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Keywords = N2O soil fluxes

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17 pages, 1459 KiB  
Article
Assessing Controlled Traffic Farming as a Precision Agriculture Strategy for Minimising N2O Losses
by Bawatharani Raveendrakumaran, Miles Grafton, Paramsothy Jeyakumar, Peter Bishop and Clive Davies
Nitrogen 2025, 6(3), 63; https://doi.org/10.3390/nitrogen6030063 - 4 Aug 2025
Abstract
Intensive vegetable farming emits high nitrous oxide (N2O) due to traffic-induced compaction, highlighting the need for preventing nitrogen (N) losses through better traffic management. This study examined the effects of Controlled Traffic Farming (CTF) and Random Traffic Farming (RTF) on N [...] Read more.
Intensive vegetable farming emits high nitrous oxide (N2O) due to traffic-induced compaction, highlighting the need for preventing nitrogen (N) losses through better traffic management. This study examined the effects of Controlled Traffic Farming (CTF) and Random Traffic Farming (RTF) on N2O emissions using intact soil cores (diameter: 18.7 cm; depth: 25 cm) collected from a vegetable production system in Pukekohe, New Zealand. Soil cores from CTF beds, CTF tramlines, and RTF plots were analysed under fertilised (140 kg N/ha) and unfertilised conditions. N2O fluxes were monitored over 58 days using gas chambers. The fertilised RTF system significantly (p < 0.05) increased N2O emissions (5.4 kg N2O–N/ha) compared to the unfertilised RTF system (1.53 kg N2O–N/ha). The emission from fertilised RTF was 46% higher than the maximum N2O emissions (3.7 kg N2O–N/ha) reported under New Zealand pasture conditions. The fertilised CTF system showed a 31.6% reduction in N2O emissions compared to fertilised RTF and did not differ significantly from unfertilised CTF. In general, CTF has demonstrated some resilience against fertiliser-induced N2O emissions, indicating the need for further investigation into its role as a greenhouse gas mitigation strategy. Full article
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19 pages, 3536 KiB  
Article
Loss and Early Recovery of Biomass and Soil Organic Carbon in Restored Mangroves After Paspalum vaginatum Invasion in West Africa
by Julio César Chávez Barrera, Juan Fernando Gallardo Lancho, Robert Puschendorf and Claudia Maricusa Agraz Hernández
Resources 2025, 14(8), 122; https://doi.org/10.3390/resources14080122 - 29 Jul 2025
Viewed by 264
Abstract
Invasive plant species pose an increasing threat to mangroves globally. This study assessed the impact of Paspalum vaginatum invasion on carbon loss and early recovery following four years of restoration in a mangrove forest with Rhizophora racemosa in Benin. Organic carbon was quantified [...] Read more.
Invasive plant species pose an increasing threat to mangroves globally. This study assessed the impact of Paspalum vaginatum invasion on carbon loss and early recovery following four years of restoration in a mangrove forest with Rhizophora racemosa in Benin. Organic carbon was quantified in the total biomass, including both aboveground and belowground components, as well as in the soil to a depth of −50 cm. In addition, soil gas fluxes of CO2, CH4, and N2O were measured. Three sites were evaluated: a conserved mangrove, a site degraded by P. vaginatum, and the same site post-restoration via hydrological rehabilitation and reforestation. Invasion significantly reduced carbon storage, especially in soil, due to lower biomass, incorporation of low C/N ratio organic residues, and compaction. Restoration recovered 7.8% of the total biomass carbon compared to the conserved mangrove site, although soil organic carbon did not rise significantly in the short term. However, improvements in deep soil C/N ratios (15–30 and 30–50 cm) suggest enhanced soil organic matter recalcitrance linked to R. racemosa reforestation. Soil CO2 emissions dropped by 60% at the restored site, underscoring restoration’s potential to mitigate early carbon loss. These results highlight the need to control invasive species and suggest that restoration can generate additional social benefits. Full article
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20 pages, 2635 KiB  
Article
Regulation of CH4 and N2O Emissions by Biochar Application in a Salt-Affected Sorghum Farmland
by Yibo Zhao, Wei Yang, Zhongyi Qu, Liping Wang, Yixuan Yang and Yusheng Hao
Agriculture 2025, 15(15), 1592; https://doi.org/10.3390/agriculture15151592 - 24 Jul 2025
Viewed by 251
Abstract
The ameliorative mechanism of biochar in reducing soil greenhouse gas emissions in arid saline farmland remains unclear. A two-year field study in sorghum farmland in China’s Hetao Irrigation District was conducted to assess the influence of corn straw-derived biochar on GHG emissions and [...] Read more.
The ameliorative mechanism of biochar in reducing soil greenhouse gas emissions in arid saline farmland remains unclear. A two-year field study in sorghum farmland in China’s Hetao Irrigation District was conducted to assess the influence of corn straw-derived biochar on GHG emissions and explore the role of soil physicochemical properties in regulating GHG fluxes. Four different biochar application rates were tested: 0 (CK), 15 (C15), 30 (C30), and 45 t hm−2 (C45). Compared to CK, C15 reduced CH4 emissions by 15.2% and seasonal CH4 flux by 77.0%. The N2O flux followed CK > C45 > C30 > C15 from 2021 to 2022. C15 and C30 significantly decreased GWP, mitigating GHG emission intensity. Biochar application enhanced sorghum grain yield. Soil temperature was the primary determinant of CH4 flux (total effect = 0.92). In the second year, biochar’s influence on CH4 emissions increased by 0.76. Multivariate SEM identified soil moisture (total effect = −0.72) and soil temperature (total effect = −0.70) as primary negative regulators of N2O fluxes. C40 lead to salt accumulation, which increases CH4 emissions but inhibits N2O emissions. Averaged over two years, GWP under C15 and C30 decreased by 76.5–106.7% and 5.3–56.1%, respectively, compared to CK. Overall, the application of biochar at a rate of 15 t hm−2 significantly reduced CH4 and N2O emissions and increased sorghum yield. Full article
(This article belongs to the Section Agricultural Soils)
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23 pages, 2618 KiB  
Article
The Impact of Rice–Frog Co-Cultivation on Greenhouse Gas Emissions of Reclaimed Paddy Fields
by Haochen Huang, Zhigang Wang, Yunshuang Ma, Piao Zhu, Xinhao Zhang, Hao Chen, Han Li and Rongquan Zheng
Biology 2025, 14(7), 861; https://doi.org/10.3390/biology14070861 - 16 Jul 2025
Viewed by 319
Abstract
Reclaimed fields have a low soil fertility and low productivity compared to conventional arable land, necessitating research on productivity enhancement. The rice–frog co-culture model is an ecologically intensive practice that combines biodiversity objectives with agricultural production needs, offering high ecological and economic value. [...] Read more.
Reclaimed fields have a low soil fertility and low productivity compared to conventional arable land, necessitating research on productivity enhancement. The rice–frog co-culture model is an ecologically intensive practice that combines biodiversity objectives with agricultural production needs, offering high ecological and economic value. However, there is a lack of research on this model that has focused on factors other than soil nutrient levels. The present study evaluated the rice–frog co-culture model in a reclaimed paddy field across three experimental plots with varying frog stocking densities: a rice monoculture (CG), low-density co-culture (LRF), and high-density co-culture (HRF). We investigated the effects of the frog density on greenhouse gas emissions throughout the rice growth. The rice–frog co-culture model significantly reduced methane (CH4) emissions, with fluxes highest in the CG plot, followed by the LRF and then HRF plots. This reduction was achieved by altering the soil pH, the cation exchange capacity, the mcrA gene abundance, and the mcrA/pmoA gene abundance ratio. However, there was a contrasting nitrous oxide (N2O) emission pattern. The co-culture model actually increased N2O emissions, with fluxes being highest in the HRF plots, followed by the LRF and then CG plots. The correlation analysis identified the soil nosZ gene abundance, redox potential, urease activity, nirS gene abundance, and ratio of the combined nirK and nirS abundance to the nosZ abundance as key factors associated with N2O emissions. While the co-cultivation model increased N2O emissions, it also significantly reduced CH4 emissions. Overall, the rice–frog co-culture model, especially at a high density, offers a favorable sustainable agricultural production model. Full article
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18 pages, 1414 KiB  
Article
Field Validation of the DNDC-Rice Model for Crop Yield, Nitrous Oxide Emissions and Carbon Sequestration in a Soybean System with Rye Cover Crop Management
by Qiliang Huang, Nobuko Katayanagi, Masakazu Komatsuzaki and Tamon Fumoto
Agriculture 2025, 15(14), 1525; https://doi.org/10.3390/agriculture15141525 - 15 Jul 2025
Viewed by 394
Abstract
The DNDC-Rice model effectively simulates yield and greenhouse gas emissions within a paddy system, while its performance under upland conditions remains unclear. Using data from a long-term cover crop experiment (fallow [FA] vs. rye [RY]) in a soybean field, this study validated the [...] Read more.
The DNDC-Rice model effectively simulates yield and greenhouse gas emissions within a paddy system, while its performance under upland conditions remains unclear. Using data from a long-term cover crop experiment (fallow [FA] vs. rye [RY]) in a soybean field, this study validated the DNDC-Rice model’s performance in simulating soil dynamics, crop growth, and C-N cycling processes in upland systems through various indicators, including soil temperature, water-filled pore space (WFPS), soybean biomass and yield, CO2 and N2O fluxes, and soil organic carbon (SOC). Based on simulated results, the underestimation of cumulative N2O flux (25.6% in FA and 5.1% in RY) was attributed to both underestimated WFPS and the algorithm’s limitations in simulating N2O emission pulses. Overestimated soybean growth increased respiration, leading to the overestimation of CO2 flux. Although the model captured trends in SOC stock, the simulated annual values differed from observations (−9.9% to +10.1%), potentially due to sampling errors. These findings indicate that the DNDC-Rice model requires improvements in its N cycling algorithm and crop growth sub-models to improve predictions for upland systems. This study provides validation evidence for applying DNDC-Rice to upland systems and offers direction for improving model simulation in paddy-upland rotation systems, thereby enhancing its applicability in such contexts. Full article
(This article belongs to the Special Issue Detection and Management of Agricultural Non-Point Source Pollution)
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20 pages, 2217 KiB  
Article
Organic Nitrogen Substitution Enhances Carbon Sequestration but Increases Greenhouse Gas Emissions in Maize Cropping Systems
by Yanan Liu, Xiaoqing Zhao, Yuchen Cheng, Rui Xie, Tiantian Meng, Liyu Chen, Yongfeng Ren, Chunlei Xue, Kun Zhao, Shuli Wei, Jing Fang, Xiangqian Zhang, Fengcheng Sun and Zhanyuan Lu
Agronomy 2025, 15(7), 1703; https://doi.org/10.3390/agronomy15071703 - 15 Jul 2025
Viewed by 348
Abstract
Excessive chemical fertilizers degrade soil and increase greenhouse gas (GHG) emissions. Organic substitution of nitrogen fertilizers is recognized as a sustainable agricultural-management practice, yet its dual role in carbon sequestration and emissions renders the net GHG balance (NGHGB) uncertain. To assess the GHG [...] Read more.
Excessive chemical fertilizers degrade soil and increase greenhouse gas (GHG) emissions. Organic substitution of nitrogen fertilizers is recognized as a sustainable agricultural-management practice, yet its dual role in carbon sequestration and emissions renders the net GHG balance (NGHGB) uncertain. To assess the GHG mitigation potential of organic substitution strategies, this study analyzed GHG fluxes, soil organic carbon (SOC) dynamics, indirect GHG emissions, and Net Primary Productivity (NPP) based on a long-term field positioning experiment initiated in 2016. Six fertilizer regimes were systematically compared: no fertilizer control (CK); only phosphorus and potassium fertilizer (PK); total chemical fertilizer (NPK); 1/3 chemical N substituted with sheep manure (OF1); dual substitution protocol with 1/6 chemical N substituted by sheep manure and 1/6 substituted by straw-derived N (OF2); complete chemical N substitution with sheep manure (OF3). The results showed that OF1 and OF2 maintained crop yields similar to those under NPK, whereas OF3 reduced yield by over 10%; relative to NPK, OF1, OF2, and OF3 significantly increased SOC sequestration rates by 50.70–149.20%, reduced CH4 uptake by 7.9–70.63%, increased CO2 emissions by 1.4–23.9%, decreased N2O fluxes by 3.6–56.2%, and mitigated indirect GHG emissions from farm inputs by 24.02–63.95%. The NGHGB was highest under OF1, 9.44–23.99% greater than under NPK. These findings demonstrate that partial organic substitution increased carbon sequestration, maintained crop yields, whereas high substitution rates increase the risk of carbon emissions. The study results indicate that substituting 1/3 of chemical nitrogen with sheep manure in maize cropping systems represents an effective fertilizer management approach to simultaneously balance productivity and ecological sustainability. Full article
(This article belongs to the Section Agroecology Innovation: Achieving System Resilience)
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14 pages, 671 KiB  
Article
Effects of Nitrogen and Phosphorus Additions on Soil N2O Emission and Soil Carbon Storage in Lakeshore Zone
by Sichen Qi, Guoxiu Jia, Weijia Cao, Wentao Zhong, Zhenxing Wang, Lixin Wang, Tiejun Liu, Jianying Guo and Lu Wen
Sustainability 2025, 17(13), 5987; https://doi.org/10.3390/su17135987 - 29 Jun 2025
Viewed by 450
Abstract
This study examined the short-term effects of nitrogen (N) and phosphorus (P) addition on soil N2O flux and organic carbon content in the lakeshore zone of an arid inland lake, Daihai. Treatments included control (N0P0), N addition (N1P0), P addition (N0P1), [...] Read more.
This study examined the short-term effects of nitrogen (N) and phosphorus (P) addition on soil N2O flux and organic carbon content in the lakeshore zone of an arid inland lake, Daihai. Treatments included control (N0P0), N addition (N1P0), P addition (N0P1), and NP co-addition (N1P1). Using the static chamber method and lab analyses, we measured soil N2O flux and organic carbon content at different growth stages. Results showed that, in the early growing season, short-term N and P addition had no significant effect on soil N2O flux, with all treatments acting as N2O sources. However, N and NP treatments significantly increased soil organic carbon (SOC) storage, improving carbon sequestration benefits by 72.7% to 98.1%. During the peak growing season, N and NP treatments significantly enhanced soil N2O emissions, while NP treatment further increased SOC storage, the carbon sequestration benefits of all treatments ranging from 49.0% to 56.5%. At the late growing season, N and P addition had no significant impact on soil N2O flux or organic carbon storage, with all sites acting as N2O sinks and SOC storage showing no significant change across treatments (carbon sequestration benefits ranged from 0.3% to 38.5%). The study highlights that the response of soil N2O flux to short-term N and P addition varies at different growth stages, while overall, N and P addition promotes soil carbon sequestration throughout the growing season in the lakeshore zone. Full article
(This article belongs to the Section Environmental Sustainability and Applications)
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23 pages, 4515 KiB  
Article
Impact of Coastal Beach Reclamation on Seasonal Greenhouse Gas Emissions: A Study of Diversified Saline–Alkaline Land Use Patterns
by Jiayi Xie, Ye Yuan, Xiaoqing Wang, Rui Zhang, Rui Zhong, Jiahao Zhai, Yumeng Lu, Jiawei Tao, Lijie Pu and Sihua Huang
Agriculture 2025, 15(13), 1403; https://doi.org/10.3390/agriculture15131403 - 29 Jun 2025
Viewed by 382
Abstract
Reclaiming coastal wetlands for agricultural purposes has led to intensified farming activities, which are anticipated to affect greenhouse gas (GHG) flux processes within coastal wetland ecosystems. However, how greenhouse gas exchanges respond to variations in agricultural reclamation activities across different years remains uncertain. [...] Read more.
Reclaiming coastal wetlands for agricultural purposes has led to intensified farming activities, which are anticipated to affect greenhouse gas (GHG) flux processes within coastal wetland ecosystems. However, how greenhouse gas exchanges respond to variations in agricultural reclamation activities across different years remains uncertain. To address this knowledge gap, this study characterized dynamic exchanges within the soil–plant–atmosphere continuum by employing continuous monitoring across four representative coastal wetland soil–vegetation systems in Jiangsu, China. The results show the carbon dioxide (CO2) and nitrous oxide (N2O) flux exchanges between the system and the atmosphere and soil–vegetation carbon pools, which revealed the drivers of carbon dynamics in the coastal wetland system. The four study sites, converted from coastal wetlands to agricultural lands at different times (years), generally act as CO2 sinks and N2O sources. Higher levels of CO2 sequestration occur as the age of reclamation rises. In terms of time scale, crops lands were found to be CO2 sinks during the growing period but became CO2 sources during the crop fallow period. Although the temporal trend of the N2O flux was generally smooth, reclaimed farmlands acted as net sources of N2O, particularly during the crop-growing period. The RDA and PLS-PM models illustrate that soil salinity, acidity, and hydrothermal conditions were the key drivers affecting the magnitude of the GHG flux exchanges under reclamation. This study demonstrates that GHG emissions from reclaimed wetlands can be effectively regulated through science-based land management, calling for prioritized attention to post-development practices rather than blanket restrictions on coastal exploitation. Full article
(This article belongs to the Section Agricultural Soils)
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17 pages, 7728 KiB  
Article
Comparative Effects of Nitrogen Fertigation and Granular Fertilizer Application on Pepper Yield and Soil GHGs Emissions
by Antonio Manco, Matteo Giaccone, Luca Vitale, Giuseppe Maglione, Maria Riccardi, Bruno Di Matteo, Andrea Esposito, Vincenzo Magliulo and Anna Tedeschi
Horticulturae 2025, 11(6), 708; https://doi.org/10.3390/horticulturae11060708 - 19 Jun 2025
Viewed by 738
Abstract
Quantitative greenhouse gas (GHG) budgets for Mediterranean pepper cultivation are still missing, limiting evidence-based nitrogen management. Furthermore, mitigation value of fertigation respect to granular fertilization in vegetable systems remains uncertain. This study therefore compared the GHG footprint and productivity of ‘papaccella’ pepper under [...] Read more.
Quantitative greenhouse gas (GHG) budgets for Mediterranean pepper cultivation are still missing, limiting evidence-based nitrogen management. Furthermore, mitigation value of fertigation respect to granular fertilization in vegetable systems remains uncertain. This study therefore compared the GHG footprint and productivity of ‘papaccella’ pepper under two nitrogen fertilization methods: granular fertilization versus low-frequency fertigation with urea, each supplying about 63 kg N ha−1. Eight automated static chambers coupled to a cavity ring-down spectrometer monitored soil CO2 and N2O fluxes throughout the season. Cumulative emissions did not differ between treatments (CO2: 811 ± 6 g m−2 vs. 881 ± 4 g m−2; N2O: 0.038 ± 0.008 g m−2 vs. 0.041 ± 0.015 g m−2, fertigation vs. granular), and marketable yield remained at ~11 t ha−1, leaving product-scaled global warming potential (GWP) unchanged. Although representing less than 2% of measured fluxes, “hot moments,” burst emissions exceeding four standard deviations (SD) from the mean, accounted for up to 4% of seasonal CO2 and 19% of N2O. Fertigation doubled the frequency of these events but reduced their peak magnitude, whereas granular application produced fewer but more extreme bursts (>11 SD). Results showed that fertigation did not mitigate GHGs emission nor improve productivity for Mediterranean pepper, mainly due to the low application frequency and the use of a urea fertilizer. Moreover, we can highlight that in horticultural systems, omitting ‘hot moments’ leads to systematic underestimation of emissions. Full article
(This article belongs to the Section Plant Nutrition)
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19 pages, 1200 KiB  
Article
Effects of Rice–Fish Coculture on Greenhouse Gas Emissions: A Case Study in Terraced Paddy Fields of Qingtian, China
by Qixuan Li, Lina Xie, Shiwei Lin, Xiangbing Cheng, Qigen Liu and Yalei Li
Agronomy 2025, 15(6), 1480; https://doi.org/10.3390/agronomy15061480 - 18 Jun 2025
Viewed by 544
Abstract
Rice–fish coculture, a traditional integrated agriculture–aquaculture system, has been recognized as a “Globally Important Agricultural Heritage System” due to its ecological and socio-economic benefits. However, the impact of rice–fish coculture on greenhouse gas emissions remains controversial. This study investigated the effects of rice–fish [...] Read more.
Rice–fish coculture, a traditional integrated agriculture–aquaculture system, has been recognized as a “Globally Important Agricultural Heritage System” due to its ecological and socio-economic benefits. However, the impact of rice–fish coculture on greenhouse gas emissions remains controversial. This study investigated the effects of rice–fish coculture on methane (CH4) and nitrous oxide (N2O) emissions in the Qingtian rice–fish system, a 1200-year-old terraced paddy field system in Zhejiang Province, China. A field experiment with two treatments, rice–fish coculture (RF) and rice monoculture (RM), was conducted to examine the relationships between fish activities, water and soil properties, microbial communities, and greenhouse gas fluxes. Results showed that the RF system had significantly higher CH4 emissions, particularly during the early rice growth stage, compared to the RM system. This increase was attributed to the lower dissolved oxygen levels and higher methanogen abundance in the RF system, likely driven by the grazing, “muddying”, and burrowing activities of fish. In contrast, no significant differences in N2O emissions were observed between the two systems. Redundancy analysis revealed that water variables contributed more to the variation in greenhouse gas emissions than soil variables. Microbial community analysis indicated that the RF system supported a more diverse microbial community involved in methane cycling processes. These findings provide new insights into the complex interactions between fish activities, environmental factors, and microbial communities in regulating greenhouse gas emissions from rice–fish coculture systems. The results suggest that optimizing water management strategies and exploring the potential of microbial community manipulation could help mitigate greenhouse gas emissions while maintaining the ecological and socio-economic benefits of these traditional integrated agriculture–aquaculture systems. Full article
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14 pages, 1413 KiB  
Article
Influence of Nitrogen Addition Levels on N2O Flux and Yield of Spring Wheat in the Loess Plateau
by Haiyan Wang, Jiangqi Wu, Guang Li and Jianyu Yuan
Agronomy 2025, 15(6), 1377; https://doi.org/10.3390/agronomy15061377 - 4 Jun 2025
Viewed by 399
Abstract
Nitrogen fertilizer plays a crucial role in enhancing soil fertility, impacting both crop yields and nitrous oxide (N2O) emissions from farmland soils. However, while nitrogen fertilizers increase yields, they also influence N2O emissions, and this relationship remains understudied in [...] Read more.
Nitrogen fertilizer plays a crucial role in enhancing soil fertility, impacting both crop yields and nitrous oxide (N2O) emissions from farmland soils. However, while nitrogen fertilizers increase yields, they also influence N2O emissions, and this relationship remains understudied in the Loess Plateau region of China. This study examined the effect of four nitrogen fertilizer levels—no nitrogen (CK), low (LN), medium (MN), and high (HN)—on N2O emissions and spring wheat yield. Over two years, nitrogen fertilization significantly increased N2O emissions, with HN treatment resulting in emissions 229.95%, 69.38%, and 46.52% higher than CK, LN, and MN, respectively. Emission fluxes exhibited strong seasonal variability, influenced by soil temperature, enzyme activity, and nitrogen availability. Spring wheat yields initially increased and then decreased, with the highest yields recorded under MN treatment (1283.67 and 1335.83 kg·ha−1). Given the sharp rise in N2O emissions due to nitrogen application in arid areas, the contribution of spring wheat soil to global warming and ozone depletion cannot be overlooked. Results suggest that a moderate nitrogen application of 110 kg·ha−1 in the Loess Plateau optimizes yield, enhances soil conditions, and mitigates N2O emissions, whereas excessive nitrogen leads to nitrate accumulation, exacerbating environmental issues like the greenhouse effect, and ultimately reducing wheat yield and causing economic losses. Full article
(This article belongs to the Section Agroecology Innovation: Achieving System Resilience)
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36 pages, 10376 KiB  
Article
Genetic K-Means Clustering of Soil Gas Anomalies for High-Enthalpy Geothermal Prospecting: A Multivariate Approach from Southern Tenerife, Canary Islands
by Ángel Morales González-Moro, Luca D’Auria and Nemesio M. Pérez Rodríguez
Geosciences 2025, 15(6), 204; https://doi.org/10.3390/geosciences15060204 - 1 Jun 2025
Viewed by 476
Abstract
High-enthalpy geothermal resources in volcanic settings often lack clear surface manifestations, requiring integrated, data-driven approaches to identify hidden reservoirs. In this study, we apply a multivariate clustering technique—genetic K-Means clustering (GKMC)—to a comprehensive soil gas dataset collected from 1050 sampling sites across the [...] Read more.
High-enthalpy geothermal resources in volcanic settings often lack clear surface manifestations, requiring integrated, data-driven approaches to identify hidden reservoirs. In this study, we apply a multivariate clustering technique—genetic K-Means clustering (GKMC)—to a comprehensive soil gas dataset collected from 1050 sampling sites across the ~100 km2 Garehagua mining license, located in the southern rift zone of Tenerife (Canary Islands). The survey included diffuse CO2 flux measurements and concentrations of key soil gases (He, H2, CH4, O2, N2, Ar isotopes, and 222Rn, among others). Statistical-graphical analysis using the Sinclair method allowed for an objective classification of geochemical anomalies relative to background populations. The GKMC algorithm segmented the dataset into geochemically coherent clusters. One cluster, defined by elevated CO2, helium, and 222Rn levels, showed a clear spatial correlation with inferred tectonic lineaments in the southern rift zone. These anomalies are interpreted as structurally controlled conduits for the ascent of deep magmatic-hydrothermal fluids. The findings support the presence of a concealed geothermal system structurally constrained in the southern region of Tenerife. This study demonstrates that integrating GKMC clustering with soil gas geochemistry offers a robust methodology for detecting hidden geothermal anomalies. By enhancing anomaly detection in areas with subtle or absent surface expression, this approach contributes to reducing exploration risk and provides a valuable decision-support tool for targeting future drilling operations in volcanic terrains. Full article
(This article belongs to the Section Geochemistry)
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18 pages, 3130 KiB  
Article
Effects of Exogenous Silicon Addition on Nitrification and Denitrification-Derived N2O Emissions from Moso Bamboo (Phyllostachys edulis) Forest Soil
by Jie Yang, Kecheng Wang, Lijun Liu, Yongchun Li, Jiasen Wu, Jinhuan Zhong, Rong Zheng, Lili Fan, Chengpeng Huang and Peikun Jiang
Land 2025, 14(5), 1004; https://doi.org/10.3390/land14051004 - 6 May 2025
Cited by 1 | Viewed by 382
Abstract
It has been reported that applying silicon (Si) to agricultural soils can reduce N2O emissions. But, we do not fully understand how this might work in forest ecosystems, especially in Phyllostachys edulis plantations. This study set out to determine how exogenous [...] Read more.
It has been reported that applying silicon (Si) to agricultural soils can reduce N2O emissions. But, we do not fully understand how this might work in forest ecosystems, especially in Phyllostachys edulis plantations. This study set out to determine how exogenous Si impacts soil nitrification and denitrification. Also, it aimed to assess their separate contributions to N2O emissions. A pot incubation experiment that lasted 28 days was carried out under controlled conditions. The soil used was collected from a bamboo plantation that is intensively managed. The treatments included adding silicon. Also, 3,4-dimethylpyrazole phosphate (DMPP) and acetylene (C2H2) were applied to specifically hold back nitrification and denitrification. We measured the rates of soil N2O emissions, the cumulative fluxes, and the concentrations of NH4+-N, NO3-N, and NO2-N. A positive correlation that was significant (p < 0.05) was found between N2O emissions and the levels of soil NO3-N. Adding Si continued to reduce both the emission rate and the cumulative flux in all of the treatment groups. Also worth mentioning is that the relative contribution of denitrification to N2O emissions dropped from 38.2% to 11.4%. Meanwhile, nitrification’s contribution went up from 61.8% to 88.6%. These findings show that adding Si mainly suppresses denitrification. And, by doing so, it lessens N2O emissions in bamboo plantations. This study underlines the potential of Si amendments. They could be used as an effective management strategy to reduce greenhouse-gas emissions in forest soils. It also provides a scientific basis for making Phyllostachys edulis ecosystems more sustainable. Full article
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15 pages, 2964 KiB  
Article
Monthly Diurnal Variations in Soil N2O Fluxes and Their Environmental Drivers in a Temperate Forest in Northeastern China: Insights from Continuous Automated Monitoring
by Chuying Guo, Leiming Zhang, Shenggong Li and Fuxi Ke
Forests 2025, 16(5), 766; https://doi.org/10.3390/f16050766 - 30 Apr 2025
Viewed by 318
Abstract
Global warming, driven by increased greenhouse gas emissions, is a critical global concern. However, long-term trends in emissions remain poorly understood due to limited year-round data. The automated chamber method was used for continuous monitoring of soil N2O fluxes in a [...] Read more.
Global warming, driven by increased greenhouse gas emissions, is a critical global concern. However, long-term trends in emissions remain poorly understood due to limited year-round data. The automated chamber method was used for continuous monitoring of soil N2O fluxes in a mixed forest in Northeast China’s Changbai Mountains, analyzing monthly diurnal patterns and their relationships with soil temperature (Ts) and soil volumetric water content (VWC). The results revealed significant diurnal and seasonal variations, with peak emissions at 11:00 during the growing season (May–October) and elevated nighttime fluxes in winter (March, April, November, and December). The optimal sampling time was 14:00, closely reflecting daily mean fluxes. Soil Ts and VWC were key drivers, with seasonal variability in their effects: N2O fluxes showed no significant relationship with Ts in January but strong correlations in February and March. The growing season Q10 values ranged from 0.4 to 7.2 (mean = 2.5), indicating high-temperature sensitivity. Soil VWC effects were complex, with moderate VWC promoting denitrification and excessive VWC suppressing microbial activity. These findings provide critical insights for optimizing N2O monitoring and improving emission estimates. Full article
(This article belongs to the Section Forest Soil)
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18 pages, 5286 KiB  
Article
Daily Variation of Soil Greenhouse Gas Fluxes in Rubber Plantations Under Different Levels of Organic Fertilizer Substitution
by Wangxin Zhang, Qingmian Chen, Hongyu Ran, Wen Lu, Wenxian Xu, Waqar Ali, Qiu Yang, Wenjie Liu, Mengyang Fang and Huai Yang
Forests 2025, 16(4), 706; https://doi.org/10.3390/f16040706 - 21 Apr 2025
Viewed by 388
Abstract
It has been widely recognized that replacing chemical fertilizers with organic fertilizers (organic substitution) could significantly increase the long-term productivity of the land and potentially enhance resilience to climate change. Nevertheless, there is limited information on the accurate monitoring of soil greenhouse gas [...] Read more.
It has been widely recognized that replacing chemical fertilizers with organic fertilizers (organic substitution) could significantly increase the long-term productivity of the land and potentially enhance resilience to climate change. Nevertheless, there is limited information on the accurate monitoring of soil greenhouse gas (GHG) fluxes at different levels of organic substitution in rubber plantations. Before accurate estimation of soil GHG fluxes can be made, it is important to investigate diurnal variations and suitable sampling times. In this study, six treatment groups of rubber plantations in the Longjiang Farm of Baisha Li autonomous county, Hainan Island, including the control (CK), conventional fertilizer (NPK), and organic substitution treatments in which organic fertilizer replaced 25% (25%M), 50% (50%M), 75% (75%M), and 100% (100%M) of chemical nitrogen fertilizer were selected as study objectives. The soil GHG fluxes were observed by static chamber-gas chromatography for a whole day (24 h) during both wet and dry seasons. The results showed the following: (1) There was a significant single-peak daily variation of GHGs in rubber plantation soils. (2) The soil GHG fluxes observed from 9:00–12:00 are closer to the daily average fluxes. (3) Organic fertilizer substitution influenced soil CO2 and N2O fluxes and had no significant effect on soil CH4 fluxes. Fluxes of soil CO2 and N2O increased firstly and then decreased gradually when the substitution ratios exceeded 50% or 75%. (4) Soil CO2 and N2O fluxes were positively correlated with soil temperature and soil moisture, and CH4 fluxes were negatively correlated with soil temperature and soil moisture in both wet and dry seasons. The study indicated that understanding the daily pattern of GHG changes in rubber forest soils under different levels of organic fertilizer substitution and the optimal observation time could improve the accurate assessment of long-timescale observation studies. Full article
(This article belongs to the Section Forest Soil)
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