Search Results (369)

This study investigates the rheological, thermal, and microstructural performance of three novel high-elasticity polymer modifiers (HEMs) incorporated into asphalt binders. The modifiers were evaluated at their recommended dosages using a multi-scale framework combining rotational viscosity, dynamic shear rheometry (frequency sweeps, Cole-Cole plots, Black diagrams, and master curves), bending beam rheometry, differential scanning calorimetry (DSC), fluorescence microscopy (FM), atomic force microscopy (AFM), and Fourier transform infrared spectroscopy (FTIR). Results show that HEM-B achieved the highest values of the superpave rutting parameter (G*/sinδ = 5.07 kPa unaged, 6.73 kPa aged), reflecting increased high-temperature stiffness but also higher viscosity, which may affect workability. HEM-C exhibited the lowest total enthalpy (1.18 W·g⁻¹) and a glass transition temperature of −7.7 °C, indicating improved thermal stability relative to other binders. HEM-A showed the greatest increase in fluorescent area (+85%) and the largest reduction in fluorescent number (−60%) compared with base asphalt, demonstrating more homogeneous phase dispersion despite higher enthalpy. Comparison with SBS confirmed that the novel HEMs not only meet but exceed conventional performance thresholds while revealing distinct modification mechanisms, dense cross-linking (HEM-B), functionalized thermoplastic compatibility (HEM-C), and epoxy-tackified network formation (HEM-A). These findings establish quantitative correlations between rheology, thermal stability, and microstructure, underscoring the importance of dosage, compatibility, and polymer network architecture. The study provides a mechanistic foundation for optimizing high-elasticity modifiers in asphalt binders and highlights future needs for dosage normalization and long-term aging evaluation. Full article

To overcome the limitations of conventional high-viscosity high-elasticity modified asphalt, including high production costs, phase separation, and thermal degradation, this study introduces a novel fast melting Styrene-Butadiene-Styrene modifier (SBS-T) for asphalt modification. The primary novelty of SBS-T lies in its ability to mitigate phase separation and thermal degradation while simplifying the production process, thereby offering a more robust and cost-effective alternative. The viscoelastic properties of SBS-T-modified asphalt were characterized through frequency sweep tests under varying loading conditions, while its fatigue behavior was quantitatively assessed using the Simplified Viscoelastic Continuum Damage (S-VECD) model. The results indicate that the SBS-T-modified asphalt exhibits outstanding viscoelastic performance across a broad range of temperatures and loading frequencies, and can better adapt to the temperature and load changes in complex pavement environments. Among them, the influence of long-term aging on the linear viscoelastic characteristics of SBS-T-modified asphalt is greater than that of ultraviolet aging. The SBS-T-modified asphalt also shows better stiffness and resistance to shear deformation. The fatigue life of asphalt gradually decreases with the deepening of the aging degree, among which the impact of long-term aging on fatigue life is greater than that of ultraviolet aging. Under different aging conditions, SBS-T-modified asphalt has shown good fatigue performance and is suitable for practical engineering applications. Full article

Moisture damage remains a primary distress mechanism in asphalt pavements, leading to reduced service life and viscoelastic property loss due to weakened asphalt–aggregate adhesion. This study evaluated moisture susceptibility in eight asphalt mixtures combining two aggregates (limestone/granite) and four binders (two neat, two SBS-modified) using dynamic mechanical analysis (DMA). Thin-section specimens underwent DMA temperature sweeps under dry and water-immersed conditions to characterize shifts in viscoelastic properties. Results demonstrated that moisture exposure significantly reduced complex modulus values and shifted characteristic temperatures (T₀, T₁, T₂, T_g) toward lower ranges, indicating compromised performance. Specifically, granite mixtures showed average reductions in T₀, T₁, and T_g of 2.9 °C, 1.8 °C, and 3.7 °C, respectively, compared to 2.1 °C, 1.5 °C, and 1.7 °C for limestone mixtures. The magnitude of these changes—quantified by residual modulus (RM) ratios and characteristic temperature differentials—effectively ranked mixture susceptibility, with granite mixtures and specific binders (A1, B1) showing higher sensitivity. Notably, minimum residual modulus (RM_min) values ranged from 28.2% to 65.8%, and its critical temperature (T_RM) identified the most severe moisture damage conditions (approximately 40 °C for neat asphalt; 60 °C for modified asphalt). The DMA-derived indices correlated with surface free energy-based adhesion work, confirming the method’s reliability for rapid moisture sensitivity assessment. This approach provides an efficient basis for selecting moisture-resistant materials tailored to operational temperature environments. Full article

Microorganisms present in asphalt pavement service environments can alter the composition of asphalt through metabolic activities, thereby affecting its rheological properties. To investigate this influence and compare performance variations across asphalt types, two asphalt-degrading bacterial strains were isolated from in-service pavements. Following 16S rRNA gene sequencing and phylogenetic analysis, the strains were identified as Pseudomonas putida and a putative novel species within the Citrobacter genus. Using a custom-designed thin-film inoculation system, the performance evolution of base asphalt and styrene-butadiene-styrene (SBS) modified asphalt was systematically evaluated after microbial activity periods of 5, 10, and 15 days. Conventional property tests and multi-temperature rheological analyses (temperature sweep, multiple stress creep recovery test, linear amplitude sweep, 4 mm DSR) were conducted. Results demonstrated that microbial action reduced penetration, elevated softening point, and decreased ductility in both asphalt types, with more pronounced changes observed in base asphalt. High-temperature rheological parameters (G*/sinδ), recovery rate, and non-recoverable creep compliance indicated compromised resistance to permanent deformation. SBS-modified asphalt substantially mitigated these detrimental effects. Fatigue life of base asphalt decreased overall with periodic fluctuations, whereas SBS-modified asphalt exhibited superior fatigue stability: after an initial decline at 5 days, performance recovered and stabilized between 10 and 15 days. Low-temperature performance showed slight improvement in base asphalt, while SBS-modified asphalt demonstrated significant enhancement during later activity stages. Full article

The mastic asphalt mixture (MA) is one of the first mineral and asphalt mixtures used in history. Its composition and structure allow it (the mixture) to be produced both in industrial conditions (in mineral and asphalt mixing plants) and in field conditions—in mobile boilers (especially when the produced mixture is used to repair damaged surface). The high proportion of the sand fraction makes the mixture highly workable, allowing it to be laid/incorporated without special equipment. MA, however, also has some drawbacks. The asphalt content is higher than in other mixtures, which can make it prone to plastic deformation. Mastic asphalt requires higher processing temperatures than other “hot” mixtures. Mastic asphalt mixtures are installed as road pavement layers and, because of their high density, as the protective layer on roof felt isolation on bridge decks. The high temperature of embedding creates a risk of damaging the roof felt, as its typical temperature resistance is lower than 180 °C, whereas the temperature of the mastic asphalt mixture is higher. The use of zeolites can enable reconciliation of technological requirements of mastic asphalt and asphalt roof isolation. The mixes MA 8 and MA 11 containing 0 and 5% of two types of zeolites and asphalt binders 35/50 or elastomer-SBS-modified asphalt binder PMB 25/55-60 were used in the research. Laboratory tests revealed that the addition of a 5% amount of zeolite by asphalt mass makes it possible to reduce the mastic asphalt laying temperature by up to 30 °C, which seems to be very important from ecological, economical, and pavement durability points of view. Full article

The durability of asphalt pavements is crucial for sustainable road infrastructures. This systematic review compares the Marshall and Superpave asphalt mix design protocols, with a particular focus on the integration of polymer-modified bitumen (PMB) and rejuvenators. Although the Marshall method remains widely used for its simplicity and cost-efficiency, its empirical basis limits its effectiveness to meet modern pavement performance demands. In contrast, the Superpave system offers improved resistance to rutting, longer fatigue life, and better mitigation of moisture damage. The review traces the evolution of asphalt mix design, identifies current challenges, and emphasizes the need for transitioning toward performance-based frameworks. Special attention is given to the incorporation of polymers such as Styrene–Butadiene–Styrene (SBS), Styrene–Butadiene–Rubber (SBR), and Polyethylene (PE), which significantly enhance the mechanical properties of asphalt mixtures. The role of rejuvenators in restoring aged binders and enabling pavement recycling is also examined. Finally, the manuscript provides strategic recommendations for adopting Superpave to enhance pavement durability and reduce lifecycle maintenance costs. Overall, this comprehensive review advances knowledge on asphalt mix design, fostering innovation and sustainability while promoting long-term resilience in road pavement infrastructures. Full article

To facilitate the sustainable recycling of retired wind turbine blades (RWTBs) and promote the green development of the wind energy sector in China, this study investigates the reuse of crushed RWTBs as composite fiber additives in asphalt mixtures. A systematic optimization of the incorporation process was conducted, and the effects of RWTB fibers on pavement performance were comprehensively evaluated. Using the entropy weight method, the optimal fiber content and particle size were identified as 0.15 wt% and 0.3–1.18 mm, respectively. The experimental results demonstrated that, under optimal conditions, the dynamic stability, low-temperature flexural tensile strain, Marshall stability after water immersion, and freeze-thaw splitting strength of the base asphalt mixture increased by 27.1%, 23.8%, 9.9%, and 8.1%, respectively. Microstructural analyses using SEM and EDS revealed that the reinforcing mechanism of RWTB fibers involves adsorption, bridging, and network formation, which collectively enhance the toughness and elasticity of the asphalt matrix. In addition, a comparative evaluation was performed using the Analytic Hierarchy Process (AHP), incorporating both performance and cost considerations. The comprehensive performance ranking of fiber-modified asphalt mixtures was consistent for both base and SBS-modified asphalt: BF AC-13 > RWTB AC-13 > GF AC-13 > PF AC-13 > unmodified AC-13. Overall, this study confirms the feasibility of high-value reuse of RWTB waste in road engineering and provides practical insights for advancing resource recycling and promoting sustainability within the wind power industry. Full article

Latent stripping has become increasingly apparent in asphalt pavements, particularly in highway rehabilitation and international construction projects supported by Official Development Assistance (ODA) from the Government of Japan. Stripping accelerates structural deterioration, making countermeasures essential. However, in ODA projects, securing high-quality aggregates or evaluating local materials is often difficult due to environmental and budgetary constraints. This study focused on Surface Free Energy (SFE) as a small-sample evaluation method and developed ten types of styrene–butadiene–styrene (SBS) polymers to enhance interfacial adhesion by targeting aggregate surface functional groups. The SFE of each Polymer-Modified Bitumen (PMB) and thirteen aggregates was measured, and the work of adhesion and moisture sensitivity index (MSI) were calculated for all combinations. Twenty-one Hot-Mix Asphalts (HMA) were then prepared and evaluated using the Hamburg Wheel Tracking Test (HWTT) based on load cycles to stripping initiation (LC_SN) and to 12.5 mm rut depth (LC_ST). The developed PMBs showed a higher work of adhesion, a lower MSI, and substantially increased LC_SN and LC_ST values. Strong negative correlations were observed between MSI and both HWTT indicators, confirming the utility of SFE-based MSI for material screening. This study demonstrates that interface-targeted PMBs can improve stripping resistance, thereby promoting the use of lower-quality aggregates in durable pavements. Full article

Energy demand is a critical challenge for sustainable infrastructure, yet in road asset management, it is rarely considered a central decision criterion. Most decision frameworks remain focused on financial and structural performance. This study introduces a comparative Energy Balance Analysis (EBA) as a complementary tool to existing life-cycle approaches. A case study is presented in which the only variable is binder composition—conventional 50/70 bitumen versus the same binder modified with 3% styrene–butadiene–styrene (SBS) polymer. The methodology integrates material-level energy demand estimation, laboratory performance testing, and pavement life modeling with HDM-4, and vehicle operational energy analysis. Results show that although SBS modification increases initial binder production energy by 13.3%, it doubles pavement service life and avoids mid-life rehabilitation, leading to a net saving of 110,671.75 MJ over 20 years. These findings confirm that early-stage material improvements can generate long-term energy efficiency gains. The study thus demonstrates the potential of EBA as a practical decision-support tool for sustainable pavement management. Full article

Crumb rubber used in asphalt modification can generally improve the road performance of asphalt mixture pavement while offering substantial environmental and economic benefits. This study investigates the volatile organic compound emissions from crumb rubber-modified asphalt binders via gas chromatography–mass spectrometry, focusing on the effects of crumb rubber types (e.g., activated crumb rubber, non-activated crumb rubber), contents, and additives (warm-mix agents, deodorants, styrene–butadiene–styrene (SBS)). The analysis encompasses total volatile organic compound emissions, compositional variations, secondary organic aerosol and ozone formation potentials, and carcinogenic risks. Results indicate that non-activated crumb rubber increases volatile organic compound emissions initially, peaking at a 15% content (3.99 times higher than base asphalt), dominated by trichloroethylene. The surfactant-based warm-mix additive significantly reduces emissions by 73%, whereas deodorants exhibited limited efficacy. At equivalent contents, activated crumb rubber-modified asphalt emits more volatile organic compounds than non-activated crumb rubber-modified asphalt and leads to a higher ozone formation potential. Activated crumb rubber/SBS-modified asphalt blends reduce emissions by 69%–81% due to synergistic effects. In contrast, non-activated crumb rubber/SBS blends increase emissions, likely due to phase separation. All samples contain carcinogens, primarily trichloroethylene (20%–79%) and benzene (0.1%–9%). These findings underscore the critical importance of crumb rubber activation status and SBS addition in controlling volatile organic compound diffusion. The activated crumb rubber/SBS combination achieves a synergistic reduction exceeding the sum of individual effects (“1 + 1 > 2”). These findings provide valuable insights for designing eco-friendly asphalt. Full article

This study examined the synergistic effects of Styrene–Butadiene–Styrene (SBS) polymer and nanoclay on asphalt concrete mixture performance through a systematic experimental program using 4.5% SBS with varying nanoclay concentrations (0–8%). Performance evaluation included Indirect Tensile Strength (ITS), Indirect Tensile Resilient Modulus (E_RI), and Hamburg Wheel Tracking Tests (HWTT), along with novel quantitative analysis of visco-plastic and moisture resistance indices. Results demonstrated that 4.5% SBS with 6% nanoclay (4.5S6N) yielded optimal performance, achieving 38% increase in dry ITS, 68% improvement in wet ITS, and enhanced moisture resistance with Tensile strength Ratio (TSR) improving from 79.53% to 97.14%. The E_RI value increased by 39%, while rutting resistance improved by 39.3%. At this optimal concentration, nanoclay’s uniform dispersion and layered silicate structure created an effective reinforcement network, enhancing stress distribution and interfacial bonding with the SBS polymer network and asphalt components. However, exceeding 6% nanoclay content led to performance deterioration due to particle agglomeration. These findings demonstrate that optimized SBS–nanoclay modification effectively addresses both mechanical and moisture-related performance requirements for modern pavement applications. Full article

To reduce reflective cracking in asphalt pavements, gravel base layers are commonly employed to disperse stress and delay structural damage. However, the loose nature of gravel bases results in complex interlayer contact conditions, typically involving interlocking between gravel particles in the base and aggregates in the asphalt surface course. In order to accurately simulate this interaction and to improve the interlayer shear performance, a mesoscale finite element model was developed and combined with macroscopic tests. Effects due to the type and amount of binder material, type of asphalt surface layer, and external loading on shear strength were systematically analyzed. The results indicate that SBS (Styrene–Butadiene–Styrene)-modified asphalt provides the highest interlayer strength, followed by SBR (Styrene–Butadiene Rubber)-modified emulsified asphalt and unmodified base bitumen. SBS (Styrene–Butadiene–Styrene)-modified asphalt achieves optimal interlaminar shear strength at a coating rate of 0.9 L/m². Additionally, shear strength increases with applied load but decreases with increasing void ratio and the nominal maximum aggregate size of the surface course in the analyzed spectra. Based on simulation and experimental data, an equivalent macro–meso predictive model relating shear strength to key influencing factors was established. This model effectively bridges mesoscale mechanisms and practical engineering applications, providing theoretical support for the design and performance optimization of asphalt pavements with gravel bases. Full article

The interlayer bonding strength between a cement-stabilized macadam (CSM) base and an asphalt surface layer significantly influences asphalt pavement performance. This study analyzes the calculation method for the interlayer bonding coefficient, investigates its impact on pavement structural response, and proposes a threshold value. Pavement mechanics software was first employed to analyze horizontal displacement at the CSM-asphalt interface, leading to a proposed method for calculating the bonding coefficient using initial stress and displacement derived from interlayer shear tests. Subsequently, the bonding coefficient was evaluated under three interface conditions: untreated, emulsified asphalt-treated, and SBS-modified hot asphalt-treated. Results reveal substantial inherent bonding strength even in untreated interfaces. SBS-modified hot asphalt increased bonding strength by 40–50% compared to untreated interfaces and by 15–20% relative to emulsified asphalt-treated interfaces. Analysis of varying bonding coefficients demonstrates that insufficient CSM-asphalt bonding readily induces asphalt layer fatigue cracking, with bonding strength exerting the dominant influence on fatigue life. Pavements with SBS-modified hot asphalt interlayers exhibited approximately 70% longer fatigue life than untreated interfaces and 30% longer than emulsified asphalt-treated interfaces. Crucially, an interlayer bonding coefficient exceeding 5000 MPa/cm is required for layers to be considered fully bonded. Full article

Epoxy asphalt is a superior polymer-modified asphalt material; however, significant differences in physicochemical properties, such as solubility parameters and dielectric constants, between epoxy resin and asphalt have led to compatibility issues that hinder its development. This study employed molecular dynamics simulations to investigate the effect of maleic anhydride-grafted styrene-butadiene-styrene (MAH-g-SBS) on the compatibility of epoxy asphalt. By analyzing parameters such as cohesive energy density, solubility parameters, energy distribution, interaction energy, radial distribution function, free volume fraction, and mean square displacement, the molecular mechanism underlying the enhanced compatibility was elucidated. The results indicate that the amphiphilic molecular structure of MAH-g-SBS significantly improves the thermodynamic compatibility between asphalt and epoxy resin, enhances interfacial affinity and stability, reduces the system’s total interaction and nonbonded energies, facilitates the dispersion and permeation of epoxy molecules into asphalt, and increases molecular mobility, thereby comprehensively enhancing the compatibility of the epoxy asphalt blend. Segregation tests and fluorescence microscopy further verified the simulation results, demonstrating that MAH-g-SBS improves the storage stability and phase uniformity of the epoxy asphalt system. Full article

This study investigates the evolution laws and prediction models of anti-skid and wear-resistant performance for asphalt pavements during the operation period. Using a combination of indoor accelerated wear tests and field detection, mixed specimens are prepared with SBS modified asphalt, limestone, and basalt aggregates. Through accelerated wear tests of different durations, the structural depth and friction coefficient are measured. Combined with the field data from the G56 K2319 section of the Hangrui Expressway, the decay laws of anti-skid performance are analyzed, and prediction models are established. The results show that the anti-skid performance of basalt mixtures is superior to that of limestone. The deepened structure technology significantly enhances the performance of basalt but has a negative impact on the pendulum value of limestone. The influence degrees of wear duration, aggregate type, and deepened structure state on structural depth and pendulum value vary. The initial structural depth of basalt mixtures (0.85 mm) is 11.8% higher than that of limestone (0.76 mm). The longitudinal pendulum value of basalt (44) is 10% higher than that of limestone (40), while the transverse pendulum value of limestone (50) is 4.2% higher than that of basalt (48). After 21 h of wear, the structural depth of basalt (0.68 mm) is 4.6% higher than that of limestone (0.65 mm), with a decay rate 23.6% lower. The pendulum value of basalt remains above 50, while limestone’s longitudinal pendulum value drops to 36 (10% lower than its initial value), even below the unmodified state. The influence order for structural depth is deepened structure state > wear duration > aggregate type, and for lateral pendulum value, it is wear duration > deepened structure state > aggregate type. There is a significant linear relationship between structural depth/pendulum value and wear duration, and the prediction models are reliable. The indoor accelerated wear of 44.5 h is equivalent to the field operation wear of 3 years. The research findings provide a theoretical basis for the evaluation of anti-skid performance, maintenance decision-making, and material optimization of asphalt pavements. Full article