Search Results (25)

Oxybenzone (OBZ), an organic ultraviolet filter, is an emerging contaminant posing severe threats to ecosystem health. Using tobacco (Nicotiana tabacum) as a model plant, this study investigated the alleviation mechanisms of exogenous silicon (Na₂SiO₃, Si) and bamboo-based biochar (Bc) under OBZ stress. We systematically analyzed physiological and biochemical responses, including phenotypic parameters, reactive oxygen species metabolism, photosynthetic function, chlorophyll synthesis, and endogenous hormone levels. Results reveal that OBZ significantly inhibited tobacco growth and triggered a reactive oxygen species (ROS) burst. Additionally, OBZ disrupted antioxidant enzyme activities and hormonal balance. Exogenous Bc mitigated OBZ toxicity by adsorbing OBZ, directly scavenging ROS, and restoring the ascorbate-glutathione (AsA-GSH) cycle, thereby enhancing photosynthetic efficiency, while Si alleviated stress via cell wall silicification, preferential regulation of root development and hormonal signaling, and repair of chlorophyll biosynthesis precursor metabolism and PSII function. The mechanisms of the two stress mitigators were complementary, Bc primarily relied on physical adsorption and ROS scavenging, whereas Si emphasized metabolic regulation and structural reinforcement. These findings provide practical strategies for simultaneously mitigating organic UV filter pollution and enhancing plant resilience in contaminated soils. Full article

Excessive phosphate from agriculture and industry has led to widespread eutrophication, posing a serious environmental threat. To address this issue, metal-modified biochars have emerged as promising adsorbents due to their high affinity for phosphate ions. This study investigates the application of two magnesium-modified biochar hydrogels denoted as magnesium–bamboo biochar hydrogel (Mg-BBH) and magnesium–pulp biochar hydrogel (Mg-PBH) for phosphate recovery from aqueous solutions, with an additional aim as slow-release fertilizers. The adsorbents were synthesized by impregnating Mg-modified biochars into sodium-alginate-based hydrogel. The influence of initial phosphate concentration, contact time, and temperature were investigated to determine optimal adsorption conditions. Both adsorbents exhibited excellent adsorption performance, with maximum capacities of 309.96 mg PO₄/g (Mg-BBH) and 234.69 mg PO₄/g (Mg-PBH). Moreover, the adsorption performance of the adsorbents was greatly influenced by the magnesium content. The adsorption process followed the Temkin isotherm and pseudo-second-order kinetics, suggesting that the adsorption energy decreases proportionally with surface coverage and the phosphate uptake was governed by chemisorption. Thermodynamic study confirmed the process was spontaneous and endothermic at 40 °C. A slow-release study further demonstrated a great release of phosphate in soil over time. These findings highlight the dual functionality of Mg-BBH and Mg-PBH as effective materials for both phosphate recovery and controlled nutrient delivery, contributing to sustainable phosphate management. Full article

Lignocellulosic waste biomass, a versatile natural resource derived from plants, has gained significant attention for its potential in the sustainable production of biobased chemicals. Furfural (FAL), xylo-oligosaccharides (XOSs), and reducing sugars are important platform chemicals, which can be obtained through the valorization of lignocellulosic solid biomass in a green and sustainable way. Waste yellow bamboo (YB) is one kind of abundant, inexpensive, and renewable lignocellulosic biomass resource. In order to improve the high-value utilization rate of raw YB, biochar-based solid acid catalyst (AT-Sn-YB) was utilized to assist the hydrothermal pretreatment for the valorization of YB in water. Under the optimal reaction conditions (200 °C, 60 min, and AT-Sn-YB dosage of 5.4 wt%), the FAL yield reached 60.8%, and 2.5 g/L of XOSs was obtained in the pretreatment system. It was observed that the surface structure of YB became rough and loose, exposing a significant number of pores. The accessibility increased from 101.8 mg/g to 352.6 mg/g after combined treatment. The surface area and hydrophobicity of lignin were 70.7 m²/g and 2.5 L/g, respectively, which were significantly lower than those of untreated YB (195.4 m²/g and 4.1 L/g, respectively). The YB solid residues obtained after treatment were subjected to enzymatic saccharification, achieving an enzymatic hydrolysis efficiency of 47.9%. Therefore, the hydrothermal pretreatment assisted by the AT-Sn-YB catalyst shows potential application value in FAL production and bamboo utilization, providing important references for other biomass materials. Full article

As global efforts to achieve net-zero emissions intensify, the role of nature-based solutions (NbSs) in mitigating climate change through circular economy practices is increasingly recognized. This study evaluates the potential of various NbS strategies at the Asian Institute of Technology (AIT) campus to contribute to ambitious net-zero targets by 2030. Our research systematically analyzes baseline carbon emissions, stocks, and removals associated with the following three NbS strategies: improved forest management (IFM), afforestation on available land, and biochar application for soil carbon sequestration. The campus’s baseline emissions were calculated at 8367 MgCO₂e, with electricity consumption contributing 61% of total emissions. Our findings indicate that improved forest management can sequester 2476 MgCO₂ annually, while afforestation strategies utilizing fast-growing species, bamboo species, and slow-growing species have the potential to remove 7586 MgCO₂, 4711 MgCO₂, and 2131 MgCO₂ per year, respectively. In addition, biochar application across 70 hectares could result in cumulative carbon sequestration of 603 MgCO₂ per hectare by 2050. While net-zero emissions may not be achieved by 2030 under retrospective and stable baselines, projections suggest it will be realized shortly thereafter, with Scenario 1—combining IFM, fast-growing species, and biochar—achieving net-zero by 2033.5. These findings highlight the critical role of tailored NbSs in enabling small institutions like the AIT to effectively contribute to global net-zero targets, provided that these strategies are implemented and scaled appropriately. Full article

Adsorbents derived from bamboo, such as biochar, charcoal, activated carbon, and chemically modified bamboo, are recognized for their efficiency and cost-effectiveness in removing heavy metals from water. Despite this, there remains a gap in applying bamboo-based adsorbents for treating heavy metal-contaminated water sources, particularly regarding their physicochemical properties, adsorption mechanisms, and modifications. This review highlights the influence of factors such as specific surface area, pore distribution, pH, cation exchange capacity, elemental composition, and surface functional groups on the ability of bamboo adsorbents to adsorb heavy metals. It also discusses recent advancements in enhancing the properties of bamboo adsorbents through physical and chemical modifications and examines how variables like adsorbent dosage, water pH, temperature, initial concentrations of cations, and heavy metals affect heavy metal removal. The review categorizes the mechanisms of heavy metal adsorption into surface complexation, physical adsorption, electrostatic interaction, ion exchange, precipitation, and redox effect. While bamboo-based adsorbents have shown higher sorption capacity in laboratory settings, there is a need for more comprehensive studies to optimize their performance, scalability, and cost-effectiveness in real-world applications. Full article

Herein, biochars derived from corn stalks, rice husks, and bamboo powder were modified by nitric acid oxidation and sodium hydroxide alkali activation to identify efficient and cost-effective polycyclic aromatic hydrocarbon-adsorbent and microbial-immobilized carriers. The surface characterization and adsorption investigation results suggested that acid/alkali modification promoted the phenanthrene removal ability in an aqueous solution of biochars via facilitating π–π/n–π electron donor–acceptor interactions, electrostatic interactions, hydrogen bonds, and hydrophobic interactions. Subsequently, the degrading bacteria Rhodococcus sp. DG1 was successfully immobilized on the rice husk-derived biochar with nitric acid oxidation (RBO), which exhibited the maximum phenanthrene adsorption efficiency (3818.99 µg·g⁻¹), abundant surface functional groups, and a larger specific surface area (182.6 m²·g⁻¹) and pore volume (0.141 m³·g⁻¹). Degradation studies revealed that the microorganisms immobilized on RBO by the adsorption method yielded a significant phenanthrene removal rate of 80.15% after 30 days, which was 38.78% higher than that of the control. Conversely, the polymer gel network-based microenvironment in the microorganism-immobilized RBO by the combined adsorption–embedding method restricted the migration and diffusion of nutrients and pollutants in the reaction system. This study thus introduces an innovative modified biochar-based microbial immobilization technology characterized by a simple design, convenient operation, and high adsorption efficiency, offering valuable insights into material selection for PAH contamination bioremediation. Full article

The global prevalence of counterfeit and low-quality pharmaceuticals poses significant health risks and challenges in medical treatments, creating a need for rapid and reliable drug screening technologies. This study introduces a cost-effective electrochemical paper-based device (ePAD) modified with functionalized bamboo-derived biochar (BCF) for the detection of paracetamol in substandard medicines. The sensor was fabricated using a custom 3D-printed stencil in PLA, designed for efficient production, and a 60:40 (m/m) graphite (GR) and glass varnish (GV) conductive ink, resulting in a robust and sensitive platform. The electroactive area of the ePAD/BCF sensor was determined as 0.37 cm². Characterization via SEM and cyclic voltammetry (CV) verified its structural and electrochemical stability. The sensor demonstrated linear detection of paracetamol from 5.0 to 60.0 µmol L⁻¹ with a detection limit of 3.50 µmol L⁻¹. Interference studies showed high selectivity, with recoveries of over 90%, and the sensor successfully quantified paracetamol in commercial analgesic and anti-flu samples. This sustainable, bamboo-based ePAD offers a promising solution for rapid on-site pharmaceutical quality control, with significant potential to enhance drug screening accuracy. Full article

Fall armyworm (FAW, Spodoptera frugiperda) has now spread to more than 26 Chinese provinces. The government is working with farmers and researchers to find ways to prevent and control this pest. The use of biochar is one of the economic and environmentally friendly strategies to increase plant growth and improve pest resistance. We tested four v/v combinations of bamboo charcoal with coconut bran [BC1 (10:1), BC2(30:1), BC3(50:1)] against a control (CK) in maize. We found that plant height, stem thickness, fresh weight and chlorophyll content were significantly higher in BC2, in addition to the lowest FAW survival %. We then compared the metabolome and transcriptome profiles of BC2 and CK maize plants under FAW herbivory. Our results show that the levels of flavonoids, amino acids and derivatives, nucleotides and derivatives and most phenolic acids decreased, while terpenoids, organic acids, lipids and defense-related hormones increased in BC-grown maize leaves. Transcriptome sequencing revealed consistent expression profiles of genes enriched in these pathways. We also observed the increased expression of genes related to abscisic acid, jasmonic acid, auxin and MAPK signaling. Based on these observations, we discussed the possible pathways involved in maize against FAW herbivory. We conclude that bamboo charcoal induces anti-herbivory responses in maize leaves. Full article

The substitution of ethyl acetate for ammonia in NH₃-SCR provides a novel strategy for the simultaneous removal of VOCs and NO. In this study, three distinct types of biochar were fabricated through pyrolysis at 700 °C. MnO_x and TiO₂ were sequentially loaded onto these biochar substrates via a hydrothermal process, yielding a family of biochar-based catalysts with optimized dosages. Upon exposure to xenon lamp irradiation at 240 °C, the biochar catalyst designated as 700-12-3GN, derived from Ginkgo shells, demonstrated the highest catalytic activity when contrasted with its counterparts prepared from moso bamboo and loofah. The conversion efficiencies for NO and ethyl acetate (EA) peaked at 73.66% and 62.09%, respectively, at a catalyst loading of 300 mg. The characterization results indicate that the 700-12-3GN catalyst exhibits superior activity, which can be attributed to the higher concentration of Mn⁴⁺ and Ti⁴⁺ species, along with its superior redox properties and suitable elemental distribution. Notably, the 700-12-3GN catalyst has the smallest specific surface area but the largest pore volume and average BJH pore size, indicating that the specific surface area is not the predominant factor affecting catalyst performance. Instead, pore volume and average BJH pore diameter appear to be the more influential parameters. This research provides a reference and prospect for the resource utilization of biochar and the development of photothermal co-catalytic ethyl acetate and NO at low cost. Full article

Biochar (BC), also referred to as “black gold”, is a carbon heterogeneous material rich in aromatic systems and minerals, preparable by the thermal decomposition of vegetable and animal biomasses in controlled conditions and with clean technology. Due to its adsorption ability and presence of persistent free radicals (PFRs), BC has demonstrated, among other uses, great potential in the removal of environmental organic and inorganic xenobiotics. Bamboo is an evergreen perennial flowering plant characterized by a short five-year growth period, fast harvesting, and large production in many tropical and subtropical countries worldwide, thus representing an attractive, low-cost, eco-friendly, and renewable bioresource for producing BC. Due to their large surface area and increased porosity, the pyrolyzed derivatives of bamboo, including bamboo biochar (BBC) or activated BBC (ABBC), are considered great bio-adsorbent materials for removing heavy metals, as well as organic and inorganic contaminants from wastewater and soil, thus improving plant growth and production yield. Nowadays, the increasing technological applications of BBC and ABBC also include their employment as energy sources, to catalyze chemical reactions, to develop thermoelectrical devices, as 3D solar vapor-generation devices for water desalination, and as efficient photothermal-conversion devices. Anyway, although it has great potential as an alternative biomass to wood to produce BC, thus paving the way for new bio- and circular economy solutions, the study of bamboo-derived biomasses is still in its infancy. In this context, the main scope of this review was to support an increasing production of BBC and ABBC and to stimulate further studies about their possible applications, thus enlarging the current knowledge about these materials and allowing their more rational, safer, and optimized application. To this end, after having provided background concerning BC, its production methods, and its main applications, we have reviewed and discussed the main studies on BBC and ABBC and their applications reported in recent years. Full article

The presence of antibiotics in water environments increases the resistance of bacterial and can also cause irreversible damage to ecosystems and the human body. In this study, disposable bamboo chopsticks were used as raw material to prepare bamboo biochar (BB) via oxygen-limited pyrolysis to remove norfloxacin (NOR) from aqueous solutions. The properties of the BB were explained through the characterization of its SBET, morphology, structure, and functional groups. The effects of the dosage, pH, ionic strength, and water type on the removal of NOR using BB were investigated. The maximum theoretical adsorption capacities (Q_max) of NOR removed by BB at 25, 35, and 45 °C obtained using the Langmuir model were 76.17, 77.22, and 105.19 mg/g, respectively. To facilitate a comparison with other types of biochar, this study also prepared biochar of rice straw, wheat straw, soybean straw, corn straw, rape straw, peanut shell, Eichhornia crassipes, and other biomass raw materials under the same preparation conditions as the BB. The results demonstrated that the removal rate of NOR using BB was the highest under the same adsorption conditions, reaching 99.71%. Biochar from waste disposable bamboo chopsticks can be used for the treatment of new types of pollutants in water bodies, such as antibiotics and other organic contaminants, which will help to achieve sustainable solid waste management. Full article

Farmland soil is an important source of the greenhouse gas nitrous oxide (N₂O), and soil nitrification and denitrification are key processes affecting N₂O production. In this study, the acidic soil of a pomelo orchard was used to investigate the effects of a bamboo-biochar-based fertilizer (BB) on soil N₂O emissions and nitrifier and denitrifier communities. In this study, five treatments, namely, CK (no urea and BB), N (0.72 g·kg⁻¹ urea), 5BB+N (0.72 g·kg⁻¹ urea plus 5 g·kg⁻¹ BB), 10BB+N (0.72 g·kg⁻¹ urea plus 10 g·kg⁻¹ BB), and 20BB+N (0.72 g·kg⁻¹ urea plus 20 g·kg⁻¹ BB) were applied to the acidic soil of a pomelo orchard. The nitrification (AOA-amoA, AOB-amoA) and denitrification (nirS, nirK, nosZ) gene copy numbers were analyzed by qPCR, and their community diversities were determined by Illumina MiSeq sequencing. The results showed that N treatment significantly promoted soil N₂O emissions compared with CK, while all BB+N treatments significantly inhibited soil N₂O emissions compared with N treatment. BB fertilizer promoted soil nitrification, alleviated the adverse effects from N fertilizer inputs on the AOA-amoA gene copy numbers and community diversity, and restored the AOA-amoA diversity to the initial level. BB had a strong effect on Crenarchaeota (AOA-amoA) and Nitrosospira (AOB-amoA). BB significantly promoted the denitrification gene copy numbers; increased nirS and nirK community diversity; particularly affected the relative abundance of denitrifiers such as Nonomuraea (nirS), Proteobacteria (nirK), and Rhodanobacter (nosZ); and, finally, reduced N₂O emissions. Full article

Biochar is considered to be the most promising substrate for the preparation of environmentally functional materials. The modification of bamboo char can significantly improve the removal rate of toxic ions from wastewater; however, there are few reports that focus on the radiation grafting method. Here, glyceride methacrylate (GMA) is successfully grafted onto bamboo char through electron beam radiation, followed by amination using the existing epoxide group in diethyltriamine, and finally, treated with hydrochloric acid to obtain protonated diethyltriamine-functionalized bamboo char (CDGBC). The results of IR, TG, XRD, and SEM prove the successful fabrication of a CDGBC biosorbent. The results show that the solution pH has a great effect on the adsorption capacity, and a maximum adsorption capacity of 169.13 mg/g is obtained at pH = 2 for Cr(VI). In addition, the adsorption behavior of Cr(VI) onto CDGBC is demonstrated to obey the pseudo-second-order kinetic and Freundlich isotherm models, and thermodynamic analysis exhibits that Cr(VI) adsorption is an endothermic spontaneous process. A possible adsorption mechanism based on the electrostatic interaction, reduction, and surface complexation is proposed, according to the obtained results. This work confirms that radiation-induced grafting modification can effectively transform biochar into a high-performance adsorbent for Cr(VI) removal, offering a new approach to synthesizing an efficient biosorbent. Full article

The production of agricultural waste is associated with environmental problems and risks to public health. The general interest demands, as an ecological alternative, the proper management of waste generated by industrial activity through its transformation into value-added products. Carbonization/activation (2 h/2 h) at 700 °C in a vertical furnace (20 K/min), to produce biochar and activated carbon (AC) from bamboo, orange, and paulownia residue, was carried out in a laboratory facility with physical activation by CO₂ and steam. The characterization of the carbonaceous material obtained was based on the determination of the N₂ adsorption–desorption isotherms at 77 K, the specific surface area with the BET procedure, and its internal structure by means of SEM images. The BET surface area values obtained as a function of the CO₂/steam agent used were 911/1182 m²/g, 248/388 m²/g, and 800/1166 m²/g for bamboo, orange, and paulownia, respectively. The range of variation of porosity in paulownia residue generated after steam activation was 485–1166 m²/g, varying depending on the degree of maturity of the biomass used. Research has shown that both the type of activation agent used to produce AC and the degree of plant maturation of the precursor residue affect the quality and characteristics of the final product. Full article

Based on the decision of representatives from the West African region and feedback from locals in Togo, an advanced continuous-feed, forced-draft, biomass cookstove named “Apeli” was developed. The stove was tested in modified ISO measurements based on the ISO 19867-1:2018 standard. This included a long shutdown operation using wood pellets and short shutdown operations using wood pellets, bamboo pellets, wheat straw pellets and palm kernel shells. Due to the fast shutdown capability, the short shutdown was chosen for more realistic results using this stove type. For cold start and long shutdown operation using wood pellets, the thermal efficiency is determined as 44.1% at a 1116 W power output by emitting 0.272 g CO and 17.2 mg PM 2.5 per MJ_d at high load. At low load, the efficiency is 38.0% at a 526 W power output by emitting 1.1 g CO and 45.1 mg PM 2.5 per MJ_d. Due to a misinterpretation of the standard, the burnout duration of the tests with long shutdown is approx. 1.5 min shorter than required. Using a worst-case approximation, values for a theoretical ISO-conforming measurement were calculated and rated according to the ISO 19867-3:2018 standard. The results showed that the Apeli would correspond to Tier 4 for efficiency and PM 2.5 as well as Tier 5 for CO in high-power operation using wood pellets. The use of alternative fuels is possible, but can lead to higher emissions compared to the use of wood pellets. With regard to possibly using the biochar produced in the process for soil application, it has been demonstrated that the PAH content ensures European BioChar-Agro-Organic limitations. The first results of a field test in Togo have shown that operating and feeding the stove by the target group is easy. The required permanent presence of the user during cooking with this stove seems to have a limited influence on acceptance, which seems to primarily depend on the age of the user. Moreover, it can be concluded that the Apeli has good potential to be mass-produced locally at low costs with a reliable supply of spare parts. This can contribute not only to improving clean cooking, but also to fighting air pollution and deforestation caused by solid fuel burning due to the reduced consumption of resources in the form of fuel, especially wood. Full article