Search Results (16)

In bulk heterojunction (BHJ) organic solar cells (OSCs) employing perylene diimide (PDI)-based non-fullerene acceptors, excessive intermolecular interactions among PDI units lead to severe aggregation and pronounced donor–acceptor phase separation, both of which critically limit device performance. To address these issues, numerous structurally engineered PDI derivatives have been developed. In particular, twisted multi-PDI architectures designed to suppress intermolecular aggregation have shown improved morphological control; however, such twisted structures are often highly amorphous, which reduces electron-transport efficiency and constrains OSC performance. In this work, we introduce a mixed-acceptor strategy combining a twisted PDI dimer (SF-PDI₂) with a planar monomeric PDI (m-PDI) to balance aggregation and morphological uniformity. Ternary blend OSCs consisting of PTB7-Th as the donor and these two PDI acceptors exhibit systematic performance variations depending on their relative ratios. At the optimized composition (SF-PDI₂:m-PDI = 90:10 by weight), the device outperforms single-acceptor systems, which is attributed to controlled aggregation arising from the complementary structural features of the two PDI acceptors. This study demonstrates that combining mixed PDI acceptors with similar molecular moieties enables precise control of aggregation, improving both morphology and photovoltaic performance. Full article

This study aimed to address the challenge of monitoring and managing soil moisture in dryland agriculture with supplemental irrigation under increasingly extreme climate conditions. Using unmanned aerial vehicles (UAVs) equipped with hyperspectral sensors, we collected imagery of wheat fields on Kinmen Island at various growth stages. The Modified Perpendicular Drought Index (MPDI) was calculated to quantify soil drought conditions. Simultaneously, soil samples were collected to measure the actual soil moisture content. These datasets were used to develop a Gradient Boosting Regression (GBR) model to estimate soil moisture across the entire field. The resulting AI-based model can guide decisions on the timing and scale of supplemental irrigation, ensuring water is applied only when needed during crop growth. Furthermore, MPDI values and wheat spike samples were used to construct another GBR model for yield prediction. When applying MPDI values from multispectral imagery collected at a similar stage in the following year, the model achieved a prediction accuracy of over 90%. The proposed approach offers a reliable solution for enhancing the resilience and productivity of dryland crops under climate stress and demonstrates the potential of integrating remote sensing and machine learning in precision water management. Full article

Droughts are a major driver of global environmental degradation, threatening lives and causing significant economic losses, with approximately 80% of these losses linked to agricultural drought, characterized by soil moisture deficits. Remote sensing technology offers high spatiotemporal resolution data for continuous monitoring of soil moisture and drought severity. However, the effectiveness of remote sensing drought indices across different soil depths remains unclear. This study assessed the performance of eight widely used drought indices—Perpendicular Drought Index (PDI), Modified Perpendicular Drought Index (MPDI), Temperature Condition Index (TCI), Vegetation Condition Index (VCI), Vegetation Health Index (VHI), Normalized Vegetation Supply Water Index (NVSWI), Temperature–Vegetation Dryness Index (TVDI), and Standardized Precipitation–Evapotranspiration Index (SPEI) at multiple timescales—in monitoring soil moisture at five depths (0–50 cm, at 10 cm intervals) across nine agricultural regions of China from 2001 to 2020. Results reveal that the monitoring performance of drought indices varies significantly across regions and soil depths, with a general decline in performance as soil depth increases. For soil depths between 10–40 cm, VCI and NVSWI exhibited the highest accuracy, while PDI, MPDI, and VHI performed optimally in the Northeast China Plain. At 50 cm depth, however, optical remote sensing indices struggled to accurately capture soil moisture conditions. Additionally, TCI and TVDI showed notable lag effects, with 4-month and 5-month delays, respectively, while SPEI exhibited cumulative effects over 3–6 months. These findings provide critical insights to guide the selection of appropriate drought indices for soil moisture monitoring, aiding agricultural drought management and decision-making. Full article

The demand for preserving existing roadway infrastructure has been increasing to regulate expensive reconstruction activities. The maintenance of homogeneous road sections is one of the approaches to economize the overall management of pavement systems. The existing homogeneous delineation methods consider one or two parameters for segmenting the pavements based on similar characteristics, which are found to be a repetitive process. Also, there is a need to consider multiple parameters that represent the functional, structural, and traffic characteristics in segmentation process. Therefore, the objective of this study was to develop a multi-parameter-based delineation approach (MPDA) to segment the pavements into subsections with similar features considering functional, structural, and traffic characteristics. Deflection bowl parameters, unified pavement health index (functional performance metric), surface layer modulus, and traffic reported in terms of AADT were employed for developing a multi-parametric delineation index (MPDI). A total of 1781 datapoints covering 26 road sections in the State of Andhra Pradesh, India, were used. The C-charts method-based segmentation for MPDI was applied to obtain the homogeneous sections. The devised approach was found to be efficient in segmenting the pavements as well as robust in selecting suitable maintenance strategies for each group of the homogeneous sections. Further, the segmentation processes were automated for easier implementation by the agencies. Full article

Maintenance of homogeneous road sections is one of the approaches to economizing the overall management of pavement systems. The objective of this study was to develop a multi-parameter-based delineation approach to segmenting the pavements into subsections in a way that considers multiple pavement characteristics. Deflection bowl parameters, pavement functional performance, surface layer modulus, and traffic were analyzed to develop a multi-parametric delineation index (MPDI), which was used in C-charts-based segmentation to obtain homogeneous sections. Importantly, the segmentation processes were automated using a deep neural network designed for rational implementation by practitioners. The devised approach was found to be efficient in segmenting the pavements, selecting the sections that are in direst need of maintenance, and necessitating prompt response from the agencies. Full article

Land surface microwave emissivity is crucial to the accurate retrieval of surface and atmospheric parameters and the assimilation of microwave data into numerical models over land. The microwave radiation imager (MWRI) sensors aboard on Chinese FengYun-3 (FY-3) series satellites provide valuable measurements for the derivation of global microwave physical parameters. In this study, an approximated microwave radiation transfer equation was used to estimate land surface emissivity from MWRI by using brightness temperature observations along with corresponding land and atmospheric properties obtained from ERA-Interim reanalysis data. Surface microwave emissivity at the 10.65, 18.7, 23.8, 36.5, and 89 GHz vertical and horizontal polarizations was derived. Then, the global spatial distribution and spectrum characteristics of emissivity over different land cover types were investigated. The seasonal variations of emissivity for different surface properties were presented. Furthermore, the error source was also discussed in our emissivity derivation. The results showed that the estimated emissivity was able to capture the major large-scale features and contains a wealth of information regarding soil moisture and vegetation density. The emissivity increased with the increase in frequency. The smaller surface roughness and increased scattering effect may result in low emissivity. Desert regions showed high emissivity microwave polarization difference index (MPDI) values, which suggested the high contrast between vertical and horizontal microwave signals in this region. The emissivity of the deciduous needleleaf forest in summer was almost the greatest among different land cover types. There was a sharp decrease in the emissivity at 89 GHz in the winter, possibly due to the influence of deciduous leaves and snowfall. The land surface temperature, the radio-frequency interference, and the high-frequency channel under cloudy conditions may be the main error sources in this retrieval. This work showed the potential capabilities of providing continuous and comprehensive global surface microwave emissivity from FY-3 series satellites for a better understanding of its spatiotemporal variability and underlying processes. Full article

As the fundamental regulator of energy exchange in the vegetation–soil–atmosphere circulation system, soil moisture is a key parameter for drought monitoring and is indispensable to the land surface hydrological processes. In order to overcome the constraints of the Perpendicular Drought Index, PDI (performs poorly over the fields with dense vegetation and hard to construct the soil line), and the Temperature Vegetation Drought Index, TVDI (requires similar atmospheric forcing and large enough dimension of mapping area), in soil moisture monitoring, a new drought index (Normalized Temperature Drought Index, NTDI) is proposed to explore the spatiotemporal changes of soil moisture by substituting red and near-infrared reflectances with vegetation index and normalized land surface temperature on the basis of the PDI framework. Victoria, Australia, was selected as the study area as it experiences many severe droughts and has been affected for more than ten years. Time series of satellite-based data were applied to evaluate the effectiveness and applicability of the NTDI at the regional scale. Results indicated that the expression of the soil line representing the water condition of the bare soil is easier to obtain in the new trapezoid framework and has good fits with the coefficients of determination (R²) of more than 0.8. Compared with PDI, TVDI and Modified PDI (MPDI) at the cropping sites, NTDI exhibits a relatively better performance in soil moisture monitoring for most days where the R² achieved can reach to more than 0.7 on DOY 242, 254 and 272. Meanwhile, spatial–temporal mappings of the four drought indices from satellite data were conducted, and the NTDI presented the slightly seasonal variation and effectively described the real spatial characteristics of regional drought. Overall, the NTDI seems to a viable approach and can provide insight into spatial and temporal soil moisture monitoring at different scales. Full article

Soil moisture (SM) is an important parameter in land surface processes and the global water cycle. Remote sensing technologies are widely used to produce global-scale SM products (e.g., European Space Agency’s Climate Change Initiative (ESA CCI)). However, the current spatial resolutions of such products are low (e.g., >3 km). In recent years, using auxiliary data to downscale the spatial resolutions of SM products has been a hot research topic in the remote sensing research area. A new method, which spatially downscalesan SM product to generate a daily SM dataset at a 16 m spatial resolution based on a spatiotemporal fusion model (STFM) and modified perpendicular drought index (MPDI), was proposed in this paper. (1) First, a daily surface reflectance dataset with a 16 m spatial resolution was produced based on an STFM. (2) Then, a spatial scale conversion factor (SSCF) dataset was obtained by an MPDI dataset, which was calculated based on the dataset fused in the first step. (3) Third, a downscaled daily SM product with a 16 m spatial resolution was generated by combining the SSCF dataset and the original SM product. Five cities in southern Hebei Province were selected as study areas. Two 16 m GF6 images and nine 500 m MOD09GA images were used as auxiliary data to downscale a timeseries 25 km CCI SM dataset for nine dates from May to June 2019. A total of 151 in situ SM observations collected on 1 May, 21 May, 1 June, and 11 June were used for verification. The results indicated that the downscaled SM data with a 16 m spatial resolution had higher correlation coefficients and lower RMSE values compared with the original CCI SM data. The correlation coefficients between the downscaled SM data and in situ data ranged from 0.45 to 0.67 versus 0.33 to 0.54 for the original CCI SM data; the RMSE values ranged from 0.023 to 0.031 cm³/cm³ versus 0.027 to 0.032 cm³/cm³ for the original CCI SM data. The findings described in this paper can ensure effective farmland management and other practical production applications. Full article

High-throughput, pillar-strip-based assays have been proposed as a drug-safety screening tool for developmental toxicity. In the assay described here, muscle cell culture and differentiation were allowed to occur at the end of a pillar strip (eight pillars) compatible with commercially available 96-well plates. Previous approaches to characterize cellular differentiation with immunostaining required a burdensome number of washing steps; these multiple washes also resulted in a high proportion of cellular loss resulting in poor yield. To overcome these limitations, the approach described here utilizes cell growth by easily moving the pillars for washing and immunostaining without significant loss of cells. Thus, the present pillar-strip approach is deemed suitable for monitoring high-throughput myogenic differentiation. Using this experimental high-throughput approach, eight drugs (including two well-known myogenic inhibitory drugs) were tested at six doses in triplicate, which allows for the generation of dose–response curves of nuclei and myotubes in a 96-well platform. As a result of comparing these F-actin (an actin-cytoskeleton protein), nucleus, and myotube data, two proposed differentiation indices—curve-area-based differentiation index (CA-DI) and maximum-point-based differentiation index (MP-DI) were generated. Both indices successfully allowed for screening of high-myogenic inhibitory drugs, and the maximum-point-based differentiation index (MP-DI) experimentally demonstrated sensitivity for quantifying drugs that inhibited myogenic differentiation. Full article

The temperature vegetation dryness index (TVDI) has been commonly implemented to estimate regional soil moisture in arid and semi-arid regions. However, the parameterization of the dry edge in the TVDI model is performed with a constraint to define the maximum water stress conditions. Mismatch of the spatial scale between visible and thermal bands retrieved from remotely sensed data and terrain variations also affect the effectiveness of the TVDI. Therefore, this study proposed a new drought index named the condition vegetation drought index (CVDI) to monitor the temporal and spatial variations of soil moisture status by substituting the land surface temperature (LST) with the modified perpendicular drought index (MPDI). In situ soil moisture observations at crop and pasture sites in Victoria were used to validate the effectiveness of the CVDI. The results indicate that the dry and wet edges in the parameterization scheme of the CVDI formed a better-defined trapezoid shape than that of the TVDI. Compared with the MPDI and TVDI for soil moisture monitoring at crop sites, the CVDI exhibited a performance superior to the MPDI and TVDI in most days where the coefficients of determination (R²) achieved can reach to 0.67 on DOY023, 137, 274 and 0.71 on DOY 322 and reproduced more accurate spatial and seasonal variation of soil moisture. Moreover, the CVDI showed higher correlation with the Australian Water Resource Assessment Landscape (AWRA-L) soil moisture product on temporal scales. The R² can reach to 0.69 and the root mean square error (RMSE) is also much better than that of the MPDI and TVDI. Overall, it can be concluded that the CVDI appears to be a feasible method and can be successfully used in regional soil moisture monitoring. Full article

As a basic agricultural parameter in the formation, transformation, and consumption of surface water resources, soil moisture has a very important influence on the vegetation growth, agricultural production, and healthy operation of regional ecosystems. The Aksu river basin is a typical semi-arid agricultural area which seasonally suffers from water shortage. Due to the lack of knowledge on soil moisture change, the water management and decision-making processes have been a difficult issue for local government. Therefore, soil moisture monitoring by remote sensing became a reasonable way to schedule crop irrigation and evaluate the irrigation efficiency. Compared to in situ measurements, the use of remote sensing for the monitoring of soil water content is convenient and can be repetitively applied over a large area. To verify the applicability of the typical drought index to the rapid acquisition of soil moisture in arid and semi-arid regions, this study simulated, compared, and validated the effectiveness of soil moisture inversion. GF-1 WFV images, Landsat 8 OLI images, and the measured soil moisture data were used to determine the Perpendicular Drought Index (PDI), the Modified Perpendicular Drought Index (MPDI), and the Vegetation Adjusted Perpendicular Drought Index (VAPDI). First, the determination coefficients of the correlation analyses on the PDI, MPDI, VAPDI, and measured soil moisture in the 0–10, 10–20, and 20–30 cm depth layers based on the GF-1 WFV and Landsat 8 OLI images were good. Notably, in the 0–10 cm depth layers, the average determination coefficient was 0.68; all models met the accuracy requirements of soil moisture inversion. Both indicated that the drought indices based on the Near Infrared (NIR)-Red spectral space derived from the optical remote sensing images are more sensitive to soil moisture near the surface layer; however, the accuracy of retrieving the soil moisture in deep layers was slightly lower in the study area. Second, in areas of vegetation coverage, MPDI and VAPDI had a higher inversion accuracy than PDI. To a certain extent, they overcame the influence of mixed pixels on the soil moisture spectral information. VAPDI modified by Perpendicular Vegetation Index (PVI) was not susceptible to vegetation saturation and, thus, had a higher inversion accuracy, which makes it performs better than MPDI’s in vegetated areas. Third, the spatial heterogeneity of the soil moisture retrieved by the GF-1 WFV and Landsat 8 OLI image were similar. However, the GF-1 WFV images were more sensitive to changes in the soil moisture, which reflected the actual soil moisture level covered by different vegetation. These results provide a practical reference for the dynamic monitoring of surface soil moisture, obtaining agricultural information and agricultural condition parameters in arid and semi-arid regions. Full article

The daily AMSR-E/NASA (the Advanced Microwave Scanning Radiometer-Earth Observing System/the National Aeronautics and Space Administration) and JAXA (the Japan Aerospace Exploration Agency) soil moisture (SM) products from 2002 to 2011 at 25 km resolution were developed and distributed by the NASA National Snow and Ice Data Center Distributed Active Archive Center (NSIDC DAAC) and JAXA archives, respectively. This study analyzed and evaluated the temporal changes and accuracy of the AMSR-E/NASA SM product and compared it with the AMSR-E/JAXA SM product. The accuracy of both AMSR-E/NASA and JAXA SM was low, with RMSE (root mean square error) > 0.1 cm³ cm⁻³ against the in-situ SM measurements, especially the AMSR-E/NASA SM. Compared with the AMSR-E/JAXA SM, the dynamic range of AMSR-E/NASA SM is very narrow in many regions and does not reflect the intra- and inter-annual variability of soil moisture. We evaluated both data products by building a linear relationship between the SM and the Microwave Polarization Difference Index (MPDI) to simplify the AMSR-E/NASA SM retrieval algorithm on the basis of the observed relationship between samples extracted from the MPDI and SM data. We obtained the coefficients of this linear relationship (i.e., A₀ and A₁) using in-situ measurements of SM and brightness temperature (T_B) data simulated with the same radiative transfer model applied to develop the AMSR-E/NASA SM algorithm. Finally, the linear relationships between the SM and MPDI were used to retrieve the SM monthly from AMSR-E T_B data, and the estimated SM was validated using the in-situ SM measurements in the Naqu area on the Tibetan Plateau of China. We obtained a steeper slope, i.e., A₁ = 8, with the in-situ SM measurements against A₁ = 1, when using the NASA SM retrievals. The low A₁ value is a measure of the low sensitivity of the NASA SM retrievals to MPDI and its narrow dynamic range. These results were confirmed by analyzing a data set collected in Poland. In the case of the Tibetan Plateau, the higher value A₁ = 8 gave more accurate monthly AMSR-E SM retrievals with RMSE = 0.065 cm³ cm⁻³. The dynamic range of the improved retrievals was more consistent with the in-situ SM measurements than with both the AMSR-E/NASA and JAXA SM products in the Naqu area of the Tibetan Plateau in 2011. Full article

This study aims at furthering our understanding of the Modified Philip–Dunne Infiltrometer (MPDI), which is used to determine the saturated hydraulic conductivity K_s and the Green–Ampt suction head Ψ at the wetting front. We have developed a forward-modeling algorithm that can be used to simulate water level changes inside the infiltrometer with time when the soil hydraulic properties K_s and Ψ are known. The forward model was used to generate 30,000 water level datasets using randomly generated values of K_s and Ψ values. These model data were then compared against field-measured water level drawdown data collected for three types of soil. The Nash–Sutcliffe efficiency (NSE) was used to assess the quality of the fit. Results show that multiple sets of the model parameters K_s and Ψ can yield drawdown curves that can fit the field-measured data equally well. Interestingly, all the successful sets of parameters (delineated by NSE ≥ the threshold value) give K_s values converged to a valid range that is fully consistent with the tested soil texture class. However, Ψ values varied significantly and did not converge to a valid range. Based on these results, we conclude that the MPDI is a useful field method to estimate K_s values, but it is not a robust method to estimate Ψ values. Further studies are needed to improve the experimental procedures that can yield more sensitive data that can help uniquely identify K_s and Ψ values. Full article

Continuous daily evapotranspiration (ET) monitoring at the field-scale is crucial for water resource management in irrigated agricultural areas in arid regions. Here, an integrated framework for daily ET, with the required spatiotemporal resolution, is described. Multi-scale surface energy balance algorithm evaluations and a data fusion algorithm are combined to optimally exploit the spatial and temporal characteristics of image datasets, collected by the advanced space-borne thermal emission reflectance radiometer (ASTER) and the moderate resolution imaging spectroradiometer (MODIS). Through combination with a linear unmixing-based method, the spatial and temporal adaptive reflectance fusion model (STARFM) is modified to generate high-resolution ET estimates for heterogeneous areas. The performance of this methodology was evaluated for irrigated agricultural fields in arid and semiarid areas of Northwest China. Compared with the original STARFM, a significant improvement in daily ET estimation accuracy was obtained by the modified STARFM (overall mean absolute percentage error (MAP): 12.9% vs. 17.2%; root mean square error (RMSE): 0.7 mm d⁻¹ vs. 1.2 mm d⁻¹). The modified STARFM additionally preserved more spatial details than the original STARFM for heterogeneous agricultural fields, and provided field-to-field variability in water use. Improvements were further evident in the continuous daily ET, where the day-to-day dynamics of ET estimates were captured. ET data fusion provides a unique means of monitoring continuous daily crop ET values at the field-scale in agricultural areas, and may have value in supporting operational water management decisions. Full article

Accurate continuous daily evapotranspiration (ET) at the field scale is crucial for allocating and managing water resources in irrigation areas, particularly in arid and semi-arid regions. The authors integrated the modified perpendicular drought index (MPDI) as an indicator of water stress into surface energy balance system (SEBS) to improve ET estimation under water-limited conditions. The new approach fed with Chinese satellite HJ-1 (environmental and disaster monitoring and forecasting with a small satellite constellation) images was used to map daily ET on the desert-oasis irrigation fields in the middle of the Heihe River Basin. The outputs, including instantaneous sensible heat flux (H) and daily ET from the MPDI-integrated SEBS and the original SEBS model, were compared with the eddy covariance observations. The results indicate that the MPDI-integrated SEBS significantly improved the surface turbulent fluxes in water-limited regions, especially for sparsely vegetated areas. The new approach only uses one optical satellite data and meteorological data as inputs, providing a considerable operational improvement for ET mapping. Moreover, HJ-1 high-resolution data promised continuous daily ET at the field scale, which helps in understanding the corresponding relationships among field, crop, and water consumption. Such detailed ET information can greatly serve water resources management in the study area as well as other arid and semi-arid regions. Full article