareness of environmental benefits of delivery and the subjective norm predicts the willingness to separate and deliver MSW. Nonetheless, various psychosocial and contextual barriers hinder these actions. Based on these insights, we propose a low-cost, community-tailored intervention to enhance the separation and delivery of difficult-to-manage MSW and foster civic engagement in similar socio-environmental contexts. Full article

This review contains a compilation of data about the occurrence, mining, refining, and biological actions of lithium, without claiming completeness of knowledge. This should give a baseline for judging future pollutions of environmental and agricultural items and human nutrition and may show still existing gaps of screening. Emerging electromobility and use of computers leads to a steep increase in Li-based batteries, which are a source of hazardous waste unless recycled. Lack of recovery methods from effluents and sewage, however, will increase pollution with soluble Li-salts from increasing mining and waste in the future; therefore, biochemical effects of levels out of ambient range have been included. Many published data are hidden in multi-element tables, including the data of the author. Mobile fractions of soils and soil-to-plant transfer, as well as retainment in animal tissues, are low. A lot of data, starting from geology via soils, plants, water, and human nutrition, lead to a largely unknown average daily intake for men. With respect to nutrition of dairy cows, the contribution of Li from water was highest among all elements investigated, but only 4% of intake. Main sources for human nutrition are mineral water and table salt. Li is not labelled on mineral water bottles, nor table salt, which are the main sources. Though some data have been gathered, for human nutrition, the average daily intake is uncertain to estimate because some mineral waters are quite high in Li. Full article

The increasing need-based demand for lithium iron phosphate (LFP) batteries in electric vehicles and energy storage systems necessitates the development of efficient and sustainable recycling methods. This study investigates the effect of oxidative roasting on lithium extraction from industrially sourced LiFePO₄ (LFP) blackmass containing high graphite content (~46%) and mixed electrode materials. Roasting at 650 °C for one hour converted LiFePO₄ into water-soluble Li₃Fe₂(PO₄)₃ and Fe₂O₃, while reducing carbon and fluorine levels. However, contrary to expectations, mild-acid leaching (pH 2, 40 g/L, 20 °C) of roasted blackmass did not improve lithium recovery compared to unroasted material, yielding approximately 33% extraction efficiency. Strong-acid leaching (pH 0, H₂SO₄/H₂O₂) achieved over 95% lithium recovery but also resulted in significant co-dissolution of iron and other impurities. Our XRD and SEM analyses showed that some lithium-containing phases remained in the residue after water leaching, while acid leaching left mainly iron oxide and graphite. These results suggest that, for complex and graphite-rich industrial blackmass, roasting may not always deliver the expected boost in lithium recovery. Our findings highlight the need to tailor recycling processes to the specific characteristics of battery waste and suggest that direct hydrometallurgical methods could be more effective for complex, impurity-rich LFP blackmass streams. Full article

The integration of renewable energy sources, battery energy storage, and electric vehicles into industrial systems unlocks new opportunities for reducing emissions and improving sustainability. However, the coordination and management of these new technologies also pose new challenges due to complex interactions. This paper proposes a methodology for designing a holistic energy management system, based on advanced digital twins and optimization techniques, to minimize the cost of supplying industry loads and electric vehicles using local renewable energy sources, second-life battery energy storage systems, and grid power. The digital twins represent and forecast the principal energy assets, providing variables necessary for optimizers, such as photovoltaic generation, the state of charge and state of health of electric vehicles and stationary batteries, and industry power demand. Furthermore, a two-layer optimization framework based on mixed-integer linear programming is proposed. The optimization aims to minimize the cost of purchased energy from the grid, local second-life battery operation, and electric vehicle fleet charging. The paper details the mathematical fundamentals behind digital twins and optimizers. Finally, a real-world case study is used to demonstrate the operation of the proposed approach within the context of the waste collection and management industry. The study confirms the effectiveness of digital twins for forecasting and performance analysis in complex energy systems. Furthermore, the optimization strategies reduce the operational costs by 1.3%, compared to the actual industry procedure, resulting in daily savings of EUR 24.2 through the efficient scheduling of electric vehicle fleet charging. Full article