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Keywords = agro-industrial plantations

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32 pages, 1155 KiB  
Review
Using Date Palm Residues to Improve Soil Properties: The Case of Compost and Biochar
by Victor Kavvadias, Elie Le Guyader, Mohamed El Mazlouzi, Maxime Gommeaux, Belkacem Boumaraf, Mohamed Moussa, Hafouda Lamine, Mahtali Sbih, Ines Rahma Zoghlami, Kamel Guimeur, Aissa Tirichine, Abid Adelfettah, Beatrice Marin and Xavier Morvan
Soil Syst. 2024, 8(3), 69; https://doi.org/10.3390/soilsystems8030069 - 24 Jun 2024
Cited by 11 | Viewed by 6638
Abstract
Agricultural residues are generated during the production and processing of agricultural crops. Under modern date palm plantation practices, field operations generate huge quantities of residues, which are discarded with little valorization. The date palm agro-industry produces significant amounts of waste. The accumulation of [...] Read more.
Agricultural residues are generated during the production and processing of agricultural crops. Under modern date palm plantation practices, field operations generate huge quantities of residues, which are discarded with little valorization. The date palm agro-industry produces significant amounts of waste. The accumulation of these residues can cause ecological damage to the oasis ecosystems. There is a lack of comprehensive data on long-term research studies that aim to assess the impact of date palm waste management practices. Composting and/or pyrolysis of date palm residues showed benefits for improving soil physical and chemical properties, particularly in sandy soils. This claim holds particular significance for arid and semi-arid regions, which are characterized by low fertility and are susceptible to soil degradation, accentuated by ongoing climate change. This review summarizes the existing literature concerning the valorization of date palm residues with regards to compost and pyrolysis processes, as well as the impact of their application on soil quality. Further research is required to assess the effects of using date palm residues for better soil amendment management. Research should focus on composting and biochar technologies for date palm residues and their application in arid and semi-arid regions to combat soil erosion and degradation. Increasing the beneficial uses of date palm residues could lead to sustainable and economic growth in dry areas. Full article
(This article belongs to the Special Issue Soil Bioremediation)
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28 pages, 7723 KiB  
Article
Demystifying Heavy Metals and Physicochemical Characteristics of Groundwater in a Volcano-Tectonic Region of Middle Awash, Ethiopia, for Multipurpose Use
by Yosef Abebe, Taye Alemayehu, Behailu Birhanu, Tena Alamirew and Esayas Alemayehu
Sustainability 2024, 16(12), 5257; https://doi.org/10.3390/su16125257 - 20 Jun 2024
Cited by 3 | Viewed by 2180
Abstract
This study investigates the concentrations of physicochemical and heavy metal contaminants in the groundwater of the Middle Awash Basin, Ethiopia, to inform targeted water management strategies. A total of 32 groundwater samples were collected from 16 stations via piezometers and boreholes at the [...] Read more.
This study investigates the concentrations of physicochemical and heavy metal contaminants in the groundwater of the Middle Awash Basin, Ethiopia, to inform targeted water management strategies. A total of 32 groundwater samples were collected from 16 stations via piezometers and boreholes at the end of both the dry (June 2021) and wet (October 2021) seasons. Utilizing Inductively Coupled Plasma Mass Spectrometry (ICP-MS), Atomic Absorption Spectroscopy (AAS), and in situ metering, 22 physicochemical and 24 heavy metal parameters were analyzed. The data revealed significant levels of contamination; notably, sample GW11 had extraordinarily high concentrations of total dissolved solids (10,826 mg/L), strontium (908 µg/L), molybdenum (802.4 µg/L), zinc (6060 µg/L), and electrical conductivity (15,645 µS/cm), while GW12 exhibited elevated levels of aluminum (2615 µg/L), zinc (4446 µg/L), and arsenic (117.2 µg/L). Contaminants such as arsenic, vanadium, gallium, lithium, rubidium, chromium, manganese, copper, and zinc were found enriched in groundwater near Lake Beseka, majorly influenced by geogenic activities, volcanic ash, and weathering of rocks. The sampled waters might be affected by human activities including agricultural runoff from sugarcane plantations, sugar factories wastewaters, and agro-industry activities (decade’s activities). Over half of the groundwater sources were unsuitable for drinking, posing significant health risks to local communities that rely heavily on these sources due to limited access to clean surface water. The findings emphasize the urgent need for comprehensive groundwater management and remediation plans in the Middle Awash region to ensure safe and sustainable water use, particularly addressing the variation in contamination levels influenced by Lake Beseka. These measures are critical to protect public health and support local development in the face of ongoing environmental and anthropogenic pressures. Full article
(This article belongs to the Section Sustainable Water Management)
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20 pages, 4722 KiB  
Article
Water Footprint and Water Sustainability of Agroindustrial Avocado Production in a Warm Tropical Climate Municipality: A Case Study in the Michoacan Avocado Belt in Central México
by Diana J. Fuerte-Velázquez and Alberto Gómez-Tagle
Water 2024, 16(12), 1719; https://doi.org/10.3390/w16121719 - 17 Jun 2024
Cited by 1 | Viewed by 5037
Abstract
Water is a fundamental resource for ecosystems, humans, and the development of all economic sectors; it is necessary to identify and evaluate its environmental pressures and impacts. The water footprint (WF) is an appropriate indicator for the consumption of water used to produce [...] Read more.
Water is a fundamental resource for ecosystems, humans, and the development of all economic sectors; it is necessary to identify and evaluate its environmental pressures and impacts. The water footprint (WF) is an appropriate indicator for the consumption of water used to produce a product. The present study uses this tool to evaluate the green and blue water requirements and the sustainability of irrigation water use for agroindustrial avocado production in Ziracuaretiro, Michoacán (2012–2021). Our analysis was based on aggregating weather and soil data at the municipal level and official government databases of avocado cultivated surface, fruit production, and water rights concessions. The analysis considers the homogeneity of information throughout the study area. We estimated that rainfed plantations require 839.03 m3/ton, and irrigated plantations require 2355.80 m3/ton, with an average of 1597.47 m3/ton. In addition, we determined that avocado cultivation can demand up to 124.3% of agricultural water concessions in this municipality. Moreover, the WF estimates and the analysis indicate that such studies are fundamental for decision-makers to develop and implement water use efficiency strategies and shows the need for further research related to the water consumption of avocado as a crop at more detailed scales. Full article
(This article belongs to the Special Issue Studies on Water Resource and Environmental Policies)
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21 pages, 920 KiB  
Review
Potentials of Biomass Waste Valorization: Case of South America
by Sofía Sampaolesi, Laura Estefanía Briand, Mario Carlos Nazareno Saparrat and María Victoria Toledo
Sustainability 2023, 15(10), 8343; https://doi.org/10.3390/su15108343 - 21 May 2023
Cited by 13 | Viewed by 4033
Abstract
Various surveys carried out by the government and scientific projects on the availability of direct and indirect waste biomass in South America have reported that Brazil and Colombia produce 97% of the total waste biomass in the region, directly obtained from their extensive [...] Read more.
Various surveys carried out by the government and scientific projects on the availability of direct and indirect waste biomass in South America have reported that Brazil and Colombia produce 97% of the total waste biomass in the region, directly obtained from their extensive plantations of sugarcane. In addition, Argentina generates 45% of the total indirect biomass, followed by Brazil, Peru, Chile and Paraguay. The major source of those residues comprises sub-products of the wood (43%) and alimentary industries (20% from sugarcane and 11% from tea). Meaningful quantities of agricultural waste originate from soybean and corn, as the continent produces 50% and 11% of the global harvest of these crops. The higher content of cellulose in eucalyptus and willow waste (49%), among woody residues, along with their low lignin levels, makes them more suitable for delignification and exploitation as a biorefinery feedstock. Regarding the remains of agroindustrial activities, sugarcane bagasse (53%), corn cob (40%), wheat straw (49%) and banana hulls (38%) are the remarkable ones. In this context, the latest research concerning the use of commercial enzymatic cocktails for cellulose and hemicellulose deconstruction and the consequent feedstock hydrolysis is reviewed. In addition, we introduce the potential applications of cellulases isolated from native Latin American microbiota explored by South American research groups. Full article
(This article belongs to the Special Issue Recycling Biomass for Agriculture and Bioenergy Production)
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13 pages, 966 KiB  
Article
Innovative Collagen Based Biopolymers Tested as Fertilizers for Poor Soils Amendment
by Carolina Constantin, Daniela Simina Stefan, Ana-Maria Manea-Saghin and Irina Meghea
Polymers 2023, 15(9), 2085; https://doi.org/10.3390/polym15092085 - 27 Apr 2023
Cited by 3 | Viewed by 2037
Abstract
Improving soil quality is of growing interest and, among optimal solutions, the reuse and recycling of biopolymers of pelt waste from the tannery industry have been proposed, one of them being for collagen hydrolysate with micronutrients and polymers incorporated, to be used as [...] Read more.
Improving soil quality is of growing interest and, among optimal solutions, the reuse and recycling of biopolymers of pelt waste from the tannery industry have been proposed, one of them being for collagen hydrolysate with micronutrients and polymers incorporated, to be used as fertilizers for poor soils rehabilitation. As functionalization agents, polyacrylamide, starch and dolomite were included into biopolymer matrixes in order to enhance their specific efficiency. These fertilizers were adequately characterized for their physical–chemical properties, including nutrient content, and tested on three poor soils, while a fourth sample of normal soil was chosen for comparative purposes. These soils were also characterized for their texture and physical–chemical properties in order to establish the fertility state of the soils as a function of nutrient content. In this respect, a series of agrochemical tests were developed at laboratory scale, simulating real agriculture environments in a vegetation room, where a significant plant growth in height was observed for all the agro-hydrogels with nutrients encapsulated, and multiplication of the nodosities number was observed in the case of the soybean culture. The most significant effect was obtained in the case of the fertilizer functionalized with starch. Finally, the application dose of the organic fertilizers for specific culture plants was estimated, such as field cultures (cereals, corn), field vegetables, vineyards or fruit-growing plantations. These agro-collagen fertilizers are particularly recommended for amendment of field cereals and vegetables. The novelty of this study mainly consists of the recovery and recycling of the pelt waste as efficient fertilizers after their adequate functionalization with synthetic or natural biopolymers. Full article
(This article belongs to the Special Issue Environmentally Friendly Bio-Based Polymeric Materials)
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12 pages, 2866 KiB  
Article
Environmental Analysis of the Incorporation of Sugarcane Bagasse in Medium Density Particleboard Panels through Life Cycle Assessment
by Nara Cangussu, Maria Luiza C. Vieira and Lino Maia
Recycling 2023, 8(2), 44; https://doi.org/10.3390/recycling8020044 - 21 Apr 2023
Cited by 8 | Viewed by 4669
Abstract
The growth of civil construction and agroindustry, resulting from population growth, caused an increase in the demand for non-renewable resources and for the exploitation of natural resources. Consequently, it caused a greater generation of waste, causing the current scenario to require alternatives for [...] Read more.
The growth of civil construction and agroindustry, resulting from population growth, caused an increase in the demand for non-renewable resources and for the exploitation of natural resources. Consequently, it caused a greater generation of waste, causing the current scenario to require alternatives for the reuse of these materials. Particleboard panels, for example, used in civil construction, can add value to waste or materials of low acceptance, such as thinning wood, mechanical wood processing waste or agro-industrial waste. Thus, this study proposed to analyse the life cycle of the sugarcane bagasse, considering the stages of extraction of materials and energy resources until their final disposal. This study aimed to compare impacts generated by the production of particleboards panels produced with wood from plantations (pine) and with the sugarcane bagasse. As a result, a better environmental performance was obtained from the panel composed of sugarcane bagasse, as it generated lower environmental impacts in all impact categories studied. The benefits range from the reduction in waste disposed of in landfills, which increase its useful life, the lower demand for reforestation, with steps that generate atmospheric emissions and degrade the soil. Full article
(This article belongs to the Special Issue Recycling and Recovery of Biomass Materials II)
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19 pages, 2815 KiB  
Review
Production of Hydrogen from Lignocellulosic Biomass: A Review of Technologies
by Lourdes Jara-Cobos, Mónica Abril-González and Verónica Pinos-Vélez
Catalysts 2023, 13(4), 766; https://doi.org/10.3390/catal13040766 - 18 Apr 2023
Cited by 31 | Viewed by 7186
Abstract
Hydrogen is considered one of the most important forms of energy for the future, as it can be generated from renewable sources and reduce CO2 emissions. In this review, the different thermochemical techniques that are currently used for the production of hydrogen [...] Read more.
Hydrogen is considered one of the most important forms of energy for the future, as it can be generated from renewable sources and reduce CO2 emissions. In this review, the different thermochemical techniques that are currently used for the production of hydrogen from biomass from plantations or crops, as well as those from industrial or agro-industrial processes, were analyzed, such as gasification, liquefaction, and pyrolysis. In addition, the yields obtained and the reactors, reaction conditions, and catalysts used in each process are presented. Furthermore, a brief comparison between the methods is made to identify the pros and cons of current technologies. Full article
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12 pages, 2289 KiB  
Article
Mass Spectrometry-Based Investigation of Sugarcane Exposed to Five Different Pesticides
by Thalisson A. de Souza, Gabriela C. S. Rodrigues, Pedro H. N. de Souza, Lucas S. Abreu, Laiane C. O. Pereira, Marcelo S. da Silva, Josean F. Tavares, Luciana Scotti and Marcus Tullius Scotti
Life 2023, 13(4), 1034; https://doi.org/10.3390/life13041034 - 17 Apr 2023
Viewed by 2207
Abstract
The use of agrochemicals has become a standard practice worldwide to ensure the productivity and quality of sugarcane crops. This study aimed to analyze the metabolic changes in sugarcane culms treated with five different nematicides. The experimental design was randomized in blocks, and [...] Read more.
The use of agrochemicals has become a standard practice worldwide to ensure the productivity and quality of sugarcane crops. This study aimed to analyze the metabolic changes in sugarcane culms treated with five different nematicides. The experimental design was randomized in blocks, and agro-industrial and biometric variables were evaluated. The samples were extracted and then analyzed using LC–MS, LC–MS/MS, and LC–HRMS. The data obtained were submitted to statistical methods (PCA and PLS). Fragmentation patterns, retention time, and UV absorptions of the main features were analyzed. The plantations treated with carbosulfan (T4) obtained higher agricultural productivity and total recoverable sugar (TRS), while the use of benfuracarb (T3) was associated with lower growth and lower TRS. Statistical analysis revealed the contribution of the features at m/z 353 and m/z 515, assigned as chlorogenic acids, which discriminated the groups. The MS profile also supported the occurrence of flavonoids (C-glycosides and O-glycosides) in the samples. Full article
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15 pages, 2364 KiB  
Article
Landscape Fragmentation at Arauco Province in the Chilean Forestry Model Context (1976–2016)
by Edilia Jaque Castillo, Carolina G. Ojeda and Rodrigo Fuentes Robles
Land 2022, 11(11), 1992; https://doi.org/10.3390/land11111992 - 7 Nov 2022
Cited by 5 | Viewed by 2823
Abstract
Land Cover–Land Use Changes (LULCC) and landscape fragmentation have been a common research topic for Geographic Information Systems (GIS) scientists since the middle of the 20th century; particularly, they have helped to make accessible the spatial characteristics of land management through time. We [...] Read more.
Land Cover–Land Use Changes (LULCC) and landscape fragmentation have been a common research topic for Geographic Information Systems (GIS) scientists since the middle of the 20th century; particularly, they have helped to make accessible the spatial characteristics of land management through time. We researched LULCC and landscape fragmentation in Arauco Province in Chile using satellite image analysis (1976–2016) and FRAGSTAT software. This area is in a constant struggle for land use between agroindustry, urban sprawl, and the expansion of exotic plantations (pine-eucalyptus) subsidized by Chilean government. The main results are: (1) we obtained the surface percentages for each land cover , (2) net changes for each cover by adding and losing surface (ha), (3) the transition map that enlightens the surface transformations of LULCC by its four processes substitution, abandonment, habilitation, regeneration and degradation, (4) the native forest loss in the first half of the period (1976–2001) was 1.85%/year, meanwhile for the second half (2001–2016) it was 6.5%/year, (5) landscape fragmentation processes occurred in patches and deforestation is its main driver, (6) aggregation changed the landscape since fragmentation and deforestation processes started the substitution of native forest, and (7) the habilitation of agricultural lands and degradation of wooded masses with exotic species increased their aggregation to 90%. Full article
(This article belongs to the Section Landscape Ecology)
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35 pages, 15156 KiB  
Article
Weakening of Coastlines and Coastal Erosion in the Gulf of Guinea: The Case of the Kribi Coast in Cameroon
by Philippes Mbevo Fendoung, Mesmin Tchindjang and Aurélia Hubert-Ferrari
Land 2022, 11(9), 1557; https://doi.org/10.3390/land11091557 - 13 Sep 2022
Cited by 6 | Viewed by 4858
Abstract
For more than four decades, the Gulf of Guinea’s coasts have been undergoing a significant phenomenon of erosion, resulting from the pressures of both anthropogenic and marine weather forcings. From the coasts of West Africa (Senegal, Ivory Coast, Ghana, Benin, Togo, and Nigeria) [...] Read more.
For more than four decades, the Gulf of Guinea’s coasts have been undergoing a significant phenomenon of erosion, resulting from the pressures of both anthropogenic and marine weather forcings. From the coasts of West Africa (Senegal, Ivory Coast, Ghana, Benin, Togo, and Nigeria) to those of Central Africa (Gabon, Equatorial Guinea, and Cameroon), the phenomenon has been growing for more than four decades. The southern Cameroonian coastline from Kribi to Campo has become the scene of significant environmental dynamics that render it vulnerable to coastal erosion, which appears to be the major hazard of this coastal territory and causes a gradual degradation of the vegetative cover, thereby leading to the degradation of the coast’s land/ground cover and human-made infrastructure. The objective of this work is to analyze the kinematics of the Kribian coastline between 1973 and 2020; to quantify the levels of retreat, accretion, and stability; and finally, to discuss the factors influencing the evolution of the coastline. The methodological approach is based on the large-scale processing of Landsat images with a spatial resolution of 30 m. Then, small-scale processing is carried out around the autonomous port of Kribi using Pléiades and Google Earth images from the years 2013, 2018, and 2020 with a 0.5 m spatial resolution. The Digital Shoreline Analysis System (DSAS) version 5 and ArcMap 10.5® tool are used to model coastal kinematics. In addition, the dynamics of the agro-industrial plantations are assessed via satellite images and landscape perception. Environmental degradation is measured with respect to the entire Cameroonian coastline through the supervised classification of Landsat images (1986–2020). The results show that erosion is in its initial phase in Kribi because significant retreats of the coastline are noticeable over the period from 2015–2020. Thus, between 1973 and 2020, the linear data present a certain stability. In total, +72.32% of the line remained stable, with values of +1.3% for accretion and +26.33% for erosion—obtained from Landsat images of 30 m resolution—with an average retreat of +1.3 m/year and an average accretion of 0.9 m/year between 1973–2020. Based on high-resolution images, between 2013 and 2019, the average retreat of the coastline on the Kribian coast was −8.5 m/year and the average accretion was about 7 m/year. Agro-industrial plantations are responsible for environmental degradation. Thus, at SOCAPALM in Apouh, there has been a clear growth in plantations, which has fallen from 53% in 1990 to 78% in 2020, i.e., an increase of 25% of its baseline area. This is linked to the fact that plantations are growing significantly, with increases of 16% in 1990, 28% in 2000, and 29% in 2020, for old plantations. Full article
(This article belongs to the Special Issue Land Modifications and Impacts on Coastal Areas)
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18 pages, 2993 KiB  
Article
Effect of the Application of a Coating Native Potato Starch/Nopal Mucilage/Pectin on Physicochemical and Physiological Properties during Storage of Fuerte and Hass Avocado (Persea americana)
by David Choque-Quispe, Yasmine Diaz-Barrera, Aydeé M. Solano-Reynoso, Yudith Choque-Quispe, Betsy S. Ramos-Pacheco, Carlos A. Ligarda-Samanez, Diego E. Peralta-Guevara, Edgar L. Martínez-Huamán, John Peter Aguirre Landa, Odilon Correa-Cuba, Henrry W. Agreda Cerna, Mery Luz Masco-Arriola, Washington Julio Lechuga-Canal, Julio C. Loayza-Céspedes and Genaro Julio Álvarez-López
Polymers 2022, 14(16), 3421; https://doi.org/10.3390/polym14163421 - 21 Aug 2022
Cited by 9 | Viewed by 4059
Abstract
The avocado fruit is an agro-industrial product with high export demand in Peru due to its sensory and nutritional qualities, which can be affected during storage. The study aimed to evaluate the effect of the application of a coating formulated with potato starch [...] Read more.
The avocado fruit is an agro-industrial product with high export demand in Peru due to its sensory and nutritional qualities, which can be affected during storage. The study aimed to evaluate the effect of the application of a coating formulated with potato starch (Solanum tuberosum ssp andigena), nopal mucilage (Opuntia ficus indica), and pectin on the physicochemical and physiological properties during the storage of Fuerte and Hass avocados. Samples were taken in their harvest state from the plantation in “Occobamba”, which is cultivated by the Avocado Producers Association in Chincheros, Apurímac, Peru. Physicochemical properties (titratable acidity, pH, total soluble solids) and physiological properties (weight loss, firmness, and color L* a* b*) were determined during 20 days of storage at 20 °C. The elaborated films present high transparency and low aw values. In the coated avocado of the Hass and Fuerte varieties, acidity and total soluble solids decreased significantly (p-value < 0.05) during the storage time. Weight loss and firmness of coated fruits decrease to a lesser extent. Luminosity L*, color index, and color variation showed better attributes for the coated samples. The use of coatings made with potato starch, nopal mucilage, and pectin allows the physicochemical and physiological properties of avocado fruits to be maintained for a longer time during storage. Full article
(This article belongs to the Special Issue Smart Natural-Based Polymers)
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20 pages, 3214 KiB  
Article
Blue and Green Water Footprint of Agro-Industrial Avocado Production in Central Mexico
by Alberto F. Gómez-Tagle, Alberto Gómez-Tagle, Diana J. Fuerte-Velázquez, Alma G. Barajas-Alcalá, Fernando Quiroz-Rivera, Pablo E. Alarcón-Chaires and Hilda Guerrero-García-Rojas
Sustainability 2022, 14(15), 9664; https://doi.org/10.3390/su14159664 - 5 Aug 2022
Cited by 13 | Viewed by 9164
Abstract
Mexico is the world-leading avocado producer. The municipality of Uruapan in the Avocado Belt region in Central Mexico produces 153,000 tons a year, nearly 6.4% of Mexico’s total volume. We performed a green and blue water footprint (WF) analysis between 2012 to 2017 [...] Read more.
Mexico is the world-leading avocado producer. The municipality of Uruapan in the Avocado Belt region in Central Mexico produces 153,000 tons a year, nearly 6.4% of Mexico’s total volume. We performed a green and blue water footprint (WF) analysis between 2012 to 2017 in this municipality, and compared the estimated WF volumes with water concessions for agriculture. Mean annual rainfall was 1757.0 mm in the study period, mean effective rainfall 877.2 mm, mean crop evapotranspiration 933.1 mm, and 312.5 mm of mean irrigation requirement. The mean WFtotal was 744.3 m3 ton−1, below the global mean WF for this crop (1086 m3 ton−1). WFtotal was 2.5 times higher in irrigated plantations (1071.4 m3 ton⁻1) than in rainfed plantations (417.1 m3 ton−1). The crop yield was slightly higher (3.8%) under irrigated (10.26 ton ha−1 year−1) than in rainfed plantations (9.88 ton ha−1 year−1). WF and its components varied between years. The lowest WFblue was in 2015 when atypical spring rainfall increased available water during the dry season. The irrigation of avocado plantations doubles water use with a slight yield increase in relation to rainfed plantations. Regarding WF volumes and water concessions, we found that agroindustrial avocado production consumes up to 120% of the surface and groundwater volumes granted to agriculture use in years with dry conditions. The results indicate that other water users are depleted of this resource, creating water stress and scarcity, and leading to water rights conflicts and social discomfort. Full article
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18 pages, 4304 KiB  
Article
Fungal Extracellular Lipases from Coffee Plantation Environments for the Sustainable Management of Agro-Industrial Coffee Biomass
by Randall Syedd-León, Frank Solano-Campos, Jorge Campos-Rodríguez, Daniela Pereira-Arce, Luis Roberto Villegas-Peñaranda and Manuel Sandoval-Barrantes
Biomass 2022, 2(2), 62-79; https://doi.org/10.3390/biomass2020005 - 22 Mar 2022
Cited by 1 | Viewed by 3886
Abstract
Coffee wastes have large amounts of by-products rich in phenolic compounds such as chlorogenic and caffeic acid, with potential applications for developing fine chemicals such as caffeic acid phenethyl ester (CAPE). A screening for microorganisms was undertaken in a coffee plantation environment to [...] Read more.
Coffee wastes have large amounts of by-products rich in phenolic compounds such as chlorogenic and caffeic acid, with potential applications for developing fine chemicals such as caffeic acid phenethyl ester (CAPE). A screening for microorganisms was undertaken in a coffee plantation environment to isolate native tropical species able to modify secondary metabolites present in this kind of biomass enzymatically. From the screening, 130 fungal strains could grow in lipase inducer media. Fungal strains were identified via ITS-based sequencing. Classification based on BLAST assigned 51 isolates to 12 different genera, including Absidia, Aspergillus, Cunninghamella, Fusarium, Metarhizium, Meyerozyma, Mucor, Neocosmospora, Papiliotrema, Penicillium, Rhizopus, and Trichoderma. DNA sequencing identified 14 putative extracellular lipases. According to the extracellular lipase activity, the most promising strain was identified as Fusarium sp. by DNA barcoding. Extracellular lipases from this strain exhibited maximal hydrolytic activity at a temperature of 45 °C, a pH of 7.00, and 200 ppm of NaCl, with an affinity towards substrates having carbon chain lengths of 8 or longer. Under these conditions, lipase instead of esterase activity is the main feature. The Km and Vmax values calculated using p-nitrophenyl palmitate (pNPP) as hydrolysis substrate were 0.003 mM and 299.8 μmol min−1 mg−1, respectively. Fusarium sp. lipases presented high stability during freeze–thawing, allowing the storage of enzyme solutions at −20 °C, but not as a lyophilized powder. According to our kinetic study, these lipases catalyzed CAPE hydrolysis, showing a progressive decrease in the concentration of the CAPE and a correspondent increase in the caffeic acid concentration as a product of this hydrolysis. Being able to carry out this type of reaction under mild conditions shows that Fusarium sp. lipases recognize CAPE as substrate and suggest CAPE synthesis (reverse reaction) and transformation can be engineered, using caffeic acid from coffee biomass, as a potential industrial application for these lipases. Full article
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23 pages, 2155 KiB  
Article
Estimation of Aboveground Oil Palm Biomass in a Mature Plantation in the Congo Basin
by Pierre Migolet, Kalifa Goïta, Alfred Ngomanda and Andréana Paola Mekui Biyogo
Forests 2020, 11(5), 544; https://doi.org/10.3390/f11050544 - 12 May 2020
Cited by 11 | Viewed by 4837
Abstract
Agro-industrial oil palm plantations are becoming increasingly established in the Congo Basin (West Equatorial Africa) for mainly economic reasons. Knowledge of oil palm capacity to sequester carbon requires biomass estimates. This study implemented local and regional methods for estimating palm biomass in a [...] Read more.
Agro-industrial oil palm plantations are becoming increasingly established in the Congo Basin (West Equatorial Africa) for mainly economic reasons. Knowledge of oil palm capacity to sequester carbon requires biomass estimates. This study implemented local and regional methods for estimating palm biomass in a mature plantation, using destructive sampling. Eighteen 35-year-old oil palms with breast height diameters (DBH) between 48 and 58 cm were felled and sectioned in a plantation located in Makouké, central Gabon. Field and laboratory measurements determined the biomasses of different tree compartments (fruits, leaflets, petioles, rachises, stems). Fruits and leaflets contributed an average of 6% to total aboveground palm biomass, which petioles accounted for 8%, rachises for 13% and the stem, 73%. The best allometric equation for estimating stem biomass was obtained with a composite variable, formulated as DBH2 × stem height, weighted by tissue infra-density. For leaf biomass (fruits + leaflets + petioles + rachises), the equation was of a similar form, but included the leaf number instead of infra-density. The allometric model combining the stem and leaf biomass yielded the best estimates of the total aboveground oil palm biomass (coefficient of determination (r2) = 0.972, p < 0.0001, relative root mean square error (RMSE) = 5%). Yet, the model was difficult to implement in practice, given the limited availability of variables such as the leaf number. The total aboveground biomass could be estimated with comparable results using DBH2 × stem height, weighted by the infra-density (r2 = 0.961, p < 0.0001, relative RMSE (%RMSE) = 5.7%). A simpler model excluding infra-density did not severely compromise results (R2 = 0.939, p < 0.0003, %RMSE = 8.2%). We also examined existing allometric models, established elsewhere in the world, for estimating aboveground oil palm biomass in our study area. These models exhibited performances inferior to the best local allometric equations that were developed. Full article
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23 pages, 6806 KiB  
Article
Sustainable Thermal Energy Generation at Universities by Using Loquat Seeds as Biofuel
by Miguel-Angel Perea-Moreno, Francisco Manzano-Agugliaro, Quetzalcoatl Hernandez-Escobedo and Alberto-Jesus Perea-Moreno
Sustainability 2020, 12(5), 2093; https://doi.org/10.3390/su12052093 - 9 Mar 2020
Cited by 13 | Viewed by 4475
Abstract
Global energy consumption has increased the emission of greenhouse gases (GHG), these being the main cause of global warming. Within renewable energies, bioenergy has undergone a great development in recent years. This is due to its carbon neutral balance and the fact that [...] Read more.
Global energy consumption has increased the emission of greenhouse gases (GHG), these being the main cause of global warming. Within renewable energies, bioenergy has undergone a great development in recent years. This is due to its carbon neutral balance and the fact that bioenergy can be obtained from a range of biomass resources, including residues from forestry, agricultural or livestock industries, the rapid rotation of forest plantations, the development of energy crops, organic matter from urban solid waste, and other sources of organic waste from agro-food industries. Processing factories that use loquats to make products such as liqueurs and jams generate large amounts of waste mainly in the form of skin and stones or seeds. These wastes are disposed of and sent to landfills without making environmentally sustainable use of them. The University of Almeria Sports Centre is made up of indoor spaces in which different sports can be practiced: sports centre pavilion (central court and two lateral courts), rocodrome, fitness room, cycle inner room, and indoor swimming pool. At present, the indoor swimming pool of the University of Almeria (UAL) has two fuel oil boilers, with a nominal power of 267 kW. The main objective of this study is to propose an energetic analysis to determine, on the one hand, the energetic properties of the loquat seed and, on the other hand, to evaluate its suitability to be used as a solid biofuel to feed the boilers of the heated swimming pool of the University of Almeria (Spain), highlighting the significant energy and environmental savings obtained. Results show that the higher calorific value of loquat seed (17.205 MJ/kg), is like other industrial wastes such as wheat straw, or pistachio shell, which demonstrates the energy potential of this residual biomass. In addition, the change of the fuel oil boiler to a biomass (loquat seed) boiler in the UAL’s indoor swimming pool means a reduction of 147,973.8 kg of CO2 in emissions into the atmosphere and an annual saving of 35,739.5 €, which means a saving of 72.78% with respect to the previous fuel oil installation. A sensitivity analysis shows that fuel cost of base case is the variable with the most sensitivity changing the initial cost and net present value (NPV). Full article
(This article belongs to the Special Issue Environmental Energy Sustainability at Universities)
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