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Keywords = LTCC technology

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12 pages, 7999 KB  
Article
A Transition Structure from Stripline to Substrate-Integrated Waveguide Based on LTCC
by Lu Teng, You Zhou, Ting Zhang, Zhongjun Yu and Shunli Han
Micromachines 2026, 17(2), 155; https://doi.org/10.3390/mi17020155 - 26 Jan 2026
Viewed by 58
Abstract
With the advancement of wireless communication technologies into high-frequency millimeter wave and sub-THz bands, conventional transmission lines such as microstrip and stripline face significant limitations. Under the circumstances, along with the increased application of new transmission lines such as substrate-integrated waveguides (SIWs), the [...] Read more.
With the advancement of wireless communication technologies into high-frequency millimeter wave and sub-THz bands, conventional transmission lines such as microstrip and stripline face significant limitations. Under the circumstances, along with the increased application of new transmission lines such as substrate-integrated waveguides (SIWs), the design of transition structures between different transmission lines has become a practical requirement in modern signal transmission systems. This paper presents a novel stripline to SIW transition structure. Drawing inspiration from the classical microstrip probe techniques in metal waveguides, the proposed design employs Low-Temperature Co-fired Ceramic (LTCC) technology for both device fabrication and SIW implementation. The developed structure demonstrates a stable performance, structural simplicity, and manufacturing feasibility. Through fabrication and testing, the transition structure can achieve a return loss below −10 dB across the 89–100 GHz frequency range, with an insertion loss of approximately 0.75 dB. Full article
(This article belongs to the Special Issue Microwave Passive Components, 3rd Edition)
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19 pages, 3085 KB  
Article
Bismuth-Based Ceramic Processed at Ultra-Low-Temperature for Dielectric Applications
by Susana Devesa, Sílvia Soreto Teixeira, Manuel Pedro Graça and Luís Cadillon Costa
Nanomaterials 2026, 16(1), 46; https://doi.org/10.3390/nano16010046 - 29 Dec 2025
Viewed by 331
Abstract
High-performance dielectric materials that can be processed at ultra-low temperatures are essential for next-generation LTCC technologies and compact RF–microwave components. In this work, a multicomponent Bi–Fe–Nb oxide system was synthesized using a modified citrate sol–gel method and thermally treated at only 400 °C [...] Read more.
High-performance dielectric materials that can be processed at ultra-low temperatures are essential for next-generation LTCC technologies and compact RF–microwave components. In this work, a multicomponent Bi–Fe–Nb oxide system was synthesized using a modified citrate sol–gel method and thermally treated at only 400 °C to investigate its structural evolution and dielectric behavior. XRD and Raman analysis revealed the coexistence of a well-crystallized BiOCl phase embedded within a partially amorphous Bi–Fe–Nb–O matrix. SEM and EDS mapping confirmed the presence of two distinct microstructural regions, reflecting differences in local composition and crystallization kinetics. Microwave measurements at 2.7 and 5.0 GHz showed low dielectric losses and a stable dielectric response. Impedance spectroscopy in the RF range revealed strong Maxwell–Wagner polarization at low frequencies and thermally activated relaxation evidenced by the temperature shift in the modulus and impedance peaks. Arrhenius analysis of the relaxation frequencies yielded similar activation energies from both modulus and impedance formalisms, indicating a single underlying relaxation mechanism. Equivalent-circuit fitting confirmed non-Debye behavior, with nearly temperature-independent capacitance and decreasing resistance consistent with thermally activated conduction. These results demonstrate that the Bi–Fe–Nb system exhibits promising dielectric stability and functional behavior even when processed at exceptionally low temperatures. Full article
(This article belongs to the Special Issue Advanced Ceramics and Polymer Nanocomposites for Energy Storage)
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20 pages, 4134 KB  
Article
Effect of Hyaluronic Acid Content on Functional Properties, Antioxidant Activity, and In Vitro Digestion of Food-Grade Furcellaran Hydrogels and Emulgels
by Anna Stępień, Lesław Juszczak, Aneta Koronowicz, Aleksandra Such, Grzegorz Kowalski, Beata Synkiewicz-Musialska, Piotr Zachariasz and Ewelina Jamróz
Materials 2025, 18(24), 5581; https://doi.org/10.3390/ma18245581 - 12 Dec 2025
Viewed by 298
Abstract
Gel biocomposites, with their wide range of properties, are increasingly popular in many industries, while hyaluronic acid (HA), due to its unique water-binding mechanisms, has a high application potential in these types of materials. Furcellaran-based composite hydrogels and emulsion gels with different HA [...] Read more.
Gel biocomposites, with their wide range of properties, are increasingly popular in many industries, while hyaluronic acid (HA), due to its unique water-binding mechanisms, has a high application potential in these types of materials. Furcellaran-based composite hydrogels and emulsion gels with different HA additions were produced and the effect of HA concentration on physical, color, textural, mechanical, rheological, and antioxidant properties was evaluated. A polysaccharide network was observed, which—according to Fourier transform infrared spectroscopy(FTIR) and X-ray diffraction (XRD) data—is stabilized by hydrogen bonding. Emulsion gels revealed denser structures. Small deformation tests confirmed elastic–solid type of all investigated gels. The opposite effect of HA on the swelling behavior of hydro- and emulgels was observed. Increasing hyaluronic acid content resulted in elasticity enhancement and hardness reduction. Antioxidant potential of composites significantly increased with HA concentration. The obtained materials have potential applications as plat-based delivery systems for hydrophilic and lipophilic bioactive components. Full article
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20 pages, 7738 KB  
Article
A Stacked Substrate-Integrated Waveguide-Based Pyramidal Horn Antenna for Terahertz Communications
by Biswash Paudel, Xue Jun Li and Boon-Chong Seet
Electronics 2025, 14(23), 4780; https://doi.org/10.3390/electronics14234780 - 4 Dec 2025
Viewed by 434
Abstract
The terahertz (THz) band offers ultra-wide bandwidth for next-generation high-speed wireless communication systems. However, achieving compact, high-gain, and beam-symmetric THz antennas remains challenging due to fabrication and propagation constraints. This paper presents a simulation-based design and optimization of a stacked substrate-integrated waveguide (SIW) [...] Read more.
The terahertz (THz) band offers ultra-wide bandwidth for next-generation high-speed wireless communication systems. However, achieving compact, high-gain, and beam-symmetric THz antennas remains challenging due to fabrication and propagation constraints. This paper presents a simulation-based design and optimization of a stacked substrate-integrated waveguide (SIW) pyramidal horn antenna achieving equal half-power beamwidths (HPBWs) in both E- and H-planes. The design employs vertically stacked SIW layers coupled through optimized slot apertures to ensure dominant TE10 mode propagation with minimal reflection. Using full-wave electromagnetic simulations, the effects of layer number, dielectric loading, amplitude tapering, and phase distribution are systematically analyzed. The optimized five-layer configuration exhibits 10 dBi gain, 41° HPBW, and sidelobe levels around −3.2 dB at 210 GHz. This framework aims to develop high-performance, beam-symmetric THz SIW antennas compatible with standard LTCC/PCB technologies. Full article
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3087 KB  
Proceeding Paper
Design of an X-Band TR Module Based on LTCC
by Qingqi Zou and Jie Cui
Eng. Proc. 2025, 118(1), 29; https://doi.org/10.3390/ECSA-12-26546 - 7 Nov 2025
Viewed by 354
Abstract
Phased array radar, with its electronic scanning, high reliability, and multifunctionality, has become a core equipment for unmanned aerial vehicle detection, modern air defense, meteorological monitoring, and satellite communication. The T/R module is the core equipment of the active phased array radar, and [...] Read more.
Phased array radar, with its electronic scanning, high reliability, and multifunctionality, has become a core equipment for unmanned aerial vehicle detection, modern air defense, meteorological monitoring, and satellite communication. The T/R module is the core equipment of the active phased array radar, and its performance largely determines the performance of the phased array. At the same time, the application scenario requires relatively high transmission gain and transmission power, so attention should be paid to its heating situation. In addition, the overall size requirements for components are gradually becoming stricter, and miniaturization has become a trend in the development of T/R modules. This paper presents a four-channel T/R module in an X-band based on LTCC technology. In order to reduce weight and have high-density electronic devices, this module uses the latest technologies such as low-temperature cofired ceramic substrate (LTCC), Monolithic Microwave Integrated Chip (MMIC), and the MIC assembly process, and is hermetically sealed. The transmission channel of this module has high gain and high power, and the RF signal is transmitted through an eight-layer LTCC board to reduce interference between adjacent signal transmission lines and reduce the module size at the same time. The method of dividing the transmission and reception channels using a metal shell frame reduces crosstalk between the input and output ports of the transmission channel. Good heat dissipation design ensures the thermal management of the module. The test results show that the size of the TR module is 70 mm × 55 mm × 10 mm, the transmission power is ≥39 dBm, the reception gain is >28 dB, and the noise figure is <3 dB. Full article
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15 pages, 6959 KB  
Article
Impact of AlF3-CaB4O7 Doping on Terahertz Dielectric Properties and Feasibility of Low/Ultra-Low Temperature Co-Fired Ceramics
by Beata Synkiewicz-Musialska and Dorota Szwagierczak
Materials 2025, 18(18), 4272; https://doi.org/10.3390/ma18184272 - 12 Sep 2025
Cited by 1 | Viewed by 536
Abstract
Modification of the composition by doping is an effective way to develop new substrate materials for 5G/6G communication systems. This paper aims to study the impact of AlF3-CaB4O7 doping on dielectric properties at very high frequencies, sintering temperature, [...] Read more.
Modification of the composition by doping is an effective way to develop new substrate materials for 5G/6G communication systems. This paper aims to study the impact of AlF3-CaB4O7 doping on dielectric properties at very high frequencies, sintering temperature, microstructure, and feasibility in LTCC/ULTCC (low/ultra-low temperature cofired ceramics) technology of four low dielectric permittivity materials based on CuB2O4, Zn2SiO4, LiBO2, and Li2WO4. Sintering behavior, microstructure, elemental and phase composition, and dielectric properties in the terahertz range were characterized using a heating microscope, SEM, EDS, XRD methods, and time domain spectroscopy. The developed ceramics exhibit excellent dielectric behavior at terahertz frequencies and are feasible in ULTCC or LTCC technology. These properties make them good candidates for substrates in 5G/6G communication systems. Full article
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29 pages, 9470 KB  
Review
Millimeter-Wave Antennas for 5G Wireless Communications: Technologies, Challenges, and Future Trends
by Yutao Yang, Minmin Mao, Junran Xu, Huan Liu, Jianhua Wang and Kaixin Song
Sensors 2025, 25(17), 5424; https://doi.org/10.3390/s25175424 - 2 Sep 2025
Cited by 2 | Viewed by 6949
Abstract
With the rapid evolution of 5G wireless communications, millimeter-wave (mmWave) technology has become a crucial enabler for high-speed, low-latency, and large-scale connectivity. As the critical interface for signal transmission, mmWave antennas directly affect system performance, reliability, and application scope. This paper reviews the [...] Read more.
With the rapid evolution of 5G wireless communications, millimeter-wave (mmWave) technology has become a crucial enabler for high-speed, low-latency, and large-scale connectivity. As the critical interface for signal transmission, mmWave antennas directly affect system performance, reliability, and application scope. This paper reviews the current state of mmWave antenna technologies in 5G systems, focusing on antenna types, design considerations, and integration strategies. We discuss how the multiple-input multiple-output (MIMO) architectures and advanced beamforming techniques enhance system capacity and link robustness. State-of-the-art integration methods, such as antenna-in-package (AiP) and chip-level integration, are examined for their importance in achieving compact and high-performance mmWave systems. Material selection and fabrication technologies—including low-loss substrates like polytetrafluoroethylene (PTFE), hydrocarbon-based materials, liquid crystal polymer (LCP), and microwave dielectric ceramics, as well as emerging processes such as low-temperature co-fired ceramics (LTCC), 3D printing, and micro-electro-mechanical systems (MEMS)—are also analyzed. Key challenges include propagation path limitations, power consumption and thermal management in highly integrated systems, cost–performance trade-offs for mass production, and interoperability standardization across vendors. Finally, we outline future research directions, including intelligent beam management, reconfigurable antennas, AI-driven designs, and hybrid mmWave–sub-6 GHz systems, highlighting the vital role of mmWave antennas in shaping next-generation wireless networks. Full article
(This article belongs to the Special Issue Millimeter-Wave Antennas for 5G)
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17 pages, 3277 KB  
Article
Design and Evaluation of Micromixers Fabricated with Alternative Technologies and Materials for Microanalytical Applications In Situ
by Rosa M. Camarillo-Escobedo, Jorge L. Flores, Juana M. Camarillo-Escobedo, Elizabeth Hernandez-Campos and Luis H. Garcia-Muñoz
Chemosensors 2025, 13(5), 191; https://doi.org/10.3390/chemosensors13050191 - 21 May 2025
Cited by 1 | Viewed by 1093
Abstract
Micromixing is a crucial process in microfluidic systems. In biochemical and chemical analysis, the sample is usually tested with reagents. These solutions must be well mixed for the reaction to be possible, generally using micromixers manufactured with sophisticated and expensive technology. The present [...] Read more.
Micromixing is a crucial process in microfluidic systems. In biochemical and chemical analysis, the sample is usually tested with reagents. These solutions must be well mixed for the reaction to be possible, generally using micromixers manufactured with sophisticated and expensive technology. The present work shows the design and evaluation of micromixers fabricated with LTCC (low-temperature co-fired ceramics) and FDM (fused deposition modeling) technologies for the development of functional and complex geometries. Two-dimensional planar serpentine and 3D chaotic convection serpentine micromixers were manufactured and implemented in an automated microanalytical system using photometric methods. To evaluate the performance of the micromixers, flow, mixing and absorbance measurements were carried out. Green tape and PP materials were used and showed good resistance to the acidic chemical solutions. The devices presented achieved mixing times in seconds, a reduced dispersion due to their aspect ratio, high sensitivity, and precision in photometric measurement. The optical sensing cells stored sample volumes in a range of 10 to 600 µL, which allowed the reduction of reagent consumption and waste generation. These are ideal characteristics for in situ measurement, portable, and low-cost applications focused on green chemistry and biochemistry. Full article
(This article belongs to the Section Analytical Methods, Instrumentation and Miniaturization)
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17 pages, 10237 KB  
Review
Research Progress on Micromachining Technologies Used to Fabricate Terahertz Micro-Metallic Rectangular Cavity Structures
by Xiaolei Bi, Xuemin Li, Bin Li and Xueli Cheng
Micromachines 2025, 16(5), 518; https://doi.org/10.3390/mi16050518 - 28 Apr 2025
Cited by 1 | Viewed by 1538
Abstract
Terahertz metal rectangular cavity structures are widely used in terahertz devices due to their performance advantages, and various microfabrication techniques have been applied to the manufacturing of their high performance. In this paper, several typical application fields of terahertz technology and the reasons [...] Read more.
Terahertz metal rectangular cavity structures are widely used in terahertz devices due to their performance advantages, and various microfabrication techniques have been applied to the manufacturing of their high performance. In this paper, several typical application fields of terahertz technology and the reasons for its application in these fields are elaborated in detail. Several typical terahertz devices with terahertz metal rectangular cavity structures are introduced in detail. The research progress of various micromachining techniques for manufacturing terahertz rectangular cavity structures, such as DRIE, UV-LIGA, micro-milling, LTCC, 3D printing, and electrochemical micromachining, is discussed in detail. Finally, the advantages and disadvantages of various micromachining techniques for manufacturing terahertz micro-rectangular cavity structures are discussed, and the results show that electrochemical micromachining technology and micro-nano 3D printing technology are relatively promising methods for the manufacturing of high-frequency terahertz rectangular cavity structures. Full article
(This article belongs to the Section E:Engineering and Technology)
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13 pages, 4498 KB  
Article
BaCo0.06Bi0.94O3-Doped NiZn Ferrites for High Frequency Low Loss Current Sensors: LTCC Sintering and Magnetic Properties
by Shao-Pu Jiang, Chang-Lai Yuan, Wei Liu, Lin Li, Huan Li and Jing-Tai Zhao
Sensors 2025, 25(9), 2731; https://doi.org/10.3390/s25092731 - 25 Apr 2025
Cited by 2 | Viewed by 1339
Abstract
In order to meet the demand for high-frequency current sensors in 5G communication and new energy fields, there is an urgent need to develop high-performance nickel-zinc ferrite-based co-fired ceramic magnetic cores. In this study, a nickel-zinc ferrite core based on low temperature co-fired [...] Read more.
In order to meet the demand for high-frequency current sensors in 5G communication and new energy fields, there is an urgent need to develop high-performance nickel-zinc ferrite-based co-fired ceramic magnetic cores. In this study, a nickel-zinc ferrite core based on low temperature co-fired ceramic (LTCC) technology was developed. The regulation mechanism of BaCo0.06Bi0.94O3 doping on the low-temperature sintering characteristics of NiZn ferrites was systematically investigated. The results show that the introduction of BaCo0.06Bi0.94O3 reduces the sintering temperature to 900 °C and significantly improves the density and grain uniformity of ceramics. When the doping amount is 0.75 wt%, the sample exhibits the lowest coercivity of 35.61 Oe and the following optimal soft magnetic properties: initial permeability of 73.74 (at a frequency of 1 MHz) and quality factor of 19.64 (at a frequency of 1 MHz). The highest saturation magnetization reaches 66.07 emu/g at 1 wt% doping. The results show that BaCo0.06Bi0.94O3 doping can regulate the grain boundary liquid phase distribution and modulate the magnetocrystalline anisotropy, which provides an experimental basis and optimization strategy for the application of LTCC technology in high-frequency current sensors. Full article
(This article belongs to the Special Issue New Sensors Based on Inorganic Material)
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15 pages, 8617 KB  
Article
Integrated Sensors Based on Low-Temperature Co-Fired Ceramic Technology for the Inside Pressure and Temperature Monitoring of Lithium-Ion Batteries
by Wanjia Han, Mingsheng Ma, Yitong Guo, Zexi Yang, Zeyan Liu, Feng Liu, Jingjing Feng, Faqiang Zhang, Yingchun Lyu, Shigang Lu, Yongxiang Li, Jianjiang Bian and Zhifu Liu
Sensors 2025, 25(7), 2095; https://doi.org/10.3390/s25072095 - 27 Mar 2025
Cited by 1 | Viewed by 3745
Abstract
Monitoring internal pressure and temperature in lithium-ion batteries is essential for investigating internal chemical reactions, failure mechanisms, and providing early warnings of thermal runaway. The existing sensors face challenges in withstanding the high temperatures and corrosive electrolytes inside lithium-ion batteries. This work develops [...] Read more.
Monitoring internal pressure and temperature in lithium-ion batteries is essential for investigating internal chemical reactions, failure mechanisms, and providing early warnings of thermal runaway. The existing sensors face challenges in withstanding the high temperatures and corrosive electrolytes inside lithium-ion batteries. This work develops an integrated sensor with high robustness using low-temperature co-fired ceramic (LTCC) technology, which incorporates a multilayer ceramic circuit board, a digital pulse temperature sensor, a MEMS pressure sensor, and a microcontroller. It offers the real-time monitoring of pressure and temperature with digital output and calibrated accuracy, achieving a pressure resolution of 1 kPa with 0.085% F.S. accuracy and a temperature resolution of 0.1 °C with deviations under 0.5 °C. The pressure and temperature signals are independently output with drift below 0.067 kPa/°C. The integrated sensors were implanted into a pouch and prototype lithium-ion battery, respectively, for charge–discharge cycle monitoring. The results demonstrated that the integrated sensors could detect cyclic variations in pressure and temperature during charging and discharging until battery failure. Furthermore, the integrated sensors showed high stability after being immersed 60 days in the corrosive electrolyte, suggesting their potential as a novel method for monitoring the internal pressure and temperature of lithium-ion batteries. Full article
(This article belongs to the Section Physical Sensors)
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17 pages, 23179 KB  
Article
Impact of Bonding Pressure on the Reactive Bonding of LTCC Substrates
by Erik Wiss, Nesrine Jaziri, Jens Müller and Steffen Wiese
Micromachines 2025, 16(3), 321; https://doi.org/10.3390/mi16030321 - 11 Mar 2025
Cited by 4 | Viewed by 1312
Abstract
Reactive bonding can overcome the issues associated with conventional soldering processes, such as potential damage to heat-sensitive components and the creation of thermomechanical stress due to differing coefficients of thermal expansion. The risk of such damage can be reduced by using localized heat [...] Read more.
Reactive bonding can overcome the issues associated with conventional soldering processes, such as potential damage to heat-sensitive components and the creation of thermomechanical stress due to differing coefficients of thermal expansion. The risk of such damage can be reduced by using localized heat sources like reactive multilayer systems (RMS), which is already a well-established option in the field of silicon or metal bonding. Adapting this process to other materials, such as low temperature co-fired ceramics (LTCC), is difficult due to their differing properties, but it would open new technological possibilities. One aspect that significantly affects the quality of the bonding joints is the pressure applied during the bonding process. To investigate its influence more closely, various LTCC samples were manufactured, and cross-sections were prepared. The microscopical analysis reveals that there is an optimum range for the bonding pressure. While too little pressure results in the formation of lots of voids and gaps, most likely in poor mechanical and electrical properties, too high pressure seems to cause a detachment of the metallization from the base material. Full article
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13 pages, 4920 KB  
Article
Multilayered Manufacturing Method for Microfluidic Systems Using Low-Cost, Resin-Based Three-Dimensional Printing
by Victor Edi Manqueros-Avilés, Hesner Coto-Fuentes, Karla Victoria Guevara-Amatón, Francisco Valdés-Perezgasga and Julian Alonso-Chamarro
Sensors 2025, 25(3), 694; https://doi.org/10.3390/s25030694 - 24 Jan 2025
Viewed by 3622
Abstract
This work presents a multilamination method for fabricating microfluidic devices or analytical microsystems using commercial 3D printers and photocurable resins as primary components. The developed method was validated by fabricating devices for the colorimetric measurement of copper ions in aqueous solutions, achieving results [...] Read more.
This work presents a multilamination method for fabricating microfluidic devices or analytical microsystems using commercial 3D printers and photocurable resins as primary components. The developed method was validated by fabricating devices for the colorimetric measurement of copper ions in aqueous solutions, achieving results comparable to traditional cyclic olefin copolymer (COC) systems. The microfluidic platforms demonstrated stability and functionality over a twelve-week testing period. Channels with minimum dimensions of 0.4 mm × 0.4 mm were fabricated, and the feasibility of using resin modules for optical applications was demonstrated. This study highlights the potential of combining 3D printing with multilamination procedures as a versatile alternative, offering flexibility through the selection of a variety of available resins and commercial printers, as well as the ease of design development. This method offers significant reductions in cost, time, and manufacturing complexity by eliminating the need for equipment such as CNC machines, presses, and ovens, which are typically required in other multilamination technologies like LTCC and COC. Full article
(This article belongs to the Collection Microfluidic Sensors)
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11 pages, 6207 KB  
Article
A Generalized Design of On-Chip LTCC Balanced Filters Using Novel Hybrid Resonators with Intrinsic Ultra-Wideband Suppression for 5G Applications
by Wei Zhao, Yongle Wu, Zuoyu Xu and Weimin Wang
Electronics 2025, 14(1), 17; https://doi.org/10.3390/electronics14010017 - 24 Dec 2024
Viewed by 1592
Abstract
In this paper, we examine an ultra-compact on-chip balanced filter based on novel hybrid resonators (NHRs) comprising short transmission line sections (STLSs) and series LC blocks using low-temperature co-fired ceramic (LTCC) technology. Based on a rigorous theoretical analysis, the proposed NHR demonstrates the [...] Read more.
In this paper, we examine an ultra-compact on-chip balanced filter based on novel hybrid resonators (NHRs) comprising short transmission line sections (STLSs) and series LC blocks using low-temperature co-fired ceramic (LTCC) technology. Based on a rigorous theoretical analysis, the proposed NHR demonstrates the potential for intrinsic ultra-wideband differential-mode (DM) and common-mode (CM) suppression without any additional suppressing structures. Furthermore, the resonance of NHRs was determined by four degrees of freedom, providing flexibility for miniaturization. Theoretical extensions of the Nth-order topology can be easily achieved by the simple coupling schemes that occur exclusively between STLSs. For verification, a balanced filter covering the 5G band n78 with an area of 0.065λg × 0.072λg was designed using the proposed optimization-based design procedure. An ultra-low insertion loss of 0.8 dB was obtained. The quasi-full CM stopband with a 20 dB rejection level ranged from 0 to 12.9 GHz. And the ultra-wide upper DM stopband with a 20 dB rejection level ranged from 4.4 to 11.5 GHz. Good agreement between the theoretical, simulated, and measured results indicate the validity of the proposed design principle. Full article
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13 pages, 13370 KB  
Article
Low-Temperature Sintering and Microwave Dielectric Properties of CuxZn1−xTi0.2Zr0.8Nb2O8 Ceramics with the Aid of LiF
by Xing-Hua Ma, Qi Qu, Haitao Wu, Zhenlu Zhang and Xingyi Ma
Materials 2024, 17(24), 6251; https://doi.org/10.3390/ma17246251 - 20 Dec 2024
Cited by 2 | Viewed by 1431
Abstract
M2+N4+Nb2O8-type ceramics (where M = Mg, Ca, Mn, Co, Ni, Zn and N = Ti, Zr) are essential for satellite communication and mobile base stations due to their medium relative permittivity (εr) [...] Read more.
M2+N4+Nb2O8-type ceramics (where M = Mg, Ca, Mn, Co, Ni, Zn and N = Ti, Zr) are essential for satellite communication and mobile base stations due to their medium relative permittivity (εr) and high quality factor (Q × f). Although ZnTi0.2Zr0.8Nb2O8 ceramic exhibits impressive microwave dielectric properties, including an εr of 29.75, a Q × f of 107,303 GHz, and a τf of −24.41 ppm/°C, its sintering temperature of 1150 °C remains a significant barrier for integration into low-temperature co-fired ceramic (LTCC) technologies. To overcome this limitation, a strategy involving the partial substitution of Zn2+ with Cu2+ and the addition of LiF as a sintering aid was devised for ZnTi0.2Zr0.8Nb2O8. The dual impact of Cu2+ partial substitution and LiF as a sintering enhancer facilitated the successful sintering of Cu0.3Zn0.7Ti0.2Zr0.8Nb2O8 ceramics at a reduced temperature of 950 °C using the conventional solid-state reaction method. These ceramics exhibited excellent microwave dielectric properties. Notably, Cu0.3Zn0.7Ti0.2Zr0.8Nb2O8 ceramic with 40 mol% LiF addition demonstrated optimal microwave dielectric properties without any reaction with a silver electrode at a sintering temperature of 950 °C, yielding εr = 32, Q × f = 45,543 GHz, and τf = −43.5 ppm/°C. Full article
(This article belongs to the Section Advanced and Functional Ceramics and Glasses)
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