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15 pages, 2361 KiB  
Article
Geochemical Characteristics of the Hida Granitoids in the Unazuki and Katakaigawa Areas, Central Japan
by Kazuki Oishi, Rui Kuwahara, Kazuya Shimooka and Motohiro Tsuboi
Geosciences 2025, 15(8), 285; https://doi.org/10.3390/geosciences15080285 - 29 Jul 2025
Viewed by 270
Abstract
The Hida Belt in central Japan is a key geological unit for understanding the crustal growth of the Eurasian continent in the Mesozoic. However, while previous studies have focused primarily on geochronology, the geochemical characteristics of its rocks and minerals remain largely unexplored. [...] Read more.
The Hida Belt in central Japan is a key geological unit for understanding the crustal growth of the Eurasian continent in the Mesozoic. However, while previous studies have focused primarily on geochronology, the geochemical characteristics of its rocks and minerals remain largely unexplored. This study investigates the geochemical characteristics and magmatic processes of the Hida granitoids, including adakitic rocks, distributed in the Unazuki and Katakaigawa areas. Whole-rock major oxides and trace elements, as well as Rb-Sr isotopes, were analyzed. Based on Rb–Sr isotopic compositions, the Hida granitoids are classified into two types. The younger and older granitoids in the Unazuki area, categorized as Type I, exhibit a narrow range of isotopic ratios, whereas the older granitoids in the Katakaigawa area, classified as Type II, display significantly higher values than those of Type I. The geochemical data suggest that the adakitic rocks in the older granitoids originated from interaction with alkali-rich melts or fluids, while those in the younger granitoids were derived from hydrous felsic magmas sourced from subducted oceanic crust. These findings provide new insights into the formation and evolution of granitic magmatism in the Hida Belt. Full article
(This article belongs to the Section Geochemistry)
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32 pages, 32586 KiB  
Article
Magmatic Evolution at the Saindak Cu-Au Deposit: Implications for the Formation of Giant Porphyry Deposits
by Jun Hong, Yasir Shaheen Khalil, Asad Ali Narejo, Xiaoyong Yang, Tahseenullah Khan, Zhihua Wang, Huan Tang, Haidi Zhang, Bo Yang and Wenyuan Li
Minerals 2025, 15(8), 768; https://doi.org/10.3390/min15080768 - 22 Jul 2025
Viewed by 1276
Abstract
The Chagai porphyry copper belt is a major component of the Tethyan metallogenic domain, which spans approximately 300 km and hosts several giant porphyry copper deposits. The tectonic setting, whether subduction-related or post-collisional, and the deep dynamic processes governing the formation of these [...] Read more.
The Chagai porphyry copper belt is a major component of the Tethyan metallogenic domain, which spans approximately 300 km and hosts several giant porphyry copper deposits. The tectonic setting, whether subduction-related or post-collisional, and the deep dynamic processes governing the formation of these giant deposits remain poorly understood. Mafic microgranular enclaves (MMEs), mafic dikes, and multiple porphyries have been documented in the Saindak mining area. This work examines both the ore-rich and non-ore intrusions in the Saindak porphyry Cu-Au deposit, using methods like molybdenite Re-Os dating, U-Pb zircon ages, Hf isotopes, and bulk-rock geochemical data. Geochronological results indicate that ore-fertile and barren porphyries yield ages of 22.15 ± 0.22 Ma and 22.21 ± 0.33 Ma, respectively. Both MMEs and mafic dikes have zircons with nearly identical 206Pb/238U weighted mean ages (21.21 ± 0.18 Ma and 21.21 ± 0.16 Ma, respectively), corresponding to the age of the host rock. Geochemical and Sr–Nd–Hf isotopic evidence indicates that the Saindak adakites were generated by the subduction of the Arabian oceanic lithosphere under the Eurasian plate, rather than through continental collision. The adakites were mainly formed by the partial melting of a metasomatized mantle wedge, induced by fluids from the dehydrating subducting slab, with minor input from subducted sediments and later crust–mantle interactions during magma ascent. We conclude that shallow subduction of the Arabian plate during the Oligocene–Miocene may have increased the flow of subducted fluids into the sub-arc mantle source of the Chagai arc. This process may have facilitated the widespread deposition of porphyry copper and copper–gold mineralization in the region. Full article
(This article belongs to the Section Mineral Deposits)
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30 pages, 11512 KiB  
Article
Petrogenesis of Late Jurassic–Early Cretaceous Granitoids in the Central Great Xing’ an Range, NE China
by Cheng Qian, Lu Lu, Yan Wang, Junyu Fu, Xiaoping Yang, Yujin Zhang and Sizhe Ni
Minerals 2025, 15(7), 693; https://doi.org/10.3390/min15070693 - 28 Jun 2025
Viewed by 329
Abstract
The Great Xing’ an Range is located in the eastern part of the Xing’ an-Mongolian Orogenic Belt, which is an important component of the Central Asian Orogenic Belt. To determine the emplacement age and petrogenesis of the granitoids in the Gegenmiao and Taonan [...] Read more.
The Great Xing’ an Range is located in the eastern part of the Xing’ an-Mongolian Orogenic Belt, which is an important component of the Central Asian Orogenic Belt. To determine the emplacement age and petrogenesis of the granitoids in the Gegenmiao and Taonan areas of the central Great Xing’an Range, and to investigate its tectonic setting, petrographic studies, zircon U-Pb geochronology, whole-rock Sr-Nd isotopic analysis, zircon Hf isotopic analysis, and detailed geochemical investigations of this intrusion were carried out. The results indicate the following, in relation to the granitoids in the study areas: (1) The zircon U-Pb dating of the granitic rocks in the study areas yields ages ranging from 141.4 ± 2.0 Ma to 158.7 ± 1.9 Ma, indicating their formation during the Late Jurassic to Early Cretaceous; (2) the geochemical characteristics indicate that these rocks belong to the calc-alkaline series and peraluminous, classified as highly fractionated I-type granites with adakite features; (3) the Sr-Nd isotopic data show that the εNd(t) values of Gegenmiao granitic rocks are 2.8 and 2.1, while those of Taonan granitic rocks range from −1.5 to 0.7; (4) the Zircon εHf(t) values of the granitic rocks from Gegenmiao and Taonan vary from 2.11 to 6.48 and 0.90 to 8.25, respectively. They are interpreted to have formed through partial melting of thickened lower crustal material during the Meso-Neoproterozoic. The Gegenmiao and Taonan granitic rocks were formed in a transitional environment from post-orogenic compression to extension, which is closely associated with the Mongolia–Okhotsk tectonic system. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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25 pages, 5462 KiB  
Article
Late Carboniferous Slab Rollback in the Southern Altaids: Evidence from a Slab-Derived Adakitic Granodiorite in the South Tianshan
by Nijiati Abuduxun, Wenjiao Xiao, Wanghu Zhang, He Yang, Abidan Alimujiang, Peng Huang and Jingmin Gan
Minerals 2025, 15(7), 674; https://doi.org/10.3390/min15070674 - 24 Jun 2025
Viewed by 369
Abstract
The South Tianshan records the latest accretionary and collisional events in the southwestern Altaids, but the internal subduction-related processes are controversial. This study provides an integrative analysis of a newly identified Late Carboniferous adakitic granodiorite from the South Tianshan, incorporating geochronological, zircon U-Pb [...] Read more.
The South Tianshan records the latest accretionary and collisional events in the southwestern Altaids, but the internal subduction-related processes are controversial. This study provides an integrative analysis of a newly identified Late Carboniferous adakitic granodiorite from the South Tianshan, incorporating geochronological, zircon U-Pb and Lu-Hf isotopic, whole-rock geochemical, and Sr-Nd isotopic data. Zircon U-Pb analysis indicates that the granite was emplaced at 310 ± 2.5 Ma. Based on major element compositions, the granodiorite belongs to medium-K calc-alkaline weakly peraluminous series (A/CNK = 0.95–1.09). The samples exhibit typical high-silica adakitic affinity, as evidenced by the elevated contents of SiO2 (67.75–69.27 wt.%), Al2O3 (15.29–15.90 wt.%), Sr (479–530 ppm), and Ba (860–910 ppm); low concentrations of Yb (0.43–0.47 ppm) and Y (7.12–7.44 ppm); high Sr/Y ratios (67–72); and slight Eu anomalies (δEu = 0.89–1.03). The sodium-rich composition (K2O/Na2O = 0.48–0.71) is comparable to adakitic rocks from slab-derived melts. Elevated concentrations of Ni (22.12–24.25 ppm), Cr (33.20–37.86 ppm), Co (6.32–6.75 ppm), and V (30.33–32.48 ppm), along with high Mg# values (55–57), suggest melt–mantle interaction during magma ascent. The slightly enriched isotopic signatures, characterized by higher initial 87Sr/86Sr ratios (0.706086–0.706205) and lower εNd(t) (−3.09 to –2.47) and εHf(t) (−3.11 to +7.66) values, point to notable sedimentary contributions, potentially through source contamination and/or shallow-level crustal contamination. By integrating the new results with previously published data, we consider that the adakitic granodiorite was generated by partial melting of the subducted oceanic crust, triggered by asthenospheric upwelling associated with the southward rollback of the north-dipping South Tianshan oceanic lithosphere. Our data provide new insights into Late Carboniferous retreating subduction along the southern active margin of the Yili-Central Tianshan and the accretionary architecture of the southern Altaids. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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24 pages, 8945 KiB  
Article
Chronological and Geochemical Characteristics of a Newly Discovered Biotite Granite Porphyry in the Zhuxi W-Cu Polymetallic Deposit, Jiangxi Province, South China: Implications for Cu Mineralization
by Yongpeng Ouyang, Qi Chen, Runling Zeng and Tongfei Li
Minerals 2025, 15(6), 624; https://doi.org/10.3390/min15060624 - 9 Jun 2025
Viewed by 315
Abstract
Multiple occurrences of adakitic rocks, with crystallization ages clustering around ~160 Ma, have been documented in the Zhuxi district, northeast Jiangxi Province, South China. This research identifies a new adakitic biotite granite porphyry within the Zhuxi W-Cu polymetallic deposit. Zircon U-Pb geochronology of [...] Read more.
Multiple occurrences of adakitic rocks, with crystallization ages clustering around ~160 Ma, have been documented in the Zhuxi district, northeast Jiangxi Province, South China. This research identifies a new adakitic biotite granite porphyry within the Zhuxi W-Cu polymetallic deposit. Zircon U-Pb geochronology of this porphyry yields a crystallization age of 161.6 ± 2.1 Ma. Integrated with previously published data, the adakitic rocks in the study area—comprising diorite porphyrite, biotite quartz monzonite porphyry, and the newly identified biotite granite porphyry—are predominantly calc-alkaline and peraluminous. They exhibit enrichment in light rare-earth elements (LREEs) and depletion in heavy rare-earth elements (HREEs), with slight negative Eu anomalies. The trace element patterns are characterized by enrichment in Ba, U, K, Pb, and Sr, alongside negative Nb, Ta, P, and Ti anomalies, indicative of arc-like magmatic signatures. Comparative analysis of geological and geochemical characteristics suggests that these three rock types are not comagmatic. Petrogenesis of the Zhuxi adakitic suite is linked to a dynamic tectonic regime involving Mesozoic crustal thickening, subsequent delamination, and lithospheric extension. Asthenospheric upwelling likely triggered partial melting of the overlying metasomatized lithospheric mantle, generating primary mantle-derived magmas. Underplating and advection of heat by these magmas induced partial melting of the thickened lower crust, forming the biotite granite porphyry. Partial melting of delaminated lower crustal material, interacting with the asthenosphere or asthenosphere-derived melts, likely generated the diorite porphyrite. The biotite quartz monzonite porphyry is interpreted to have formed from mantle-derived magmas that underwent assimilation of, or mixing with, silicic crustal melts during ascent. The ~160 Ma crystallization ages of these adakitic rocks are broadly contemporaneous with W-Mo mineralization in the Taqian mining area of the Zhuxi district. Furthermore, their geochemical signatures imply a prospective metallogenic setting for Cu-Mo mineralization around this period in the Taqian area. Full article
(This article belongs to the Special Issue Using Mineral Chemistry to Characterize Ore-Forming Processes)
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30 pages, 7259 KiB  
Article
Hornblende and Plagioclase Micro-Texture and Compositions: Evidence for Magma Mixing in High-Mg Adakitic Pluton, North China Craton
by Xiaowei Guo and Nengsong Chen
Minerals 2025, 15(6), 604; https://doi.org/10.3390/min15060604 - 4 Jun 2025
Viewed by 425
Abstract
In this study, we performed microtextural, major/minor element, and Sr-isotope analyses on hornblende and plagioclase (as phenocrysts, groundmass, or inclusions) from the Early Cretaceous Jiagou pluton (eastern North China Craton), to elucidate the magma source, possible magma mixing process, and the transition from [...] Read more.
In this study, we performed microtextural, major/minor element, and Sr-isotope analyses on hornblende and plagioclase (as phenocrysts, groundmass, or inclusions) from the Early Cretaceous Jiagou pluton (eastern North China Craton), to elucidate the magma source, possible magma mixing process, and the transition from low-Mg to high-Mg adakitic magmas. Petrographic study and electron microprobe (EMP) analyses reveal well-defined compositional zoning in hornblende and plagioclase phenocrysts. Outward from the core (first zone), the second and third zones show pronounced oscillatory zoning and significant variations in Mg# and An%, while the fourth zone is relatively homogeneous. A corroded albitic plagioclase core with sieve texture is enclosed in the first zone and locally intergrows with worm-like quartz streaks and fine hornblende inclusions, featuring Mg# = 81 (core) and 62 (rim). The new plagioclase infill has An% = 14–41. The corroded plagioclase has an initial 87Sr/86Sr = 0.7074, while that of zoned phenocrystic plagioclase ranges from 0.7068 to 0.7079, suggesting EMI and EMII mantle input. Inclusion hornblende is low in Ti and Cr, while phenocrystic hornblende shows higher Cr in the first zone and lower Cr in the outer zones. The newly discovered mafic microgranular enclaves (MMEs) and regional geochemical data suggest three major magma mixing events. The felsic parental magma was likely originated from a mixed EMI–EMII mantle source before mixing with a mafic magma derived from the partial melting of, successively, a low-Cr and a high-Cr peridotite. Our findings support a petrogenetic model of lower crustal delamination and highlight the critical role of repeated mafic injections in generating high-Mg adakitic magmas. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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19 pages, 20369 KiB  
Article
Magmatic Telescoping as a Reflection of the Shift in Geodynamic Circumstances and Patterns of Formation of Gold Ore Manifestations in the Example of the Uskalin Granitoid Massif (Russia)
by Inna M. Derbeko
Minerals 2025, 15(6), 592; https://doi.org/10.3390/min15060592 - 1 Jun 2025
Viewed by 401
Abstract
This paper considers the spatial distribution of gold occurrences, their geochemical anomalies, and late Mesozoic igneous complexes within the framing of the eastern flank of the Mongol–Okhotsk orogenic belt (EF MOOB). It is established that elevated gold concentrations are associated with telescoped igneous [...] Read more.
This paper considers the spatial distribution of gold occurrences, their geochemical anomalies, and late Mesozoic igneous complexes within the framing of the eastern flank of the Mongol–Okhotsk orogenic belt (EF MOOB). It is established that elevated gold concentrations are associated with telescoped igneous complexes formed in different geodynamic regimes. The southern framing of the EF MOOB (Russia) was chosen as the key study area due to its well-preserved superposition of multi-stage igneous events. These stages are considered using the example of the Uskalin intrusive massif. It is a representative example where three geodynamic phases are recorded, namely initial supra-subduction (149–138 Ma), subduction (140–122 Ma), and collision (119–97 Ma). It is shown that the massif is composed of granitoids aged 145 Ma, 129 Ma, and 112 Ma, which correspond to the distinguished geodynamic stages. Geochemical characteristics of the rocks of the first two stages completely coincide with those of the rocks corresponding to the geodynamic stages. The exception is the formations from the collision process. At this stage, differences appear in the rocks, which are manifested in the Sr/Y ratio. These values are comparable with those in the granitoids of the adakite series. Such differences were established only within gold-bearing areas. The formation of the Uskalin massif was accompanied by extensive mineralization zones with gold-bearing veins. Gold concentrations in granitoids of the adakite series (145 Ma) exceed the crustal Clarke value by 2.25 times, which directly links mineralization with magmatic processes. It is assumed that the presence of collision-stage rocks with signs of the adakite signature may be one of the signs of detection of epithermal gold ore objects in the zones of magmatic telescoping. Taking into account the evolution of the MOOB associated with the closure of the MOB and with the accompanying magmatic events, an analog of which is considered using the example of the southern framing of the EF MOOB, it is possible to assume the use of the obtained results in conducting exploration work for ore gold in this region. Full article
(This article belongs to the Section Mineral Deposits)
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27 pages, 21759 KiB  
Article
Origin and Tectonic Implication of Cenozoic Alkali-Rich Porphyry in the Beiya Au-Polymetallic Deposit, Western Yunnan, China
by Yun Zhong, Yajuan Yuan, Ye Lu and Bin Xia
Minerals 2025, 15(5), 531; https://doi.org/10.3390/min15050531 - 16 May 2025
Viewed by 330
Abstract
Cenozoic alkali-rich porphyries are widely distributed in the junction zone between the Sanjiang Orogenic belt and the Yangtze Plate. They are of great significance for understanding the regional geodynamics, tectonic evolution, and metallogenesis. However, the origin of these porphyries remains controversial. In this [...] Read more.
Cenozoic alkali-rich porphyries are widely distributed in the junction zone between the Sanjiang Orogenic belt and the Yangtze Plate. They are of great significance for understanding the regional geodynamics, tectonic evolution, and metallogenesis. However, the origin of these porphyries remains controversial. In this study, new petrological, geochemical, and geochronological data are presented for Cenozoic syenite porphyry from the Beiya porphyry Au-polymetallic deposit in western Yunnan. Zircon U-Pb dating results show that the Beiya syenite porphyries formed around 36.3–35.0 Ma, coinciding with the magmatic peak in the Jinshajiang-Red River (JSJ-RR) alkali-rich porphyry belt. Geochemical analyses indicate that the Beiya porphyries have potassic characteristics and an arc-like geochemical affinity, with C-type adakite affinity, suggesting a post-collisional setting. The JSJ-RR fault zone is unlikely to be the primary mechanism responsible for the formation of this alkali-rich porphyry magmatism. Instead, the development of the Beiya alkali-rich porphyries is likely associated with the convective removal of the lower part of the overthickened lithospheric mantle and asthenospheric upwelling during the Eocene–Oligocene. Their magmas probably originated from the partial melting of Paleo–Mesoproterozoic garnet amphibolite facies rocks in the thickened lower continental crust, with the addition of shoshonitic mafic magmas produced by the partial melting of metasomatized lithospheric mantle triggered by asthenospheric upwelling. This study provides additional reliable evidence to further constrain the origin of Cenozoic alkali-rich porphyries in the JSJ-RR belt. Full article
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21 pages, 8878 KiB  
Article
Significance of Adakitic Plutons for Mineralization in Wubaduolai Copper Deposit, Xizang: Evidence from Zircon U-Pb Age, Hf Isotope, and Geochemistry
by Ke Gao, Zhi Zhang, Linkui Zhang, Peiyan Xu, Yi Yang, Jianyang Wu, Yingxu Li, Miao Sun and Wenpeng Su
Minerals 2025, 15(5), 500; https://doi.org/10.3390/min15050500 - 8 May 2025
Viewed by 463
Abstract
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and [...] Read more.
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and assessing the metallogenic potential. This paper presents the zircon U-Pb dating, Hf isotope analysis, and whole-rock major and trace geochemical analysis of the plutons in the Wubaduolai mining area. The results indicate that the zircon U-Pb concordia age of the monzogranite is 15.7 ± 0.1 Ma, while the granodiorite porphyry has a concordia age of 15.9 ± 0.2 Ma, both corresponding to a Miocene diagenesis. The geochemical data show that both plutons belong to the high-K calc-alkaline series, characterized by a relative enrichment of large-ion lithophile elements (K, Rb, Ba, and Sr) and a depletion of high-field-strength elements (Nb, Ta, and Ti). Both plutons are characterized by low Y, low Yb, and high Sr/Y values, displaying the typical geochemical characteristics of adakites. Their mineral composition is similar to that of adakite. The εHf(t) values of the monzogranite and granodiorite porphyry range from −5.34 to −2.3 and −5.2 to −3.43, respectively, with two-stage model ages (TDM2) of 1246–1441 Ma and 1318–1432 Ma. Based on the regional data and this study, the plutons in the Wubaduolai mining area formed in a post-collision setting following the India–Asia continental collision. The magma source is identified as the partial melting of a thickened, newly formed lower crust. The above characteristics are consistent with the diagenetic and metallogenic ages, magma source, and dynamic backgrounds of the typical regional deposits. Full article
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28 pages, 6120 KiB  
Article
Machine Learning Classification of Fertile and Barren Adakites for Refining Mineral Prospectivity Mapping: Geochemical Insights from the Northern Appalachians, New Brunswick, Canada
by Amirabbas Karbalaeiramezanali, Fazilat Yousefi, David R. Lentz and Kathleen G. Thorne
Minerals 2025, 15(4), 372; https://doi.org/10.3390/min15040372 - 2 Apr 2025
Cited by 1 | Viewed by 764
Abstract
This study applies machine learning (ML) techniques to classify fertile [for porphyry Cu and (or) Au systems] and barren adakites using geochemical data from New Brunswick, Canada. It emphasizes that not all intrusive units, including adakites, are inherently fertile and should not be [...] Read more.
This study applies machine learning (ML) techniques to classify fertile [for porphyry Cu and (or) Au systems] and barren adakites using geochemical data from New Brunswick, Canada. It emphasizes that not all intrusive units, including adakites, are inherently fertile and should not be directly used as the heat source evidence layer in mineral prospectivity mapping without prior analysis. Adakites play a crucial role in mineral exploration by helping distinguish between fertile and barren intrusive units, which significantly influence ore-forming processes. A dataset of 99 fertile and 66 barren adakites was analyzed using seven ML models: support vector machine (SVM), neural network, random forest (RF), decision tree, AdaBoost, gradient boosting, and logistic regression. These models were applied to classify 829 adakite samples from around the world into fertile and barren categories, with performance evaluated using area under the curve (AUC), classification accuracy, F1 score, precision, recall, and Matthews correlation coefficient (MCC). SVM achieved the highest performance (AUC = 0.91), followed by gradient boosting (0.90) and RF (0.89). For model validation, 160 globally recognized fertile adakites were selected from the dataset based on well-documented fertility characteristics. Among the tested models, SVM demonstrated the highest classification accuracy (93.75%), underscoring its effectiveness in distinguishing fertile from barren adakites for mineral prospectivity mapping. Statistical analysis and feature selection identified middle rare earth elements (REEs), including Gd and Dy, with Hf, as key indicators of fertility. A comprehensive analysis of 1596 scatter plots, generated from 57 geochemical variables, was conducted using linear discriminant analysis (LDA) to determine the most effective variable pairs for distinguishing fertile and barren adakites. The most informative scatter plots featured element vs. element combinations (e.g., Ga vs. Dy, Ga vs. Gd, and Pr vs. Gd), followed by element vs. major oxide (e.g., Fe2O3T vs. Gd and Al2O3 vs. Hf) and ratio vs. element (e.g., La/Sm vs. Gd, Rb/Sr vs. Hf) plots, whereas major oxide vs. major oxide, ratio vs. ratio, and major oxide vs. ratio plots had limited discriminatory power. Full article
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29 pages, 27225 KiB  
Article
Paleo-Asian Ocean Ridge Subduction: Evidence from Volcanic Rocks in the Fuyun–Qinghe Area, Southern Margin of the Chinese Altay
by Jixu Liu, Cui Liu, Qing Liu, Zhaohua Luo, Yong Liu, Chenghao Zhou, Xu Guo, Xianghui Yu and Miao Wang
Appl. Sci. 2025, 15(7), 3736; https://doi.org/10.3390/app15073736 - 28 Mar 2025
Viewed by 404
Abstract
The Chinese Altay is located in the western segment of the Central Asian Orogenic Belt (CAOB) and preserves critical records of the Paleo-Asian Ocean (PAO) Plate evolution during the Paleozoic era. This region also hosts significant mineral deposits, making it a focal point [...] Read more.
The Chinese Altay is located in the western segment of the Central Asian Orogenic Belt (CAOB) and preserves critical records of the Paleo-Asian Ocean (PAO) Plate evolution during the Paleozoic era. This region also hosts significant mineral deposits, making it a focal point for geological research. In this paper, field investigation, petrology, mineralogy, and petrography studies were conducted on volcanic rocks in the Fuyun–Qinghe area, southern margin of the Chinese Altay, and the paper provided new zircon LA-ICP-MS dating data, Lu-Hf isotope data, and whole-rock geochemical data of the basaltic to andesitic volcanic rocks. Thus, the formation age, petrogenesis, and tectonic setting of these rocks were discussed, which was of great significance to reveal the nature of the PAO Plate. The findings showed that the basaltic andesitic volcanic breccia was formed at 382.9 ± 3.4 Ma, the basalt was 401.7 ± 4.7 Ma, and the andesites were 405.1 ± 5.6 Ma and 404.8 ± 6.7 Ma, which indicated that the above rocks were formed in the Early–Middle Devonian. The volcanic rock assemblages were hawaiite, mugearite, potassic trachybasalt, basaltic andesite, andesite, benmoreite, etc., which contained labeled magmatic rocks such as adakite, sub-boninite, niobium-enriched arc basalt (NEAB), picrite, high-magnesium andesite (HMA), and magnesium andesite (MA). Comprehensive analysis indicated that magma probably mainly originated from three sources: (1) partial melting of the PAO slab, (2) partial melting of the overlying garnet–spinel lherzolite mantle peridotite metasomatized by subducting-related fluids (melts), and (3) a possible input of the asthenosphere. Comparative analysis with modern analogs (e.g., Chile Triple Junction) indicates that ridge subduction of the PAO had existed in the Fuyun–Qinghe area during the Early–Middle Devonian. Based on available evidence, we tentatively named the oceanic plates in this region the central Fuyun–Qinghe Ridge and the Junggar Ocean Plates, separated by the ridge on both sides. Although the ocean had a certain scale, it had entered the climax period of transition from ocean to continent. Full article
(This article belongs to the Special Issue Recent Advances in Geochemistry)
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21 pages, 6656 KiB  
Article
A Geochemical and Sr–Nd–Hf–O Isotopic Study of the Early Silurian Shandan Adakites in the Longshoushan Area: Implications for the Collisional Setting of the Proto–Tethyan North Qilian Orogen, Northwest China
by Zhihan Bai, Yang Yang, Xijun Liu, Pengde Liu, Gang Chen, Xiao Liu, Rongguo Hu, Hao Tian, Yande Liu, Wenmin Huang and Yao Xiao
Minerals 2025, 15(4), 352; https://doi.org/10.3390/min15040352 - 27 Mar 2025
Viewed by 448
Abstract
The North Qilian Orogen experienced a series of late Neoproterozoic to early Paleozoic tectonic events, including the opening and closure of the Proto-Tethyan Qilian Ocean, as well as post-subduction processes. This study investigated the Shandan adakites in the Longshoushan area of the North [...] Read more.
The North Qilian Orogen experienced a series of late Neoproterozoic to early Paleozoic tectonic events, including the opening and closure of the Proto-Tethyan Qilian Ocean, as well as post-subduction processes. This study investigated the Shandan adakites in the Longshoushan area of the North Qilian Orogen, focusing on zircon U–Pb geochronology, whole-rock geochemistry, and Sr–Nd–Hf–O isotopic compositions. The Shandan adakites yield ages of ca. 446–440 Ma, suggesting they crystallized during the collision between the Alxa and Qilian blocks following the closure of the Proto-Tethyan North Qilian Ocean. High Sr/Y (40.9–117) ratios and enrichments in light rare earth elements indicate that the Shandan adakites were formed by partial melting of thickened magnesian lower crust. They have relatively rich εNd (t) (−7.66 to −6.32), εHf(t) (3.30 to −12.4), and δ18O (5.34‰–7.52‰). Zircon Hf–O and whole-rock Sr–Nd isotopes confirm significant contributions from the ancient crust and mantle-derived melts, suggesting complex crust–mantle interactions in their magma sources. We propose that the Shandan adakites formed during the (early) post-collisional stage of orogenesis. Based on regional geological evidence and previous studies, we suggest the Alxa and Central Qilian blocks collided during ca. 446–440 Ma, leading to the thickening of the lower crust. After ca. 440 Ma, the tectonic setting of the Northern Qilian Orogen transitioned from a collisional to a post-collisional stage. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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26 pages, 15286 KiB  
Article
Late Triassic Felsic and Mafic Magmatism in the South Qinling Orogen, Central China: Insights from the Petrology, Zircon U-Pb Geochronology, and Geochemistry of the Huoshaodian Pluton
by Meijing Li, Xianzhi Pei, Lei Pei, Zuochen Li, Ruibao Li, Shaowei Zhao, Li Qin, Mao Wang and Xiao Wang
Minerals 2025, 15(2), 120; https://doi.org/10.3390/min15020120 - 26 Jan 2025
Cited by 1 | Viewed by 898
Abstract
The petrology, geochemistry, and zircon U-Pb chronology of the Huoshaodian pluton in the Liuba area of the western part of the South Qinling tectonic belt are investigated in this study. The Huoshaodian pluton consists of gabbro, quartz diorite, and granodiorite, and the dominated [...] Read more.
The petrology, geochemistry, and zircon U-Pb chronology of the Huoshaodian pluton in the Liuba area of the western part of the South Qinling tectonic belt are investigated in this study. The Huoshaodian pluton consists of gabbro, quartz diorite, and granodiorite, and the dominated rock type is quartz diorite. The results indicate that the Huoshaodian pluton belongs to the calc-alkaline series. In the chondrite-normalized REE, all of the samples showed similar patterns, with an enrichment of light REEs and depletion of heavy REEs, but they showed slight differences in the degrees of Eu anomalies. The primitive mantle-normalized trace element diagram reveals an enrichment of large-ion lithophile elements (LILEs) and light rare earth elements (LREEs), as well as depleted high field strength elements (HFSEs). The zircon U-Pb dating results reveal that the gabbro, quartz diorite, and granodiorite have crystallization ages of 214.9 ± 0.58 Ma, 215.0 ± 1.2 Ma, and 215.4 ± 1.9 Ma, respectively, indicating that the Huoshaodian pluton was emplaced during the late Triassic period (214.9–215.4 Ma). In terms of petrogenesis, the gabbro of the Huoshaodian pluton originates from a transitional lithospheric mantle that has undergone fluid metasomatism and partial melting. Specifically, it originated through 1%–2% garnet spinel peridotite undergoing partial melting. In addition, the gabbro underwent a slight degree of contamination by crustal materials during its ascent and intrusion, with some continental crust material being incorporated. The quartz diorite and granodiorite of the Huoshaodian pluton are formed through partial melting processes occurring within the normal lower crust. Combined with the previous studies on the early Mesozoic tectonic evolution of the South Qinling, this study proposes that the formation mechanism of the Huoshaodian pluton may be as follows: in the early Triassic, the Mianlue Ocean subducted northward beneath the Qinling microblock, resulting in a large-scale continental-continental collision between the North China Block and the Yangtze Block; when the oceanic crust subducted to a certain depth, the detachment of the subducting slab triggered the upwelling of mantle material. The heat from mantle-derived magma caused the partial melting of the mafic lower crust, while the mafic magma entered into the upper granitic magma chamber and began to mix. Due to the high viscosity contrast and temperature difference between the two end-member magmas, incomplete mixing led to the formation of a melt with distinct adakitic characteristics and a mafic melt representing mantle-derived material. Full article
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20 pages, 21100 KiB  
Article
Petrogenesis and Metallogenic Significance of the Demingding Mo-Cu Porphyry Deposit in the Gangdese Belt, Xizang: Insights from U-Pb and Re-Os Geochronology and Geochemistry
by Sudong Shi, Shuyuan Chen, Sangjiancuo Luo, Huan Ren and Xiaojia Jiang
Minerals 2024, 14(12), 1232; https://doi.org/10.3390/min14121232 - 3 Dec 2024
Viewed by 1126
Abstract
The 1500 km-long Gangdese magmatic belt is a crucial region for copper polymetallic mineralization, offering valuable insights into collisional porphyry copper systems. This study focuses on the Demingding deposit, a newly identified occurrence of molybdenum–copper (Mo-Cu) mineralization within the eastern segment of the [...] Read more.
The 1500 km-long Gangdese magmatic belt is a crucial region for copper polymetallic mineralization, offering valuable insights into collisional porphyry copper systems. This study focuses on the Demingding deposit, a newly identified occurrence of molybdenum–copper (Mo-Cu) mineralization within the eastern segment of the belt. While the mineralization age, magmatic characteristics, and tectonic context are still under investigation, we examine the deposit’s petrology, zircon U-Pb geochronology, whole-rock chemistry, and Re-Os isotopic data. The Demingding deposit exhibits a typical alteration zoning, transitioning from an inner potassic zone to an outer propylitic zone, which is significantly overprinted by phyllic alteration closely associated with Mo and Cu mineralization. Zircon U-Pb dating of the ore-forming monzogranite porphyries reveals crystallization ages ranging from 21 to 19 Ma, which is indistinguishable within error from the mean Re-Os age of 21.3 ± 0.4 Ma for Mo veins and veinlets hosted by these porphyries. This alignment suggests a late Miocene magmatic event characterized by Mo-dominated mineralization, coinciding with the continuous thickening of the continental crust during the collision of the Indian and Asian continents. The ore-forming porphyries range in composition from granodiorite to monzogranite and are classified as high-K calc-alkaline with adakite-like features, primarily resulting from the partial melting of subduction-modified thickened mafic lower crust. Notably, the ore-forming porphyries exhibit higher fO2 and H2O levels than barren porphyries in this area during crustal thickening, highlighting the significant contributions of hydrous and oxidized fluids from their source to the Mo-Cu mineralization process. Regional data indicate that the Gangdese porphyry metallogenic belt experienced concentrated Cu-Mo mineralization between 17 and 13 Ma. The formation of Mo-dominated deposits such as Demingding and Tangbula in the eastern segment of the belt, with slightly older ages around 20 Ma, underscores the presence of a significant porphyry Mo metallogenic event during this critical post-collision mineralization period. Full article
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21 pages, 20991 KiB  
Article
Petrogenesis of Diorite-Porphyrite in the Southern Xintai Area of the Mid-Western Shandong Peninsula, North China Craton: Insights from Geochronology, Mineralogy, Geochemistry, and Sr-Nd-Hf Isotopes
by Lijie Jin, Jilin Wang, Pinrui Qin, Chunjia Li, Shuang Xu, Zhixin Han, Wei Wang, Wei Liu, Zisheng Wang, Jilei Gao and Fangfang Li
Minerals 2024, 14(12), 1220; https://doi.org/10.3390/min14121220 - 29 Nov 2024
Viewed by 898
Abstract
The Early Cretaceous intermediate intrusive rocks have important significance in understanding the crust–mantle interaction, iron mineralization, and tectonic evolution in the western Shandong Peninsula. In this study, we present new zircon U–Pb ages, and Hf isotope, whole-rock geochemistry, Sr–Nd isotopes, and the mineral [...] Read more.
The Early Cretaceous intermediate intrusive rocks have important significance in understanding the crust–mantle interaction, iron mineralization, and tectonic evolution in the western Shandong Peninsula. In this study, we present new zircon U–Pb ages, and Hf isotope, whole-rock geochemistry, Sr–Nd isotopes, and the mineral chemistry of the diorite-porphyrite in the southern Xintai area, mid-western Shandong Peninsula. The diorite-porphyrite formed at ca. 125 Ma. They have intermediate SiO2 (59.57–62.29 wt.%) and MgO (2.78–3.58 wt.%) contents, high Mg# values (53–56), high Sr (589–939 ppm) and low Y (9.2–10.8 ppm) contents, and high Sr/Y ratios (54–94), showing adakitic affinity. The diorite-porphyrite exhibits lower zircon εHf(t) values (−30.1 to 7.5) and whole-rock εNd(t) values (−3.5 to −6.0), with (87Sr/86Sr)i ratios of 0.70514–0.70567. We suggest that the diorite-porphyrite was derived from the partial melting of the local delamination of lower continental crust and then by the interaction with the enriched lithospheric mantle. The genesis of diorite-porphyrite may be related to the rollback process of the Paleo-Pacific slab in the Early Cretaceous. This geodynamic process induced the melting of the enriched lithospheric mantle, subducted oceanic crust, and local delamination of lower continental crust, which produced different types of adakitic magmatism in the western Shandong Peninsula. Full article
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