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Keywords = additive polymers to concrete

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22 pages, 2478 KB  
Article
The Influence of Synthetic Reinforcing Fibers on Selected Properties of Asphalt Mixtures for Surface and Binder Layers
by Peter Gallo, Amira Ben Ameur and Jan Valentin
Infrastructures 2025, 10(11), 303; https://doi.org/10.3390/infrastructures10110303 - 11 Nov 2025
Abstract
Increasing traffic volumes, heavier axle loads, and the growing frequency of premature pavement distress pose major challenges for modern road infrastructure. In many regions, asphalt pavements experience early rutting, cracking, and moisture-induced damage, underscoring the need for improved material performance and longer service [...] Read more.
Increasing traffic volumes, heavier axle loads, and the growing frequency of premature pavement distress pose major challenges for modern road infrastructure. In many regions, asphalt pavements experience early rutting, cracking, and moisture-induced damage, underscoring the need for improved material performance and longer service life. Reinforcing fibres are increasingly used to enhance asphalt mixture properties, with aramid fibres recognised for their superior mechanical and thermal stability. This study evaluates the effect of FlexForce (FF) fibres on the mechanical and fracture behaviour of two dense-graded asphalt concretes, AC 16 surf and AC 16 bin, produced with different binders and fibre dosages (0.02% and 0.04% by mixture weight). Laboratory tests, including indirect tensile strength ratio (ITSR), indirect tensile stiffness modulus (IT-CY), crack propagation resistance, and dynamic modulus measurements, were performed to assess moisture susceptibility, stiffness, and viscoelastic behaviour. The results showed that fibre addition had little effect on compactability and stiffness under standard conditions but improved temperature stability and stiffness at elevated temperatures, particularly when used with polymer-modified binders. Moisture resistance decreased slightly, while fracture performance improved moderately at intermediate temperatures. Overall, low fibre dosages (~0.02%) provided the most balanced performance, indicating that the mechanical benefits of aramid reinforcement depend strongly on binder rheology, temperature, and interfacial compatibility. These findings contribute to optimising fibre dosage and binder selection for aramid-reinforced asphalt layers in practice. Full article
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28 pages, 5092 KB  
Article
Hybrid Flexural Strengthening Technique of Reinforced Concrete Beams Using Fe-SMA and CFRP Materials
by Mohammadsina Sharifi Ghalehnoei, Ahad Javanmardi, Maria Rashidi and Andreas Lampropoulos
Buildings 2025, 15(22), 4039; https://doi.org/10.3390/buildings15224039 - 10 Nov 2025
Viewed by 27
Abstract
This study proposes a hybrid flexural strengthening technique for reinforced concrete (RC) beams by combining the near-surface mounted (NSM) and externally bonded reinforcement (EBR) methods. In this technique, iron-based shape memory alloy (Fe-SMA) strips are used for the NSM component, while either a [...] Read more.
This study proposes a hybrid flexural strengthening technique for reinforced concrete (RC) beams by combining the near-surface mounted (NSM) and externally bonded reinforcement (EBR) methods. In this technique, iron-based shape memory alloy (Fe-SMA) strips are used for the NSM component, while either a carbon fiber reinforced polymer (CFRP) sheet or an Fe-SMA sheet is applied as the EBR component. The proposed hybrid-strengthening method aims to enhance the flexural load capacity and ductility of existing RC beams. To evaluate the effectiveness of the proposed method, numerical models were developed using ABAQUS software and validated against experimental results. A comprehensive numerical investigation was carried out on 52 RC beams, categorized into six groups with various hybrid-strengthening configurations. In addition, the effect of the prestressing of NSM Fe-SMA strips and the prestressing of EBR CFRP or EBR Fe-SMA sheet on the flexural performance of the beams was also examined. The results indicated that the hybrid-strengthening method significantly improved the cracking, yielding, and ultimate load capacities of the beams; however, in most cases, it reduced their deflection. Notably, prestressing the EBR Fe-SMA sheet in beams with higher reinforcement ratios produced a pronounced improvement in ductility. Full article
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23 pages, 8298 KB  
Article
Effect of Freeze–Thaw Cycles on Bond Properties at the FRP-Concrete Interface: Experimental Evaluation and Machine Learning Prediction
by Wei Liang, Shiying Liu, Haoran Liu, Guang Yang and Yongming Gao
Buildings 2025, 15(22), 4038; https://doi.org/10.3390/buildings15224038 - 9 Nov 2025
Viewed by 168
Abstract
Fiber-reinforced polymer (FRP)–concrete bonding is widely adopted for structural strengthening, yet its durability is highly vulnerable to freeze–thaw (FT) degradation. This study combines experimental testing with interpretable machine learning (ML) to reveal the degradation mechanism and predict the interfacial behavior of FRP–concrete systems [...] Read more.
Fiber-reinforced polymer (FRP)–concrete bonding is widely adopted for structural strengthening, yet its durability is highly vulnerable to freeze–thaw (FT) degradation. This study combines experimental testing with interpretable machine learning (ML) to reveal the degradation mechanism and predict the interfacial behavior of FRP–concrete systems under FT exposure. Single-lap shear tests showed that all specimens failed through interfacial debonding accompanied by partial concrete peeling. The ultimate bond strength decreased by 6.0–18.5%, and the peak shear stress dropped by 53–80%, indicating a pronounced loss of ductility and adhesion. To extend the analysis, experimental data were integrated with literature datasets, and three ensemble ML algorithms—AdaBoost, Random Forest (RF), and Extreme Gradient Boosting (XGBoost)—were employed to predict key bond–slip parameters including ultimate bond strength, local maximum bond stress, slip values, and interfacial fracture energy. Among them, XGBoost achieved the highest predictive accuracy, with R2 values exceeding 0.94 for most output parameters and consistently low RMSE values. Shapley Additive exPlanations (SHAP) and Partial Dependence Plots (PDPs) further identified adhesive tensile strength, fiber modulus, FRP thickness, and concrete strength as dominant factors and defined their optimal ranges. The findings offer a scientific foundation for evaluating and predicting the long-term bond durability of FRP–concrete systems and support the development of reliable reinforcement strategies for infrastructure in cold and severe environments. Full article
(This article belongs to the Special Issue The Greening of the Reinforced Concrete Industry)
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23 pages, 6706 KB  
Article
Mechanical and Microstructural Evaluation of Compacted Mixtures of Tropical Soils with Expanded Polystyrene (EPS) Waste for Sustainable Construction Applications
by Gian Fonseca dos Santos, Heraldo Nunes Pitanga, Klaus Henrique de Paula Rodrigues, Gustavo Henrique Nalon and Taciano Oliveira da Silva
Buildings 2025, 15(22), 4037; https://doi.org/10.3390/buildings15224037 - 9 Nov 2025
Viewed by 151
Abstract
Expanded polystyrene (EPS), a lightweight thermoplastic polymer widely used in packaging and insulation, has become a growing environmental concern due to its non-biodegradable nature and escalating global consumption. Although EPS waste shows potential in construction applications, previous studies have primarily incorporated it into [...] Read more.
Expanded polystyrene (EPS), a lightweight thermoplastic polymer widely used in packaging and insulation, has become a growing environmental concern due to its non-biodegradable nature and escalating global consumption. Although EPS waste shows potential in construction applications, previous studies have primarily incorporated it into mortars, concrete, or soil–cement mixtures, often relying on the addition of cement to improve its mechanical performance. This approach compromises sustainability and has generally overlooked the role of microstructural interactions in the behavior of soil–EPS waste mixes without cement. This study differs from prior works by exploring the mechanical and microstructural properties of soil–EPS waste mixtures without cementitious binders under different compaction energies. Experimental tests were carried out for the technical characterization of soils, ground EPS waste, and mixtures of soil and different contents of EPS waste (0%, 20%, 30%, and 40% of the total apparent volume of the composite), using different compaction energies (Intermediate and Modified Proctor). The mixtures were subjected to Unconfined Compressive Strength (UCS), California Bearing Ratio (CBR), and direct shear strength tests, in addition to physical and microstructural characterization. The results indicated that both soil type and compaction energy influenced the engineering behavior of the mixtures. The clayey soil exhibited superior mechanical performance, while the sandy soil showed reductions in all mechanical properties. The UCS values of the clayey soil with the addition of EPS did not change significantly (297 kPa to 286 kPa at intermediate energy and 514 kPa to 505 kPa at modified energy), while for the sandy soil, there was a decrease in values (from 167 kPa to 46 kPa at intermediate energy and from 291 kPa to 104 kPa at modified energy). In the CBR tests, only the 20% and 30% addition of EPS to the clayey soil, using the Modified Proctor energy, showed an increase (from 18% to 20% for both percentages). This behavior was primarily attributed to adhesion mechanisms at the soil–EPS waste interface, with friction playing a secondary role, thereby suggesting that clayey soils may offer better mechanical response. The lower dry density of these mixtures compared to compacted natural soils presents a technical benefit for use as backfill in areas with low bearing capacity, where minimizing the load from the fill material is critical. Full article
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20 pages, 3539 KB  
Article
Investigating the Static and Dynamic Mechanical Properties of Fiber-Reinforced Concrete Incorporating Recycled Carbon Fiber and Modified Basic Oxygen Furnace Slag Aggregate
by Yeou-Fong Li, Hung-Sheng Lin, Jin-Yuan Syu, Wei-Hao Lee, Chih-Hong Huang, Ying-Kuan Tsai and Asia Shvarzman
Recycling 2025, 10(6), 206; https://doi.org/10.3390/recycling10060206 - 6 Nov 2025
Viewed by 196
Abstract
This study explores the mechanical behavior of concrete reinforced with recycled carbon fiber (RCF) and incorporating modified basic oxygen furnace slag (MBOF) as a sustainable aggregate. The RCF was recovered from waste carbon fiber-reinforced polymer (CFRP) bicycle rims via microwave-assisted pyrolysis (MAP), while [...] Read more.
This study explores the mechanical behavior of concrete reinforced with recycled carbon fiber (RCF) and incorporating modified basic oxygen furnace slag (MBOF) as a sustainable aggregate. The RCF was recovered from waste carbon fiber-reinforced polymer (CFRP) bicycle rims via microwave-assisted pyrolysis (MAP), while MBOF was produced by water-based treatment of hot BOF slag. The experimental program included compressive, splitting tensile, and flexural strength tests, as well as impact resistance and stress-reversal Split Hopkinson Pressure Bar (SRSHPB) tests. The effects of RCF length (6 mm and 12 mm) on the mechanical performance of MBOF-based concrete were systematically examined. The results demonstrated that incorporating MBOF as aggregate, combined with the addition of RCF, significantly enhanced both static strength and dynamic impact resistance. Compared with fiber-free MBOF concrete, the incorporation of 6 mm and 12 mm RCF increased compressive strength by 3.03% and 13.77%, flexural strength by 14.50% and 19.74%, and splitting tensile strength by 2.60% and 25.84%, respectively. Similarly, the impact number increased by approximately 6.81 and 12.67 times for the 6 mm and 12 mm RCF specimens, respectively, relative to the fiber-free specimen. Furthermore, the SRSHPB test results indicated that MBOF concrete reinforced with 12 mm RCF exhibited greater dynamic compressive strength than that reinforced with 6 mm RCF. Overall, MBOF concrete incorporating 12 mm RCF demonstrated superior performance to its 6 mm counterpart across all evaluated strength parameters. These findings highlight the potential of utilizing metallurgical and composite waste to develop high-performance, sustainable concrete materials. Full article
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30 pages, 13805 KB  
Article
Structure–Property Relationships of Polymer-Modified Cement Concrete (PCC) Under Service Temperature Conditions
by Alexander Flohr, Savitha Devarajamohalla Narayana, Luise Göbel and Andrea Osburg
Materials 2025, 18(21), 5043; https://doi.org/10.3390/ma18215043 - 5 Nov 2025
Viewed by 304
Abstract
Polymer modification is a widely employed technique for optimizing specific properties of mortars and concretes. This process entails the precise tailoring of the binder phase to the requirements of the given application. The polymer addition exerts a significant influence on both the fresh [...] Read more.
Polymer modification is a widely employed technique for optimizing specific properties of mortars and concretes. This process entails the precise tailoring of the binder phase to the requirements of the given application. The polymer addition exerts a significant influence on both the fresh and hardened states of mortar or concrete. In this study, a systematic, stepwise experimental campaign was carried out to investigate the effects of three different polymer dispersions on the time-dependent properties of cement pastes, mortars, and concretes at different temperatures in the service temperature range. The experimental findings demonstrate that polymer modifications significantly influence the behavior of hardened cement-based materials. In general, the strength and deformation resistance decreased with increasing temperature, with this effect being more pronounced in polymer-modified materials. This is indicative of the intrinsic temperature-dependent behavior of the polymers. Temperatures of −20 °C induced specific alterations in the mechanical behavior, particularly evident in the flexural strength and in the early age stiffness development of the pastes, mortars, and concretes. This phenomenon is attributed to the freezing of pore water, which results in the stiffening of the binder structure. In summary, the findings offer significant insights into the structure–property relationships of polymer-modified cement-based materials in relation to temperature. Full article
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20 pages, 8731 KB  
Article
Connecting with the Past: Filament Development and 3D Printing from Historical Wood Waste
by Aljona Gineiko
Sustainability 2025, 17(21), 9402; https://doi.org/10.3390/su17219402 - 22 Oct 2025
Viewed by 408
Abstract
Waste prevention is at the top of the EU Waste Framework directive hierarchy. With this in mind, this article considers the application of novel technologies in the Cultural Heritage Restoration and Conservation field through environmental and circular economy principles. While previous research has [...] Read more.
Waste prevention is at the top of the EU Waste Framework directive hierarchy. With this in mind, this article considers the application of novel technologies in the Cultural Heritage Restoration and Conservation field through environmental and circular economy principles. While previous research has explored the use of wood waste for composite materials such as building insulation and concrete additives, the suitability of degraded historical wood waste for filament production and 3D printing has not yet been addressed. This article contributes to this topic by studying the PLA/wood composite, material composed of a polylactic acid (PLA) polymer matrix reinforced with wood particles, produced from degraded historical construction materials. The paper describes the process of producing filament from bio- and moisture-damaged pine beam and oak parquet, followed by the 3D printing of historical platband replica. Research methods include photogrammetry, filament machine construction, filament production and 3D printing. The machines settings used in the process: heater temperatures were set to 140 °C, 90 °C and 105 °C; servo speed was 33 s; spool tension was 12.5; winding speed was 24 RPM; and screw speed was 9.2 RPM. For material preparation, a mixture containing 25% pine and oak sawdust and PLA dust was processed to achieve particle sizes of 312 μm, 471 μm, and 432 μm, respectively. Filament production was carried out with diameters of 2.85 mm for the pine/PLA composite and 1.75 mm for the oak/PLA composite. Finally, replica samples were fabricated using 3D printing. The dual objective of this research was to develop the method of 3D printing from degraded historical materials and introduce it to restoration practice as a wood waste minimization technique. Perspectives for further study include the testing of 3D-printed construction materials in outdoor conditions, and pellet production to achieve a higher wood content, compared to the filament thread. The processes described are adaptable to a variety of materials and disciplines. Full article
(This article belongs to the Special Issue Advances in Research on Sustainable Waste Treatment and Technology)
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15 pages, 2550 KB  
Article
Investigation of the Effects of Polymer-Based Grinding Aids on the Surface Chemistry Properties of Cement
by Kenan Çinku, Ebru Dengiz Özcan, Şenel Özdamar and Hasan Ergin
Polymers 2025, 17(19), 2691; https://doi.org/10.3390/polym17192691 - 4 Oct 2025
Viewed by 601
Abstract
Polymer-based superplasticizers represent an emerging class of additives in cement and concrete production with demonstrated effects on zeta potential, ion exchange, turbidity and rheological behavior during hydration. This study examines the influence of polymer-based grinding aids focusing on the dosage of A2 on [...] Read more.
Polymer-based superplasticizers represent an emerging class of additives in cement and concrete production with demonstrated effects on zeta potential, ion exchange, turbidity and rheological behavior during hydration. This study examines the influence of polymer-based grinding aids focusing on the dosage of A2 on the grinding performance of Portland cement. Among the tested additives, A2 exhibited superior dispersing ability and agglomeration-preventing activity, yielding a zeta potential of −8.98 mV. Correspondingly, the release of the ion concentration of Ca2+ decreased to 190 mg/L, while SO42− increased to 400 mg/L, indicating enhanced ionic interaction at the optimal A2 dosage of 2.5 g. The turbidity tests further revealed that cement samples ground with 2.5 g of A2 remained homogeneously suspended for longer periods compared to other additives. Overall, the analysis of cement surface properties confirmed that polymer-based grinding aids, particularly A2, significantly improve the dispersion stability of cement particles during grinding. Full article
(This article belongs to the Special Issue Advanced Polymer Materials: Synthesis, Structure, and Properties)
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13 pages, 1556 KB  
Article
Prediction of Plate End Debonding of FRP-Strengthened RC Beams Based on Explainable Machine Learning
by Sheng Zheng and Woubishet Zewdu Taffese
Buildings 2025, 15(19), 3576; https://doi.org/10.3390/buildings15193576 - 4 Oct 2025
Viewed by 488
Abstract
This research explores the phenomenon of plate-end (PE) debonding in reinforced concrete (RC) beams strengthened with fiber-reinforced polymer (FRP) composites. This type of failure represents a key mechanism that undermines the structural performance and efficiency of FRP reinforcement systems. Despite the widespread use [...] Read more.
This research explores the phenomenon of plate-end (PE) debonding in reinforced concrete (RC) beams strengthened with fiber-reinforced polymer (FRP) composites. This type of failure represents a key mechanism that undermines the structural performance and efficiency of FRP reinforcement systems. Despite the widespread use of FRP in structural repair due to its high strength and corrosion resistance, PE debonding—often triggered by shear or inclined cracks—remains a major challenge. Traditional computational models for predicting PE debonding suffer from low accuracy due to the nonlinear relationship between influencing parameters. To address this, the research employs machine learning techniques and SHapley Additive exPlanations (SHAP), to develop more accurate and explainable predictive models. A comprehensive database is constructed using key parameters affecting PE debonding. Machine learning algorithms are trained and evaluated, and their performance is compared with existing normative models. The study also includes parameter importance and sensitivity analyses to enhance model interpretability and guide future design practices in FRP-based structural reinforcement. Full article
(This article belongs to the Special Issue AI-Powered Structural Health Monitoring: Innovations and Applications)
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29 pages, 618 KB  
Review
End-of-Life Strategies for Wind Turbines: Blade Recycling, Second-Life Applications, and Circular Economy Integration
by Natalia Cieślewicz, Krzysztof Pilarski and Agnieszka A. Pilarska
Energies 2025, 18(19), 5182; https://doi.org/10.3390/en18195182 - 29 Sep 2025
Viewed by 1750
Abstract
Wind power is integral to the transformation of energy systems towards sustainability. However, the increasing number of wind turbines approaching the end of their service life presents significant challenges in terms of waste management and environmental sustainability. Rotor blades, typically composed of thermoset [...] Read more.
Wind power is integral to the transformation of energy systems towards sustainability. However, the increasing number of wind turbines approaching the end of their service life presents significant challenges in terms of waste management and environmental sustainability. Rotor blades, typically composed of thermoset polymer composites reinforced with glass or carbon fibres, are particularly problematic due to their low recyclability and complex material structure. The aim of this article is to provide a system-level review of current end-of-life strategies for wind turbine components, with particular emphasis on blade recycling and decision-oriented comparison, and its integration into circular economy frameworks. The paper explores three main pathways: operational life extension through predictive maintenance and design optimisation; upcycling and second-life applications; and advanced recycling techniques, including mechanical, thermal, and chemical methods, and reports qualitative/quantitative indicators together with an indicative Technology Readiness Level (TRL). Recent innovations, such as solvolysis, microwave-assisted pyrolysis, and supercritical fluid treatment, offer promising recovery rates but face technological and economic as well as environmental compliance limitations. In parallel, the review considers deployment maturity and economics, including an indicative mapping of cost and deployment status to support decision-making. Simultaneously, reuse applications in the construction and infrastructure sectors—such as concrete additives or repurposed structural elements—demonstrate viable low-energy alternatives to full material recovery, although regulatory barriers remain. The study also highlights the importance of systemic approaches, including Extended Producer Responsibility (EPR), Digital Product Passports and EU-aligned policy/finance instruments, and cross-sectoral collaboration. These instruments are essential for enhancing material traceability and fostering industrial symbiosis. In conclusion, there is no universal solution for wind turbine blade recycling. Effective integration of circular principles will require tailored strategies, interdisciplinary research, and bankable policy support. Addressing these challenges is crucial for minimising the environmental footprint of the wind energy sector. Full article
(This article belongs to the Collection Feature Papers in Energy, Environment and Well-Being)
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18 pages, 4165 KB  
Article
Mechanical and Thermal Characteristics of Cement Composites Containing PEDOT:PSS and Amorphous Metallic Fibers
by Se-Jin Choi, Jeong-Yeon Park, Min-Jeong Kim and Jae-In Lee
Materials 2025, 18(19), 4486; https://doi.org/10.3390/ma18194486 - 26 Sep 2025
Viewed by 481
Abstract
Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a conductive polymer that has attracted significant attention in various industries. However, studies on the application of PEDOT:PSS in cement composites are scarce. The thermal performance and mechanical properties of conductive cement composites manufactured using amorphous metallic fibers (AFs), reinforcing [...] Read more.
Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a conductive polymer that has attracted significant attention in various industries. However, studies on the application of PEDOT:PSS in cement composites are scarce. The thermal performance and mechanical properties of conductive cement composites manufactured using amorphous metallic fibers (AFs), reinforcing fibers with excellent conductivity in concrete, and the conductive polymer PEDOT:PSS in various ratios are investigated in this study. When only PEDOT:PSS and a combination of AFs and PEDOT:PSS are used, the splitting tensile strength of the composite at 28 d increases by 15.4% and 38.5%, respectively, compared with that of the plain sample (without PEDOT:PSS and AFs). Additionally, the simultaneous incorporation of PEDOT:PSS and AFs significantly reduces the brittleness of cement composites. The heat-generation performance shows minimal changes when only PEDOT:PSS is used; however, when 0.6% PEDOT:PSS and AFs are used together, a temperature increase rate of 182% is observed, which is 138% better than that of the plain sample. In scanning electron microscopy–energy-dispersive X-ray spectroscopy analysis, spherical hydrates, likely comprising PEDOT, are observed in samples incorporated with only PEDOT:PSS; samples incorporated with PEDOT:PSS and AFs show hydrates with a clearer shape than those observed in the plain sample. This study is expected to open new frontiers in the design and development of high-performance additive-incorporated cement composites with unique properties for specific applications. Full article
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27 pages, 10062 KB  
Article
Performance Evolution of CFRP Strip Anodes in Concrete: An Integrated Electrochemical and Mechanical Study
by Xuan Wu, Yichen Jia, Yingwu Zhou, Chengcheng Xue, Biao Hu, Yinghou He and Xiaoxu Huang
Polymers 2025, 17(18), 2494; https://doi.org/10.3390/polym17182494 - 16 Sep 2025
Viewed by 536
Abstract
Impressed current cathodic protection (ICCP) is one of the most effective techniques in preventing steel corrosion in concrete structures. Based on the exceptional electrical conductivity and mechanical properties of carbon fiber reinforced polymers (CFRP), a novel structural system employing ICCP is proposed in [...] Read more.
Impressed current cathodic protection (ICCP) is one of the most effective techniques in preventing steel corrosion in concrete structures. Based on the exceptional electrical conductivity and mechanical properties of carbon fiber reinforced polymers (CFRP), a novel structural system employing ICCP is proposed in this paper, in which CFRP strips are used as both concrete stirrups and as an auxiliary anode for cathodic protection. To further verify the dual functions of CFRP strips for this new system, the electrochemical and mechanical behaviors of the CFRP strip anode are investigated experimentally in this study through the anodic polarization test, electrochemical impedance spectroscopy test, uniaxial tensile test, and interfacial acidification test. The effects of concrete type and anode current density on the properties of CFRP strip anodes are identified. The results show that the CFRP strip anode possesses satisfactory electrical conductivity and relatively low output resistance, and the ultimate strength of the CFRP strip after polarization is reduced as the current density increases due to the gradual degradation of the CFRP anode. The mechanical properties of CFRP strips in Engineered Cementitious Cement (ECC) concrete and geopolymer concrete outperform those of ordinary concrete, and the degradation rate of CFRP strips subjected to anodic polarization in ECC concrete is lower than that of geopolymer concrete. The cathodic protection mechanism of CFRP strips as an anode is further revealed via numerical analysis. In addition, the prediction model of the service life is constructed for the proposed novel concrete structural system. The predicted service life of the system decreases as the reinforcement ratio increases, and it increases as the stirrup ratio increases. The predicted service life of the ICCP system in ECC concrete is significantly longer than that in geopolymer concrete and ordinary concrete. Full article
(This article belongs to the Section Polymer Fibers)
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22 pages, 2535 KB  
Article
From Recycled Polyethylene Terephthalate Waste to High-Value Chemicals and Materials: A Zero-Waste Technology Approach
by Maciej Kapkowski, Sonia Kotowicz, Karina Kocot, Mateusz Korzec, Jerzy Kubacki, Maciej Zubko, Krzysztof Aniołek, Urszula Siudyga, Tomasz Siudyga and Jaroslaw Polanski
Energies 2025, 18(16), 4375; https://doi.org/10.3390/en18164375 - 17 Aug 2025
Viewed by 1072
Abstract
The presence of PET (polyethylene terephthalate) in the environment is a global problem due to soil and water microplastic contamination. There is a constant demand for new technologies that expand the possibilities of PET disposal or recycling while reducing energy consumption and anthropogenic [...] Read more.
The presence of PET (polyethylene terephthalate) in the environment is a global problem due to soil and water microplastic contamination. There is a constant demand for new technologies that expand the possibilities of PET disposal or recycling while reducing energy consumption and anthropogenic carbon footprint. In this study, we developed a comprehensive zero-waste management system for PET recycling (rPET) to cyclic ketals and terephthalic acid. The developed method is based on the hydrolysis of rPET flakes in an inert environment with the separation and purification of terephthalic acid and the dehydration of ethylene glycol. For the first time, we present the use of cheap and readily available Cr/SiO2 and Fe/SiO2 nanocatalysts for direct acetalization of ethylene glycol without organic co-solvents. The catalysts were characterized by EDXRF, XPS and TEM techniques. The 2,2-dimethyl-1,3-dioxolane (DMD), a product of ethylene glycol’s direct acetalization with acetone, was tested as a solvent for polymers with satisfactory results in the solubility of epoxy resins. The addition of unpurified terephthalic acid and residues constituting post-production waste to concrete allows for a reduction in the mass of concrete in the range of 11.3–23.4% and the material modified in this way allows for a reduction in concrete consumption. This rPET waste management methodology is consistent with the assumptions of the circular economy and allows for a significant reduction of anthropogenic CO2 emissions. Full article
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15 pages, 1889 KB  
Article
Influence of Mixing Duration and Absorption Characteristics of Superabsorbent Polymers on the Fresh and Hardened Properties of High-Performance Concrete
by Yu-Cun Gu and Kamal H. Khayat
Materials 2025, 18(15), 3609; https://doi.org/10.3390/ma18153609 - 31 Jul 2025
Viewed by 549
Abstract
This study investigates the combined influence of superabsorbent polymers (SAPs) with distinct absorption kinetics and extended mixing sequences on the rheological, mechanical, and transport properties of high-performance concrete (HPC). Two SAPs—an ionic acrylamide-co-acrylic acid copolymer (SAP-P) and a non-ionic acrylamide polymer (SAP-B)—were incorporated [...] Read more.
This study investigates the combined influence of superabsorbent polymers (SAPs) with distinct absorption kinetics and extended mixing sequences on the rheological, mechanical, and transport properties of high-performance concrete (HPC). Two SAPs—an ionic acrylamide-co-acrylic acid copolymer (SAP-P) and a non-ionic acrylamide polymer (SAP-B)—were incorporated at an internal curing level of 100%. The impact of extended mixing times (3, 5, and 7 min) following SAP addition was systematically evaluated. Results showed that longer mixing durations led to increased superplasticizer demand and higher plastic viscosity due to continued water absorption by SAPs. However, yield stress remained relatively stable owing to the dispersing effect of the added superplasticizer. Both SAPs significantly enhanced the static yield stress and improved fresh stability, as evidenced by reduced surface settlement. Despite the rheological changes, mechanical properties—including compressive and flexural strengths and modulus of elasticity—were consistently improved, regardless of mixing duration. SAP incorporation also led to notable reductions in autogenous and drying shrinkage, as well as enhanced electrical resistivity, indicating better durability performance. These findings suggest that a 3 min extended mixing time is sufficient for effective SAP dispersion without compromising performance. Full article
(This article belongs to the Special Issue Characterization and Optimization of Cement-Based Materials)
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25 pages, 16276 KB  
Article
Localized Compression Behavior of GFRP Grid Web–Concrete Composite Beams: Experimental, Numerical, and Analytical Studies
by Yunde Li, Hai Cao, Yang Zhou, Weibo Kong, Kun Yu, Haoting Jiang and Zhongya Zhang
Buildings 2025, 15(15), 2693; https://doi.org/10.3390/buildings15152693 - 30 Jul 2025
Viewed by 519
Abstract
Glass fiber-reinforced polymer (GFRP) composites exhibit significant advantages over conventional structural webbing materials, including lightweight and corrosion resistance. This study investigates the localized compression performance of the proposed GFRP grid web–concrete composite beam through experimental and numerical analyses. Three specimen groups with variable [...] Read more.
Glass fiber-reinforced polymer (GFRP) composites exhibit significant advantages over conventional structural webbing materials, including lightweight and corrosion resistance. This study investigates the localized compression performance of the proposed GFRP grid web–concrete composite beam through experimental and numerical analyses. Three specimen groups with variable shear-span ratios (λ = 1.43, 1.77) and local stiffener specimens were designed to assess their localized compressive behavior. Experimental results reveal that a 19.2% reduction in shear-span ratio enhances ultimate load capacity by 22.93% and improves stiffness by 66.85%, with additional performance gains of 77.53% in strength and 94.29% in stiffness achieved through local stiffener implementation. In addition, finite element (FE) analysis demonstrated a strong correlation with experimental results, showing less than 5% deviation in ultimate load predictions while accurately predicting stress distributions and failure modes. FE parametric analysis showed that increasing the grid thickness and decreasing the grid spacing within a reasonable range can considerably enhance the localized compression performance. The proposed analytical model, based on Winkler elastic foundation theory, predicts ultimate compression capacities within 10% of both the experimental and numerical results. However, the GFRP grid strength adjustment factor βg should be further refined through additional experiments and numerical analyses to improve reliability. Full article
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