Search Results (15)

Oats (Avena sativa L.) are forage grasses moderately tolerant to saline-alkali soil and are widely used for the improvement and utilization of saline-alkali land. Using the oat varieties collected from the Qaidam Basin as experimental materials, based on the analysis data of the main agronomic traits, quality, and soil physical and chemical properties of different oat varieties at the harvest stage. The hay yield of Molasses (17,933.33 kg·hm⁻²) was the highest (p < 0.05), the plant height (113.59 cm) and crude fat (3.02%) of Qinghai 444 were the highest (p < 0.05), the fresh-dry ratio (2.62), crude protein (7.43%), and total salt content in plants (68.33 g·kg⁻¹) of Qingtian No. 1 were the highest (p < 0.05), and the Relative forage value (RFV) of Baler (122.96) was the highest (p < 0.05). In the 0–15 cm and 15–30 cm soil layers of different oat varieties, the contents of pH, EC, total salt, Ca²⁺, Mg²⁺, and HCO₃⁻ showed a decreasing trend at the harvest stage compared to the seedling stage, while the contents of organic matter, total nitrogen, Cl⁻, and SO4²⁻ showed an increasing trend. The contents of K⁺ and Na⁺ maintained a relatively balanced relationship between the seedling stage and the harvest stage in the two soil layers. Qingtian No. 1, Qingyin No. 1, and Molasses all rank among the top three in terms of production performance and soil physical and chemical properties, and they are the oat varieties suitable for cultivation in the research area. Full article

Geothermal energy exploitation in urban areas necessitates robust real-time seismic monitoring for risk mitigation. While surface-based seismic networks are valuable, they are sensitive to anthropogenic noise. This study investigates the capabilities of borehole Distributed Acoustic Sensing (DAS) for local seismic monitoring of a geothermal field located in Munich, Germany. We leverage the operator’s cloud infrastructure for DAS data management and processing. We introduce a comprehensive workflow for the automated processing of DAS data, including seismic event detection, onset time picking, and event characterization. The latter includes the determination of the event hypocenter, origin time, seismic moment, and stress drop. Waveform-based parameters are obtained after the automatic conversion of the DAS strain-rate to acceleration. We present the results of a 6-month monitoring period that demonstrates the capabilities of the proposed monitoring set-up, from the management of DAS data volumes to the establishment of an event catalog. The comparison of the results with seismometer data shows that the phase and amplitude of DAS data can be reliably used for seismic processing. This emphasizes the potential of improving seismic monitoring capabilities with hybrid networks, combining surface and downhole seismometers with borehole DAS. The inherent high-density array configuration of borehole DAS proves particularly advantageous in urban and operational environments. This study stresses that realistic prior knowledge of the seismic velocity model remains essential to prevent a large number of DAS sensing points from biasing results and interpretation. This study suggests the potential for a gradual extension of the network as geothermal exploitation progresses and new wells are equipped, owing to the scalability of the described monitoring system. Full article

Morocco has an important geothermal potential materialized by its several thermal springs which constitute an essential surface geothermal indicator. These springs are dispersed throughout the country and present in every major structural domain. However, a significant amount is concentrated in the northern and northeastern areas. Associated with the great hydrothermal system of eastern Morocco, the thermal spring of Goutitir emerges in the Meso-Cenozoic sedimentary formations located east of the Guercif Basin, composed of a mixture of clays, carbonates, and marls, covered in unconformity by Quaternary tabular molasses. The upflow of the thermal water is dependent of Alpine faults systems with N30 and N100 directions, which are probable reactivated Hercynian structures that facilitate its circulation to the surface. The Goutitir spring has been studied by an interdisciplinary approach to identify the origin of the thermal water, the rock–water interactions, and the reservoir temperatures, contributing to the establishment of the conceptual model of the associated hydrothermal system. This thermal water is of chloride-sodium type with a hyperthermal character (43–47 °C). The isotopic composition (δ¹⁸O = −8.7 to −8.35‰; δ²H = −58.6 to −54.3‰) indicates a meteoric origin and a recharging zone located at around 2000 m of altitude. The chemical composition allows to classify the water as chloride-sodium hydrochemical facies, stabilized at ~100 °C in crystalline basement rocks, which, according to seismic data, are located at ~3 km depth. The concentrations, patterns, and correlations of trace elements point out water–rock interaction processes between the deep water and basic magmatic rocks. The integration of the chemical and isotopic data and the surface geological context shows that the Goutitir water flows within a hydrothermal zone were basic to ultrabasic lamprophyres rich in gabbroic xenoliths outcrop, witnessing the existence, at depth, of basic plutons. Moreover, near the source, these veins are strongly altered and hydrothermalized, showing late recrystallization of centimetric-sized biotites. The chloride-sodium composition of this water may also be a testimony to the presence and reaction with the overlying Triassic saline and gypsiferous and Meso-Cenozoic mainly carbonated formations. Full article

We investigated fault gases (helium, radon, CO₂) in two seismically active Cenozoic sedimentary basins: (a) Meinweg (in 2015), at a tectonically quiescent horst structure in the Lower Rhine Embayment; and (b) Bodanrück (in 2012; Lake of Constance), in the Molasse Basin and part of the seismically active Freiburg–Bonndorf–Bodensee Fault Zone (FBBFZ). Both study areas were selected because recent “GeoBio-Interactions” findings showed that red wood ants (RWA) are biological indicators of otherwise undetected degassing systems. We combined presence/absence data of RWA nests, their spatial pattern analysis (prototype lines), seismicity and known tectonic settings with soil gas analyses (a total of 817 samples) to unveil geochemical anomalies related to tectonic developments unknown so far. Currently, Meinweg can be considered “no ants land” due to the very low background-level of geogas concentrations. Thus, anomalies (Rn-CO₂) weakly trending in NE-SW extension direction emerged. This could probably indicate the onset of (re)activation of the NE-SW-trending (Variscan) structures or the development of new fractures as an aftershock process of the 1992 Roermond earthquake that occurred about 15 km to the west. Results at Bodanrück (three RWA clusters and two RWA-free corridors) revealed degassing patterns in NW-SE and NNE-SSW directions in the clusters corresponding to re-activated and recent strike-slip fault systems. No gas anomalies were found in RWA-free corridors. The RWA nest distribution was shown to be a valuable tool for identifying areas of even actively degassing spotty anomalies caused by macro- and microscale brittle deformation masked by sediment cover. Full article

Most temperature predictions for deep geothermal applications rely on correcting bottom-hole temperatures (BHTs) to undisturbed or static formation temperatures (SFTs). The data used for BHT correction are usually of low quality due to a lack of information and poor documentation, and the uncertainty of the corrected SFT is therefore unknown. It is supposed that the error within the input data exceeds the error due to the uncertainty of the different correction schemes. To verify this, we combined a global sensitivity study with Sobol indices of six easy-to-use conventional correction schemes of the BHT data set of the Bavarian Molasse Basin with an uncertainty study and developed a workflow that aims at presenting a valid error range of the corrected SFTs depending on the quality of their input data. The results give an indication of which of the investigated correction methods should be used depending on the input data, as well as show that the unknown error in the input parameters exceeds the error of the individual BHT correction methods as such. The developed a priori uncertainty-based BHT correction helps to provide a real estimate of the subsurface temperatures needed for geothermal prospecting and probabilistic risk assessment. Full article

We present a data set of calcite twinning strain results (n = 209 samples; 9919 measured calcite twins) from the internal Alpine nappes northwestward across the Alps and Alpine foreland to the older extensional margin along the Atlantic coast in Ireland. Along the coast of Northern Ireland, Cretaceous chalks and Tertiary basalts are cross-cut by calcite veins and offset by calcite-filled normal and strike-slip faults. Both Irish sample suites (n = 16 with four U-Pb vein calcite ages between 70–42 Ma) record a sub-horizontal SW-NE shortening strain with vertical extension and no strain overprint. This sub-horizontal shortening is parallel to the margin of the opening of the Atlantic Ocean (~58 Ma), and this penetrative fabric is only observed ~100 km inboard of the margin to the southeast. The younger, collisional Alpine orogen (~40 Ma) imparted a stress–strain regime dominated by SE-NW sub-horizontal shortening ~1200 km northwest from the Alps preserved in Mesozoic limestones and calcite veins (n = 32) in France, Germany and Britain. This layer-parallel shortening strain (−3.4%, 5% negative expected values) is preserved across the foreland in the plane of Alpine thrust shortening (SE-NW) along with numerous outcrop-scale contractional structures (i.e., folds, thrust faults). Calcite veins were observed in the Alpine foreland in numerous orientations and include both a SE-NW layer-parallel shortening fabric (n = 11) and a sub-vertical NE-SW vein-parallel shortening fabric (n = 4). Alpine foreland strains are compared with twinning strains from the frontal Jura Mountains (n = 9; layer-parallel shortening), the Molasse basin (n = 26; layer-parallel and layer-normal shortening), Pre-Alp nappes (n = 39; layer-parallel and layer-normal shortening), Helvetic and Penninic nappes (Penninic klippe; n = 46; layer-parallel and layer-normal shortening plus four striated U-Pb calcite vein ages ~24 Ma) and calcsilicates from the internal Tauern window (n = 4; layer-normal shortening). We provide a chronology of the stress–strain history of the European plate from 58 Ma through the Alpine orogen. Full article

The stratigraphic development of foreland basins has mainly been related to surface loading in the adjacent orogens, whereas the control of slab loads on these basins has received much less attention. This has also been the case for interpreting the relationships between the Oligocene to Micoene evolution of the European Alps and the North Alpine foreland basin or Molasse basin. In this trough, periods of rapid subsidence have generally been considered as a response to the growth of the Alpine topography, and thus to the construction of larger surface loads. However, such views conflict with observations where the surface growth in the Alps has been partly decoupled from the subsidence history in the basin. In addition, surface loads alone are not capable of explaining the contrasts in the stratigraphic development particularly between its central and eastern portions. Here, we present an alternative view on the evolution of the Molasse basin. We focus on the time interval between c. 30 and 15 Ma and relate the basin-scale development of this trough to the subduction processes, and thus to the development of slab loads beneath the European Alps. At 30 Ma, the western and central portions of this basin experienced a change from deep marine underfilled (Flysch stage) to overfilled terrestrial conditions (Molasse stage). During this time, however, a deep marine Flysch-type environment prevailed in the eastern part of the basin. This was also the final sedimentary sink as sediment was routed along the topographic axis from the western/central to the eastern part of this trough. We interpret the change from basin underfill to overfill in the western and central basin as a response to oceanic lithosphere slab-breakoff beneath the Central and Western Alps. This is considered to have resulted in a growth of the Alpine topography in these portions of the Alps, an increase in surface erosion and an augmentation in sediment supply to the basin, and thus in the observed change from basin underfill to overfill. In the eastern part of the basin, however, underfilled Flysch-type conditions prevailed until 20 Ma, and subsidence rates were higher than in the western and central parts. We interpret that high subsidence rates in the eastern Molasse occurred in response to slab loads beneath the Eastern Alps, where the subducted oceanic slab remained attached to the European plate and downwarped the plate in the East. Accordingly, in the central and western parts, the growth of the Alpine topography, the increase in sediment flux and the change from basin underfill to overfill most likely reflect the response to slab delamination beneath the Central Alps. In contrast, in the eastern part, the possibly subdued topography in the Eastern Alps, the low sediment flux and the maintenance of a deep marine Flysch-type basin records a situation where the oceanic slab was still attached to the European plate. The situation changed at 20 Ma, when the eastern part of the basin chronicled a change from deep marine (underfilled) to shallow marine and then terrestrial (overfilled conditions). During the same time, subsidence rates in the eastern basin decreased, deformation at the Alpine front came to a halt and sediment supply to the basin increased possibly in response to a growth of the topography in the Eastern Alps. This was also the time when the sediment routing in the basin axis changed from an east-directed sediment dispersal prior to 20 Ma, to a west-oriented sediment transport thereafter and thus to the opposite direction. We relate these changes to the occurrence of oceanic slab breakoff beneath the Eastern Alps, which most likely resulted in a rebound of the plate, a growth of the topography in the Eastern Alps and a larger sediment flux to the eastern portion of the basin. Beneath the Central and Western Alps, however, the continental lithosphere slab remained attached to the European plate, thereby resulting in a continued downwarping of the plate in its central and western portions. This plate downwarping beneath the central and western Molasse together with the rebound of the foreland plate in the East possibly explains the inversion of the drainage direction. We thus propose that slab loads beneath the Alps were presumably the most important drivers for the development of the Molasse basin at the basin scale. Full article

We describe here the results of the characterization of subsurface structures in an area of the south-eastern edge of the Bohemian Massif, in Austria by high-resolution geophysical survey techniques and advanced analysis methods of potential fields. The employed methods included potential field multiscale techniques for source-edge location and characterization of sources at depth. Our results confirmed the presence of already known structures: the location of the Diendorf Fault and the Moldanubian Shearzone are clearly recognized in the data at the same location as on the geological maps, even where the Diendorf fault is covered with sediments of the Molasse Basin. In addition, we detected several geological contacts between different rock types in the Bohemian Massif west of the Diendorf Fault. From our results, we were also able to quickly identify and image, without a priori information, previously unknown structures, such as faults with-depth-to-the top of about 500 m and magmatic intrusions about 400 m deep. Full article

The vernacular architecture in many regions in Eastern Austria was characterized by the use of unfired clay, at least until the 19th century, and in some areas until the 20th century. Farmhouses and associated farm buildings, such as storage buildings or press houses for the production of wine and cider, were erected using different earth construction techniques. The study area stretches from the Weinviertel, a region located in the province of Lower Austria in the north-east of Austria, to the Burgenland, a region located in the south-east of Austria, which belonged to Western Hungary until 1921. From a geological point of view, in the east of Austria—in the Vienna Basin and the Molasse Zone—huge areas of Tertiary clay are covered with loess deposits, which is the best-known basic material used in local earth-building traditions. A core question in the research on vernacular earthen heritage focuses on the impact of the geological conditions in Eastern Austria on the local earth-building techniques. The mineralogical composition of the different clays had an impact on the local building techniques. From a material-culture point of view, research on the relationship between the mineralogical properties of clay resources and local building techniques sheds light on the factors which influenced the evolution of certain vernacular building features. Tertiary clays and loess from the Pleistocene favoured the making of earth lumps, cob walls and adobe bricks over the whole Eastern Austrian region. Contrarily, regions in Burgenland with a high amount of gravel preferred, by tradition, to make walls by ramming. The clay mineral smectite acts as a binding agent in earth-building techniques over the whole investigated region—Weinviertel, Burgenland and Western Hungary. Full article

Shales contain magnetic minerals generally at very low concentrations. In the early stages of diagenesis, the inherited magnetic minerals are altered, while magnetic nanominerals are formed. In this study, we proposed a study of shales over a stratigraphic thickness of 1.3 km from a borehole in the Paris basin (Borehole EST 433, France), and shales from the same formation (Opalinus Clay) collected in seven boreholes in the Jura molasse basin (Swiss). Magnetic measurements at experimental temperatures <30 K allowed the formation of a proxy of magnetite nanograins named PM. We showed that some of these nanograins formed around the pyrite grains, probably under the action of temperature and organic matter. PM was then compared to the maturity values of the organic matter. We found a correlation between PM and the percentage of reflectance of vitrinite. The shales from both Paris and molassic Swiss basins showed very comparable magnetic characteristics for a given maturity level. The magnetic study therefore provided constraints on the maturity level of the shales in the oil window area. Our study showed that PM can be used as a geothermometer in shales in which CaCO₃ is lower than 60%. Full article

A comprehensive hydrogeological understanding of the deep Upper Jurassic carbonate aquifer, which represents an important geothermal reservoir in the South German Molasse Basin (SGMB), is crucial for improved and sustainable groundwater resource management. Water chemical data and environmental isotope analyses of δD, δ${}^{18}$O and ${}^{87}$Sr/${}^{86}$Sr were obtained from groundwater of 24 deep Upper Jurassic geothermal wells and coupled with a few analyses of noble gases (${}^3$He/${}^4$He, ${}^{40}$Ar/${}^{36}$Ar) and noble gas infiltration temperatures. Hierarchical cluster analysis revealed three major water types and allowed a hydrochemical zoning of the SGMB, while exploratory factor analyses identified the hydrogeological processes affecting the water chemical composition of the thermal water. Water types 1 and 2 are of Na-[Ca]-HCO${}_3$-Cl type, lowly mineralised and have been recharged under meteoric cold climate conditions. Both water types show ${}^{87}$Sr/${}^{86}$Sr signatures, stable water isotopes values and calculated apparent mean residence times, which suggest minor water-rock interaction within a hydraulically active flow system of the Northeastern and Southeastern Central Molasse Basin. This thermal groundwater have been most likely subglacially recharged in the south of the SGMB in close proximity to the Bavarian Alps with a delineated northwards flow direction. Highly mineralised groundwater of water type 3 (Na-Cl-HCO${}_3$ and Na-Cl) occurs in the Eastern Central Molasse Basin. In contrast to water types 1 and 2, this water type shows substantial water-rock interaction with terrestrial sediments and increasing ${}^{40}$Ar/${}^{36}$Ar ratios, which may also imply a hydraulic exchange with fossil formation waters of overlying Tertiary sediments. Full article

This work presents new apatite fission track LA–ICP–MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) data from Mid–Late Paleozoic rocks, which form the substratum of the Swiss Jura mountains (the Tabular Jura and the Jura fold-and-thrust belt) and the northern margin of the Swiss Molasse Basin. Samples were collected from cores of deep boreholes drilled in North Switzerland in the 1980s, which reached the crystalline basement. Our thermochronological data show that the region experienced a multi-cycle history of heating and cooling that we ascribe to burial and exhumation, respectively. Sedimentation in the Swiss Jura Mountains occurred continuously from Early Triassic to Early Cretaceous, leading to the deposition of maximum 2 km of sediments. Subsequently, less than 1 km of Lower Cretaceous and Upper Jurassic sediments were slowly eroded during the Late Cretaceous, plausibly as a consequence of the northward migration of the forebulge of the neo-forming North Alpine Foreland Basin. Following this event, the whole region remained relatively stable throughout the Paleogene. Our data show that the Tabular Jura region resumed exhumation at low rates in early–middle Miocene times (≈20–15 Ma), whereas exhumation in the Jura fold-and-thrust belt probably re-started later, in the late Miocene (≈10–5 Ma). Erosional exhumation likely continues to the present day. Despite sampling limitations, our thermochronological data record discrete periods of slow cooling (rates of about 1°C/My), which might preclude models of elevated cooling (due to intense erosion) in the Jura Mountains during the Miocene. The denudation (≈1 km) of the Tabular Jura region and the Jura fold-and-thrust belt (≈500 m) has provided sediments to the Swiss Molasse Basin since at least 20 Ma. The southward migration of deformation in the Jura mountains suggests that the molasse basin started to uplift and exhume only after 5 Ma, as suggested also by previous authors. The data presented here show that the deformation of the whole region is occurring in an out-of-sequence trend, which is more likely associated with the reactivation of thrust faults beneath the foreland basin. This deformation trend suggests that tectonics is the most determinant factor controlling denudation and exhumation of the region, whereas the recently proposed “climate-induced exhumation” mechanism might play a secondary role. Full article

Hydromechanical models of gas storage in porous media provide valuable information for various applications ranging from the prediction of ground surface displacements to the determination of maximum reservoir pressure and storage capacity to maintain fault stability and caprock integrity. A workflow to set up such models is presented and applied to a former gas field in southern Germany for which transformation to a gas storage site is considered. The workflow comprises 1D mechanical earth modeling (1D MEM) to calculate elastic properties as well as a first estimate for the vertical and horizontal stresses at well locations by using log data. This information is then used to populate a 3D finite element model (3D MEM) which has been built from seismic data and comprises not only the reservoir but the entire overburden up to the earth’s surface as well as part of the underburden. The size of this model is 30 × 24 × 5 km³. The pore pressure field has been derived from dynamic fluid flow simulation through history matching for the production and subsequent shut-in phase. The validated model is ready to be used for analyzing new wells for future field development and testing arbitrary injection-production schedules, among others. Full article

Knowing how stream discharge in an ungauged catchment reacts to dry spells is a major challenge for managing water resources. The role of geology on these dynamics is poorly understood. For the Swiss Molasse basin, we therefore explored how the geology influences the groundwater contribution to stream flow during low-flow conditions. Using existing data from geological reports and maps as well as from deep boreholes, we constructed a basin-wide overview of the hydrogeological quality of the bedrock and investigated five catchments in 3D. We found that catchments with the most permeable sedimentary bedrock are least sensitive to low flows (marine sandstone, K = 10⁻⁴ to 10⁻⁵ m/s, P_eff = 5–10%). In contrast, if bedrock K is low (K < 10⁻⁶ m/s), the presence of a productive Quaternary volume becomes decisive for groundwater contribution to stream flow. Limitations exist due to a restricted database for K and P_eff values of the Molasse and limited information on continuation of lithologies with depth. This emphasizes the need for more hydrogeologically relevant data for the future management of water resources. Our results highlighting what lithotypes favor groundwater contribution to stream flow are valid also in other regions for the assessment of a catchment’s sensitivity to low flows. Full article

Geothermal power plants based on the organic Rankine cycle (ORC) are used to convert the thermal power of brine into electricity. The efficiency and profitability of these power plants can be increased by an additional heat supply. The purpose of this study is to evaluate different combined heat and power (CHP) concepts for geothermal applications by thermodynamic and economic considerations. Therefore, a dynamic simulation model of a double-stage ORC is developed to perform annual return simulations. The transient ORC model is validated in a wide range by operational data of an existing power plant in the German Molasse Basin. A district heating system is considered and the corresponding heat load profiles are derived from a real geothermal driven heating network. For CHP, parallel and combined configurations are considered. The validation of the transient model is satisfying with a correlation coefficient of 0.99 between the simulation and real power plant data. The results show that additional heat extraction leads to a higher exergetic efficiency and a higher profitability. The exergetic efficiency and the profitability are increased by up to 7.9% and 16.1%, respectively. The combined concept shows a slightly better performance than the parallel configuration. The efficiency can be increased by up to 1.3%. In economic terms, for CHP the annual return can be increased by at least 2,500,000 €. In principle, the dynamic model shows reliable results for high power gradients. This enables an investigation of geothermal ORC models for the reserve market in future works. Full article