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Search Results (1,463)

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Keywords = Sediment composition

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22 pages, 7156 KiB  
Communication
Water Management, Environmental Challenges, and Rehabilitation Strategies in the Khyargas Lake–Zavkhan River Basin, Western Mongolia: A Case Study of Ereen Lake
by Tseren Ochir Soyol-Erdene, Ganbat Munguntsetseg, Zambuu Burmaa, Ulziibat Bilguun, Shagijav Oyungerel, Soninkhishig Nergui, Nyam-Osor Nandintsetseg, Michael Walther and Ulrich Kamp
Geographies 2025, 5(3), 38; https://doi.org/10.3390/geographies5030038 (registering DOI) - 1 Aug 2025
Abstract
The depletion of water resources caused by climate change and human activities is a pressing global issue. Lake Ereen is one of the ten natural landmarks of the Gobi-Altai of western Mongolia is included in the list of “important areas for birds” recognized [...] Read more.
The depletion of water resources caused by climate change and human activities is a pressing global issue. Lake Ereen is one of the ten natural landmarks of the Gobi-Altai of western Mongolia is included in the list of “important areas for birds” recognized by the international organization Birdlife. However, the construction of the Taishir Hydroelectric Power Station, aimed at supplying electricity to the western provinces of Mongolia, had a detrimental effect on the flow of the Zavkhan River, resulting in a drying-up and pollution of Lake Ereen, which relies on the river as its water source. This study assesses the pollution levels in Ereen Lake and determines the feasibility of its rehabilitation by redirecting the flow of the Zavkhan River. Field studies included the analysis of water quality, sediment contamination, and the composition of flora. The results show that the concentrations of ammonium, chlorine, fluorine, and sulfate in the lake water exceed the permissible levels set by the Mongolian standard. Analyses of elements from sediments revealed elevated levels of arsenic, chromium, and copper, exceeding international sediment quality guidelines and posing risks to biological organisms. Furthermore, several species of diatoms indicative of polluted water were discovered. Lake Ereen is currently in a eutrophic state and, based on a water quality index (WQI) of 49.4, also in a “polluted” state. Mass balance calculations and box model analysis determined the period of pollutant replacement for two restoration options: drying-up and complete removal of contaminated sediments and plants vs. dilution-flushing without direct interventions in the lake. We recommend the latter being the most efficient, eco-friendly, and cost-effective approach to rehabilitate Lake Ereen. Full article
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22 pages, 6820 KiB  
Article
Bathymetric Profile and Sediment Composition of a Dynamic Subtidal Bedform Habitat for Pacific Sand Lance
by Matthew R. Baker, H. G. Greene, John Aschoff, Michelle Hoge, Elisa Aitoro, Shaila Childers, Junzhe Liu and Jan A. Newton
J. Mar. Sci. Eng. 2025, 13(8), 1469; https://doi.org/10.3390/jmse13081469 - 31 Jul 2025
Abstract
The eastern North Pacific Ocean coastline (from the Salish Sea to the western Aleutian Islands) is highly glaciated with relic sediment deposits scattered throughout a highly contoured and variable bathymetry. Oceanographic conditions feature strong currents and tidal exchange. Sand wave fields are prominent [...] Read more.
The eastern North Pacific Ocean coastline (from the Salish Sea to the western Aleutian Islands) is highly glaciated with relic sediment deposits scattered throughout a highly contoured and variable bathymetry. Oceanographic conditions feature strong currents and tidal exchange. Sand wave fields are prominent features within these glaciated shorelines and provide critical habitat to sand lance (Ammodytes spp.). Despite an awareness of the importance of these benthic habitats, attributes related to their structure and characteristics remain undocumented. We explored the micro-bathymetric morphology of a subtidal sand wave field known to be a consistent habitat for sand lance. We calculated geomorphic attributes of the bedform habitat, analyzed sediment composition, and measured oceanographic properties of the associated water column. This feature has a streamlined teardrop form, tapered in the direction of the predominant tidal current. Consistent flow paths along the long axis contribute to well-defined and maintained bedform morphology and margin. Distinct patterns in amplitude and period of sand waves were documented. Strong tidal exchange has resulted in well-sorted medium-to-coarse-grained sediments with coarser sediments, including gravel and cobble, within wave troughs. Extensive mixing related to tidal currents results in a highly oxygenated water column, even to depths of 80 m. Our analysis provides unique insights into the physical characteristics that define high-quality habitat for these fish. Further work is needed to identify, enumerate, and map the presence and relative quality of these benthic habitats and to characterize the oceanographic properties that maintain these benthic habitats over time. Full article
(This article belongs to the Special Issue Dynamics of Marine Sedimentary Basin)
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25 pages, 4302 KiB  
Article
Human Health Risk and Bioaccessibility of Arsenic in Wadis and Marine Sediments in a Coastal Lagoon (Mar Menor, Spain)
by Salvadora Martínez López, Carmen Pérez Sirvent, María José Martínez Sánchez and María Ángeles Esteban Abad
Toxics 2025, 13(8), 647; https://doi.org/10.3390/toxics13080647 (registering DOI) - 30 Jul 2025
Abstract
This study evaluates the potential health risks posed by geogenic arsenic in environments suitable for leisure activities, such as walking, bathing, and playing, for adults and children alike, as well as in neighbouring agricultural areas. The study includes an analysis of environmental characteristics [...] Read more.
This study evaluates the potential health risks posed by geogenic arsenic in environments suitable for leisure activities, such as walking, bathing, and playing, for adults and children alike, as well as in neighbouring agricultural areas. The study includes an analysis of environmental characteristics and the main stream originating in the adjacent mining area, with water and sediment samples taken. The study area is representative of other areas in the vicinity of the Mar Menor Lagoon, which is one of the largest and most biodiverse coastal lagoons in the Mediterranean Sea. The general characteristics of the soil and water were determined for this study, as was the concentration of As in the soil and water samples. A granulometric separation was carried out into four different fractions (<2 mm, <250 µm, <100 µm, and <65 µm). The mineralogical composition, total As content, and bioaccessible As content are analysed in each of these fractions. This provides data with which to calculate the danger of arsenic (As) to human health by ingestion and to contribute to As bioaccessibility studies and the role played by the mineralogical composition and particle size of soil ingestion. The conclusions rule out residential use of this environment, although they allow for eventual tourist use and traditional agricultural use of the surrounding soils. Full article
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18 pages, 8458 KiB  
Article
Exploring the Biosynthetic Potential of Microorganisms from the South China Sea Cold Seep Using Culture-Dependent and Culture-Independent Approaches
by Gang-Ao Hu, Huai-Ying Sun, Qun-Jian Yin, He Wang, Shi-Yi Liu, Bin-Gui Wang, Hong Wang, Xin Li and Bin Wei
Mar. Drugs 2025, 23(8), 313; https://doi.org/10.3390/md23080313 - 30 Jul 2025
Abstract
Cold seep ecosystems harbor unique microbial communities with potential for producing secondary metabolites. However, the metabolic potential of cold seep microorganisms in the South China Sea remains under-recognized. This study employed both culture-dependent and culture-independent approaches, including 16S rRNA amplicon sequencing and metagenomics, [...] Read more.
Cold seep ecosystems harbor unique microbial communities with potential for producing secondary metabolites. However, the metabolic potential of cold seep microorganisms in the South China Sea remains under-recognized. This study employed both culture-dependent and culture-independent approaches, including 16S rRNA amplicon sequencing and metagenomics, to investigate microbial communities and their potential for secondary metabolite production in the South China Sea cold seep. The results indicate microbial composition varied little between two non-reductive sediments but differed significantly from the reductive sediment, primarily due to Planctomycetes and Actinobacteria. Predicting the Secondary Metabolism Potential using Amplicon (PSMPA) predictions revealed 115 strains encoding more than 10 biosynthetic gene clusters (BGCs), with lower BGC abundance in reductive sediment. Culture-dependent studies showed Firmicutes as the dominant cultivable phylum, with strains from shallow samples encoding fewer BGCs. Metagenomic data confirmed distinct microbial compositions and BGC distributions across sediment types, with cold seep type having a stronger influence than geographic location. Certain BGCs showed strong correlations with sediment depth, reflecting microbial adaptation to nutrient-limited environments. This study provides a comprehensive analysis of the metabolic capabilities of South China Sea cold seep microorganisms and reveals key factors influencing their secondary metabolic potential, offering valuable insights for the efficient exploration of cold seep biological resources. Full article
(This article belongs to the Section Marine Biotechnology Related to Drug Discovery or Production)
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28 pages, 11074 KiB  
Article
Sedimentary Characteristics and Reservoir Quality of Shallow-Water Delta in Arid Lacustrine Basins: The Upper Jurassic Qigu Formation in the Yongjin Area, Junggar Basin, China
by Lin Wang, Qiqi Lyu, Yibo Chen, Xinshou Xu and Xinying Zhou
Appl. Sci. 2025, 15(15), 8458; https://doi.org/10.3390/app15158458 (registering DOI) - 30 Jul 2025
Abstract
The lacustrine to deltaic depositional systems of the Upper Jurassic Qigu Formation in the Yongjin area constitute a significant petroleum reservoir in the central Junggar Basin, China. Based on core observations, petrology analyses, paleoenvironment indicators and modern sedimentary analyses, sequence stratigraphy, lithofacies associations, [...] Read more.
The lacustrine to deltaic depositional systems of the Upper Jurassic Qigu Formation in the Yongjin area constitute a significant petroleum reservoir in the central Junggar Basin, China. Based on core observations, petrology analyses, paleoenvironment indicators and modern sedimentary analyses, sequence stratigraphy, lithofacies associations, sedimentary environment, evolution, and models were investigated. The Qigu Formation can be divided into a third-order sequence consisting of a lowstand systems tract (LST) and a transgressive systems tract (TST), which is further subdivided into six fourth-order sequences. Thirteen lithofacies and five lithofacies associations were identified, corresponding to shallow-water delta-front deposits. The paleoenvironment of the Qigu Formation is generally characterized by an arid freshwater environment, with a dysoxic to oxic environment. During the LST depositional period (SQ1–SQ3), the water depth was relatively shallow with abundant sediment supply, resulting in a widespread distribution of channel and mouth bar deposits. During the TST depositional period (SQ4–SQ6), the rapid rise in base level, combined with reduced sediment supply, resulted in swift delta retrogradation and widespread lacustrine sedimentation. Combined with modern sedimentary analysis, the shallow-water delta in the study area primarily comprises a composite system of single main channels and distributary channel-mouth bar complexes. The channel-bar complex eventually forms radially distributed bar assemblages with lateral incision and stacking. The distributary channel could incise a mouth bar deeply or shallowly, typically forming architectural patterns of going over or in the mouth bar. Reservoir test data suggest that the mouth bar sandstones are favorable targets for lithological reservoir exploration in shallow-water deltas. Full article
(This article belongs to the Section Earth Sciences)
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29 pages, 9060 KiB  
Article
Satellite-Based Prediction of Water Turbidity Using Surface Reflectance and Field Spectral Data in a Dynamic Tropical Lake
by Elsa Pereyra-Laguna, Valeria Ojeda-Castillo, Enrique J. Herrera-López, Jorge del Real-Olvera, Leonel Hernández-Mena, Ramiro Vallejo-Rodríguez and Jesús Díaz
Remote Sens. 2025, 17(15), 2595; https://doi.org/10.3390/rs17152595 - 25 Jul 2025
Viewed by 127
Abstract
Turbidity is a crucial parameter for assessing the ecological health of aquatic ecosystems, particularly in shallow tropical lakes that are subject to climatic variability and anthropogenic pressures. Lake Chapala, the largest freshwater body in Mexico, has experienced persistent turbidity and sediment influx since [...] Read more.
Turbidity is a crucial parameter for assessing the ecological health of aquatic ecosystems, particularly in shallow tropical lakes that are subject to climatic variability and anthropogenic pressures. Lake Chapala, the largest freshwater body in Mexico, has experienced persistent turbidity and sediment influx since the 1970s, primarily due to upstream erosion and reduced water inflow. In this study, we utilized Landsat satellite imagery in conjunction with near-synchronous in situ reflectance measurements to monitor spatial and seasonal turbidity patterns between 2023 and 2025. The surface reflectance was radiometrically corrected and validated using spectroradiometer data collected across eight sampling sites in the eastern sector of the lake, the area where the highest rates of horizontal change in turbidity occur. Based on the relationship between near-infrared reflectance and field turbidity, second-order polynomial models were developed for spring, fall, and the composite annual model. The annual model demonstrated acceptable performance (R2 = 0.72), effectively capturing the spatial variability and temporal dynamics of the average annual turbidity for the whole lake. Historical turbidity data (2000–2018) and a particular case study in 2016 were used as a reference for statistical validation, confirming the model’s applicability under varying hydrological conditions. Our findings underscore the utility of empirical remote-sensing models, supported by field validation, for cost-effective and scalable turbidity monitoring in dynamic tropical lakes with limited monitoring infrastructure. Full article
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12 pages, 632 KiB  
Article
Tailoring Inflammatory Biomarker Assessment in Axial Spondyloarthritis: A Comparative Study of Erythrocyte Sedimentation Rate and C-Reactive Protein Across Disease Profiles
by Rubén Queiro, Sara Alonso, Stefanie Burger, Estefanía Pardo, Ignacio Braña, Marta Loredo and Mercedes Alperi
J. Pers. Med. 2025, 15(8), 329; https://doi.org/10.3390/jpm15080329 - 25 Jul 2025
Viewed by 209
Abstract
Background: Personalized medicine in axial spondyloarthritis (axSpA) requires accurate tools to assess inflammation and tailor disease monitoring. The role of traditional biomarkers such as erythrocyte sedimentation rate (ESR) and C-reactive protein (CRP) remains controversial due to limited sensitivity and variability across disease [...] Read more.
Background: Personalized medicine in axial spondyloarthritis (axSpA) requires accurate tools to assess inflammation and tailor disease monitoring. The role of traditional biomarkers such as erythrocyte sedimentation rate (ESR) and C-reactive protein (CRP) remains controversial due to limited sensitivity and variability across disease profiles. Objective: To compare the performance of ESR and CRP in different clinical scenarios of axSpA, including disease activity, functional impact, severity, disease duration, and exposure to biologic therapy. Methods: We conducted a cross-sectional analysis of 330 patients with axSpA. Correlations among ESR, CRP, and composite disease indices were evaluated. The discriminatory capacity of each biomarker for relevant clinical thresholds was analyzed using ROC curves and optimal cut-offs identified by the Youden index. Results: ESR showed broader correlations with disease impact and activity scores than CRP. While both markers had low sensitivity overall, they were highly specific for identifying patients with very high disease activity in select scenarios. ESR ≥ 8.5 mm/h and CRP ≥ 1.88 mg/dL were strongly discriminatory in patients not exposed to biologics. CRP ≥ 0.56 mg/dL showed good performance in early disease. Conclusions: Both ESR and CRP provide complementary insights into disease activity in axSpA. ESR may offer a broader reflection of disease burden beyond inflammation. These results support a more personalized biomarker strategy in real-world axSpA management, adapted to patient profile and treatment context. Full article
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32 pages, 3950 KiB  
Article
Macrozoobenthos Response to Sediment Contamination near the S/s Stuttgart Wreck: A Biological and Chemical Assessment in the Gulf of Gdańsk, Southern Baltic Sea
by Anna Tarała, Diana Dziaduch, Katarzyna Galer-Tatarowicz, Aleksandra Bojke, Maria Kubacka and Marcin Kalarus
Water 2025, 17(15), 2199; https://doi.org/10.3390/w17152199 - 23 Jul 2025
Viewed by 262
Abstract
This study provides an up-to-date assessment of the environmental status in the area of the S/s Stuttgart wreck in the southern Baltic Sea, focusing on macrozoobenthos, sediment chemistry, and contamination in Mytilus trossulus soft tissues. Comparative analyses from 2016 and 2023 revealed increased [...] Read more.
This study provides an up-to-date assessment of the environmental status in the area of the S/s Stuttgart wreck in the southern Baltic Sea, focusing on macrozoobenthos, sediment chemistry, and contamination in Mytilus trossulus soft tissues. Comparative analyses from 2016 and 2023 revealed increased species richness and distinct benthic assemblages, shaped primarily by depth and distance from the wreck. Among macrozoobenthos, there dominated opportunistic species, characterized by a high degree of resistance to the unfavorable state of the environment, suggesting adaptation to local conditions. Elevated concentrations of heavy metals were detected in sediments, with maximum values of Cd—0.85 mg·kg−1, Cu—34 mg·kg−1, Zn—119 mg·kg−1, and Ni—32.3 mg·kg−1. However, no significant correlations between sediment contamination and macrozoobenthos composition were found. In Mytilus trossulus, contaminant levels were mostly within regulatory limits; however, mercury concentrations reached 0.069 mg·kg−1 wet weight near the wreck and 0.493 mg·kg−1 at the reference station, both exceeding the threshold defined in national legislation (0.02 mg·kg−1) (Journal of Laws of 2021, item 568). Condition indices for Macoma balthica were lower in the wreck area, suggesting sublethal stress. Ecotoxicological tests showed no acute toxicity in most sediment samples, emphasizing the complexity of pollutant effects. The data presented here not only enrich the existing literature on marine pollution but also contribute to the development of more effective environmental protection strategies for marine ecosystems under international protection. Full article
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24 pages, 4663 KiB  
Article
Neoproterozoic Subduction Zone Fluids and Sediment Melt-Metasomatized Mantle Magmatism on the Northern Yangtze Block: Constraints from the Ca. 880 Ma Taoyuan Syenogranite
by Shilei Liu, Yiduo Li, Han Liu, Peng Wang, Shizhen Zhang and Fenglin Chen
Minerals 2025, 15(7), 730; https://doi.org/10.3390/min15070730 - 12 Jul 2025
Viewed by 184
Abstract
The Yangtze Block, with its widespread Neoproterozoic mafic–felsic magmatic rock series and volcanic–sedimentary rock assemblages, is one of the key windows for reconstructing the assembly and fragmentation process of Rodinia. This study focuses on the Taoyuan syenogranite from the Micangshan Massif on the [...] Read more.
The Yangtze Block, with its widespread Neoproterozoic mafic–felsic magmatic rock series and volcanic–sedimentary rock assemblages, is one of the key windows for reconstructing the assembly and fragmentation process of Rodinia. This study focuses on the Taoyuan syenogranite from the Micangshan Massif on the northern Yangtze Block, by conducting systematic chronology, mineralogy, and geochemistry analyses to investigate their source, petrogenesis, and tectonic setting. LA-ICP-MS U–Pb geochronology reveals that the medium- to coarse-grained and medium- to fine-grained syenogranites have crystallization ages of 878 ± 4.2 Ma and 880 ± 6.5 Ma, respectively. These syenogranites have aluminum saturation index (A/CNK) values ranging from 0.79 to 1.06, indicating quasi-aluminous to weakly peraluminous compositions, and are classified as calc-alkaline I-type granites. The geochemical indicators of these rocks, including Mg# (44–48, mean 46), Zr/Hf (40.07), Nb/La (0.4), and zircon εHf(t) values (+9.2 to +10.9), collectively indicate a depleted lithospheric mantle source. The mantle source was metasomatized by subduction-derived fluids and sediment melts prior to partial melting as evidenced by their higher Mg#, elevated Ba content, and distinctive ratios (Rb/Y, Nb/Y, Th/Yb, Th/Sm, Th/Ce, and Ba/La). Integrating regional data, this study confirms crust–mantle interaction along the northern Yangtze during the early Neoproterozoic, supporting a sustained subduction-related tectonic setting. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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62 pages, 4192 KiB  
Review
Advancements in Magnetorheological Foams: Composition, Fabrication, AI-Driven Enhancements and Emerging Applications
by Hesamodin Khodaverdi and Ramin Sedaghati
Polymers 2025, 17(14), 1898; https://doi.org/10.3390/polym17141898 - 9 Jul 2025
Viewed by 532
Abstract
Magnetorheological (MR) foams represent a class of smart materials with unique tunable viscoelastic properties when subjected to external magnetic fields. Combining porous structures with embedded magnetic particles, these materials address challenges such as leakage and sedimentation, typically encountered in conventional MR fluids while [...] Read more.
Magnetorheological (MR) foams represent a class of smart materials with unique tunable viscoelastic properties when subjected to external magnetic fields. Combining porous structures with embedded magnetic particles, these materials address challenges such as leakage and sedimentation, typically encountered in conventional MR fluids while offering advantages like lightweight design, acoustic absorption, high energy harvesting capability, and tailored mechanical responses. Despite their potential, challenges such as non-uniform particle dispersion, limited durability under cyclic loads, and suboptimal magneto-mechanical coupling continue to hinder their broader adoption. This review systematically addresses these issues by evaluating the synthesis methods (ex situ vs. in situ), microstructural design strategies, and the role of magnetic particle alignment under varying curing conditions. Special attention is given to the influence of material composition—including matrix types, magnetic fillers, and additives—on the mechanical and magnetorheological behaviors. While the primary focus of this review is on MR foams, relevant studies on MR elastomers, which share fundamental principles, are also considered to provide a broader context. Recent advancements are also discussed, including the growing use of artificial intelligence (AI) to predict the rheological and magneto-mechanical behavior of MR materials, model complex device responses, and optimize material composition and processing conditions. AI applications in MR systems range from estimating shear stress, viscosity, and storage/loss moduli to analyzing nonlinear hysteresis, magnetostriction, and mixed-mode loading behavior. These data-driven approaches offer powerful new capabilities for material design and performance optimization, helping overcome long-standing limitations in conventional modeling techniques. Despite significant progress in MR foams, several challenges remain to be addressed, including achieving uniform particle dispersion, enhancing viscoelastic performance (storage modulus and MR effect), and improving durability under cyclic loading. Addressing these issues is essential for unlocking the full potential of MR foams in demanding applications where consistent performance, mechanical reliability, and long-term stability are crucial for safety, effectiveness, and operational longevity. By bridging experimental methods, theoretical modeling, and AI-driven design, this work identifies pathways toward enhancing the functionality and reliability of MR foams for applications in vibration damping, energy harvesting, biomedical devices, and soft robotics. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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25 pages, 9967 KiB  
Article
Study on the Influence and Mechanism of Mineral Admixtures and Fibers on Frost Resistance of Slag–Yellow River Sediment Geopolymers
by Ge Zhang, Huawei Shi, Kunpeng Li, Jialing Li, Enhui Jiang, Chengfang Yuan and Chen Chen
Nanomaterials 2025, 15(13), 1051; https://doi.org/10.3390/nano15131051 - 6 Jul 2025
Viewed by 274
Abstract
To address the demands for resource utilization of Yellow River sediment and the durability requirements of engineering materials in cold regions, this study systematically investigates the mechanisms affecting the frost resistance of slag-Yellow River sediment geopolymers through the incorporation of mineral admixtures (silica [...] Read more.
To address the demands for resource utilization of Yellow River sediment and the durability requirements of engineering materials in cold regions, this study systematically investigates the mechanisms affecting the frost resistance of slag-Yellow River sediment geopolymers through the incorporation of mineral admixtures (silica fume and metakaolin) and fibers (steel fiber and PVA fiber). Through 400 freeze-thaw cycles combined with microscopic characterization techniques such as SEM, XRD, and MIP, the results indicate that the group with 20% silica fume content (SF20) exhibited optimal frost resistance, showing a 19.9% increase in compressive strength after 400 freeze-thaw cycles. The high pozzolanic reactivity of SiO2 in SF20 promoted continuous secondary gel formation, producing low C/S ratio C-(A)-S-H gels and increasing the gel pore content from 24% to 27%, thereby refining the pore structure. Due to their high elastic deformation capacity (6.5% elongation rate), PVA fibers effectively mitigate frost heave stress. At the same dosage, the compressive strength loss rate (6.18%) and splitting tensile strength loss rate (21.79%) of the PVA fiber-reinforced group were significantly lower than those of the steel fiber-reinforced group (9.03% and 27.81%, respectively). During the freeze-thaw process, the matrix pore structure exhibited a typical two-stage evolution characteristic of “refinement followed by coarsening”: In the initial stage (0–100 cycles), secondary hydration products from mineral admixtures filled pores, reducing the proportion of macropores by 5–7% and enhancing matrix densification; In the later stage (100–400 cycles), due to frost heave pressure and differences in thermal expansion coefficients between matrix phases (e.g., C-(A)-S-H gel and fibers), interfacial microcracks propagated, causing the proportion of macropores to increase back to 35–37%. This study reveals the synergistic interaction between mineral admixtures and fibers in enhancing freeze–thaw performance. It provides theoretical support for the high-value application of Yellow River sediment in F400-grade geopolymer composites. The findings have significant implications for infrastructure in cold regions, including subgrade materials, hydraulic structures, and related engineering applications. Full article
(This article belongs to the Special Issue Nanomaterials and Nanotechnology in Civil Engineering)
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23 pages, 4329 KiB  
Article
Sediment Fingerprinting Enables the Determination of Soil Erosion Sources and Sediment Transport Processes in a Topographically Complex Nile Headwater Basin
by Amartya K. Saha, Christopher L. Dutton, Marc Manyifika, Sarah C. Jantzi and Sylvere N. Sirikare
Soil Syst. 2025, 9(3), 70; https://doi.org/10.3390/soilsystems9030070 - 4 Jul 2025
Viewed by 242
Abstract
Sediment fingerprinting was utilized to identify potential hotspots of soil erosion and sediment transport pathways in the Nile Nyabarongo Upper Catchment (NNYU) in Rwanda, where rivers and reservoirs are suffering from alarmingly high levels of sedimentation. Sediment fingerprinting is a practical approach used [...] Read more.
Sediment fingerprinting was utilized to identify potential hotspots of soil erosion and sediment transport pathways in the Nile Nyabarongo Upper Catchment (NNYU) in Rwanda, where rivers and reservoirs are suffering from alarmingly high levels of sedimentation. Sediment fingerprinting is a practical approach used to identify erosional hotspots and sediment transport processes in highly mountainous regions undergoing swift land use transformation. This technique involves a statistical comparison of the elemental composition of suspended sediments in river water with the elemental composition of soils belonging to different geological formations present in the catchment, thereby determining the sources of the suspended sediment. Suspended sediments were sampled five times over dry and wet seasons in all major headwater tributaries, as well as the main river channel, and compared with soils from respective delineated watersheds. Elemental composition was obtained using laser ablation inductively coupled plasma mass spectrometry, and elements were chosen that could reliably distinguish between the various geological types. The final results indicate different levels of sediment contribution from different geological types. A three-level intervention priority system was devised, with Level 1 indicating the areas with the most serious erosion. Potential sources were located on an administrative map, with the highest likely erosion over the study period (Level 1) occurring in Kabuga cell in the Mwogo sub-catchment, Nganzo and Nyamirama cells in the Nyagako sub-catchment and Kanyana cell in the NNYU downstream sub-catchment. This map enables the pinpointing of site visits in an extensive and rugged terrain to verify the areas and causes of erosion and the pathways of sediment transport. Sediment concentrations (mg L−1) were the highest in the Secoko and Satinsyi tributaries. The composition of suspended sediment was seen to be temporally and spatially dynamic at each sampling point, suggesting the need for an adequate number of sampling locations to identify erosion hotspots in a large mountainous watershed. Apart from prioritizing rehabilitation locations, the detailed understanding of critical zone soil–land cover–climate processes is an important input for developing region-specific watershed management and policy guidelines. Full article
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26 pages, 9198 KiB  
Article
The Exotic Igneous Clasts Attributed to the Cuman Cordillera: Insights into the Makeup of a Cadomian/Pan-African Basement Covered by the Moldavides of the Eastern Carpathians, Romania
by Sarolta Lőrincz, Marian Munteanu, Ştefan Marincea, Relu Dumitru Roban, Valentina Maria Cetean, George Dincă and Mihaela Melinte-Dobrinescu
Geosciences 2025, 15(7), 256; https://doi.org/10.3390/geosciences15070256 - 3 Jul 2025
Viewed by 279
Abstract
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock [...] Read more.
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock fragments preserved in the sedimentary successions of the Carpathian fold and thrust belt, specifically in the Outer Dacides and the Moldavides. Fragments of felsic rocks occurring within the sedimentary units of the Upper Cretaceous successions of the Moldavides have long been attributed to the Cuman Cordillera—an intrabasinal ridge in the Eastern Outer Carpathians. This work is the first complex geochemical and geochronological study on the exotic igneous clasts of the Cuman Cordillera. Igneous clasts from the southern part of the Moldavides (Variegated clay nappe/formation) are investigated here. They include mainly granites and rhyolites. Phaneritic rocks are composed of cumulus plagioclase, albite, amphibole and biotite, and intercumulus quartz and potassium feldspar, with apatite, magnetite, sphene, and zircon as main accessories, while the porphyritic rocks have a mineral assemblage similar to that mentioned above, displayed in a porphyritic texture with a usually crystallized groundmass. SHRIMP U-Pb zircon dating indicated the 583–597 Ma age interval for magma crystallization. Based on calcareous nannofossils, the depositional age of the investigated igneous clasts is Cenomanian to Maastrichtian, implying that the Cuman Cordillera was an emerged piece of land, herein an active source of sediments in the flysch basin for at least 40 Ma, from the Early Cretaceous (Aptian) to the Late Cretaceous (Maastrichtian). The intrusive and subvolcanic rocks show similar trends for trace and major elements, evincing their comagmatic nature. The enrichment in LILE and LREE relative to HFSE and HREE, as well as the element anomalies (e.g., negative Nb, Ta, and Eu and positive Rb, Ba, K, and Pb) suggest a convergent continental plate margin tectonic setting. Mineral chemistry suggests magma crystallization in relatively oxic conditions (magnetite series), during ascent within a depth of 15 km to 5 km. The igneous rocks attributed to the Cuman ridge display compositional and geochronological features similar to Brno and Thaya batholiths in the Brunovistulian terrane, which could be a piece of the Carpathian foreland not covered by the Tertiary thrusts. Our data confirm the non-Carpathian origin of the igneous clasts, revealing a Neoproterozoic history of the Carpathian foreland units, which include a Cadomian/Pan-African continental arc, exposed mainly during the Late Cretaceous as an intrabasinal island of the Alpine Tethys, traditionally known as the Cuman Cordillera. Full article
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26 pages, 9572 KiB  
Article
Geochemical Characteristics and Risk Assessment of PTEs in the Supergene Environment of the Former Zoige Uranium Mine
by Na Zhang, Zeming Shi, Chengjie Zou, Yinghai Zhu and Yun Hou
Toxics 2025, 13(7), 561; https://doi.org/10.3390/toxics13070561 - 30 Jun 2025
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Abstract
Carbonaceous–siliceous–argillaceous rock-type uranium deposits, a major uranium resource in China, pose significant environmental risks due to heavy metal contamination. Geochemical investigations in the former Zoige uranium mine revealed elevated As, Cd, Cr, Cu, Ni, U, and Zn concentrations in soils and sediments, particularly [...] Read more.
Carbonaceous–siliceous–argillaceous rock-type uranium deposits, a major uranium resource in China, pose significant environmental risks due to heavy metal contamination. Geochemical investigations in the former Zoige uranium mine revealed elevated As, Cd, Cr, Cu, Ni, U, and Zn concentrations in soils and sediments, particularly at river confluences and downstream regions, attributed to leachate migration from ore bodies and tailings ponds. Surface samples exhibited high Cd bioavailability. The integrated BCR and mineral analysis reveals that Acid-soluble and reducible fractions of Ni, Cu, Zn, As, and Pb are governed by carbonate dissolution and Fe-Mn oxide dynamics via silicate weathering, while residual and oxidizable fractions show weak mineral-phase dependencies. Positive Matrix Factorization identified natural lithogenic, anthropogenic–natural composite, mining-related sources. Pollution assessments using geo-accumulation index and contamination factor demonstrated severe contamination disparities: soils showed extreme Cd pollution, moderate U, As, Zn contamination, and no Cr, Pb pollution (overall moderate risk); sediments exhibited extreme Cd pollution, moderate Ni, Zn, U levels, and negligible Cr, Pb impacts (overall extreme risk). USEPA health risk models indicated notable non-carcinogenic (higher in adults) and carcinogenic risks (higher in children) for both age groups. Ecological risk assessments categorized As, Cr, Cu, Ni, Pb, and Zn as low risk, contrasting with Cd (extremely high risk) and sediment-bound U (high risk). These findings underscore mining legacy as a critical environmental stressor and highlight the necessity for multi-source pollution mitigation strategies. Full article
(This article belongs to the Special Issue Assessment and Remediation of Heavy Metal Contamination in Soil)
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32 pages, 68153 KiB  
Review
Barite Deposits of Türkiye: A Review
by Zeynep Cansu, Hüseyin Öztürk and Nurullah Hanilçi
Minerals 2025, 15(7), 692; https://doi.org/10.3390/min15070692 - 28 Jun 2025
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Abstract
Türkiye hosts a wide variety of barite deposits that can be broadly classified into two major groups based on their tectonic settings: magmatism-associated and passive margin-hosted deposits. The magmatism-associated deposits include Kızılcaören (F + Ba + REE + Th, Beylikova–Eskişehir), Kirazören (Bulancak–Giresun), and [...] Read more.
Türkiye hosts a wide variety of barite deposits that can be broadly classified into two major groups based on their tectonic settings: magmatism-associated and passive margin-hosted deposits. The magmatism-associated deposits include Kızılcaören (F + Ba + REE + Th, Beylikova–Eskişehir), Kirazören (Bulancak–Giresun), and Karacaören (Mesudiye–Ordu). The Kızılcaören deposit formed in relation to the emplacement of a late Oligocene carbonatitic sill, while the Kirazören and Karacaören deposits are associated with the Cretaceous Pontide magmatic arc. Passive margin-hosted deposits occur within various Paleozoic sedimentary lithologies—such as metasandstone, shale, schist, and limestone—and are found in the Taurides and the Arabian Platform. These deposits occur as either concordant or discordant veins. This barite belt extends from Şarkikaraağaç (Isparta), through Hüyük (Konya) and Alanya (Antalya), to Silifke (Mersin), Tordere (Adana), Önsen, Şekeroba (Kahramanmaraş), and Hasköy (Muş). The Paleozoic deposits represent the major barite resources of Türkiye, with an annual production of approximately 300,000 metric tons. Smaller deposits around Gazipaşa (Antalya) contain minor Pb-Zn sulfides. Mesozoic barite deposits are hosted in Triassic dolomites and are associated with Pb-Zn mineralization in the Hakkari region of the Arabian Platform. Pb and Sr isotope data indicate that the barium in these deposits was derived from ancient continental crust. The isotopic compositions of both concordant (stratabound) and discordant (vein-type) barites are generally homogeneous. In northwestern Türkiye, the Sr isotope compositions of the barite deposits align well with those of the Oligocene carbonatite host complex. The 87Sr/86Sr isotope ratio of the Kızılcaören deposit (0.706‰) is the least radiogenic among Turkish barite deposits, suggesting a mantle contribution. The Kirazören deposit in the Pontide magmatic arc follows with a slightly higher ratio (0.707‰). Triassic barites from the Hakkari region yield 87Sr/86Sr values around 0.709‰, slightly more radiogenic than coeval seawater. Paleozoic barite deposits show the most radiogenic 87Sr/86Sr values, including Aydıncık (0.718‰), Şarkikaraağaç (0.714‰), Hasköy (0.713‰), Kahramanmaraş (0.712‰), Tordere, and Hüyük (both 0.711‰), consistent with their respective host rocks. The elevated radiogenic Pb and Sr isotope values in the passive margin-hosted deposits suggest that the barium originated from deeper, barium-enriched rocks, whereas stable sulfur isotope data point to a marine sulfur source. Moreover, Sr and S isotopic signatures indicate that the Paleozoic sediment-hosted deposits formed in association with cold seeps on the seafloor, resembling modern analogs. In contrast, the Mesozoic Karakaya deposit (Hakkari) represents a typical vent-proximal, sediment-hosted deposit with no magmatic signature. Full article
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