Search Results (144)

When processing widely used materials in welded structures such as steels, a surface operation such as plasma cutting applied in the automated Computer Numerical Control (CNC) version can provide technical and economic benefits to the cut components, but the impact on health and environment must be addressed accordingly. In this paper, a plate with a base material made of S355J2 + AR structural steel is cut in 10 pieces with plasma in a water-bed designed and manufactured by the authors in order to mitigate such risks. The surfaces cut in the water-bed are compared to surfaces cut in open air by macroscopic analyses of the edge cut, by microscopic analyses of the cut parts—base material, heat-affected zone, and cut area—and by hardness determinations. The results reveal improvements as a result of plasma cutting in the water-bed: slag reduction, preservation of granulation, transformations in the austenitic temperature zone, and hardness in the heat-affected zone. Compared to a classical cutting procedure such as oxygen flame cutting, the proposed procedure offers a clean alternative and also requires low maintenance. Full article

The world’s energy demand increases daily, fostering the search for renewable fuels to reconcile production needs with environmental sustainability. To prevent the severe atmospheric impact of fossil fuels, reducing greenhouse gas emissions is both essential and urgent, reinforcing the necessity of developing and adopting renewable fuel alternatives. Therefore, this work aimed to produce bio-oil through sugarcane bagasse fast pyrolysis. The methodology is based on fast pyrolysis operation in a fluidized bed reactor (pilot plant) as a thermochemical method for bio-oil production. This research required the conditioning of the raw material for system feeding, along with optimizing key variables, operating temperature, airflow, and sugarcane bagasse feed rate, to achieve improved yields compared to previous studies conducted in this pilot plant. The sugarcane bagasse was conditioned through drying and milling, followed by characterization using various analytical methods, including calorific value, thermogravimetric analysis (TGA), particle size analysis by laser diffraction (Mastersizer—MS), and ultimate analysis (determining carbon, hydrogen, nitrogen, sulfur, and oxygen by difference). The bio-oil produced showed promising yield results, with a maximum estimated value of 61.64%. Fourier Transform Infrared Spectroscopy (FT-IR) analysis confirmed the presence of aromatic compounds, as well as ester, ether, carboxylic acid, ketone, and alcohol functional groups. Full article

This study explores the production of anhydrous ethanol from discarded fruits, aiming to determine optimal fermentation conditions and evaluate the feasibility of a green separation technology. Fermentation experiments were performed using juices from Psidium guajava (S1), Carica paapaya (S2), and mucilage residues of Coffea arabica (S3). All fermentations were carried out at a pH of 4.5 for 7 days in 1 L bioreactors. A full 2² factorial design was applied to evaluate the effects of two variables: yeast type (commercial Saccharomyces cerevisiae [CY] vs. native yeast [NY]) and temperature (21 °C vs. 30 °C). Higher ethanol concentrations were achieved with CY at 30 °C, yielding 6.79% ethanol for S3. A multi-criteria matrix prioritized coffee residues due to their high ethanol yield, biomass availability, and economic viability. The ethanol was dehydrated using a packed-bed bioadsorption system with crushed corn, which increased purity from 6.7% v/v to 98.9% v/v in two stages, while avoiding azeotropic limitations. Energy analysis revealed low specific consumption (3.68 MJ/kg), outperforming conventional distillation. The results of this study, obtained at operating temperatures of 30 °C and 21 °C, a pH of 4.5, and an operating time of 7 days in a 1L bioreactor, demonstrate ethanol concentrations of 6.79%, confirming the technical feasibility of using agricultural waste as a raw material and validating the efficiency of a bioadsorption-based dehydration system. These findings address the current gap in integrating green ethanol separation with low-cost agricultural residues and highlight a sustainable alternative for decentralized bioethanol production. Full article

This study developed a novel pulsation-fluidized bed system, and the device was integrated into a reflux classifier to enhance the preconcentration of antimony oxide ore. The diaphragm-based pulsation device converts a stable upward water flow into a vertically alternating pulsation flow. By precisely controlling the pulsation parameters and optimizing operational conditions, the density-based stratification of particles can be significantly enhanced, thereby improving bed layering and effectively reducing entrainment. An antimony oxide ore from flotation tailings with an Sb grade of 0.8% was used as the feed material to evaluate the performance of the pulsation reflux classifier (PRC). Under optimized conditions, the PRC produced a concentrate with an Sb grade of 5.48% and a recovery of 81.68%, corresponding to a high separation efficiency of 70.97%. The response surface statistical model revealed that the interaction between the fluidization rate and pulsation frequency significantly enhanced the Sb grade of the concentrate, while pulsation stroke was identified as the key factor influencing separation efficiency. Furthermore, the variation in bed profile parameters with changing pulsation characteristics elucidates the interplay between particle suspension, stratification, and fluid disturbances. This study demonstrates that pulsation fluidization significantly enhances the separation performance of the reflux classifier, offering a new approach for the efficient preconcentration of complex fine-grained minerals. Full article

Deep dehumidification is crucial for industrial applications requiring ultra-low humidity levels. Traditional cooling-based dehumidification struggles to achieve low dew points efficiently due to excessive energy consumption and frost formation risks. As an alternative, desiccant-based methods, particularly solid desiccant systems, offer improved performance with lower energy demands. This study experimentally investigates a fixed-bed dehumidification system utilizing a plate-fin heat exchanger filled with a silica gel/calcium chloride composite material. The performance evaluation focuses on the influence of ambient conditions and operating parameters, including air velocity and cooling fluid temperature. Among these, the most influential parameter was the velocity of air. For the tested heat exchanger, an optimum value in the range of 0.4–0.6 m/s was identified. Under optimal conditions, the tested HEX was able to reduce the dew point of air down to −2 °C, achieving a reduction in the humidity ratio up to 13 g/kg. The results indicate that air velocity significantly impacts also heat and mass transfer, with coefficients ranging from 80 to 140 W/(m² K) and 0.015 to 0.060 kg/(m² s), respectively. The findings highlight the potential of composite desiccant fixed-bed systems for efficient deep dehumidification, outperforming conventional lab-scale components in heat and mass transfer effectiveness. A comparison with other works in the literature indicated that up to 30% increased mass transfer coefficient was achieved and up to seven times higher heat transfer coefficient was measured. Full article

This study explores the development and optimization of quartz-based filtration media for industrial oil–water separation, focusing on enhancing surface wettability, minimizing fouling, and improving oil rejection efficiency. High-purity quartz particles (SiO₂: 98%, Fe₂O₃: 0.18%, particle size: 0.8–1.8 mm) were evaluated in three configurations: raw, acid-washed, and surface-coated with hydrophilic nanoparticles (Al₂O₃ and P₂O₅). The filtration medium was constructed as a packed-bed of quartz particles rather than a continuous sintered membrane, providing a cost-effective and modular structure for separation processes. Comprehensive material characterization was performed using X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive Spectroscopy (EDS). XRD confirmed the crystalline stability of quartz across all treatments, while SEM and EDS revealed enhanced surface morphology and elemental distribution—especially phosphorus and aluminum—in coated samples. Performance testing with synthetic oily wastewater (initial oil concentration: 183,754.8 mg/L) demonstrated that the coated quartz medium achieved superior separation, reducing residual oil concentration to 29.3 mg/L, compared to 1583.7 mg/L and 1859.8 mg/L for washed and raw quartz, respectively. Contact angle analysis confirmed improved hydrophilicity in coated media, which also exhibited lower fouling propensity. Taguchi optimization (conducted via Minitab 21.3) and regression modeling identified surface coating and operational pressure (optimal at 2.5 bar) as the most significant parameters influencing oil rejection. Post-filtration SEM and XRD confirmed structural integrity and coating durability. Additionally, flux recovery above 90% after backwashing indicated strong regeneration capability. These findings validate surface-modified quartz packed beds as robust, scalable, and economically viable alternatives to conventional membranes in oily wastewater treatment. Future research will explore multilayer coatings, long term performance under aggressive conditions, and AI-based prediction models. Full article

Laser powder bed fusion (L-PBF) has become a highly viable method for manufacturing metal structural components for a variety of industries. Despite many attractive qualities, the rough surfaces of L-PBF components often necessitates post-processing treatments to improve the surface finish. Furthermore, heat treatments are generally necessary to control the microstructure and properties of L-PBF components, which can impart a detrimental surface oxide layer that requires removal. In this investigation, cavitation abrasive surface finishing (CASF) was adopted for the surface treatment of Ti6Al4V components produced by L-PBF and removal of the surface oxide layer. The surface texture, residual stress, and material removal were evaluated over a range of treatment conditions and as a function of the target surface orientation. Results showed that CASF reduced the average surface roughness from the as-built condition (R_a ≈ 15 µm) to below 5 µm as well as imparted a surface compressive residual stress of up to 600 MPa. The CASF treatment removed the alpha case from direct line-of-sight surfaces under a range of treatment intensity. However, deep valleys and surfaces at large oblique angles of incidence (≥60°) proved challenging to treat uniformly. Overall, results suggest that CASF could serve as a potent alternative to chemical treatments for post-processing of L-PBF components of titanium and other metals. Further investigation is recommended for improving the process effectiveness and to characterize the fatigue performance of the treated metal. Full article

Peripheral nerve injury disrupts the function of the peripheral nervous system, leading to sensory, motor, and autonomic deficits. While peripheral nerves possess an intrinsic regenerative capacity, complete sensory and motor recovery remains challenging due to the unpredictable nature of the healing process, which is influenced by the extent of the injury, age, and timely intervention. Recent advances in microsurgical techniques, imaging technologies, and a deeper understanding of nerve microanatomy have enhanced functional outcomes in nerve repair. Nerve injury initiates complex pathophysiological responses, including Wallerian degeneration, macrophage activation, Schwann cell dedifferentiation, and axonal sprouting. Complete nerve disruptions require surgical intervention to restore nerve continuity and function. Direct nerve repair is the gold standard for clean transections with minimal nerve gaps. However, in cases with larger nerve gaps or when direct repair is not feasible, alternatives such as autologous nerve grafting, vascularized nerve grafts, nerve conduits, allografts, and nerve transfers may be employed. Autologous nerve grafts provide excellent biocompatibility but are limited by donor site morbidity and availability. Vascularized grafts are used for large nerve gaps and poorly vascularized recipient beds, while nerve conduits serve as a promising solution for smaller gaps. Nerve transfers are utilized when neither direct repair nor grafting is possible, often involving re-routing intact regional nerves to restore function. Nerve conduits play a pivotal role in nerve regeneration by bridging nerve gaps, with significant advancements made in material composition and design. Emerging trends in nerve regeneration include the use of 3D bioprinting for personalized conduits, gene therapy for targeted growth factor delivery, and nanotechnology for nanofiber-based conduits and stem cell therapy. Advancements in molecular sciences have provided critical insights into the cellular and biochemical mechanisms underlying nerve repair, leading to targeted therapies that enhance axonal regeneration, remyelination, and functional recovery in peripheral nerve injuries. This review explores the current strategies for the therapeutic management of peripheral nerve injuries, highlighting their indications, benefits, and limitations, while emphasizing the need for tailored approaches based on injury severity and patient factors. Full article

Anthropization has significantly altered the natural water cycle by increasing impermeable surfaces, reducing evapotranspiration, and limiting groundwater recharge. Permeable Interlocking Concrete Pavements (PICPs) have emerged as a permeable pavement, effectively reducing runoff and improving water quality. This study investigates the base depth for PICPs regarding the strength and permeability. This study examines the hydraulic and structural performance of Permeable Interlocking Concrete Pavements (PICPs) for urban and industrial applications by evaluating the effects of subgrade conditions, traffic loads, and material properties. Using DesignPave and PermPave software, the optimal base layer thickness is determined to prevent rutting while ensuring effective stormwater infiltration beneath 110 mm-thick concrete pavers placed on a 30 mm-thick bedding course. The required base thickness for urban pavements ranges from 100 mm to 395 mm, whereas for industrial pavements, it varies between 580 mm and 1760 mm, depending on subgrade permeability, traffic volume, and loading conditions. The findings demonstrate that PICPs serve as a viable and environmentally sustainable alternative to conventional impermeable pavements, offering significant hydrological and ecological benefits. Full article

In recent years, packed-bed systems for large-scale applications have emerged as a highly promising design for Thermal Energy Storage systems because of their high thermal efficiency and economic feasibility. Large-scale application systems typically include packed-bed thermal energy stores as essential components, enabling effective integration with renewable energy and processed heat. The packed-bed systems investigated in this paper utilise Magnesia as the storage medium and optimised parameters, which have previously been identified through research involving charging and discharging cycles of both the hot and cold storage systems when air is the heat transfer fluid. This includes solid particle diameters of 0.004 m, a material porosity of 0.2, an aspect ratio of 1 for the storage tank, and a mass flow rate of 13.7 kg/m³. This paper aims to present a comparative analysis of the influence of alternative heat transfer gases, namely air, argon, carbon dioxide, helium, hydrogen, and nitrogen, on the performance of Pumped Thermal Energy Storage hot and cold storage systems. The performance of the six gases in the storage system was evaluated using an axisymmetric model simulated with COMSOL Multiphysics 5.6 software, with the total energy stored and the capacity factor serving as key performance indicators. The results revealed that carbon dioxide gas was the most promising heat transfer fluid and that the packed bed could be operated efficiently over 72% and 76% of its range for hot and cold systems, respectively. Hydrogen, nitrogen, and air performed similarly but less adequately than carbon dioxide and had operating ranges of 55% and 75% for hot and cold storage. Helium and argon had the poorest performance, with optimal charging and discharging rates corresponding to 50% and 66%. Full article

Bedding is an important component of equine accommodation management. Choosing the right bedding is important for stable management and its selection may include considerations such as the sourcing of the material, the capital investment and ongoing costs, delivery, storage, installation, ongoing labour and maintenance, removal and disposal. Furthermore, it is crucial that the consequences for the health and welfare of horses and humans and the impact on the environment should also be considered. This review aimed to outline the advantages and disadvantages of different horse bedding types, focusing on their effects on the well-being of horses, humans, and the environment. The Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) technique was used as the methodology for this review. The search was performed in Scopus and Web of Science bibliometric databases and a total of 176 records were screened reading the title and the abstract. After screening, 58 records were retained and another 19 records were identified using their reference lists (i.e., snowballing). Therefore, a total of 77 records were considered. Straw and wood shavings were the most commonly used and studied bedding materials, while research on alternative options remains limited. Straw is identified as horses’ preferred option, while shavings appear to be the easiest to clean, making them the preferred choice for stable workers. The parameters to consider when choosing the bedding most fit for purpose are many and their attributes differ across the various bedding types. This review has compared all the bedding types within the research literature to determine the best overall option using the research-based evidence. Each bedding type offers unique benefits and drawbacks summarised in a user-friendly table. Stable managers must consider and evaluate them to suit their specific needs, including the health and welfare of each horse and the husbandry system involved. Our findings may, therefore, be useful in the decision-making process of equine industry members. Full article

The fuel-cell (FC) power system, utilizing biohydrogen from biomass resources, is a promising alternative to fossil fuels. However, hydrogen sulfide (H₂S) in bio-syngas can severely degrade FC performance and increase environmental impact, necessitating impurity removal. This study investigates a multi-stage desulfurization process using neutralized sediment (NS) and a metal hydride (LaNi₅) as H₂S adsorbents. NS, a mining waste material, can potentially reduce environmental impact when repurposed as an adsorbent, with its performance influenced by pore configuration and Fe content. However, the purified gas does not fully meet FC fuel specifications. To address this, LaNi₅, which selectively absorbs and releases hydrogen, was incorporated to achieve higher purification levels. In our study, H₂S adsorption tests were conducted using two fixed-bed flow reactors heated to 250 °C, where a gas mixture containing 196 ppm of H₂S flowed through the system. The proposed multi-stage system achieved a breakthrough time of 182.5 h with purified gas remaining under 0.1 ppm and an adsorption capacity of 16.4 g/g-sorbent. These results demonstrate the high desulfurization performance achieved using NS and LaNi₅. Full article

The scientific community has placed increasing importance on sustainability, leading to the exploration of alternative bedding materials to the widely used aspen wood chips. Bedding plays a critical role in ensuring the wellbeing of animals and the validity of experimental outcomes. Compared to the frequently evaluated biological materials, such as corncobs or spelts, synthetic materials such as plastic granules have been less investigated. We characterized two thermostable plastic materials as an alternative bedding material in C57BL/6J and BALB/c mice. We examined the impact of those bedding alternatives on physiological parameters, behavior, health status, and cage climate in static and digitally ventilated cages as well as the possibility of a reuse cycle after reprocessing. The mouse lines showed different locomotor activity, feeding, and nestbuilding behavior on plastic granules. While ammonia levels were constantly higher in static cages than in ventilated cages, blood parameters were unaltered, and health status was maintained during the reuse procedure. We show the use of plastic granulate as bedding material for mice that has the potential for processing and recycling. Further, we show that the material is accepted differently by the lines in the preference choice test without affecting their health or hygiene status. Full article

Triply periodic minimal surfaces (TPMSs) are known for their smooth, fully interconnected, and naturally porous characteristics, offering a superior alternative to traditional porous structures. These structures often suffer from stress concentration and a lack of adjustability. Using laser powder bed fusion (LPBF), we have fabricated Inconel 625 sheet-based TPMS lattice structures with four distinct topologies: Primitive, IWP, Diamond, and Gyroid. The compressive responses and energy absorption capabilities of the four lattice designs were meticulously evaluated. The discrepancies between theoretical predictions and the fabricated specimens were precisely quantified using the Archimedes’ principle for volume displacement. Subsequently, the LPBF-manufactured samples underwent uniaxial compression tests, which were complemented by numerical simulation for validation. The experimental results demonstrate that the IWP lattice consistently outperformed the other three configurations in terms of yield strength. Furthermore, when comparing energy absorption efficiencies, the IWP structures were confirmed to be more effective and closer to the ideal performance. An analysis of the deformation mechanisms shows that the IWP structure characteristically failed in a layer-by-layer manner, distinct from the other structures that exhibited significant shear banding. This distinct behavior was responsible for the higher yield strength (113.16 MPa), elastic modulus (735.76 MPa), and energy absorption capacity (9009.39 MJ/m³) observed in the IWP configuration. To examine the influence of porosity on structural performance, specimens with two varying porosities (70% and 80%) were selected for each of the four designs. Ultimately, the mechanical performance of Inconel 625 under compression was assessed both pre- and post-deformation to elucidate its impact on the material’s integrity. Full article

A huge variety of chemical commodities are built from propylene molecules, and its conventional production technologies (naphtha steam cracking and fluid catalytic cracking) are unable to satisfy C₃H₆’s increasing requirements. In this scenario, Direct Propane Dehydrogenation (PDH) provides a practical and reliable route for supplying this short demand due to the economic availability of the raw material (C₃H₈) and the high propylene selectivities. The main challenges of propane dehydrogenation technology are related to the design of very active catalysts with negligible byproduct formation. In particular, the issue of catalyst deactivation by coke deposition still requires further development. In addition, PDH is a considerable endothermic reaction, and the efficiency of this technology is strictly related to heat transfer management. Thus, this current review specifically discusses the recent advances in highly dispersed bimetallic and trimetallic catalysts proposed for the PDH reaction in both conventional-heated and microwave-heated reactors. From the point of view of catalyst development, the recent research is mainly addressed to obtain nanometric and single-atom catalysts and core–shell alloys: atomically dispersed metal atoms promote the desorption of surface-bonded propylene and inhibit its further dehydrogenation. The discussion is focused on the alternative formulations proposed in the last few years, employing active species and supports different from the classical Pt-Sn/Al₂O₃ catalyst. Concerning the conventional route of energy-supply to the catalytic bed, the advantage of using a membrane as well as fluidized bed reactors is highlighted. Recent developments in alternative microwave-assisted dehydrogenation (PDH) employing innovative catalytic systems based on silicon carbide (SiC) facilitate selective heating of the catalyst. This advancement leads to improved catalytic activity and propylene selectivity while effectively reducing coke formation. Additionally, it promotes environmental sustainability in the ongoing electrification of chemical processes. Full article