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21 pages, 14185 KB  
Article
Disentangling Management and Climate Drivers in an Anthropogenic Transitional Mediterranean Coastal Groundwater-Dependent Ecosystem
by Luigi Alessandrino, Nicolò Colombani, Alessio Usai and Micòl Mastrocicco
Remote Sens. 2026, 18(11), 1738; https://doi.org/10.3390/rs18111738 - 28 May 2026
Viewed by 362
Abstract
Mediterranean coastal groundwater-dependent ecosystems are among the most vulnerable environments to the combined effects of climate change and local anthropogenic pressures, yet long-term quantitative assessments disentangling these drivers remain limited. The 41-year hydro-ecological dynamics (1984–2025) of “Le Soglitelle”, a transitional man-made coastal GDE [...] Read more.
Mediterranean coastal groundwater-dependent ecosystems are among the most vulnerable environments to the combined effects of climate change and local anthropogenic pressures, yet long-term quantitative assessments disentangling these drivers remain limited. The 41-year hydro-ecological dynamics (1984–2025) of “Le Soglitelle”, a transitional man-made coastal GDE located in the Campania Plain (southern Italy), were reconstructed across three management regimes: illegal hunting via electric pumps augmentation of flooded areas (1984–2004), post-seizure transition (2005–2015), and fenced natural reserve sustained by artesian wells flow (2016–2025). A monthly multi-sensor time series of seven spectral indices was derived from cross-calibrated Landsat program Surface Reflectance products via Google Earth Engine. Spectral indices were then combined with climatic variables (precipitation, reference evapotranspiration, air temperature) and then integrated in a statistical framework including Mann–Kendall test, Pettitt test, and Principal Component Analysis. Significant breakpoints were identified for the water fraction (2007; mean decrease from 0.18 to 0.09) and the Normalized Difference Vegetation Index (2009; mean increase from 0.30 to 0.42), consistent with a hydrological regime shift following the interruption of anthropogenic pressures. The relationship between the water fraction and the Vegetation Soil Salinity Index was 2.7 times steeper in the last period than the first one, indicating that, for an equivalent flooded extent, osmotic stress on vegetation is substantially higher under the artesian flow alone, likely due to reduced dilution of saline inputs combined with the effect of ongoing climate change. PCA showed that PC1 reflected the transition from anthropogenic to more natural system conditions, whereas PC2 was associated with increasing ET0, became more prominent during the last period of management, suggesting a shift toward stronger climate-driven control. Long-term satellite monitoring provides a quantitative baseline for designing targeted management interventions aimed at sustaining ecosystem functioning under ongoing Mediterranean warming. Full article
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19 pages, 7005 KB  
Article
Water Level Response to Earthquakes in an Open Well and in a Closed Well—Analysis of Field Observations
by Hallel Lutzky, Ittai Kurzon, Haim Gvirtzman, Vladimir Lyakhovsky and Eyal Shalev
Water 2025, 17(16), 2453; https://doi.org/10.3390/w17162453 - 19 Aug 2025
Viewed by 1680
Abstract
Seismic waves induce pore pressure changes in aquifers, leading to water level oscillations in wells. These oscillations are often used to estimate the poroelastic properties of aquifers, but their interpretation is influenced by factors such as aquifer properties, seismic wave characteristics, and wellbore [...] Read more.
Seismic waves induce pore pressure changes in aquifers, leading to water level oscillations in wells. These oscillations are often used to estimate the poroelastic properties of aquifers, but their interpretation is influenced by factors such as aquifer properties, seismic wave characteristics, and wellbore storage. The aim of this study is to evaluate the effect of wellbore storage on seismically induced water level oscillations. We analyze water level responses to similar seismic forcing in two adjacent deep wells (~1000 m) tapping the same confined aquifer: one open (artesian) and one closed (flowing artesian). Seismic forcing was characterized using ground motion velocity data from a nearby seismic station. The results show that the wells differ by three orders of magnitude in their wellbore storage. In the open well, pore pressure oscillations are reliably detected only for teleseismic events, while in the closed well, they are also reliably recorded for regional earthquakes. Under these conditions, it is possible to estimate the first-order approximation of the aquifer’s poroelastic coefficients. These findings emphasize the importance of accounting for wellbore storage when interpreting seismically induced water level fluctuations. Full article
(This article belongs to the Section Hydrogeology)
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23 pages, 9084 KB  
Article
Microbial Community Assembly Mechanisms of Groundwater Under Salinity–Oxygen Stress in the Golmud River Watershed, Northwest China
by Liang Guo, Haisong Fang, Yuanyuan Ding, Chunxue An and Nuan Yang
Life 2025, 15(8), 1301; https://doi.org/10.3390/life15081301 - 15 Aug 2025
Cited by 5 | Viewed by 1496
Abstract
The mechanisms underlying groundwater microbial community assembly have long attracted attention in earth, environmental, and ecological studies. Nevertheless, limited knowledge is available regarding microbial community assembly within the intact groundwater flow systems in arid regions. In this study, long-term hydrochemical data and microbial [...] Read more.
The mechanisms underlying groundwater microbial community assembly have long attracted attention in earth, environmental, and ecological studies. Nevertheless, limited knowledge is available regarding microbial community assembly within the intact groundwater flow systems in arid regions. In this study, long-term hydrochemical data and microbial community profiles were integrated to unravel the assembly processes and driving forces mediating microbial communities in the Golmud River watershed. Our results indicated that hydrochemical conditions gradually transitioned from oxidizing to reducing environments along the groundwater flow path, as evidenced by a 28.57% and 65.45% decrease in DO and ORP, respectively. Major ions, represented by TDS, displayed minimal variations in phreatic (519.72 ± 16.83 mg/L) and artesian groundwater (486.01 ± 27.71 mg/L), followed by pronounced enrichment in high-salinity groundwater (TDS: 316,112.74 ± 12,452.19 mg/L). Gammaproteobacteria and Actinobacteria declined markedly from phreatic (51.69 ± 6.83% and 9.54 ± 3.40%, respectively) to high-salinity groundwater (13.97 ± 3.70% and 4.77 ± 2.46%). Conversely, halophiles such as Halobacteria and Parcubacteria were rarely detected in low-TDS groundwater, but increased sharply in high-salinity groundwater, reaching 23.22 ± 10.42% and 8.34 ± 3.71%, respectively. Deterministic processes primarily controlled groundwater microbial communities across hydrochemical conditions (relative importance > 50%, NST index < 50%). Microbial co-occurrence networks revealed increasingly tight interactions and intensified competition among communities, driven by accumulated salinity–oxygen stress along the groundwater flow path. This study emphasizes the role of deterministic processes in shaping groundwater microbial community structure, particularly the impact of salinity–oxygen stress. Our findings advance the current understanding of the mechanisms by which hydrochemical processes shape groundwater microbial assemblages. Full article
(This article belongs to the Special Issue Microbial Diversity and Function in Aquatic Environments)
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37 pages, 20031 KB  
Article
MODFLOW Application for Exploitable Groundwater Resource Assessment of the Zhem Artesian Basin Aquifer Complex, Kazakhstan
by Daniyar Serikovich Sapargaliyev, Yermek Zhamshitovich Murtazin, Vladimir Mirlas, Vladimir Alexandrovich Smolyar and Yaakov Anker
Appl. Sci. 2025, 15(10), 5443; https://doi.org/10.3390/app15105443 - 13 May 2025
Cited by 2 | Viewed by 2167
Abstract
Groundwater resources are becoming increasingly scarce, especially in arid regions of western Kazakhstan. By 2070, the domestic and drinking water demands will increase from 640 to 901 thousand m3/day. This deficiency may be overcome by utilizing the Zhem Artesian Basin’s Cretaceous [...] Read more.
Groundwater resources are becoming increasingly scarce, especially in arid regions of western Kazakhstan. By 2070, the domestic and drinking water demands will increase from 640 to 901 thousand m3/day. This deficiency may be overcome by utilizing the Zhem Artesian Basin’s Cretaceous Albian–Cenomanian aquifer complex. The hydrodynamic interactions between the 123 known aquifer segments and recharge zones of these promising, exploitable, high-quality groundwater sources are unclear. While MODFLOW is a nominal platform for groundwater flow assessment, which is usually used for the simulation of simple hydrological scenarios, in this study, integrating several different scales and functional modules over a GIS platform enabled delineation and the forecast of this multi-layer aquifer complex. The MODFLOW simulation assessed exploitable groundwater resources and reservoir interactions, enabling the establishment of a simultaneous operation to the Zhem aquifer complex and its neighboring reservoirs. The model suggests that the total exploitable groundwater resources may grow to 629.4 thousand m3/day during the next 50 years. The simultaneous drawdown model suggests a water level decrease of up to 80 m at the end of this period, which will cause a river flow reduction of approximately 6% of the average long-term river flow. Thus, the assessed exploitable groundwater resources will cover more than 70% of the future regional water demand. The mathematical model developed may be used for monitoring and forecasting groundwater head and water balance changes and may be applied to attain a more detailed groundwater resource transfer scheme with economic criteria. Full article
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16 pages, 12834 KB  
Article
Temperature Variations in Deep Thermal Well LZT-1 in Lądek-Zdrój (Bohemian Massif; SW Poland)—Evidence of Geothermal Anomaly and Paleoclimatic Changes
by Barbara Kiełczawa, Wojciech Ciężkowski, Mirosław Wąsik, Karolina Szostak, Iwona Sieniawska and Marek Rasała
Energies 2024, 17(14), 3362; https://doi.org/10.3390/en17143362 - 9 Jul 2024
Cited by 1 | Viewed by 1898
Abstract
The thermal water deposit in Lądek-Zdrój (SW Poland) occurs in fractured reservoir rocks, and its hydrogeological regime is controlled by the features of the local geology and lithology of the hosting crystalline complexes, mainly impermeable high-grade metamorphosed mica schists and gneisses. The fractured [...] Read more.
The thermal water deposit in Lądek-Zdrój (SW Poland) occurs in fractured reservoir rocks, and its hydrogeological regime is controlled by the features of the local geology and lithology of the hosting crystalline complexes, mainly impermeable high-grade metamorphosed mica schists and gneisses. The fractured thermal water aquifer is confined by a thrust fault-type aquitard that creates artesian pressure and, therefore, the water intakes and natural springs in Lądek Zdrój provide spontaneous outflow. Classical geothermometers yield an estimation of reservoir temperatures that ranges from 50 to 70 °C, with a maximum of 88 °C. The heat flux (HF) value of the Lądek-Zdrój region is 64 mW/m2. The new borehole, LZT-1, is in the border zone of a local thermal anomaly with a geothermal degree of 25–27 m/°C. The estimated temperature at the bottom of the LZT-1 borehole, under thermal equilibrium conditions, ranges between 70 °C and 80 °C. A stream of heated waters from the deep system flows from the recharge areas, shaping the local geothermal anomaly and thus influencing the thermal conditions in the Lądek-Zdrój area. The activation of this water circulation system occurred in the Pleistocene. Full article
(This article belongs to the Section H: Geo-Energy)
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33 pages, 16477 KB  
Article
Geophysical and Geochemical Pilot Study to Characterize the Dam Foundation Rock and Source of Seepage in Part of Pensacola Dam in Oklahoma
by Oluseun Sanuade and Ahmed Ismail
Water 2023, 15(23), 4036; https://doi.org/10.3390/w15234036 - 21 Nov 2023
Cited by 9 | Viewed by 5228
Abstract
Pensacola Dam, operated by the Grand River Dam Authority (GRDA), is a multiple-arch buttress dam constructed in 1940. The dam has little or no existing geophysical reports on the integrity of the dam foundation rock and even less knowledge at depth. Visual inspection [...] Read more.
Pensacola Dam, operated by the Grand River Dam Authority (GRDA), is a multiple-arch buttress dam constructed in 1940. The dam has little or no existing geophysical reports on the integrity of the dam foundation rock and even less knowledge at depth. Visual inspection indicated evidence of seepage at some arches of the dam. As a pilot study, we conducted a suite of geophysical surveys inside two arches (Arch-16 and Arch-17) and a part of the downstream berm to characterize the dam foundation rock, delineate seepage zones, and identify the most appropriate geophysical methods for temporal monitoring of the dam’s conditions. The geophysical methods included electrical resistivity tomography (ERT), self-potential (SP), multichannel analysis of surface waves (MASW), compressional (P)-wave refraction, and shear (S)-wave reflection. Water samples were collected for geochemical analysis to investigate the source of the seepage flow inside Arch-16. The geophysical results characterized the dam foundation rock into an unsaturated limestone and chert overlying a water-saturated limestone and chert. The ERT profiles indicated that groundwater is rising inside the arches and significantly dropping under the downstream berm, which can be due to the uplift pressure beneath the dam base. Zones of high seepage potential were detected near the buttress walls of the two surveyed arches, which may be related to previous blasting, excavation of the dam foundation, concrete placement, or improper grouting. The geochemical analysis of water samples taken from the artesian wells inside Arch-16 and the Grand Lake revealed different chemical compositions, suggesting that the source of water could be a mixture of groundwater and lake water or lake water interacting with rock and reaching the surface through fractures; however, more sampling and further analysis are required to ascertain the source of the seeps. This study showed that the ERT, SP, and S-wave reflection methods have effectively characterized the dam foundation rock and seepage zones beneath the arches. The study provided a better understanding of the conditions of the dam foundation rock, evaluated the utilized geophysical methods, and determined the optimum geophysical methods that can be used for the characterization and monitoring of the subsurface conditions along the entire length of the dam. In this study, we have demonstrated that the integration of effective geophysical surveys and geochemical analysis yielded optimum results in solving a complex dam safety problem. This strategy promotes the best practice for dam safety investigation. Full article
(This article belongs to the Special Issue Groundwater Exploration and Hydrogeophysical Research)
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16 pages, 7350 KB  
Article
Study of Urban Flooding Response under Superstandard Conditions
by Jian Chen, Yangyang Tian, Shanju Zhang, Yaowei Li and Zhikai Guo
Water 2023, 15(8), 1492; https://doi.org/10.3390/w15081492 - 11 Apr 2023
Cited by 7 | Viewed by 3074
Abstract
Superstandard conditions refer to extreme rainfall and river flooding that exceed the flood control system or flood control works. In order to explore the influence of superstandard conditions on urban waterlogging, based on the MIKE FLOOD platform, this paper takes the downtown area [...] Read more.
Superstandard conditions refer to extreme rainfall and river flooding that exceed the flood control system or flood control works. In order to explore the influence of superstandard conditions on urban waterlogging, based on the MIKE FLOOD platform, this paper takes the downtown area of Zhoukou as the research object, and it conducts waterlogging simulation in this area under the extreme rainfall conditions of once in 20 years and once in 50 years combined with the ultra-high water level of the river. The simulation results of inundation depth, inundation range and drainage capacity of a self-flowing river are compared and analyzed. The results show that heavy rainfall is the main cause of waterlogging disaster. When extreme rainfall and river flood occur at the same time, the artesian drainage capacity of the pipeline is seriously affected due to the high water level of the river. The city has a large amount of water, and when the river embankment overflows, it poses a serious threat to the safety of the city. Full article
(This article belongs to the Special Issue Flooding in Urban Areas: Risks and Responses)
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23 pages, 1759 KB  
Article
Evaluation of Water Quality of Buritis Lake
by Renata Kikuda, Raylane Pereira Gomes, Aline Rodrigues Gama, Junilsom Augusto De Paula Silva, Adailton Pereira Dos Santos, Keliane Rodrigues Alves, Poliana Nascimento Arruda, Paulo Sérgio Scalize, José Daniel Gonçalves Vieira, Lilian Carla Carneiro and Debora De Jesus Pires
Water 2022, 14(9), 1414; https://doi.org/10.3390/w14091414 - 28 Apr 2022
Cited by 13 | Viewed by 4469
Abstract
The implementation of natural parks in cities is a current and controversial theme. Therefore, in Lake Buritis, which is a leisure area for the population of the city of Goiatuba, Goiás, Brazil, the quality of the water was analyzed, carrying out quantitative tests [...] Read more.
The implementation of natural parks in cities is a current and controversial theme. Therefore, in Lake Buritis, which is a leisure area for the population of the city of Goiatuba, Goiás, Brazil, the quality of the water was analyzed, carrying out quantitative tests of the water samples at six different points between the source and the outlet of the lake that flows into the stream, Chico À Toa. Physical–chemical tests (turbidity, pH, alkalinity, electrical conductivity, color, nitrate and hardness parameters), microbiological tests for species identification, analysis of the antimicrobial susceptibility profile, metals analysis and Allium cepa test, were performed. The total coliforms number in water samples was higher than the maximum value established by Brazilian legislation, demonstrating high fecal contamination during the spring in samples from an artesian well. The bacterial diversity found was large and there were many pathogenic bacteria. The A. cepa test demonstrated a cytotoxic potential for water from the source and outlet of Buritis Lake. Statistical tests were applied to verify existing correlations between parameters. Among the analyzed data, the highest correlation was between the color and turbidity parameters and the grouping between the metals (lead, iron, cadmium and magnesium). Full article
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21 pages, 2688 KB  
Article
Extension of Duplexed Single-Ended Distributed Temperature Sensing Calibration Algorithms and Their Application in Geothermal Systems
by Matías Lillo, Francisco Suárez, Mark B. Hausner, Gonzalo Yáñez and Eugenio A. Veloso
Sensors 2022, 22(9), 3319; https://doi.org/10.3390/s22093319 - 26 Apr 2022
Cited by 7 | Viewed by 3409
Abstract
Fiber-optic distributed temperature sensing (DTS) has been widely used since the end of the 20th century, with various industrial, Earth sciences, and research applications. To obtain precise thermal measurements, it is important to extend the currently available DTS calibration methods, considering that environmental [...] Read more.
Fiber-optic distributed temperature sensing (DTS) has been widely used since the end of the 20th century, with various industrial, Earth sciences, and research applications. To obtain precise thermal measurements, it is important to extend the currently available DTS calibration methods, considering that environmental and deployment factors can strongly impact these measurements. In this work, a laboratory experiment was performed to assess a currently available duplexed single-ended DTS calibration algorithm and to extend it in case no temperature information is available at the end of the cables, which is extremely important in geothermal applications. The extended calibration algorithms were tested in different boreholes located in the Atacama Desert and in the Central Andes Mountains to estimate the geothermal gradient in these regions. The best algorithm found achieved a root mean square error of 0.31 ± 0.07 °C at the far end of a ~1.1-km cable, which is much smaller than that obtained using the manufacturer algorithm (2.17 ± 0.35 °C). Moreover, temperature differences between single- and double-ended measurements were less than 0.3 °C at the far end of the cable, which results in differences of ~0.5 °C km−1 when determining the geothermal gradient. This improvement in the geothermal gradient is relevant, as it can reduce the drilling depth by at least 700 m in the study area. Future work should investigate new extensions of the algorithms for other DTS configurations and determining the flow rate of the Central Andes Mountains artesian well using the geothermal profile provided by the DTS measurements and the available data of the borehole Full article
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26 pages, 12371 KB  
Article
Groundwater-Extracting Rice Production in the Rejoso Watershed (Indonesia) Reducing Urban Water Availability: Characterisation and Intervention Priorities
by Ni’matul Khasanah, Lisa Tanika, Lalu Deden Yuda Pratama, Beria Leimona, Endro Prasetiyo, Fitri Marulani, Adis Hendriatna, Mukhammad Thoha Zulkarnain, Alix Toulier and Meine van Noordwijk
Land 2021, 10(6), 586; https://doi.org/10.3390/land10060586 - 1 Jun 2021
Cited by 14 | Viewed by 5804
Abstract
Production landscapes depend on, but also affect, ecosystem services. In the Rejoso watershed (East Java, Indonesia), uncontrolled groundwater use for paddies reduces flow of lowland pressure-driven artesian springs that supply drinking water to urban stakeholders. Analysis of the water balance suggested that the [...] Read more.
Production landscapes depend on, but also affect, ecosystem services. In the Rejoso watershed (East Java, Indonesia), uncontrolled groundwater use for paddies reduces flow of lowland pressure-driven artesian springs that supply drinking water to urban stakeholders. Analysis of the water balance suggested that the decline by about 30% in spring discharge in the past decades is attributed for 47 and 53%, respectively, to upland degradation and lowland groundwater abstraction. Consequently, current spring restoration efforts support upland agroforestry development while aiming to reduce lowland groundwater wasting. To clarify spatial and social targeting of lowland interventions five clusters (replicable patterns) of lowland paddy farming were distinguished from spatial data on, among other factors, reliance on river versus artesian wells delivering groundwater, use of crop rotation, rice yield, fertiliser rates and intensity of rodent control. A survey of farming households (461 respondents), complemented and verified through in-depth interviews and group discussions, identified opportunities for interventions and associated risks. Changes in artesian well design, allowing outflow control, can support water-saving, sustainable paddy cultivation methods. With rodents as a major yield-reducing factor, solutions likely depend on more synchronized planting calendars and thus on collective action for effectiveness at scale. Interventions based on this design are currently tested. Full article
(This article belongs to the Special Issue Agroforestry-Based Ecosystem Services)
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15 pages, 3756 KB  
Article
Probabilistic Groundwater Flow, Particle Tracking and Uncertainty Analysis for Environmental Receptor Vulnerability Assessment of a Coal Seam Gas Project
by Dennis Gonzalez, Sreekanth Janardhanan, Daniel E. Pagendam and Daniel W. Gladish
Water 2020, 12(11), 3177; https://doi.org/10.3390/w12113177 - 13 Nov 2020
Cited by 6 | Viewed by 3067
Abstract
The production of coalbed methane, or coal seam gas (CSG) in Australia increased 250-fold since the 1990s to around 1502 petajoules in 2019 and continues to expand. Groundwater flow in the aquifers intersected by gas wells could potentially facilitate a transport pathway for [...] Read more.
The production of coalbed methane, or coal seam gas (CSG) in Australia increased 250-fold since the 1990s to around 1502 petajoules in 2019 and continues to expand. Groundwater flow in the aquifers intersected by gas wells could potentially facilitate a transport pathway for migration of contaminants or poorer quality water from deeper formations. While regulatory and mitigation mechanisms are put in place to minimize the risks, quantitative environmental impact assessments are also undertaken. When many gas wells are drilled in a wide area where many potential receptors are also spatially distributed, potential source-receptor combinations are too numerous to undertake detailed contamination risk assessment using contaminant transport modelling. However, valuable information can be gleaned from the analysis of groundwater flow directions and velocities to inform and prioritise contamination risk assessment and can precede computationally challenging stochastic contaminant transport modelling. A probabilistic particle tracking approach was developed as a computationally efficient screening analysis of contamination pathways for a planned CSG development near Narrabri in northern New South Wales, Australia. Particle tracking was run iteratively with a numerical groundwater flow model across a range of plausible parameter sets to generate an ensemble of estimated flow paths through the main Great Artesian Basin aquifer in the area. Spatial patterns of path lines and spatial relationships with potential receptors including neighbouring groundwater extraction wells and hydrologically connected ecological systems were analysed. Particle velocities ranged from 0.5 to 11 m/year and trajectories indicated dedicated contaminant transport modeling would be ideally focused at the local scale where wells are near potential receptors. The results of this type of analysis can inform the design of monitoring strategies and direct new data collection to reduce uncertainty and improve the effectiveness of adaptive management strategies and early detection of impacts. Full article
(This article belongs to the Section Hydrology)
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22 pages, 9587 KB  
Article
Temporal Variations of Spring Water in Karst Areas: A Case Study of Jinan Spring Area, Northern China
by Zongjun Gao, Jiutan Liu, Xingyong Xu, Qingbing Wang, Min Wang, Jianguo Feng and Tengfei Fu
Water 2020, 12(4), 1009; https://doi.org/10.3390/w12041009 - 1 Apr 2020
Cited by 28 | Viewed by 6089
Abstract
Jinan is known as “Spring City,” because of its famous 72 artesian springs. Spring water plays an important role in the social and economic development of Jinan. However, the accelerating process of urbanization and more intensive human activities have significantly affected the Jinan [...] Read more.
Jinan is known as “Spring City,” because of its famous 72 artesian springs. Spring water plays an important role in the social and economic development of Jinan. However, the accelerating process of urbanization and more intensive human activities have significantly affected the Jinan springs. Based on the data from four spring groups (2015–2018), the hydrochemical characteristics of spring water were analyzed and 14 parameters were selected to evaluate the quality of spring water. In addition, the main ions variation characteristics of spring water in Jinan from 1958 to 2018 were analyzed, based on the previous studies. Subsequently, the spring flow dynamics of the Jinan spring area from 1958 to 2012 were also discussed. Overall, the water quality of the four spring groups is good. The chemical composition of the spring water is mainly controlled by the dissolution of calcite, followed by dolomite, and de-dolomitization. However, spring water is affected by human activities, and the hydrochemical type tends to evolve from HCO3-Ca to HCO3·SO4-Ca or HCO3-Ca·Mg. From 1958 to 2013, the main ions in spring water increased, while a relatively steady and certain fluctuation trend was observed from 2015 to 2018. Since 1958, the spring water flow in Jinan has experienced four stages, from decline to recovery. The exploitation of karst groundwater, change of land use type, and decrease of atmospheric precipitation are the three most important factors, affecting spring discharge dynamics. The slowdown of the increase of the main ion concentration in Jinan spring water and the resumption of spring water flowing indicate that remarkable achievements have been made to protect spring water, but there is still a long way to go to fully protect Jinan spring water. Full article
(This article belongs to the Section Hydrology)
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12 pages, 839 KB  
Article
Novel Approach to Automated Flow Titration for the Determination of Fe(III)
by Joanna Kozak, Justyna Paluch, Marek Kozak, Marta Duracz, Marcin Wieczorek and Paweł Kościelniak
Molecules 2020, 25(7), 1533; https://doi.org/10.3390/molecules25071533 - 27 Mar 2020
Cited by 6 | Viewed by 5680
Abstract
A novel approach to automated flow titration with spectrophotometric detection for the determination of Fe(III) is presented. The approach is based on the possibility of strict and simultaneous control of the flow rates of sample and titrant streams over time. It consists of [...] Read more.
A novel approach to automated flow titration with spectrophotometric detection for the determination of Fe(III) is presented. The approach is based on the possibility of strict and simultaneous control of the flow rates of sample and titrant streams over time. It consists of creating different but precisely defined concentration gradients of titrant and analyte in each successively formed monosegments, and is based on using the calculated titrant dilution factor. The procedure was verified by complexometric titration of Fe(III) in the form of a complex with sulfosalicylic acid, using EDTA as a titrant. Fe(III) and Fe(II) (after oxidation to Fe(III) with the use of H2O2) were determined with good precision (CV lower than 1.7%, n = 6) and accuracy ( | RE | lower than 3.3%). The approach was applied to determine Fe(III) and Fe(II) in artesian water samples. Results of determinations were consistent with values obtained using the ICP–OES reference method. Using the procedure, it was possible to perform titration in 6 min for a wide range of analyte concentrations, using 2.4 mL of both sample and titrant. Full article
(This article belongs to the Special Issue Modern Flow Analysis)
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15 pages, 6272 KB  
Article
Potential Impacts to Wetlands and Water Bodies Due to Mineral Exploration, Pebble Copper-Gold Prospect, Southwest Alaska
by Kendra Zamzow and David M. Chambers
Environments 2019, 6(7), 84; https://doi.org/10.3390/environments6070084 - 19 Jul 2019
Cited by 3 | Viewed by 8413
Abstract
There is little information in the literature about the impacts of mineral exploration drilling on natural waters. A copper-gold-molybdenum mining deposit in Alaska was heavily explored until 2012 and partially reclaimed; however, full reclamation of drill sites remained incomplete in 2016. Copper is [...] Read more.
There is little information in the literature about the impacts of mineral exploration drilling on natural waters. A copper-gold-molybdenum mining deposit in Alaska was heavily explored until 2012 and partially reclaimed; however, full reclamation of drill sites remained incomplete in 2016. Copper is sub-lethally toxic to salmon, a highly-valued resource in this area. Of 109 sites inspected, 9 sites had confirmed impacts due to un-reclaimed drill-holes or drill waste disposal practices. At seven sites artesian waters at the drill stem resulted in surface water or sediment elevated in aluminum, iron, copper, or zinc with neutral pH. Copper concentrations at artesian sites were <0.4, 0.7, 2, 7, 15, 76, and 215 µg/L; the latter four exceed water quality criteria. Drilling waste is known to have been disposed of in ponds and unlined sumps. At one of five ponds sampled, copper declined from 51 to 8 µg/L over nine years. At the one sump area with historical data, copper increased from 0.3 to 1.8 µg/L at a downgradient wetland spring over five years. This research identifies contaminant types and sources and can be used to guide future ecotoxicity studies and improve regulatory oversight. Full article
(This article belongs to the Special Issue Groundwater Quality and Groundwater Vulnerability Assessment)
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20 pages, 3073 KB  
Article
Experimental Study and Estimation of Groundwater Fluctuation and Ground Settlement due to Dewatering in a Coastal Shallow Confined Aquifer
by Jiong Li, Ming-Guang Li, Lu-Lu Zhang, Hui Chen, Xiao-He Xia and Jin-Jian Chen
J. Mar. Sci. Eng. 2019, 7(3), 58; https://doi.org/10.3390/jmse7030058 - 1 Mar 2019
Cited by 8 | Viewed by 4764
Abstract
The coastal micro-confined aquifer (MCA) in Shanghai is characterized by shallow burial depth, high artesian head, and discontinuous distribution. It has a significant influence on underground space development, especially where the MCA is directly connected with deep confined aquifers. In this paper, a [...] Read more.
The coastal micro-confined aquifer (MCA) in Shanghai is characterized by shallow burial depth, high artesian head, and discontinuous distribution. It has a significant influence on underground space development, especially where the MCA is directly connected with deep confined aquifers. In this paper, a series of pumping well tests were conducted in the MCA located in such area to investigate the dewatering-induced groundwater fluctuations and stratum deformation. In addition, a numerical method is proposed for the estimation of hydraulic parameter, and an empirical prediction method is developed for dewatering-induced ground settlement. Test results show that groundwater drawdowns and soil settlement can be observed not only in MCA but also in the aquifers underneath it. This indicates that there is a close hydraulic connection among each aquifer. Moreover, the distributions and development of soil settlement at various depths are parallel to those of groundwater drawdowns in most areas of the test site except the vicinity of pumping wells, where collapse-induced subsidence due to high-speed flow may occur. Furthermore, the largest deformation usually occurs at the top of the pumping aquifer instead of the ground surface, because the top layer is expanded due to the stress arch formed in it. Finally, the proposed methods are validated to be feasible according to the pumping well test results and can be employed to investigate the responses of groundwater fluctuations and stratum deformations due to dewatering in MCA. Full article
(This article belongs to the Special Issue Coastal Geohazard and Offshore Geotechnics)
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