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30 pages, 2966 KB  
Article
Influence of PVD TiN Coatings on the Wear Behavior and Durability of HSS Milling Tools in Solid Wood Machining
by Cristina Vasilica Icociu, Nicoleta Elisabeta Pascu, Eduard Bendic, Dan Dobrotă, Gabriel Tiberiu Dobrescu and Ionela Magdalena Rotaru
Coatings 2026, 16(4), 500; https://doi.org/10.3390/coatings16040500 - 20 Apr 2026
Abstract
Tool wear remains a critical limiting factor in machining performance, particularly in dry cutting conditions where friction and tribological interactions dominate. This study investigates the influence of a 5–8 μm PVD-deposited TiN coating on the wear behavior of high-speed steel (HSS) end mills [...] Read more.
Tool wear remains a critical limiting factor in machining performance, particularly in dry cutting conditions where friction and tribological interactions dominate. This study investigates the influence of a 5–8 μm PVD-deposited TiN coating on the wear behavior of high-speed steel (HSS) end mills during milling of three representative wood species (oak, beech, and fir). A spatially resolved wear evaluation methodology was employed, based on ten measurement points distributed along a 20 mm active cutting edge, enabling simultaneous assessment of mean wear and maximum localized wear (Umax). A factorial experimental design combining material type and feed rate (1500–2500 mm/min) was analyzed using two-way ANOVA with effect size quantification (η2). The results reveal a statistically significant reduction in mean wear for TiN-coated tools (F = 7.46, p = 0.0195, η2 = 0.34), corresponding to an average decrease of approximately 46% compared to uncoated tools. Maximum wear was influenced by both coating (F = 14.73, p = 0.0028, η2 = 0.399) and material (F = 4.37, p = 0.040, η2 = 0.237). The experimental findings are interpreted through a tribological framework, indicating a transition from abrasion- and micro-chipping-dominated degradation in uncoated tools to a controlled wear regime in TiN-coated tools, characterized by reduced asperity penetration, delayed crack initiation, and limited tribochemical interactions. These results demonstrate that coating effects dominate global wear evolution, while material properties influence localized degradation. The proposed combined experimental–statistical–mechanistic approach provides a robust framework for understanding and optimizing tool performance in dry machining environments. Full article
(This article belongs to the Section Metal Surface Process)
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21 pages, 2750 KB  
Article
Ignition of Vegetation Induced by Discharge from Abraded Medium-Voltage Insulated Overhead Lines
by Tian Tan, Huajian Peng, Xin Yang, Jiaxi Liu, Mingzhe Li, Shuaiwei Fu and Yafei Huang
Energies 2026, 19(8), 1990; https://doi.org/10.3390/en19081990 - 20 Apr 2026
Abstract
Tree contact discharge is a key contributing factor to wildfires caused by medium-voltage insulated conductors. Prolonged abrasion of the insulation layer by branches gradually creates weak points in the insulation. When subjected to lightning strikes, these areas are prone to forming lightning-induced pinholes, [...] Read more.
Tree contact discharge is a key contributing factor to wildfires caused by medium-voltage insulated conductors. Prolonged abrasion of the insulation layer by branches gradually creates weak points in the insulation. When subjected to lightning strikes, these areas are prone to forming lightning-induced pinholes, which can subsequently trigger partial discharge and even ignition. This study systematically investigates the discharge-induced ignition mechanism for 10 kV overhead insulated conductors in tree contact scenarios by establishing an experimental platform integrated with high-speed imaging, ultraviolet detection, and simulation methods. Three types of typical defects were set up in the experiments: complete insulation abrasion, lightning puncture holes accompanied by localized abrasion, and lightning puncture holes without abrasion. The development process and characteristics of different discharge forms were observed and analyzed. The results indicate that the tree contact discharge ignition mechanism can be categorized into two types: thermal accumulation and direct arcing. The former occurs when insulation abrasion or composite defects exist, where sustained partial discharge or a high-resistance current leads to gradual heat accumulation, resulting in an ignition delay lasting tens of seconds. The latter occurs when only small defects such as lightning puncture holes exist in the insulation layer. A concentrated arc forms due to gap breakdown under high voltage, leading to a millisecond-level ignition process. The study found that different discharge forms produce significantly distinct ablation and carbonization patterns on both the insulation layer and the branch surface, reflecting differences in energy transfer pathways. Simulation analysis further indicated that the thickness of the insulation layer affects the electric field distribution in the tree contact gap, with the initial discharge field strength decreasing as the thickness increases. This study provides experimental evidence and classification guidance for tree contact fault monitoring, insulation condition assessment, and wildfire prevention and control in medium-voltage distribution networks. Full article
38 pages, 24690 KB  
Review
Glass-Ceramic Bonding Agents for High-Performance Grinding: A Material Design Framework Based on Multi-System Comparisons
by Yufei Li, Le Tian, Longyao Xu, Mingmin Li, Huaying Bian, Xuetao Wang and Shuanghua Wang
Inorganics 2026, 14(4), 116; https://doi.org/10.3390/inorganics14040116 - 20 Apr 2026
Abstract
This review systematically analyzes the technological progress, structural characteristics, and performance disparities among various diamond grinding wheel bond systems, aiming to establish a unified performance evaluation framework. This framework clarifies material selection criteria and highlights promising research directions. Eight prevalent bond systems are [...] Read more.
This review systematically analyzes the technological progress, structural characteristics, and performance disparities among various diamond grinding wheel bond systems, aiming to establish a unified performance evaluation framework. This framework clarifies material selection criteria and highlights promising research directions. Eight prevalent bond systems are encompassed: resin, metal, ceramic, brazing, electroplating, composite, additive manufacturing, and glass-ceramics. A comparative analysis of these systems is conducted across multiple dimensions. Key evaluation metrics primarily include bond strength, thermal stability, self-sharpening capability, thermal conductivity, and formability. Considerable variations in these indicators are observed across the different bonding agents. Each system presents distinct advantages alongside inherent limitations. Within the constructed multi-metric framework, glass-ceramic bonding agents demonstrate high comprehensive potential in critical aspects such as bond strength and thermal stability, underscoring their research value as a novel high-performance bond system. Current primary challenges focus on the regulation of crystallization kinetics, the design of interfacial reaction layers, and multiscale performance prediction. Future research may advance along several paths. Synergistic design of material composition and microstructure is essential, while in-depth investigation into multiphysics coupling mechanisms remains necessary. Furthermore, data-driven material optimization methods are poised to unlock new possibilities for bond development. These approaches are expected to facilitate the precise design and application of high-performance diamond grinding wheel bonds. Full article
(This article belongs to the Special Issue Novel Ceramics and Refractory Composites)
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15 pages, 1589 KB  
Article
Bond Strength of Pretreated SFRC CAD/CAM Blocks: Comparison of Two SBS Test Methods
by Deniz Mizrak, Sufyan Garoushi, Pekka K. Vallittu, Mine Betul Uctasli and Lippo Lassila
Polymers 2026, 18(8), 990; https://doi.org/10.3390/polym18080990 - 19 Apr 2026
Abstract
The reliability of adhesive bonding to CAD/CAM resin composites is influenced not only by material composition and surface treatment but also by the testing methodology used to assess bond strength. However, the impact of different shear bond strength (SBS) test configurations remains insufficiently [...] Read more.
The reliability of adhesive bonding to CAD/CAM resin composites is influenced not only by material composition and surface treatment but also by the testing methodology used to assess bond strength. However, the impact of different shear bond strength (SBS) test configurations remains insufficiently clarified. This study evaluated the influence of different surface pretreatment protocols and SBS test methods on the bonding performance of a self-adhesive resin cement to two CAD/CAM materials: a conventional particulate-filled composite (Cerasmart 270) and an experimental short glass fiber-reinforced composite (SFRC CAD). Specimens (14 × 12 × 3 mm; n = 80 per material) were ground with 320-grit silicon carbide paper and divided according to surface pretreatment: airborne-particle abrasion (APA) or APA followed by hydrofluoric acid application for 60 s (APA + HF). Each group was further subdivided based on the SBS test method using either resin cement cylinders fabricated with a custom transparent mold (diameter: 3.6 mm; height: 3 mm) or metallic cylinders cemented to the treated surface. Half of the specimens were tested after 48 h of water storage, while the remainder underwent hydrothermal aging by boiling in water for 16 h prior to testing. Material type, SBS test method, surface pretreatment, and aging significantly affected bond strength (p < 0.05). The metallic cylinder method produced higher SBS values than the transparent mold technique, particularly for SFRC CAD. APA + HF tended to reduce SBS in Cerasmart 270, particularly after aging, whereas SFRC CAD showed comparable or higher bond strength values with APA alone. Aging decreased SBS in most groups. Overall, bond strength was influenced by both material type and test methodology. Within the limitations of this study, airborne-particle abrasion alone may be sufficient for SFRC CAD materials, while additional HF treatment may not provide further benefit. These findings highlight the importance of considering both material characteristics and test configuration when interpreting laboratory bond strength data. Full article
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14 pages, 4278 KB  
Article
Study on the Wear Resistance of Laser Cladding h-BN Reinforced by TiCN/Ni-Based Coating on TC4 Alloy Surface
by Yu Liu, Guohui Li, Ruoyu Xu, Hui Liang, Nan Ma and Zhanhui Zhang
Coatings 2026, 16(4), 490; https://doi.org/10.3390/coatings16040490 - 18 Apr 2026
Viewed by 60
Abstract
Three Ni-based composite coatings with varying TiCN/h-BN contents were fabricated on the surface of Ti-6Al-4V (TC4) alloy by laser cladding. The coatings were formulated with a fixed 15% TiCN and 0%, 2% and 5% h-BN, corresponding to L1–L3 coatings. The microstructure and phase [...] Read more.
Three Ni-based composite coatings with varying TiCN/h-BN contents were fabricated on the surface of Ti-6Al-4V (TC4) alloy by laser cladding. The coatings were formulated with a fixed 15% TiCN and 0%, 2% and 5% h-BN, corresponding to L1–L3 coatings. The microstructure and phase composition were fully characterized and investigated. In addition, the microhardness and wear resistance of the coating were evaluated too. The analysis revealed that the L1–L3 coatings primarily consisted of Ti, TiNi, Ti(C, N) and TiAl3 phases. Microstructural analysis indicated that the top region of the coating was predominantly composed of granular crystals, while the middle and bonding regions featured a combination of dendrites and white granular crystals. The average microhardness values for the L1–L3 coatings were measured at 1203.8, 1216.8 and 1235.5 HV0.2, respectively, while the corresponding wear volumes were 0.098, 0.094 and 0.086 mm3. As the h-BN content increased, the microstructure of the Ni-based composite coating became finer and finer. Some TiB particles were also generated in the coating, which made the average microhardness and wear resistance increase gradually. Notably, the coating with 5% h-BN demonstrated the highest average microhardness and optimal wear resistance. Compared with the substrate, 5% h-BN increased the wear resistance of the substrate by 47.6%. The primary wear mechanism observed was abrasive wear. Full article
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14 pages, 2117 KB  
Proceeding Paper
Cutting Performance and Damage Metrics in Abrasive Waterjet Machining of Delrin–Ramie Fiber Composites
by Natarajan Senthilkumar, Subramanian Thirumalvalavan, Saminathan Selvarasu and Ganapathy Perumal
Eng. Proc. 2026, 130(1), 8; https://doi.org/10.3390/engproc2026130008 - 17 Apr 2026
Viewed by 64
Abstract
In this study, Delrin® (POM) polymer was reinforced with 15 wt.% chopped ramie fiber (RF) to develop a sustainable composite, which was injection-molded and machined using abrasive waterjet machining (AWJM). SEM revealed a skin-core morphology with flow-induced RF alignment and small voids [...] Read more.
In this study, Delrin® (POM) polymer was reinforced with 15 wt.% chopped ramie fiber (RF) to develop a sustainable composite, which was injection-molded and machined using abrasive waterjet machining (AWJM). SEM revealed a skin-core morphology with flow-induced RF alignment and small voids at bundle crossovers, indicating interfacial adhesion. A Taguchi L9 (33) design evaluated waterjet pressure (WJP: 100–300 MPa), traverse speed (TS: 100–200 mm/min), and stand-off distance (SoD: 1–3 mm) on kerf width (KW) and surface roughness (SR). Increasing WJP from 100 to 300 MPa lowered mean SR from 6.23 to 4.80 µm (23% reduction) and KW from 1.31 to 1.07 mm (reduction of 18%); enlarging SoD from 1 to 3 mm raised SR from 4.98 to 5.55 µm (an 11% increase) and KW from 1.12 to 1.20 mm (a of 7% increase); and raising TS from 100 to 200 mm/min narrowed KW from 1.24 to 1.11 mm (a 10.5% reduction) with a modest SR decrease from 5.45 to 5.28 µm. ANOVA confirmed WJP as the dominant factor for SR (79.8%), as well as a significant SoD (18.3%). For KW, the influence of WJP (68.8%) was substantial, followed by TS (19.9%) and SoD (11%). Linear models captured the trends well (SR: R2 = 88.29%; KW: R2 = 93.36%). A desirability-based multi-response optimizer yielded ideal conditions for TS (200 mm/min), WJP (300 MPa), and SoD (1 mm), predicting a KW of 0.94 mm and an SR of 4.1567 µm. Confirmation tests produced a KW (0.970 ± 0.01 mm) and SR (4.27 ± 0.05 µm), which are within 3.19% and 2.73% of the predicted values, validating the DoE regression approach. Full article
(This article belongs to the Proceedings of The 19th Global Congress on Manufacturing and Management (GCMM 2025))
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14 pages, 372 KB  
Article
Probing Short-Range Nucleon–Nucleon Correlations by Detecting Spectator Neutrons in Collider Experiments
by Aleksandr Svetlichnyi, Savva Savenkov, Polina Iusupova and Igor Pshenichnov
Universe 2026, 12(4), 118; https://doi.org/10.3390/universe12040118 - 17 Apr 2026
Viewed by 177
Abstract
We investigate whether short-range nucleon–nucleon correlations (NN-SRC) and cluster configurations in nuclei can be explored by studying spectator neutrons produced in high-energy nucleus–nucleus collisions. In particular, we propose to measure the multiplicity distributions of forward spectator neutrons in symmetric 12C–12C [...] Read more.
We investigate whether short-range nucleon–nucleon correlations (NN-SRC) and cluster configurations in nuclei can be explored by studying spectator neutrons produced in high-energy nucleus–nucleus collisions. In particular, we propose to measure the multiplicity distributions of forward spectator neutrons in symmetric 12C–12C and 40Ca–40Ca collisions at sNN=11 GeV with the Spin Physics Detector (SPD) at the NICA facility. To assess this method, we simulate the production of spectator nucleons in these reactions using the Abrasion–Ablation Monte Carlo for Colliders model with MST clustering (AAMCC-MST). Short-range nucleon–nucleon correlations inside 12C and 40Ca are implemented via a Monte Carlo rejection sampling procedure. Our results indicate that spectator production exhibits only a weak dependence on the specific features of NN-SRC. We also observe that including α-cluster configurations in 12C leads to a reduction of the average multiplicity of spectator neutrons as a function of collision centrality. Full article
(This article belongs to the Special Issue Relativistic Heavy-Ion Collisions: Theory and Observation)
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19 pages, 5925 KB  
Article
Femtosecond Laser-Engineered Sustainable Glass Surfaces with Tunable Wettability Properties for Photovoltaic System Applications
by Emil Filipov, Liliya Angelova, Aleksandra Zhelyazkova and Albena Daskalova
Nanomaterials 2026, 16(8), 475; https://doi.org/10.3390/nano16080475 - 17 Apr 2026
Viewed by 173
Abstract
This study investigates the femtosecond laser surface texturing approach to tune the wetting properties of glass substrates applied for photovoltaic panels. Two types of microstructured LIPSS-containing motifs—parallel channels and intersecting (crossing) patterns—were fabricated and evaluated through comprehensive durability tests, including thermal cycling, UV [...] Read more.
This study investigates the femtosecond laser surface texturing approach to tune the wetting properties of glass substrates applied for photovoltaic panels. Two types of microstructured LIPSS-containing motifs—parallel channels and intersecting (crossing) patterns—were fabricated and evaluated through comprehensive durability tests, including thermal cycling, UV exposure, chemical immersion, mechanical abrasion, and dust retention assessment. Wettability measurements showed that both textures exhibit stable hydrophilicity behavior, with the intersecting patterns exhibiting the fastest wetting dynamics; in many cases, complete surface wetting occurred within the first few minutes, preventing a measurable contact angle at later stages. The durability tests caused only minor smoothing of the textured features, and the overall micro- and nanostructures remained intact. Optical characterization revealed that the laser-induced textures maintained high transmittance with no significant degradation after environmental exposure. Overall, the results demonstrate that femtosecond laser texturing provides a robust, coating-free method for producing stable and tunable wetting behavior on glass, offering a promising pathway for the future creation of durable, highly hydrophilic self-cleaning surfaces in photovoltaic systems. Full article
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21 pages, 3725 KB  
Article
Functionalization of the Surface of Ti6Al4V Alloy Samples Printed Using Additive Technology DMLS for Orthopedic Applications Using Glow Discharge Treatment
by Gabriela Wielgus, Wojciech Kajzer, Julia Lisoń-Kubica, Aleksandra Żurawska, Jakub Wężowicz, Tomasz Borowski, Bogusława Adamczyk-Cieślak and Anita Kajzer
Materials 2026, 19(8), 1604; https://doi.org/10.3390/ma19081604 - 16 Apr 2026
Viewed by 143
Abstract
Previous studies of nitrogen and carbonitride layers on titanium alloys have mainly focused on cast or wrought materials. These traditional manufacturing methods are increasingly being replaced by additive methods, which allow the geometry of the manufactured product to be personalized. In the case [...] Read more.
Previous studies of nitrogen and carbonitride layers on titanium alloys have mainly focused on cast or wrought materials. These traditional manufacturing methods are increasingly being replaced by additive methods, which allow the geometry of the manufactured product to be personalized. In the case of multi-component structures, and implant systems in particular, the hardness and abrasion resistance of the surface are insufficient. Therefore, these surfaces must be modified to improve these properties. Therefore, the aim of this work was to evaluate the properties of surface-modified Ti64 ELI alloy samples produced by the additive Direct Metal Laser Sintering method. To increase the hardness and abrasion resistance of the surface, a diffusion layer of TiN was produced under glow discharge conditions on samples previously heat-treated at temperatures of 800 °C, 910 °C, and 1020 °C. Since these implants remain in the body, it is important to sterilize them beforehand. Therefore, this study included samples after steam sterilization, and the results were compared to unsterilized samples. This study evaluated the structure of the material, the phase composition of the layer, the topography and wettability of the surface, along with the surface energy (before sterilization θav > 106°), resistance to pitting corrosion, hardness, and tribological properties. Full article
(This article belongs to the Section Metals and Alloys)
21 pages, 2694 KB  
Article
Tribological Performance Study and Simulation Analysis of Anti-Adhesive Wear PEEK Composite Coatings
by Xiangdian Wang, Zhijun Yan, Dahong Zeng and Keliang Dong
Appl. Sci. 2026, 16(8), 3853; https://doi.org/10.3390/app16083853 - 15 Apr 2026
Viewed by 202
Abstract
PEEK coatings have been applied to sliding bearings in marine machinery and equipment, but their low bonding force, poor thermal conductivity and weak oleophilicity result in insufficient anti-adhesive wear performance. To solve this problem, the textured surface of the substrate was fabricated using [...] Read more.
PEEK coatings have been applied to sliding bearings in marine machinery and equipment, but their low bonding force, poor thermal conductivity and weak oleophilicity result in insufficient anti-adhesive wear performance. To solve this problem, the textured surface of the substrate was fabricated using laser texturing technology to enhance the bonding force. The PEEK coatings were reinforced by introducing oleophilic-modified nano-SiO2 and graphene. The tribological properties of the PEEK composite coatings were studied using the ball–disc reciprocating friction wear test and Abaqus wear simulation. The results show that the texturing treatment of the substrate surface improves the bonding force of the coating. The addition of nano-SiO2 and graphene enhances the hardness, thermal conductivity and oleophilicity of the composite coating, which shifts the wear mechanism from adhesive to abrasive. Under dry friction conditions, the composite coating containing 5 wt% SiO2 and 1 wt% graphene exhibits a low friction coefficient and the lowest wear rate. Under oil lubrication conditions, the composite coating containing 2 wt% graphene shows the lowest friction coefficient and wear rate. In summary, under the load-bearing capacity enhancement of nano-SiO2 and the thermal conductivity enhancement of graphene, the composite coating exhibits excellent anti-adhesive wear performance. Full article
15 pages, 5441 KB  
Article
A Simple and Scalable Two-Step Process for Durable Hydrophobic and Stain-Resistant Leather Coatings
by Susana A. F. Neves, Silvia Pinho, Manuel F. Almeida, Maria A. Lopes and Carlos Fonseca
Coatings 2026, 16(4), 471; https://doi.org/10.3390/coatings16040471 - 15 Apr 2026
Viewed by 172
Abstract
There is a strong and growing need for low environmental impact, fluorine-free finishes that deliver durable water repellency and stain resistance to leather while preserving its original appearance. This work successfully addresses this need by introducing a simple, robust, and scalable two-step coating [...] Read more.
There is a strong and growing need for low environmental impact, fluorine-free finishes that deliver durable water repellency and stain resistance to leather while preserving its original appearance. This work successfully addresses this need by introducing a simple, robust, and scalable two-step coating strategy that endows leather surfaces with excellent hydrophobic and self-cleaning properties. The process relies on a straightforward spray application of functionalized silica nanoparticles followed by a hydrophobic silane, namely hexadecyltrimethoxysilane (HDTMS), enabling precise control over surface properties through the number of applied layers. Comprehensive characterization by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM–EDS) confirmed the effective formation and uniformity of the coating. Performance testing demonstrated excellent functional outcomes: the optimized coating achieved a water contact angle (WCA) of 128° and maintained values above 125° even after abrasion, highlighting its durability. Treated leather exhibited resistance to common liquid stains such as tea and coffee, maintaining a clean surface. These functional gains were achieved without compromising the leather’s natural look or soft feel, even after multiple coating cycles. This work delivers a fluorine-free solution offering an effective route to high-value water- and stain-resistant leather finishes that respect both environmental and aesthetic requirements. Full article
(This article belongs to the Section Composite Coatings)
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15 pages, 3002 KB  
Article
Effect of Adhesive Type and Surface Preparation on the Debonding Behavior of Glass and Carbon Fiber Reinforced Epoxy Adhesive Joints
by Paula Vigón, Antonio Argüelles, Miguel Lozano and Jaime Viña
Materials 2026, 19(8), 1561; https://doi.org/10.3390/ma19081561 - 14 Apr 2026
Viewed by 274
Abstract
In this work, the debonding behavior under quasi-static Mode I fracture loading of adhesive joints made on two types of composite materials with the same epoxy matrix and unidirectional carbon or glass fiber reinforcement was analyzed. Standard DCB tests were used to quantify [...] Read more.
In this work, the debonding behavior under quasi-static Mode I fracture loading of adhesive joints made on two types of composite materials with the same epoxy matrix and unidirectional carbon or glass fiber reinforcement was analyzed. Standard DCB tests were used to quantify the influence of adhesive type and substrate surface preparation on interlaminar fracture toughness. For the fabrication of the joints under study, three commercial structural adhesives from different manufacturers were selected, two epoxy-based and one acrylic-based. Substrate surface preparation was carried out using three different procedures: manual abrasion, sanding with P220 Al2O3 sandpaper, grit blasting with Al2O3, and peel ply PA80 polyamide fabric. The experimental results revealed the same trend for both epoxy-based adhesives: sanding provided the best results, regardless of the substrate used. Surface preparation by grit blasting proved highly sensitive to the applied parameters, generally yielding poorer results than manual sanding. Surface preparation using PA80 peel ply fabric may be a viable option. However, its main drawback is that it must be incorporated during composite manufacturing. The results demonstrate that fracture performance is governed by the interaction between adhesive chemistry and surface morphology rather than by surface roughness alone. Full article
(This article belongs to the Special Issue Mechanical Behavior of Composite Materials (4th Edition))
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19 pages, 19846 KB  
Article
Influence of Microstructure Evolution on Tribological and Corrosion Performances of QPQ-Treated 40Cr Steel
by Jingtao Yang, Chengyuan Ni, Sen Feng, Chengdong Xia and Minghua Yin
Materials 2026, 19(8), 1557; https://doi.org/10.3390/ma19081557 - 13 Apr 2026
Viewed by 341
Abstract
Quench–polish–quench (QPQ) of 40Cr steel was performed to improve its tribological properties and corrosion resistance, thereby enhancing the service performance of components such as gears and bearings. The 40Cr steel was treated by QPQ at 580 °C and 620 °C for 90 or [...] Read more.
Quench–polish–quench (QPQ) of 40Cr steel was performed to improve its tribological properties and corrosion resistance, thereby enhancing the service performance of components such as gears and bearings. The 40Cr steel was treated by QPQ at 580 °C and 620 °C for 90 or 120 min. Optical microscopy (OM, Sunny Group, Ningbo, China), scanning electron microscopy (SEM, Hitachi, Tokyo, Japan), and X-ray diffraction (XRD Rigaku Corporation, Tokyo, Japan) were used to characterise the microstructure and phase constitution. Ball-on-disk tribometry, electrochemical tests, and salt spray tests in 3.5 wt.% NaCl evaluated surface performance. At 580 °C, a composite structure of Fe3O4 and ε-Fe2−3N formed on the surface. When the temperature rose to 620 °C, ε-Fe2–3N gradually transformed into γ′-Fe4N. Within the scope of this study, the diffusion layer depth exhibits an approximately linear relationship with increasing processing temperature and holding time, and the surface hardness is 67–112% higher than that of the untreated sample. After QPQ treatment, the wear mechanism changed from adhesive wear to abrasive wear. However, under the treatment conditions of 620 °C × 120 min, brittle surface spalling increased roughness, thereby increasing the coefficient of friction. As treatment time increases, nitrogen atoms continue to diffuse outward as Fe2N transforms to the γ′ phase. This increases the composite layer’s porosity and decreases its corrosion resistance. The best corrosion resistance was observed at 580 °C for 120 min, with a corrosion potential of −0.4325 V, corrosion current density of 1.80 × 10−6 A·cm−2, and polarisation resistance of 24,500 Ω. Corrosion performance depends on overall surface integrity. Porosity morphology strongly influences this property. For 40Cr steel, the results show that surface properties are primarily determined by the quality of the compound layer’s microstructure. Specifically, density, phase-composition stability, and defect control are more important than the commonly held view of layer thickness. Full article
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17 pages, 3717 KB  
Article
Two-Step Polishing Technique for Flat and Smooth Copper Substrates by Electrochemical and Chemical Etching
by Ke Wang, Xinghua Chen, Boju Hou, Peng Xu, Yufei Li, Xutong Liu, Huirong Shi, Ming Zhang and Hongding Wang
Micromachines 2026, 17(4), 466; https://doi.org/10.3390/mi17040466 - 12 Apr 2026
Viewed by 218
Abstract
Methods of single-point diamond turning and chemical mechanical polishing can achieve an ultra-flat substrate. However, these methods which rely on mechanical interactions to achieve material removal can easily lead to defects such as abrasive embedding and scratches on the surface. In addition, for [...] Read more.
Methods of single-point diamond turning and chemical mechanical polishing can achieve an ultra-flat substrate. However, these methods which rely on mechanical interactions to achieve material removal can easily lead to defects such as abrasive embedding and scratches on the surface. In addition, for low-rigidity and thin-plate workpieces, clamping deformation and force deformation are critical factors affecting the machining accuracy. This paper proposes a two-step polishing chain that uses controllable electrochemical and chemical etching to correct the shape error of the workpiece. With the optimized parameters, the jet electrochemical machining (Jet-ECM), which uses the electrochemical etching mechanism, is applied to the computer-controlled optical surfacing (CCOS) to achieve the rapid convergence of the shape accuracy. In addition, electrogenerated chemical polishing (EGCP) is implemented as a follow-up process which uses the mechanism of diffusion-controlled chemical etching to reduce the mid-spatial-frequency (MSF) error caused by the computer-controlled optical surfacing. Based on this two-step polishing chain and the self-developed devices, the peak-to-valley (PV) value of the φ 50 mm workpiece (valid dimensions = 90% of the central region) is reduced from 2.678 μm to 0.384 μm. This study has great implications for further understanding the mechanism of Jet-ECM and EGCP, which expands the applications of stress-free polishing to solve the processing problems of the low-rigidity workpiece. Full article
(This article belongs to the Section E:Engineering and Technology)
24 pages, 14732 KB  
Article
Mechanism of Tungsten Film Adhesion Enhancement on Alumina Ceramics via Microgroove Spacing During Multi-Abrasive Scratching
by Xue Yang, Jiayi Wu, Wenlong Liu, Wenhao Ma and Chen Jiang
Micromachines 2026, 17(4), 465; https://doi.org/10.3390/mi17040465 - 11 Apr 2026
Viewed by 210
Abstract
During the high-temperature deposition of tungsten thin films on alumina ceramic substrates, the inherent mismatch in thermal expansion coefficients frequently triggers interfacial delamination, where uncontrollable factors in stochastic surface topographies can exacerbate localized stress concentrations. To resolve these interfacial failures, the enhancement of [...] Read more.
During the high-temperature deposition of tungsten thin films on alumina ceramic substrates, the inherent mismatch in thermal expansion coefficients frequently triggers interfacial delamination, where uncontrollable factors in stochastic surface topographies can exacerbate localized stress concentrations. To resolve these interfacial failures, the enhancement of interfacial adhesion through a deterministic surface microgroove design is identified as the general objective of the present research. Within this framework, the establishment of a robust quantitative mapping between the transverse scratching offset distances and the resultant periodic microgeometry is first pursued as a specific experimental objective. This methodological approach effectively transforms the stochastic nature of the substrate into deterministic geometric configurations. Second, a specific numerical objective is fulfilled by evaluating the interfacial stress redistribution and damage evolution utilizing refined thermomechanical coupled simulations based on the cohesive zone model. The integrated findings demonstrate that optimizing the microgroove spacing effectively governs the morphological transition and broadens stress diffusion pathways to mitigate thermal mismatch effects. Specifically, the structural optimization at a spacing of 28.8 µm facilitates an approximately 31.8% reduction in the maximum interfacial stress and a 10% decrease in the average film stress compared to the 13.6 µm spacing. Finally, this research clarifies the underlying mechanisms of stress buffering and provides a rigorous engineering methodology for the structural design of reliable high-performance ceramic–metal interfaces in extreme environments. Full article
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