Search Results (498)

Color is a primary determinant of the value of jadeite jade, but the petrological provenance of the chromogenic elements of jadeite jade remains uncertain. The characteristics of the associated chromite in Myanmar jadeite jade were systematically investigated through a series of tests, including polarized microscopy, microarea X-ray fluorescence spectroscopy (micro-XRF) mapping, electron probe microanalysis (EPMA), and backscattered electron (BSE) imaging. The results demonstrate that the chromite composition in Myanmar jadeite jade is characterized by a high concentration of Cr₂O₃ (46.18–67.11 wt.%), along with a notable abundance of MnO (1.68–9.13 wt.%) compared with the chromite from the adjacent Myitkyina peridotite. The diffusion of chromium (Cr) and manganese (Mn) in jadeite jade is accomplished by accompanying the metamorphic pathway of Mn-rich chromite → kosmochlor → chromian jadeite → jadeite. In the subsequent phase of jadeite jade formation, the chromium-rich omphacite veins generated by the fluid enriched in Ca and Mg along the fissures of kosmochlor and chromian jadeite play a role in the physical diffusion of Cr and Mn. The emergence of the lavender hue in jadeite is contingent upon the presence of a relatively high concentration of Mn (approximately 100–1000 ppmw) and the simultaneous absence of Cr, which would otherwise serve as a more effective chromophore (no Cr or up to a dozen ppmw). The distinctive Mn-rich chromite represents the primary origin of the chromogenic element Cr (green) and, perhaps more notably, an overlooked provider of Mn (lavender) in Myanmar jadeite jade. Full article

The effects of trace Ce on the microstructure and texture of non-oriented silicon steel during recrystallization and grain growth were examined using X-ray diffraction and electron backscatter diffraction. Additionally, this study focused on investigating the mechanisms by which trace Ce influences the evolution of the {114} <481> and γ-fiber textures. During the recrystallization process, as the recrystallization fraction of annealed sheets increased, the intensity of α-fiber texture decreased, while the intensities of α*-fiber and γ-fiber textures increased. The {111} <112> grains preferentially nucleated in the deformed γ-grains and their grain-boundary regions and tended to form a colony structure with a large amount of nucleation. In addition, the {100} <012> and {114} <481> grains mainly nucleated near the deformed α-grains, which were evenly distributed but found in relatively small quantities. The hindering effect of trace Ce on dislocation motion in cold-rolled sheets results in a 2–7% lower recrystallization ratio for the annealed sheets, compared to conventional annealed sheets. Trace Ce suppresses the nucleation and growth of γ-grains while creating opportunities for α*-grain nucleation. During grain growth, trace Ce reduces γ-grain-boundary migration rate in annealed sheets, providing growth space for {114} <418> grains. Consequently, the content of the corresponding {114} <481> texture increased by 6.4%, while the γ-fiber texture content decreased by 3.6%. Full article

This study investigates the influence of plastic deformation and temperature on the formation of mechanically induced martensite and the associated changes in hardness in AISI 304 austenitic stainless steel. Cold rolling was performed at three temperatures (20 °C, 0 °C, and −196 °C) and various degrees of deformation (10–70%). Microstructural changes, including the formation of ε and α′ martensite, were characterized using X-ray diffraction (XRD) and electron backscatter diffraction (EBSD). The results confirm that martensitic transformation proceeds via the γ → ε → α′ sequence, with transformation rates and martensite fractions increasing at lower temperatures and higher strains. The stacking fault energy of 25.9 mJ/m² favors this transformation pathway. Transformation rates of α′ martensite fractions significantly increased at lower temperatures and higher strains, 91.8% α′ martensite was observed at just 30% deformation at −196 °C. Hardness measurements revealed a strong correlation with martensite content: strain hardening dominated at lower deformations, while martensite formation became the primary hardening mechanism at higher deformations, especially at cryogenic temperatures. The highest hardness (551 HV) was observed in samples deformed to 70% at −196 °C. The findings provide insights into optimizing the mechanical properties of AISI 304 stainless steel through controlled deformation and temperature conditions. Full article

This work provides a comprehensive investigation into the synergistic effects of zirconium and oxygen on the microstructural evolution, high-temperature oxidation resistance, and mechanical properties of γ-phase Ti52AlxZr alloys (x = 0, 0.5, 1, and 2 at.%) under systematically controlled oxygen concentrations. Unlike prior studies that have examined these alloying elements in isolation, this study uniquely decouples the contributions of interstitial (oxygen) and substitutional (zirconium) solutes by employing low (LOx) and high (HOx) oxygen levels. Alloys were synthesized via vacuum arc melting and subsequently subjected to homogenization annealing at 1250 °C for 100 h to ensure phase and microstructural stability. Characterization techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD), and electron backscatter diffraction (EBSD) were employed to elucidate phase constitution and grain morphology. Zirconium addition was found to stabilize the γ-TiAl matrix, suppress α₂-phase formation, and promote grain coarsening in LOx specimens. Conversely, elevated oxygen concentrations led to α₂-phase precipitation along grain boundaries. Mechanical testing, comprising Vickers hardness and uniaxial compression at ambient and elevated temperatures (800 °C), revealed that both zirconium and oxygen significantly enhanced strength and hardness, with Ti52Al2Zr delivering optimal mechanical performance. Moreover, zirconium substantially improved oxidation resistance by promoting the formation of a thinner, adherent Al₂O₃ scale while simultaneously inhibiting TiO₂ growth. Collectively, the findings demonstrate the critical role of zirconium in engineering advanced γ-TiAl-based intermetallics with superior high-temperature structural integrity and oxidation resistance. Full article

This investigation implemented an integrated aging–cryogenic thermal processing method for extruded Mg-8Gd-3Y-0.4Zr alloy to further improve its performance and broaden its scope of application, employing a characterization approach combining optical microscopy (OM), electron backscatter diffraction (EBSD), X-ray diffraction (XRD), and transmission electron microscopy (TEM). The comprehensive microstructure characterization was systematically correlated with mechanical property evolution to establish structure–property relationships. The results show that aging combined with cryogenic treatment significantly enhances the hardness and improves the microstructure of magnesium alloys. Specimens aged at 210 °C for 20 h followed by one-hour cryogenic treatment exhibited the highest average hardness (113.5 HV), representing a 11.2–25% improvement compared to those aged at lower temperatures. This enhancement can be attributed to the elevated aging temperature promoting substantial precipitation and subsequent growth of second phases such as Mg₃(Gd,Y), which benefit from sufficient thermal activation energy. The increased density and larger dimensions of these second phases contribute to enhanced hardness through elevated internal stress generation. However, their non-uniform distribution may induce localized stress concentration, consequently reducing hardness uniformity. Notably, specimens subjected solely to 210 °C aging for 20 h showed marginally lower hardness compared to their cryogenically treated counterparts, suggesting that although cryogenic treatment may refine grain structures and introduce dislocation defects to enhance hardness, its concurrent reduction in residual stresses might limit the overall improvement magnitude. Full article

This study proposes a novel non-destructive methodology for assessing structural integrity in liquefied natural gas (LNG) carrier cargo containment systems (CCSs), addressing limitations of conventional inspection techniques like visual inspection and vacuum box testing. The method leverages strain-induced martensitic transformation (SIMT) in austenitic stainless steel (SUS304L), widely used in CCS membranes, quantifying magnetic permeability increase via a Feritscope to evaluate deformation history and damage. To analyze SUS304L SIMT behavior, uniaxial tensile (UT) and equi-biaxial tensile (EBT) tests were conducted, as these stress states predominate in CCS membranes. Microstructural evolution was examined using X-ray diffraction (XRD) and electron backscatter diffraction (EBSD), allowing a quantitative assessment of the transformed martensite volume fraction versus plastic strain. Subsequently, Feritscope measurements under the same conditions were calibrated against the XRD-measured martensite volume fraction for accuracy. Based on testing, this study introduces three complementary Feritscope approaches for evaluating CCS health: outlier detection, quantitative damaged area analysis, and time-series analysis. The methodology integrates data-driven quantitative assessment with conventional qualitative inspection, enhancing safety and maintenance efficiency. Full article

Bending fatigue significantly affects the mechanical stability and lifespan of biomedical implants, such as bone plates and orthopaedic fixation devices, which undergo cyclic loading in the human body. This study examines the microstructure, porosity, and bending fatigue properties of PBF-LB/M SS316L. Samples were analysed across three faces (top, front, and side) using optical microscopy (OM) and scanning electron microscopy (SEM) to observe microstructural features and porosity. Elemental composition was measured by energy-dispersive X-ray spectroscopy (EDX). Phase structures and grain orientations were characterised via X-ray diffraction (XRD) and electron backscatter diffraction (EBSD). Four-point bending fatigue tests, conducted under two loading conditions, below and slightly above the yield point, demonstrated that defects inherent to the PBF-LB/M process, particularly micropores and unmelted powder particles, strongly influence fatigue crack initiation. Real-time monitoring of crack initiation and propagation on the external sample surface was performed using a high-speed digital microscope. These findings indicate the influence of microstructural defects on fatigue performance in PBF-LB/M SS316L, supporting the design and development of more reliable patient-specific biomedical implants. Full article

High-sensitivity fiber scintillator detectors are the key to achieving high signal-to-noise ratio and high contrast imaging in X-ray Compton backscattering technology. We established a simulation model of wavelength-shifting fiber (WSF) scintillator detectors based on Geant4. The influences of ray source energy, detection area, number of WSFs, and coupling mechanism on detection efficiency were simulated. By using the epoxy resin coupling method, the transmission efficiency between the WSF and scintillator was increased from 4.56% to 19.79%. Based on the simulation data, we developed an X-ray WSFs scintillator detector, built an X-ray backscattering imaging experimental system, obtained high-contrast backscattering images, and verified the performance of the detector. Full article

Hessonite, a special variety of grossularite, is well-known for the heat-wave effect, which is a characteristic swirled or roiled interior appearance within the crystal. Although the heat-wave effect has been observed for a long time, it has not been studied in depth. In this study, the gemological properties, mineral compositions, fabric characteristics, and grain sizes of hessonite samples were investigated using infrared spectroscopy, electron backscatter diffraction (EBSD), and energy-dispersive X-ray spectroscopy (EDS). Hessonite exhibits the heat-wave effect and is found to be polycrystal rather than single-crystal, composed of submillimeter-sized granules with random orientation and limited variations in Fe and Al contents. Abundant micropores exist among the granules, indicating imperfect contact among them. Due to these structural features, incident light is interrupted and undergoes changes in direction and speed as it passes through the hessonite granules, grain borders, and micropores. Light reflects off the granules’ surfaces and refracts within the granules, respectively, causing the incident light to swirl and roil within the hessonite and form the heat-wave effect. This study considers that the heat-wave effect is a special optical phenomenon not caused by impurity minerals or inclusions. Full article

BaBiO₃ has recently gained significant research attention as a parent material for an interesting family of alloyed compositions with multiple technological applications. In order to grow a variety of structures, a versatile deposition tool such as molecular beam epitaxy must be employed. In this work, the molecular beam epitaxy growth of BaBiO₃ on SrTiO₃(001) and MgO(001) substrates is studied. When grown by molecular beam epitaxy on SrTiO₃(001) or MgO(001) substrates, BaBiO₃ is known to have two competing orientations, namely (001) and (011). Characterization of the thin film is carried out by X-ray diffraction, X-ray reflectivity, atomic force microscopy, Rutherford backscattering, and transmission electron microscopy. Pathways to block the growth of BaBiO₃(011) and to grow only the technologically relevant BaBiO₃(001) are described for both substrates. An understanding of the enabling mechanism of the co-growth is established from an epitaxial point of view. This can be beneficially utilized for the growth of different compositions in the BaBiO₃ material family in a more controlled manner. Full article

Under the dual impetus of environmental regulations and reliability requirements, the Pb–free/Pb hybrid assembly process in aerospace-grade ball grid array (BGA) components has become an unavoidable industrial imperative. However, constrained process compatibility during single or multiple reflow protocols amplifies structural heterogeneity in solder joints and accelerates dynamic microstructural evolution, thereby elevating interfacial reliability risks at solder joint interfaces. This paper systematically investigated phase composition, grain dimensions, thickness evolution, and crystallographic orientation patterns of interfacial intermetallic compounds (IMCs) in hybrid micro-solder joints under multiple reflows, employing electron backscatter diffraction (EBSD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). The result shows that the first reflow induces prismatic Cu₆Sn₅ grain formation driven by Pb aggregation zones and elevated Cu concentration gradients. Surface-protruding fine grains significantly increase kernel average misorientation (KAMave) of 0.68° while minimizing crystallographic orientation preference density (PF_max) of 15.5. Higher aspect ratios correlate with elongated grain morphology, consequently elevating grain size of 5.3 μm and IMC thickness of 5.0 μm. Subsequent reflows fundamentally alter material dynamics: Pb redistribution transitions from clustered to randomized spatial configurations, while grains develop pronounced in-plane orientation preferences that reciprocally influence Sn crystal alignment. The second reflow produces scallop-type grains with minimized dimensions of 4.0 μm and a thickness of 2.1 μm, with a KAMave of 0.37° and PF_max of 20.5. The third reflow initiates uniform growth of scalloped grains of 7.0 μm with a stable population density, whereas the fifth reflow triggers a semicircular grain transformation of 9.1 μm through conspicuous coalescence mechanisms. This work elucidates multiple reflow IMC growth mechanisms in Pb–free/Pb hybrid solder joints, providing critical theoretical and practical insights for optimizing hybrid technologies and reliability management strategies in high-reliability aerospace electronics. Full article

The significant phase transformation hysteresis in TiNi alloys limits their performance. To address this, copper (Cu) was added as an alloying element to reduce hysteresis. This study synthesized three compositions of Ti₅₀Ni_50−xCu_x (x = 0, 5, 7 at.%) shape memory alloys (SMAs) via vacuum arc melting to optimize the Cu content. The alloys were homogenized through hot rolling to maintain stable mechanical and shape memory properties. The hot-rolled Ti₅₀Ni₄₅Cu₅ alloy demonstrated excellent shape memory behavior, achieving 100% thermal recovery after one cycle at 4% and 6% strain and 99.2% recovery after six cycles at 4% strain. It also exhibited outstanding mechanical performance, with a tensile strength of 900 MPa and 40% elongation. Microscopic analysis using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS), electron backscatter diffraction (EBSD), and transmission electron microscopy (TEM) revealed that Cu preferentially segregates at grain boundaries, suppressing the formation of the Ti₂(Ni,Cu) phase. This moderate segregation, combined with hot rolling, promotes the reprecipitation and uniform distribution of phases, reducing the likelihood of premature fracture caused by stress concentration during deformation. The moderate thickness and uniformly distributed martensite, as well as the Type II twins with strong deformation ability, significantly improved the shape memory properties of Ti₅₀Ni₄₅Cu₅. This study provides valuable insights into the microscopic mechanisms influenced by Cu in TiNi alloys and proposes a novel strategy for controlling precipitate phases through adjustments in alloy composition and optimized processing conditions. Full article

Advanced packaging represents a crucial technological evolution aimed at overcoming limitations posed by Moore’s Law, driving the semiconductor industry from two-dimensional toward three-dimensional integrated structures. The increasing complexity and miniaturization of electronic devices have significantly heightened the challenges associated with failure analysis during process development. The focused ion beam–scanning electron microscope (FIB-SEM), characterized by its high processing precision and exceptional imaging resolution, has emerged as a powerful solution for the fabrication, defect localization, and failure analysis of micro- and nano-scale devices. This paper systematically reviews the innovative applications of FIB-SEM in the research of core issues, such as through-silicon-via (TSV) defects, bond interfacial failures, and redistribution layer (RDL) electromigration. Additionally, the paper discusses multimodal integration strategies combining FIB-SEM with advanced analytical techniques, such as high-resolution three-dimensional X-ray microscopy (XRM), electron backscatter diffraction (EBSD), and spectroscopy. Finally, it provides a perspective on the emerging applications and potential of frontier technologies, such as femtosecond-laser-assisted FIB, in the field of advanced packaging analysis. Full article

High-purity tantalum plates form inhomogeneous microstructures and texture gradients along the thickness through conventional rolling, which seriously affects the sputtering performance of the target. In this work, tantalum plates with a random microstructure were used on different rolling paths, such as those in unidirectional rolling (UR) and cross rolling (CR). The microstructure of the rolled tantalum plates was characterized using electron backscatter diffraction (EBSD), X-ray diffraction (XRD), and Vickers hardness (HV). The results indicated that the UR specimen exhibited the highest hardness values, with a gradual increase in hardness across the entire thickness layer from the surface to the center. Furthermore, specimens with different rolling directions demonstrated distinct texture gradient distributions throughout the thickness. The unidirectional rolling (UR) sample had a {110} (<110>//ND) texture on the surface and a {111} (<111>//ND) texture on the rest of its thickness. Compared with UR, cross rolling introduces more shear deformation, increases the content of the {100} (<100>//ND) texture, and weakens the {111} texture intensity everywhere except the center region. An increase in the rolling direction is beneficial for weakening the inhomogeneity between microstructures. Full article

The integral welded panel represents a highly promising aircraft structural component, owing to its lightweight design and reduced connector requirements. However, the complexity of its welded structure results in the formation of cross-welded joints. This study systematically investigated the mechanical properties of the cross-welded joints through tensile tests across different welded regions, which were complemented by fracture morphology examination via scanning electron microscopy (SEM). The residual stress distribution was characterized using X-ray diffraction, while electron backscatter diffraction (EBSD) analysis was used to elucidate the relationship between residual stress and microstructure. Key findings revealed that the cross-welded zone exhibited lower yield strength and ductility than the single-welded zone, and the advancing heat-affected zone demonstrated superior tensile properties relative to the retreating side. Residual stress analysis showed that the cross-welded joint lacked the “double peak” profile characteristic and displayed lower maximum residual stress than the single-welded joint. EBSD analysis indicated significant grain elongation in the cross-welded zone due to mechanical forces during the welding process, resulting in higher dislocation density and deformation, corresponding with elevated residual stress levels. Full article